A kind of impregnated porous copper self-lubricating bearing cage material and its preparation method and application
By immersing supramolecular gel lubricant in the porous copper bearing cage material to form a three-dimensional network structure, the problems of low oil content and oil retention are solved, and efficient lubrication and low wear bearing performance are achieved, which is suitable for high-speed environments.
Patent Information
- Application Number
- CN202411833555.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-12-13
- Publication Date
- 2025-10-03
- Estimated Expiration
- 2044-12-13
AI Technical Summary
Existing oil-containing bearing cage materials have high oil loss during high-speed operation, and low oil content and oil retention, which affects the lubrication effect and service life. Liquid lubricants also pose a risk of leakage and environmental pollution.
A porous copper material with a porosity of more than 30% is used as the matrix and is immersed in a supramolecular gel lubricant. The gel factors include N-dodecyl-2,4-(3,4-dichlorobenzyl)-D-glucamide and bis(stearate) lipoic acid aluminum, forming a three-dimensional network structure to improve oil retention and tribological properties.
It achieves high oil content and high oil retention rate, reduces lubricant loss, improves the lubrication performance and tribological properties of the bearing, has a wide applicable temperature range, and the oil retention rate can reach 90% especially at high speeds.
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Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of lubricating materials, and in particular to an impregnated porous copper self-lubricating bearing cage material, a preparation method thereof, and applications thereof. Background Art
[0002] With the development of modern science and technology, high-precision mechanical components are widely used in many fields such as aerospace, electronic manufacturing, etc. These fields have extremely high requirements for the precision and stability of mechanical components, and put forward more stringent requirements for reducing the negative impact of friction and wear.
[0003] Liquid lubricants have a risk of leakage during the use of equipment, which will not only cause waste of lubricants or even lubrication failure, but may also pollute the environment and other components around the equipment. The leakage of liquid lubricants poses a potential pollution to the environment. If liquid lubricants enter water bodies or soil, they will cause harm to the environment. In order to solve the sealing problem of the lubrication system, some oil-containing self-lubricating materials have been developed. The related art discloses a metal-polymer composite oil-containing bearing retainer material. The oil-containing bearing retainer itself can store and release lubricating oil, and can continuously provide lubrication for bearings and other components during the operation of the equipment. However, the oil content and oil retention rate of current oil-containing bearing retainer materials are still relatively low, and there is a problem of high oil loss when the bearings run at high speeds. This not only limits its scope of use, but also seriously affects the lubrication effect and service life of the bearings. Summary of the Invention
[0004] In view of this, the present invention provides a gel-impregnated porous copper self-lubricating bearing cage material and its preparation method and application. The gel-impregnated porous copper self-lubricating bearing cage material provided by the present invention has high oil content and high oil retention rate, and has better tribological properties.
[0005] In order to achieve the above-mentioned object of the invention, the present invention provides the following technical solutions:
[0006] A gel-impregnated porous copper self-lubricating bearing cage material comprises porous copper and a supramolecular gel lubricant impregnated into the pores of the porous copper; the supramolecular gel lubricant comprises a base oil and a gelling factor; the gelling factor comprises one or two of N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide and aluminum bis(stearate) lipoate; the porosity of the porous copper is greater than 30%.
[0007] Preferably, the pore size of the porous copper is in the micron level; the porosity of the porous copper is 30-70%.
[0008] Preferably, the method for preparing the porous copper preferably comprises the following steps: mixing copper powder and iron powder and sintering them to obtain a copper-iron precursor; and soaking the copper-iron precursor in an acid solution to obtain the porous copper.
[0009] Preferably, the base oil includes one or more of PAO4, PAO10, 150SN and 500SN.
[0010] Preferably, the mass percentage of the gelling factor in the supramolecular gel lubricant is 1 to 10%.
[0011] Preferably, when the gel factor is N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide, the mass percentage of the gel factor in the supramolecular gel lubricant is 2-3%; when the gel factor is aluminum bis(stearate) lipoate, the mass percentage of the gel factor in the supramolecular gel lubricant is 5-6%.
[0012] The present invention also provides a method for preparing the impregnated porous copper self-lubricating bearing cage material described in the above scheme, comprising the following steps:
[0013] heating and mixing the gelling factor and the base oil to obtain a gelling factor oil solution;
[0014] The porous copper is immersed in the gel factor oil solution and then cooled to obtain the gel-impregnated porous copper self-lubricating bearing cage material.
