Polyester fabric with antibacterial and moisture-absorbing functions and production process thereof

By preparing modified composite polyester fibers and functional fibers and adopting specific process flows, the problem of insufficient hygroscopicity and antibacterial properties of polyester fabrics is solved, and the efficient hygroscopicity and long-lasting antibacterial effects of the fabrics are achieved, improving the wearing experience and market competitiveness.

CN120174629APending Publication Date: 2025-06-20GONGQINGCHENG YUTONG ZHONGMIAO TEXTILE & CLOTHING CO LTD
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Patent Information

Application Number
CN202510178594.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-02-18
Publication Date
2025-06-20

AI Technical Summary

Technical Problem

Polyester fabrics have poor hygroscopicity, which leads to inability to absorb and spread in time when sweating in hot environments, causing stuffy and skin problems. At the same time, the antibacterial performance is also poor, which limits its application.

Method used

By preparing modified composite polyester fibers and functional fibers, a specific process flow is adopted, including spinning, weaving, desizing, cooking, drying and baking, and combined with amino silicone oil softener treatment, the hygroscopicity and antibacterial properties of the fabric are improved.

Benefits of technology

It significantly improves the hygroscopicity and antibacterial properties of polyester fabrics, improves wear comfort and skin-friendliness, broadens the application range of fabrics, and improves market competitiveness.

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Abstract

The invention relates to the technical field of fabrics, and discloses a polyester fabric with antibacterial and moisture-absorbing functions and a production process thereof.The polyester fabric is prepared by the steps that modified composite polyester fibers and functional fibers are spun into yarn and woven into gray fabric, the gray fabric is desized, boiled and then placed in clear water to be padded, and a fabric layer is obtained through drying and baking; the modified composite polyester fibers are prepared, so that the mechanical property of the polyester fabric is effectively improved, the durability of the polyester fabric is improved, the hygroscopicity of the fabric is enhanced, and the wearing comfort and the skin-friendly degree are improved; and antibacterial substances are introduced in a chemical bonding manner, so that the fabric still has excellent antibacterial performance after being washed for multiple times, and the probability that the antibacterial substances fall off or are separated out along with washing is reduced.
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Description

Technical Field

[0001] The invention relates to the technical field of fabrics, and in particular to a polyester fabric with antibacterial and moisture-absorbing functions and a production process thereof. Background Art

[0002] With the rapid improvement of living standards, people's demand for fabrics has gradually diversified. Polyester fabric is a synthetic fiber fabric, mainly composed of polyester fiber. Usually, in order to meet the needs of different products, it is often blended with other fibers. Polyester fiber is also called polyester fiber. The composition is polyethylene terephthalate. Fabrics made of polyester fiber have wear resistance and good elasticity, are not easy to deform, not easy to wrinkle, can maintain a good appearance, have good heat resistance, are not easy to fade, and are not easily damaged by bleaching agents, etc. However, fabrics made of polyester fiber also have shortcomings, such as poor moisture absorption. In the hot summer environment, human skin sweat cannot be absorbed in time. and diffusion, resulting in sweat retention on the skin surface causing stuffiness and discomfort. In severe cases, it may even cause skin problems, leading to eczema or prickly heat. Polyester fabrics with poor hygroscopicity will produce static electricity in a dry environment, causing the polyester fabric to absorb dust and hair, affecting the hygiene of the fabric. Polyester fabrics with poor hygroscopicity usually have poor warmth retention because the sweat on the skin surface cannot evaporate in time and takes away the heat. In addition, polyester fabrics have poor antibacterial properties. Due to poor hygroscopicity, sweat is retained on the fabric surface, creating a humid growth environment for bacteria and other microorganisms. Therefore, the shortcomings of polyester fabrics limit their application, and the modification of polyester fabrics is worthy of study.

