Cosmetic

Abstract

A cosmetic material which contains an organopolysiloxane represented by formula (1), and which has excellent long-term stability and make-up persistence even when various oil agents such as silicone, hydrocarbon oils and esters, an organic ultraviolet light absorber, and an oily component that is solid at 25 DEG C are blended. # imgabs0 #

Description

Technical Field

[0001] The present invention relates to a cosmetic containing an organopolysiloxane. Background Art

[0002] Silicones such as dimethylpolysiloxane have been widely used as oils for cosmetics in recent years because of their soft and smooth feel, good spreading, excellent water repellency, and high safety.

[0003] Among them, for example, volatile cyclic siloxanes such as octamethylcyclotetrasiloxane (D4), decamethylcyclopentasiloxane (D5), and dodecamethylcyclohexasiloxane (D6) are included, and the viscosity at 25° C. is 0.65 to 2 mm 2 Cosmetics such as volatile straight-chain siloxanes with a volatile content of 1 / s and siloxane chain branched volatile siloxanes such as tris(trimethylsiloxy)methylsilane (M3T) have a soft and smooth feeling when applied to the skin, good spreading, and excellent water repellency (Patent Document 1). In particular, in cosmetics containing ingredients such as ultraviolet absorbers and solid waxes that give a sticky or heavy residual feeling, volatile silicones are used to alleviate these feelings and provide a soft and smooth feeling.

[0004] However, these volatile silicones have poor compatibility with polar oils and cannot be transparently mixed, which sometimes impairs the feel and stability of cosmetics. This tendency is particularly evident when an organic ultraviolet absorber is used. In addition, when the affinity with oily components such as waxes that are mixed for the purpose of solidifying cosmetics is low, the crystallization of the oily components is hindered, and the expected hardness of the preparation cannot be obtained.

[0005] In order to improve these problems, that is, to improve compatibility with polar oils, waxes, etc., it is also known to use phenyl-modified silicones, esters, etc. as compatibilizers. However, in these cases, due to the influence of the compatibilizer, the feel becomes heavier, and the soft and smooth feeling unique to volatile silicones is sometimes lost. In addition, these compatibilizers have a higher refractive index than silicones, so they sometimes give unnatural glare after coating. In addition, for the same purpose, octyl methyl polysiloxane, which feels lighter, is sometimes used as a compatibilizer. However, if it is used in a small amount, sufficient compatibility cannot be obtained, and if it is used in a large amount, the soft feeling of volatile silicones is sometimes still damaged.

[0006] On the other hand, Patent Document 2 proposes a composition containing one or more acyclic volatile silicone oils and having specific evaporation characteristics in order to provide an alternative to the formulation of a composition containing volatile oils. However, there is no specific description of compounding other than decamethyltetrasiloxane and dodecamethylpentasiloxane, and no research on the use of acyclic silicone oils for achieving improved compatibility with polar oils, waxes, etc. is disclosed.

[0007] In addition, Patent Document 3 discloses a study on the usability of a composition obtained by replacing a part of the methyl groups of acyclic dimethylsiloxane with ethyl groups. However, in this patent document, there is no study on improving the compatibility with polar oils, waxes, etc. when compounded in cosmetics.

[0008] Prior art documents

[0009] Patent documents

[0010] Patent Document 1: International Publication No. 2001 / 015658

[0011] Patent Document 2: International Publication No. 2004 / 087077

[0012] Patent Document 3: Specification of U.S. Patent Application Publication No. 2010 / 0144897 Summary of the invention

[0013] Problems to be solved by the invention

[0014] In view of the above actual situation, the present invention has been completed. For example, an object of the present invention is to provide a cosmetic that has excellent temporal stability and makeup persistence even when various oils such as silicone, hydrocarbon oil, and ester, an organic ultraviolet absorber, and an oily component that is solid at 25°C are compounded.

[0015] Means for solving the problems

[0016] In order to achieve the above object, the present inventors conducted in-depth research and as a result found that: by compounding the following specific organopolysiloxane in a cosmetic, the above problems can be solved, and the present invention has been completed.

[0017] Therefore, the present invention provides the following cosmetic.

[0018] 1. A cosmetic containing an organopolysiloxane represented by the following formula (1),

[0019] [Chemical formula 1]

[0020]

[0021] [In the formula, R 1 independently represents an alkyl group having 1 to 16 carbon atoms, R 2 represents an organic group represented by the following formula (2), R 3 is R 1 or R 2 , x is an integer from 0 to 50, y is an integer from 0 to 50, R 2 or R 3More than one of them is an organic group represented by the general formula (2). When y = 0, at least one R 3 is R 2 . Further, the bond of the siloxane unit surrounded by the above x and y may be block or random.

[0022] [Chemical formula 2]

[0023]

[0024] (In the formula (2), R 4 is a hydrogen atom or a methyl group,

[0025] Q is an organic group selected from the linking groups represented by the following formulas (3) to (6),

[0026] [Chemical formula 3]

[0027]

[0028] -O-CH2- (4)

[0029]

[0030] (In the above formula (5), s is an integer from 0 to 3, t is an integer from 0 to 3, and the bond of each oxyalkylene group may be block or random.)

[0031] When Q is the above formula (3), m is 8, and n is an integer from 1 to 22,

[0032] When Q is the above formula (4), m is an integer from 1 to 10, and n is an integer from 7 to 22,

[0033] When Q is the above formula (5), m is an integer from 1 to 10, and n is an integer from 7 to 22,

[0034] When Q is the above formula (6), m is an integer from 1 to 10, and n is an integer from 7 to 22.)

[0035] 2. The cosmetic according to 1, wherein the surface tension of the organopolysiloxane is 28 mN / m or less and it is non-volatile.

[0036] 3. The cosmetic according to 1 or 2, which further contains an organic ultraviolet absorber.

[0037] 4. The cosmetic according to 3, wherein the organic ultraviolet absorber is at least one selected from ethylhexyl methoxycinnamate, diethylamino hydroxybenzoyl hexyl benzoate, octyl salicylate, polysiloxane-15, tert-butyl methoxydibenzoylmethane, oxybenzone, methylene bis-benzotriazolyl tetramethylbutylphenol, bis-ethylhexyloxyphenol methoxyphenyl triazine, and octocrylene.

[0038] 5. The cosmetic according to any one of 1 to 4, which further contains an oily component that is solid at 25°C.

[0039] 6. The cosmetic according to 5, wherein the oily component that is solid at 25°C is at least one selected from polyethylene, purified ceresin, natural wax, candelilla wax, carnauba wax, beeswax, microcrystalline wax, stearyl alcohol, behenyl alcohol, and cetyl alcohol.

[0040] Effects of the Invention

[0041] According to the present invention, it is possible to provide a cosmetic that has excellent long-term stability and makeup persistence even when various oil agents such as silicone, hydrocarbon oil, and ester, an organic ultraviolet absorber, and an oily component that is solid at 25°C are blended. In addition, it is possible to impart effects as various cosmetics. Detailed Description of the Invention

[0042] Hereinafter, the present invention will be described in detail, but the present invention is not limited to these. It should be noted that in the present invention, the component names may be described using cosmetic names or International Nomenclature of Cosmetic Ingredient (INCI). When the cosmetic name corresponds to INCI, the English description or the cosmetic name description may sometimes be omitted.

[0043] [Organopolysiloxane]

[0044] The organopolysiloxane of the present invention is an organopolysiloxane represented by the following formula (1).

[0045] [Chemical Formula 4]

[0046]

[0047] [In the formula, R 1 independently represents an alkyl group having 1 to 16 carbon atoms, and R 2 is represented by the following formula (2)

[0048] [Chemical Formula 5]

[0049]

[0050] (In formula (2), R 4is a hydrogen atom or a methyl group,

[0051] Q is selected from the following formulas (3) to (6)

[0052] [Chemical formula 6]

[0053]

[0054] -O-CH2- (4)

[0055]

[0056] (In the above formula (5), s is an integer from 0 to 3, t is an integer from 0 to 3, and the bonding of each oxyalkylene group can be block or random.)

