A solid state hydrogen storage device
By designing a specific structure in the solid-state hydrogen storage device, the full reaction and uniform dispersion of hydrogen with magnesium-based hydrogen storage materials are ensured, solving the problem of insufficient reaction between magnesium-based hydrogen storage materials and hydrogen, and improving the storage capacity and release efficiency of hydrogen.
Patent Information
- Application Number
- CN202510262533.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2025-03-06
- Publication Date
- 2025-12-30
- Estimated Expiration
- 2045-03-06
AI Technical Summary
In existing technologies, magnesium-based hydrogen storage materials do not react sufficiently with hydrogen, resulting in low hydrogen storage capacity.
A solid-state hydrogen storage device was designed. Through structures such as an inlet pipe, a connecting pipe, a jet pipe, a drive blade, and a stirring blade, hydrogen is ensured to be uniformly dispersed and fully react with magnesium-based hydrogen storage material. The release of hydrogen is controlled by a heating plate and an isolation cover structure.
This increased the hydrogen storage capacity and release efficiency, enhancing the practical value of the device.
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Figure CN120083911B_ABST
Abstract
Description
Technical Field
[0001] This invention relates to the field of solid-state hydrogen storage technology, specifically to a solid-state hydrogen storage device. Background Technology
[0002] Hydrogen energy is a green energy source with advantages such as wide availability, high energy density, large-scale storage capability, and clean, low-carbon operation, making it considered the most ideal "ultimate energy source" for humankind. Among these technologies, solid-state hydrogen storage (SSD) using hydrides has shown remarkable performance in recent years, offering advantages such as high volumetric hydrogen storage density, low pressure, and safe storage and transportation. However, it places high demands on storage materials, making it more suitable for stationary hydrogen storage. With significant improvements in the performance of storage materials, SSDs have demonstrated excellent application prospects and potential in high-safety hydrogen refueling (storage) stations.
[0003] However, in current hydrogen storage, the magnesium-based hydrogen storage material powder is placed directly in the storage tank, allowing the hydrogen to react with the magnesium-based hydrogen storage material on its own. However, due to the stacking of the magnesium-based hydrogen storage material, the hydrogen cannot fully react with the magnesium-based hydrogen storage material, resulting in a low hydrogen storage capacity. Summary of the Invention
[0004] To address the deficiencies in existing technologies, this invention provides a solid-state hydrogen storage device, comprising a tank body. An inlet pipe is fixedly installed through the top of the tank body, and an outlet pipe is fixedly installed through the top of the tank body on one side of the inlet pipe. A partition plate is fixedly installed inside the tank body below the inlet pipe, and a fixed plate is fixedly installed inside the tank body below the partition plate. A rotating shaft is rotatably connected through the middle of the partition plate to a shaft located directly below the inlet pipe. A drive blade is fixedly installed at the top of the rotating shaft above the partition plate. A jet pipe with its end facing the drive blade is fixedly installed at the bottom of the outer circumference of the inlet pipe. A stirring blade is fixedly installed on the outer circumference of the rotating shaft above the fixed plate. A connecting pipe is fixedly installed inside the side wall of the tank body. A gas guide pipe located above the partition plate is integrally connected to the top of the connecting pipe, and a dispersion pipe penetrating into the fixed plate is integrally connected to one side of the connecting pipe. An outlet hole is provided at the bottom of the dispersion pipe.
[0005] Preferably, a fixed circular plate is fixedly installed at the bottom of the fixed plate below the dispersion tube, the air outlet is through the fixed circular plate, the bottom of the air outlet is flush with the bottom of the fixed circular plate, and a heating plate is fixedly installed at the top of the fixed plate, the top of the heating plate is flush with the top of the fixed plate.
[0006] Preferably, a set of dispersion tubes are provided through the bottom of the partition, a fixed circular plate located below the dispersion tubes is fixedly installed at the bottom of the partition, and a heating plate is fixedly installed at the bottom of the tank body.
[0007] Preferably, the intake pipe has a movable groove in the middle located above the jet pipe, and a sealing ring is integrally formed inside the intake pipe located above the movable groove. The movable groove is located inside the tank body, and a connecting plate is slidably connected inside the movable groove. A connecting post that passes through the sealing ring is fixedly installed on the top of the connecting plate, and a sealing plate is integrally connected to the top of the connecting post.
