A zeolite rotor adsorption catalytic combustion system
By introducing adjustable cooling modules and reusing hot gases into the zeolite wheel adsorption catalytic combustion system, the problems of reduced net gas rate and high energy consumption are solved, and more efficient waste gas treatment and cost reduction are achieved.
Patent Information
- Application Number
- CN202510306899.8
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2025-03-15
- Publication Date
- 2025-08-08
- Estimated Expiration
- 2045-03-15
AI Technical Summary
The existing zeolite wheel adsorption catalytic combustion system has a decrease in the net gas rate and high energy consumption during long-term waste gas treatment. The unstable temperature of the zeolite wheel in the cooling zone affects the adsorption effect.
The adjustable cooling module and reusable hot gases for thermal blowing and desorption are adopted to enhance the cooling effect and reduce energy consumption. The exhaust gas treatment process is optimized by setting up a purification mechanism and heater.
The cooling time of the zeolite runner is extended, energy consumption is reduced, net gas rate is increased and operating costs are reduced.
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Figure CN119971711B_ABST
Abstract
Description
Technical Field
[0001] The present invention relates specifically to the technical field of organic waste gas treatment, in particular to a zeolite rotor adsorption catalytic combustion system. Background Art
[0002] The petrochemical, pharmaceutical, printing, coating, electronics and other industries emit a large amount of waste gas containing VOCs during the production process. The rapid development of these industries has led to an increasing demand for waste gas treatment. Traditional waste gas treatment technologies such as activated carbon adsorption and direct combustion have certain limitations when treating large air volume and low concentration waste gas. The zeolite rotor adsorption catalytic combustion system can efficiently treat this type of waste gas and meet the actual needs of enterprises.
[0003] The zeolite rotor adsorption catalytic combustion system combines zeolite rotor adsorption technology with catalytic combustion technology, forming a combined process with complementary advantages. The zeolite rotor can concentrate high-volume, low-concentration exhaust gas into low-volume, high-concentration exhaust gas, reducing the difficulty and cost of subsequent catalytic combustion treatment; while catalytic combustion technology can completely decompose the concentrated high-concentration exhaust gas into harmless carbon dioxide and water, achieving efficient exhaust gas purification. However, existing zeolite rotor adsorption catalytic combustion systems still have the following drawbacks:
[0004] 1. There are still some defects in the treatment of exhaust gas in the zeolite rotor adsorption catalytic combustion system. During long-term exhaust gas treatment operations, the net gas rate is likely to gradually decrease, there is a risk of exhaust gas failure, and energy consumption is high;
[0005] 2. When the zeolite wheel rotates to the cooling zone, since the temperature of the heated air in the desorption zone is between 180 and 250°C, in the case of unstable temperature, it is easy for the zeolite wheel in the cooling zone to fail to reach the standard range of cooling temperature, thereby affecting the local adsorption effect of the zeolite wheel. Summary of the Invention
[0006] To this end, the present invention proposes a zeolite rotor adsorption catalytic combustion system to solve the problems raised in the above background technology.
[0007] To achieve the above objectives, the present invention provides the following technical solutions: a zeolite rotor adsorption catalytic combustion system, comprising:
[0008] Zeolite wheel adsorption device;
[0009] The first branch has one end that introduces the organic waste gas and the other end that flows through the air inlet end of the zeolite wheel adsorption device;
[0010] The second branch is connected between the desorption port and the heat blowing port of the zeolite wheel adsorption device, and a purification mechanism, a flame arrester, and a heater are sequentially arranged on the second branch along the flow direction thereof;
[0011] A third branch, one end of which introduces outdoor air and the other end of which is connected to the cooling port of the zeolite wheel adsorption device;
[0012] A fourth branch, one end of which is connected to the second branch located between the flame arrester and the first heater, and the other end of which is connected to the cold outlet of the zeolite rotor adsorption device;
[0013] and a fifth branch, which is connected between the exhaust port of the zeolite wheel adsorption device and the exhaust device.