[0015] Preferably, the heating and mixing is carried out at a temperature of 170 to 190° C. and for a time of 15 to 30 minutes.
[0016] Preferably, the soaking temperature is above 160° C., the vacuum degree is below -0.8 bar, and the soaking time is 4 to 10 hours.
[0017] The present invention also provides the use of the impregnated porous copper self-lubricating bearing cage material described in the above scheme or the impregnated porous copper self-lubricating bearing cage material prepared by the preparation method described in the above scheme in lubricating mechanical parts.
[0018] The present invention provides an impregnated gel porous copper self-lubricating bearing retainer material, comprising porous copper and a supramolecular gel lubricant impregnated into the pores of the porous copper; the supramolecular gel lubricant comprises a base oil and a gel factor; the gel factor comprises one or two of N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide bis(stearate) lipoic acid aluminum; the porosity of the porous copper is greater than 30%. The porous copper of the present invention has a higher porosity, can store more lubricant, and has a higher oil content; the gel factor used in the present invention can form a three-dimensional network structure through non-covalent interaction, achieve efficient capture of the base oil, and thereby effectively avoid lubricant loss inside the porous copper. Compared with ordinary oil-containing retainers, the impregnated gel porous copper self-lubricating bearing retainer material of the present invention significantly improves the oil retention rate. The results of the examples show that when the gel factor is aluminum bis(stearate) lipoate, the impregnated porous copper self-lubricating bearing cage material of the present invention can achieve an oil retention rate of approximately 90% at high rotational speeds. Furthermore, the phase transition temperature of the gel factor used in the present invention is above 150°C, resulting in a wide applicable temperature range for the impregnated porous copper self-lubricating bearing cage material. In summary, the impregnated porous copper self-lubricating bearing cage material provided by the present invention has high oil content and oil retention, exhibits superior lubrication properties, and can be used in various bearings to avoid lubricant loss and improve bearing lubrication performance. BRIEF DESCRIPTION OF THE DRAWINGS
[0019] Figure 1 The friction coefficient of the self-lubricating bearing retainer material prepared in Example 1, Example 3 and Comparative Example 1 is a trend diagram of changes over time;
[0020] Figure 2 The friction coefficient of the self-lubricating bearing retainer material prepared in Example 2, Example 4 and Comparative Example 2 is a trend diagram over time;
[0021] Figure 3 The oil retention test results of the self-lubricating bearing cage materials prepared in Example 1, Example 3 and Comparative Example 1 at different speeds;
[0022] Figure 4 These are the test results of oil retention rates of the self-lubricating bearing retainer materials prepared in Example 2, Example 4 and Comparative Example 2 at different rotational speeds. DETAILED DESCRIPTION
[0023] The present invention provides a gel-impregnated porous copper self-lubricating bearing retainer material, comprising porous copper and a supramolecular gel lubricant impregnated into the pores of the porous copper; the supramolecular gel lubricant comprises a base oil and a gel factor; the gel factor comprises one or two of N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide and aluminum bis(stearate) lipoate; the porosity of the porous copper is greater than 30%.
[0024] The present invention provides an impregnated porous copper self-lubricating bearing retainer material comprising porous copper. In the present invention, the pore size of the porous copper is preferably micrometer-sized, more preferably 0.5 to 20 μm; the porosity of the porous copper is greater than 30%, preferably 30 to 70%, and more preferably 40%, 50%, or 60%. The present invention utilizes porous copper with such a porosity to increase the oil content of the impregnated porous copper self-lubricating bearing retainer material.
