Sulfonamide compound and noxious arthropod control composition containing same

Abstract

Provided is a compound represented by formula (I) (in the formula, Q represented by the following formula (in the formula, # represents a bonding site with a sulfur atom and a bonding site with Het) represents a group represented by formula Q1 or the like, R2a and R2b are the same or different and represent a C1-C6 alkyl group or the like which may be substituted with one or more halogen atoms, R3a, R3b and R3d are the same or different, and R3d represents a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom or a hydrogen atom. A represents a hydrogen atom or the like, Het represents a group represented by formula Het5 or the like, A2 represents NR5a or CR4aR4d, A3 represents CR4bR4e, W1 represents an oxygen atom or a sulfur atom, and when Het is a group represented by formula Het5, a combination of B1, B2 and B3 represents B1 is CR6e, B2 is a nitrogen atom or CR6b, B3 is a combination of nitrogen atom or CR6c or the like, R4a, R4b, R6a, R6b and R6c are the same or different from each other and represent a hydrogen atom or the like, R4d and R4e are the same or different from each other and represent a hydrogen atom or the like, and R1 represents a hydrogen atom or the like. R6e represents a C1-C6 chain hydrocarbon group or the like substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms; and R5a represents a hydrogen atom or the like. ) A compound represented by formula (1) or an N-oxide thereof. # imgabs0 #

Description

Technical Field

[0001] This patent application asserts priority and interests under the Paris Convention based on Japanese Patent Application No. 2022-165233 (filed on October 14, 2022), the entire contents of which are incorporated herein by reference.

[0002] This invention relates to sulfonamide compounds and compositions for controlling harmful arthropods containing the sulfonamide compounds. Background Technology

[0003] To date, various compounds have been studied for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes a compound that has pest control effects.

[0004] Existing technical documents

[0005] Patent documents

[0006] Patent Document 1: International Publication No. 2020 / 158889 Summary of the Invention

[0007] The problem that the invention aims to solve

[0008] The purpose of this invention is to provide compounds that have excellent control efficacy against harmful arthropods.

[0009] Methods for solving problems

[0010] The inventors of this application conducted research in order to find compounds with excellent control efficacy against harmful arthropods, and found that the compound represented by the following formula (I) has excellent control efficacy against harmful arthropods.

[0011] That is, the present invention is as follows.

[0012] [1] The compound shown in formula (I) (hereinafter referred to as compound N of the present invention) or its N oxide (hereinafter, the compound shown in formula (I) or its N oxide is referred to as compound of the present invention).

[0013] [Chemical Formula 1]

[0014]

[0015] In the formula,

[0016] In the following formulas, Q represents the group shown in formula Q1, formula Q2, formula Q3, formula Q4, formula Q5, formula Q6, or formula Q7 (# indicates the bonding site with sulfur atoms, ● indicates the bonding site with Het).

[0017] [Chemical Formula 2]

[0018]

[0019] [Chemical Formula 3]

[0020]

[0021] A 1 Indicates NR 5 oxygen or sulfur atoms

[0022] G 1 G 2 G 3 and G 4 Combinatorial representation:

[0023] G 1 Nitrogen atom or CR 3a G 2 For CR 3b G 3 For CR 3d G 4 For CR 3c The combination;

[0024] G 1 For CR 3a G 2 For nitrogen atoms, G 3 For CR 3d G 4 For CR 3c The combination;

[0025] G 1 For CR 3a G 2 For CR 3b G 3 For nitrogen atoms, G 4 For CR 3c A combination; or

[0026] G 1 For CR 3a G 2 For CR 3b G 3 For CR 3d G 4 A combination of nitrogen atoms,

[0027] R 2a and R 2b "Same" or "different from each other" refers to a C1-C6 alkyl group that can be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group that can be substituted with one or more halogen atoms, or a hydrogen atom; or

[0028] R 2a and R 2b They can combine with the nitrogen atoms they are bonded to to form acridine, azahexacyclic butyl, pyrrolidinyl, or piperidinyl groups.

[0029] R 3a R 3b R 3c R 3d R 3f R 3g R 3i and R 3k "Same or different" indicates a C1-C6 chain hydrocarbon group that can be substituted by one or more substituents selected from group B, a C3-C7 cycloalkyl group that can be substituted by one or more substituents selected from group E, a phenyl group that can be substituted by one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group that can be substituted by one or more substituents selected from group H, OR 12 NR 11 R 12 NR 11a R 12a NR 24 NR 11 R 12 NR 24 OR 11 NR 11 C(O)R 13 NR 24 NR 11 C(O)R 13 NR 11 C(O)OR 14 NR 24 NR 11 C(O)OR 14 NR 11 C(O)NR 31 R 32 NR 24 NR 11 C(O)NR 31 R 32 N = CHNR 31 R 32 N = S(O) p R 15 R 16 C(O)R 13 C(O)OR 17 C(O)NR 31 R 32 C(O)NR 11 S(O)2R 23 CR 30 =NOR 17 NR11 CR 24 =NOR 17 S(O) q R 23 Cyano group, nitro group, hydrogen atom or halogen atom,

[0030] R 3e and R 3h "Identical" or "different from each other" refers to C1-C6 alkyl groups that can be substituted with one or more halogen atoms, or phenyl groups that can be substituted with one or more substituents selected from group H.

[0031] When Q is a group represented by formula Q1, R 3a R 3b and R 3d The two adjacent substituents in the ring can, together with the two carbon atoms they are bonded to, form a benzene ring, pyrrole ring, furan ring, thiophene ring, pyrazole ring, imidazole ring, oxazole ring, isoxazole ring, thiazole ring, isothiazole ring, oxadiazole ring, thiadiazole ring, pyridine ring, pyridazine ring, pyrimidine ring, pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring, and the pyrazine ring can be substituted by one or more substituents selected from group H}, or a triazole ring that can be substituted by one or more substituents selected from group I.

[0032] p represents 0 or 1.

[0033] q represents 0, 1, or 2.

[0034] R 30 This refers to C1-C6 chain hydrocarbon groups, halogen atoms, and OR that can be replaced by one or more halogen atoms. 35 NR 36 R 37 Or hydrogen atoms,

[0035] R 17 This indicates a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms, a phenyl group that can be substituted by one or more substituents selected from group D, or a hydrogen atom.

[0036] R 12 This indicates a C1-C6 chain hydrocarbon group that can be substituted by one or more substituents selected from group F; a C3-C7 cycloalkyl group that can be substituted by one or more substituents selected from group J; a C3-C7 cycloalkenyl group that can be substituted by one or more substituents selected from group J; a phenyl group that can be substituted by one or more substituents selected from group D; a 6-membered aromatic heterocyclic group that can be substituted by one or more substituents selected from group D; a hydrogen atom; or S(O)2R. 23 ,

[0037] R23 This indicates a C1-C6 chain hydrocarbon group that can be substituted by one or more halogen atoms, or a phenyl group that can be substituted by one or more substituents selected from group D.

[0038] R 11a and R 12a Together with the nitrogen atoms they are bonded to, they form 3-7 membered non-aromatic heterocyclic groups that can be substituted by one or more substituents selected from group E.

[0039] R 13 This indicates a C1-C6 chain hydrocarbon group that can be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group that can be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group that can be substituted with one or more halogen atoms, a phenyl group that can be substituted with one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group that can be substituted with one or more substituents selected from group D, or a hydrogen atom.

[0040] R 14 This indicates a C1-C6 chain hydrocarbon group that can be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group that can be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group that can be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl portion of the phenyl C1-C3 alkyl group can be substituted with one or more substituents selected from group D}.

[0041] R 15 and R 16 "Identical" or "different from each other" indicates C1-C6 alkyl groups that can be substituted with one or more halogen atoms.

[0042] R 31 This refers to a C1-C6 alkyl group or a hydrogen atom that can be substituted by one or more halogen atoms.

[0043] R 32 This indicates a C1-C6 chain hydrocarbon group that can be substituted by one or more substituents selected from group F, a C3-C7 cycloalkyl group that can be substituted by one or more substituents selected from group J, or a hydrogen atom.

[0044] Het represents the group shown in formula Het5, formula Het6, or formula Het7.

[0045] [Chemical Formula 4]

[0046]

[0047] A 2 Indicates NR 5a or CR 4a R 4d ,

[0048] A 3 Indicates CR 4b R 4e ,

[0049] A 4 Indicates NR 5b or CR 4c R 4f ,

[0050] W 1 Represents oxygen or sulfur atoms.

[0051] When Het is a group represented by formula Het5.

[0052] B 1 B 2 and B 3 Combinatorial representation:

[0053] B 1 For CR 6e B 2 Nitrogen atom or CR 6b B 3 Nitrogen atom or CR 6c The combination;

[0054] B 1 Nitrogen atom or CR 6a B 2 For CR 6e B 3 Nitrogen atom or CR 6c A combination; or

[0055] B 1 Nitrogen atom or CR 6a B 2 Nitrogen atom or CR 6b B 3 For CR 6e The combination

[0056] When Het is a group represented by formula Het6.

[0057] A 2 and A 4 Combinatorial representation:

[0058] A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f A combination; or

[0059] A 2 For NR 5a A4 For CR 4c R 4f The combination;

[0060] B 1 B 2 and B 3 Combinatorial representation:

[0061] B 1 For CR 6e B 2 Nitrogen atom or CR 6b B 3 Nitrogen atom or CR 6c The combination;

[0062] B 1 Nitrogen atom or CR 6a B 2 For CR 6e B 3 Nitrogen atom or CR 6c A combination; or

[0063] B 1 Nitrogen atom or CR 6a B 2 Nitrogen atom or CR 6b B 3 For CR 6e The combination

[0064] When Het is a group represented by formula Het7.

[0065] A 2 and A 4 Combinatorial representation:

[0066] A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f A combination; or

[0067] A 2 For NR 5a A 4 For CR 4c R 4f The combination;

[0068] B 1 B 2 B 3 and B 4 Combinatorial representation:

[0069] B 1 Nitrogen atom or CR6a B 2 For CR 6e B 3 Nitrogen atom or CR 6c B 4 Nitrogen atom or CR 6d The combination;

[0070] B 1 Nitrogen atom or CR 6a B 2 Nitrogen atom or CR 6b B 3 For CR 6e B 4 Nitrogen atom or CR 6d The combination;

[0071] B 1 Nitrogen atom or CR 6a B 2 Nitrogen atom or CR 6b B 3 For CR 6c B 4 For CR 6e The combination;

[0072] B 1 Nitrogen atom or CR 6a B 2 For CR 6b B 3 For nitrogen atoms, B 4 For CR 6e A combination; or

[0073] B 1 For CR 6a B 2 For nitrogen atoms, B 3 For nitrogen atoms, B 4 For CR 6e The combination

[0074] R 4a R 4b R 4c R 6a R 6b R 6c and R 6d Same or different from each other, indicating C1-C6 chain hydrocarbon groups, nitro groups, OR groups that can be substituted by more than one halogen atom. 18 NR 18 R 19 , cyano, amino, halogen or hydrogen atom,

[0075] R 4d R 4eand R 4f "Identical" or "different from each other" indicates a C1-C6 chain hydrocarbon group, cyano group, halogen atom, or hydrogen atom that can be substituted by one or more halogen atoms.

[0076] R 6e This indicates a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms, a C3-C4 cycloalkyl group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms, and S(O). m R 7 OR 7 halogen atoms or OS(O)2R 7 ,

[0077] R 5 This indicates a C1-C6 chain hydrocarbon group that can be substituted with one or more halogen atoms, a C1-C6 alkoxy group that can be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group that can be substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group that can be substituted with one or more halogen atoms, or a hydrogen atom.

[0078] R 5a and R 5b "Identical" or "different from each other" indicates a C1-C6 chain hydrocarbon group that can be substituted with one or more substituents selected from group K, a C1-C6 alkoxy group that can be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group that can be substituted with one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group that can be substituted with one or more halogen atoms, or a hydrogen atom.

[0079] R 7 This refers to a C1-C6 chain hydrocarbon group that has been substituted by one or more halogen atoms.

[0080] m represents 0, 1, or 2.

[0081] R 18 and R 35 The same or different from each other indicates C1-C6 chain hydrocarbon groups that can be substituted by more than one halogen atom.

[0082] R 11 R 19 R 24 R 36 and R 37 "Same or different" indicates a C1-C6 chain hydrocarbon group or hydrogen atom that can be replaced by one or more halogen atoms.

[0083] Group B: The group consisting of C1-C6 alkoxy groups that can be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups that can be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups that can be substituted with one or more halogen atoms, C1-C6 alkylthioalkyl groups that can be substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups that can be substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups that can be substituted with one or more halogen atoms, C3-C6 cycloalkyl groups, cyano groups, hydroxyl groups, and halogen atoms.

[0084] Group C: A group consisting of C1-C6 chain hydrocarbon groups that can be substituted by one or more halogen atoms, C1-C6 alkoxy groups that can be substituted by one or more halogen atoms, C3-C6 chain alkenyloxy groups that can be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups that can be substituted by one or more halogen atoms, and halogen atoms.

[0085] Group D: Composed of C1-C6 chain hydrocarbon groups that can be substituted with one or more halogen atoms, hydroxyl groups, C1-C6 alkoxy groups that can be substituted with one or more halogen atoms, C3-C6 alkenyloxy groups that can be substituted with one or more halogen atoms, C3-C6 alkynyloxy groups that can be substituted with one or more halogen atoms, thioalkyl groups, C1-C6 alkylthioalkyl groups that can be substituted with one or more halogen atoms, C1-C6 alkylsulfinyl groups that can be substituted with one or more halogen atoms, C1-C6 alkylsulfonyl groups that can be substituted with one or more halogen atoms, amino groups, NHR 21 NR 21 R 22 C(O)R 21 OC(O)R 21 C(O)OR 21 It is a group composed of cyano, nitro and halogen atoms.

[0086] R 21 and R 22 "Identical" or "different from each other" indicates C1-C6 alkyl groups that can be substituted by one or more halogen atoms.

[0087] Group E: The group consisting of C1-C6 chain hydrocarbon groups that can be substituted by one or more halogen atoms, C1-C6 alkoxy groups that can be substituted by one or more halogen atoms, C3-C6 chain alkenyloxy groups that can be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups that can be substituted by one or more halogen atoms, halogen atoms, oxo groups, hydroxyl groups, cyano groups, and nitro groups.

[0088] Group F: Composed of C1-C6 alkoxy groups that can be substituted with one or more halogen atoms, phenyl groups that can be substituted with one or more substituents selected from Group D, 5- or 6-membered aromatic heterocyclic groups that can be substituted with one or more substituents selected from Group D, C3-C7 cycloalkyl groups that can be substituted with one or more halogen atoms, 3- to 7-membered non-aromatic heterocyclic groups that can be substituted with one or more substituents selected from Group C, amino groups, NHR groups. 21 NR 21 R 22 A group composed of halogen atoms and cyano groups.

[0089] Group H: Composed of C1-C6 alkyl groups or OR groups that can be substituted with one or more halogen atoms. 10 NR 9 R 10 C(O)R 10 C(O)NR 9 R 10 OC(O)R 9 OC(O)OR 9 NR 10 C(O)R 9 NR 10 C(O)OR 9 C(O)OR 10 It is a group composed of halogen atoms, nitro groups, cyano groups, amino groups, and 5 or 6-membered aromatic heterocyclic groups.

[0090] R 9 This refers to C1-C6 alkyl groups that can be substituted with one or more halogen atoms, or C3-C6 cycloalkyl groups that can be substituted with one or more halogen atoms.

[0091] R 10 It indicates a C1-C6 alkyl group that can be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group that can be substituted with one or more halogen atoms, or a hydrogen atom.

[0092] Group I: The group consisting of C2-C6 chain hydrocarbon groups that can be substituted with one or more halogen atoms, C3-C6 cycloalkyl groups that can be substituted with one or more halogen atoms, phenyl groups that can be substituted with one or more substituents selected from Group D, 5- or 6-membered aromatic heterocyclic groups that can be substituted with one or more substituents selected from Group D, C2-C6 alkyl carbonyl groups that can be substituted with one or more halogen atoms, C2-C6 alkoxy carbonyl groups that can be substituted with one or more halogen atoms, amino carbonyl groups, (C1-C6 alkyl)amino carbonyl groups that can be substituted with one or more halogen atoms, methyl groups, and di(C1-C4 alkyl)amino carbonyl groups that can be substituted with one or more halogen atoms.

[0093] Group J: A group consisting of C1-C6 alkyl groups that can be substituted by one or more halogen atoms, halogen atoms, and cyano groups.

[0094] Group K: A group consisting of C1-C6 alkoxy groups that can be substituted with one or more halogen atoms, phenyl groups that can be substituted with one or more substituents selected from Group D, 5- or 6-membered aromatic heterocyclic groups that can be substituted with one or more substituents selected from Group D, C3-C7 cycloalkyl groups that can be substituted with one or more halogen atoms, and 3- to 7-membered non-aromatic heterocyclic groups that can be substituted with one or more substituents selected from Group C.

[0095] [2] The compound or its N oxide as described in [1], wherein Q is a group represented by formula Q2, formula Q3 or formula Q4.

[0096] [3] The compound or its N oxide as described in [1], wherein Q is a group represented by formula Q1 or a group represented by formula Q5.

[0097] [4] The compound or its N oxide as described in [1], wherein Q is a group represented by formula Q5.

[0098] [5] The compound or its N oxide as described in [1], wherein Q is a group represented by formula Q5, and G 1 For CR 3a G 2 For CR 3b G 3 For CR 3d G 4 For CR 3c .

[0099] [6] The compound or its N oxide as described in [1], wherein Q is a group represented by formula Q5, and G 1 For CR 3a G 2 For CR 3b G 3 For CR 3d G 4 For CR 3c R 3a For hydrogen atoms, R 3b R is a C1-C6 chain hydrocarbon group, hydrogen atom, or halogen atom that can be substituted by one or more substituents selected from group B. 3c For hydrogen atoms, R 3d It is a C1-C6 chain hydrocarbon group, hydrogen atom or halogen atom that can be substituted by one or more substituents selected from group B.

[0100] [7] The compound or its N oxide as described in any one of [1] to [6], wherein Het is a group represented by formula Het7, and A 2 For CR 4a R 4d A 4 For NR 5b W1 It is an oxygen atom.

[0101] [8] A composition for controlling harmful arthropods, comprising an inactive carrier and any one of [1] to [7] or its N oxide.

[0102] [9] A composition comprising one or more components selected from the groups (a), (b), (c), and (d), and a compound or its N oxide as described in any one of [1] to [7],

[0103] Group (a): A group consisting of insecticidal, acaricidal, and nematicidal active ingredients;

[0104] Group (b): Bactericidal active ingredient;

[0105] Group (c): Plant growth regulators;

[0106] Group (d): Repellent component.

[0107]

[10] A method for controlling harmful arthropods, wherein an effective amount of any one of [1] to [7] or its N oxide or an effective amount of the composition described in [9] is applied to the harmful arthropod or its habitat.

[0108]

[11] A seed or vegetative reproductive organ containing an effective amount of any one of [1] to [7] or its N oxide or an effective amount of the composition described in [9].

[0109] Invention Effects

[0110] This invention enables the prevention and control of harmful arthropods. Detailed Implementation

[0111] The substituents in this invention will be explained.

[0112] Halogen atoms refer to fluorine, chlorine, bromine, or iodine atoms.

[0113] When a substituent is replaced by two or more halogen atoms or substituents, these halogen atoms or substituents may be the same or different.

[0114] In this specification, expressions such as "CX-CY" refer to carbon atoms ranging from X to Y. For example, expressions such as "C1-C6" refer to carbon atoms ranging from 1 to 6.

[0115] The term "chain hydrocarbon group" refers to alkyl, alkenyl, or alkynyl groups.

[0116] Examples of alkyl groups include methyl, ethyl, propyl, isopropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-ethylpropyl, butyl, sec-butyl, tert-butyl, pentyl, and hexyl.

[0117] Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl.

[0118] Examples of alkynyl groups include ethynyl, 1-propynyl, 2-propynyl, 1-methyl-2-propynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 2-butynyl, 4-pentynyl, and 5-hexynyl.

[0119] Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentoxy, and hexyloxy.

[0120] Examples of alkenyloxy groups include 2-propenyloxy, 2-butenyloxy, and 5-hexenyloxy.

[0121] Examples of alkynyloxy groups include 2-propynyloxy, 2-butynyloxy, and 5-hexynyloxy.

[0122] Examples of cycloalkyl groups include cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, and cycloheptyl.

[0123] Examples of cycloalkenyl groups include cyclopropenyl, cyclobutenyl, cyclopentenyl, cyclohexenyl, and cycloheptenyl.

[0124] Examples of 3-7 membered non-aromatic heterocyclic groups include acridinel, oxadiazolyl, thiohexacyclopropane, aziridine, oxadiazolyl, thiohexacyclobutane, pyrrolidinyl, tetrahydrofuranyl, tetrahydrothiophenyl, piperidinyl, pyranyl, dihydropyranyl, tetrahydropyranyl, tetrahydrothiophenyl, aziridine, oxadiazolyl, thiohexacyclobutane, pyrazolinyl, pyrazolinyl, imidazolinyl, imidazolinyl, oxazolinyl, thiazolinyl, isoxazolinyl, isoxazolinyl, isothiazolinyl, isothiazolinyl, isothiazolinyl, m-dioxadiazolinyl, dioxadiazolinyl, dioxadiazolinyl, morpholinyl, thiomorpholinyl, and piperazinel.

[0125] Examples of 5- or 6-membered aromatic heterocyclic groups include pyrroleyl, furanyl, thiophenyl, pyrazolyl, imidazoleyl, triazolyl, tetrazolyl, oxazolyl, isoxazolyl, thiazolyl, isothiazolyl, oxadiazolyl, thiazolyl, pyridinyl, pyrazinyl, triazinyl, and tetraazinyl.

[0126] Examples of 6-membered aromatic heterocyclic groups include pyridinyl, pyridinyl, pyrimidinyl, triazinyl, and tetraazinyl.

[0127] The term "(C3-C6 cycloalkyl)C1-C3 alkyl" refers to a (C3-C6 cycloalkyl) and / or (C1-C3 alkyl) group that can be substituted by one or more halogen atoms. Examples of such groups include cyclopropylmethyl, (2-fluorocyclopropyl)methyl, cyclopropyl(fluoro)methyl, and (2-fluorocyclopropyl(fluoro)methyl.

[0128] The term "(C3-C7 cycloalkyl)C1-C6 alkyl" refers to a group in which (C3-C7 cycloalkyl) and / or (C1-C6 alkyl) can be substituted by one or more halogen atoms. Examples of such groups include (2,2-difluorocyclopropyl)methyl, 2-cyclopropyl-1,1,2,2-tetrafluoroethyl, 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl, (2,2-difluorocyclopropyl)propyl, (2,2-difluorocyclopropyl)butyl, (2,2-difluorocyclopropyl)pentyl, and (2,2-difluorocyclopropyl)hexyl.