[0057] the organic group in the linking group represented by

[0058] When Q is the above formula (3), m is 8, and n is an integer from 1 to 22,

[0059] When Q is the above formula (4), m is an integer from 1 to 10, and n is an integer from 7 to 22,

[0060] When Q is the above formula (5), m is an integer from 1 to 10, and n is an integer from 7 to 22,

[0061] When Q is the above formula (6), m is an integer from 1 to 10, and n is an integer from 7 to 22.)

[0062] the organic group represented by

[0063] R 3 is R 1 or R 2 , x is an integer from 0 to 50, y is an integer from 0 to 50, and one or more of R 2 or R 3 are organic groups represented by the general formula (2). When y = 0, at least one R 3 is R 2 . Furthermore, the bonding of the siloxane units enclosed by the above x and y can be block or random.)

[0064] R 1 is independently an alkyl group having 1 to 16 carbon atoms, preferably an alkyl group having 1 to 12 carbon atoms. Examples of the alkyl group include linear alkyl groups such as methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, and cyclic alkyl groups such as cyclopentyl and cyclohexyl. Preferred examples of R 1 include methyl, ethyl, hexyl, dodecyl, etc., and among them, methyl is preferred.

[0065] R 2 is selected from the following formula (2)

[0066] [Chemical formula 7]

[0067]

[0068] (In formula (2), R 4 is a hydrogen atom or a methyl group,

[0069] Q is the following formula (3) to (6)

[0070] [Chemical formula 8]

[0071]

[0072] -O-CH2- (4)

[0073]

[0074] (In the above formula (5), s is an integer from 0 to 3, t is an integer from 0 to 3, and the bonding of each oxyalkylene group can be block or random.)

[0075] the organic group in the linking group represented by

[0076] R 4 is a hydrogen atom or a methyl group, preferably a hydrogen atom.

[0077] When Q is the above formula (3), m is 8, and n is an integer from 1 to 22, preferably an integer from 1 to 18.

[0078] When Q is the above formula (4), m is an integer from 1 to 10, preferably an integer from 1 to 8, and n is an integer from 7 to 22, preferably an integer from 8 to 18.

[0079] When Q is the above formula (5), m is an integer from 1 to 10, preferably an integer from 1 to 6, and n is an integer from 7 to 22, preferably an integer from 8 to 18. s is an integer from 0 to 3, preferably an integer from 0 to 2, and t is an integer from 0 to 3, preferably an integer from 0 to 2. s + t is preferably 1 or more. Further, the bonding of each oxyalkylene group can be block or random. Specifically, the linking groups having the following structures can be exemplified.

[0080] [Chemical formula 9]

[0081]

[0082] When Q is the above formula (6), m is an integer from 1 to 10, preferably an integer from 1 to 8, and n is an integer from 7 to 22, preferably an integer from 8 to 18.

[0083] As the linking group of Q, the above formulas (3), (4), and (5) are preferred, and the above formulas (3) and (4) are more preferred.

[0084] R 3 is R 1 or R 2 , and each can list groups the same as those exemplified in the above R 1 and R 2 . As R 3 , methyl and the group represented by the above (2) are preferred, and the group represented by (2) is more preferred. When y = 0, at least one R 3 is R 2 , and one or more of R 2 and R 3 are organic groups represented by the above formula (2). The number of organic groups represented by the above formula (2) in one molecule is preferably 1 to 40, more preferably 1 to 30.

[0085] x is an integer from 0 to 50, preferably an integer from 0 to 30, and y is an integer from 0 to 50, preferably an integer from 0 to 30. Furthermore, the bond of the siloxane units surrounded by the above x and y can be block or random, and the bonding order of each siloxane unit is not limited by the above. Furthermore, x and y can each be 1 or more. Even when x = y = 0 in the above, it is treated as an organopolysiloxane in the present invention.

[0086] [Manufacturing Method]

[0087] The organopolysiloxane represented by the above formula (1) can be produced, for example, by a hydrosilylation reaction of a corresponding organohydrogenpolysiloxane with a compound containing a long-chain alkyl group having a carbon-carbon double bond at the terminal. The hydrogen atoms of the unreacted hydrosilyl groups remaining at this time and the generated hydroxyl groups can be used as the above R 1 . Specifically, it can be 10% or less, preferably 5% or less, based on the total number of all R 1 .

[0088] Preferably, the surface tension of the organopolysiloxane of the present invention is 28 mN / m or less and it is non-volatile. The surface tension is more preferably 15 to 28 mN / m. The surface tension is a value measured at 25 °C using a tensiometer by the Wilhelmy method. In the present invention, the so-called "non-volatile" means that when 0.5 g of the sample is accurately weighed in an aluminum dish with a diameter of 60 mmφ, at atmospheric pressure (1,013 hPa), the mass reduction after being left at 25 °C for 3 hours is 10 mass% or less.

[0089] [Cosmetics]

[0090] The present invention contains the above-mentioned organopolysiloxane, which can be used alone or in combination of two or more kinds. There is no particular limitation on its content, and it is preferably 1 to 70% by mass in the cosmetic. As long as it is a cosmetic containing such an organopolysiloxane, for example, when various oil agents such as silicone, hydrocarbon oil and ester, an organic ultraviolet absorber, and an oily component in a solid state at 25°C are blended, a cosmetic having excellent long-term stability and makeup persistence can also be obtained. Furthermore, it does not impair the smooth feeling peculiar to silicone, has good spreadability, is not rough, the formed film is smooth, and the film is refreshing. In addition, it has a refreshing and smooth feeling, good spreadability, excellent water repellency, and can achieve a good feeling in use.

[0091] [Organic ultraviolet absorber]

[0092] Since the organopolysiloxane of the present invention has excellent compatibility with the organic ultraviolet absorber, a cosmetic containing such an organic ultraviolet absorber becomes a cosmetic having a good feeling in use, excellent long-term stability, and makeup persistence.

[0093] As the organic ultraviolet absorber, as long as it is a raw material that can be blended in ordinary cosmetics, there is no particular limitation, and one kind can be used alone or two or more kinds can be used in combination. Specifically, examples include benzophenone-1 (designated name (INCI: Benzophenone-1)), benzophenone-2 (designated name (INCI: Benzophenone-2)), benzophenone-3 (designated name (INCI: Benzophenone-3)), benzophenone-4 (designated name (INCI: Benzophenone-4)), benzophenone-5 (designated name (INCI: Benzophenone-5)), benzophenone-6 (designated name (INCI: Benzophenone-6)), benzophenone-9 (designated name (INCI: Benzophenone-9)), homosalate (INCI), octocrylene, tert-butyl methoxydibenzoylmethane, ethylhexyl salicylate, diethylamino hydroxybenzoyl hexyl benzoate, polysiloxane-15, octyl dimethoxybenzylidene dioxoimidazolidine propionate (designated name (INCI: EthylhexylDimethoxybenzylideneDioxoimidazolidine Propionate)), terephthalylidene dicamphor sulfonic acid (designated name (INCI: Terephthalylidene Dicamphor Sulfonic Acid)), ethylhexyl triazone (INCI), methyl bis(trimethylsilyloxy)silyl isopentyl trimethoxycinnamate (designated name (INCI: IsopentylTrimethoxycinnamate Trisiloxane)), cresyl triazone (INCI), ethylhexyl dimethyl PABA (designated name (INCI: Ethylhexyl Dimethyl PABA)), isopropyl methoxycinnamate (designated name (INCI: IsopropylMethoxycinnamate)), ethylhexyl methoxycinnamate, bis-ethylhexyloxyphenol methoxyphenyl triazine, phenylbenzimidazole sulfonic acid (designated name (INCI: Phenylbenzimidazole Sulfonic Acid)), methylene bis-benzotriazolyl tetramethylbutylphenol, glyceryl ethylhexanoateDimethoxycinnamate), Glyceryl PABA (INCI), Methyl Diisopropylcinnamate (designated name (INCI: DiisopropylMethylCinnamate)), Cinoxate (INCI), Ethylhexyl DimethoxybenzylideneDioxoimidazolidine Propionate (designated name (INCI: Ethylhexyl DimethoxybenzylideneDioxoimidazolidine Propionate)), etc. In addition, a UVA absorber (e.g., Hexyl Diethylaminohydroxybenzoylbenzoate, etc.) and a UVB absorber (e.g., Ethylhexyl Methoxycinnamate, etc.) can be used in combination, or they can be arbitrarily combined.