[0008] Preferably, the diameter of the inner annular surface of the sealing ring is larger than the diameter of the connecting column, the diameter of the sealing sheet is larger than the diameter of the inner annular surface of the sealing ring, and a rubber sealing ring is provided on the contact surface between the sealing sheet and the sealing ring.
[0009] Preferably, a sealing sleeve located outside the air intake pipe is connected to the outer peripheral surface of the connecting plate. The sealing sleeve is slidably fitted with the outer peripheral surface of the air intake pipe. An isolation cover is integrally connected to the bottom of the outer peripheral surface of the sealing sleeve. The diameter of the isolation cover is larger than the diameter of the drive blade.
[0010] Preferably, the bottom of the vent pipe is slidably connected to the top of the isolation cover, the top of the partition is fixedly installed with a sealing groove located directly below the isolation cover, a sealing ring is provided inside the sealing groove, the bottom of the vent pipe is higher than the jet pipe, and a valve located outside the tank is provided at the top of the vent pipe.
[0011] Preferably, a bidirectional lead screw located directly above the isolation cover is rotatably connected to the top of the tank body. A clamping motor located at one end of the bidirectional lead screw is fixedly installed on the top of the tank body. The output end of the clamping motor is fixedly installed to one end of the bidirectional lead screw. The bidirectional lead screw is threadedly connected to two symmetrical moving blocks. Support rods are rotatably mounted on both sides of the moving blocks. The other end of the support rods is rotatably connected to the top of the isolation cover.
[0012] Preferably, the inside of the tank is uniformly fixedly installed with fixed plates located below the partition, the distance between adjacent fixed plates is the same, and the top of the fixed plates is filled with powdered magnesium-based hydrogen storage material.
[0013] Preferably, the bottom of the stirring blade is higher than the top of the heating plate, the width of the stirring blade is less than half the distance between adjacent fixed plates, and the stirring blade is an inclined elongated shape.
[0014] The beneficial effects of this invention are reflected in:
[0015] 1. This solid-state hydrogen storage device, by setting an inlet pipe and a connecting pipe, allows hydrogen gas to enter the upper part of the internal partition of the tank through the inlet pipe, enter the connecting pipe and the dispersion pipe through the gas guide pipe, and be sprayed out through the gas outlet onto the powdered magnesium-based hydrogen storage material fixed above. Several gas outlets evenly dispersed below the fixed plate evenly spray the hydrogen gas transported by the inlet pipe onto the powdered magnesium-based hydrogen storage material, so that the hydrogen gas and the magnesium-based hydrogen storage material can react fully, thereby increasing the hydrogen storage capacity of the device.
[0016] 2. This solid-state hydrogen storage device, by setting up a jet nozzle and a drive blade, sprays hydrogen gas through the jet pipe onto the drive blade, causing the drive blade to rotate, which in turn drives the rotating shaft to rotate, thereby causing the stirring blade to rotate, stirring the powdered magnesium-based hydrogen storage material above the fixed plate, so that the hydrogen gas can fully react with the magnesium-based hydrogen storage material, further increasing the hydrogen storage capacity and improving the practical value of the device.
[0017] 3. This solid hydrogen storage device, by setting up an isolation cover, a pressing motor drives a bidirectional lead screw to rotate, which in turn moves a moving block, causing the support rod to push the isolation cover down to seal the groove. At the same time, the sealing sleeve moves down to expose the movable groove. Simultaneously, the connecting plate and connecting column pull the sealing plate down to seal it against the sealing ring. The heating plate heats the magnesium-based hydrogen storage material, causing the hydrogen stored in the magnesium-based hydrogen storage material to overflow. The overflowing hydrogen enters the interior of the isolation cover through the movable groove and the jet pipe, and is then discharged through the gas outlet pipe.