[0003] The patent with publication number CN110606944B discloses a mildew-proof polyester with high washing resistance and a preparation method thereof. The mildew-proof polyester uses terephthalic acid and ethylene glycol as starting materials. After the esterification reaction of terephthalic acid and ethylene glycol is completed, a modifier is added to participate in the polymerization reaction to obtain a modified mildew-proof polyester. Organic silicon and quaternary ammonium salt are introduced in a chemically bonded manner. The N positive ions in the quaternary ammonium salt are combined on the fiber surface in the form of chemical bonds, thereby attracting negatively charged fungi and bacteria to restrain the activity of the bacteria and enter through the bacterial cell membrane. In its cells, it destroys the metabolism of enzymes in bacteria and causes cell death, thereby achieving the effect of sterilization or inhibiting bacterial growth. It is combined in the form of chemical bonds and is not easy to fall off. It has strong wash resistance and can maintain the antibacterial and mildew-proof properties of polyester fabrics for a long time. However, this patent does not take into account the poor hygroscopicity of polyester fabrics, which will cause discomfort, promote the breeding and reproduction of bacteria, and limit the application of polyester fabrics. Therefore, the present invention provides a polyester fabric with antibacterial and hygroscopic functionality, which has excellent hygroscopicity and antibacterial properties, broadens the application range of polyester fabrics, and improves the wearing experience. Summary of the invention

[0004] To solve the problems mentioned in the background art, the object of the present invention is to provide a polyester fabric with antibacterial and moisture-absorbing functions and its production process.

[0005] The object of the present invention can be achieved by the following technical solutions:

[0006] A production process of a polyester fabric with antibacterial and moisture-absorbing functions, comprising the following steps:

[0007] The first step: Prepare modified composite polyester fibers and functional fibers respectively;

[0008] The second step: Place 75-85 parts by weight of modified composite polyester fibers and 30-40 parts of functional fibers in a spinning machine to spin into yarns, and then place the two spun yarns in a weaving machine to weave to obtain a grey cloth;

[0009] The third step: Place the grey cloth in an overflow machine for desizing and scouring, set the temperature at 90-105 °C, and the treatment time at 50-80 min to obtain the treated grey cloth;

[0010] The fourth step: Immerse the treated grey cloth in clear water and then roll it, dry it at a temperature of 70-85 °C for 5-15 min, and bake it at a temperature of 100-120 °C for 3-6 min to obtain a fabric layer;

[0011] The fifth step: Immerse the fabric layer in an amino silicone softener at room temperature and roll it, and obtain the polyester fabric after drying and cooling.

[0012] Further, the preparation method of the modified composite polyester fibers comprises the following steps:

[0013] Step A: Add polyester fibers to an acetone solution, soak for 16-18 h, then wash and dry them with deionized water, and put the dried polyester fibers into a plasma generator for treatment to obtain treated polyester fibers;

[0014] Step B: Add the treated polyester fibers to dimethyl sulfoxide, stir and mix evenly, add a halogen isocyanate modifier and catalyst A, raise the temperature to 60-75 °C, stir and react for 3-5 h, then filter, wash, and dry to obtain modified polyester fibers;

[0015] Step C: Add the modified polyester fibers and bacterial cellulose to N,N-dimethylformamide, mix evenly, add triethylamine, raise the temperature to 65-75 °C, react for 2-5 h, then separate the product, wash, and dry to obtain modified composite polyester fibers.

[0016] By adopting the above technical solution, after the polyester fiber is treated by a plasma generator, the oxygen-containing functional group hydroxyl on the surface increases, and the treated polyester fiber is obtained. Under the action of catalyst A, the hydroxyl group on the surface of the treated polyester fiber reacts with the isocyanate in the structure of the halogen isocyanate modifier, and a halogen substituent is introduced on the surface of the treated polyester fiber to obtain a modified polyester fiber. The halogen substituent on the surface of the modified polyester fiber can undergo a substitution reaction with the hydroxyl group in bacterial cellulose under the action of triethylamine to obtain a modified composite polyester fiber.