[0129] The term "phenyl C1-C3 alkyl" refers to a phenyl moiety in which the phenyl portion may be substituted by one or more substituents selected from group D. Examples of such substituents include benzyl, 2-fluorobenzyl, 4-(difluoromethyl)benzyl, 4-fluorobenzyl, 4-(trifluoromethyl)benzyl, and 2-[4-(trifluoromethyl)phenyl]ethyl.

[0130] The terms alkylthioalkyl, alkylsulfinyl, and alkylsulfonyl indicate the presence of S(O). z The alkyl group shown.

[0131] Examples of alkylthioalkyl groups with z=0 include methylthioalkyl, ethylthioalkyl, propylthioalkyl, and isopropylthioalkyl.

[0132] Examples of alkyl sulfinyl groups with z=1 include methyl sulfinyl, ethyl sulfinyl, propyl sulfinyl, and isopropyl sulfinyl.

[0133] Examples of alkyl sulfonyl groups with a z=2 include methyl sulfonyl, ethyl sulfonyl, propyl sulfonyl, and isopropyl sulfonyl.

[0134] Examples of alkyl carbonyl groups include acetyl, propionyl, 2-methylpropionyl, and hexanoyl.

[0135] Examples of alkoxycarbonyl groups include methoxycarbonyl, ethoxycarbonyl, isopropoxycarbonyl, and pentyloxycarbonyl.

[0136] Examples of (C1-C6 alkyl)aminocarbonyl groups include methylaminocarbonyl, ethylaminocarbonyl, propylaminocarbonyl, isopropylaminocarbonyl, butylaminocarbonyl, pentylaminocarbonyl, and hexylaminocarbonyl.

[0137] As a di(C1-C4 alkyl)aminocarbonyl, the two (C1-C4 alkyl) moieties can be the same or different from each other, and examples include dimethylaminocarbonyl, diethylaminocarbonyl, dipropylaminocarbonyl, dibutylaminocarbonyl, ethylmethylaminocarbonyl, and ethylisopropylaminocarbonyl.

[0138] As N oxides of the compounds shown in formula (I), examples include compounds shown in the following formula.

[0139] [Chemical Formula 5]

[0140]

[0141] [In the formula, the symbols have the same meaning as in the preceding text.]

[0142] In this specification, unless otherwise specified, the term "compound of the present invention" refers to compound N of the present invention.

[0143] The compounds of the present invention sometimes contain more than one stereoisomer. Examples of stereoisomers include enantiomers, diastereomers, and geometric isomers. The compounds of the present invention include each stereoisomer and mixtures of stereoisomers in any ratio.

[0144] The compounds of the present invention sometimes form acid addition salts. Examples of acids that can form acid addition salts include inorganic acids such as hydrogen chloride, phosphoric acid, and sulfuric acid, as well as organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, and p-toluenesulfonic acid. Acid addition salts can be obtained by mixing the compounds of the present invention with an acid.

[0145] Examples of compounds N in this invention include the following compounds.

[0146] [Method 1] In the compound N of the present invention, Q is a compound of the group represented by formula Q2, the group represented by formula Q3, or the group represented by formula Q4.

[0147] [Method 2] In the compound N of the present invention, Q is a compound in which Q is a group represented by formula Q1 or a group represented by formula Q5.

[0148] [Method 3] In the compound N of the present invention, Q is a compound in which Q is a group represented by formula Q5.

[0149] [Method 4] In compound N of the present invention, Q is a group represented by formula Q5, and G 1 For CR 3a G2 For CR 3b G 3 For CR 3d G 4 For CR 3c Compounds.

[0150] [Method 5] In compound N of the present invention, Q is a group represented by formula Q5, and G 1 For CR 3a G 2 For CR 3b G 3 For CR 3d G 4 For CR 3c R 3a For hydrogen atoms, R 3b R is a C1-C6 chain hydrocarbon group, hydrogen atom, or halogen atom that can be substituted by one or more substituents selected from group B. 3c For hydrogen atoms, R 3d It is a compound that can be substituted by one or more substituents selected from group B, consisting of a C1-C6 chain hydrocarbon group, a hydrogen atom, or a halogen atom.

[0151] [Method 6] In compound N of the present invention, Q is the group represented by formula Q5, and G 1 For CR 3a G 2 For CR 3b G 3 For CR 3d G 4 For CR 3c R 3a For hydrogen atoms, R 3b R is a C1-C6 chain hydrocarbon group or a halogen atom that can be substituted by one or more substituents selected from group B. 3c For hydrogen atoms, R 3d Compounds containing hydrogen atoms.

[0152] [Method 7] In compound N of the present invention, Q is a group represented by formula Q5, and G 1 For CR 3a G 2 For CR 3b G 3 For CR 3d G 4 For CR 3c R 3a R 3c and R 3d For hydrogen atoms, R 3b It is a compound of C1-C6 chain hydrocarbon group that can be substituted by one or more substituents selected from group B.

[0153] [Method 8] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0154] [Method 9] In compound N of the present invention, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0155] [Method 10] In compound N of the present invention, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e Compounds.

[0156] [Method 11] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0157] [Method 12] In compound N of the present invention, Het is the group represented by formula Het6, A 2 For CR4a R 4d W 1 Compounds containing oxygen atoms.

[0158] [Method 13] In compound N of the present invention, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0159] [Method 14] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0160] [Method 15] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 4a R 4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR7 Or compounds containing halogen atoms.

[0161] [Method 16] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0162] [Method 17] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e A compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0163] [Method 18] In compound N of the present invention, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0164] [Method 19] In compound N of the present invention, Het is a group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0165] [Method 20] In Method 1, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0166] [Method 21] In Method 2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0167] [Method 22] In Method 3, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0168] [Method 23] In Method 4, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0169] [Method 24] In Method 5, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0170] [Method 25] In Method 6, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0171] [Method 26] In Method 7, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 Compounds containing oxygen atoms.

[0172] [Method 27] In Method 1, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0173] [Method 28] In Method 2, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0174] [Method 29] In Method 3, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0175] [Method 30] In Method 4, Het is the group shown in Formula Het6, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0176] [Method 31] In Method 5, Het is the group shown in Formula Het6, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0177] [Method 32] In Method 6, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0178] [Method 33] In Method 7, Het is the group shown in Formula Het6, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0179] [Method 34] In Method 1, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3For CR 4b R 4e Compounds.

[0180] [Method 35] In Method 2, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e Compounds.

[0181] [Method 36] In Method 3, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e Compounds.

[0182] [Method 37] In Method 4, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e Compounds.

[0183] [Method 38] In Method 5, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e Compounds.

[0184] [Method 39] In Method 6, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e Compounds.

[0185] [Method 40] In Method 7, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e Compounds.

[0186] [Method 41] In Method 1, Het is the group represented by formula Het7, A 2 For CR 4a R4d A 4 For NR 5b W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0187] [Method 42] In Method 2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0188] [Method 43] In Method 3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0189] [Method 44] In Method 4, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0190] [Method 45] In Method 5, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 B 2 B 3 and B4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0191] [Method 46] In Method 6, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0192] [Method 47] In Method 7, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2For CR 6e B 3 For CR 6c B 4 For CR 6d Combinations; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0193] [Method 48] In Method 1, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0194] [Method 49] In Method 2, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0195] [Method 50] In Method 3, Het is the group shown in Formula Het6, A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0196] [Method 51] In Method 4, Het is the group shown in Formula Het6, A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0197] [Method 52] In Method 5, Het is the group shown in Formula Het6, A2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0198] [Method 53] In Method 6, Het is the group represented by formula Het6, A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0199] [Method 54] In Method 7, Het is the group shown in Formula Het6, A 2 For CR 4a R 4d A 4 For NR 5b or CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0200] [Method 55] In Method 1, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0201] [Method 56] In Method 2, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0202] [Method 57] In Method 3, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0203] [Method 58] In Method 4, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0204] [Method 59] In Method 5, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0205] [Method 60] In Method 6, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0206] [Method 61] In Method 7, Het is the group shown in Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 Compounds containing oxygen atoms.

[0207] [Method 62] In Method 1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0208] [Method 63] In Method 2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0209] [Method 64] In Method 3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0210] [Method 65] In Method 4, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0211] [Method 66] In Method 5, Het is the group shown in Formula Het7, A2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0212] [Method 67] In Method 6, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0213] [Method 68] In Method 7, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 6a R 6c and R 6d Compounds containing hydrogen atoms.

[0214] [Method 69] In Method 1, Het is the group shown in Formula Het7, A 2 For CR 4a R4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 4a R 4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0215] [Method 70] In Method 2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 4a R 4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0216] [Method 71] In Method 3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 4a R 4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0217] [Method 72] In Method 4, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 4a R 4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0218] [Method 73] In Method 5, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3For CR 6c B 4 For CR 6d R 4a R 4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0219] [Method 74] In Method 6, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 4a R 4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0220] [Method 75] In Method 7, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For CR 6d R 4a R4d R 6a R 6c and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0221] [Method 76] In Method 1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0222] [Method 77] In Method 2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6eC1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0223] [Method 78] In Method 3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0224] [Method 79] In Method 4, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6eC1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0225] [Method 80] In Method 5, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0226] [Method 81] In Method 6, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6eC1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0227] [Method 82] In Method 7, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0228] [Method 83] In Method 1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e A compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0229] [Method 84] In Method 2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e A compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0230] [Method 85] In Method 3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e A compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0231] [Method 86] In Method 4, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e A compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0232] [Method 87] In Method 5, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e A compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0233] [Method 88] In Method 6, Het is the group shown in Formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6eA compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0234] [Method 89] In Method 7, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For NR 5b W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 6a R 6b and R 6d For hydrogen atoms, R 6e A compound consisting of a C1-C6 chain hydrocarbon group substituted with one or more substituents selected from the group consisting of cyano and halogen atoms.

[0235] [Method 90] In Method 1, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0236] [Method 91] In Method 2, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0237] [Method 92] In Method 3, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0238] [Method 93] In Method 4, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0239] [Method 94] In Method 5, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0240] [Method 95] In Method 6, Het is the group shown in Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0241] [Method 96] In Method 7, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b Compounds containing hydrogen atoms.

[0242] [Method 97] In Method 1, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4bR 4d R 4e and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0243] [Method 98] In Method 2, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0244] [Method 99] In Method 3, Het is the group represented by Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b For hydrogen atoms, R 6eC1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0245] [Method 100] In Method 4, Het is the group shown in Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0246] [Method 101] In Method 5, Het is the group represented by formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0247] [Method 102] In Method 6, Het is the group shown in Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0248] [Method 103] In Method 7, Het is the group shown in Formula Het5, A 2 For CR 4a R 4d A 3 For CR 4b R 4e W 1 For oxygen atoms, B 1 For CR 6e B 2 For CR 6b B 3 For nitrogen atoms, R 4a R 4b R 4d R 4e and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0249] [Method 104] In any of Methods 1 to 103 or Compound N of the present invention, R 2a and R 2b The same or different from each other and being a C1-C6 alkyl group that can be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group that can be substituted with one or more halogen atoms, or a hydrogen atom, or R2a and R 2b Together with the nitrogen atoms they are bonded to, they form compounds of pyrrolidinyl or piperidinyl groups.

[0250] [Method 105] In any of Methods 1 to 103 or Compound N of the present invention, R 2a and R 2b The same or different from each other and being C1-C6 alkyl or hydrogen atoms that can be substituted by one or more halogen atoms, or, R 2a and R 2b Together with the nitrogen atoms they are bonded to, they form compounds of pyrrolidinyl or piperidinyl groups.

[0251] [Method 106] In any of Methods 1 to 103 or Compound N of the present invention, R 2a and R 2b Compounds that are the same as or different from each other and are C1-C6 alkyl groups that can be substituted with one or more halogen atoms.

[0252] [Method A1] In the compound N of the present invention, Q is a compound in which Q is a group represented by formula Q1.

[0253] [Method A2] In compound N of the present invention, Q is a group represented by formula Q1, and R 3a For hydrogen atoms, R 3b It can be a C1-C6 chain hydrocarbon group that can be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group that can be substituted with one or more halogen atoms, a phenyl group that can be substituted with one or more halogen atoms, a 5- or 6-membered aromatic heterocyclic group that can be substituted with one or more halogen atoms, or OR 12 , hydrogen atom or halogen atom, R 12 R is a C1-C6 chain hydrocarbon group that can be replaced by one or more halogen atoms. 3d Compounds containing hydrogen atoms.

[0254] [Method A3] In compound N of the present invention, Q is a group represented by formula Q1, and R 3a For hydrogen atoms, R 3b For hydrogen atoms, R 3d Compounds containing hydrogen atoms.

[0255] [Method A4] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0256] [Method A5] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 A combination of nitrogen atoms; B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 A combination of nitrogen atoms; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0257] [Method A6] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 6a and R 6c Compounds containing hydrogen atoms.

[0258] [Method A7] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0259] [Method A8] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0260] [Method A9] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3For CR 6e B 4 For nitrogen atoms, R 6a and R 6b Compounds containing hydrogen atoms.

[0261] [Method A10] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0262] [Method A11] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0263] [Method A12] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 6a R 6b and R 6d Compounds containing hydrogen atoms.

[0264] [Method A13] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 4c R 4f R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0265] [Method A14] In compound N of the present invention, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 4c R 4f R 6a R 6b and R 6d For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0266] [Scheme A15] In scheme A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0267] [Method A16] In Method A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 A combination of nitrogen atoms; B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 A combination of nitrogen atoms; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6dCompounds consisting of combinations of .

[0268] [Scheme A17] In scheme A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 6a and R 6c Compounds containing hydrogen atoms.

[0269] [Scheme A18] In scheme A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0270] [Scheme A19] In scheme A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0271] [Scheme A20] In scheme A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 6a and R 6b Compounds containing hydrogen atoms.

[0272] [Method A21] In Method A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0273] [Method A22] In Method A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0274] [Method A23] In Method A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 6a R 6b and R 6d Compounds containing hydrogen atoms.

[0275] [Method A24] In Method A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4For CR 6d R 4a R 4d R 4c R 4f R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0276] [Method A25] In Method A1, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 4c R 4f R 6a R 6b and R 6d For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0277] [Method A26] In Method A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0278] [Scheme A27] In scheme A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 A combination of nitrogen atoms; B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 A combination of nitrogen atoms; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0279] [Scheme A28] In scheme A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 6a and R 6c Compounds containing hydrogen atoms.

[0280] [Scheme A29] In scheme A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0281] [Scheme A30] In scheme A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0282] [Method A31] In Method A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 6a and R 6b Compounds containing hydrogen atoms.

[0283] [Method A32] In Method A2, Het is the group represented by formula Het7, A 2 For CR4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0284] [Method A33] In Method A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0285] [Method A34] In Method A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 6a R 6b and R 6d Compounds containing hydrogen atoms.

[0286] [Scheme A35] In scheme A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 4c R 4f R 6a R 6b and R 6d For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0287] [Method A36] In Method A2, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 4c R 4f R6a R 6b and R 6d For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0288] [Scheme A37] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 Compounds containing oxygen atoms.

[0289] [Scheme A38] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 B 2 B 3 and B 4 The combination is B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 A combination of nitrogen atoms; B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 A combination of nitrogen atoms; or B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d Compounds consisting of combinations of .

[0290] [Scheme A39] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 6a and R 6c Compounds containing hydrogen atoms.

[0291] [Scheme A40] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0292] [Method A41] In Method A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6e B 3 For CR 6c B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6c For hydrogen atoms, R 6eCompounds containing halogen atoms.

[0293] [Method A42] In Method A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 6a and R 6b Compounds containing hydrogen atoms.

[0294] [Scheme A43] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e C1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0295] [Scheme A44] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B2 For CR 6b B 3 For CR 6e B 4 For nitrogen atoms, R 4a R 4d R 4c R 4f R 6a and R 6b For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0296] [Scheme A45] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 6a R 6b and R 6d Compounds containing hydrogen atoms.

[0297] [Scheme A46] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 4c R 4f R 6a R 6b and R 6d For hydrogen atoms, R 6eC1-C6 chain hydrocarbon groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; C3-C4 cycloalkyl groups substituted with one or more substituents selected from the group consisting of cyano and halogen atoms; OR 7 Or compounds containing halogen atoms.

[0298] [Scheme A47] In scheme A3, Het is the group represented by formula Het7, A 2 For CR 4a R 4d A 4 For CR 4c R 4f W 1 For oxygen atoms, B 1 For CR 6a B 2 For CR 6b B 3 For CR 6e B 4 For CR 6d R 4a R 4d R 4c R 4f R 6a R 6b and R 6d For hydrogen atoms, R 6e Compounds containing halogen atoms.

[0299] [Method A48] In any of methods A1 to A47, R 2a and R 2b The same or different from each other and being a C1-C6 alkyl group that can be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group that can be substituted with one or more halogen atoms, or a hydrogen atom, or R 2a and R 2b Together with the nitrogen atoms they are bonded to, they form compounds of pyrrolidinyl or piperidinyl groups.

[0300] [Method A49] In any of methods A1 to A47, R 2a and R 2b The same or different from each other and being C1-C6 alkyl or hydrogen atoms that can be substituted by one or more halogen atoms, or, R 2a and R 2b Together with the nitrogen atoms they are bonded to, they form compounds of pyrrolidinyl or piperidinyl groups.

[0301] [Method A50] In any of methods A1 to A47, R 2a and R 2b Compounds that are the same as or different from each other and are C1-C6 alkyl groups that can be substituted with one or more halogen atoms.

[0302] Next, the method for manufacturing the compounds of the present invention (including compound N of the present invention) will be described.

[0303] Manufacturing Method 1

[0304] The compound shown in formula (I) (compound N of the present invention) can be produced by reacting the compound shown in formula (M-1) (hereinafter referred to as compound (M-1)) with the compound shown in formula (M-2) (hereinafter referred to as compound (M-2)).

[0305] [Chemical Formula 6]

[0306]

[0307] [In the formula, the symbols have the same meaning as in the preceding text.]

[0308] The reaction is usually carried out in a solvent. Examples of solvents include tetrahydrofuran (THF), 1,4-dioxane, 1,2-dimethoxyethane (DME), methyl tert-butyl ether (MTBE), diethyl ether, and other ethers; halogenated hydrocarbons such as dichloromethane and chloroform; aromatic hydrocarbons such as toluene and xylene; nitriles such as acetonitrile; water; and mixtures of two or more of these solvents.

[0309] In the reaction, compound (M-2) is usually used in a ratio of 0.8 to 10 moles relative to 1 mole of compound (M-1).

[0310] The reaction can be carried out by mixing compound (M-1) with compound (M-2). The reaction can also be carried out in the presence of a base, if desired. Examples of bases include alkali metal carbonates such as sodium carbonate and potassium carbonate (hereinafter referred to as alkali metal carbonates); tertiary amines such as triethylamine (hereinafter referred to as tertiary amines); and nitrogen-containing aromatic compounds such as pyridine (hereinafter referred to as nitrogen-containing aromatic compounds). When a base is used in the reaction, it is usually used in a ratio of 1 to 3 moles relative to 1 mole of compound (M-1).

[0311] The reaction temperature is typically in the range of -20 to 200°C. The reaction time is typically in the range of 0.1 to 24 hours.

[0312] After the reaction is complete, water can be injected into the reaction mixture, and then extraction can be performed using an organic solvent. Post-processing operations such as drying and concentrating the organic layer are then carried out to obtain compound N of the present invention.

[0313] Compound (M-2) is a commercially available compound or can be manufactured using known methods.

[0314] Manufacturing Method 2

[0315] The compound shown in formula (I) (compound N of the present invention) can be prepared by reacting the compound shown in formula (M-3) (hereinafter referred to as compound (M-3)) with the compound shown in formula (M-4) (hereinafter referred to as compound (M-4)) in the presence of a base.

[0316] [Chemical Formula 7]

[0317]

[0318] [In the formula, the symbols have the same meaning as in the preceding text.]

[0319] The reaction is usually carried out in a solvent. Examples of solvents include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents such as dimethylformamide (DMF), N-methylpyrrolidone (NMP), and dimethyl sulfoxide (DMSO); water and mixtures of two or more of them.

[0320] Examples of alkalis include alkali metal carbonates and alkali metal hydrides such as sodium hydride (hereinafter referred to as alkali metal hydrides).

[0321] In the reaction, compound (M-4) is usually used in a ratio of 0.8 to 1.2 moles relative to 1 mole of compound (M-3), and the base is usually used in a ratio of 1 to 3 moles.

[0322] The reaction temperature is typically in the range of -20 to 200°C. The reaction time is typically in the range of 0.5 to 24 hours.

[0323] After the reaction is complete, water can be injected into the reaction mixture, and then extraction can be performed using an organic solvent. Post-processing operations such as drying and concentrating the organic layer are then carried out to obtain compound N of the present invention.

[0324] Compound (M-3) is known or can be prepared according to methods described, for example, in Bioorganic & Medicinal Chemistry Letters 2016, 26, 3822-3825., Journal of Heterocyclic Chemistry 2003, 40, 677-679., Bioorg. Med. Chem. Lett. 2009, 19, 1773-1778., or Org. Process Res. Dev. 2021, 25, 858-870.

[0325] Manufacturing method 3

[0326] The compound shown in formula (I) (compound N of the present invention) can be prepared by reacting compound (M-3) with compound (M-5) (hereinafter referred to as compound (M-5)) in the presence of a metal catalyst.

[0327] [Chemical Formula 8]

[0328]

[0329] [In the formula, X] a This symbol represents a chlorine, bromine, or iodine atom; other symbols have the same meaning as described above.

[0330] The reaction is usually carried out in a solvent. Examples of solvents include ethers; aromatic hydrocarbons; nitriles; aprotic polar solvents; and mixtures of two or more of them.

[0331] Examples of metal catalysts include copper catalysts such as copper iodide (I), copper bromide (I), copper chloride (I), copper oxide (I), copper trifluoromethanesulfonate (I) benzene complex, copper tetraacetonitrile hexafluorophosphate (I), and copper 2-thiophenecarboxylate (I); nickel catalysts such as bis(cyclooctadiene)nickel (O) and nickel chloride (II); and palladium catalysts such as palladium acetate (II), tetra(triphenylphosphine)palladium (O), and tris(dibenzylideneacetone)dipalladium (II).

[0332] In the reaction, compound (M-5) is typically used at a ratio of 0.8 to 1.2 moles relative to 1 mole of compound (M-3), and the metal catalyst is typically used at a ratio of 0.01 to 0.5 moles.

[0333] In the reaction, ligands can be used as needed. Examples of ligands include triphenylphosphine, 4,5-bis(diphenylphosphino)-9,9-dimethylxanthocyanidin (hereinafter referred to as Xantphos), 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, 1,10-phenanthroline, trans-1,2-cyclohexanediamine, trans-N,N'-dimethylcyclohexane-1,2-diamine, and N,N'-dimethylethylenediamine. When ligands are used in a reaction, the ligand is typically used in a ratio of 0.01 to 0.5 moles relative to 1 mole of compound (M-1).