[0094] Among them, from the aspect of high ultraviolet absorption effect and excellent compatibility with the organopolysiloxane in the present invention, it is preferably an organic ultraviolet absorber selected from Ethylhexyl Methoxycinnamate (designated name (INCI: EthylhexylMethoxycinnamate)), Hexyl Diethylaminohydroxybenzoylbenzoate (designated name (INCI: Diethylamino Hydroxybenzoyl HexylBenzoate)), Ethylhexyl Salicylate (designated name (INCI: Ethylhexyl Salicylate)), Polysiloxane-15 (INCI), ButylMethoxydibenzoylmethane (designated name (INCI: ButylMethoxydibenzoylmethane)), Benzophenone (designated name (INCI: Benzophenone)), Methylene Bis-Benzotriazolyl Tetramethylbutylphenol (INCI), Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine (INCI), and Octocrylene (INCI).

[0095] When an organic ultraviolet absorber is contained, its content is preferably 1 to 40% by mass, more preferably 2 to 10% by mass in the cosmetic.

[0096] [Volatile organosilicon]

[0097] The so-called volatile organosilicon refers to a silicone oil that is at least partially volatile at 25°C. The volatile organosilicon is not particularly limited as long as it is a raw material that can usually be blended in cosmetics, and one kind can be used alone or two or more kinds can be used in combination. Specifically, decamethyltetrasiloxane, undecamethylpentasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, diethyl octamethyltetrasiloxane, tris(trimethylsilyloxy)methylsilane, etc. can be cited.

[0098] [Oily component that is solid at 25°C]

[0099] In the present invention, when the organopolysiloxane is used in combination with an oily component that is solid at 25°C, it also has a high affinity for the oily component. Therefore, without interfering with the curing of the oily component, it is possible to easily prepare a preparation obtained by curing a rod-shaped cosmetic, etc.

[0100] The oily component that is solid at 25°C is not particularly limited, and one kind can be used alone or two or more kinds can be used in combination. Specifically, waxes, hydrocarbons, esters, higher alcohols, higher fatty acids, etc. that are solid at 25°C can be mentioned.

[0101] The oily component that is solid at 25°C preferably has a melting point of 40°C or higher, more preferably 60 to 110°C, and waxes, hydrocarbons, esters, higher alcohols, higher fatty acids can be mentioned. As long as it is a raw material that can usually be blended in cosmetics, there is no particular limitation.

[0102] Specifically, carnauba wax, sugarcane wax, candelilla wax, refined candelilla wax, rice wax, wood wax, jojoba wax, kapok wax, rice bran wax, bayberry fruit wax, shea butter, cocoa butter, Japanese sumac wax (INCI: Rhus Succedanea Fruit Wax), montan wax (INCI: Montan Wax), hydrogenated castor oil isostearate and other vegetable waxes, beeswax, beef tallow, beef bone fat, lard (INCI: Lard), horse fat (INCI: Horse Fat), mutton fat, lanolin (INCI: Lanolin), crane wax, shellac wax, spermaceti and other animal waxes, lanolin esters, lanolin fatty acid esters, beeswax acid esters and other semi-synthetic waxes, hydrogenated castor oil, hydrogenated coconut oil and other hydrogenated oils, paraffin wax, polyethylene, refined ceresin, natural ceresin, microcrystalline wax and other hydrocarbon waxes, stearyl alcohol, behenyl alcohol, cetyl alcohol and other higher alcohols, wax esters such as synthetic beeswax, amino acid stearyl alcohols such as dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, fatty acids such as stearic acid, behenic acid, and silicone waxes such as acrylic silicone resins obtained by acrylic-silicone graft or block copolymers (manufactured by Shin-Etsu Chemical Co., Ltd.: acrylic-silicone graft copolymer: KP-561P, 562P, etc.), or derivatives thereof, and preferably one kind or two or more kinds selected from these.

[0103] Among them, it is preferably at least one selected from polyethylene (INCI), ozokerite (INCI), ceresin (INCI), candelilla wax (indicated name (INCI: Euphorbia Cerifera (Candelilla) Wax)), carnauba wax (indicated name (INCI: Copernicia Cerifera (Carnauba) Wax)), beeswax (indicated name (INCI: Beeswax)), microcrystalline wax (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), and cetyl alcohol (indicated name (INCI: Cetyl Alcohol)).

[0104] In the case of containing an oily component that is solid at 25°C, its content is preferably 0.5 to 35% by mass, more preferably 5 to 15% by mass in the cosmetic.

[0105] In the cosmetic of the present invention, various optional components used in ordinary cosmetics can be blended.

[0106] <Other Optional Components>

[0107] As other optional components, for example, it may include (1) an oil agent, (2) an aqueous component, (3) a surfactant, (4) a powder, (5) a composition composed of a crosslinked organopolysiloxane and an oil agent that is liquid at room temperature, (6) a film-forming agent, (7) an antiperspirant, (8) an antibacterial agent, and (9) other additives. These can be used alone or in appropriate combination of two or more. Further, in the case where the above components are repeatedly described as optional components, the above components are preferred.

[0108] (1) Oil Agent

[0109] The oil agent can be any of semi-solid and liquid except for the above-mentioned oily component that is solid at 25°C. For example, natural animal and plant oils and fats, semi-synthetic oils, hydrocarbon oils, higher fatty acids, higher alcohols, esters, and silicone oils other than organopolysiloxanes that are essential components for showing the effects of the present invention, and fluorine-based oil agents can be used.

[0110] · Natural Animal and Plant Oils and Fats, and Semi-Synthetic Oils

[0111] Examples of natural animal and vegetable oils and semi-synthetic oils include avocado oil (designation (INCI: Persea Gratissima (Avocado) Oil)), linseed oil (designation (INCI: Linum Usitatissimum (Linseed) Seed Oil)), almond oil (designation (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil)), perilla oil (designation), olive oil (designation (INCI: Olea Europaea (Olive) Fruit Oil)), California torreya oil (designation (INCI: Torreya Californica (California Nutmeg) Oil)), citronella oil (designation (INCI: Cymbopogon Nardus (Citronella) Oil)), torreya grandis seed oil (designation (INCI: Torreya Nucifera Seed Oil)), almond oil (designation (INCI: Kyounin Yu)), wheat germ oil (designation (INCI: Triticum Vulgare (Wheat) Germ Oil)), sesame oil (designation (INCI: Sesamum Indicum (Sesame) Seed Oil)), rice germ oil (designation (INCI: Oryza Sativa (Rice) Germ Oil)), rice bran oil (designation (INCI: Oryza Sativa (Rice) Bran Oil)), camellia kissi seed oil (designation (INCI: Camellia Kissi Seed Oil)), safflower oil (designation (INCI: Carthamus Tinctorius (Safflower) Seed Oil)), soybean oil (designation (INCI: Glycine Soja (Soybean) Oil)), camellia sinensis seed oil (designation (INCI: Camellia Sinensis Seed Oil)), camellia japonica seed oil (designation (INCI: Camellia Japonica Seed Oil)), evening primrose oil (designation (INCI: Oenothera Biennis (Evening Primrose) Oil)), rapeseed oil (designation (INCI: RAPE SHUSHIYU)), corn germ oil (designation (INCI: Zea Mays (Corn) Germ Oil)) and other germ oils, peach kernel oil (designation), palm oil (designation (INCI: ElaeisGuineensis (Palm) Oil), palm kernel oil (INCI: Elaeis Guineensis (Palm) Kernel Oil), castor oil (INCI: Ricinus Communis (Castor) Seed Oil), sunflower seed oil (INCI: Helianthus Annuus (Sunflower) Seed Oil), grape seed oil (INCI: Vitis Vinifera (Grape) Seed Oil), jojoba seed oil (INCI: Simmondsia Chinensis (Jojoba) Seed Oil), macadamia ternifolia seed oil (INCI: Macadamia Ternifolia Seed Oil), limnanthes alba (meadowfoam) seed oil (INCI: Limnanthes Alba (Meadowfoam) Seed Oil), cottonseed oil (INCI: Gossypium Herbaceum (Cotton) Seed Oil), coconut oil (INCI: Cocos Nucifera (Coconut) Oil), peanut oil (INCI: Arachis Hypogaea (Peanut) Oil) and other natural vegetable oils, shark liver oil (INCI: Shark Liver Oil), cod liver oil (INCI: Cod Liver Oil), fish liver oil (INCI: Fish Liver Oil), turtle oil (INCI: Turtle Oil), mink oil (INCI: Mink Oil), egg oil (INCI: Egg Oil) and other natural animal oils, hydrogenated coconut oil (INCI: Hydrogenated Coconut Oil), lanolin oil (INCI: Lanolin Oil) and other semi-synthetic oils, etc.