[0017] Further, in step A, the treatment by the plasma generator is to first evacuate and then introduce oxygen for treatment for 60 - 80 s, adjust the pressure to 45 - 55 Pa, and the power to 35 - 45 W.

[0018] Further, in step B, the halogen isocyanate modifier is any one of chloroethyl isocyanate, 4-chlorophenyl isocyanate or 3-chloropropyl isocyanate.

[0019] Further, in step B, the catalyst A is dibutyltin dilaurate or stannous octoate.

[0020] Further, the preparation method of the functional fiber includes the following steps:

[0021] Step T1: Add bamboo fiber into a potassium hydroxide solution, stir evenly, then raise the temperature to 40 - 45 °C, oscillate for 1 - 2 h under the condition of 100 - 200 r / min, wash, filter by suction, and dry to obtain pretreated bamboo fiber;

[0022] Step T2: Disperse the pretreated bamboo fiber in a toluene solution to form a uniform suspension, add a diglycidyl ether modifier and catalyst B, mix evenly, then raise the temperature to 60 - 70 °C, stir for 3 - 5 h, filter, wash, and dry to obtain modified bamboo fiber;

[0023] Step T3: Disperse the modified bamboo fiber in N,N-dimethylformamide to form a uniform suspension, add 2-mercaptopyridine-N-oxide and tetrabutylammonium fluoride, mix evenly, then raise the temperature to 40 - 50 °C, react for 4 - 6 h, filter by suction, wash, and dry to obtain the functional fiber.

[0024] By adopting the above technical solution, after treatment with the potassium hydroxide solution, more hydroxyl groups on the surface of bamboo fibers can be exposed, and the pores increase, obtaining pretreated bamboo fibers. The hydroxyl groups contained on the surface of the pretreated bamboo fibers can react with the epoxy groups in the structure of the diglycidyl ether modifier under the action of catalyst B, thereby introducing epoxy groups into the bamboo fibers to obtain modified bamboo fibers. Under the action of tetrabutylammonium fluoride, the epoxy groups on the surface of the modified bamboo fibers can react with the mercapto groups in the structure of 2-mercaptopyridine-N-oxide to obtain functional fibers.

[0025] Further, in step T1, the mass fraction of the potassium hydroxide solution is 10 - 15%.

[0026] Further, in step T2, the diglycidyl ether modifier is any one of ethylene glycol diglycidyl ether, neopentyl glycol diglycidyl ether, or 1,4-butanediol diglycidyl ether.

[0027] Further, in step T2, the catalyst B is boron trifluoride diethyl etherate.

[0028] A polyester fabric with antibacterial and moisture-absorbing functions is prepared by adopting the above production process.

[0029] The beneficial effects of the present invention:

[0030] (1) The modified composite polyester fiber prepared by the present invention combines polyester fiber with bacterial cellulose organically. Bacterial cellulose has high strength and high elastic modulus. On the one hand, it can improve the mechanical properties of the fabric, avoid damage caused by the decrease in strength during long-term use of the fabric, reduce the service durability of the fabric, and effectively improve the durability of the fabric; on the other hand, the porous network structure of bacterial cellulose can provide more adsorption sites for water molecules, enhance the moisture absorption performance of the fabric, contribute to the sweating and breathability of the fabric. In addition, bacterial cellulose has good skin compatibility, can improve the wearing comfort and skin-friendliness, and thus improve the market competitiveness of the polyester fabric.

[0031] (2) The functional fibers prepared by the present invention use bamboo fibers as the matrix. On the one hand, bamboo fibers have a large number of pore structures and good hygroscopicity. During the preparation process, hydrophilic hydroxyl groups are generated, enhancing the hygroscopicity and skin-friendly property. They can cooperate with the modified composite polyester fibers to improve the hygroscopicity of the polyester fabric. At the same time, bamboo fibers have good strength and toughness, which play a positive role in the mechanical properties of the fabric. On the other hand, 2-mercaptopyridine-N-oxide is a safe, efficient antibacterial substance with a broad-spectrum antibacterial effect. By introducing 2-mercaptopyridine-N-oxide into bamboo fibers through chemical bonding, this firmly bonded method can ensure that the fabric still has excellent antibacterial properties after being washed multiple times during use, avoiding the shedding or precipitation of antibacterial substances during the washing process, resulting in a reduction in antibacterial performance, the erosion of the fabric by bacteria and other microorganisms, the generation of unpleasant odors due to bacterial growth on the fabric, an increase in cleaning difficulty, and a shortening of the service life of the fabric.