[0334] In the reaction, a base may be used as needed. Examples of bases include organic bases such as tertiary amines and nitrogen-containing aromatic compounds (hereinafter referred to as organic bases); alkali metal carbonates and alkali metal hydrides. When a base is used in the reaction, it is usually used in a ratio of 1 to 3 moles relative to 1 mole of compound (M-3).

[0335] The reaction temperature is typically in the range of -20℃ to 150℃. The reaction time is typically in the range of 0.5 to 24 hours.

[0336] After the reaction is complete, water can be added to the reaction mixture, and extraction can be performed using an organic solvent. Post-processing operations such as drying and concentrating the organic layer are then carried out to obtain compound N of the present invention.

[0337] Reference manufacturing method 1

[0338] Compound (M-1) can be prepared by reacting the compound shown in formula (M-7) (hereinafter referred to as compound (M-7)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0339] [Chemical Formula 9]

[0340]

[0341] [In the formula, the symbols have the same meaning as in the preceding text.]

[0342] The reaction can be carried out in a solvent as needed. Examples of solvents used in the reaction include ethers; aromatic hydrocarbons; aromatic hydrocarbons and mixtures of two or more of them.

[0343] Phosphoryl chloride and thionyl chloride are examples of chlorinating agents.

[0344] In the reaction, chlorosulfonic acid is usually used in a ratio of 1 to 10 moles relative to 1 mole of compound (M-7), and chlorinating agent is usually used in a ratio of 1 to 10 moles.

[0345] The reaction temperature is typically in the range of -20℃ to 200℃. The reaction time is typically in the range of 0.1 to 24 hours.

[0346] After the reaction is complete, water can be added to the reaction mixture, and extraction can be performed using an organic solvent. Post-processing operations such as drying and concentrating the organic layer are then carried out to obtain compound (M-1).

[0347] The compound (M-7) is known or can be manufactured according to methods described, for example, in International Publication No. 2020 / 203763.

[0348] Reference manufacturing method 2

[0349] The compound shown in formula (M-9) (hereinafter referred to as compound (M-9)) can be prepared by reacting the compound shown in formula (M-8) (hereinafter referred to as compound (M-8)) with a chlorinating agent in the presence of chlorosulfonic acid.

[0350] [Chemical Formula 10]

[0351]

[0352] [In the formula, the symbols have the same meaning as in the preceding text.]

[0353] The reaction can be carried out using compound (M-8) instead of compound (M-7) according to the method described in Reference Manufacturing Method 1.

[0354] Compound (M-8) is a commercially available compound or can be manufactured using known methods.

[0355] Reference manufacturing method 3

[0356] Compound (M-5) can be produced by reacting compound (M-9) with compound (M-2).

[0357] [Chemical Formula 11]

[0358]

[0359] [In the formula, the symbols have the same meaning as in the preceding text.]

[0360] The reaction can be carried out using compound (M-9) instead of compound (M-1) according to the method described in manufacturing method 1.

[0361] Reference manufacturing method 4

[0362] Compound (M-4) can be produced by reacting compound (M-5) with a fluorinating agent.

[0363] [Chemical Formula 12]

[0364]

[0365] [In the formula, the symbols have the same meaning as in the preceding text.]

[0366] The reaction is usually carried out in a solvent. Examples of solvents include aromatic hydrocarbons; aprotic polar solvents; and mixtures of two or more of them.

[0367] Examples of fluorinating agents include cesium fluoride and potassium fluoride.

[0368] In the reaction, the fluorinating agent is usually used in a ratio of 1 to 10 moles relative to 1 mole of compound (M-5).

[0369] The reaction temperature is typically in the range of 20℃ to 300℃. The reaction time is typically in the range of 0.1 to 24 hours.

[0370] After the reaction is complete, water can be added to the reaction mixture, and extraction can be performed using an organic solvent. Post-processing operations such as drying and concentrating the organic layer are then carried out to obtain compound (M-4).

[0371] The compounds of the present invention (including compound N of the present invention) may be used in combination or in combination with one or more components (hereinafter referred to as the component) selected from the group consisting of group (a), group (b), group (c) and group (d) below.

[0372] The aforementioned combination or use refers to using the compound of the present invention and the ingredient simultaneously, separately, or at intervals.

[0373] When the compound of the present invention and the ingredient are used simultaneously, the compound of the present invention and the ingredient may be contained in separate formulations or in the same formulation.

[0374] One aspect of the present invention is a composition comprising one or more components selected from groups (a), (b), (c) and (d) of the present invention (i.e., the component itself) and the compound of the present invention (hereinafter referred to as composition A).

[0375] Group (a) comprises acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABA-gated chloride channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride channel allosteric modulators (e.g., macrolide insecticides), juvenile hormones, multisite inhibitors, chordal organ TRPV channel modulators, mite growth inhibitors, and insect midgut membrane disruption derived from microorganisms. This group comprises insecticides, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncoupling agents, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin-based insecticides), chitin biosynthesis inhibitors, ecdysone inhibitors, ecdysone receptor agonists, octopamine receptor agonists, inhibitors of mitochondrial electron transport chain complexes I, II, III, and IV, voltage-dependent sodium channel blockers, acetyl-CoA carboxylase inhibitors, ranitidine receptor modulators (e.g., diamide-based insecticides), string organ modulators, microbial insecticides, and other insecticidal, acaricidal, and nematicidal active ingredients. These ingredients are described according to their IRAC-based mechanisms of action.

[0376] Group (b) comprises nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acyl amino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiration inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid and protein synthesis inhibitors (e.g., phenylaminopyridine fungicides), signal transduction inhibitors, lipid and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., DMI fungicides such as triazoles), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-point contact active fungicides, microbial fungicides, and other fungicidal active ingredients. These ingredients are described according to the classification based on FRAC-based mechanisms of action.

[0377] Group (c) is a group of plant growth regulators (including mycorrhizal fungi and rhizobia).

[0378] Group (d) is the group containing the repellent component.

[0379] The following describes examples of combinations of this ingredient with compounds of the present invention (including compound N of the present invention). For example, alanycarb + SX refers to the combination of alanycarb and SX.

[0380] It should be noted that the abbreviation SX refers to any one of the compounds of the present invention selected from compound groups SX1 to SX944 (including compound N of the present invention). Furthermore, all the ingredients described below are known ingredients and can be obtained from commercially available formulations or manufactured by known methods. In the case of microorganisms, these ingredients can also be obtained from microbial depositories. It should be noted that the numbers in parentheses represent CAS RN (registered trademark).

[0381] The combination of the component of group (a) above with the compounds of the present invention (including compound N of the present invention):

[0382] Abamectin + SX, acephate + SX, acequinocyl + SX, acetamiprid + SX, acetoprole + SX, acridine lactate + SX, acynonapyr + SX, afidopyropen + SX, afoxolaner + SX, alanycarb + SX, aldicarb + SX, allethrin + SX, alpha-cypermethrin + SX, alpha-endosulfan + SX, aluminum phosphide Phosphide + SX, Amitraz + SX, Azadirachtin + SX, Azamethiphos + SX, Azinphos-ethyl + SX, Azinphos-methyl + SX, Azocyclotin + SX, Bark of Celastrus Angulatus + SX, Bendiocorb + SX, Benfluthrin + SX, Benfuracarb + SX, Bensultap + SX, Benximate + SX, Benzpyrimoxan + SX, Beta-cyfluthrin + SX, Beta-cypermethrin + SX, Bifenazate + SX, Bifenthrin + SX, Bioallethrin + SX, Bioresmethrin + SX, Bistrifluron + SX, Borax + SX, Boric acid acid) + SX, broflanilide + SX, bromopropylate + SX, buprofezin + SX, butocarboxim + SX, butoxycarboxim + SX, cadusafos + SX, calcium phosphidePhosphide + SX, Carbaryl + SX, Carbofuran + SX, Carbosulfan + SX, Cartap hydrochloride Hydrochloride + SX, Cartap + SX, Chinomethionat + SX, Chlorantraniliprole + SX, Chlordane + SX, Chlorethoxyfos + SX, Chlorfenapyr + SX, Chlorfenvinphos + SX, Chlorfluazuron + SX, Chlormephos + SX, Chlorpicrin + SX, Chlorpyrifos + SX, Chlorpyrifos-methyl + SX, Chlorafenozide + SX, Clofentezine + SX, Clothianidin + SX, Concanavalin AA) + SX, coumaphos + SX, cryolite + SX, cyanophos + SX, cyantraniliprole + SX, cyclaniliprole + SX, cyclobutrifluram + SX, cycloprothrin + SX, cycloxaprid + SX, cyenopyrafen + SX, cyetpyrafen + SX, cyflumetofen + SX, cyfluthrin + SX, cyhalodiamide + SX, cyhalothrin + SX, cyhexatin + SX, cypermethrin + SX, cyphenothrin + SX, cyprofen flanilide + SX, cyromazine + SX, dazomet + SX, deltamethrin + SX, demeton-S-methyl + SX, diafenthiuron + SX, dizinon + SX, dichlorvos + SX, diloromezotiazine + SX, dicofol + SX, dicrotophos + SX, diflovidazin + SX, diflubenzuron + SX, dimefluthrin + SX, dimethoate + SX, dimethylvinphos + SX, dimpropyridaz + SX, dinotefuran + SX, disodium octaborate octaborate + SX, disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol + SX), doramectin + SX, dried leaves of Dryopterisfilix-mas)+SX, emamectin-benzoate+SX, empenthrin+SX, endosulfan+SX, EPN (O-ethyl O-(4-nitrophenyl)phenylphosphonothioate)+SX, epsilon-metofluthrin+SX, epsilon-momfluorothrin+SX, esfenvalerate+SX, ethiofencarb+SX, ethion+SX, etiprole+SX, ethoprophos+SX, etofenprox+SX, etoxazole+SX, extract of Artemisia absinthium+SX, neem extract Azadirachta indica + SX, Cassia nigricans extract + SX, Butterfly pea extract + SX, Symphytum officinale extract + SX, Chenopodium ambrosioides extract + SX, Tanacetum vulgare extract + SX, Urtica dioica extract + SX, Viscum album extract + SX, Famphur + SX, Fenamiphos + SX, Fenazaquin + SX, Fenbutatinoxide) + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, fenvalerate + SX, fipronil + SX, fometoquin + SX, flonicamid + SX, fluacrypyrim + SX, fluazaindolizine + SX, fluazuron + SX, flubendiamide + SX, fluchlordiniliprole + SX, flucycloxuron + SX, flucythrinate + SX Fluensulfone + SX, flufenoprox + SX, flufenoxuron + SX, flufiprole + SX, flumethrin + SX, flupentiofenox + SX, flupyradifurone + SX, flupyrimin + SX, flupyroxystrobin + SX, fluralaner + SX, fluvalinate + SX, fluxametamide + SX, formetanate + SX, fosthiazate + SX, furamethrin + SX, furathiocarb + SX, gamma-cyhalothrin + SX, GS-omega / kappa HXTX-Hv1a peptide (GS-omega / kappa HXTX-Hv1apeptide) + SX, halfenprox + SX, halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX, potassium salt of hop betaacid)+SX, hydramethylnon+SX, hydroprene+SX, imicafos+SX, imidacloprid+SX, imidaclothiz+SX, imiprothrin+SX, indazapyroxamet+SX, indoxacarb+SX, isocycloseram+SX, isofenphos+SX, isoprocarb+SX, O-(methoxyaminothiophosphoryl)salicylic acid isopropyl (isopropyl-O-(me Thoxyaminothiophosphoryl salicylate + SX, isoxathion + SX, ivermectin + SX, kadethrin + SX, kappa-tefluthrin + SX, kappa-bifenthrin + SX, kinoprene + SX, lambda-cyhalothrin + SX, ledprona + SX, lenoremycin + SX, lepimectin + SX, lime sulfur (lime) sulfur) + SX, Lotilana + SX, Lufenuron + SX, Machine Oil + SX, Malathion + SX, Mecarbam + SX, Meperfluthrin + SX, Metaflumizone + SX, Metam + SX, Methamidophos + SX, Methidathion + SX, Methiocarb + SX, Methomyl + SX, Methoprene + SX, Methoxychlor + SX, Methoxyfenozide + SX, Methyl bromide bromide + SX, metofluthrin + SX, metolcarb + SX, metoxadiazone + SX, mevinphos + SX, milbemectin + SX, milbemycinoxime)+SX, mivorilaner+SX, modoflaner+SX, momfluorothrin+SX, monocrotophos+SX, moxidectin+SX, naled+SX, nicofluprole+SX, nicotine+SX, nicotine-sulfate+SX, nitenpyram+SX, novaluron+SX, noviflumuron+SX, Chenopodium anthelminticum seed oil (oil of the seeds of Chenopodium) Anthelminticum + SX, Omethoate + SX, Oxamyl + SX, Oxazosulfyl + SX, Oxydemeton-methyl + SX, Parathion + SX, Parathion-methyl + SX, Permethrin + SX, Phenothrin + SX, Phenthoate + SX, Phorate + SX, Phosalone + SX, Phosm et)+SX, phosphamidon+SX, phosphine+SX, phoxim+SX, pirimicarb+SX, pirimiphos-methyl+SX, prallethrin+SX, profenofos+SX, profluthrin+SX, propargite+SX, propetamphos+SX, propoxur+SX, propylene glycol alginateglycolalginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, pyri... minostrobin + SX, pyriprole + SX, pyriproxyfen + SX, quinalphos + SX, resmethrin + SX, rotenone + SX, ryanodine + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate Borate + SX, Sodium Metaborate + SX, Spidoxamat + SX, Spinetoram + SX, Spinosad + SX, Spirobudifen + SX, Spirodiclofen + SX, Spiomesifen + SX, Spiropidion + SX, Spiotetramat + SX, Sulfiflumin + SX, Sulfuramid + SX, Sulfotep + SX, Sulfoxaflor + SX, Sulfur + SX, Sulfurylfluoride + SX, Tartar emetic)+SX, tau-fluvalinate+SX, tebufenozide+SX, tebufenpyrad+SX, tebupirimfos+SX, teflubenzuron+SX, tefluthrin+SX, temephos+SX, terbufos+SX, terpene components extracted from *Tetrandria thunbergii*The constituents of the extract of chenopodium ambrosioides (near ambrosioides) + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX, tetramethrin + SX, tetramethylfluthrin + SX, tetraliprole + SX, theta-cypermethrin + SX, thiacloprid + SX, thiamethoxam + SX, thiocyclam + SX, thiodicarb + SX, thiofanox + SX, thiometon + SX, thiosultap-disodium + SX, and thiosultap-disodium + SX. ultap-monosodium)+SX, tigolaner+SX, tiorantraniliprole+SX, tioxazafen+SX, tolfenpyrad+SX, tralomethrin+SX, transfluthrin+SX, triazamate+SX, triazophos+SX, trichlorfon+SX, trifluenfuronate+SX, triflumezopyrim+SX, triflumuron+SX, trimethacarb+SX, tyclopyrazoflor+SX, umifoxolaner+SX, vamidothion+SX, wood extract of the nanmu tree (wood) extract of Quassia amara) + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX, xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide (zinc)phosphide)+SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothiohexacyclobutane-3-yl)benzamide (1241050-20-3)+SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propionamide (1118626-57-5)+SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methyl 3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9)+SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazole-4-yl]-2-(methanesulfonyl)propionamide (2396747-83-2)+SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazolyl-5-yl]-N-ethyl-3-(methanesulfonyl)propionamide+SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazole-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09- 3) +SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) +SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidine-1-yl]phenyl}methyl)cyclopropanecarboxamide +SX, 7-fluoro-N-[1-(methylthioalkyl)-2-methylpropane-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide +SX, 7-fluoro-N-[1-(methanethionyl)-2-methylpropane-2-yl]-2 -(pyridin-3-yl)-2H-indazole-4-carboxamide +SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropane-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide +SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide +SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyridolo[2,3-b][1,4]oxazapyro-10-one (2607927-97-7) +SX, BT crop protein Cry1Ab (BT crop protein Cry1Ab) +SX, BT crop protein Cry1Ac (BT crop protein Cry1Ac) +SX, BT crop protein Cry1Fa (BT crop protein Cry1Fa)The following are a list of protein strains and their components: Cry1Fa (BT crop protein Cry1A.105), Cry2Ab (BT crop protein Cry2Ab), Vip3A (BT crop protein Vip3A), mCry3A (BT crop protein mCry3A), Cry3Ab (BT crop protein Cry3Ab), Cry3Bb (BT crop protein Cry3Bb), Cry34Ab1 / Cry35Ab1 (BT crop protein Cry34Ab1 / Cry35Ab1), Tea leafroller granulovirus strain BV-0001 (Adoxophyes orana GV (granulovirus) strain BV-0001), and Soybean noctuid moth nucleopolyhedrovirus (Anticarsia gemmatalis). MNPV (multiple nucleocapsid nucleopolyhedrovirus) + SX, Alfalfa Silver-striped Noctuid Moth Nucleopolyhedrovirus (Autographacalifornica MNPV) + SX, Codling Moth Granulovirus V15 (Cydia pomonella GV strain V15) + SX, Codling Moth Granulovirus V22 (Cydia pomonella GV strain V22) + SX, Apple Small Leaf Roller Granulovirus (Cryptophlebia leucotreta GV) + SX, Pine Caterpillar Cypovirus (Dendrolimus punctatus cypovirus) + SX, Cotton Bollworm Nucleopolyhedrovirus BV-0003 (Helicoverpa armigera NPV (nucleopolyhedrovirus) strain BV-0003) + SX, Corn Borer Nucleopolyhedrovirus (Helicoverpazea NPV+SX, Lymantria dispar NPV+SX, Mamestra brassicae NPV+SX, Mamestra configurata NPV+SX, Neodiprion abietis NPV+SX,The following are listed: NPV+SX, Neodiprion lecontei NPV+SX, Neodiprionsertifer NPV+SX, Nosema locustae NPV+SX, Orgyia pseudotsugata NPV+SX, Pieris rapae GV+SX, Plodia interpunctella GV+SX, Spodopteraexigua MNPV+SX, Spodoptera littoralis MNPV+SX, and Spodoptera litura NPV+SX. NPV)+SX, Arthrobotrysdactyloides+SX, Bacillus firmus strain GB-126+SX, Bacillus firmus strain I-1582+SX, Bacillus firmus strain NCIM2637+SX, Bacillus megaterium+SX, Bacillus sp. strain AQ175+SX, Bacillus sp. strain AQ177+SX, Bacillus sp. strain AQ178+SX, Bacillus sphaericus strain 2362 serotype H5a5b 2362serotypeH5a5b)+SX, Bacillus sphaericus strain ABTS1743+SX, Bacillus thuringiensis strain AQ52+SX, Bacillus thuringiensis strain BD#32+SX, Bacillus thuringiensis strain CR-371CR-371)+SX, Bacillus thuringiensis subsp. Aizawai strain ABTS-1857+SX, Bacillus thuringiensis subsp. Aizawai strain AM65-52+SX, Bacillus thuringiensis subsp. Aizawai strain GC-91+SX, Bacillus thuringiensis subsp. Aizawai strain NB200+SX, Bacillus thuringiensis subsp. Aizawai serotype H-7 (Bacillus thuringiensis subsp. Aizawai serotype strain) H-7)+SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351+SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123+SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306+SX, Bacillus thuringiensis subsp. Kurstaki strain EG2348+SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 EG7841)+SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19+SX, Bacillus thuringiensis subsp. Kurstaki strain F810+SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1The following strains of Bacillus thuringiensis were tested: strain HD-1+SX, strain PB54+SX, strain SA-11+SX, strain SA-12+SX, strain NB176+SX, strain MPPL002+SX, and strain Morrison+SX. The following strains of Bacillus thuringiensis are listed: subsp. *morrisoni* + SX, Bacillus thuringiensis var. *colmeri* + SX, Bacillus thuringiensis var. *darmstadiensis* strain 24-91 + SX, Bacillus thuringiensis var. *dendrolimus* + SX, Bacillus thuringiensis var. *galeriae* + SX, Bacillus thuringiensis var. *israelensis* strain BMP144 + SX, and Bacillus thuringiensis var. *israelensis* serotype strain H-14. H-14)+SX, Bacillus thuringiensis var. japonicus strain buibui+SX, Bacillus thuringiensis var. sandiego strain M-7M-7)+SX, Bacillus thuringiensis var. 7216+SX, Bacillus thuringiensis var. aegypti+SX, Bacillus thuringiensis var. T36+SX, Beauveria bassiana strain ANT-03+SX, Beauveria bassiana strain ATCC74040+SX, Beauveria bassiana strain GHA+SX, Beauveria brongniartii+SX, and the novel heat-inactivated bacterium A396 strain (Burkholderia rinojensis strain). A396)+SX, active purple bacteria PRAA4-1T strain (Chromobacterium subtsugae strain PRAA4-1T)+SX, Dactyllela ellipsospora+SX, Decylaria thaumasia+SX, Hirsutella minnesotensis+SX, Hirsutella rhossiliensis+SX, Hirsutella thompsonii+SX, Lagenidium giganteum+SX, Lecanicillium lecanii strain KV01+SX, conidia of strain DAOM198499 (Lecanicillium lecanii conidia of strain DAOM198499)+SX, conidia of strain DAOM216596 (Lecanicillium lecanii) The following strains were identified: DAOM216596+SX, Lecanicillium muscarium strain Ve6+SX, Metarhizium anisopliae strain F52+SX, Metarhizium anisopliae var. acridum+SX, and BIPESCO.The following strains of bacteria were tested: Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium flavoviride + SX, Monacrosporium phymatopagum + SX, Paecilomyces fumosoroseus Apopka strain 97 + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain T1 + SX, Paenibacillus popilliae + SX, Pasteuria nishizawaestrain Pn1 + SX, and Pasteuria penetrans + SX. usgae+SX, Pasteuria thornei+SX, Serratia entomophila+SX, Verticillium chlamydosporium+SX, Verticillium lecani strain NCIM1312+SX, Wolbachia pipientis+SX.

