Full-automatic high-concentration free radical modular generation equipment

Abstract

The invention relates to full-automatic high-concentration free radical modular generation equipment which comprises free radical reaction devices which are mounted on a driving box, a plurality of free radical reaction devices can be modularly configured according to subsequent yield requirements, and the free radical reaction devices are used for generating free radical nano bubbles; the control valve unit is used for controlling the radical generating raw material to be conveyed to the radical reaction device; the free radical nanobubble collecting tank is used for collecting free radical nanobubbles generated by the free radical reaction device; and the vacuum pump is used for generating the power of the free radical nanobubbles. According to the full-automatic high-concentration free radical modular generation equipment, a physical mechanism is utilized, a liquid solvent and gas molecules are controlled through a mechanical movement device, micro-nano bubble production is carried out, high-concentration nano gas is induced to generate high-concentration free radicals, a high-concentration free radical production device is developed, large-scale continuous free radical production is supported, and the production efficiency is improved. The requirements of high-concentration free radical reagents are met.

Description

Technical Field

[0001] The invention relates to the technical field of free radicals, in particular to a fully automatic high-concentration free radical modular generating device. Background Art

[0002] Free radicals are atoms or groups with unpaired electrons, which are highly oxidizing and reactive. They are also called "free radicals" in chemistry. They refer to atoms or groups with unpaired electrons formed when the covalent bonds of the molecules of a compound are homogenously cleaved under external conditions such as light and heat. (When the covalent bonds are unevenly cleaved, the shared electron pair between the two atoms is completely transferred to one of the atoms, resulting in the formation of positively and negatively charged ions. This type of cleavage is called heterolytic cleavage of the bond.) Common free radicals include hydroxyl radicals (·OH), superoxide radicals (O2-·), hydrogen radicals (H·), chlorine radicals (Cl·) and methyl radicals (CH3·).

[0003] When a compound undergoes a chemical reaction, it is always accompanied by the breaking of some covalent bonds and the formation of new covalent bonds. When a covalent bond is homolytically split, the two bonding electrons are separated, and the resulting fragment has an unpaired electron, such as H·, CH·, Cl·, etc. If it is composed of more than one atom, it is called a free radical. Because of the presence of unpaired electrons, free radicals and free atoms are very active and usually cannot be separated. However, in many reactions, free radicals and free atoms exist as intermediates, although the concentration is very low and the residence time is very short.

[0004] Free radicals, also known as free radicals, are groups or atoms with non-even electrons. They have two main characteristics: one is high chemical reactivity; the other is magnetic moment. In a chemical reaction, or under the influence of external factors (light, heat, etc.), the result of the splitting of covalent bonds in the molecule is that the shared electron pair becomes exclusive to one party, forming an ion; if the result of the splitting is that the shared electron pair belongs to two atoms (or groups), a free radical is formed. It includes the following generation methods: ① Initiator initiation, free radicals are generated by the decomposition of the initiator; ② Thermal initiation, by directly heating the monomer, the double bond of the vinyl monomer is opened to generate free radicals; ③ Photoinitiation, under the excitation of light, many olefin monomers form free radicals and polymerize; ④ Radiation initiation, through high-energy radiation, the monomer absorbs radiation energy and decomposes into free radicals; ⑤ Plasma initiation, plasma can induce monomers to form free radicals for polymerization, and can also cause heterocyclic ring-opening polymerization; ⑥ Microwave initiation, microwaves can directly induce some olefin monomers to undergo free radical polymerization.

[0005] Simply put, in our world composed of atoms, there is a special rule, that is, as long as there are more than two atoms combined together, its outer electrons must be paired. If they are not paired, they will look for another electron to turn themselves into a stable substance. Scientists call atoms or molecules with unpaired electrons free radicals. Free radicals are very active and very restless. For living organisms, if a kind of free radical is produced and the corresponding free radicals cannot be replenished in time to balance their functions, it will cause malignant mutations in the long run, such as cancer; if it is actively supplemented through effective means, the long-term vitality of the body can be maintained. After large-scale industrial products are manufactured, a large number of free radicals are generated in the environment, water, air, etc., and there are many parts such as engineering plastics. The highly active free radicals can be used to actively accelerate their decomposition or treatment to reduce secondary pollution. For example, hydrogen free radicals can neutralize the free radicals of biological peroxidation, reduce the aging of the body, etc.; superoxide free radicals can quickly decompose pollutants in water, and can be used to treat organic matter, nitrogen and phosphorus, and toxic and harmful substances in water, thereby effectively improving the water quality. ‌ The current common method of generating free radicals usually adopts a chemical reaction process, which is produced under the influence of external light, electricity and heat, and often carries many other products, making it impossible to efficiently extract free radicals; at the same time, the free radicals generated cannot be used on a large scale and cannot directly generate economic value. There are also chemical and physical methods to generate superoxide free radicals through gas Venturi negative pressure extraction and water pump injection, but the efficiency is very low, the concentration of free radicals generated is low, and the use is limited. Summary of the invention