[0112] · Hydrocarbon oils

[0113] Examples of the hydrocarbon oil include linear or branched hydrocarbon oils, which may be volatile or non-volatile hydrocarbon oils.

[0114] Specifically, examples include olefin oligomers (INCI), isoparaffins such as (C13,14) isoparaffin (INCI), isododecane (INCI), undecane (INCI), dodecane (INCI), isocetane (INCI), hydrogenated polyisobutene (trade name (INCI: Hydrogenated Polyisobutene)), squalane (INCI), mineral oil (INCI), coconut alkane (INCI), (C13-15) alkane (INCI), petrolatum (trade name (INCI: Petrolatum)), and other alkanes.

[0115] · Higher fatty acids

[0116] Examples of higher fatty acids include oleic acid (trade name (INCI: Oleic Acid)), linoleic acid (trade name (INCI: Linoleic Acid)), linolenic acid (trade name (INCI: Linolenic Acid)), arachidonic acid (trade name (INCI: Arachidonic Acid)), eicosapentaenoic acid (trade name (INCI: Eicosapentaenoic Acid)), docosahexaenoic acid (trade name (INCI: Docosahexaenoic Acid)), isostearic acid (trade name (INCI: Isostearic Acid)), hydroxystearic acid (trade name (INCI: Hydroxystearic Acid)), and the like.

[0117] · Higher alcohols

[0118] Examples of higher alcohols include alcohols preferably having 6 or more carbon atoms. Specific examples of higher alcohols include lauryl alcohol (INCI), myristyl alcohol (INCI), cetyl alcohol (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), oleyl alcohol (INCI), isostearyl alcohol (INCI), octyldodecanol (INCI), cholesterol (INCI), phytosterol (INCI), batyl alcohol (INCI), and the like.

[0119] · Ester oils

[0120] Examples of ester oils include diisobutyl adipate (designated name (INCI: Diisobutyl Adipate)), dihexyl decyl adipate (designated name), diheptyl undecyl adipate (designated name (INCI: Diheptylundecyl Adipate)), n-alkyl glycol monoisostearates such as isostearyl isostearate (designated name (INCI: Isostearyl Isostearate)), isocetyl isostearate (designated name (INCI: Isocetyl Isostearate)), trimethylolpropane triisostearate (designated name (INCI: Trimethylolpropane Triisostearate)), ethylene glycol diethylhexanoate (designated name (INCI: Glycol Diethylhexanoate)), cetyl ethylhexanoate (designated name (INCI: Cetyl Ethylhexanoate)), trimethylolpropane triethylhexanoate (designated name (INCI: Trimethylolpropane Triethylhexanoate)), pentaerythrityl tetraethylhexanoate (designated name (INCI: Pentaerythrityl Tetraethylhexanoate)), octyldodecyl esters such as cetyl ethylhexanoate (designated name (INCI: Cetyl Ethylhexanoate)), octyldodecyl stearoyl stearate (designated name (INCI: Octyldodecyl Stearoyl Stearate)), oleyl oleate (designated name (INCI: Oleyl Oleate)), octyldodecyl oleate (designated name (INCI: Octyldodecyl Oleate)), decyl oleate (designated name (INCI: Decyl Oleate)), neopentyl glycol diethylhexanoate (designated name (INCI: Neopentyl Glycol Diethylhexanoate)), neopentyl glycol dicaprate (designated name (INCI: Neopentyl Glycol Dicaprate)), diisostearyl malate (designated name (INCI: Diisostearyl Malate)), triethyl citrate (designated name (INCI: Triethyl Citrate)), diethylhexyl succinate (designated name (INCI: Diethylhexyl Succinate)), amyl acetate (designated name (INCI: Amyl Acetate)), ethyl acetate (designated name (INCI: EtylAcetate), butyl acetate (indicated name (INCI: Butyl Aceetate)), isocetyl stearate (indicated name (INCI: Isocetyl Stearate)), butyl stearate (indicated name (INCI: Butyl Stearate)), diisopropyl sebacate (indicated name (INCI: Diisopropyl Sebacate)), diethylhexyl sebacate (indicated name (INCI: Diethylhexyl Sebacate)), cetyl lactate (indicated name (INCI: Cetyl Lactate)), myristyl lactate (indicated name (INCI: Myristyl Lactate)), isononyl isononanoate (indicated name (INCI: Isononyl Isononanoate)), isotridecyl isononanoate (indicated name (INCI: Isotridecyl Isononanoate)), isopropyl palmitate (indicated name (INCI: Isopropyl Palmitate)), ethylhexyl isopalmitate (indicated name (INCI: Ethylhexyl Isopalmitate)), palmitic acid esters such as hexyl decyl palmitate (indicated name (INCI: Isocetyl Palmitate, Hexyldecyl Palmitate)), cholesteryl hydroxystearate (indicated name (INCI: Cholesteryl Hydroxystearate)), isopropyl myristate (indicated name (INCI: Isopropyl Myristate)), octyldodecyl myristate (indicated name (INCI: Octyldodecyl Myristate)), myristic acid esters such as myristyl myristate (indicated name (INCI: Myristyl Myristate)), ethylhexyl laurate (indicated name (INCI: Ethylhexyl Laurate)), hexyl laurate (indicated name (INCI: Hexyl Laurate)), dioctyldodecyl lauroyl glutamate (indicated name (INCI: Dioctyldodecyl Lauroyl Glutamate)), isopropyl lauroyl sarcosinate (indicated name (INCI: Isopropyl Lauroyl Sarcosinate)), etc.

[0121] In addition, among ester oils, examples of glyceride oils include glyceryl triisooctanoate (INCI), triglyceride (caprylic / capric) (designated name (INCI: Caprylic / Capric Triglyceride)), coconut oil glyceride (INCI), triglyceride (caprylic / capric / succinic) (designated name (INCI: Caprylic / Capric / Succinic Triglyceride)), glyceride (caprylic / capric) (designated name (INCI: Caprylic / Capric Glycerides)), and the like.

[0122] · Silicone oil

[0123] As silicone oil, it is possible to blend silicone oils other than organopolysiloxane, which is an essential component for exhibiting the effects of the present invention.

[0124] For example, examples include dimethylpolysiloxane (INCI), trisiloxane (INCI), methyltrimethylpolysiloxane (INCI), ethyltrisiloxane (INCI), ethylmethylpolysiloxane (INCI), alky-modified silicones such as hexyldimethylpolysiloxane (INCI), long-chain alky-modified silicones such as octylmethylpolysiloxane (INCI), phenyltrimethylpolysiloxane (INCI), diphenyldimethylpolysiloxane (INCI), diphenylmethoxysilylphenyltrimethylpolysiloxane (INCI), tetraphenyldimethyldisiloxane (INCI), methylhydrogenpolysiloxane, and other linear or branched organopolysiloxanes with low to high viscosities, cyclic organopolysiloxanes such as cyclotetrasiloxane (INCI), cyclopentasiloxane (INCI), cyclohexasiloxane (INCI), amino-modified organopolysiloxanes such as aminoterminated dimethylpolysiloxane (INCI) and aminopropyldimethylpolysiloxane (INCI), pyrrolidone-modified organopolysiloxanes such as PCA dimethylpolysiloxane (INCI), pyrrolidone carboxylic acid-modified organopolysiloxane, highly polymerized colloidal dimethylpolysiloxane, colloidal amino-modified organopolysiloxane, silicone rubbers such as colloidal dimethylsiloxane-methylphenylsiloxane copolymer, and low-viscosity organopolysiloxane solutions of organosilicone or organosilicone rubber, amino-modified silicone, fluorine-modified silicone, silicone resin, and dissolved substances of silicone resin.