[0014] Further, preferably, the zeolite wheel adsorption device comprises:
[0015] a casing, in which a bearing frame is disposed;
[0016] The front end of the zeolite runner is rotatably mounted on the bearing frame by a rotating shaft, and the rear end of the zeolite runner is provided with a collar, and the collar is fixed to the casing;
[0017] and a cooling module, which and the high-temperature module are both fixed on the bearing frame, the cooling module is connected to the high-temperature module, and the cooling module and the high-temperature module are both fitted with the zeolite rotor.
[0018] Furthermore, preferably, the cooling module consists of an outer shell, an inner shell, a sealing plate and a driving mechanism, wherein the outer shell and the inner shell both adopt a fan-shaped structure, the inner shell is slidingly connected to the outer shell through the driving mechanism, and the outer end of the inner shell is fixedly sealed with a sealing plate.
[0019] Furthermore, preferably, the end face of the outer shell that fits with the zeolite rotor is open, the bottom plate of the inner shell is fitted with the zeolite rotor, and the inner shell is driven by a driving mechanism to slide along the arc direction of the outer shell to adjust and control the contact area between the zeolite rotor and the cooling module.
[0020] Furthermore, preferably, the driving mechanism includes:
[0021] an arc-shaped rack fixed in the inner housing;
[0022] A driven gear 1 meshes with the arc-shaped rack for transmission, and the driven gear 1 is connected to the driven gear 2 via a connecting column;
[0023] A transmission gear is rotatably mounted on a bracket fixed in the inner housing, and the transmission gear is meshed with the driven gear for transmission;
[0024] and a driving gear, which is driven by a heat-proof motor fixed in the inner shell, and the driving gear is meshed with the transmission gear for transmission.
[0025] Furthermore, as a preference, a ventilation chamber is attached to the rear end surface of the zeolite rotor, and the ventilation chamber is fixed to the casing. A plurality of partitions are provided in the ventilation chamber, and the inner cavity of the ventilation chamber is divided into a cooling zone, a high-temperature desorption zone, an emptying zone, and an adsorption zone, wherein,
[0026] The cooling zone is connected between the cooling module and the cold outlet;
[0027] The high temperature desorption zone is connected between the high temperature module and the heat blowing port;
[0028] The adsorption zone is communicated with the exhaust port, and the emptying zone is communicated with the circulation port of the zeolite wheel adsorption device.
[0029] Furthermore, as a preference, a pressurizing fan, a pressure gauge, an air volume regulating valve 1, and a multi-stage filtering device are sequentially arranged on the first branch and along its flow direction, and an exhaust pipe is connected to the first branch between the pressure gauge and the air volume regulating valve 1, and an exhaust valve is installed on the exhaust pipe.
[0030] Furthermore, preferably, the circulation port of the zeolite wheel adsorption device is connected to one end of a sixth branch, the other end of the sixth branch is connected to the first branch located in front of the pressurized fan, and an exhaust valve 1 is installed on the sixth branch.
[0031] Furthermore, as a preference, an air volume regulating valve 4 is installed on the second branch between the purification mechanism and the zeolite wheel adsorption device;
[0032] A thermometer, a desorption fan, and a second air volume regulating valve are also installed on the second branch and located between the first heater and the zeolite wheel adsorption device;
[0033] The third branch line is provided with an air volume regulating valve 3, a cooling fan, and a refrigerator in sequence along its flow direction;
[0034] The fourth branch is provided with a second heater;
[0035] The fifth branch is provided with an exhaust valve 2.
[0036] Furthermore, preferably, the purification mechanism includes:
[0037] The catalytic combustion chamber has an air inlet connected to a seventh branch for introducing outdoor air, and an air volume regulating valve 5 and an air inlet fan are installed on the seventh branch;
[0038] and a heat exchanger, which is connected to the catalytic combustion chamber through a second branch, and the heat exchanger is located behind the catalytic combustion chamber.