[0006] Therefore, the technical problem to be solved by the present invention is to overcome the problem that the method and equipment for generating free radicals in the prior art cannot be used on a large scale and have low production efficiency.

[0007] In order to solve the above technical problems, the present invention provides a fully automatic high-concentration free radical modular production equipment, comprising: a base, on which a driving box is provided, and an upper supporting plate is installed on the upper end of the driving box; a free radical reaction device, which is installed on the driving box, and the fully automatic high-concentration free radical modular production equipment can modularly configure a plurality of free radical reaction devices according to subsequent production needs; a control valve unit, which is arranged on the upper supporting plate, the input end of the control valve unit is connected to the free radical generating raw material, and the output end of the control valve unit is connected to the free radical reaction device, and the control valve unit is used to control the delivery of the free radical generating raw material to the free radical reaction device; a free radical nano bubble collection tank, which is connected to the free radical reaction device, and the free radical nano bubble collection tank is used to collect the free radical nano bubbles generated by the free radical reaction device; a vacuum pump, which is connected to the input pipeline of the free radical nano bubble collection tank, and the vacuum pump serves as the power for the free radical nano bubble collection tank to collect the free radical nano bubbles generated by the free radical reaction device.

[0008] In one embodiment of the present invention, the control valve unit is composed of a plurality of control valves, the input feed ports of the plurality of control valves are connected to the raw material end, and the output ports of the plurality of control valves are connected to the free radical reaction device, and the plurality of control valves are used to control the delivery of pure water, alkaline solution, acidic solution, nitrogen, oxygen, hydrogen and chlorine.

[0009] In one embodiment of the present invention, the pipes at the output ends of the several control valves are connected to the first ends of the switching three-way control valve 1 and the switching three-way control valve 2, the second ends of the switching three-way control valve 1 and the switching three-way control valve 2 are connected to the free radical reaction device, and the third ends of the switching three-way control valve 1 and the switching three-way control valve 2 are connected to the free radical nano bubble collection tank.

[0010] In one embodiment of the present invention, a first cut-off valve is provided between the second end of the first switching three-way control valve and the free radical reaction device, and a second cut-off valve is provided between the second end of the second switching three-way control valve and the free radical reaction device.

[0011] In one embodiment of the present invention, the control valve unit also includes a manifold 2, the third ends of the switching three-way control valve 1 and the switching three-way control valve 2 are both connected to the manifold 2, and the manifold 2 is connected to a pipeline 12, the pipeline 12 is connected to the free radical nano bubble collection tank, and a cut-off valve 3 is provided on the pipeline 12.

[0012] In one embodiment of the present invention, the free radical reaction device includes a drive assembly, two symmetrically arranged traction clamps, a slider, a guide column, a spring, a free radical reaction pool and a piston push rod. The slider is sleeved on the guide column and can slide along the axial direction of the guide column. The drive assembly is connected to the two symmetrically arranged traction clamps, and the drive assembly drives the traction clamps to drive the slider to move linearly along the guide column. The spring is sleeved on the guide column, one end of the spring is fixed, and the other end of the spring is against the slider. One end of the piston push rod is arranged in the free radical reaction pool, and the other end of the piston push rod extending out of the free radical reaction pool is connected to the slider. The free radical reaction pool and the piston push rod constitute the structure of a syringe, and the free radical reaction pool is connected to the control valve unit.

[0013] In one embodiment of the present invention, a reaction pool mounting seat is provided on the driving box, an upper cover plate is installed on the reaction pool mounting seat through fasteners, the free radical reaction pool is arranged on the reaction pool mounting seat, and the free radical reaction pool is limited on the reaction pool mounting seat by the upper cover plate.