[0025] In the present invention, the preparation method of the porous copper preferably includes the following steps: mixing copper powder and iron powder and sintering them to obtain a copper-iron precursor; soaking the copper-iron precursor in an acid solution to obtain the porous copper. In the present invention, taking the total molar amount of the copper powder and the iron powder as 100%, the molar fraction of the iron powder is preferably 30-70%, more preferably 40-60%; the present invention has no special requirements for the particle size of the copper powder and the iron powder, and can adopt those known to those skilled in the art. In a specific embodiment of the present invention, the particle size of the copper powder is 0.5 μm, and the particle size of the iron powder is 5 μm; the mixing is preferably ball milling, and the ball milling time is preferably 18-24 hours; the ball milling is preferably carried out in a light ball mill; the sintering is preferably plasma activated sintering, and the sintering temperature is preferably 700-8 00℃, the pressure is preferably 50-60MPa, the time is preferably 5-8min, and the heating rate to the sintering temperature is preferably 40-50℃ / min; in a specific embodiment of the present invention, the copper-iron mixed powder obtained by mixing is preferably loaded into a graphite mold for sintering; before the soaking, the copper-iron precursor is preferably cut and polished; the acid solution is preferably a sulfuric acid solution, and the mass fraction of the sulfuric acid solution is preferably 5-10%; the soaking temperature is preferably 80-90℃, and the soaking is performed until no bubbles are generated; after the soaking is completed, the obtained porous copper is preferably soaked alternately with deionized water and ethanol.
[0026] The present invention provides an impregnated porous copper self-lubricating bearing retainer material comprising a supramolecular gel lubricant impregnated into the pores of the porous copper. In the present invention, the supramolecular gel lubricant comprises a base oil and a gelling factor; the gelling factor comprises one or both of N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide and aluminum bis(stearate) lipoate; the structural formula of the N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide is shown in Formula I; the structural formula of the aluminum bis(stearate) lipoate is shown in Formula II;
[0027]
[0028] In the present invention, the base oil preferably includes one or more of PAO4, PAO10, 150SN, and 500SN; the mass percentage of the gel factor in the supramolecular gel lubricant is preferably 1-10%; when the gel factor is N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide, the mass percentage of the gel factor in the supramolecular gel lubricant is preferably 2-3%; when the gel factor is aluminum bis(stearate) lipoate, the mass percentage of the gel factor in the supramolecular gel lubricant is preferably 5-6%. The gel factor used in the present invention can form a three-dimensional network structure through non-covalent interaction, achieving efficient capture of the base oil, thereby effectively preventing lubricant loss within the porous copper and improving the oil retention rate of the impregnated porous copper self-lubricating bearing cage material. In particular, when aluminum bis(stearate) lipoate is used, the oil retention rate at high speed can reach about 90%.
[0029] The gel-impregnated porous copper self-lubricating bearing cage material provided by the present invention has a high oil retention rate, still contains a large amount of gel lubricant after high-speed operation, has less oil loss, and has better lubrication performance; and, compared with oil-impregnated bearings with the same oil content, the gel-impregnated porous copper self-lubricating bearing cage material provided by the present invention has better tribological performance, mainly because the gel factor greatly improves the tribological performance of the base oil, and when the gel factor is aluminum bis(stearate) lipoate, it can also avoid oxidation of porous copper wear debris, thereby greatly improving the tribological performance of the material.
[0030] The present invention also provides a method for preparing the impregnated porous copper self-lubricating bearing cage material described in the above scheme, comprising the following steps:
[0031] heating and mixing the gelling factor and the base oil to obtain a gelling factor oil solution;
[0032] The porous copper is immersed in the gel factor oil solution and then cooled to obtain the gel-impregnated porous copper self-lubricating bearing cage material.
[0033] The present invention heats and mixes the gelling factor and base oil to obtain a gelling factor oil solution. In the present invention, the heating and mixing temperature is preferably 170 to 190° C., specifically 170° C., 180° C., or 190° C., and the heating and mixing time is preferably 15 to 30 minutes.
[0034] After obtaining the gel factor oil solution, the present invention soaks the porous copper in the gel factor oil solution and then cools it to obtain the impregnated gel porous copper self-lubricating bearing retainer material. In the present invention, the soaking temperature is preferably above 160°C, more preferably 170-190°C, specifically 170°C, 180°C or 190°C; the soaking vacuum is preferably below -0.8 Bar, and the soaking time is preferably 4-10h, more preferably 5-6h. The present invention soaks under the above conditions, so that the gel factor oil solution can fully enter the tiny pores of the porous copper. After the soaking is completed, the present invention preferably cools the gel factor oil solution soaked with the porous copper to room temperature, then takes out the porous copper and wipes off the attached supramolecular gel lubricant to obtain the impregnated gel porous copper self-lubricating bearing retainer material.
[0035] The present invention also provides the use of the impregnated porous copper self-lubricating bearing cage material described in the above scheme, or the impregnated porous copper self-lubricating bearing cage material prepared by the preparation method described in the above scheme, in the lubrication of mechanical components. The present invention has no particular requirements for the specific method of application, and methods familiar to those skilled in the art can be used.