[0039] The present invention adopts the above technology and has the following beneficial effects compared with the existing technology:
[0040] 1. This zeolite rotor adsorption device is equipped with an adjustable cooling module. The outer shell and the inner shell are slidably connected. On the one hand, the volume of the arc-shaped cavity formed by the two is changed, increasing the amount of cooling gas introduced and enhancing the cooling effect. On the other hand, the contact position between the bottom plate of the inner shell and the zeolite rotor is changed, so that the cooling area of the zeolite rotor is increased, thereby extending the local cooling time of the zeolite rotor and ensuring that it reaches the standard cooling temperature range.
[0041] 2. In the system of the present invention, the second branch uses reused hot gas to perform hot-blowing desorption treatment on the zeolite rotor. The reuse of hot gas avoids the energy consumption of reheating fresh gas for each desorption. The hot gas is circulated within the system, and only a small amount of heat lost due to factors such as heat dissipation needs to be replenished, which greatly reduces the energy required to heat the gas. Generally, 30% to 50% of heating energy can be saved, effectively reducing the operating cost of the equipment. BRIEF DESCRIPTION OF THE DRAWINGS
[0042] Figure 1 A schematic diagram of a zeolite rotor adsorption catalytic combustion system;
[0043] Figure 2 Schematic diagram of the internal structure of a zeolite rotor adsorption device in a zeolite rotor adsorption catalytic combustion system Figure 1 ;
[0044] Figure 3 Schematic diagram of the internal structure of a zeolite rotor adsorption device in a zeolite rotor adsorption catalytic combustion system Figure 2 ;
[0045] Figure 4 A rear structural cross-sectional view of a cooling module in a zeolite rotor adsorption catalytic combustion system;
[0046] Figure 5 for Figure 4 A magnified schematic diagram of part A;
[0047] Figure 6 This is a schematic diagram of the internal structure of the ventilation chamber in a zeolite rotor adsorption catalytic combustion system.
[0048] Figure: 1, drain valve; 2, air volume control valve 1; 3, multi-stage filtration device; 4, zeolite wheel adsorption device; 5, exhaust valve 1; 6, exhaust device; 7, exhaust valve 2; 8, air volume control valve 2; 9, desorption fan; 10, thermometer; 11, heater 1; 12, heater 2; 13, refrigerator; 14, cooling fan; 15, air volume control valve 3; 16, air volume control valve 4; 17, catalytic combustion chamber; 18, air volume control valve 5; 19, induced air fan; 20, flame arrester; 21, heat exchanger; 22, barometer; 23, pressurization Fan; 401, collar; 402, zeolite rotor; 403, hot air outlet; 404, cold air outlet; 405, exhaust port; 406, casing; 407, cooling module; 408, high-temperature module; 409, ventilation chamber; 410, circulation port; 411, motor; 4071, outer shell; 4072, inner shell; 4073, baffle plate; 4074, driving gear; 4075, heat-proof motor; 4076, transmission gear; 4077, driven gear 1; 4078, connecting column; 4079, bracket; 4080, arc-shaped rack. DETAILED DESCRIPTION
[0049] The following will clearly and completely describe the technical solutions in the embodiments of the present invention in conjunction with the accompanying drawings. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative efforts are within the scope of protection of the present invention.
[0050] Example: Please see the attached Figure 1-6 The present invention provides a technical solution: a zeolite rotor adsorption catalytic combustion system, which includes:
[0051] Zeolite wheel adsorption device 4;
[0052] The first branch has one end that introduces the organic waste gas and the other end that flows through the air inlet end of the zeolite wheel adsorption device 4;
[0053] The second branch is connected between the desorption port of the zeolite wheel adsorption device 4 and the heat blowing port 403. The second branch is provided with a purification mechanism, a flame arrester 20, and a heater 11 in sequence along the flow direction thereof;
[0054] The third branch has one end that introduces outdoor air and the other end that is connected to the cooling port of the zeolite wheel adsorption device 4;
[0055] A fourth branch, one end of which is connected to the second branch located between the flame arrester 20 and the heater 11, and the other end is connected to the cold outlet 404 of the zeolite wheel adsorption device 4;
[0056] And a fifth branch, which is connected between the exhaust port 405 of the zeolite wheel adsorption device 4 and the exhaust device 6.