[0032] Of course, it is not necessary for any product implementing the present invention to achieve all the above-mentioned advantages simultaneously. BRIEF DESCRIPTION OF THE DRAWINGS

[0033] In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the following will briefly introduce the drawings required for the description of the embodiments. Obviously, the drawings in the following description are only some embodiments of the present invention. For those of ordinary skill in the art, without creative efforts, other drawings can be obtained based on these drawings.

[0034] Figure 1 It is the infrared spectrum diagram of the modified composite polyester fiber prepared by the present invention. DETAILED DESCRIPTION OF THE EMBODIMENTS

[0035] The following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the drawings in the embodiments of the present invention. Obviously, the described embodiments are only some, rather than all, embodiments of the present invention. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative efforts fall within the scope of protection of the present invention.

[0036] The preparation methods of the modified composite polyester fibers and functional fibers in the following examples and comparative examples are as follows:

[0037] I. Preparation of Modified Composite Polyester Fibers

[0038] Step A: Add 3.2 g of polyester fibers to an acetone solution. After soaking for 16 h, wash and dry them with deionized water. Then put the dried polyester fibers into a plasma generator, evacuate first and then introduce oxygen for treatment for 80 s, adjust the pressure to 50 Pa, and the power to 45 W to obtain treated polyester fibers;

[0039] Step B: Add 3 g of treated polyester fibers into dimethyl sulfoxide. After stirring and mixing evenly, add 2 g of 3-chloropropyl isocyanate and 0.2 g of dibutyltin dilaurate. Raise the temperature to 65 °C and stir and react for 4 h. Then filter, wash, and dry to obtain modified polyester fibers.

[0040] Step C: Add 3 g of modified polyester fibers and 2.5 g of bacterial cellulose into N,N-dimethylformamide. After mixing evenly, add 1 g of triethylamine. Raise the temperature to 70 °C and react for 3 h. Then separate the product, wash, and dry to obtain modified composite polyester fibers.

[0041] Perform infrared testing on the modified composite polyester fibers. As Figure 1 shown, through analysis, an absorption peak of N-H appears at 3312 cm -1 ; an absorption peak of ester group C=O appears at 1734 cm -1 ; an absorption peak of C=O in carbamate appears at 1708 cm -1 ; an absorption peak of C-N appears at 1540 cm -1 ; an absorption peak of C-O-C appears at 1080 cm -1 ; and an absorption peak of glycosidic bond appears at 902 cm -1 .

[0042] II. Preparation of functional fibers

[0043] Step T1: Add 3.5 g of bamboo fibers into a potassium hydroxide solution with a mass fraction of 10%. After stirring evenly, raise the temperature to 45 °C and oscillate at 150 r / min for 1 h. Then wash, filter by suction, and dry to obtain pretreated bamboo fibers.

[0044] Step T2: Disperse 3.3 g of pretreated bamboo fibers in toluene solution to form a uniform suspension. Add 2 g of neopentyl glycol diglycidyl ether and 0.3 g of boron trifluoride diethyl etherate. After mixing evenly, raise the temperature to 65 °C and stir for 4 h. Then filter, wash, and dry to obtain modified bamboo fibers.

[0045] Step T3: Disperse 3 g of modified bamboo fibers in N,N-dimethylformamide to form a uniform suspension. Add 1.8 g of 2-mercaptopyridine-N-oxide and 0.2 g of tetrabutylammonium fluoride. After mixing evenly, raise the temperature to 45 °C and react for 5 h. Then filter by suction, wash, and dry to obtain functional fibers.