[0125] Examples of commercially available silicone oils include those manufactured by Shin-Etsu Chemical Co., Ltd.: KF-96L-1cs, KF-96L-1.5cs, KF-96L-2cs, KF-96A-6cs, KF-4422, KF-4418, KF-54, KF-54HV, KF-56A, KF-995, etc.

[0126] · Fluorine-based oil agent

[0127] Examples of fluorine-based oil agents include perfluorodecalin (INCI), perfluorononyl dimethyl polysiloxane (INCI), perfluoromethylcyclopentane (INCI), etc.

[0128] (2) Aqueous components

[0129] The aqueous components are not particularly limited as long as they are aqueous components that can generally be formulated in cosmetics. Specifically, water, humectants, water-soluble high molecular compounds, etc. can be cited. These can be used alone or in appropriate combination of two or more.

[0130] Examples of water include seawater, hot spring water, peat water, etc. defined in the name, in addition to purified water, distilled water of fruits and plants generally used in cosmetics.

[0131] Examples of humectants include lower alcohols with 2 to 5 carbon atoms such as ethanol (name shown (INCI: Alcohol)), isopropyl alcohol (name shown (INCI: Isopropyl Alcohol)), sugar alcohols such as sorbitol (INCI), maltose (INCI), xylitol (INCI), polyhydric alcohols such as BG (name shown (INCI: Butylene Glycol)), PG (name shown (INCI: Propylene Glycol)), DPG (name shown (INCI: Dipropylene Glycol)), pentylene glycol (INCI), 1,10-decanediol (INCI), octanediol (INCI), 1,2-hexanediol (INCI), erythritol (INCI), glycerin (INCI), diglycerin (INCI), polyethylene glycol; glucose (INCI), glucosylglycerol (INCI), betaine (INCI), sodium chondroitin sulfate (name shown (INCI: Sodium Chondroitin Sulfate)), PCA-Na (name shown (INCI: Sodium PCA)), methyl gluceth-10 (INCI), methyl gluceth-20 (INCI), etc. In addition, sterols such as cholesterol (INCI), beta-sitosterol (name shown (INCI: Beta-Sitosterol)), phytosterol (INCI), lanosterol (INCI), etc. can be cited. Examples of other humectants include hyaluronic acid, egg yolk lecithin, soybean lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingomyelin, etc. The blending amount of the humectant is preferably 1 to 90% by mass of the whole cosmetic, more preferably 3 to 50% by mass, and further preferably 5 to 20% by mass.

[0132] As water-soluble polymer compounds, natural water-soluble polymer compounds such as carrageenan, hyaluronate, xanthan gum, etc., semi-synthetic water-soluble polymer compounds such as hydroxyethyl cellulose, hydroxypropyl methyl cellulose, carboxymethyl cellulose, etc.; synthetic water-soluble polymer compounds such as polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, etc.; inorganic water-soluble polymer compounds such as bentonite, synthetic laponite, etc. can be cited. The compounding amount of the water-soluble polymer compound is preferably 0.01 to 1% by mass of the whole cosmetic.

[0133] (3) Surfactant

[0134] As surfactants, there are nonionic, anionic, cationic and amphoteric surfactants, and there is no particular limitation as long as they are surfactants used in ordinary cosmetics, they can all be used. Among these surfactants, partially crosslinked polyether-modified silicone, partially crosslinked polyglycerol-modified silicone, linear or branched polyoxyethylene-modified organopolysiloxane, linear or branched polyoxyethylene-polyoxypropylene-modified organopolysiloxane, linear or branched polyoxyethylene-alkyl co-modified organopolysiloxane, linear or branched polyoxyethylene-polyoxypropylene-alkyl co-modified organopolysiloxane, linear or branched polyglycerol-modified organopolysiloxane, linear or branched polyglycerol-alkyl co-modified organopolysiloxane are preferred.

[0135] Among these surfactants, the content of hydrophilic polyoxyethylene group, polyoxyethylene-polyoxypropylene group or polyglycerol residue preferably accounts for 10 to 70% by mass in the molecule.

[0136] As partially crosslinked polyether-modified silicone and partially crosslinked polyglycerol-modified silicone, for example, (dimethylpolysiloxane / (PEG-10 / 15)) crosslinked polymer (INCI), (PEG-15 / lauryldimethylpolysiloxane) crosslinked polymer (INCI), (PEG-10 / lauryldimethylpolysiloxane) crosslinked polymer (INCI), (PEG-15 / laurylpolydimethylsilanyloxyethyldimethylpolysiloxane) crosslinked polymer (INCI), (dimethylpolysiloxane / polyglycerol-3) crosslinked polymer (INCI), (lauryldimethylpolysiloxane / polyglycerol-3) crosslinked polymer (INCI), (polyglycerol-3 / laurylpolydimethylsilanyloxyethyldimethylpolysiloxane) crosslinked polymer (INCI), etc. can be cited.

[0137] In addition, when using partially crosslinked polyether-modified silicone and partially crosslinked polyglycerol-modified silicone, in a composition composed of this crosslinked organopolysiloxane and an oil agent that is liquid at room temperature, it is preferred that the crosslinked organopolysiloxane swells with respect to the liquid oil containing liquid oil agent greater than or equal to its weight.

[0138] As the liquid oil agent, it can be the organopolysiloxane in the present invention, or the liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, etc. in the optional component (1) oil agent, and fluorine-based oil. For example, cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isocetane (INCI), glyceryl triisooctanoate (INCI), isotridecyl isononanoate (indicated name (INCI: Isotridecyl Isononanoate)), squalane (INCI), etc. can be cited.

[0139] As an example of a commercially available crosslinked organopolysiloxane swollen by a liquid oil agent, examples include those manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-210, KSG-240, KSG-270, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-710, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, KSG-850Z, etc.

[0140] As surfactants that are not crosslinked organopolysiloxanes, for example, PEG-11 methyl ether dimethicone (INCI), PEG / PPG-20 / 22 butyl ether dimethicone (INCI), PEG-3 dimethicone (INCI), PEG-10 dimethicone (INCI), PEG-9 polydimethylsiloxylethyl dimethicone (INCI), lauryl PEG-9 polydimethylsiloxylethyl dimethicone (INCI), cetyl PEG / PPG-10 / 1 dimethicone (INCI), polyglyceryl-3 disiloxane dimethicone (INCI), polyglyceryl-3 polydimethylsiloxylethyl dimethicone (INCI), lauryl polyglyceryl-3 polydimethylsiloxylethyl dimethicone (INCI), etc. can be cited.

[0141] As examples of commercially available products, examples include those manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6011, KF-6011P, KF-6012, KF-6015, KF-6017, KF-6043, KF-6028, KF-6038, KF-6048, KF-6100, KF-6104, KF-6106, KF-6105, KF-6115, etc.

[0142] In any case, as the compounding amount of the surfactant, it is preferably 0.1 to 20% by mass of the whole cosmetic. If it is 0.1% by mass or more, the functions of dispersion and emulsification can be sufficiently exerted. If it is 20% by mass or less, there is no need to worry about the sticky feeling in using the cosmetic, so it is preferred. There is no limitation on the HLB of the surfactant. For the purpose of maintaining the water resistance of the cosmetic, 2 to 14.5 is preferred.

[0143] (4) Powders

[0144] Examples of the powders include coloring pigments, inorganic powders, metal powders, organic powders, inorganic / organic composite powders, etc. Specifically, they are as described below.

[0145] · Coloring pigments

[0146] As coloring pigments, generally, as long as they are pigments used for the purpose of coloring cosmetics, there are no particular limitations. Red iron oxides (designated name (INCI: Iron Oxides)), yellow iron oxides (designated name (INCI: Iron Oxides)), white titanium dioxide (designated name (INCI: Titanium Dioxide)), black iron oxides (designated name (INCI: Iron Oxides)), ultramarine (designated name (INCI: Ultramarines)), Prussian blue (designated name (INCI: Ferric Ferrocyanide, Ferric Ammonium Ferrocyanide)), manganese violet (designated name (INCI: Manganese Violet)), cobalt titanate (designated name (INCI: Cobalt Titanium Oxide)), chromium hydroxide green (designated name (INCI: Chromium Hydroxide Green)), chromium oxide greens (designated name (INCI: Chromium Oxide Greens)), aluminum / cobalt oxide (designated name (INCI: Cobalt Aluminum Oxide)), (titanium / titanium dioxide) fired product (designated name (INCI: Titanium / Titanium Dioxide)), lithium / cobalt titanate (designated name (INCI: Lithium Cobalt Titanate)), (iron oxide / titanium dioxide) sintered product (designated name), iron oxide-doped titanium dioxide (designated name (INCI: Iron Oxides, Titanium Dioxide)) and other complex compounds doped with different metals, titanium nitride (designated name (INCI: Titanium Nitride)), ferrous hydroxide (designated name (INCI: Iron Hydroxide)), γ-iron oxide and other inorganic brown pigments, loess and other inorganic yellow pigments, products obtained by lake-forming tar-based pigments, products obtained by lake-forming natural pigments and other colored pigments can all be used.