[0057] In this embodiment, the zeolite wheel adsorption device 4 includes:
[0058] The housing 406 has a bearing frame disposed therein;
[0059] The front end of the zeolite wheel 402 is rotatably mounted on a bearing frame using a rotating shaft, and the rear end of the zeolite wheel 402 is provided with a collar 401, which is fixed to the housing 406;
[0060] and a cooling module 407, which and a high-temperature module 408 are fixed on the bearing frame, the cooling module 407 is connected to the high-temperature module 408, and the cooling module 407 and the high-temperature module 408 are both fitted with the zeolite wheel 402;
[0061] It should be added that a large synchronous wheel is fixed on the rotating shaft, and a belt is used between the large synchronous wheel and the small synchronous wheel, and the small synchronous wheel is fixed on the driving end of the motor 411;
[0062] Furthermore, the casing 406 adopts a sealed structure, and the exhaust gas is injected from the front port of the casing 406 , and is discharged from the exhaust port 405 or the circulation port 410 after the zeolite wheel adsorption process.
[0063] In this embodiment, the cooling module 407 is composed of an outer shell 4071, an inner shell 4072, a sealing plate 4073 and a driving mechanism, wherein the outer shell 4071 and the inner shell 4072 both adopt a fan-shaped structure, the inner shell 4072 is slidingly connected to the outer shell 4071 through the driving mechanism, and the outer end of the inner shell 4072 is fixedly sealed with a sealing plate 4073.
[0064] In this embodiment, the end surface of the outer shell 4071 that contacts the zeolite rotor 402 is open, and the bottom plate of the inner shell 4072 is contacted with the zeolite rotor 402. The inner shell 4072 is driven by a driving mechanism to slide along the arc of the outer shell 4071 to adjust and control the contact area between the zeolite rotor 402 and the cooling module 407.
[0065] Specifically, the outer shell and the inner shell are slidably connected, which, on the one hand, changes the volume of the arc-shaped cavity formed by the two, increases the amount of cooling gas introduced, and enhances the cooling effect; on the other hand, it changes the contact position between the bottom plate of the inner shell and the zeolite rotor, thereby increasing the cooling area of the zeolite rotor and extending the local cooling time of the zeolite rotor to ensure that it reaches the standard range of the cooling temperature.
[0066] In this embodiment, the driving mechanism includes:
[0067] an arc-shaped rack 4080 fixed in the inner housing 4072;
[0068] Driven gear 1 4077 is meshed with arc-shaped rack 4080 for transmission. Driven gear 1 4077 is connected to driven gear 2 via connecting column 4078.
[0069] The transmission gear 4076 is rotatably mounted on a bracket 4079 fixed in the inner housing 4072, and the transmission gear 4076 is meshed with the driven gear for transmission;
[0070] and a driving gear 4074, which is driven by a heat-proof motor 4075 fixed in the inner housing 4072, and the driving gear 4074 is meshed with a transmission gear 4076 for transmission;
[0071] It should be added that the arc-shaped rack 4080, the outer shell and the inner shell share the same center, so as to drive the inner shell to slide along the arc direction of the outer shell.
[0072] In this embodiment, a ventilation chamber 409 is attached to the rear end surface of the zeolite rotor 402, and the ventilation chamber 409 is fixed to the housing 406. A plurality of partitions are provided in the ventilation chamber 409, and the inner cavity of the ventilation chamber 409 is divided into a cooling zone, a high-temperature desorption zone, an emptying zone, and an adsorption zone.
[0073] The cooling zone is connected between the cooling module 407 and the cold outlet 404;
[0074] The high-temperature desorption zone is connected between the high-temperature module 408 and the heat blowing port 403;
[0075] The adsorption zone is connected to the exhaust port 405, and the emptying zone is connected to the circulation port 410 of the zeolite wheel adsorption device 4;
[0076] Specifically, the area of the exhaust zone is 1 / 2 of the adsorption zone. Since the local zeolite rotor in the exhaust zone is in long-term adsorption treatment, its adsorption capacity decreases. Therefore, the exhaust gas passing through the local zeolite rotor is re-discharged into the first branch for re-adsorption treatment.