[0014] In one embodiment of the present invention, the driving assembly includes a driving motor, a bevel gear 1, a transmission shaft 1, a bevel gear 2 and two bevel gears 3, the rotating shaft of the driving motor is connected to the bevel gear 1, the bevel gear 2 is sleeved on the transmission shaft 1, and the bevel gear 2 is meshed with the bevel gear 1, and the bevel gear 3 is provided at both ends of the transmission shaft 1.

[0015] In one embodiment of the present invention, the traction clamp includes a transmission shaft 2, a bevel gear 4, a gear 1, a chain and a gear 2, the two ends of the transmission shaft 2 are respectively connected to the bevel gear 4 and the gear 1, the bevel gear 4 is meshed with the bevel gear 3, the gear 1 is connected to the gear 2 through a chain, a triangular bracket is installed on the chain, a roller is installed on the triangular bracket, a rectangular protrusion is provided on the side wall of the slider opposite to the chain, and the roller is in contact with the rectangular protrusion.

[0016] In one embodiment of the present invention, a T-slot is provided on the end surface of the slider opposite to the piston push rod, and one end of the piston push rod extending out of the free radical reaction tank is connected to a piston handle, and the piston handle is arranged in the T-slot.

[0017] The above technical solution of the present invention has the following beneficial effects compared with the prior art: 1. Based on physical methods, free radicals can be generated, which can generate 1*10 10 The high concentration of free radical reagents per ml solves the problem of the urgent need for high concentration free radical reagent catalytic mechanism reaction in the scientific research field of related fields; 2. Design control fluid pipelines and control processes such as pure water, alkaline solution, acidic solution, nitrogen, oxygen, hydrogen and chlorine, which can also be easily expanded to achieve the needs of conveniently and quickly providing a variety of high-concentration free radicals while taking into account production; 3. The modular reaction pool design method is adopted. The modularization of the combined reaction pools one, two, and three can efficiently produce free radical nanobubbles and can adapt to industrial intermittent and continuous production needs; 4. Free radicals are the basic energy units for the operation of life organisms and the basic particles for the continued prosperity of nature. However, due to their short existence and difficulty in capturing, this method makes up for the controllability of the source of free radical-based laboratory materials; 5. Environmental governance encounters various difficulties. Many methods such as chemical reactions or incineration will produce "secondary" pollution sources. Different free radicals have different characteristics, especially strong oxidizing or reducing properties. According to the scenario of environmental governance, free radical nanobubbles can be used for efficient treatment without subsequent pollution. BRIEF DESCRIPTION OF THE DRAWINGS

[0018] In order to make the content of the present invention more clearly understood, the present invention is further described in detail below according to specific embodiments of the present invention in conjunction with the accompanying drawings, wherein Figure 1 This is an appearance diagram of a fully automatic high-concentration free radical modular production device in a preferred embodiment of the present invention; Figure 2 The structure of the fully automatic high-concentration free radical modular production device in the preferred embodiment of the present invention is shown in FIG. Figure 1 ; Figure 3 The structure of the control valve unit in the preferred embodiment of the present invention is shown in FIG. Figure 1 ; Figure 4 The structure of the control valve unit in the preferred embodiment of the present invention is shown in FIG. Figure 2 ; Figure 5 The structure of the free radical reaction device in the preferred embodiment of the present invention is shown in FIG. Figure 1 ; Figure 6 It is a structural schematic diagram of a driving component in a preferred embodiment of the present invention; Figure 7 It is a structural schematic diagram of a traction clamp in a preferred embodiment of the present invention; Figure 8 It is a partial enlarged view of the free radical reaction device in the preferred embodiment of the present invention.