[0383] The combination of this component of group (b) above with the compounds of the present invention (including compound N of the present invention):

[0384] Acibenzolar-S-methyl + SX, Al dimorph + SX, Ametoctradin + SX, Aminopyrifen + SX, Amisulbrom + SX, Anilazine + SX, Aza conazole + SX, Azoxystrobin + SX, Basic copper sulfate + SX, Benalaxyl + SX, Benalaxyl M + SX, Benodanil + SX, Benomyl + SX, Benthiavalicarb + SX, Benthiavalicarb-isopropyl ester (opropyl) + SX, benzovindiflupyr + SX, binapacryl + SX, biphenyl + SX, bitertanol + SX, bixafen + SX, blasticidin-S + SX, Bordeaux mixture The following are listed: mixture + SX, boscalid + SX, bromothalonil + SX, bromuconazole + SX, bupirimate + SX, captafol + SX, captan + SX, carbendazim + SX, carboxin + SX, carpropamid + SX, chinomethionat + SX, chitin + SX, chloroinconazide + SX, chl oroneb + ​​SX, chlorothalonil + SX, chlozolinate + SX, colletochlorin B+SX, copper(II)acetate+SX, copper(II)hydroxide+SX, basic copper chloride+SX, copper(II)sulfate+SX, coumoxystrobin+SX, cyazofamid+SX, cyflufenamid+SXCymoxanil + SX, Cyproconazole + SX, Cyprodinil + SX, Dichlobentiazox + SX, Dichlofluanid + SX, Diclomemet + SX, Diclomezine + SX, Dicloran + SX, Dietofenad + SX, Difenoconazole + SX, Diflumetorim + SX, Dimethachlone + SX, Dimethirim ol + SX, Dimethomorph + SX, Dimoxystrobin + SX, Diniconazole + SX, Diniconazole-M + SX, Dinocap + SX, Dipotassium hydrogen phosphate Hydrogenphosphite + SX, Dipymetitrone + SX, Dithianon + SX, Dodecylbenzenesulphonic bis(ethylenediamine)copper(II)salt + SX, Dodemorph + SX, Dodine + SX, Edifenphos + SX, Enoxastrobin + SX, Epiconazole + SX, Etaconazole + SX, Ethaboxam + SX, Ethirimol + SX, Etridiazole + SX, Allium sativum extract + SX, Lupine cotyledon extract (“BLAD”) + SX, Horsetail extract arvense)+SX, Melaleuca alternifolia extract+SX, Reynoutria sachalinens extract+SX, Tropaeolum majus extract+SX,Famoxadone + SX, Fenamidone + SX, Fenaminstrobin + SX, Fenarimol + SX, Fenbuconazole + SX, Fenfuram + SX, Fenhexamid + SX, Fenoxanil + SX, Fenpiclonil + SX, Fenpicoxamid + SX, Fenpropidin + SX, Fenpropimorph + SX, Fenpyrazamine + SX, Fentin acetate + SX, Fentin chloride + SX, Fentin... Hydroxide + SX, Ferbam + SX, Ferimzone + SX, Florylpicoxamid + SX, Fluazinam + SX, Flubeneteram + SX, Fludioxonil + SX, Flufenoxa diazam + SX, Flufenoxystrobin + SX, Fluin dapyr + SX, Flumetylsulforim + SX, Flumorph + SX, Fluopicolide + SX, Fluopyram + SX, Fluopimomide + SX, Fluoxapiprolin + SX, Fluoxastrobin + SX, Fluoxytioconazol e)+SX, fluquinconazole+SX, flusilazole+SX, flusulfamide+SX, flutianil+SX, flutolanil+SX, flutriafol+SX, fluxapyroxa d+SX, folpet+SX, fosetyl+SX, fos etyl-aluminium+SX, furberidazole+SX, furalaxyl+SX, furamettapyr+SX,Guazatine + SX, hexaconazole + SX, hymexazole + SX, imazalil + SX, imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate + SX, inpyrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + SX, ip flufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX, isofetamid + SX, isoflucypram + SX, isoprethiolane + SX, isopyrazam + SX, isotiafil + SX, kasugamycin + SX, kresoxim-methyl + SX, laminarin + SX, leaves and bark of oak trees Quercus + SX, Mancozeb + SX, Mandestrobin + SX, Mandipropamid + SX, Maneb + ​​SX, Mefentrifluconazole + SX, Mepanipyrim + SX, Mepronil + SX, Me... ptyldinocap)+SX, metalaxyl+SX, metalaxyl-M+SX, metarylpicoxamid+SX, metconazole+SX, metasulfocarb+SX, metiram+SX, metominostrobin+SX, metrafenone+SX, metyltetraprole+SX, myclobutanil+SX, naftifine+SX, nuarimol+SX, octhilinone+SX, ofuronamide+SX, orysastrobin+SXOxadixyl + SX, oxathiapiprolin + SX, oxine-copper + SX, oxolinic acid + SX, oxpoconazole + SX, oxpoconazole fumarate + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiophanate-methyl + SX, phenamacril + SX, phosphorous acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin bin)+SX, piperalin+SX, polyoxins+SX, potassium hydrogencarbonate+SX, potassium dihydrogen phosphite+SX, probenazole+SX, prochloraz+SX, procymidone+SX, propamidine+SX, propamocarb+SX, propic The following are a list of aerobic fungicides: onazole + SX, propineb + ​​SX, proquinazid + SX, prothiocarb + SX, prothioconazole + SX, pydiflumetofen + SX, piraclostrobin + SX, pirametostrobin + SX, piraoxystrobin + SX, pirapropoyne + SX, piraziflumid + SX, pyrazophos + SX, pyribencarb + SX, pyrib uticarb + SX, pyridachlometyl + SX, pyrifenox + SX, and pyrimethanil + SX.Pyrimorph + SX, pyriofenone + SX, pyrisoxazole + SX, pyro quilon + SX, Quillaja extract + SX, quinconazole + SX, quinofumelin + SX, quinoxyfen + SX, quintozene + SX, saponins of Chenopodium quinoa + SX, seboctylamine + SX, sedaxane + SX, silthiofam + SX, simeconazole + SX, sodium hydrogencarbonate + SX, spirocycline oxamine + SX, streptomycin + SX, sulfur + SX, tebuconazole + SX, tebufloquin + SX, teclofthalam + SX, tetrachloronitrobenzene + SX, terbinafine + SX, tetraconazole + SX, thiabendazole + SX, thifluzamide + SX, thiophanate + SX, thiophanate-methyl + SX, thiram + SX, thymol + SX, tiadinil + SX, tol clofos-methyl + SX, tolfenpyrad + SX, tolp Rocarb + SX, Tolylfluanid + SX, Triadimefon + SX, Triadimenol + SX, Triazoxide + SX, Trilopyricarb + SX, Tricyclazole + SX, Triridemorph + SX, Trifloxystrobin + SX, Triflumizole + SX, Triforine + SX, Triticonazole + SX, Validamycin + SXValifenalate + SX, Vinclozolin + SX, Yellow Mustard Powder + SX, Zinc Thiazole + SX, Zineb + ​​SX, Ziram + SX, Zoxamide + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylformamidin (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylformamidin (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N -Ethyl-N-methylformamidinium (1052688-31-9)+SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylformamidinium (2055589-28-9)+SX, N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylformamidinium (2055756-21-1)+SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylformamidinium (2062599-39-5)+SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl] [5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylformamidin (1817828-69-5)+SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine (1362477-26-6)+SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazolin (1257056-97-5)+SX, (2Z)-3-amino-2-cyano-3- Ethyl phenyl acrylate (39491-78-6)+SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridine-2-amine (1446247-98-8)+SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4)+SX, (1R,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2)+SX,(1S,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-07-3)+SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6)+SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4)+SX, (1S, 2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5)+SX, 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-carboxylic acid methyl ester (1791398-02-1)+SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0)+SX, 1-(2,4- (difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8)+SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazol-5-carboxylon (2018316-13-5)+SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazol-5-carboxylon (2018317-25-2)+SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4- Triazol-1-yl)propane-2-ol (2082661-43-4)+SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propane-2-ol (2082660-27-1)+SX, ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8)+SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridin-3-carboxamide (1616239-21-4)+SX,2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9)+SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2)+SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl] 5-Chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methyl Pyrimidine (1605340-92-8)+SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9)+SX, N-(1-benzyl-3,3,3-trifluoro-1-methylpropyl)-8-fluoroquinoline-3-carboxamide (2132414-00-5)+SX, 4,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl) Isoxazoline-3-one (2098918-25-1) + SX, 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazoline-3-one (2098918-26-2) + SX, N-ethyl-2-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, N,2-dimethoxy-N-({4-[5,

[0385] -(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide +SX, N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropionamide +SX, N-methoxy-N'-methyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea +SX, N'-ethyl -N-methoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N,N'-dimethoxy-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea+SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoro... (Methyl)benzamide (2043675-28-9)+SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(4-bromo-7-fluoroindole-1-yl)but-2-yl ester+SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromo ... [-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(7-bromo-4-fluoroindole-1-yl)but-2-yl ester +SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine 3-(3,5-dichloropyridin-2-yl)but-2-yl ester +SX, N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alanine 3-(3,5-Dichloropyridin-2-yl)but-2-yl ester +SX, N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl ester ((1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate) +SX, N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl ester ((1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl ester ((1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alanine ninate)+SX、N-{[3-(acetyloxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alanine(1S)-1-[1-(naphthal-1-yl)cyclopropyl]ethyl ester((1S)-1-[1-(naphthalene n-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate)+SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)cyclopropionic acid +SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)acetamide +SX, N-allyl-N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionic acid +SX, N-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionic acid +SX, 3,3,3-trifluoro- N-({2-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, 3,3,3-trifluoro-N-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, 3,3,3-trifluoro-N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)propionamide + SX, N-({2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)butyramide + SX, N-methoxy-N-methyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N,N-Diethyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, N-Methyl-N'-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)urea + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidone-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidone-2-one + SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidone-2-one + SX, ]phenyl}methyl)piperidin-2-one+SX, 4-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)morpholin-3-one+SX, 2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxazolin-3-one+SX, 3,3-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)piperidin-2-one+SX, 2-({4,

[0386] -[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1,2-oxazinan-3-one+SX, 1-({3-fluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)azacycloheptane-2-one+SX, 4,4-dimethyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)pyrrolidine-2-one+SX, 5-methyl-1-({4-[5-(trifluoromethyl)- 1,2,4-Oxadiazol-3-yl]phenyl}methyl)pyrrolidone-2-one +SX, 1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxylic acid ethyl ester +SX, N-methyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)-1H-pyrazole-4-carboxamide +SX, N-propyl-1-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl] 4-(4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl)methyl)-1H-pyrazole-4-carboxamide +SX, N-methoxy-N-methyl-1-(4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl)methyl)-1H-pyrazole-4-carboxamide +SX, N,N-dimethyl-1-(4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl)methyl)-1H-pyrazole-4-carboxamide +SX, N,N-dimethyl-1-(4-[5-(trifluoromethyl)-1,2,4-oxadiazol) -3-yl]phenyl}methyl)-1H-1,2,4-triazol-3-amine +SX, N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide +SX, 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionate methyl ester +SX, 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionate ethyl ester +SX, 2

[0387] -[2-(trifluoromethyl)-4-(4-chlorophenoxy)phenyl]-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propionate methyl ester +SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline +SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline +SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide +SX, 1-[2-(1-chlorocyclopropyl)-3-(3- [Chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazol-5-carboxynitrile +SX, 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolane-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylic acid ethyl ester +SX, 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylic acid ethyl ester +SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide +SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-( [3,4-Dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide +SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide +SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazol-4-carboxamide +SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3,4]oct-1-yl)-5-methylthiazol-4-carboxamide +SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methyl 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide +SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide +SX, 2-[(2-methylpropionyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide +SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide +SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide +SX,2-{[(oxecyclobutane-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazol-4-carboxamide+SX, 2-{[(oxecyclopentane-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazol-4-carboxamide+SX, 2-{[(oxane-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazol-4-carboxamide+SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2- [Fluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + S X, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidin + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1 2,4-Oxadiazine + SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,(5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine+SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutanediol Alkyl-2-yl)-2-methylpropionamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutane-2-yl)-2,2-dimethylpropionamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propane-2-yl)-2-methylpropionamide + SX, N-((2S)-1-{ 3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propane-2-yl)-2-methylpropionamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propane-2-yl)-2-methylpropionamide + SX, ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamic acid Methyl carbamate + SX, ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazole-3-yl]-2-methylphenyl}methyl)carbamate + SX, ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazole-3-yl]-2-methylphenyl}methyl)carbamate + SX, (Z)-2-(5-cyclopentyl-2-methylphenoxy)-3-methoxy-2-acrylate methyl ester + SX, (Z)-2-(5-cyclohexyl-2-methylphenoxy)-3-methoxy-2-acrylate methyl ester + SX, (Z)-2-[(3-isopropyl-1H-pyrazole-1-yl)-2-methylphenoxy]-3-methoxy-2-acrylate methyl ester + SX,1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-di Methyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinoline-4(3H)-one + SX, (2Z)-3-methoxy-2-[(4-methyl[1,1'-biphenyl]-3-yl)oxy]-2-acrylate methyl ester + SX, Agrobacterium radioactivity K1026 strain (Agrobac The following strains were found to contain *Agrobacterium radiobactor strain K1026* + SX, *Agrobacterium radiobactor strain K84* + SX, *Bacillus amyloliquefaciens strain PTA-4838* (Aveo EZ Nematicide) + SX, *Bacillus amyloliquefaciens strain AT332* + SX, *Bacillus amyloliquefaciens strain B3* + SX, *Bacillus amyloliquefaciens strain D747* + SX, *Bacillus amyloliquefaciens strain DB101* + SX, and *Bacillus amyloliquefaciens strain DB102*. Bacillus amyloliquefaciens strain DB102+SX, Bacillus amyloliquefaciens strain GB03+SX, Bacillus amyloliquefaciens strain FZB24+SX, Bacillus amyloliquefaciens strain FZB42+SX, Bacillus amyloliquefaciens strain IN937a+SX,Bacillus amyloliquefaciens strain MBI600 + SX, Bacillus amyloliquefaciens strain QST713 + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens subsp. plantarum strain D747 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 SB3086)+SX, Bacillus pumilus strain AQ717+SX, Bacillus pumilus strain BUF-33+SX, Bacillus pumilus strain GB34+SX, Bacillus pumilus strain QST2808+SX, Bacillus simplex strain CGF2856+SX, Bacillus subtilis strain AQ153+SX, Bacillus subtilis strain AQ743+SX, Bacillus subtilis strain BU1814 BU1814)+SX, Bacillus subtilis strain D747+SX, Bacillus subtilis strain DB101+SX, Bacillus subtilis strain FZB24+SX,Bacillus subtilis strain GB03+SX, Bacillus subtilis strain HAI0404+SX, Bacillus subtilis strain IAB / BS03+SX, Bacillus subtilis strain MBI600+SX, Bacillus subtilis strain QST30002 / AQ30002+SX, Bacillus subtilis strain QST30004 / AQ30004+SX, Bacillus subtilis strain QST713+SX strains QST713+SX, Bacillus subtilis strain QST714+SX, Bacillus subtilis var. Amyloliquefaciens strain FZB24+SX, Bacillus subtilis strain Y1336+SX, Burkholderia cepacia+SX, Burkholderia cepacia type Wisconsin strain J82+SX, Burkholderia cepacia type Wisconsin strain M54+SX, Candidaoleophila strain O+SX, Candida hydrolytica strain O... saitoana)+SX, Chaetomium cupreum+SX, Clonostachys rosea+SX, Coniothyrium minitans strain CGMCC8325+SX, Coniothyrium minitans strain CON / M / 91-8+SX,Cryptococcus albidus + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Fusarium oxysporum strain Fo47 + SX, Gliocladium catenulatum strain J1446 + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Pantoea agglomerans strain E325 + SX, Phlebiopsis giganteastrain strain VRA1992 VRA1992)+SX, Pseudomonas aureofaciens strain TX-1+SX, Pseudomonas chlororaphis strain 63-28+SX, Pseudomonas chlororaphis strain AFS009+SX, Pseudomonas ch lororaphis strain MA342+SX, Pseudomonas fluorescens strain 1629RS+SX, Pseudomonas fluorescens strain A506+SX, Pseudomonas fluorescens strain CL145A CL145A)+SX, Pseudomonas fluorescens strain G7090+SX, Pseudomonas sp. strain CAB-02+SX, Pseudomonas syringae strain 742RS+SX,*Pseudomonas syringae* strain MA-4 + SX, *Pseudozyma flocculosa* strain PF-A22UL + SX, *Pseudomonas rhodesiae* strain HAI-0804 + SX, *Pythium oligandrum* strain DV74 + SX, *Pythium oligandrum* strain M1 + SX, *Streptomyces griseoviridis* strain K61 + SX, *Streptomyces lydicus* strain WYCD108US + SX, *Streptomyces lydicus* strain WYEC108 + SX. The following strains were tested: WYEC108+SX, Talaromyces flavus strain SAY-Y-94-01+SX, Talaromyces flavus strain V117b+SX, Trichoderma asperellum strain ICC012+SX, Trichoderma asperellum strain SKT-1+SX, Trichoderma asperellum strain T25+SX, Trichoderma asperellum strain T34+SX, Trichoderma asperellum strain TV1+SX, and Trichoderma atroviride strain CNCM 1-1237. 1-1237)+SX, Trichoderma atroviride strain LC52+SX, Trichoderma atroviri de strain IMI 206040+SX, Trichoderma atroviri strain SC1+SX,Trichoderma atroviride strain SKT-1+SX, Trichoderma atroviride strain T11+SX, Trichoderma ga msii strain ICC080+SX, Trichoderma harzianu mstrain 21+SX, Trichoderma harzianum strain DB104+SX, Trichoderma harzianum strain DSM 14944+SX, Trichoderma harzianum strain ESALQ-1303+SX, Trichoderma harzianum strain ESALQ-1306+SX The following strains were tested: ESALQ-1306+SX, Trichoderma harzianum strain IIHR-Th-2+SX, Trichoderma harzianum strain ITEM908+SX, Trichoderma harzianum strain kd+SX, Trichoderma harzianum strain MO1+SX, Trichoderma harzianum strain SF+SX, Trichoderma harzianum strain T22+SX, Trichoderma harzianum strain T39+SX, Trichoderma harzianum strain T78+SX, and Trichoderma harzianum strain TH35. TH35)+SX, Trichoderma polysporum strain IMI206039+SX, Trichoderma stromaticum+SX,Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 + SX, Trichoderma viride + SX, Variovora paradoxus strain CGF4526 + SX, Harpin protein + SX.

[0388] The combination of the component of group (c) above with the compounds of the present invention (including compound N of the present invention):

[0389] 1-Methylcyclopropene + SX, 1,3-diphenylurea + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) Acid + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, choline chloride chloride) + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, damidohydrazinenozide + SX, decan-1-ol + SX, dichlorprop + SX, dikegulac + SX, dimethipin + SX, diquat + SX, ethephon + SX, ethychlozate + SX, flumetralin + SX, flurprimidol + SX, forchlorfenuron + SX, formononetin + SX, gibberellin A + SX, gibberellin A3 + SX, inabenfide + SX, kinetin + SX, lipochitooligosaccharide SP104 + SX, maleic acid Hydrazide + SX, Mefluidide + SX, Mepiquat-chloride + SX, Oxidized glutathione + SX, Paclobutrazol + SX, Pendimethalin + SX, Prohexa dione-calcium + SX, Prohydrojasmon + SX, Pyr aflufen-ethyl + SX, Sintofen + SX, Sodium 1-naphthaleneacetate + SX, Sodium cyanate + SX, Thidiazuron + SX, Triapenthenol + SX, Tribufos s)+SX, trinexapac-ethyl+SX, uniconazole-P+SX, 2-(naphthalen-1-yl)acetamide+SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid+SX, methyl 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate+SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propane-1-ol+SX, Claroideoglomus etunicatum+SX, Claroideoglomus claroideum+SX, Funneliformis mosseae)+SX, Gigaspaora margarita+SX, Gigaspaora rosea+SX, Glomus aggregatum+SX, Glomus deserticola+SX, Glomu smonosporum+SX, Paraglomus brasillianum+SX, Rhizophagusclarus+SX, Rhizophagus intraradices RTI-801 strain+SX, Rhizophagus irre gularis DAOM 197198 strain+SX, Azorhizobium caulinodans+SX, Azospirillum amazonense+SX, Azospirillum brasiliensis * *Azospira brasilense* XOH strain + SX, *Azospira brasilense* Ab-V5 strain + SX, *Azospira brasilense* Ab-V6 strain + SX, *Azospira caulinodans* + SX, *Azospirillum halopraeferens* + SX, *Azospirillum irakense* + SX, *Azospirillum lipoferum* + SX, *Bradyrhizobium elka nii* SEMIA 587 strain + SX, *Bradyrhizobium elka nii* SEMIA 5019 strain + SX, *Bradyrhizobium japonicum* TA-11 strain + SX, *Bradyrhizobium japonicum* USDA 110 strain + SX, *Bradyrhizobium liaotiensis* The following bacteria were found to have the following rhizobia strains: * ...* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * **"""""""" " " (The text abruptly " ), which are likely related to the following bacteria strains, including * liaoningense (s * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *Rhizobium leguminosarum bv. Phaseoli + SX, Rhizobium leguminosarum bv. Trifolii + SX, Rhizobium leguminosarum bv. Viciae + SX, Rhizobium leguminosarum bv. Vifolii + SX, Rhizobium leguminosarum bv. Vifolii + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Zucchini Yellow Mosaik Virus weak strain + SX.

[0390] The combination of the component of group (d) above with the compounds of the present invention (including compound N of the present invention):

[0391] Anthraquinone + SX, DEET + SX, Icaridin + SX.

[0392] The ratio of the compound of the present invention (including compound N of the present invention) to the component is not particularly limited, and examples of weight ratios (compound of the present invention: component) of 1000:1 to 1:1000, 500:1 to 1:500, 100:1 to 1:100, 50:1, 20:1, 10:1, 9:1, 8:1, 7:1, 6:1, 5:1, 4:1, 3:1, 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:50, etc.

[0393] Compound N of the present invention, or any compound of the present invention, is effective against harmful arthropods such as harmful insects and mites, harmful nematodes, and harmful mollusks. Examples of harmful arthropods, harmful nematodes, and harmful mollusks include the following animals.