[0036] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions of the present invention. Obviously, the embodiments described are only some embodiments of the present invention, not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative efforts are within the scope of protection of the present invention.
[0037] In the following examples, N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide was prepared by the following method:
[0038] 3,4-Dichlorobenzaldehyde (0.05 mol) was dissolved in 40 mL of methanol at room temperature to obtain a 3,4-dichlorobenzaldehyde solution. 215.8 g (0.055 mol) of a 50 wt% aqueous D-gluconic acid solution was then added to the 3,4-dichlorobenzaldehyde solution. Concentrated hydrochloric acid (20 mL) was then added with vigorous stirring. The reaction mixture was stirred for 36 hours and filtered to collect the white solid. The filter cake was washed with water until neutral and then washed twice with hot dichloromethane to obtain methyl 2,4-(3,4-dichlorobenzylidene)-D-gluconate. Dissolve 2,4-(3,4-dichlorobenzylidene)-D-gluconic acid methyl ester (0.01 mol) in 50 mL of methanol, add n-dodecylamine (0.03 mol) and DMAP (0.005 mmol), stir for 12 h, add 20 mL of water, collect the white solid by filtration, wash the filter cake with hot dichloromethane twice, and recrystallize from methanol to obtain N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide.
[0039] In the following examples, aluminum bis(stearate) lipoate was prepared by the following method:
[0040] Dissolve lipoic acid (0.01 mol) and stearic acid (0.02 mol) in chloroform (50 mL). Add aluminum isopropoxide (0.01 mol) in chloroform (50 mL) to the solution. Heat to 55°C with stirring for 6 hours. After the reaction is complete, remove the solvent in vacuo to obtain aluminum bis(stearate) lipoate.
[0041] Example 1
[0042] 32g of Cu powder (particle size 0.5μm) and 28g of Fe powder (particle size 5μm) were mixed in a light ball mill for 24h, and then the mixed powder was placed in a graphite mold and sintered at 800℃, 50MPa for 5min, with a heating rate of 50℃ / min, to obtain a Cu50Fe50 alloy precursor. After cutting and polishing, the Cu50Fe50 alloy precursor was placed in a prepared 10wt.% H2SO4 solution and heated at 90℃. When no more bubbles were generated in the solution, the porous copper sample was taken out and then alternately soaked in deionized water and ethanol, each treatment was repeated 3 times, and each soaking was 15min. The porous copper block M50 was obtained. After testing, the average pore size of M50 was 1.9 microns and the porosity was 47%.
[0043] 0.4 g of N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide was added to 20 g of PAO10 lubricating oil, and the mixture was stirred at 180° C. for 20 min to obtain oil solution A.
[0044] Porous copper M50 was immersed in hot oil solution A and placed in a vacuum oven at -0.8 bar and 180°C for 5 hours. The oil solution was then removed from the vacuum oven and allowed to cool to room temperature under atmospheric pressure. The porous copper block was then removed from the oil solution and the excess gel on the surface was wiped clean with a dust-free cloth, yielding a gel-impregnated porous copper self-lubricating bearing cage material.
[0045] Example 2
[0046] After 25g of Cu powder (particle size 0.5μm) and 33g of Fe powder (particle size 5μm) were mixed in a light ball mill for 24h, the mixed powder was placed in a graphite mold and sintered at 800℃, -50MPa for 5min, with a heating rate of 50℃ / min to obtain a Cu40Fe60 alloy precursor. After cutting and polishing, the Cu40Fe60 alloy precursor was placed in a prepared 10wt.% H2SO4 solution and heated at 90℃. When no bubbles were generated in the solution, the porous copper sample was taken out and then alternately soaked in deionized water and ethanol, each treatment was repeated 3 times, and each soaking was 15min. The porous copper block M60 was obtained. After testing, the average pore size of M60 was 1.6 microns and the porosity was 56%.
[0047] The preparation method of oil solution A is the same as that in Example 1.
[0048] Porous copper M60 was immersed in hot oil solution A and placed in a vacuum oven at -0.8 bar and 180°C for 5 hours. The oil solution was then removed from the vacuum oven and allowed to cool to room temperature under atmospheric pressure. The porous copper block was then removed from the gel and the excess gel on the surface was wiped clean with a dust-free cloth, yielding a gel-impregnated porous copper self-lubricating bearing cage material.