[0019] Description of the accompanying drawings: base 1, first drive box 2, right angle plate 20, reaction pool mounting seat 21, upper cover plate 22, second drive box 3, upper support plate 4, first free radical reaction device 5, drive assembly 51, drive motor 511, bevel gear 1 512, transmission shaft 1 513, bevel gear 2 514, bevel gear 3 515, traction clamp 52, transmission shaft 2 521, bevel gear 4 522, gear 1 523, chain 524, gear 2 525, triangular bracket 526, roller 527, rectangular convex portion 528, slider 53, T-slot 531, guide column 54, spring 55, free radical reaction pool 56, injection port 561, piston push rod 57, piston handle 571, second free radical reaction device 6, Control valve unit 7, control valve one 71, pipeline one 711, control valve two 72, pipeline two 721, control valve three 73, pipeline three 731, control valve four 74, pipeline four 741, control valve five 75, pipeline five 751, control valve six 76, pipeline six 761, control valve seven 77, pipeline seven 771, switch three-way control valve one 78, cut-off valve one 781, switch three-way control valve two 79, cut-off valve two 791, cut-off valve three 700, main manifold one 701, branch pipe one 702, branch pipe two 703, pipeline eight 704, pipeline nine 705, pipeline ten 706, pipeline eleven 707, manifold two 708, pipeline twelve 709, free radical nano bubble collection tank 8, vacuum pump 9, outer cover shell 10. DETAILED DESCRIPTION

[0020] The present invention is further described below in conjunction with the accompanying drawings and specific embodiments so that those skilled in the art can better understand the present invention and implement it, but the embodiments are not intended to limit the present invention.

[0021] Reference Figure 1 , 2As shown, the fully automatic high-concentration free radical modular production equipment of the present invention includes: a base 1, on which a first drive box 2 and a second drive box 3 are provided, the first drive box 2 and the second drive box 3 are arranged in parallel, and an upper support plate 4 is installed on the upper ends of the first drive box 2 and the second drive box 3; a first free radical reaction device 5, which is installed on the first drive box 2; a second free radical reaction device 6, which is installed on the second drive box 3, the second free radical reaction device 6 and the first free radical reaction device 5 are independent working modules, and the second free radical reaction device 6 and the first free radical reaction device 5 are used to generate free radical nanobubbles; a control valve unit 7, which is arranged on the upper support plate 4, and the input end of the control valve unit 7 is connected to the free radical generating raw material , and the output end of the control valve unit 7 is connected to the first free radical reaction device 5 and the second free radical reaction device 6, and the control valve unit 7 is used to control the delivery of free radical generating raw materials to the first free radical reaction device 5 and the second free radical reaction device 6; the free radical nano bubble collection tank 8 is connected to the first free radical reaction device 5 and the second free radical reaction device 6, and the free radical nano bubble collection tank 8 is used to collect the free radical nano bubbles generated by the first free radical reaction device 5 and the second free radical reaction device 6; the vacuum pump 9 is connected to the input pipeline of the free radical nano bubble collection tank 8, and the vacuum pump 9 serves as the power for the free radical nano bubble collection tank 8 to collect the free radical nano bubbles generated by the first free radical reaction device 5 and the second free radical reaction device 6. The outer cover of the first driving box 2 and the second driving box 3, the free radical nano bubble collection tank 8 and the vacuum pump 9 is provided with an outer cover shell 10.

[0022] Reference Figure 3 , 4As shown, the control valve unit 7 is composed of a number of control valves, the input end feed ports of the control valves are connected to the raw material end, and the output ends of the control valves are connected to the first free radical reaction device 5 and the second free radical reaction device 6, and the control valves are used to control the delivery of pure water, alkaline solution, acidic solution, nitrogen, oxygen, hydrogen and chlorine. Specifically, the control valve unit 7 includes control valve 1 71, control valve 2 72, control valve 3 73, control valve 4 74, control valve 5 75, control valve 6 76 and control valve 7 77. The input end of the control valve 1 71 is connected to the pure water supply source, and the control valve 1 71 is used to control the on-off of the pure water delivery, the input end of the control valve 2 72 is connected to the alkaline solution supply source, and the control valve 2 72 is used to control the on-off of the alkaline solution delivery, the input end of the control valve 3 73 is connected to the acidic solution supply source, and the control valve 3 73 is used to control the on-off of the pure water delivery. For controlling the on-off of the acidic solution delivery, the input end of the control valve 4 74 is connected to the nitrogen supply source, and the control valve 4 74 is used to control the on-off of the nitrogen delivery, the input end of the control valve 5 75 is connected to the oxygen supply source, and the control valve 5 75 is used to control the on-off of the oxygen delivery, the input end of the control valve 6 76 is connected to the hydrogen supply source, and the control valve 6 76 is used to control the on-off of the hydrogen delivery, the input end of the control valve 77 is connected to the chlorine supply source, and the control valve 77 is used to control the on-off of the chlorine delivery.