[0147] In addition, as the shape of the pigment, all shapes such as spherical, substantially spherical, rod-shaped, spindle-shaped, petal-shaped, strip-shaped, irregular-shaped, etc. can be used. As long as the cosmetics can be given color, there are no particular limitations on their geometric forms.

[0148] · Inorganic powder

[0149] As inorganic powders, examples include zirconium dioxide (designated name (INCI: Zirconium Dioxide)), zinc oxide (designated name (INCI: Zinc Oxide)), cerium oxide (designated name (INCI: Cerium Oxide)), magnesium oxide (designated name (INCI: Magnesium Oxide)), barium sulfate (designated name (INCI: Barium Sulfate)), calcium sulfate (designated name (INCI: Calcium Sulfate)), magnesium sulfate (designated name (INCI: Magnesium Sulfate)), calcium carbonate (designated name (INCI: Calcium Carbonate)), magnesium carbonate (designated name (INCI: Magnesium Carbonate)), talc (INCI), mica (INCI), kaolin (INCI), synthetic fluorphlogopite (designated name (INCI: Synthetic Fluorphlogopite)), synthetic phlogopite iron (designated name), biotite (designated name (INCI: Biotite)), potassium silicate (designated name (INCI: Potassium Silicate)), silicon dioxide (INCI), aluminum silicate (designated name (INCI: Aluminum Silicate)), magnesium silicate (designated name (INCI: Magnesium Silicate)), magnesium aluminum silicate (designated name (INCI: Magnesium Aluminum Silicate)), calcium silicate (designated name (INCI: Calcium Silicate)), aluminum calcium sodium silicate (designated name (INCI: Aluminum Calcium Sodium Silicate)), lithium magnesium sodium silicate (designated name (INCI: Lithium Magnesium Sodium Silicate)), sodium magnesium silicate (designated name (INCI: Sodium Magnesium Silicate)), calcium aluminum borosilicate (designated name (INCI: Calcium Aluminum Borosilicate)), calcium sodium borosilicate (designated name (INCI: Calcium Sodium Borosilicate)), hydroxyapatite (INCI), bentonite (INCI), montmorillonite (INCI), hectorite (INCI), zeolite (INCI), aluminum oxide (INCI), aluminum hydroxide (designated name (INCI: Aluminum Hydroxide)), boron nitride (designated name (INCI: BoronParticles composed of nitride), glass (indicated name (INCI: Glass)), etc.

[0150] In addition, as inorganic colored pearlescent pigments, examples include mica (INCI) coated with titanium dioxide (indicated name (INCI: Titanium Dioxide)), synthetic fluorophlogopite (indicated name (INCI: Synthetic Fluorphlogopite)) coated with titanium dioxide (indicated name (INCI: Titanium Dioxide)), and other pearlescent agents such as bismuth oxychloride (indicated name (INCI: Bismuth Oxychloride)), bismuth oxychloride (indicated name (INCI: Bismuth Oxychloride)) coated with titanium dioxide (indicated name (INCI: Titanium Dioxide)), talc (INCI) coated with titanium dioxide (indicated name (INCI: Titanium Dioxide)), fish scale foil (indicated name), and colored mica coated with titanium dioxide (indicated name (INCI: Titanium Dioxide)). They can be untreated or can be the well-known surface treatments generally used in cosmetics, and there is no particular limitation.

[0151] · Metal powder

[0152] Examples of metal powder include metal particles composed of aluminum (indicated name (INCI: Aluminum, Aluminum Powder)), copper (indicated name (INCI: Copper Powder)), silver (indicated name (INCI: Silver Powder)), gold (indicated name (INCI: Gold)), etc.

[0153] · Organic powder

[0154] Examples of organic powder include powders composed of silicone, polyamide, polyacrylate-acrylate, polyester, polyethylene (INCI), polypropylene (INCI), polystyrene (INCI), styrene-acrylic copolymer, divinylbenzene-styrene copolymer, polyurethane, vinyl resin, urea-formaldehyde resin, melamine resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethyl methacrylate, cellulose (INCI), silk (INCI), nylon (indicated name), phenolic resin, epoxy resin, polycarbonate, etc.

[0155] In particular, examples of silicone include silicone resin particles; polymethylsilsesquioxane (INCI), silicone rubber powder, silicone resin-coated silicone rubber powder; (vinyldimethylpolysiloxane / methylpolysiloxane silsesquioxane) cross-linked polymer (designated name (INCI: vinyldimethicone / methicone silsesquioxane crosspolymer)), (diphenyldimethylpolysiloxane / vinyldiphenyldimethylpolysiloxane / silsesquioxane) cross-linked polymer (designated name (INCI: diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer)), polysiloxane-1 cross-linked polymer (INCI), polysiloxane-22 (INCI), etc.

[0156] Examples of commercially available powders composed of silicone include those manufactured by Shin-Etsu Chemical Co., Ltd.: KMP-590, KMP-591, KMP-592, KMP-597, KMP-598, KSP-100, KSP-101, KSP-102, KSP-105, KSP-300, KSP-411, KSP-441, KM-9729, KM-440, etc.

[0157] In addition, metal soaps can also be cited. As specific examples, powders composed of zinc stearate (designated name (INCI: Zinc Stearate)), aluminum stearate (designated name (INCI: Aluminum Stearate)), calcium stearate (designated name (INCI: Calcium Stearate)), magnesium stearate (designated name (INCI: Magnesium Stearate)), zinc myristate (designated name (INCI: Zinc Myristate)), magnesium myristate (designated name (INCI: Magnesium Myristate)), cetyl phosphate (zinc / sodium) (designated name (INCI: Sodium Zinc Cetyl Phosphate)), potassium cetyl phosphate (designated name (INCI: Potassium Cetyl Phosphate)), etc. can be cited.

[0158] Furthermore, organic pigments etc. can also be cited. As specific examples, Red 3, Red 104(1) (designated name (INCI: Red 28, Red 28 Lake)), Red 106, Red 201 (designated name (INCI: Red 6)), Red 202 (designated name (INCI: Red 7)), Red 204, Red 205, Red 220 (designated name (INCI: Red 34)), Red 226 (designated name (INCI: Red 30)), Red 227 (designated name (INCI: Red 33, RED 33 Lake)), Red 228 (designated name (INCI: Red 36)), Red 230(1) (designated name (INCI: Red 22, Red 22 Lake)), Red 230(2) (designated name), Red 401 (designated name), Red 505 (designated name), Yellow 4 (designated name (INCI: Yellow 5)), Yellow 5 (designated name (INCI: Yellow 6, Yellow 6 Lake)), Yellow 202(1) (designated name (INCI: Yellow 8)), Yellow 203 (designated name (INCI: Yellow 10, Yellow 10 Lake)), Yellow 204 (designated name (INCI: Yellow 11)), Yellow 401, Blue 1 (designated name (INCI: Blue 1, Blue 1 Lake)), Blue 2, Blue 201, Blue 205 (designated name (INCI: Blue 4)), Blue 404 (designated name), Green 3 (designated name (INCI: Green 3, Green 3 Lake)), Green 201 (designated name (INCI: Green 5)), Green 202 (designated name (INCI: Green 6)), Green 204 (designated name (INCI: Green 8)), Green 205 (designated name), Orange 201 (designated name (INCI: Orange 5)), Orange 203 (designated name (INCI: Pigment Orange 5)), Orange 204 (designated name), Orange 205 (designated name (INCI: Orange 4, Orange 4 Lake)), Orange 206 (designated name (INCI: Orange 10)), Orange 207 (designated name (INCI: Orange 11)) and other coal-tar pigments, carminic acid (INCI), laccaic acid (designated name (INCI: Laccaic Acid)), safflower red (designated name (INCI: Carthamus Tinctorius (Safflower) Flower Extract)), Lithospermum officinale root extract (designated name (INCI: Lithospermum OfficinaleNatural pigments such as Root Extract, Gardenia Yellow (indicated name), Gardenia Blue (indicated name (INCI: Hydrolyzed Gardenia Florida Extract)), etc.