[0049] Example 3
[0050] The preparation method of the porous copper block M50 is the same as that in Example 1.
[0051] 1 g of aluminum bis(stearate) lipoate was added to 20 g of PAO10 lubricating oil, and the mixture was stirred at 170° C. for 20 min to obtain oil solution B.
[0052] Porous copper M50 was immersed in hot oil solution B and placed in a vacuum oven at -0.8 bar and 180°C for 5 hours. The oil solution was then removed from the vacuum oven and allowed to cool to room temperature under atmospheric pressure. The porous copper block was then removed from the gel and the excess gel on the surface was wiped clean with a dust-free cloth, yielding a gel-impregnated porous copper self-lubricating bearing cage material.
[0053] Example 4
[0054] The preparation method of the porous copper block M60 is the same as that of Example 2; the preparation method of the oil solution B is the same as that of Example 3.
[0055] Porous copper M60 was immersed in hot oil solution B and placed in a vacuum oven at -0.8 bar and 180°C for 5 hours. The oil solution was then removed from the vacuum oven and allowed to cool to room temperature under atmospheric pressure. The porous copper block was then removed from the gel and the excess gel on the surface was wiped clean with a dust-free cloth, yielding a gel-impregnated porous copper self-lubricating bearing cage material.
[0056] Comparative Example 1
[0057] The preparation method of the porous copper block M50 is the same as that in Example 1.
[0058] Porous copper M50 was immersed in PAO10 at 180°C and placed in a vacuum oven at -0.8 bar at 180°C for 5 hours. The PAO10 was then removed from the vacuum oven and allowed to cool to room temperature under atmospheric pressure. The porous copper block was then removed from the PAO10 and the excess PAO10 on the surface was wiped clean with a dust-free cloth, resulting in an oil-impregnated porous copper self-lubricating bearing cage material.
[0059] Comparative Example 2
[0060] The preparation method of the porous copper block M60 is the same as that in Example 2.
[0061] Porous copper M60 was immersed in PAO10 at 180°C and placed in a vacuum oven at -0.8 bar at 180°C for 5 hours. The PAO10 was then removed from the vacuum oven and allowed to cool to room temperature under atmospheric pressure. The porous copper block was then removed from the PAO10 and the excess PAO10 on the surface was wiped clean with a dust-free cloth, resulting in an oil-impregnated porous copper self-lubricating bearing cage material.
[0062] Test Example 1
[0063] The properties of the self-lubricating bearing retainer materials prepared in Examples 1 to 4 and Comparative Examples 1 to 2 were tested. The specific testing methods are as follows:
[0064] Using TRB produced by Anton Paar in Germany 3The tribological properties of the materials obtained in Examples 1-4 and Comparative Examples 1-2 were evaluated using a ball-on-disc friction and wear tester. The upper friction pair consisted of a CGr15 steel ball, and the lower friction pair consisted of the self-lubricating bearing retainer material prepared in Examples 1-4 or Comparative Examples 1-2. Test conditions were: temperature 25°C, frequency 1 Hz, amplitude 5 mm, load 5 N, and test time 30 min.
[0065] The friction coefficient of the self-lubricating bearing retainer material prepared in Example 1, Example 3 and Comparative Example 1 varies with time. Figure 1 As shown in the graph, the friction coefficient of the self-lubricating bearing retainer material prepared in Example 2, Example 4 and Comparative Example 2 changes with time. Figure 2 The average friction coefficient of the lubricating materials obtained in each embodiment is shown in Table 1.
[0066] Table 1 Average friction coefficient of lubricating materials obtained in Examples 1 to 4 and Comparative Examples 1 to 2
[0067] Sample number Example 1 Example 2 Example 3 Example 4 Comparative Example 1 Comparative Example 2 Average friction coefficient 0.17408 0.2453 0.12003 0.12047 0.32167 0.34323
[0068] According to Table 1, Figure 1 and Figure 2 It can be seen from the data in that the gel-impregnated porous copper self-lubricating bearing cage material prepared by the present invention has a significantly lower average friction coefficient and improved lubrication stability compared with the oil-impregnated porous copper self-lubricating bearing cage material in the comparative example.