[0023] The pipes at the output ends of the control valves are connected to the first ends of the switching three-way control valve 1 78 and the switching three-way control valve 2 79, the second ends of the switching three-way control valve 1 78 and the switching three-way control valve 2 79 are connected to the first free radical reaction device 5 and the second free radical reaction device 6, and the third ends of the switching three-way control valve 1 78 and the switching three-way control valve 2 79 are connected to the free radical nano bubble collection tank 8. The output ends of control valve one 71, control valve two 72, control valve three 73, control valve four 74, control valve five 75, control valve six 76 and control valve seven 77 are respectively connected to pipeline one 711, pipeline two 721, pipeline three 731, pipeline four 741, pipeline five 751, pipeline six 761 and pipeline seven 771, and the output ends of pipeline one 711, pipeline two 721, pipeline three 731, pipeline four 741, pipeline five 751, pipeline six 761 and pipeline seven 771 are collected to the main conduit one 701, and the main conduit one 701 is connected to branch pipe one 702 and branch pipe two 703, the branch pipe one 702 is connected to the first end of the switching three-way control valve one 78, and the branch pipe two 703 is connected to the first end of the switching three-way control valve two 79.

[0024] A cut-off valve 1 781 is provided between the second end of the switching three-way control valve 1 78 and the first free radical reaction device 5, and a cut-off valve 2 791 is provided between the second end of the switching three-way control valve 2 79 and the second free radical reaction device 6. A pipeline 8 704 is provided between the second end of the switching three-way control valve 1 78 and the cut-off valve 1 781, a pipeline 9 705 is provided between the second end of the switching three-way control valve 2 79 and the cut-off valve 2 791, a pipeline 10 706 is connected between the cut-off valve 1 781 and the first free radical reaction device 5, and a pipeline 11 707 is connected between the cut-off valve 2 791 and the second free radical reaction device 6.

[0025] In addition, the control valve unit 7 further includes a second manifold 708, the third ends of the switching three-way control valve 1 78 and the switching three-way control valve 2 79 are both connected to the manifold 2 708, and the manifold 2 708 is connected to a pipeline 12 709, the pipeline 12 709 is connected to the free radical nano bubble collection tank 8, and the pipeline 12 709 is provided with a cut-off valve 3 700. The vacuum pump 9 is connected to the pipeline 12 709 through a pipeline, so the vacuum pump 9 provides power to drive the free radical nano bubbles generated in the first free radical reaction device 5 and the second free radical reaction device 6 to be transported into the free radical nano bubble collection tank 8 through the pipeline 12 709.

[0026] Reference Figure 5As shown, the first free radical reaction device 5 and the second free radical reaction device 6 have the same structure, and both the first free radical reaction device 5 and the second free radical reaction device 6 include a driving assembly 51, two symmetrically arranged traction clamps 52, a slider 53, a guide column 54, a spring 55, a free radical reaction pool 56 and a piston push rod 57. The slider 53 is sleeved on the guide column 54, and the slider 53 can slide along the axial direction of the guide column 54. The driving assembly 51 is connected to the two symmetrically arranged traction clamps 52, and the driving assembly 51 drives the traction clamps 52 to drive the slider 53 to move linearly along the guide column 54. The spring 55 is sleeved on the guide column 54, one end of the spring 55 is fixed, and the other end of the spring 55 is against the slider 53. One end of the piston push rod 57 is arranged in the free radical reaction pool 56, and the other end of the piston push rod 57 extending out of the free radical reaction pool 56 is connected to the slider 53. The free radical reaction pool 56 and the piston push rod 57 constitute the structure of a syringe, and the free radical reaction pool 56 is connected to the control valve unit 7. The free radical reaction pool 56 is a syringe structure, and one end of the free radical reaction pool 56 is connected to a material injection port 561. The material injection port 561 of the first free radical reaction device 5 and the output end of the cut-off valve 1 781 are connected through a pipeline 10 706, and the material injection port 561 of the second free radical reaction device 6 and the output end of the cut-off valve 2 791 are connected through a pipeline 11 707. The slider 53 is located between two symmetrically arranged traction clamps 52, so that the two symmetrically arranged traction clamps 52 form a synchronous driving force on both sides to drive the slider 53 to move linearly along the axial direction of the guide column 54.