[0159] · Inorganic / organic composite powder

[0160] As the inorganic / organic composite powder, for example, a composite powder in which the surface of the inorganic powder is coated with an organic powder by a publicly known and commonly used method can be cited.

[0161] Furthermore, the above-mentioned powder can also use a product in which the particle surface has been treated. In addition, from the viewpoint of the water resistance of the cosmetic, the surface treatment agent preferably can impart hydrophobicity. There is no particular limitation as the treatment agent for imparting hydrophobicity, and examples thereof include silicone treatment agents, waxes, paraffins, organic fluorine compounds such as perfluoroalkyls and phosphates, surfactants, amino acids such as N-acylglutamic acid, and metal soaps such as aluminum stearate and magnesium myristate. More preferably, it is a silicone treatment agent, and examples thereof include silanes or silylating agents such as triethoxyoctylsilane (INCI), dimethylpolysiloxane (INCI), methylpolysiloxane (INCI), hydrogen dimethylpolysiloxane (INCI), triethoxysilylethylpolydimethylsiloxysilylethyldimethylpolysiloxane (INCI), triethoxysilylethylpolydimethylsiloxysilylethylhexyldimethylpolysiloxane (INCI), (acrylate / acrylate tridecyl ester / methacrylate triethoxysilylpropyl ester / methacrylate dimethicone) copolymer (indicated name (INCI: Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / Dimethicone Methacrylate Copolymer)), etc. Specific examples of these silicone treatment agents include those manufactured by Shin-Etsu Chemical Co., Ltd.: AES-3083, KF-99P, KF-9901, KF-9908, KF-9909, KP-574, KP-541, etc.

[0162] Furthermore, the above-mentioned surface hydrophobizing treatment agent can be used alone or in combination of two or more. Specific examples of the colored pigment subjected to surface treatment include those manufactured by Shin-Etsu Chemical Co., Ltd.: KTP-09 series, especially KTP-09W, KTP-09R, KTP-09Y, KTP-09B, etc.

[0163] (5) A composition composed of a crosslinked organopolysiloxane and an oil agent that is liquid at room temperature

[0164] In a composition composed of a crosslinked organopolysiloxane and an oil agent that is liquid at room temperature, it is preferred that the crosslinked organopolysiloxane swells with respect to the liquid oil by an amount greater than or equal to the weight of the liquid oil agent. As the liquid oil agent, the organopolysiloxane in the present invention can be used, and liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, etc., and fluorine-based oil in the optional component (1) can be used. For example, cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isocetane (INCI), glyceryl triisooctanoate (INCI), isotridecyl isononanoate (designated name (INCI: Isotridecyl Isononanoate)), squalane (INCI), etc. can be cited.

[0165] (5) The component is different from the above-mentioned component (3) and is a compound that does not have a polyether or polyglycerol structure in its molecular structure. As specific examples, (dimethylsilicone / vinyl dimethylsilicone) crosslinked polymer (INCI), (dimethylsilicone / phenyl vinyl dimethylsilicone) crosslinked polymer (designated name (INCI: Dimethicone / Phenyl Vinyl dimethicone crosspolymer)), (vinyl dimethylsilicone / lauryl dimethylsilicone) crosslinked polymer (INCI), (lauryl poly(dimethylsiloxysilylethyl) dimethylsilicone / bis(vinyl dimethylsilicone)) crosslinked polymer (INCI), etc. can be cited.

[0166] As an example of a commercially available composition composed of a crosslinked organopolysiloxane and an oil agent that is liquid at room temperature, Shin-Etsu Chemical Co., Ltd.'s products such as KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-19, KSG-016F, KSG-18A, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-042Z, KSG-045Z, KSG-048Z, etc. can be cited.

[0167] (6) Film-forming agent

[0168] The film-forming agent is mainly compounded to further maintain the persistence of the effects of the cosmetic. Although there is no particular limitation, from the viewpoint of imparting water repellency, an organosilicon-based composition is preferred. Specifically, trimethylsilyloxy silicic acid, acrylic-organic silicon film-forming agent, organosilicon-modified norbornene, organosilicon-modified branched starch, etc. can be used.

[0169] Examples of the film-forming agent of the silicone-based composition include trimethylsilyloxy silicic acid (designated name (INCI: Trimethylsiloxysilicate)), (acrylate / dimethylpolysiloxane) copolymer (INCI), (norbornene / tris(trimethylsilyloxy)silylnorbornene) copolymer (INCI), tris(trimethylsilyloxy)silylpropylcarbamoyl pullulan (designated name (INCI: TrimethylsiloxysilylcarbamoylPullulan)), etc.

[0170] The film-forming agent can be dissolved in an oil agent that is liquid at room temperature in advance and then blended into the cosmetic. As the liquid oil agent, it can be the organopolysiloxane in the present invention, or a liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, etc. in the optional component (1) oil agent, or a fluorine-based oil. For example, cyclopentasiloxane (INCI), dimethylpolysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isocetane (INCI), glyceryl triisooctanoate (INCI), isotridecyl isononanoate (designated name (INCI: IsotridecylIsononanoate)), squalane (INCI), butyl acetate (designated name (INCI: Butyl Acetate)), etc. can be cited.

[0171] Specific examples of commercially available silicone film-forming agents include those manufactured by Shin-Etsu Chemical Co., Ltd.: KF-7312J, KP-545, KP-549, KP-543, NBN-30-ID, TSPL-30-ID, TSPL-30-D5, etc.

[0172] (7) Antiperspirant

[0173] When the cosmetic according to the present invention is a deodorant, an antiperspirant can be optionally blended. The antiperspirant is not particularly limited as long as it is a component that inhibits sweat production by astringing the skin, and general components can be widely used. For example, aluminum chlorohydroxide, aluminum hydroxyhalides such as allantoin aluminum chlorohydroxide, aluminum halides such as aluminum chloride, aluminum allantoin salt, tannic acid, oyster tannin, potassium aluminum sulfate, zinc oxide, zinc p-phenolsulfonate, burnt alum, (aluminum / zirconium) tetrachloride hydrate, (aluminum / zirconium) trichlorohydroxyglycine, etc. can be cited. In particular, as a component showing high effects, an antiperspirant active ingredient selected from aluminum halides, aluminum hydroxyhalides, and complexes or mixtures of them with zirconium oxyhalide and zirconium hydroxyoxyhalide is preferably used.

[0174] These antiperspirants can be dissolved in water for compounding, or the powder can be directly compounded into the preparation for use. Commercially available products can also be used as the antiperspirant. The commercially available products used can be in the form of a mixed raw material with other components. There is no particular limitation on the content of the antiperspirant, and it can be appropriately changed according to the compounding amount of other components. For the purpose of obtaining a deodorant with excellent antiperspirant effect and a deodorant with reduced irritation to the skin, its content is preferably in the range of 0.001 to 30% by mass, more preferably in the range of 0.01 to 20% by mass, based on the total deodorant.

[0175] (8) Antibacterial agent

[0176] The antibacterial agent is not particularly limited as long as it can obtain an anti-odor effect by inhibiting the proliferation of resident bacteria on the skin that produce the raw materials of body odor. For example, antibacterial agents such as triclosan, benzalkonium chloride, benzethonium chloride, chlorhexidine hydrochloride, chlorhexidine gluconate, halocarban, and m-cresol are generally used. In addition, substances with antibacterial properties such as dry distillation extracts of green tea, essential oils from herbs, and extracts can be compounded and used. As antibacterial agents with anti-odor effects such as essential oils and extracts from herbs, for example, green tea extract, lavender extract, Scutellaria baicalensis extract, Coptis chinensis extract, Phellodendron amurense extract, Artemisia capillaris extract, Aloe vera extract, Sophora flavescens root extract, Sasa albo-marginata leaf extract, garlic extract, Hamamelis virginiana extract, black tea extract, Salvia officinalis extract, Zanthoxylum bungeanum extract, Zingiber officinale root extract, Acorus calamus root extract, Hedera helix extract, Houttuynia cordata extract, peach fruit extract, peach leaf extract, Mentha arvensis extract, Ligusticum chuanxiong extract, Eucalyptus globulus leaf extract, peanut seed coat extract, Litchi chinensis extract, Sanguisorba officinalis extract, etc. can be used. One or a mixture of two or more plant extracts can be used.