[0018] 4. This solid hydrogen storage device, by setting up a stirring blade, when the heating plate heats the magnesium-based hydrogen storage material, hydrogen gas is sprayed out through the jet pipe to drive the blade to rotate, thereby driving the stirring blade to stir the heated magnesium-based hydrogen storage material, so that the magnesium-based hydrogen storage material can be fully heated and the stored hydrogen gas can be completely released. Attached Figure Description
[0019] To more clearly illustrate the specific embodiments of the present invention or the technical solutions in the prior art, the accompanying drawings used in the description of the specific embodiments or the prior art will be briefly introduced below. In all the drawings, similar elements or parts are generally identified by similar reference numerals. In the drawings, the elements or parts are not necessarily drawn to scale.
[0020] Figure 1 This is a schematic diagram of the overall structure of the present invention;
[0021] Figure 2 This is a schematic diagram of the partition structure of the present invention;
[0022] Figure 3 This is a schematic diagram of the structure of the fixing plate of the present invention;
[0023] Figure 4 This is a schematic diagram of the dispersion tube of the present invention;
[0024] Figure 5 This is a schematic diagram of the structure of the isolation cover of the present invention;
[0025] Figure 6 This is a schematic diagram of the intake pipe of the present invention;
[0026] Figure 7 This is a schematic diagram of the tank body of the present invention;
[0027] Figure 8 This is a schematic diagram of the bidirectional lead screw of the present invention.
[0028] In the attached diagram: 1. Tank body; 2. Inlet pipe; 3. Outlet pipe; 4. Fixing plate; 5. Partition plate; 6. Connecting pipe; 7. Guide pipe; 8. Dispersion pipe; 9. Outlet hole; 10. Fixing circular plate; 11. Heating plate; 12. Rotating shaft; 13. Stirring blade; 14. Drive blade; 15. Sealing groove; 16. Movable groove; 17. Jet pipe; 18. Connecting plate; 19. Connecting column; 20. Sealing sheet; 21. Isolation cover; 22. Sealing ring; 23. Two-way lead screw; 24. Pressing motor; 25. Moving block; 26. Support rod; 27. Sealing sleeve. Detailed Implementation
[0029] The embodiments of the technical solution of the present invention will now be described in detail with reference to the accompanying drawings. These embodiments are merely illustrative of the technical solution of the present invention and are therefore intended to limit the scope of protection of the present invention.
[0030] It should be noted that, unless otherwise stated, the technical or scientific terms used in this application should have the ordinary meaning as understood by one of ordinary skill in the art to which this invention pertains.
[0031] Please see Figures 1 to 8A solid hydrogen storage device includes a tank 1. An inlet pipe 2 is fixedly installed through the top of the tank 1. An outlet pipe 3 is fixedly installed through the top of the tank 1 on one side of the inlet pipe 2. A partition 5 is fixedly installed inside the tank 1 below the inlet pipe 2. A fixed plate 4 is fixedly installed inside the tank 1 below the partition 5. A rotating shaft 12 located directly below the inlet pipe 2 is rotatably connected through the middle of the partition 5. A drive blade 14 located above the partition 5 is fixedly installed at the top of the rotating shaft 12. A jet pipe 17 with its end facing the drive blade 14 is fixedly installed at the bottom of the outer periphery of the inlet pipe 2. A stirring blade 13 located above the fixed plate 4 is fixedly installed on the outer periphery of the rotating shaft 12. A connecting pipe 6 is fixedly installed inside the side wall of the tank 1. A gas guide pipe 7 located above the partition 5 is integrally connected to the top of the connecting pipe 6. A dispersion pipe 8 penetrating into the interior of the fixed plate 4 is integrally connected to one side of the connecting pipe 6. An outlet is provided at the bottom of the dispersion pipe 8. Through the inlet pipe 2 and connecting pipe 6, hydrogen enters the tank 1 from above the internal partition 5 via the inlet pipe 2, then enters the connecting pipe 6 and the dispersion pipe 8 via the guide pipe 7, and is sprayed out through the outlet 9 onto the powdered magnesium-based hydrogen storage material above the fixed plate. Several outlets 9 evenly distributed below the fixed plate 4 spray the hydrogen delivered by the inlet pipe 2 onto the powdered magnesium-based hydrogen storage material, allowing the hydrogen to react fully with the magnesium-based hydrogen storage material, thereby increasing the hydrogen storage capacity of the device. Through the jet nozzle and drive blade 14, hydrogen is sprayed out through the jet pipe 17 onto the drive blade 14, causing the drive blade 14 to rotate, which in turn drives the rotating shaft 12 to rotate, thereby driving the stirring blade 13 to rotate, stirring the powdered magnesium-based hydrogen storage material above the fixed plate 4, thus allowing the hydrogen to react fully with the magnesium-based hydrogen storage material, further increasing the hydrogen storage capacity and improving the practical value of the device.