[0027] In the above structure, the first drive box 2 and the second drive box 3 are both provided with a reaction pool mounting seat 21, and an upper cover plate 22 is installed on the reaction pool mounting seat 21 through fasteners. The free radical reaction pool 56 is arranged on the reaction pool mounting seat 21, and the free radical reaction pool 56 is limited on the reaction pool mounting seat 21 through the upper cover plate 22. The first drive box 2 and the second drive box 3 are provided with a right angle plate 20, the upper end of the guide column 54 is installed on the reaction pool mounting seat 21, the lower end of the guide column 54 is installed on the right angle plate 20, and the lower end of the spring 55 is against the right angle plate 20.

[0028] Reference Figure 6As shown, the driving assembly 51 includes a driving motor 511, a bevel gear 1 512, a transmission shaft 1 513, a bevel gear 2 514 and two bevel gear 3 515. The rotating shaft of the driving motor 511 is connected to the bevel gear 1 512. The bevel gear 2 514 is sleeved on the transmission shaft 1 513, and the bevel gear 2 514 and the bevel gear 1 512 are meshed. Both ends of the transmission shaft 1 513 are provided with bevel gear 3 515. The driving motor 511 drives the bevel gear 1 512 to rotate, and the bevel gear 1 512 drives the bevel gear 2 514 to rotate. Since the bevel gear 2 514 is arranged on the transmission shaft 1 513, the transmission shaft 1 513 rotates, so the bevel gear 3 515 rotates synchronously, and the bevel gear 3 515 drives the two symmetrically arranged traction clamps 52 to act synchronously.

[0029] Reference Figure 7 , 8 As shown, the traction fixture 52 includes a transmission shaft 2 521, a bevel gear 4 522, a gear 1 523, a chain 524 and a gear 2 525. The two ends of the transmission shaft 2 521 are connected to the bevel gear 4 522 and the gear 1 523 respectively. The bevel gear 4 522 is meshed with the bevel gear 3 515. The gear 1 523 is connected to the gear 2 525 through the chain 524. A triangular bracket 526 is installed on the chain 524. A roller 527 is installed on the triangular bracket 526. A rectangular convex portion 528 is provided on the side wall of the slider 53 opposite to the chain 524. The roller 527 contacts the rectangular convex portion 528. The driving assembly 51 can drive the bevel gear 4 522 to rotate, thereby synchronously driving the transmission shaft 2 521 to rotate, so that the gear 1 523 rotates. Since the chain 524 is sleeved on the gear 1 523 and the gear 2 525, the chain 524 rotates. When the roller 527 is transmitted to the upper end surface of the rectangular protrusion 528, the roller 527 contacts the upper end surface of the rectangular protrusion 528. As the driving component 51 drives the roller 527 to move downward, the roller 527 presses down the rectangular protrusion 528, so that the slider 53 moves downward, compressing the spring 55. At the same time, the movement of the slider 53 drives the piston push rod 57 to be withdrawn from the free radical reaction pool 56, forming an action of pulling the piston push rod 57 out of the free radical reaction pool 56; when the roller 527 is transmitted to the lower end surface of the rectangular protrusion 528, the roller 527 contacts the upper end surface of the rectangular protrusion 528. As the driving component 51 drives the roller 527 to move upward, the roller 527 pushes up the rectangular protrusion 528, so that the slider 53 moves upward, and the piston push rod 57 compresses the space in the free radical reaction pool 56.

[0030] Reference Figure 8As shown, a T-slot 531 is provided on the end surface of the slider 53 opposite to the piston push rod 57, and one end of the piston push rod 57 extending out of the free radical reaction pool 56 is connected to a piston handle 571, and the piston handle 571 is arranged in the T-slot 531. The piston handle 571 is in the shape of a disc, and the piston handle 571 is arranged in the large end of the T-slot 531, and the piston push rod 57 passes through the small end of the T-slot 531 and is inserted into the free radical reaction pool 56.