[0394] Hemiptera: Planthoppers such as *Laodelphax striatellus*, *Nilaparvatalugens*, *Sogatella furcifera*, *Peregrinus maidis*, *Javesella pellucida*, *Perkinsiella saccharicida*, *Tagosodesorizicolus*, and *Stenocranus pacificus* belong to the family Delphacidae; leafhoppers such as *Nephotettix cincticeps*, *Nephotettix virescens*, *Nephotettix nigropictus*, *Recilia dorsalis*, *Empoasca onukii*, *Empoasca fabae*, and *Dalbulus*. Leafhoppers include the family Cicadellidae (including maidis, Cofanaspectra, and Amrasca biguttula biguttula); leafhoppers include the family Aphrophoridae (including Philaenus spumarius); and leafhoppers include the family Cercopidae (including Mahanarvaposticata and Mahanarva fimbriolata).Beet aphid (Aphis fabae), soybean aphid (Aphis glycines), cotton aphid (Aphis gossypii), apple aphid (Aphis pomi), spiraecola aphid (Aphis spiraecola), peach aphid (Myzus persicae), plum aphid (Brachycaudus helichrysi), cabbage aphid (Brevicoryne brassicae), rose apple aphid (Dysaphis plantaginea), cabbage aphid (Lipaphis erysimi), potato aphid (Macrosiphum euphorbiae), eggplant aphid (Aulacorthum solani), lettuce aphid (Nasonovia ribisnigri), cereal aphid (Rhopalosiphumpadi), corn aphid (Rhopalosiphum maidis), orange aphid (Toxoptera citricida), peach aphid (Hyalopterus pruni), sorghum aphid (Melanaphis) The aphid family includes: *Sacchari*, *Tetraneuranigriabdominalis*, *Ceratovacuna lanigera*, *Eriosomalanigerum*, and *Sitobion avenae*; the root aphid family includes: *Daktulosphaira vitifoliae*, *Phylloxera devastatrix*, *Phylloxera notabilis*, and *Phylloxera russelae*; and the ball aphid family includes: *Adelges tsugae*, *Adelges piceae*, and *Aphrastasia pectinatae*.The species include the black rice bug (Scotinophara lurida), the Malayan black rice bug (Scotinophara coarctata), the black-bearded green rice bug (Nezara antennata), the northern two-spotted bug (Eysarcoris aeneus), the large-spined white-spotted bug (Eysarcoris lewisi), the broad-spotted two-spotted bug (Eysarcoris ventralis), the false two-spotted bug (Eysarcoris annamita), the tea-winged bug (Halyomorpha halys), the green rice bug (Nezara viridula), the brown bug (Euschistus heros), the red-banded bug (Piezodorus guildinii), the rice bug (Oebalus pugnax), the stink bug (Dichelops melacanthus), and the wall stink bug (Piezodorus hybneri), all belonging to the family Pentatomidae; the burrowing brown bug (Scaptocoris). Cydnidae (including *Castanea*); Alydidae (including *Riptortus clavatus*, *Leptocorisa chinensis*, and *Leptocorisa acuta*); Coreidae (including *Cletus punctiger* and *Leptoglossus australis*); Lygaeidae (including *Cavelerius saccharivorus*, *Togohemipterus*, and *Blissus leucopterus*); Trigonotylus caelestialium, Stenotus rubrovittatus, and Stenodema. Miridae (including the mirid bug *Calcarata* and *Lygus lineolaris*); Aleyrodidae (including the whitefly family *Trialeurodes vaporariorum*, *Bemisia tabaci*, *Dialeurodescitri*, *Aleurocanthus spiniferus*, *Aleurocanthus cameelliae*, and *Pealius euryae*).The species include scale insects of the family Diaspididae (such as *Abgrallaspis cyanophylli*, *Aonidiella aurantii*, *Diaspidiotus perniciosus*, *Pseudaulacaspis pentagona*, *Unaspis yanonensis*, and *Unaspis citri*); scale insects of the family Coccidae (such as *Ceroplastes rubens*); cottony cushion scales such as *Icerya purchasi* and *Icerya seychellarum*; and scale insects of the family Margarodidae (such as *Phenacoccus solani*, *Phenacoccus sonopsis*, and *Planococcus rubens*). The family Pseudococcidae includes species such as *Pseudococcus comstocki*, *Planococcus citri*, *Pseudococcus calceolariae*, *Pseudococcus longispinus*, and *Brevennia rehi*. The family Psyllidae includes species such as *Diaphorina citri*, *Trioza erytreae*, *Cacopsylla pyrisuga*, *Cacopsylla chinensis*, *Bactericera cockerelli*, and *Cacopsylla pyricola*. The family Psyllidae includes species such as *Corythucha ciliata* and *Corythucha ciliata*. The family Tingidae includes species such as *Marmorata*, *Stephanitis nashi*, and *Stephanitis pyrioides*; the family Cimicidae includes species such as *Cimex lectularius* and *Cimex hemipterus*; and the family Cicadidae includes species such as *Quesada gigas*.The Reduviidae family includes assassin bugs such as the harassing kissing bug (Triatoma infestans), the red-banded kissing bug (Triatoma rubrofasciata), the two-part kissing bug (Triatoma dimidiata), and the long red assassin bug (Rhodonius prolixus).

[0395] Lepidoptera: Rice stem borer (Chilo suppressalis), Taiwan rice stem borer (Chilo polychrysus), rice white stem borer (Scirpophaga innotata), rice stem borer (Scirpophaga incertulas), Rupela albina, rice leaf roller (Cnaphalocrocis medinalis), broad-striped leaf roller (Marasmia patnalis), rice leaf roller (Marasmia exigua), cotton leaf roller (Notarcha derogata), Asian corn borer (Ostrinia furnacalis), European corn borer (Ostrinia nubilalis), cabbage leaf borer (Hellula undalis), grape leaf cutter moth (Herpetogramma luctuosale), Kentucky bluegrass stem borer (Parapedia siateterrellus), rice three-spotted stem borer (Nymphula) Crombidae (grass moths such as depunctalis, sugarcane moth (Diatraea saccharalis), and eggplant yellow moth (Leucinodes orbonalis); Pyralidae (small corn moth (Elasmopalpus lignosellus), Indian grain moth (Plodia interpunctella), dark-skinned moth (Euzophera batangensis), and powdery moth (Cadra cautella);Spodoptera litura, Spodoptera exigua, Mythimna separata, Mamestrabrassicae, Sesamia inferens, Spodoptera mauritia, Naranga aenescens, Spodoptera frugiperda, Spodoptera exempta, Spodoptera cosmioides, Spodoptera eridania, Agrotis ipsilon, Agrotis segetum, Autographanigrisigna, Plusia festucae, Chrysodeixis includens, Trichoplusia spp., Heliothis Noctuidae include genus *Heliothis* (e.g., *Virescens*), genus *Helicoverpa* (e.g., *Helicoverpa armigera*), genus *Helicoverpa* (e.g., *Helicoverpa zea*), genus *Anticarsia gemmatalis*, genus *Alabamaargillacea*, and genus *Hydraecia immanis*; Pieridae include butterfly species such as cabbage white butterfly.The following moths belong to the family Tortricidae: pear fruit moth (Grapholita molesta), crabapple fruit moth (Grapholita dimorpha), soybean fruit moth (Leguminivora glycinivorella), soybean leafroller (Matsumuraeses azukivora), apple leafroller (Adoxophyesorana fasciata), tea leafroller (Adoxophyes honmai), tea long leafroller (Homona magnanima), apple yellow leafroller (Archipsfuscocupreanus), apple small leafroller (Cydia pomonella), yellow rice borer (Tetramoera schistaceana), bean shooter (Epinotia aporema), citrus fruit fly (Citripestissagittiferella), grape flower leafroller (Lobesia botrana); tea leafroller (Caloptilia theivora), golden leafroller (Phyllonorycter). Gracillariidae (e.g., *Ringoniella*); Carposinidae (e.g., *Carposina sasakii*); Lyonetiidae (e.g., *Leucoptera coffeella*, *Lyonetia clerkella*, *Lyonetia prunifoliella*); Lymantriidae (e.g., *Lymantria dispar*, *Euproctis pseudoconspersa*); Plutellidae (e.g., *Plutella xylostella*); Anarsialineatella, Helcystogramma triannulella, Pectinophoragossypiella, Phthorimaea The family Gelechiidae includes species such as the American white moth (Hyphantria cunea); the family Arctiidae includes species such as the sugarcane borer (Telchin licus); and the family Castniidae includes species such as the tomato moth (Tutaabsoluta).The following are species of moths: Cossidae (aromatic wood-boring moth), Geometridae (large bridge-building moth), Limacodidae (blue-lipped tussock moth), Stathmopodidae (persimmon tussock moth), Sphingidae (ghost hawk moth), Sesiidae (clearwing moth), Hesperiidae (rice skipper), and Tineidae (clothes moth).

[0396] Thysanoptera: Thripidae (Frankliniella occidentalis), palm thistle (Thrips palmi), yellow thrips (Scirtothrips dorsalis), tobacco thrips (Thrips tabaci), flower thrips (Frankliniella intonsa), rice thrips (Stenchaetothrips biformis), American thorny thrips (Echinothrips americanus), avocado thrips (Scirtothrips perseae), etc.; Phlaeothripidae (Haplothrips aculeatus), etc.

[0397] Diptera: Anthomyiidae (including species such as *Delia platura*, *Delia antiqua*, and *Pegomya cunicularia*); Ulidiidae (including species such as *Tetanopsmyopaeformis*); Agromyzidae (including species such as *Agromyza oryzae*, *Liriomyza sativae*, *Liriomyza trifolii*, and *Chromatomyia horticola*); Chloropidae (including species such as *Chlorops oryzae*); Bactrocera cucurbitae (including species such as *Bactrocera dorsalis*, *Bactrocera latifrons*, and *Bactrocera cucurbitae*). Fruit flies include: *Bactroceratryoni*, *Ceratitis capitata*, *Rhagoletis pomonella*, and *Rhacochlaena japonica* (all belonging to the family Tephritidae); rice leaf miners (*Hydrelliagriseola*), *Hydrellia philippina*, and *Hydrellia sasakii* (all belonging to the family Ephydridae); fruit flies including *Drosophila suzukii* and *Drosophila melanogaster* (all belonging to the family Drosophilidae); flea flies including *Megaselia spiracularis* (all belonging to the family Phoridae); midges including *Clogmia albipunctata* (all belonging to the family Psychodidae); and mushroom midges including *Bradysia*. Sciaridae, including *Difformis* and *Bradysia odoriphaga*; Cecidomyiidae, including *Mayetiola destructor* and *Orseolia oryzae*; and Diopsidae, including *Diopsis macrophthalma*.The following species are included: Glossinidae (flies such as *Glossina palpalis* and *Glossina morsitans*); Simuliidae (flying midges such as *Simulium japonicum* and *Simulium damnosum*); Phlebotominae (sandflies); Tipula aino (gross mosquitoes such as *Tipula oleracea* and *Tipulapaludosa*); Culex pipiens pallens (light-colored mosquitoes), Culex tritaeniorhynchus (three-banded beaked mosquitoes), Culex pipiens f. molestus (subterranean mosquitoes), Culex quinquefasciatus (mosquitoes with poor fasciatus), Culex pipiens pipiens (sharp-sounding mosquitoes), Culex vishnui (white-snout mosquitoes), Aedes albopictus (white-striped mosquitoes), and Aedes aegypti (mosquitoes with poor fasciatus). Anopheles species include: *Anopheles aegypti*, *Anopheles sinensis*, *Anopheles gambiae*, *Anopheles stephensi*, *Anopheles coluzzii*, *Anopheles albimanus*, *Anopheles saintii*, *Anopheles arabiensis*, *Anopheles funestus*, *Anopheles darlingi*, *Anopheles farauti*, and *Anopheles minimus*, belonging to the Culicidae family; *Prosimulium yezoensis* and *Simulium ornatum*, belonging to the Simulidae family; *Tabanus trigonus*, belonging to the Tabanidae family; and houseflies (*Muscadomestica*) and stable flies (*Muscina*). Muscidae (flies such as *Stomoxys calcitrans*, *Haematobia irritans*); Calliphoridae (bright flies); Sarcophagidae (flies);Chironomidae (including species such as *Chironomus plumosus*, *Chironomus yoshimatsui*, and *Glyptotendipes tokunagai*); Fannidae (including species such as *Glyptotendipes*).

[0398] Coleoptera: Genus *Diabrotica* (e.g., *Diabrotica virgifera virgifera*, *Diabrotica undecimpunctatahowardi*, *Diabrotica barberi*, *Diabrotica virgiferazeae*, *Diabrotica balteata*, *Cucurbit Beetle* (*Diabrotica speciosa*), etc.), Bean leaf beetle (*Cerotoma trifurcata*), Grain leaf beetle (*Oulemamelanopus*), Cucumber beetle (*Aulacophora femoralis*), Yellow striped flea beetle (*Phyllotreta striolata*), Cabbage flea beetle (*Phyllotreta cruciferae*), Western black flea beetle (*Phyllotreta pusilla*), Rapeseed flea beetle (*Psylliodes*). Chrysomelidae (leaf beetle), Psylliodes punctulata, Leptinotarsa ​​decemlineata, Oulema oryzae, Colaspis brunnea, Chaetocnema pulicaria, Chaetocnema confinis, Epitrix cucumeris, Dicladispa armigera, Myochrous denticollis, Laccoptera quadrimaculata, Epitrix hirtipennis, Phaeton brassicae, Medythianigrobilineata, etc.; Seedcorn beetle (Stenolophus) Carabidae family, including species such as *Lecontei* and *Clivina impressifrons*.The following species belong to the Scarabaeidae family: *Anomala cuprea*, *Anomala rufocuprea*, *Anomala albopilosa*, *Popillia japonica*, *Heptophyllapicea*, *Rhizotrogus majalis*, *Tomarus gibbosus*, *Holotrichia spp.*, *Phyllophaga crinita*, and other species in the *Phyllophaga* genus; *Diloboderus abderus* and other species in the *Diloboderus* genus; *Arenacerus coffeae* and other species in the Anthriibidae family; *Cylasus spp.* (sweet potato weevil). Aponidae family, including *Zabrotes subfasciatus*; Bruchidae family, including *Zabrotes subfasciatus*; Scolytidae family, including *Tomicus piniperda* and *Hypothenemus hampei*; West Indian sweet potato weevil (Euscepespostfasciatus), alfalfa leaf weevil (Hypera postica), maize weevil (Sitophilus zeamais), rice weevil (Sitophilus oryzae), grain weevil (Sitophilus granarius), rice weevil (Echinocnemus squameus), rice water weevil (Lissorhoptrus oryzophilus), palm weevil (Rhabdoscelus lineaticollis), cotton boll weevil (Anthonomus grandis), parasitic grain weevil (Sphenophorus venatus), and southern maize long-beaked weevil (Sphenophorus). The family Curculionidae includes species such as callosus, soybean stem weevil (Sternechus subsignatus), sugarcane weevil (Sphenophorus levis), rust weevil (Scepticus griseus), scepticus uniformis, Aracanthus mourei, and others.Tenebrionidae (including the red flour beetle *Tribolium castaneum*, the mixed flour beetle *Tribolium confusum*, and the black fungus beetle *Alphitobius diaperinus*); Coccinellidae (including the eggplant ladybug *Epilachna vigintioctopunctata*); Bostrychidae (including the brown powder beetle *Lyctus brunneus* and the grain beetle *Rhizopertha dominica*); Ptinidae (spider beetles); Cerambycidae (longhorn beetles including the star longhorn beetle *Anoplophora malasiaca*, *Migdolus fryanus*, and the peach-necked longhorn beetle *Aromiabungii*); Melanotus okinawensis (click beetle), Agriotes fuscicollis (click beetle), and Melanotus (click beetle). Click beetles (Elateridae), including genera such as *Leetus*, *Anchastus* spp., *Conoderus* spp., *Ctenicera* spp., *Limonius* spp., and *Aeolus* spp.; Paederus fuscipes and other rove beetles (Staphylinidae); Dermestidae (Dermestidae), including small round-necked beetles (*Anthrenus verbasci*), white-bellied dermestles (*Dermestes maculates*), and grazing beetles (*Trogoderma granarium*); Anobiidae (Anobiidae), including tobacco beetles (*Lasioderma serricorne*) and medicinal beetles (*Stegobium paniceum*); and Cryptolestes. Species such as *Laemophloeidae* (e.g., *ferrugineus*); *Silvanidae* (e.g., *Oryzaephilus surinamensis*); and *Nitidulidae* (e.g., *Brassicogethesaeneus*).

[0399] Orthoptera: Migratory locust (Locusta migratoria), Moroccan locust (Dociostaurus maroccanus), Australian locust (Chortoicetes terminifera), Red-winged locust (Nomadacrisseptemfasciata), Brown locust (Locustana pardalina), Tree locust (Anacridium melanorhodon), Italian locust (Calliptamus italicus), Long-fronted grasshopper (Melanoplus differentialis), Two-banded grasshopper (Melanoplus bivittatus), Migratory grasshopper (Melanoplus sanguinipes), Red-legged grasshopper (Melanoplus femurrubrum), Clearwing locust (Camnula pellucida), Desert locust (Schistocerca gregaria), Yellow-winged locust (Gastrimargus musicus), Spur-throated locust (Austracris guttulosa), Small-winged rice locust (Oxya The family Acrididae includes species such as *Yezoensis*, *Oxya japonica*, and *Patanga succincta*; the family Gryllotalpidae includes species such as *Gryllotalpa orientalis*; the family Gryllidae includes species such as *Acheta domestica* and *Teleogryllus emma*; and the family Tettigoniidae includes species such as *Anabrus simplex*.

[0400] Hymenoptera: Tenthredinidae (leaf bee family), including species such as *Athalia rosae* and *Athalia japonica*; genera such as *Solenopsis* (fire ant genus), including *Solenopsis invicta* and *Solenopsis geminata*; genera such as *Atta* (brown leaf-cutting ant), including *Acromyrmex* (leaf-cutting ant genus); *Paraponera clavata* (bullet ant); *Ochetellus glaber* (hairless stink ant); *Monomoriumpharaonis* (small yellow house ant); *Linepithema humile* (Argentine ant); *Formica japonica* (Japanese black brown ant); *Pristomyrmex punctutus* (striated leaf-cutting ant); *Pheidole* (broad-knotted big-headed ant). Formic ants (Camponotus spp.), including *Camponotus noda*, *Pheidolemegacephala*, *Camponotus japonicus*, and *Camponotus obscuripes*; ants (Pogonomyrmex spp.), including *Pogonomyrmex occidentalis*; fire ants (Wasmania spp.), including *Wasmania auropunctata*; yellow ants (Anoplolepis gracilipes); wasps (Vespidae), including *Vespa mandarinia*, *Vespa simillima*, *Vespa analis*, *Vespa velutina*, and domestic wasps (Polistes jokahamae); tree wasps (Urocerus). Families such as *Gigas* (Siricidae) and *Bethylidae* (Byrhynchidae).

[0401] Blattodea: Includes species such as the German cockroach (Blattella germanica) and the family Ectobiidae; species such as the American cockroach (Periplaneta fuliginosa), American cockroach (Periplaneta americana), Australian cockroach (Periplaneta australasiae), brown-spotted cockroach (Periplaneta brunnea), and oriental cockroach (Blattaorientalis); species such as the northern subterranean termite (Reticulitermes speratus), the Formosan subterranean termite (Coptotermes formosanus), the small jacaranda termite (Incisitermes minor), the domesticated termite (Cryptotermes domesticus), the black-winged subterranean termite (Odontotermes formosanus), the Neotermite koshunensis, and the Glyptotermes. The termite family (Termitidae) includes termites such as *Glyptotermes nakajimai*, *Glyptotermes fuscus*, *Hodotermopsis sjostedti*, *Coptotermes guangzhouensis*, *Reticulitermes amamianus*, *Reticulitermes miyatakei*, *Reticulitermes kanmonensis*, *Nasutitermes takasagoensis*, *Pericapritermes nitobei*, *Sinocapritermes mushae*, and *Cornitermes cumulans*.

[0402] Siphonaptera: Human flea (Pulex irritans), cat flea (Ctenocephalides felis), dog comb flea (Ctenocephalides canis), rat flea (Xenopsylla cheopis), bird crest flea (Echidnophaga gallinacea)) and other flea families (Pulicidae); skin-penetrating flea (Tunga penetrans) and other sand flea families (Hectopsyllidae); European mouse flea (Nosopsyllus fasciatus) and other hornlea flea families (Ceratophyllidae).

[0403] Order Psocodae: Human head louse (Pediculus humanus capitis) and other louse families (Pediculidae); pubic louse (Pthirus pubis) and other pubic louse families (Pthiridae); blood louse family (Haematopinidae) such as bovine blood louse (Haematopinuseurysternus) and swine blood louse (Haematopinus suis); calves' gnats (Linognathus vituli), sheep's gnats (Linognathus ovillus), buffalo blind louse (Solenopotescapillatus) and other gnats (Linognathidae); cattle louse family (Bovicoliidae) such as bovine hairy louse (Bovicola bovis), sheep louse (Bovicolaovis), Bovicola breviceps, Damalinia forficula, and Werneckiella spp.); dog-biting louse (Trichodectes) The following are family names for various lice families: Trichodectidae (including *F. canis* and *Felicola subrostratus*); Menoponidae (including *Menopon gallinae*, *Menacanthus stramineus*, and *Trinoton spp.*); Trimenoponidae (including *Cummingsia spp.*); Trogiidae (including *Trogium pulsatorium*); and Liposcelidae (or Liposcelididae) (including *Liposcelis corrodens*, *Liposcelis bostrychophila*, *Liposcelis pearmani*, and *Liposcelisentomophila*).

[0404] Thysanura: Lepismatidae such as Ctenolepisma villosa and Lepismasaccharina.

[0405] Order Acari: Tetranychus urticae, Tetranychus kanzawai, Tetranychus evansi, Panonychus citri, Panonychus ulmi, Oligochus spp., etc., family Tetranychidae; Aculops pelekassi, Phyllocoptruta citri, Aculops lycopersici, Calacarus carinatus, Acaphylla theavagrans, Eriophyes chibaensis, Aculus schlechtendali, Aceria The family Eriophyidae includes mites such as *Diospyri*, *Aceria tosichella*, and *Shevtchenkella* sp.; the family Tarsonemidae includes mites such as *Polyphagotarsonemus latus*; the family Tenuipalpidae includes mites such as *Brevipalpus phoenicis*; and the family Tuckerellidae.Haemaphysalis longicornis, Haemaphysalis flava, Haemaphysalis japonica, Haemaphysalis campanulata, Dermacentor variabilis, Dermacentor taiwanensis, Dermacentor andersoni, Dermacentor reticulatus, Ixodes ovatus, Ixodes persulcatus, Ixodes scapularis, Ixodes pacificus, Ixodes holocyclus, Ixodes ricinus, Amblyomma americanum, Amblyomma maculatum, Rhipicephalus Microplus, including the ringed tick (Rhipicephalus annulatus), blood-red tick (Rhipicephalus sanguineus), tailed tick (Rhipicephalus appendiculatus), and decolorized tick (Rhipicephalus decoloratus), belonging to the family Ixodidae; Argas persicus, Ornithodoros hermsi, and Ornithodorosturicata, belonging to the family Argasidae; Tyrophagus putrescentiae and Tyrophagus similis, belonging to the family Acaridae; Dermatophagoides farinae and Dermatophagoides pteronyssinus, belonging to the family Pyroglyphidae; and Cheyletus eruditus and Cheyletus malathion, belonging to the family Cheyletus eruditus. Carnivorous mites include the family Cheyletidae, such as *Chelacaropsis moorei* and *Cheyletiella yasguri*.The following are species of mites: sheep itch mite (Psoroptes ovis), horse itch mite (Psoroptes equi), mutant knee mite (Knemidocoptes muans), ear mite (Otodectes cynotis), and skin mite (Chorioptes spp.), belonging to the family Psoroptidae; cat ear mite (Notoedres cati), cat anal mite (Notoedres muris), and human scabies mite (Sarcoptes scabiei), belonging to the family Sarcoptesidae; rabbit tadpole mite (Listrophorus gibbus), belonging to the family Listrophoridae; chicken tussock mite (Dermanyssus gallinae), belonging to the family Dermanyssidae; forest avian tussock mite (Ornithonyssus sylviarum), avian tussock mite (Ornithonyssus bacoti), belonging to the family Macronyssidae; and Varroa mite (Varroa...). Varoidae (e.g., *Jacobsoni*); Demodicidae (e.g., *Demodex canis*, *Demodex cati*); Trombulidae (e.g., *Leptotrombidium akamushi*, *Leptotrombidium pallidum*, *Leptotrombidium scutellare*).