[0077] In this embodiment, a pressurizing fan 23, a pressure gauge 22, an air volume regulating valve 2, and a multi-stage filtering device 3 are sequentially arranged on the first branch and along its flow direction, and an exhaust pipe is connected to the first branch between the pressure gauge 22 and the air volume regulating valve 2, and an exhaust valve 1 is installed on the exhaust pipe.
[0078] In this embodiment, the circulation port 410 of the zeolite wheel adsorption device 4 is connected to one end of the sixth branch, the other end of the sixth branch is connected to the first branch located in front of the pressurized fan 23, and the exhaust valve 5 is installed on the sixth branch.
[0079] In this embodiment, an air volume regulating valve 4 16 is installed on the second branch between the purification mechanism and the zeolite wheel adsorption device 4;
[0080] The second branch is also equipped with a thermometer 10, a desorption fan 9, and an air volume regulating valve 8 between the heater 11 and the zeolite wheel adsorption device 4;
[0081] The third branch is provided with an air volume regulating valve 15, a cooling fan 14, and a refrigerator 13 in sequence along its flow direction;
[0082] The fourth branch is provided with a heater 2 12;
[0083] An exhaust valve 2 7 is installed on the fifth branch.
[0084] In this embodiment, the purification mechanism includes:
[0085] The catalytic combustion chamber 17 has an air inlet connected to a seventh branch for introducing outdoor air, and an air volume regulating valve 18 and an air inlet fan 19 are installed on the seventh branch;
[0086] and a heat exchanger 21, which is connected to the catalytic combustion chamber 17 via a second branch, and the heat exchanger 21 is located behind the catalytic combustion chamber 17;
[0087] It should be noted that the first branch is used to pre-filter the organic waste gas, and then introduce the organic waste gas into the zeolite wheel adsorption device 4 for organic adsorption process, while the gas passing through the adsorption zone is discharged, and the gas passing through the exhaust zone is circulated into the first branch for re-adsorption treatment;
[0088] The second branch uses reused hot gas to perform hot-blowing desorption on the zeolite wheel. The reuse of hot gas avoids the energy consumption of reheating fresh gas for each desorption. The hot gas is circulated within the system, and only a small amount of heat lost due to factors such as heat dissipation needs to be replenished, which greatly reduces the energy required to heat the gas. Generally, 30% to 50% of heating energy can be saved, effectively reducing the operating cost of the equipment.
[0089] While embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions, and variations may be made to these embodiments without departing from the principles and spirit of the invention, and that the scope of the invention is defined by the appended claims and their equivalents.
Claims
1. A zeolite rotor adsorption catalytic combustion system, characterized in that: It includes: Zeolite rotor adsorption device (4); A first branch, one end of which introduces organic waste gas and the other end of which is connected to the air inlet end of the zeolite wheel adsorption device (4); A second branch is connected between the desorption port and the heat blowing port (403) of the zeolite wheel adsorption device (4), and a purification mechanism, a flame arrester (20), and a heater (11) are sequentially arranged on the second branch along the flow direction thereof; A third branch, one end of which introduces outdoor air and the other end of which is connected to the cooling port of the zeolite wheel adsorption device (4); A fourth branch, one end of which is connected to the second branch located between the flame arrester (20) and the heater (11), and the other end of which is connected to the cold outlet (404) of the zeolite wheel adsorption device (4); and a fifth branch, which is connected between the exhaust port (405) of the zeolite wheel adsorption device (4) and the exhaust device (6); The zeolite wheel adsorption device (4) comprises: a housing (406) having a bearing frame disposed therein; A zeolite wheel (402) has a front end rotatably mounted on a bearing frame using a rotating shaft, and a rear end of the zeolite wheel (402) is sleeved with a collar (401), and the collar (401) is fixed to a housing (406); and a cooling module (407), which and a high-temperature module (408) are both fixed on the bearing frame, the cooling module (407) is connected to the high-temperature module (408), and the cooling module (407) and the high-temperature module (408) are both in contact with the zeolite rotor (402); The cooling module (407) is composed of an outer shell (4071), an inner shell (4072), a blocking plate (4073), and a driving mechanism, wherein the outer shell (4071) and the inner shell (4072) both adopt a fan-shaped structure, the inner shell (4072) is adapted and slidably connected to the outer shell (4071) through the driving mechanism, and the outer end of the inner shell (4072) is fixedly sealed with the blocking plate (4073); The end face of the outer shell (4071) that fits with the zeolite rotor (402) is open, and the bottom plate of the inner shell (4072) is fitted with the zeolite rotor (402). The inner shell (4072) is driven by a driving mechanism to slide along the arc direction of the outer shell (4071) to adjust and control the contact area between the zeolite rotor (402) and the cooling module (407).