[0032] In one embodiment of the present invention, a fixed circular plate 10 located below the dispersion tube 8 is fixedly installed on the bottom of the fixed plate 4, and the air outlet 9 is disposed through the fixed circular plate 10. The bottom of the air outlet 9 is flush with the bottom of the fixed circular plate 10. A heating plate 11 is fixedly installed on the top of the fixed plate 4, and the top of the heating plate 11 is flush with the top of the fixed plate 4.
[0033] In one embodiment of the present invention, a set of dispersion tubes 8 are provided through the bottom of the partition 5, and a fixed circular plate 10 located below the dispersion tubes 8 is fixedly installed at the bottom of the partition 5, and a heating plate 11 is fixedly installed at the bottom inside the tank 1.
[0034] In one embodiment of the present invention, the middle part of the air intake pipe 2 is provided with a movable groove 16 located above the jet pipe 17. A sealing ring 22 located above the movable groove 16 is integrally provided inside the air intake pipe 2. The movable groove 16 is located inside the tank body 1. A connecting plate 18 is slidably connected inside the movable groove 16. A connecting post 19 that penetrates the sealing ring 22 is fixedly installed on the top of the connecting plate 18. A sealing sheet 20 is integrally connected to the top of the connecting post 19.
[0035] In one embodiment of the present invention, the diameter of the inner annular surface of the sealing ring 22 is larger than the diameter of the connecting column 19, and the diameter of the sealing sheet 20 is larger than the diameter of the inner annular surface of the sealing ring 22. A rubber sealing ring is provided on the contact surface between the sealing sheet 20 and the sealing ring 22. By setting the isolation cover 21, the pressing motor 24 drives the bidirectional lead screw 23 to rotate, which drives the moving block 25 to move, so that the support rod 26 pushes the isolation cover 21 down to seal the sealing groove 15. At the same time, the sealing sleeve 27 moves down to expose the movable groove 16. At the same time, the sealing sheet 20 is pulled down by the connecting plate 18 and the connecting column 19 to seal the sealing sheet 20 against the sealing ring 22. The heating plate 11 heats the magnesium-based hydrogen storage material, causing the hydrogen stored in the magnesium-based hydrogen storage material to overflow. The overflowed hydrogen enters the interior of the isolation cover 21 through the movable groove 16 and the jet pipe 17, and is then discharged through the gas outlet pipe 3.
[0036] In one embodiment of the present invention, a sealing sleeve 27 located outside the air intake pipe 2 is connected to the outer peripheral surface of the connecting plate 18. The sealing sleeve 27 is slidably connected to the outer peripheral surface of the air intake pipe 2. An isolation cover 21 is integrally connected to the bottom of the outer peripheral surface of the sealing sleeve 27. The diameter of the isolation cover 21 is larger than the diameter of the drive blade 14.
[0037] In one embodiment of the present invention, the bottom of the vent pipe 3 is slidably connected to the top of the isolation cover 21, the top of the partition plate 5 is fixedly installed with a sealing groove 15 located directly below the isolation cover 21, a sealing ring is provided inside the sealing groove 15, the bottom of the vent pipe 3 is higher than the jet pipe 17, and a valve located outside the tank body 1 is provided at the top of the vent pipe 3.
[0038] In one embodiment of the present invention, a bidirectional lead screw 23 located directly above the isolation cover 21 is rotatably connected to the top of the inside of the tank body 1. A pressure motor 24 located at one end of the bidirectional lead screw 23 is fixedly installed on the top of the inside of the tank body 1. The output end of the pressure motor 24 is fixedly installed to one end of the bidirectional lead screw. Two symmetrical moving blocks 25 are threadedly connected through the bidirectional lead screw. Support rods 26 are rotatably connected to both sides of the moving blocks 25. The other end of the support rods 26 is rotatably connected to the top of the isolation cover 21.