[0406] Araneae: Eutichuridae (red-clawed spiders such as Cheiracanthium japonicum); Theridiidae (ball spiders such as Latrodectus hasseltii).

[0407] The order Polydesmida includes species such as Oxidus gracilis and Nedyopus tambanus, belonging to the family Paradoxosomatidae.

[0408] Isopoda: Armadillidium vulgare and Armadillidiidae.

[0409] Chilopoda: Scutigeridae (e.g., Thereuonema hilgendorfi); Scolopendridae (e.g., Scolopendra subspinipes); Ethopolyidae (e.g., Bothropolys rugosus).

[0410] Gastropoda: Limacidae (including Limax marginatus and Limaxflavus); Philomycidae (including Meghimatium bilineatum); Ampullariidae (including Pomacea canaliculata); Lymnaeidae (including Austropeplea ollula).

[0411] Nematodes: Rice stem nematode (Aphelenchoides besseyi) and other species in the family Aphelenchoididae; coffee nematode (Pratylenchus coffeae), piercing nematode (Pratylenchus brachyurus), neglected nematode (Pratylenchus neglectus), banana nematode (Radopholus similis) and other species in the family Pratylenchidae; Javan root-knot nematode (Meloidogyne javanica), southern root-knot nematode (Meloidogyne incognita), guava root-knot nematode (Meloidogyne enterolobii), northern root-knot nematode (Meloidogyne hapla), soybean cyst nematode (Heterodera glycines), potato golden nematode (Globodera). The family includes Heteroderidae (such as *Rostochiensis*, *Globodera pallida*, and *Meloidogyne chitwoodi*); Hoplolaimidae (such as *Rotylenchulus reniformis*); Anguinidae (such as *Nothotylenchus acris* and *Ditylenchus dipsaci*); Tylenchulidae (such as *Tylenchulus semipenetrans*); Longidoridae (such as *Xiphinema index*); Trichodoridae; and Parasitaphelenchidae (such as *Bursaphelenchus xylophilus*).

[0412] Harmful insects, harmful mites and other harmful arthropods, harmful mollusks and harmful nematodes can also refer to harmful insects, harmful mites and other harmful arthropods, harmful mollusks and harmful nematodes whose sensitivity to pesticides, acaricides, molluscicides or nematicides has decreased or who have strong resistance to pesticides.

[0413] As a method for controlling harmful arthropods according to the present invention, it can be implemented by directly applying an effective amount of the compound or composition A of the present invention to the harmful arthropods, and / or applying it to the habitats of the harmful arthropods (plants, soil, houses, animals, etc.). Examples of methods for controlling harmful arthropods according to the present invention include foliar treatment, soil treatment, root treatment, spraying treatment, fumigation treatment, water surface treatment, and seed treatment.

[0414] For the compound or composition A of this invention, it is typically mixed with non-active carriers such as solid carriers, liquid carriers, and gaseous carriers, and surfactants, and formulation adjuvants such as binders, dispersants, and stabilizers are added as needed to formulate it into aqueous suspensions, oil suspensions, oils, emulsions, microemulsions, microcapsules, wettable powders, water-dispersible granules, powders, granules, tablets, aerosols, resin formulations, etc. It is not limited to these formulations and can be formulated into the formulations described in the Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271~276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN:0259-2517.

[0415] These formulations typically contain 0.0001 to 99% of the compound or composition A of the present invention by weight.

[0416] Examples of solid carriers include clay (pyrophyllite clay, kaolin clay, etc.), talc, calcium carbonate, diatomite, zeolite, bentonite, acid clay, palygorskite, silica, ammonium sulfate, vermiculite, perlite, pumice, silica sand, chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.) in powder and granular form, as well as resins (polyethylene, polypropylene, polyester, polyurethane, polyamide, polyvinyl chloride, etc.).

[0417] Examples of liquid carriers include water, alcohols (ethanol, cyclohexanol, benzyl alcohol, propylene glycol, polyethylene glycol, etc.), ketones (acetone, cyclohexanone, etc.), aromatic hydrocarbons (xylene, phenylxyl ethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, etc.), esters (ethyl acetate, methyl oleate, propylene carbonate, etc.), nitriles (acetonitrile, etc.), ethers (ethylene glycol dimethyl ether, etc.), amides (N,N-dimethylformamide, N,N-dimethyloctylamide, etc.), sulfoxides (dimethyl sulfoxide, etc.), lactams (N-methylpyrrolidone, N-octylpyrrolidone, etc.), fatty acids (oleic acid, etc.), and vegetable oils (soybean oil, etc.).

[0418] Examples of gaseous carriers include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide.

[0419] Examples of surfactants include nonionic surfactants (polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, polyethylene glycol fatty acid esters, etc.) and anionic surfactants (alkyl sulfonates, alkyl aryl sulfonates, alkyl sulfates, etc.).

[0420] Examples of adjuvants used in other formulations include binders, dispersants, colorants, and stabilizers. Specific examples include polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, etc.), isopropyl phosphate, and butylated hydroxytoluene.

[0421] In addition, adjuvants may be used as components to enhance or assist the efficacy of the compounds of the present invention. Specifically, examples include Nimbus (registered trademark), Assist (registered trademark), Aureo (registered trademark), Iharol (registered trademark), Silwet L-77 (registered trademark), BreakThru (registered trademark), SundanceII (registered trademark), Induce (registered trademark), Penetrator (registered trademark), AgriDex (registered trademark), Lutensol A8 (registered trademark), NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITON X 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark), ARPON (registered trademark), EnSpray N (registered trademark), and BANOLE (registered trademark).

[0422] In this invention, the plant can be categorized as the whole plant, stem and leaves, flower, spike, fruit, trunk, branch, crown, seed, vegetative reproductive organs, and seedling.

[0423] Vegetative reproductive organs refer to the parts of a plant, such as roots, stems, and leaves, that have the ability to grow when separated from the main body and placed in the soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms or solid bulbs, tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. It should be noted that stolons are sometimes also called runners, and propagules are also called bulbils, which are divided into broad buds and bulbils. Vine cuttings refer to the shoots (including leaves and stems, without roots) of plants such as sweet potatoes and Japanese yam. Bulbs, corms, tubers, rhizomes, stem cuttings, rootstocks, or tuberous roots are collectively referred to as bulbs. The cultivation of tubers begins by planting tubers into the soil, but the tubers used are usually called seed tubers.

[0424] As a method for controlling harmful arthropods by applying an effective amount of the compound or composition A of the present invention to the soil, examples include applying an effective amount of the compound or composition A of the present invention to the soil before or after transplanting. More specifically, examples include planting hole treatment (planting hole distribution, planting hole treatment soil mixing), root treatment (root distribution, root soil mixing, root irrigation, late seedling stage root treatment), planting furrow treatment (planting furrow distribution, planting furrow soil mixing), ridge furrow treatment (ridge furrow distribution, ridge furrow soil mixing, growing season ridge furrow distribution), sowing furrow treatment (sowing season ridge furrow distribution, sowing season ridge furrow soil mixing), overall treatment (whole soil distribution, whole soil mixing), ridge planting lateral treatment, water surface treatment (water surface application, water surface application after water storage), other soil distribution treatments (growing season granule foliar distribution, distribution under the canopy or around the trunk, soil surface distribution, soil surface mixing, sowing hole distribution, ridge surface distribution). Distribute, interplant distribution), other irrigation treatments (soil irrigation, seedling irrigation, pesticide injection, basal irrigation, drip irrigation, chemical solution irrigation), seedling box treatment (seedling box distribution, seedling box irrigation, seedling box pesticide accumulation), seedling tray treatment (seedling tray distribution, seedling tray irrigation, seedling tray pesticide accumulation), seedbed treatment (seedbed distribution, seedbed irrigation, seedling bed distribution, seedling soaking), bed soil mixing treatment (bed soil mixing, pre-sowing bed soil mixing, distribution before sowing and covering with soil, distribution after sowing and covering with soil, soil mixing), and other treatments (cultivated soil mixing, turning in, topsoil mixing, rainwater drip soil mixing, planting location treatment, granular calyx distribution, paste fertilizer mixing).

[0425] As seed treatment, examples include treatment of seeds or vegetative reproductive organs by the compound or composition A of the present invention. More specifically, examples include: spraying treatment by atomizing a suspension of the compound or composition A of the present invention and spraying it onto the surface of the seed or vegetative reproductive organ; coating treatment by applying the compound or composition A of the present invention to the seed or vegetative reproductive organ; immersion treatment by immersing the seed or vegetative reproductive organ in a solution of the compound or composition A of the present invention for a certain period of time; and methods of coating seeds or vegetative reproductive organs using a carrier containing the compound or composition A of the present invention (coating treatment, granule coating treatment, etc.). Seed potatoes are a particularly good example of the aforementioned vegetative reproductive organ.

[0426] When treating seeds or vegetative reproductive organs with composition A, composition A can be formulated as a single preparation for treating the seeds or vegetative reproductive organs, or composition A can be formulated as multiple different preparations for treating the seeds or vegetative reproductive organs multiple times. Examples of methods for treating seeds or vegetative reproductive organs multiple times with multiple different preparations include: treating with a preparation containing only the compound of the present invention as an active ingredient, air-drying the seeds or vegetative reproductive organs, and then treating with a preparation containing this ingredient; and treating with a preparation containing both the compound of the present invention and this ingredient as active ingredients, air-drying the seeds or vegetative reproductive organs, and then treating with a preparation containing this ingredient other than the ingredient that has been treated.

[0427] In this invention, a seed or vegetative reproductive organ that retains the compound or composition A of the present invention refers to a seed or vegetative reproductive organ in which the compound or composition A of the present invention is attached to its surface. For the aforementioned seed or vegetative reproductive organ that retains the compound or composition A of the present invention, materials other than the compound or composition A of the present invention may be attached before or after the compound or composition A of the present invention is attached to the seed or vegetative reproductive organ.

[0428] Furthermore, when composition A adheres to the surface of a seed or vegetative reproductive organ by forming a layer, this layer is formed of one or more layers. Additionally, when multiple layers are formed, each layer may contain one or more active ingredients, or it may be formed of a layer containing one or more active ingredients and a layer not containing any active ingredient.

[0429] Seeds or vegetative reproductive organs containing the compound or composition A of the present invention can be obtained, for example, by applying a preparation containing the compound or composition A of the present invention to the seed or vegetative reproductive organ using the aforementioned seed treatment method.

[0430] When the compound or composition A of the present invention is used for the control of harmful arthropods in the agricultural field, the application rate is per 10,000 m³. 2 The amount of the compound of the present invention is typically 1 to 10,000 g. When treating seeds or vegetative reproductive organs, the amount of the compound of the present invention applied is typically in the range of 0.001 to 100 g relative to 1 kg of seeds or vegetative reproductive organs. When the compound or composition A of the present invention is formulated as an emulsion, wettable powder, suspension, etc., it is typically diluted with water to an active ingredient concentration of 0.01 to 10,000 ppm and then applied. Granules, powders, etc., are typically applied directly.

[0431] In addition, the compound or composition A of the present invention can also be processed by methods such as wrapping the processed resin preparation into sheet or thread form around the crop, laying it near the crop, or laying it in the soil around the roots.

[0432] When using the compound or composition A of the present invention to control harmful arthropods inhabiting houses, the dosage, when applied to a surface, is [amount] per 1m². 2 The amount of the compound of the present invention applied to the treatment area is typically 0.01 to 1000 mg, and in the case of treatment in a space, it is applied per 1 m². 3 The amount of the compound of the present invention used in the treatment space is typically 0.01 to 500 mg. When the compound or composition A of the present invention is formulated as an emulsion, wettable powder, suspension, etc., it is usually diluted with water and applied at an active ingredient concentration of 0.1 to 10,000 ppm. Oils, aerosols, fumigants, poison baits, etc., are applied directly.

[0433] When using the compound or composition A of the present invention to control external parasites in livestock such as cattle, horses, pigs, sheep, goats, and chickens, as well as small animals such as dogs, cats, rats, and mice, it can be administered to animals by methods known in veterinary medicine. Specifically, for systemic suppression, it can be administered via methods such as tablets, feed mixing, suppositories, or injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.). For non-systemic suppression, it can be used by methods such as spraying, pouring, or dripping an oily or aqueous solution, washing the animal with a shampoo, or making a collar or ear tag from a resin preparation for the animal to wear. The amount of the compound or composition A of the present invention administered to the animal is generally in the range of 0.1 to 1000 mg relative to 1 kg of the animal's body weight.

[0434] The compound or composition A of the present invention can be used as a control agent for harmful arthropods in farmland such as dry fields, paddy fields, lawns, and orchards. Examples of plants that can be cited as examples include the following.

[0435] Maize (dent, flint, soft, popcorn, glutinous, sweet, non-sweet maize), Rice (long-grain, short-grain, medium-grain, Japanese, tropical Japanese, Indian (Indica), Javanese, paddy rice, upland rice, floating rice, direct seeding, transplanting, glutinous rice), Wheat (bread wheat (dull, soft, medium, red, white), durum wheat, spelt wheat, dense-eared wheat, each winter wheat type, spring wheat type), Barley (two-row barley (= brewing barley), six-row barley, naked barley, sticky barley, each...) Winter barley type, spring barley type), rye (winter rye type, spring rye type), black wheat (winter black wheat type, spring black wheat type), oats (winter oat type, spring oat type), sorghum, cotton (land-grown variety, Pima variety), soybean (mature seed harvest variety, edamame variety, green-harvested variety, each with indeterminate, determinate, and semi-determinate growth types), peanut, buckwheat, sugar beet (for sugar production, feed, root vegetable, leafy vegetable, fuel), rapeseed (winter rapeseed type, spring rapeseed type), Canada rapeseed (winter Canada rapeseed type, spring Canada rapeseed type), sunflower (for oil extraction, food). Vegetables used for both medicinal and ornamental purposes include sugarcane, tobacco, tea trees, mulberries, nightshade vegetables (eggplant, tomato, green pepper, chili pepper, potato, etc.), cucurbitaceous vegetables (cucumber, pumpkin, zucchini, watermelon, cantaloupe, etc.), cruciferous vegetables (radish, turnip, horseradish, kohlrabi, cabbage, bok choy, mustard greens, broccoli, cauliflower, etc.), asteraceous vegetables (burdock, chrysanthemum, artichoke, lettuce, etc.), lilyaceous vegetables (scallions, onions, garlic, asparagus, etc.), umbelliferous vegetables (carrots, parsley, celery, parsnips, etc.), chenopodiaceae vegetables (spinach, sauvignon Blanc, etc.), and lamiaceae vegetables (perilla, mint). Basil, strawberries, sweet potatoes, Japanese yam, taro, pears (apples, European pears, Japanese pears, white pears, quince, quince, etc.), stone fruits (peach, plum, nectarine, green plum, cherry, apricot, plum, etc.), citrus fruits (Wenzhou mandarin oranges, oranges, lemons, limes, grapefruits, etc.), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, macadamia nuts, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, figs, olives, loquats, bananas, coffee, dates, coconuts, ornamental plants, forest plants, turfgrass, and pasture grasses.

[0436] The above-mentioned plants are any commonly cultivated varieties, without any particular limitation. These plants also include plants produced through natural mating, plants produced through mutation, F1 hybrids, and recombinant crops. Examples of recombinant crops include, for instance, plants conferred resistance to herbicides such as isoxaflutole (HPPD inhibitors, imidazoline, ALS inhibitors, EPSP inhibitors, glutamine synthase inhibitors, PPO inhibitors, bromobenzonitrile, or dicamba; plants capable of synthesizing known selective toxins from Bacillus species such as Bacillus thuringiensis; and plants conferred specific insecticidal activity by synthesizing gene fragments identical to endogenous genes from harmful insects and inducing gene silencing (RNAi; RNA interference) in target harmful insects.

[0437] Example

[0438] The present invention will be described in more detail below using manufacturing examples, formulation examples, and test examples, but the present invention is not limited to these examples.

[0439] In this specification, Me represents methyl, Et represents ethyl, Pr represents propyl, i-Pr represents isopropyl, Bu represents butyl, t-Bu represents tert-butyl, Boc represents tert-butoxycarbonyl, Hex represents hexyl, c-Pr represents cyclopropyl, c-Bu represents cyclobutyl, Ph represents phenyl, Py2 represents 2-pyridyl, Py3 represents 3-pyridyl, and Py4 represents 4-pyridyl. When c-Pr, c-Bu, Ph, Py2, Py3, and Py4 are substituted with substituents, the substituent and its position are listed before the symbol. For example, 1-CN-c-Pr represents 1-cyanocyclopropyl, 3,4-F2-Ph represents 3,4-difluorophenyl, and 4-CF3-Py2 represents 4-(trifluoromethyl)-2-pyridyl.

[0440] First, examples of manufacturing the compounds of the present invention and their manufacturing intermediates are shown.

[0441] When the physical properties of a compound are determined using liquid chromatography / mass spectrometry (hereinafter referred to as LCMS), the measured molecular ion value [M+H] is recorded. + Or [MH] - and retention time (hereinafter referred to as RT). The conditions for liquid chromatography (hereinafter referred to as LC) are as follows.

[0442] [LC conditions]

[0443] Column: L-column2 ODS, inner diameter 4.6 mm, length 30 mm, particle size 3 μm (Generally Incorporated Chemical Substances Evaluation and Research Organization).

[0444] UV measurement wavelength: 254nm

[0445] Mobile phase: Solution A: 0.1% formic acid aqueous solution, Solution B: 0.1% formic acid acetonitrile

[0446] Flow rate: 2.0 mL / min

[0447] Gradient conditions: The solution is delivered using the concentration gradient described in [Table LC1].

[0448] [Table 1]

[0449] [Table LC1]

[0450] Time (minutes) Solution A (%) Solution B (%) 0.O1 90 1O 2.O 0 O 100 4.OO O 100 4.O 1 90 1O

[0451] [MS conditions]

[0452] Detector: LCMS-2020 (manufactured by Shimadzu Corporation)

[0453] Ionization method: DUIS method

[0454] Reference Manufacturing Example 1

[0455] To a mixture of 5.9 g of ethyl 3-(trifluoromethyl)-1H-pyrazole-5-carboxylate and 70 mL of THF, 9.0 g of triphenylphosphine, 5.3 mL of 2-(tert-butoxycarbonylamino)-1-ethanol, and 10 g of bis(2-methoxyethyl) azodicarboxylate were added at 0 °C, and the mixture was stirred at room temperature for 6 hours. Water was added to the resulting mixture, and extraction was performed using ethyl acetate. The resulting organic layer was dried over sodium sulfate and concentrated under reduced pressure. The residue was subjected to silica gel column chromatography to give 7.8 g of intermediate 1 as shown in the formula below.

[0456] [Chemical Formula 13]

[0457]

[0458] Intermediate 1: 1 H-NMR(CDCl3)δ:7.09(1H,s),4.79(1H,br s),4.74-4.71(2H,m),4.37(2H,q),3.63(2H,q),1.40-1.37(12H,m).

[0459] Reference Manufacturing Example 2

[0460] At 0°C, 6 mL of hydrogen chloride solution (approximately 4 mol / L cyclopentyl methyl ether solution) was added to a mixture of 0.51 g of intermediate 1 and 5 mL of cyclopentyl methyl ether. The mixture was stirred at room temperature for 4 hours, and then concentrated under reduced pressure. A saturated aqueous sodium carbonate solution was added to the residue, and the mixture was stirred at room temperature for 3 hours. Extraction was performed using chloroform containing 25% 2-propanol. The resulting organic layer was dried over sodium sulfate and concentrated under reduced pressure. The residue was subjected to silica gel column chromatography to give 0.26 g of intermediate 2 as shown in the formula below.

[0461] [Chemical Formula 14]

[0462]

[0463] Intermediate 2: 1 H-NMR(CDCl3)δ:7.12(1H,s),6.16(1H,br s),4.48(2H,t),3.87-3.83(2H,m).

[0464] Manufacturing Example 1

[0465] Under a nitrogen atmosphere, 0.1 g of sodium hydride (oil-based, 60%) was added to a mixture of 0.09 g of 6-bromo-3,4-dihydroisoquinoline-1(2H)-one, 0.09 g of 2-fluoro-N,N-dimethylpyridine-3-sulfonamide, and 4 mL of dimethylformamide at 0 °C, and the mixture was stirred at 0 °C for 4 hours. Water was added to the resulting mixture, and extraction was performed using ethyl acetate. The resulting organic layer was dried with magnesium sulfate and concentrated under reduced pressure. The residue was subjected to silica gel column chromatography to give 0.05 g of compound 1 of the present invention, represented by the following formula.

[0466] [Chemical Formula 15]

[0467]

[0468] Compound 1 of this invention: LCMS: 410[M+H] + RT = 1.64 minutes

[0469] Manufacturing Example 2

[0470] The following shows the compounds manufactured according to Manufacturing Example 1 and their physical properties.

[0471] [Chemical Formula 16]

[0472]

[0473] Compound 2 of this invention: 1H-NMR(CDCl3)δ:8.79(1H,dd),8.43(1H,dd),8.32(1H,d),7.55(1H,dd),7.37(1H,d),4 .12-4.20(1H,m),3.90-3.96(1H,m),3.68-3.77(1H,m),3.20-3.24(1H,m),2.76(6H,s).

[0474] [Chemical Formula 17]

[0475]

[0476] Compound 3 of this invention: 1 H-NMR(CDCl3)δ:8.79(1H,dd),8.75(1H,d),8.49(1H,d),8.43(1H,dd),7.55(1H,dd),4 .12-4.19(1H,m),3.92-3.97(1H,m),3.63-3.72(1H,m),3.19-3.25(1H,m),2.77(6H,s).

[0477] Manufacturing Example 3

[0478] Add 0.95 g of cesium carbonate to a mixture of 0.3 g of intermediate 2, 0.3 g of 2-fluoro-N,N-dimethylpyridine-3-sulfonamide, and 5 mL of dimethyl sulfoxide, and stir at 40 °C for 10 hours. Allow the resulting mixture to cool to room temperature, add water, and filter out the precipitated solid to obtain 0.38 g of compound 4 of the present invention, as shown in the formula below.