2. The zeolite rotor adsorption catalytic combustion system according to claim 1, characterized in that: The driving mechanism comprises: an arc-shaped rack (4080) fixed in the inner shell (4072); A driven gear 1 (4077) is meshed with the arc-shaped rack (4080) for transmission, and the driven gear 1 (4077) is connected to the driven gear 2 via a connecting column (4078); A transmission gear (4076) is rotatably mounted on a bracket (4079) fixed in the inner housing (4072), and the transmission gear (4076) is meshed with a driven gear for transmission; and a driving gear (4074), which is driven by a heat-proof motor (4075) fixed in the inner shell (4072), and the driving gear (4074) is meshed with a transmission gear (4076) for transmission.
3. The zeolite rotor adsorption catalytic combustion system according to claim 1, characterized in that: A ventilation chamber (409) is attached to the rear end surface of the zeolite rotor (402), and the ventilation chamber (409) is fixed to the housing (406). A plurality of partitions are provided in the ventilation chamber (409), and the inner cavity of the ventilation chamber (409) is divided into a cooling zone, a high-temperature desorption zone, an exhaust zone, and an adsorption zone, wherein: The cooling zone is connected between the cooling module (407) and the cold outlet (404); The high-temperature desorption zone is connected between the high-temperature module (408) and the heat blowing port (403); The adsorption zone is connected to the exhaust port (405), and the emptying zone is connected to the circulation port (410) of the zeolite wheel adsorption device (4).
4. The zeolite rotor adsorption catalytic combustion system according to claim 3, characterized in that: A pressurizing fan (23), a pressure gauge (22), an air volume regulating valve (2), and a multi-stage filtering device (3) are sequentially arranged on the first branch line and along its flow direction, and an exhaust pipe is connected to the first branch line between the pressure gauge (22) and the air volume regulating valve (2), and an exhaust valve (1) is installed on the exhaust pipe.
5. The zeolite rotor adsorption catalytic combustion system according to claim 4, characterized in that: The circulation port (410) of the zeolite wheel adsorption device (4) is connected to one end of a sixth branch, the other end of the sixth branch is connected to the first branch located in front of the pressurized fan (23), and an exhaust valve (5) is installed on the sixth branch.
6. The zeolite rotor adsorption catalytic combustion system according to claim 1, characterized in that: An air volume regulating valve (16) is installed on the second branch between the purification mechanism and the zeolite wheel adsorption device (4); A thermometer (10), a desorption fan (9), and a second air volume regulating valve (8) are also installed on the second branch and located between the first heater (11) and the zeolite wheel adsorption device (4); The third branch is provided with an air volume regulating valve (15), a cooling fan (14), and a refrigerator (13) in sequence along its flow direction; The fourth branch is provided with a second heater (12); The fifth branch is provided with a second exhaust valve (7).
7. The zeolite rotor adsorption catalytic combustion system according to claim 6, characterized in that: The purification mechanism comprises: A catalytic combustion chamber (17) is provided, wherein the air inlet is connected to a seventh branch for introducing outdoor air, and the seventh branch is provided with an air volume regulating valve (18) and an air inlet fan (19); and a heat exchanger (21) is connected to the catalytic combustion chamber (17) via a second branch, and the heat exchanger (21) is located at the rear of the catalytic combustion chamber (17).
Citation Information
Patent Citations
System for treating high-boiling-point organic waste gas by zeolite runner adsorption-catalytic combustion
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Adsorber for zeolite rotating wheel
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