[0046] Weigh 0.5 g of bamboo fiber and 0.5 g of functional fiber, and use a Perkin-Elmer 2400 elemental analyzer to analyze their organic element content. From the test results, it can be seen that there is no sulfur element and nitrogen element in the bamboo fiber, while the sulfur element percentage content in the functional fiber is 8.21%, and the nitrogen element percentage content is 3.45%. It can be reasonably speculated that the bamboo fiber reacts with 2-mercaptopyridine-N-oxide, thereby providing sulfur element and nitrogen element.

[0047] Example 1

[0048] Production of polyester fabric

[0049] First step: Prepare modified composite polyester fiber and functional fiber respectively;

[0050] Second step: Place 75 g of modified composite polyester fiber and 30 g of functional fiber in a spinning machine to spin into yarns, and then place the two woven yarns in a weaving machine to weave, obtaining a grey fabric;

[0051] Third step: Place the grey fabric in an overflow machine for desizing and scouring, set the temperature at 90 °C, and the treatment time at 50 min, obtaining the treated grey fabric;

[0052] Fourth step: Immerse the treated grey fabric in clear water, then dry it at a temperature of 70 °C for 5 min, and bake it at a temperature of 100 °C for 3 min to obtain a fabric layer;

[0053] Fifth step: Immerse the fabric layer in an amino silicone softener at room temperature, and obtain the polyester fabric after drying and cooling.

[0054] Example 2

[0055] Production of polyester fabric

[0056] First step: Prepare modified composite polyester fiber and functional fiber respectively;

[0057] Second step: Place 80 g of modified composite polyester fiber and 35 g of functional fiber in a spinning machine to spin into yarns, and then place the two woven yarns in a weaving machine to weave, obtaining a grey fabric;

[0058] Third step: Place the grey fabric in an overflow machine for desizing and scouring, set the temperature at 95 °C, and the treatment time at 75 min, obtaining the treated grey fabric;

[0059] Fourth step: Immerse the treated grey fabric in clear water, then dry it at a temperature of 80 °C for 10 min, and bake it at a temperature of 110 °C for 4 min to obtain a fabric layer;

[0060] Step 5: Immerse the fabric layer in an amino silicone softener at room temperature, then pad, dry, and cool to obtain a polyester fabric.

[0061] Example 3

[0062] Production of polyester fabric

[0063] Step 1: Prepare modified composite polyester fibers and functional fibers respectively;

[0064] Step 2: Place 85 g of modified composite polyester fibers and 40 g of functional fibers in a spinning machine to spin into yarns, and then place the two spun yarns in a weaving machine to weave and obtain a grey fabric;

[0065] Step 3: Place the grey fabric in an overflow machine for desizing and scouring, set the temperature at 105 °C, and the treatment time at 80 min to obtain the treated grey fabric;

[0066] Step 4: Immerse the treated grey fabric in water, then pad, dry at 85 °C for 15 min, and bake at 120 °C for 6 min to obtain a fabric layer;

[0067] Step 5: Immerse the fabric layer in an amino silicone softener at room temperature, then pad, dry, and cool to obtain a polyester fabric.

[0068] Comparative Example 1

[0069] Production of polyester fabric

[0070] Step 1: Prepare modified composite polyester fibers;

[0071] Step 2: Place 80 g of modified composite polyester fibers in a spinning machine to spin into yarns, and then place the spun yarn in a weaving machine to weave and obtain a grey fabric;

[0072] Step 3: Place the grey fabric in an overflow machine for desizing and scouring, set the temperature at 95 °C, and the treatment time at 75 min to obtain the treated grey fabric;

[0073] Step 4: Immerse the treated grey fabric in water, then pad, dry at 80 °C for 10 min, and bake at 110 °C for 4 min to obtain a fabric layer;

[0074] Step 5: Immerse the fabric layer in an amino silicone softener at room temperature, then pad, dry, and cool to obtain a polyester fabric.