[0479] [Chemical Formula 18]

[0480]

[0481] Compound 4 of this invention: 1 H-NMR(CDCl3)δ:8.80(1H,dd),8.42(1H,dd),7.59(1H,dd),7.18(1H,s),4.79-4. 87(1H,m),4.61-4.65(1H,m),4.34-4.41(1H,m),4.00-4.05(1H,m),2.78(6H,s).

[0482] Next, examples of compounds of the present invention manufactured according to any of the manufacturing examples described in the embodiments and the manufacturing methods described in this specification are shown below.

[0483] [Chemical Formula 19]

[0484]

[0485] In the compound represented by formula (L-1) (hereinafter referred to as compound (L-1)), R 2a and R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX1).

[0486] [Table 2]

[0487]

[0488] In compound (L-1), R 2a It is methyl, R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX2).

[0489] In compound (L-1), R 2a It is methyl, R 2b It is methyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] with any substituents are referred to as compound group SX3.

[0490] In compound (L-1), R 2a For ethyl, R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] with any substituents are referred to as compound group SX4.

[0491] In compound (L-1), R 2a and R 2b For ethyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX5).

[0492] In compound (L-1), R 2a For propyl, and R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX6).

[0493] In compound (L-1), R 2a and R2b For propyl, R 6c For hydrogen atoms, R 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX7).

[0494] In compound (L-1), R 2a It is methyl, R 2b For ethyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] with any substituents are referred to as compound group SX8.

[0495] In compound (L-1), R 2a and R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX9).

[0496] In compound (L-1), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX10).

[0497] In compound (L-1), R 2a and R 2b It is methyl, R 6c R is a fluorine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX11).

[0498] In compound (L-1), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX12).

[0499] In compound (L-1), R 2a and R 2b For ethyl, R 6c R is a fluorine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX13).

[0500] In compound (L-1), R 2aFor propyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX14).

[0501] In compound (L-1), R 2a and R 2b For propyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX15).

[0502] In compound (L-1), R 2a It is methyl, R 2b For ethyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX16).

[0503] In compound (L-1), R 2a and R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX17).

[0504] In compound (L-1), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX18).

[0505] In compound (L-1), R 2a and R 2b It is methyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX19).

[0506] In compound (L-1), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX20).

[0507] In compound (L-1), R2a and R 2b For ethyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX21).

[0508] In compound (L-1), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX22).

[0509] In compound (L-1), R 2a and R 2b For propyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX23).

[0510] In compound (L-1), R 2a It is methyl, R 2b For ethyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX24).

[0511] In compound (L-1), R 2a and R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX25).

[0512] In compound (L-1), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX26).

[0513] In compound (L-1), R 2a and R 2b It is methyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX27).

[0514] In compound (L-1), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX28).

[0515] In compound (L-1), R 2a and R 2b For ethyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX29).

[0516] In compound (L-1), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX30).

[0517] In compound (L-1), R 2a and R 2b For propyl, R 6c R is a bromine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX31).

[0518] In compound (L-1), R 2a It is methyl, R 2b For ethyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX32).

[0519] In compound (L-1), R 2a and R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX33).

[0520] In compound (L-1), R 2a It is methyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX34).

[0521] In compound (L-1), R 2a and R 2b It is methyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX35).

[0522] In compound (L-1), R 2a For ethyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX36).

[0523] In compound (L-1), R 2a and R 2b For ethyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX37).

[0524] In compound (L-1), R 2a For propyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX38).

[0525] In compound (L-1), R 2a and R 2b For propyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX39).

[0526] In compound (L-1), R 2a It is methyl, R 2b For ethyl, R 6c For iodine atoms, R 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX40).

[0527] [Chemical Formula 20]

[0528]

[0529] In the compound represented by formula (L-2) (hereinafter referred to as compound (L-2)), R 2a and R 2bFor hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX41).

[0530] In compound (L-2), R 2a It is methyl, R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX42).

[0531] In compound (L-2), R 2a It is methyl, R 2b It is methyl, R 6b For hydrogen atoms, R 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX43).

[0532] In compound (L-2), R 2a For ethyl, R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX44).

[0533] In compound (L-2), R 2a and R 2b For ethyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX45).

[0534] In compound (L-2), R 2a For propyl, and R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX46).

[0535] In compound (L-2), R 2a and R 2b For propyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX47).

[0536] In compound (L-2), R 2aIt is methyl, R 2b For ethyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX48).

[0537] In compound (L-2), R 2a and R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX49).

[0538] In compound (L-2), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX50).

[0539] In compound (L-2), R 2a and R 2b It is methyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX51).

[0540] In compound (L-2), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX52).

[0541] In compound (L-2), R 2a and R 2b For ethyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX53).

[0542] In compound (L-2), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX54).

[0543] In compound (L-2), R2a and R 2b For propyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX55).

[0544] In compound (L-2), R 2a It is methyl, R 2b For ethyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX56).

[0545] In compound (L-2), R 2a and R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX57).

[0546] In compound (L-2), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX58).

[0547] In compound (L-2), R 2a and R 2b It is methyl, R 6b R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX59).

[0548] In compound (L-2), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX60).

[0549] In compound (L-2), R 2a and R 2b For ethyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX61).

[0550] In compound (L-2), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX62).

[0551] In compound (L-2), R 2a and R 2b For propyl, R 6b R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX63).

[0552] In compound (L-2), R 2a It is methyl, R 2b For ethyl, R 6b R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A with any substituents are referred to as compound group SX64.

[0553] In compound (L-2), R 2a and R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX65).

[0554] In compound (L-2), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX66).

[0555] In compound (L-2), R 2a and R 2b It is methyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX67).

[0556] In compound (L-2), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX68).

[0557] In compound (L-2), R 2a and R 2b For ethyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX69).

[0558] In compound (L-2), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX70).

[0559] In compound (L-2), R 2a and R 2b For propyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX71).

[0560] In compound (L-2), R 2a It is methyl, R 2b For ethyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX72).

[0561] In compound (L-2), R 2a and R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in Tables 1A to 3A with any substituents are referred to as compound group SX73.

[0562] In compound (L-2), R 2a It is methyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX74).

[0563] In compound (L-2), R 2a and R 2b It is methyl, R 6b For iodine atoms, R 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX75).

[0564] In compound (L-2), R 2a For ethyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX76).

[0565] In compound (L-2), R 2a and R 2b For ethyl, R 6b For iodine atoms, R 6e The compounds listed in Tables 1A to 3A with any substituents are referred to as compound group SX77.

[0566] In compound (L-2), R 2a For propyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX78).

[0567] In compound (L-2), R 2a and R 2b For propyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX79).

[0568] In compound (L-2), R 2a It is methyl, R 2b For ethyl, R 6b For iodine atoms, R 6e Compounds with any substituents listed in [Table 1A] to [Table 3A] (hereinafter referred to as compound group SX80).

[0569] [Chemical Formula 21]

[0570]

[0571] In the compound represented by formula (L-3) (hereinafter referred to as compound (L-3)), R 2a and R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX81).

[0572] In compound (L-3), R 2aIt is methyl, R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX82).

[0573] In compound (L-3), R 2a It is methyl, R 2b It is methyl, R 6c For hydrogen atoms, R 6e The compounds listed in Tables 1A to 3A with any substituents are referred to as compound group SX83.

[0574] In compound (L-3), R 2a For ethyl, R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX84).

[0575] In compound (L-3), R 2a and R 2b For ethyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX85).

[0576] In compound (L-3), R 2a For propyl, and R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX86).

[0577] In compound (L-3), R 2a and R 2b For propyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX87).

[0578] In compound (L-3), R 2a It is methyl, R 2b For ethyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX88).

[0579] In compound (L-3), R2a and R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX89).

[0580] In compound (L-3), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX90).

[0581] In compound (L-3), R 2a and R 2b It is methyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX91).

[0582] In compound (L-3), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX92).

[0583] In compound (L-3), R 2a and R 2b For ethyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX93).

[0584] In compound (L-3), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX94).

[0585] In compound (L-3), R 2a and R 2b For propyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX95).

[0586] In compound (L-3), R 2a It is methyl, R 2b For ethyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX96).

[0587] In compound (L-3), R 2a and R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A with any substituents are referred to as compound group SX97.

[0588] In compound (L-3), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX98).

[0589] In compound (L-3), R 2a and R 2b It is methyl, R 6c R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX99).

[0590] In compound (L-3), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX100).

[0591] In compound (L-3), R 2a and R 2b For ethyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX101).

[0592] In compound (L-3), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX102).

[0593] In compound (L-3), R 2a and R 2b For propyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX103).

[0594] In compound (L-3), R 2a It is methyl, R 2b For ethyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX104).

[0595] In compound (L-3), R 2a and R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in Tables 1A to 3A are compounds with any substituents (hereinafter referred to as compound group SX105).

[0596] In compound (L-3), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX106).

[0597] In compound (L-3), R 2a and R 2b It is methyl, R 6c R is a bromine atom. 6e The compounds listed in Tables 1A to 3A with any substituents are referred to as compound group SX107.

[0598] In compound (L-3), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX108).

[0599] In compound (L-3), R 2a and R 2b For ethyl, R 6c R is a bromine atom. 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX109).

[0600] In compound (L-3), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX110).

[0601] In compound (L-3), R 2a and R 2b For propyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX111).

[0602] In compound (L-3), R 2a It is methyl, R 2b For ethyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX112).

[0603] In compound (L-3), R 2a and R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX113).

[0604] In compound (L-3), R 2a It is methyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX114).

[0605] In compound (L-3), R 2a and R 2b It is methyl, R 6c For iodine atoms, R 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX115).

[0606] In compound (L-3), R 2a For ethyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6eThe compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX116).

[0607] In compound (L-3), R 2a and R 2b For ethyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX117).

[0608] In compound (L-3), R 2a For propyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX118).

[0609] In compound (L-3), R 2a and R 2b For propyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX119).

[0610] In compound (L-3), R 2a It is methyl, R 2b For ethyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX120).

[0611] [Chemical Formula 22]

[0612]

[0613] In the compound represented by formula (L-4) (hereinafter referred to as compound (L-4)), R 2a and R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX121).

[0614] In compound (L-4), R 2a It is methyl, R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX122).

[0615] In compound (L-4), R 2a It is methyl, R 2b It is methyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX123).

[0616] In compound (L-4), R 2a For ethyl, R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX124).

[0617] In compound (L-4), R 2a and R 2b For ethyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX125).

[0618] In compound (L-4), R 2a For propyl, and R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX126).

[0619] In compound (L-4), R 2a and R 2b For propyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX127).

[0620] In compound (L-4), R 2a It is methyl, R 2b For ethyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX128).

[0621] In compound (L-4), R 2a and R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6eThe compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX129).

[0622] In compound (L-4), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX130).

[0623] In compound (L-4), R 2a and R 2b It is methyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX131).

[0624] In compound (L-4), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX132).

[0625] In compound (L-4), R 2a and R 2b For ethyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX133).

[0626] In compound (L-4), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX134).

[0627] In compound (L-4), R 2a and R 2b For propyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX135).

[0628] In compound (L-4), R 2a It is methyl, R 2b For ethyl, R 6bR is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX136).

[0629] In compound (L-4), R 2a and R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX137).

[0630] In compound (L-4), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX138).

[0631] In compound (L-4), R 2a and R 2b It is methyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX139).

[0632] In compound (L-4), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX140).

[0633] In compound (L-4), R 2a and R 2b For ethyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX141).

[0634] In compound (L-4), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX142).

[0635] In compound (L-4), R 2a and R 2b For propyl, R6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX143).

[0636] In compound (L-4), R 2a It is methyl, R 2b For ethyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX144).

[0637] In compound (L-4), R 2a and R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX145).

[0638] In compound (L-4), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX146).

[0639] In compound (L-4), R 2a and R 2b It is methyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX147).

[0640] In compound (L-4), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX148).

[0641] In compound (L-4), R 2a and R 2b For ethyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX149).

[0642] In compound (L-4), R 2a For propyl, R2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX150).

[0643] In compound (L-4), R 2a and R 2b For propyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX151).

[0644] In compound (L-4), R 2a It is methyl, R 2b For ethyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX152).

[0645] In compound (L-4), R 2a and R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX153).

[0646] In compound (L-4), R 2a It is methyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX154).

[0647] In compound (L-4), R 2a and R 2b It is methyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX155).

[0648] In compound (L-4), R 2a For ethyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX156).

[0649] In compound (L-4), R2a and R 2b For ethyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX157).

[0650] In compound (L-4), R 2a For propyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX158).

[0651] In compound (L-4), R 2a and R 2b For propyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX159).

[0652] In compound (L-4), R 2a It is methyl, R 2b For ethyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX160).

[0653] [Chemical Formula 23]

[0654]

[0655] In the compound represented by formula (L-5) (hereinafter referred to as compound (L-5)), R 2a and R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX161).

[0656] In compound (L-5), R 2a It is methyl, R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX162).

[0657] In compound (L-5), R 2a It is methyl, R 2b It is methyl, R6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX163).

[0658] In compound (L-5), R 2a For ethyl, R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX164).

[0659] In compound (L-5), R 2a and R 2b For ethyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX165).

[0660] In compound (L-5), R 2a For propyl, and R 2b For hydrogen atoms, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX166).

[0661] In compound (L-5), R 2a and R 2b For propyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX167).

[0662] In compound (L-5), R 2a It is methyl, R 2b For ethyl, R 6c For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX168).

[0663] In compound (L-5), R 2a and R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX169).

[0664] In compound (L-5), R 2a It is methyl, R2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX170).

[0665] In compound (L-5), R 2a and R 2b It is methyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX171).

[0666] In compound (L-5), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX172).

[0667] In compound (L-5), R 2a and R 2b For ethyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX173).

[0668] In compound (L-5), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX174).

[0669] In compound (L-5), R 2a and R 2b For propyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX175).

[0670] In compound (L-5), R 2a It is methyl, R 2b For ethyl, R 6c R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX176).

[0671] In compound (L-5), R2a and R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX177).

[0672] In compound (L-5), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX178).

[0673] In compound (L-5), R 2a and R 2b It is methyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX179).

[0674] In compound (L-5), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX180).

[0675] In compound (L-5), R 2a and R 2b For ethyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX181).

[0676] In compound (L-5), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX182).

[0677] In compound (L-5), R 2a and R 2b For propyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX183).

[0678] In compound (L-5), R 2a It is methyl, R 2b For ethyl, R 6c R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX184).

[0679] In compound (L-5), R 2a and R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX185).

[0680] In compound (L-5), R 2a It is methyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX186).

[0681] In compound (L-5), R 2a and R 2b It is methyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX187).

[0682] In compound (L-5), R 2a For ethyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX188).

[0683] In compound (L-5), R 2a and R 2b For ethyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX189).

[0684] In compound (L-5), R 2a For propyl, R 2b For hydrogen atoms, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX190).

[0685] In compound (L-5), R 2a and R 2b For propyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX191).

[0686] In compound (L-5), R 2a It is methyl, R 2b For ethyl, R 6c R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX192).

[0687] In compound (L-5), R 2a and R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX193).

[0688] In compound (L-5), R 2a It is methyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX194).

[0689] In compound (L-5), R 2a and R 2b It is methyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX195).

[0690] In compound (L-5), R 2a For ethyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX196).

[0691] In compound (L-5), R 2a and R 2b For ethyl, R 6c For iodine atoms, R 6eThe compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX197).

[0692] In compound (L-5), R 2a For propyl, R 2b For hydrogen atoms, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX198).

[0693] In compound (L-5), R 2a and R 2b For propyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX199).

[0694] In compound (L-5), R 2a It is methyl, R 2b For ethyl, R 6c For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX200).

[0695] [Chemical Formula 24]

[0696]

[0697] In the compound represented by formula (L-6) (hereinafter referred to as compound (L-6)), R 2a and R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX201).

[0698] In compound (L-6), R 2a It is methyl, R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX202).

[0699] In compound (L-6), R 2a It is methyl, R 2b It is methyl, R 6b For hydrogen atoms, R 6eThe compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX203).

[0700] In compound (L-6), R 2a For ethyl, R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX204).

[0701] In compound (L-6), R 2a and R 2b For ethyl, R 6b For hydrogen atoms, R 6e The compounds listed in Tables 1A to 3A with any substituents (hereinafter referred to as compound group SX205).

[0702] In compound (L-6), R 2a For propyl, and R 2b For hydrogen atoms, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX206).

[0703] In compound (L-6), R 2a and R 2b For propyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX207).

[0704] In compound (L-6), R 2a It is methyl, R 2b For ethyl, R 6b For hydrogen atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX208).

[0705] In compound (L-6), R 2a and R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX209).

[0706] In compound (L-6), R 2a It is methyl, R 2b For hydrogen atoms, R 6bR is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX210).

[0707] In compound (L-6), R 2a and R 2b It is methyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX211).

[0708] In compound (L-6), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] with any substituents (hereinafter referred to as compound group SX212).

[0709] In compound (L-6), R 2a and R 2b For ethyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX213).

[0710] In compound (L-6), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] with any substituents (hereinafter referred to as compound group SX214).

[0711] In compound (L-6), R 2a and R 2b For propyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX215).

[0712] In compound (L-6), R 2a It is methyl, R 2b For ethyl, R 6b R is a fluorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX216).

[0713] In compound (L-6), R 2a and R 2b For hydrogen atoms, R6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] with any substituents (hereinafter referred to as compound group SX217).

[0714] In compound (L-6), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX218).

[0715] In compound (L-6), R 2a and R 2b It is methyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX219).

[0716] In compound (L-6), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX220).

[0717] In compound (L-6), R 2a and R 2b For ethyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] with any substituents (hereinafter referred to as compound group SX221).

[0718] In compound (L-6), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX222).

[0719] In compound (L-6), R 2a and R 2b For propyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX223).

[0720] In compound (L-6), R 2a It is methyl, R2b For ethyl, R 6b R is a chlorine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX224).

[0721] In compound (L-6), R 2a and R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX225).

[0722] In compound (L-6), R 2a It is methyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX226).

[0723] In compound (L-6), R 2a and R 2b It is methyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX227).

[0724] In compound (L-6), R 2a For ethyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX228).

[0725] In compound (L-6), R 2a and R 2b For ethyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX229).

[0726] In compound (L-6), R 2a For propyl, R 2b For hydrogen atoms, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX230).

[0727] In compound (L-6), R2a and R 2b For propyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX231).

[0728] In compound (L-6), R 2a It is methyl, R 2b For ethyl, R 6b R is a bromine atom. 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX232).

[0729] In compound (L-6), R 2a and R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX233).

[0730] In compound (L-6), R 2a It is methyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX234).

[0731] In compound (L-6), R 2a and R 2b It is methyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX235).

[0732] In compound (L-6), R 2a For ethyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX236).

[0733] In compound (L-6), R 2a and R 2b For ethyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX237).

[0734] In compound (L-6), R 2a For propyl, R 2b For hydrogen atoms, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX238).

[0735] In compound (L-6), R 2a and R 2b For propyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX239).

[0736] In compound (L-6), R 2a It is methyl, R 2b For ethyl, R 6b For iodine atoms, R 6e The compounds listed in [Table 1A] to [Table 3A] are compounds with any substituents (hereinafter referred to as compound group SX240).

[0737] [Chemical Formula 25]

[0738]

[0739] In the compound represented by formula (L-7) (hereinafter referred to as compound (L-7)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX241).

[0740] [Table 3]

[0741]

[0742] [Table 4]

[0743]

[0744] [Table 5]

[0745]

[0746] In compound (L-7), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX242).

[0747] In compound (L-7), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX243).

[0748] In compound (L-7), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX244).

[0749] In compound (L-7), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX245).

[0750] In compound (L-7), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX246).

[0751] In compound (L-7), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX247).

[0752] In compound (L-7), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX248).

[0753] [Chemical Formula 26]

[0754]

[0755] In the compound represented by formula (L-8) (hereinafter referred to as compound (L-8)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX249).

[0756] In compound (L-8), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX250).

[0757] In compound (L-8), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX251).

[0758] In compound (L-8), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX252).

[0759] In compound (L-8), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX253).

[0760] In compound (L-8), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX254).

[0761] In compound (L-8), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX255).

[0762] In compound (L-8), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX256).

[0763] [Chemical Formula 27]

[0764]

[0765] In the compound represented by formula (L-9) (hereinafter referred to as compound (L-9)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX257).

[0766] In compound (L-9), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX258).

[0767] In compound (L-9), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX259).

[0768] In compound (L-9), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX260).

[0769] In compound (L-9), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX261).

[0770] In compound (L-9), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX262).

[0771] In compound (L-9), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX263).

[0772] In compound (L-9), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX264).

[0773] [Chemical Formula 28]

[0774]

[0775] In the compound represented by formula (L-10) (hereinafter referred to as compound (L-10)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX265).

[0776] In compound (L-10), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX266).

[0777] In compound (L-10), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX267).

[0778] In compound (L-10), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX268).

[0779] In compound (L-10), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX269).

[0780] In compound (L-10), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX270).

[0781] In compound (L-10), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX271).

[0782] In compound (L-10), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX272).

[0783] [Chemical Formula 29]

[0784]

[0785] In the compound represented by formula (L-11) (hereinafter referred to as compound (L-11)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX273).

[0786] In compound (L-11), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX274).

[0787] In compound (L-11), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX275).

[0788] In compound (L-11), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX276).

[0789] In compound (L-11), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX277).

[0790] In compound (L-11), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX278).

[0791] In compound (L-11), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX279).

[0792] In compound (L-11), R 2a and R 2b It is methyl, R3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX280).

[0793] [Chemical Formula 30]

[0794]

[0795] In the compound represented by formula (L-12) (hereinafter referred to as compound (L-12)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX281).

[0796] In compound (L-12), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX282).

[0797] In compound (L-12), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX283).

[0798] In compound (L-12), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX284).

[0799] In compound (L-12), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX285).

[0800] In compound (L-12), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX286).

[0801] In compound (L-12), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX287).

[0802] In compound (L-12), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX288).

[0803] [Chemical Formula 31]

[0804]

[0805] In the compound represented by formula (L-13) (hereinafter referred to as compound (L-13)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX289).

[0806] In compound (L-13), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX290).

[0807] In compound (L-13), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX291).

[0808] In compound (L-13), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX292).

[0809] In compound (L-13), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX293).

[0810] In compound (L-13), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX294).

[0811] In compound (L-13), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX295).

[0812] In compound (L-13), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX296).

[0813] [Chemical Formula 32]

[0814]

[0815] In the compound represented by formula (L-14) (hereinafter referred to as compound (L-14)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX297).

[0816] In compound (L-14), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX298).

[0817] In compound (L-14), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX299).

[0818] In compound (L-14), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] are compounds with any substituents (hereinafter referred to as compound group SX300).

[0819] In compound (L-14), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX301).

[0820] In compound (L-14), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX302).

[0821] In compound (L-14), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX303).