[0039] In one embodiment of the present invention, a fixing plate 4 located below the partition 5 is uniformly fixedly installed inside the tank body 1, the distance between adjacent fixing plates 4 is the same, and the top of the fixing plate 4 is filled with powdered magnesium-based hydrogen storage material.
[0040] In one embodiment of the present invention, the bottom of the stirring blade 13 is higher than the top of the heating plate 11, the width of the stirring blade 13 is less than half the distance between the adjacent fixed plates 4, and the stirring blade 13 is an inclined strip. By setting the stirring blade 13, when the heating plate 11 heats the magnesium-based hydrogen storage material, the hydrogen gas sprayed through the jet pipe 17 drives the blade 14 to rotate, thereby driving the stirring blade 13 to stir the heated magnesium-based hydrogen storage material, so that the magnesium-based hydrogen storage material can be fully heated and the stored hydrogen gas can be completely released.
[0041] It should be noted that during use, hydrogen enters the tank 1 through the inlet pipe 2 above the internal partition 5, then through the gas guide pipe 7 into the connecting pipe 6 and the dispersion pipe 8, and is sprayed out through the outlet 9 onto the powdered magnesium-based hydrogen storage material above the fixed plate 4. Several outlets 9 evenly distributed below the fixed plate 4 spray the hydrogen supplied by the inlet pipe 2 evenly onto the powdered magnesium-based hydrogen storage material, allowing the hydrogen to react fully with the magnesium-based hydrogen storage material, thereby increasing the device's hydrogen storage capacity. Hydrogen is then sprayed through the jet pipe 17 onto the drive blade 14, causing the drive blade 14 to rotate. This causes the drive blade 14 to rotate the rotating shaft 12, which in turn rotates the stirring blade 13, stirring the powdered magnesium-based hydrogen storage material above the fixed plate 4. This further ensures that the hydrogen reacts fully with the magnesium-based hydrogen storage material, further increasing the hydrogen storage capacity and enhancing the practical value of the device. When releasing hydrogen, the clamping motor 24 drives the bidirectional lead screw 23 to rotate, which in turn moves the moving block 25. This causes the support rod 26 to push the isolation cover 21 down to seal the sealing groove 15. At the same time, the sealing sleeve 27 moves down to expose the movable groove 16. Simultaneously, the connecting plate 18 and the connecting column 19 pull the sealing plate 20 down to seal it against the sealing ring 22. The heating plate 11 heats the magnesium-based hydrogen storage material, causing the hydrogen stored in the material to overflow. The overflowing hydrogen enters the isolation cover 21 through the movable groove 16 and the jet pipe 17, and then exits through the outlet pipe 3. When the heating plate 11 heats the magnesium-based hydrogen storage material, the hydrogen ejected through the jet pipe 17 drives the driving blade 14 to rotate, which in turn drives the stirring blade 13 to stir the heated magnesium-based hydrogen storage material, allowing the material to be fully heated and the stored hydrogen to be completely released.
[0042] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, and not to limit them. Although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art should understand that modifications can still be made to the technical solutions described in the foregoing embodiments, or equivalent substitutions can be made to some or all of the technical features therein. Such modifications or substitutions do not cause the essence of the corresponding technical solutions to deviate from the scope of the technical solutions of the embodiments of the present invention, and they should all be covered within the scope of the claims and specification of the present invention.