[0075] Comparative Example 2

[0076] Production of polyester fabric

[0077] Step 1: Prepare functional fibers;

[0078] Step 2: Place 80 g of polyester fiber and 35 g of functional fiber in a spinning machine to spin them into yarns, and then place the two spun yarns in a weaving machine to weave, obtaining a grey fabric;

[0079] Step 3: Place the grey fabric in an overflow machine for desizing and scouring, set the temperature at 95 °C, and the treatment time at 75 min, obtaining the treated grey fabric;

[0080] Step 4: Immerse and pad the treated grey fabric in clear water, then dry it at a temperature of 80 °C for 10 min, and bake it at a temperature of 110 °C for 4 min, obtaining a fabric layer;

[0081] Step 5: Immerse and pad the fabric layer in an amino silicone softener at room temperature, and obtain a polyester fabric after drying and cooling.

[0082] Comparative Example 3

[0083] Production of Polyester Fabric

[0084] Step 1: Prepare modified composite polyester fiber;

[0085] Step 2: Place 80 g of modified composite polyester fiber and 35 g of bamboo fiber in a spinning machine to spin them into yarns, and then place the two spun yarns in a weaving machine to weave, obtaining a grey fabric;

[0086] Step 3: Place the grey fabric in an overflow machine for desizing and scouring, set the temperature at 95 °C, and the treatment time at 75 min, obtaining the treated grey fabric;

[0087] Step 4: Immerse and pad the treated grey fabric in clear water, then dry it at a temperature of 80 °C for 10 min, and bake it at a temperature of 110 °C for 4 min, obtaining a fabric layer;

[0088] Step 5: Immerse and pad the fabric layer in an amino silicone softener at room temperature, and obtain a polyester fabric after drying and cooling.

[0089] Performance Testing

[0090] Perform performance testing on the polyester fabrics prepared in Examples 1 - 3 and Comparative Examples 1 - 3. According to the GB / T 3917.1 - 2009 standard, test the tear strength of the polyester fabrics; according to the GB / T 21655.1 - 2023 standard, test the moisture absorption performance of the polyester fabrics; using Escherichia coli as the test strain, according to the GB / T 20944.2 - 2007 standard, test the antibacterial performance of the polyester fabrics. After washing the polyester fabrics 100 times with clear water, test the antibacterial performance again. The results of each test are shown in the following table:

[0091]

[0092] As can be seen from the above table, the polyester fabrics prepared in Examples 1-3 of the present invention have excellent mechanical properties and moisture absorption properties, and still have excellent antibacterial properties after 100 washes. Comparative Example 1 is a polyester fabric made of modified composite polyester fibers, without adding functional fibers, with poor mechanical properties, good moisture absorption, and poor antibacterial properties; Comparative Example 2 is a polyester fabric made of polyester fibers and functional fibers, with better mechanical properties, poor moisture absorption, and good antibacterial properties; Comparative Example 3 is a polyester fabric made of modified composite polyester fibers and bamboo fibers, with good mechanical properties, better moisture absorption, and poor antibacterial properties.

[0093] The above content is only an example and illustration of the concept of the present invention. Those skilled in the art of the present technology can make various modifications or supplements to the specific embodiments described or use similar methods to replace them. As long as they do not deviate from the concept of the invention or exceed the scope defined by this claim book, they should all fall within the protection scope of the present invention.

Claims

1. A production process of polyester fabric with antibacterial and moisture-absorbing functions, characterized in that: The following steps are involved: The first step: preparing modified composite polyester fiber and functional fiber respectively; Step 2: Spinning 75-85 parts by weight of the modified composite polyester fiber and 30-40 parts by weight of the functional fiber into yarns in a spinning machine, and then weaving the two spun yarns in a spinning machine to obtain grey cloth; Step 3: Place the blank in an overflow machine for desizing and scouring, set the temperature to 90-105°C, and process for 50-80 minutes to obtain the treated grey cloth; Step 4: Place the treated blank in clean water for immersion and rolling, then dry it at 70-85°C for 5-15 minutes, and bake it at 100-120°C for 3-6 minutes to obtain the fabric layer; Step 5: Place the fabric layer in the amino silicone oil softener to immerse and roll at room temperature, and then dry and cool to obtain the polyester fabric.