[0031] The working principle of the fully automatic high-concentration free radical modular generation device of the present invention is: The input end feed pipes of control valve 1 71, control valve 2 72, control valve 3 73, control valve 4 74, control valve 5 75, control valve 6 76 and control valve 7 7 are pre-configured with relevant liquids and gases, such as pure water, alkaline solution, acidic solution, nitrogen, oxygen, hydrogen and chlorine, and can also be related molecules related to free radical separation such as organic solution and ozone; a control operation touch screen is set on the outer cover shell 10, and one-key operation is used to produce superoxide free radicals, oxygen feed of control valve 5 75 The port is opened, the cut-off valve 1 781 and / or the cut-off valve 2 791 are opened, the drive motor 511 and the controller are operated, the tail handle slider 53 of the free radical reaction pool 56 is moved, and a certain amount of oxygen is injected into the reaction pool; after completion, the control valve 5 75 is closed, the pure water feed port control valve 1 71 is opened, the drive motor 511 and the controller are operated, the tail handle slider 53 of the free radical reaction pool 56 is continued to be moved, and a certain amount of pure water is injected into the reaction pool; after completion, the control valve 1 71 and the cut-off valve 1 781 and / or the cut-off valve 2 791 are closed. The cut-off valve 2 791 drives the motor 511 and the controller to continue to operate, and the tail handle slider 53 of the free radical reaction pool 56 is continued to be moved, so that negative pressure is formed in the free radical reaction pool 56, and the slider 53 is moved to a certain position. The transmission gear assembly composed of the gear 1 523, the chain 524 and the gear 2 525 pulls the roller 527 away from the upper end surface of the rectangular protrusion 528, thereby releasing the slider 53. The slider 53 is quickly retracted due to the suction force of the negative pressure inside the reaction pool. After the transmission rotating chain pulls the clamp to rotate half a circle, the slider 53 connected to the free radical reaction pool 56 is clamped again to stretch and move. This action is cyclically moved hundreds or thousands of times; it stops automatically after reaching the number of cycles, switches the three-way control valve 1 78 and / or switches the three-way control valve 2 79 to the drainage channel, and the vacuum pump 9 is started to evacuate the free radical nano bubble collection tank 8 and related pipelines; after the cut-off valve of the free radical reaction pool 56 is opened, the piston push rod 57 pushes the drainage and vacuum chamber, and the free radical nano bubbles are collected in the free radical nano bubble collection tank 8. The free radical reaction pools 56 of the first free radical reaction device 5 and the second free radical reaction device 6 can be operated alternately and simultaneously to generate free radical nanobubbles, which are continuously collected into the free radical nanobubble collection tank 8; according to subsequent demand, the third and fourth modules can be continuously increased to quickly and mass-produce nanobubble solutions.

[0032] A free radical reaction pool is designed and developed using physical methods. Gas and liquid solvents are mixed in the free radical reaction pool through control valve and cut-off valve control logic. A motor control system is used to design a transmission chain to drive the piston push rod to stretch. Under the physical force, a vacuum state is formed inside the free radical reaction pool, which reduces the force between gas and liquid molecules. When a certain displacement distance is reached, the rear end sealing tail handle rebounds quickly, and the force between gas and liquid molecules is restored. During the process, the liquid breaks large clusters of gas molecules to form small molecular clusters. After more than hundreds or thousands of reciprocating motions, nanobubbles and nanoliquids in the reaction pool are wrapped around each other. The free radical nanobubble collection tank and related pipelines are evacuated, and the nanobubble water in the reaction pool flows into the free radical nanobubble collection tank. Under the vacuum environment in the pipeline and the free radical nanobubble collection tank, the nanobubbles in the nanobubble water slowly burst, releasing high voltage to the liquid, electrically separating the surrounding gas and liquid to form corresponding free radicals.

[0033] Obviously, the above embodiments are merely examples for clear explanation and are not intended to limit the implementation methods. For those skilled in the art, other different forms of changes or modifications can be made based on the above description. It is not necessary and impossible to list all the implementation methods here. The obvious changes or modifications derived from these are still within the protection scope of the invention.

Claims

1. A fully automatic high-concentration free radical modular production device, characterized in that: include: A base, on which a driving box is provided, and an upper supporting plate is installed at the upper end of the driving box; The free radical reaction device is installed on the drive box. The fully automatic high-concentration free radical modular production equipment can modularly configure several free radical reaction devices according to the subsequent production needs; A control valve unit is disposed on the upper support plate, wherein an input end of the control valve unit is connected to the free radical generating raw material, and an output end of the control valve unit is connected to the free radical reaction device, and the control valve unit is used to control the delivery of the free radical generating raw material to the free radical reaction device; A free radical nano bubble collection tank is connected to the free radical reaction device and is used to collect free radical nano bubbles generated by the free radical reaction device; The vacuum pump is connected to the input pipeline of the free radical nano bubble collection tank, and the vacuum pump serves as the power for the free radical nano bubble collection tank to collect the free radical nano bubbles generated by the free radical reaction device.