Claims
1. A solid state hydrogen storage device comprising a canister (1), characterised in that: The top of the tank body (1) is fixedly provided with an air inlet pipe (2), the top of the tank body (1) is fixedly provided with an air outlet pipe (3) on the side of the air inlet pipe (2), the inside of the tank body (1) is fixedly provided with a partition plate (5) below the air inlet pipe (2), the inside of the tank body (1) is fixedly provided with a fixed plate (4) below the partition plate (5), the middle of the partition plate (5) is rotatably connected with a rotating shaft (12) directly below the air inlet pipe (2), the top of the rotating shaft (12) is fixedly provided with a driving paddle (14) above the partition plate (5), the bottom of the outer circumferential surface of the air inlet pipe (2) is fixedly provided with a jet pipe (17) with the tail end facing the driving paddle (14), the outer circumferential surface of the rotating shaft (12) is fixedly provided with a stirring paddle (13) above the fixed plate (4), the inside of the side wall of the tank body (1) is fixedly provided with a connecting pipe (6), the top of the connecting pipe (6) is integrally connected with an air guide pipe (7) above the partition plate (5), one side of the connecting pipe (6) is integrally connected with a dispersing pipe (8) penetrating into the inside of the fixed plate (4), and the bottom of the dispersing pipe (8) is provided with an air outlet hole (9); The middle of the air inlet pipe (2) is provided with a movable groove (16) above the jet pipe (17), the inside of the air inlet pipe (2) is integrally provided with a sealing ring (22) above the movable groove (16), the movable groove (16) is located in the inside of the tank body (1), the inside of the movable groove (16) is slidably connected with a connecting plate (18), the top of the connecting plate (18) is fixedly provided with a connecting column (19) penetrating through the sealing ring (22), and the top of the connecting column (19) is integrally connected with a sealing piece (20); The diameter of the inner circumferential surface of the sealing ring (22) is greater than the diameter of the connecting column (19), the diameter of the sealing piece (20) is greater than the diameter of the inner circumferential surface of the sealing ring (22), and the contact surface between the sealing piece (20) and the sealing ring (22) is provided with a rubber sealing ring; One side of the outer circumferential surface of the connecting plate (18) is connected with a sealing sleeve (27) located outside the air inlet pipe (2), the sealing sleeve (27) is in sealing sliding sleeve connection with the outer circumferential surface of the air inlet pipe (2), the bottom of the outer circumferential surface of the sealing sleeve (27) is integrally connected with an isolation cover (21), and the diameter of the isolation cover (21) is greater than the diameter of the driving paddle (14); The bottom of the air outlet pipe (3) is in penetrating sliding connection with the top of the isolation cover (21), the top of the partition plate (5) is fixedly provided with a sealing groove (15) directly below the isolation cover (21), the inside of the sealing groove (15) is provided with a sealing ring, the bottom of the air outlet pipe (3) is higher than the jet pipe (17), and the top of the air outlet pipe (3) is provided with a valve located outside the tank body (1). The top of the inside of the tank body (1) is rotatably connected with a bidirectional screw rod (23) above the isolation cover (21), the top of the inside of the tank body (1) is fixedly installed with a pressing motor (24) at one end of the bidirectional screw rod (23), the output end of the pressing motor (24) is fixedly installed with one end of the bidirectional screw rod, the bidirectional screw rod is threadedly connected with two symmetrical moving blocks (25), the both sides of the moving block (25) are rotatably connected with the supporting rods (26), the other end of the supporting rod (26) is rotatably connected with the top of the isolation cover (21).
2. A solid state hydrogen storage device according to claim 1, wherein: The bottom of the fixed plate (4) is fixedly installed with a fixed circular plate (10) below the dispersion pipe (8), the air outlet (9) is penetratingly arranged with the fixed circular plate (10), the bottom of the air outlet (9) is flush with the bottom of the fixed circular plate (10), the top of the fixed plate (4) is fixedly installed with a heating plate (11), the top of the heating plate (11) is flush with the top of the fixed plate (4).
3. A solid state hydrogen storage device according to claim 1, wherein: The bottom of the partition plate (5) is penetratingly arranged with a group of dispersion pipes (8), the bottom of the partition plate (5) is fixedly installed with a fixed circular plate (10) below the dispersion pipe (8), the bottom of the inside of the tank body (1) is fixedly installed with a heating plate (11).
4. The solid state hydrogen storage device of claim 1, wherein: The inside of the tank body (1) is uniformly fixedly installed with a fixed plate (4) below the partition plate (5), the distance between adjacent fixed plates (4) is the same, the top of the fixed plate (4) is filled with powdered magnesium-based hydrogen storage material.
5. The solid state hydrogen storage device of claim 1, wherein: The bottom of the stirring paddle (13) is higher than the top of the heating plate (11), the width of the stirring paddle (13) is less than half of the distance between adjacent fixed plates (4), the stirring paddle (13) is an obliquely arranged strip.
Citation Information
Patent Citations
Solid hydrogen storage device
CN219414400U