2. The production process of a polyester fabric with antibacterial and moisture-absorbing functionality according to claim 1, characterized in that: The preparation method of the modified composite polyester fiber comprises the following steps: Step A: adding polyester fiber into an acetone solution, soaking for 16-18 hours, then washing and drying with deionized water, and placing the dried polyester fiber into a plasma generator for treatment to obtain treated polyester fiber; Step B: adding the treated polyester fiber to dimethyl sulfoxide, stirring and mixing evenly, adding the halogen isocyanate modifier and catalyst A, raising the temperature to 60-75° C., stirring and reacting for 3-5 hours, filtering, washing, and drying to obtain the modified polyester fiber; Step C: Add the modified polyester fiber and bacterial cellulose into N,N-dimethylformamide, mix well, add triethylamine, raise the temperature to 65-75°C, react for 2-5 hours, separate the product, wash and dry to obtain the modified composite polyester fiber.

3. The production process of a polyester fabric with antibacterial and moisture-absorbing functions according to claim 2, characterized in that: In step A, the plasma generator is first vacuumed and then oxygen is introduced for 60-80 seconds, the pressure is adjusted to 45-55 Pa, and the power is 35-45 W.

4. The production process of a polyester fabric with antibacterial and moisture-absorbing functions according to claim 2, characterized in that: In step B, the halogen isocyanate modifier is any one of chloroethyl isocyanate, 4-chlorophenyl isocyanate or 3-chloropropyl isocyanate.

5. The production process of a polyester fabric with antibacterial and moisture-absorbing functionality according to claim 2, characterized in that: In step B, the catalyst A is dibutyltin dilaurate or stannous octoate.

6. The production process of a polyester fabric with antibacterial and moisture-absorbing functions according to claim 1, characterized in that: The preparation method of the functional fiber comprises the following steps: Step T1: adding bamboo fiber to potassium hydroxide solution, stirring evenly, raising the temperature to 40-45° C., shaking at 100-200 r / min for 1-2 hours, washing, filtering, and drying to obtain pretreated bamboo fiber; Step T2: dispersing the pretreated bamboo fiber in a toluene solution to form a uniform suspension, adding diglycidyl ether modifier and catalyst B, mixing evenly, raising the temperature to 60-70° C., stirring for 3-5 hours, filtering, washing, and drying to obtain modified bamboo fiber; Step T3: Disperse the modified bamboo fiber in N,N-dimethylformamide to form a uniform suspension, add 2-mercaptopyridine-N-oxide and tetrabutylammonium fluoride, mix well, raise the temperature to 40-50°C, react for 4-6 hours, filter, wash, and dry to obtain functional fiber.

7. The production process of a polyester fabric with antibacterial and moisture-absorbing functions according to claim 6, characterized in that: In step T1, the mass fraction of the potassium hydroxide solution is 10-15%.

8. The production process of a polyester fabric with antibacterial and moisture-absorbing functions according to claim 6, characterized in that: In step T2, the diglycidyl ether modifier is any one of ethylene glycol diglycidyl ether, neopentyl glycol diglycidyl ether or 1,4-butanediol diglycidyl ether.

9. The production process of a polyester fabric with antibacterial and moisture-absorbing functions according to claim 6, characterized in that: In step T2, the catalyst B is boron trifluoride etherate.

10. A polyester fabric with antibacterial and moisture-absorbing properties, characterized in that: The method is prepared by the production process as claimed in claim 1.

Citation Information

Patent Citations

  • A mildew-resistant polyester with high wash resistance and its preparation method

    CN110606944B