[0822] In compound (L-14), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX304).

[0823] [Chemical Formula 33]

[0824]

[0825] In the compound represented by formula (L-15) (hereinafter referred to as compound (L-15)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX305).

[0826] In compound (L-15), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX306).

[0827] In compound (L-15), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX307).

[0828] In compound (L-15), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX308).

[0829] In compound (L-15), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX309).

[0830] In compound (L-15), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX310).

[0831] In compound (L-15), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX311).

[0832] In compound (L-15), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX312).

[0833] [Chemical Formula 34]

[0834]

[0835] In the compound represented by formula (L-16) (hereinafter referred to as compound (L-16)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX313).

[0836] In compound (L-16), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX314).

[0837] In compound (L-16), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX315).

[0838] In compound (L-16), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX316).

[0839] In compound (L-16), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX317).

[0840] In compound (L-16), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX318).

[0841] In compound (L-16), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX319).

[0842] In compound (L-16), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX320).

[0843] [Chemical Formula 35]

[0844]

[0845] In the compound represented by formula (L-17) (hereinafter referred to as compound (L-17)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX321).

[0846] In compound (L-17), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX322).

[0847] In compound (L-17), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX323).

[0848] In compound (L-17), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX324).

[0849] In compound (L-17), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX325).

[0850] In compound (L-17), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX326).

[0851] In compound (L-17), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX327).

[0852] In compound (L-17), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX328).

[0853] [Chemical Formula 36]

[0854]

[0855] In the compound represented by formula (L-18) (hereinafter referred to as compound (L-18)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX329).

[0856] In compound (L-18), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX330).

[0857] In compound (L-18), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX331).

[0858] In compound (L-18), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX332).

[0859] In compound (L-18), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX333).

[0860] In compound (L-18), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX334).

[0861] In compound (L-18), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX335).

[0862] In compound (L-18), R 2a and R 2b It is methyl, R3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX336).

[0863] [Chemical Formula 37]

[0864]

[0865] In the compound represented by formula (L-19) (hereinafter referred to as compound (L-19)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX337).

[0866] In compound (L-19), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX338).

[0867] In compound (L-19), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX339).

[0868] In compound (L-19), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX340).

[0869] In compound (L-19), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX341).

[0870] In compound (L-19), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX342).

[0871] In compound (L-19), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX343).

[0872] In compound (L-19), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX344).

[0873] [Chemical Formula 38]

[0874]

[0875] In the compound represented by formula (L-20) (hereinafter referred to as compound (L-20)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX345).

[0876] In compound (L-20), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX346).

[0877] In compound (L-20), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX347).

[0878] In compound (L-20), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX348).

[0879] In compound (L-20), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX349).

[0880] In compound (L-20), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX350).

[0881] In compound (L-20), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX351).

[0882] In compound (L-20), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX352).

[0883] [Chemical Formula 39]

[0884]

[0885] In the compound represented by formula (L-21) (hereinafter referred to as compound (L-21)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX353).

[0886] In compound (L-21), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX354).

[0887] In compound (L-21), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX355).

[0888] In compound (L-21), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX356).

[0889] In compound (L-21), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX357).

[0890] In compound (L-21), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX358).

[0891] In compound (L-21), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX359).

[0892] In compound (L-21), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX360).

[0893] [Chemical Formula 40]

[0894]

[0895] In the compound represented by formula (L-22) (hereinafter referred to as compound (L-22)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX361).

[0896] In compound (L-22), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX362).

[0897] In compound (L-22), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX363).

[0898] In compound (L-22), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX364).

[0899] In compound (L-22), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX365).

[0900] In compound (L-22), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX366).

[0901] In compound (L-22), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX367).

[0902] In compound (L-22), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX368).

[0903] [Chemical Formula 41]

[0904]

[0905] In the compound represented by formula (L-23) (hereinafter referred to as compound (L-23)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX369).

[0906] In compound (L-23), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX370).

[0907] In compound (L-23), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX371).

[0908] In compound (L-23), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX372).

[0909] In compound (L-23), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX373).

[0910] In compound (L-23), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX374).

[0911] In compound (L-23), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX375).

[0912] In compound (L-23), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX376).

[0913] [Chemical Formula 42]

[0914]

[0915] In the compound represented by formula (L-24) (hereinafter referred to as compound (L-24)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX377).

[0916] In compound (L-24), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX378).

[0917] In compound (L-24), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX379).

[0918] In compound (L-24), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX380).

[0919] In compound (L-24), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX381).

[0920] In compound (L-24), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX382).

[0921] In compound (L-24), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX383).

[0922] In compound (L-24), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX384).

[0923] [Chemical Formula 43]

[0924]

[0925] In the compound represented by formula (L-25) (hereinafter referred to as compound (L-25)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX385).

[0926] In compound (L-25), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX386).

[0927] In compound (L-25), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX387).

[0928] In compound (L-25), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX388).

[0929] In compound (L-25), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX389).

[0930] In compound (L-25), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX390).

[0931] In compound (L-25), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX391).

[0932] In compound (L-25), R 2a and R 2b It is methyl, R3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX392).

[0933] [Chemical Formula 44]

[0934]

[0935] In the compound represented by formula (L-26) (hereinafter referred to as compound (L-26)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX393).

[0936] In compound (L-26), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX394).

[0937] In compound (L-26), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX395).

[0938] In compound (L-26), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX396).

[0939] In compound (L-26), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX397).

[0940] In compound (L-26), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R3b The compounds listed in [Table 7A] to [Table 15A] with any substituents are referred to as compound group SX398.

[0941] In compound (L-26), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX399).

[0942] In compound (L-26), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] are compounds with any substituents (hereinafter referred to as compound group SX400).

[0943] [Chemical Formula 45]

[0944]

[0945] In the compound represented by formula (L-27) (hereinafter referred to as compound (L-27)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX401).

[0946] In compound (L-27), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX402).

[0947] In compound (L-27), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX403).

[0948] In compound (L-27), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX404).

[0949] In compound (L-27), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX405).

[0950] In compound (L-27), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX406).

[0951] In compound (L-27), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX407).

[0952] In compound (L-27), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX408).

[0953] [Chemical Formula 46]

[0954]

[0955] In the compound represented by formula (L-28) (hereinafter referred to as compound (L-28)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX409).

[0956] In compound (L-28), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX410).

[0957] In compound (L-28), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX411).

[0958] In compound (L-28), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX412).

[0959] In compound (L-28), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX413).

[0960] In compound (L-28), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX414).

[0961] In compound (L-28), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX415).

[0962] In compound (L-28), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX416).

[0963] [Chemical Formula 47]

[0964]

[0965] In the compound represented by formula (L-29) (hereinafter referred to as compound (L-29)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX417).

[0966] In compound (L-29), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX418).

[0967] In compound (L-29), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX419).

[0968] In compound (L-29), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX420).

[0969] In compound (L-29), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX421).

[0970] In compound (L-29), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX422).

[0971] In compound (L-29), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX423).

[0972] In compound (L-29), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX424).

[0973] [Chemical Formula 48]

[0974]

[0975] In the compound represented by formula (L-30) (hereinafter referred to as compound (L-30)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX425).

[0976] In compound (L-30), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX426).

[0977] In compound (L-30), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX427).

[0978] In compound (L-30), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX428).

[0979] In compound (L-30), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX429).

[0980] In compound (L-30), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX430).

[0981] In compound (L-30), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX431).

[0982] In compound (L-30), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX432).

[0983] [Chemical Formula 49]

[0984]

[0985] In the compound represented by formula (L-31) (hereinafter referred to as compound (L-31)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX433).

[0986] In compound (L-31), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX434).

[0987] In compound (L-31), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX435).

[0988] In compound (L-31), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX436).

[0989] In compound (L-31), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX437).

[0990] In compound (L-31), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX438).

[0991] In compound (L-31), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX439).

[0992] In compound (L-31), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX440).

[0993] [Chemical Formula 50]

[0994]

[0995] In the compound represented by formula (L-32) (hereinafter referred to as compound (L-32)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX441).

[0996] In compound (L-32), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX442).

[0997] In compound (L-32), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX443).

[0998] In compound (L-32), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX444).

[0999] In compound (L-32), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX445).

[1000] In compound (L-32), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX446).

[1001] In compound (L-32), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX447).

[1002] In compound (L-32), R 2a and R 2b It is methyl, R3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX448).

[1003] [Chemical Formula 51]

[1004]

[1005] In the compound represented by formula (L-33) (hereinafter referred to as compound (L-33)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX449).

[1006] In compound (L-33), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX450).

[1007] In compound (L-33), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX451).

[1008] In compound (L-33), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX452).

[1009] In compound (L-33), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX453).

[1010] In compound (L-33), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX454).

[1011] In compound (L-33), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX455).

[1012] In compound (L-33), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX456).

[1013] [Chemical Formula 52]

[1014]

[1015] In the compound represented by formula (L-34) (hereinafter referred to as compound (L-34)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX457).

[1016] In compound (L-34), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX458).

[1017] In compound (L-34), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX459).

[1018] In compound (L-34), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX460).

[1019] In compound (L-34), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX461).

[1020] In compound (L-34), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX462).

[1021] In compound (L-34), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX463).

[1022] In compound (L-34), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX464).

[1023] [Chemical Formula 53]

[1024]

[1025] In the compound represented by formula (L-35) (hereinafter referred to as compound (L-35)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX465).

[1026] In compound (L-35), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3bThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX466).

[1027] In compound (L-35), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX467).

[1028] In compound (L-35), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX468).

[1029] In compound (L-35), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX469).

[1030] In compound (L-35), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX470).

[1031] In compound (L-35), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX471).

[1032] In compound (L-35), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX472).

[1033] [Chemical Formula 54]

[1034]

[1035] In the compound represented by formula (L-36) (hereinafter referred to as compound (L-36)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX473).

[1036] In compound (L-36), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX474).

[1037] In compound (L-36), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX475).

[1038] In compound (L-36), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX476).

[1039] In compound (L-36), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX477).

[1040] In compound (L-36), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX478).

[1041] In compound (L-36), R 2a and R 2b It is methyl, R 3b For hydrogen atoms, R3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX479).

[1042] In compound (L-36), R 2a and R 2b It is methyl, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX480).

[1043] [Chemical Formula 55]

[1044]

[1045] In the compound represented by formula (L-37) (hereinafter referred to as compound (L-37)), R 2a and R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX481).

[1046] In compound (L-37), R 2a and R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX482).

[1047] In compound (L-37), R 2a It is methyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3d The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX483).

[1048] In compound (L-37), R 2a It is methyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX484).

[1049] In compound (L-37), R 2a For ethyl, R 2b For hydrogen atoms, R 3b For hydrogen atoms, R 3dThe compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group SX485).

[1050] In compound (L-37), R 2a For ethyl, R 2b For hydrogen atoms, R 3d For hydrogen atoms, R 3b The compounds listed in [Table 7A] to [Table 15A] with any substituents (hereinafter referred to as compound group S...

Claims

1. A compound represented by formula (I) or an N-oxide thereof, [Chemical formula 1] In formula (I), Q shown in the following formula represents a group shown in formula Q1, a group shown in formula Q2, a group shown in formula Q3, a group shown in formula Q4, a group shown in formula Q5, a group shown in formula Q6, or a group shown in formula Q7 (# represents a bonding site with a sulfur atom, ● represents a bonding site with Het), [Chemical formula 2] [Chemical formula 3] A 1 Indicates NR 5 , oxygen atoms or sulfur atoms, G 1 , G 2 , G 3 and G 4 The combination of: G 1 is a nitrogen atom or CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c combination of; G 1 CR 3a , G 2 is a nitrogen atom, G 3 CR 3d , G 4 CR 3c combination of; G 1 CR 3a , G 2 CR 3b , G 3 is a nitrogen atom, G 4 CR 3c or G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 is the combination of nitrogen atoms, R 2a and R 2b are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom; or R 2a and R 2b Together with the nitrogen atom to which they are bound, they may form an aziridinyl, azetidinyl, pyrrolidinyl or piperidinyl group, R 3a , R 3b , R 3c , R 3d , R 3f , R 3g , R 3i and R 3k are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group B, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group E, a phenyl group which may be substituted by one or more substituents selected from group H, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group H, or an OR 12 NR 11 R 12 NR 11a R 12a NR 24 NR 11 R 12 NR 24 OR 11 NR 11 C(O)R 13 NR 24 NR 11 C(O)R 13 NR 11 C(O)OR 14 NR 24 NR 11 C(O)OR 14 NR 11 C(O)NR 31 R 32 NR 24 NR 11 C(O)NR 31 R 32 、N=CHNR 31 R 32 、N=S(O) p R 15 R 16 、C(O)R 13 、C(O)OR 17 、C(O)NR 31 R 32 、C(O)NR 11 S(O)2R 23 , CR 30 =NOR 17 NR 11 CR 24 =NOR 17 、S(O) q R 23 , cyano group, nitro group, hydrogen atom or halogen atom, R 3e and R 3h are the same or different from each other and represent a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group H, When Q is a group represented by the formula Q1, R 3a , R 3b and R 3d The two adjacent substituents in the may form, together with the two carbon atoms to which they are bonded, a benzene ring, a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, an oxazole ring, an isoxazole ring, a thiazole ring, an isothiazole ring, an oxadiazole ring, a thiadiazole ring, a pyridine ring, a pyridazine ring, a pyrimidine ring, a pyrazine ring {the benzene ring, the pyrrole ring, the furan ring, the thiophene ring, the pyrazole ring, the imidazole ring, the oxazole ring, the isoxazole ring, the thiazole ring, the isothiazole ring, the pyridine ring, the pyridazine ring, the pyrimidine ring and the pyrazine ring may be substituted with one or more substituents selected from Group H}, or a triazole ring which may be substituted with one or more substituents selected from Group I, p represents 0 or 1, q represents 0, 1 or 2, R 30 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a halogen atom, or OR 35 NR 36 R 37 or hydrogen atoms, R 17 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group D, or a hydrogen atom, R 12 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from group J, a C3-C7 cycloalkenyl group which may be substituted by one or more substituents selected from group J, a phenyl group which may be substituted by one or more substituents selected from group D, a 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a hydrogen atom or S(O)2R 23 , R 23 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group D, R 11a and R 12a Together with the nitrogen atom to which they are bonded, they form a 3-7 membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from Group E, R 13 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from Group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from Group D, or a hydrogen atom, R 14 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted with one or more halogen atoms, a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms, or a phenyl C1-C3 alkyl group {the phenyl moiety in the phenyl C1-C3 alkyl group may be substituted with one or more substituents selected from Group D}, R 15 and R 16 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, R 31 represents a C1-C6 alkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom, R 32 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group F, a C3-C7 cycloalkyl group which may be substituted by one or more substituents selected from Group J, or a hydrogen atom, Het represents a group represented by formula Het5, a group represented by formula Het6, or a group represented by formula Het7, [Chemical formula 4] A 2 Indicates NR 5a or CR 4a R 4d , A 3 Represents CR 4b R 4e , A 4 Indicates NR 5b or CR 4c R 4f , W 1 represents an oxygen atom or a sulfur atom, When Het is a group represented by the formula Het5, B 1 , B 2 and B 3 The combination of: B 1 CR 6e , B 2 is a nitrogen atom or CR 6b , B 3 is a nitrogen atom or CR 6c combination of; B 1 is a nitrogen atom or CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c or B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6e A combination of When Het is a group represented by the formula Het6, A 2 and A 4 The combination of: A 2 CR 4a R 4d , A 4 NR 5b or CR 4c R 4f or A 2 NR 5a , A 4 CR 4c R 4f combination of; B 1 , B 2 and B 3 The combination of: B 1 CR 6e , B 2 is a nitrogen atom or CR 6b , B 3 is a nitrogen atom or CR 6c combination of; B 1 is a nitrogen atom or CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c or B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6e A combination of When Het is a group represented by the formula Het7, A 2 and A 4 The combination of: A 2 CR 4a R 4d , A 4 NR 5b or CR 4c R 4f or A 2 NR 5a , A 4 CR 4c R 4f combination of; B 1 , B 2 , B 3 and B 4 The combination of: B 1 is a nitrogen atom or CR 6a , B 2 CR 6e , B 3 is a nitrogen atom or CR 6c , B 4 is a nitrogen atom or CR 6d combination of; B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6e , B 4 is a nitrogen atom or CR 6d combination of; B 1 is a nitrogen atom or CR 6a , B 2 is a nitrogen atom or CR 6b , B 3 CR 6c , B 4 CR 6e combination of; B 1 is a nitrogen atom or CR 6a , B 2 CR 6b , B 3 is a nitrogen atom, B 4 CR 6e or B 1 CR 6a , B 2 is a nitrogen atom, B 3 is a nitrogen atom, B 4 CR 6e A combination of R 4a , R 4b , R 4c , R 6a , R 6b , R 6c and R 6d The same or different, representing a C1-C6 chain hydrocarbon group, nitro group, OR 18 NR 18 R 19 , cyano group, amino group, halogen atom or hydrogen atom, R 4d , R 4e and R 4f are the same or different from each other and represent a C1-C6 chain hydrocarbon group, a cyano group, a halogen atom or a hydrogen atom which may be substituted with one or more halogen atoms, R 6e represents a C1-C6 chain hydrocarbon group substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, a C3-C4 cycloalkyl group which may be substituted by one or more substituents selected from the group consisting of a cyano group and a halogen atom, S(O) m R 7 , OR 7 , halogen atom or OS(O)2R 7 , R 5 represents a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, R 5a and R 5b are the same or different from each other and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from group K, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, a (C3-C7 cycloalkyl)C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, R 7 represents a C1-C6 chain hydrocarbon group substituted by one or more halogen atoms, m represents 0, 1 or 2, R 18 and R 35 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, R 11 , R 19 , R 24 , R 36 and R 37 are the same or different from each other, and represent a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, or a hydrogen atom, Group B: the group consisting of C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfanyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl groups which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl groups which may be substituted by one or more halogen atoms, C3-C6 cycloalkyl groups which may be substituted by one or more halogen atoms, cyano groups, hydroxyl groups and halogen atoms. Group C: a group consisting of a C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, a C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, and a halogen atom, Group D: C1-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, hydroxyl group, C1-C6 alkoxy group which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy group which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy group which may be substituted by one or more halogen atoms, sulfanyl group, C1-C6 alkylsulfanyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfinyl group which may be substituted by one or more halogen atoms, C1-C6 alkylsulfonyl group which may be substituted by one or more halogen atoms, amino group, NHR 21 NR 21 R 22 、C(O)R 21 、OC(O)R 21 、C(O)OR 21 , cyano, nitro and halogen atoms, R 21 and R 22 are the same or different from each other and represent a C1-C6 alkyl group which may be substituted by one or more halogen atoms, Group E: the group consisting of C1-C6 chain hydrocarbon groups which may be substituted by one or more halogen atoms, C1-C6 alkoxy groups which may be substituted by one or more halogen atoms, C3-C6 alkenyloxy groups which may be substituted by one or more halogen atoms, C3-C6 alkynyloxy groups which may be substituted by one or more halogen atoms, halogen atoms, oxo groups, hydroxyl groups, cyano groups and nitro groups, Group F: C1-C6 alkoxy which may be substituted with one or more halogen atoms, phenyl which may be substituted with one or more substituents selected from group D, 5- or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group D, C3-C7 cycloalkyl which may be substituted with one or more halogen atoms, 3-7-membered non-aromatic heterocyclic group which may be substituted with one or more substituents selected from group C, amino, NHR 21 NR 21 R 22 , a group consisting of a halogen atom and a cyano group, Group H: C1-C6 alkyl which may be substituted with one or more halogen atoms, OR 10 NR 9 R 10 、C(O)R 10 、C(O)NR 9 R 10 、OC(O)R 9 、OC(O)OR 9 NR 10 C(O)R 9 NR 10 C(O)OR 9 、C(O)OR 10 , a halogen atom, a nitro group, a cyano group, an amino group and a 5- or 6-membered aromatic heterocyclic group, R 9 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, R 10 represents a C1-C6 alkyl group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, or a hydrogen atom, Group I: a group consisting of a C2-C6 chain hydrocarbon group which may be substituted by one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a C2-C6 alkylcarbonyl group which may be substituted by one or more halogen atoms, a C2-C6 alkoxycarbonyl group which may be substituted by one or more halogen atoms, an aminocarbonyl group, a (C1-C6 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, a methyl group, and a di(C1-C4 alkyl)aminocarbonyl group which may be substituted by one or more halogen atoms, Group J: a group consisting of a C1-C6 alkyl group which may be substituted with one or more halogen atoms, a halogen atom and a cyano group, Group K: a group consisting of a C1-C6 alkoxy group which may be substituted by one or more halogen atoms, a phenyl group which may be substituted by one or more substituents selected from group D, a 5- or 6-membered aromatic heterocyclic group which may be substituted by one or more substituents selected from group D, a C3-C7 cycloalkyl group which may be substituted by one or more halogen atoms, and a 3-7-membered non-aromatic heterocyclic group which may be substituted by one or more substituents selected from group C.

2. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by formula Q2, a group represented by formula Q3, or a group represented by formula Q4.

3. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q1 or a group represented by the formula Q5.

4. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by the formula Q5.

5. The compound or N-oxide thereof according to claim 1, wherein Q is a group represented by formula Q5, G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c .

6. The compound or N-oxide thereof as described in [1], wherein: Q is a group represented by formula Q5, G 1 CR 3a , G 2 CR 3b , G 3 CR 3d , G 4 CR 3c , R 3a is a hydrogen atom, R 3b is a C1-C6 chain hydrocarbon group, a hydrogen atom or a halogen atom which may be substituted by one or more substituents selected from Group B, R 3c is a hydrogen atom, R 3d It is a C1-C6 chain hydrocarbon group which may be substituted by one or more substituents selected from Group B, a hydrogen atom or a halogen atom.

7. The compound or N-oxide thereof according to any one of claims 1 to 6, wherein Het is a group represented by the formula Het7, A 2 CR 4a R 4d , A 4 NR 5b , W 1 For oxygen atoms. 8 . A harmful arthropod control composition comprising an inactive carrier and the compound or N-oxide thereof according to claim 1 .

9. A composition comprising one or more components selected from the group consisting of group (a), group (b), group (c) and group (d), and the compound or N-oxide thereof according to any one of claims 1 to 7, Group (a): a group consisting of insecticidal active ingredients, acaricidal active ingredients and nematicidal active ingredients; Group (b): fungicidal active ingredients; Group (c): plant growth regulating ingredients; Group (d): repellent ingredients.

10. A method for controlling harmful arthropods, wherein: An effective amount of the compound or N-oxide thereof according to any one of claims 1 to 7 or an effective amount of the composition according to claim 9 is applied to a harmful arthropod or a habitat of a harmful arthropod.

11. A seed or a vegetative propagation organ, which holds an effective amount of the compound according to any one of claims 1 to 7 or an N-oxide thereof, or an effective amount of the composition according to claim 9.

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