[0069] Test Example 2
[0070] The oil retention rates of the self-lubricating bearing cage materials prepared in Examples 1 to 4 and Comparative Examples 1 to 2 were tested. The specific testing method is as follows:
[0071] The initial mass m of lubricant (gel or oil) contained in the materials of Examples 1 to 4 and Comparative Examples 1 to 2 was recorded. The materials of Examples 1 to 4 and Comparative Examples 1 to 2 were placed in centrifuge tubes and centrifuged at 1000 rpm for 10 minutes, and the mass m1 of the lubricant (gel or oil) was recorded. The centrifuge was then continued at a higher speed (the speed was increased by 1000 rpm each time until 8000 rpm) for 10 minutes, and the mass m2 to m8 of the lubricant (gel or oil) was recorded. According to the formula (oil retention rate = m i / m, i=1~8) to calculate the oil retention rate.
[0072] The oil retention test results of the self-lubricating bearing cage materials prepared in Example 1, Example 3 and Comparative Example 1 at different speeds are as follows: Figure 3 The oil retention test results of the self-lubricating bearing cage material prepared in Example 2, Example 4 and Comparative Example 2 at different speeds are shown as follows: Figure 4 shown.
[0073] according to Figure 3 、 Figure 4 The data in Figure 2 demonstrate that the gel-impregnated porous copper self-lubricating bearing cage material provided by the present invention exhibits significantly improved oil retention compared to oil-impregnated porous copper self-lubricating bearing cage materials. In particular, when aluminum bis(stearate) lipoate is used as the gelling agent (Examples 3 and 4), the resulting cage material can maintain a high oil content of approximately 90% even at high rotational speeds.
[0074] The above is only a preferred embodiment of the present invention. It should be pointed out that for ordinary technicians in this technical field, several improvements and modifications can be made without departing from the principles of the present invention. These improvements and modifications should also be regarded as within the scope of protection of the present invention.
Claims
1. A porous copper impregnated self-lubricating bearing cage material, characterized in that: The invention comprises porous copper and a supramolecular gel lubricant immersed in the pores of the porous copper; the supramolecular gel lubricant comprises a base oil and a gel factor; the gel factor comprises one or two of N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide and aluminum bis(stearate) lipoate; and the porosity of the porous copper is greater than 30%.
2. The impregnated porous copper self-lubricating bearing cage material according to claim 1, characterized in that: The pore size of the porous copper is in the micron level; the porosity of the porous copper is 30-70%.
3. The impregnated porous copper self-lubricating bearing cage material according to claim 1, characterized in that: The preparation method of the porous copper comprises the following steps: mixing copper powder and iron powder and sintering the mixture to obtain a copper-iron precursor; and soaking the copper-iron precursor in an acid solution to obtain the porous copper.
4. The impregnated porous copper self-lubricating bearing cage material according to claim 1, characterized in that: The base oil includes one or more of PAO4, PAO10, 150SN and 500SN.
5. The impregnated porous copper self-lubricating bearing cage material according to claim 1, characterized in that: The mass percentage of the gelling factor in the supramolecular gel lubricant is 1-10%.
6. The impregnated porous copper self-lubricating bearing cage material according to claim 1 or 5, characterized in that: When the gel factor is N-dodecyl-2,4-(3,4-dichlorobenzylidene)-D-glucamide, the mass percentage of the gel factor in the supramolecular gel lubricant is 2-3%; when the gel factor is aluminum bis(stearate) lipoate, the mass percentage of the gel factor in the supramolecular gel lubricant is 5-6%.
7. The method for preparing the impregnated porous copper self-lubricating bearing cage material according to any one of claims 1 to 6, characterized in that: The following steps are involved: heating and mixing the gelling factor and the base oil to obtain a gelling factor oil solution; The porous copper is immersed in the gel factor oil solution and then cooled to obtain the gel-impregnated porous copper self-lubricating bearing cage material.
8. The preparation method according to claim 7, characterized in that The heating and mixing is performed at a temperature of 170-190° C. and for a time of 15-30 minutes.
9. The preparation method according to claim 7, characterized in that The soaking temperature is above 160° C., the vacuum degree is below -0.8 bar, and the soaking time is 4 to 10 hours.
10. Use of the impregnated porous copper self-lubricating bearing cage material according to any one of claims 1 to 6 or the impregnated porous copper self-lubricating bearing cage material prepared by the preparation method according to any one of claims 7 to 9 in lubricating mechanical parts.
Citation Information
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