2. The fully automatic high-concentration free radical modular generation device according to claim 1, characterized in that: The control valve unit is composed of a plurality of control valves, the input feed ports of the plurality of control valves are connected to the raw material end, and the output ports of the plurality of control valves are connected to the free radical reaction device, and the plurality of control valves are used to control the delivery of pure water, alkaline solution, acidic solution, nitrogen, oxygen, hydrogen and chlorine.

3. The fully automatic high-concentration free radical modular generation device according to claim 2, characterized in that: The pipelines at the output ends of the several control valves are connected to the first ends of the switching three-way control valve 1 and the switching three-way control valve 2, the second ends of the switching three-way control valve 1 and the switching three-way control valve 2 are connected to the free radical reaction device, and the third ends of the switching three-way control valve 1 and the switching three-way control valve 2 are connected to the free radical nano bubble collection tank.

4. The fully automatic high-concentration free radical modular generation device according to claim 3, characterized in that: A cut-off valve 1 is provided between the second end of the switching three-way control valve 1 and the free radical reaction device, and a cut-off valve 2 is provided between the second end of the switching three-way control valve 2 and the free radical reaction device.

5. The fully automatic high-concentration free radical modular generation device according to claim 3, characterized in that: The control valve unit also includes a manifold 2, the third ends of the switching three-way control valve 1 and the switching three-way control valve 2 are both connected to the manifold 2, and the manifold 2 is connected to a pipeline 12, the pipeline 12 is connected to the free radical nano bubble collection tank, and a cut-off valve 3 is provided on the pipeline 12.

6. The fully automatic high-concentration free radical modular generation device according to claim 1, characterized in that: The free radical reaction device includes a driving component, two symmetrically arranged traction clamps, a slider, a guide column, a spring, a free radical reaction pool and a piston push rod. The slider is sleeved on the guide column and can slide along the axial direction of the guide column. The driving component is connected to the two symmetrically arranged traction clamps, and the driving component drives the traction clamps to drive the slider to move linearly along the guide column. The spring is sleeved on the guide column, one end of the spring is fixed, and the other end of the spring is against the slider. One end of the piston push rod is arranged in the free radical reaction pool, and the other end of the piston push rod extending out of the free radical reaction pool is connected to the slider. The free radical reaction pool and the piston push rod constitute the structure of a syringe, and the free radical reaction pool is connected to a control valve unit.

7. The fully automatic high-concentration free radical modular generation device according to claim 6, characterized in that: The driving box is provided with a reaction pool mounting seat, an upper cover plate is mounted on the reaction pool mounting seat via fasteners, the free radical reaction pool is arranged on the reaction pool mounting seat, and the free radical reaction pool is limited on the reaction pool mounting seat via the upper cover plate.

8. The fully automatic high-concentration free radical modular generation device according to claim 7, characterized in that: The driving assembly includes a driving motor, a bevel gear 1, a transmission shaft 1, a bevel gear 2 and two bevel gears 3. The rotating shaft of the driving motor is connected to the bevel gear 1, the bevel gear 2 is sleeved on the transmission shaft 1, and the bevel gear 2 is meshed with the bevel gear 1. Bevel gears 3 are provided at both ends of the transmission shaft 1.

9. The fully automatic high-concentration free radical modular generation device according to claim 8, characterized in that: The traction clamp includes a transmission shaft 2, a bevel gear 4, a gear 1, a chain and a gear 2. The two ends of the transmission shaft 2 are respectively connected to the bevel gear 4 and the gear 1. The bevel gear 4 is meshed with the bevel gear 3. The gear 1 is connected to the gear 2 through a chain. A triangular bracket is installed on the chain. A roller is installed on the triangular bracket. A rectangular convex portion is provided on the side wall of the slider opposite to the chain, and the roller is in contact with the rectangular convex portion.

10. The fully automatic high-concentration free radical modular generation device according to claim 9, characterized in that: A T-shaped groove is arranged on the end surface of the sliding block opposite to the piston push rod, and one end of the piston push rod extending out of the free radical reaction tank is connected with a piston handle, and the piston handle is arranged in the T-shaped groove.

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