[0177] (9) Other additives

[0178] Examples of other additives include oil-soluble gelling agents, ultraviolet absorption and scattering agents, preservatives, fragrances, salts, antioxidants, pH regulators, chelating agents, cooling agents, anti-inflammatory agents, skin beautifying components (whitening agents, cell activators, roughness improvers, blood circulation promoters, skin astringents, anti-seborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, etc.

[0179] · Oil-soluble gelling agent

[0180] Examples of the oil-soluble gelling agent include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as lauroyl glutamic acid (indicated name (INCI: Lauroyl Glutamic Acid)), α,γ-dibutylamine, etc.; dextrin fatty acid esters such as dextrin palmitate (indicated name (INCI: Dextrin Palmitate)), dextrin isostearate (indicated name (INCI: Dextrin Isostearate)), dextrin myristate (indicated name (INCI: Dextrin Myristate)), stearoyl inulin (indicated name (INCI: Stearoyl Inulin)), dextrin (palmitic acid / ethylhexanoic acid) ester (indicated name (INCI: Dextrin Palmitate / Ethylhexanoate)); sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; organically modified clay minerals of lithium montmorillonite such as distearyldimethylammonium lithium montmorillonite (INCI), stearalkonium lithium montmorillonite (INCI); stearalkonium bentonite (INCI), etc.

[0181] · Ultraviolet absorber and scatterer

[0182] Examples of the ultraviolet absorber and scatterer include particles that absorb and scatter ultraviolet rays such as fine titanium oxide, fine iron-containing titanium oxide, fine zinc oxide, fine cerium oxide, and their composites, and a dispersion obtained by previously dispersing these particles that absorb and scatter ultraviolet rays in an oil agent can also be used.

[0183] The oil agent can be the organopolysiloxane in the present invention, or a liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, etc. in the optional component (1) oil agent, and fluorine-based oil can be used. For example, cyclopentasiloxane (INCI), dimethylpolysiloxane (INCI), mineral oil (INCI), isododecane (INCI), isocetane (INCI), glyceryl triisooctanoate (INCI), isotridecyl isononanoate (indicated name (INCI: Isotridecyl Isononanoate)), squalane (INCI), etc. can be cited.

[0184] Specific examples of the dispersion obtained by previously dispersing particles that absorb and scatter ultraviolet rays in an oil agent include those manufactured by Shin-Etsu Chemical Co., Ltd.: SPD series (trade name), especially SPD-T5, T5L, Z5, Z5L, T6, Z6, T7, Z7L, etc.

[0185] · Preservative

[0186] Examples of preservatives include alkyl p - hydroxybenzoates, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, etc. Examples of antibacterial agents include benzoic acid, salicylic acid, phenol, sorbic acid, alkyl p - hydroxybenzoates, parachlorometacresol, hexachlorophene, triclocarban, fluorescein, phenoxyethanol, etc.

[0187] · Fragrance

[0188] Fragrances include natural fragrances and synthetic fragrances. Natural fragrances include plant - derived fragrances separated from flowers, leaves, woods, fruit peels, etc.; animal - derived fragrances such as musk and civet. Synthetic fragrances include hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols, aldehydes such as terpene aldehydes and aromatic aldehydes, ketones such as alicyclic ketones, esters such as terpene - based esters, lactones, phenols, oxides, nitrogen - containing compounds, acetals, etc.

[0189] · Salts

[0190] Examples of salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, etc. of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, nitric acid. Examples of organic acid salts include salts of organic acids such as acetic acid, dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, stearic acid. Examples of amine salts and amino acid salts include salts of amines such as triethanolamine and salts of amino acids such as glutamic acid. In addition, salts of hyaluronic acid, chondroitin sulfate, aluminum zirconium glycine complex, etc., as well as neutralization salts of acids - bases used in cosmetic formulations can also be used.

[0191] · Antioxidants

[0192] There is no particular limitation on the antioxidant. For example, it includes carotenoids, ascorbic acid and its salts, stearyl ascorbate, tocopherol, tocopheryl acetate, tocotrienol, p - tert - butylphenol, butylated hydroxyanisole, dibutylhydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfites, sorbic acid and its salts, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, kaempferol, myricetin, quercetin, etc. The antioxidant can be used alone or in combination of two or more.

[0193] · pH adjusters

[0194] Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl - malic acid, potassium carbonate, sodium bicarbonate, ammonium bicarbonate, etc.

[0195] · Chelating agents

[0196] As chelating agents, alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid, etc. can be mentioned.

[0197] ·Cooling agent

[0198] As cooling agents, L-menthol, camphor, etc. can be mentioned.

[0199] ·Anti-inflammatory agent

[0200] As anti-inflammatory agents, allantoin, glycyrrhizic acid and its salts, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, azulene, etc. can be mentioned.

[0201] ·Skin beautifying ingredients

[0202] As skin beautifying ingredients, whitening agents such as placenta extract, arbutin, glutathione, saxifrage extract, etc., cell activators such as royal jelly, photosensitizer, cholesterol derivatives, calf blood extract, etc.; skin roughness improvers, vanillyl nonamide, benzyl nicotinate, β-butoxyethyl nicotinate, capsaicin, gingerone, cantharidin tincture, ichthammol, caffeine, tannic acid, α-terpineol, tocopheryl nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, triazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, etc. for promoting blood circulation, skin astringents such as zinc oxide, tannic acid, etc., anti-seborrheic agents such as sulfur, methylthiophenol, etc. can be mentioned.

[0203] ·Vitamins

[0204] As vitamins, vitamin A oils such as vitamin A oil, retinol, retinol acetate, retinol palmitate, etc., vitamin B2s such as riboflavin, riboflavin butyrate, flavin adenine dinucleotide, etc., vitamin B6s such as pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmitate, etc., vitamin B 12 and its derivatives, vitamin B 15 and its derivatives and other vitamin Bs, vitamin Cs such as L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, dipotassium L-ascorbic acid phosphate diester, etc., vitamin Ds such as calciferol, cholecalciferol, etc., vitamin Es such as α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, dl-α-tocopherol succinate, etc.; nicotinic acids such as nicotinic acid, benzyl nicotinate, nicotinamide, etc., vitamin H, vitamin P, calcium pantothenate, D-panthenol, panthenol ethyl ether, acetyl panthenol ethyl ether and other pantothenic acids, biotin, etc.

[0205] ·Amino acids

[0206] As amino acids, glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, tryptophan, etc. can be mentioned.

[0207] · Nucleic acid

[0208] Examples of the nucleic acid include deoxyribonucleic acid and the like.

[0209] · Hormone

[0210] Examples of the hormone include estradiol, vinyl estradiol and the like.

[0211] · Inclusion compound

[0212] Examples of the inclusion compound include cyclodextrin and the like.

[0213] The cosmetic of the present invention is not particularly limited. For example, it can be applied to various products such as lotion, essence, emulsion, cream, hair care, foundation, makeup base, sunscreen, concealer, blush, lipstick, brightener, balm, mascara, eyeshadow, eyeliner, body makeup, deodorant, nail cosmetics and the like. Among these, makeup cosmetics such as foundation, makeup base, sunscreen, concealer, blush, lipstick, brightener and the like, and preparations having a sunscreen effect are particularly preferred. As the property of the cosmetic of the present invention, various properties such as liquid, paste, solid, paste, gel, mousse, spray, clay, powder, stick and the like can be selected.

[0214] The form of the above cosmetic can be any of emulsion type, oil type and water type. When an oily feeling is to be imparted, an oil-based composition or an emulsified form is selected. As the emulsified form, it can be any of O / W type emulsion, W / O type emulsion, O / W / O type emulsion, W / O / W type emulsion. When a fresh feeling of use is to be obtained, a water-based composition or a powder composition can be selected, and a good cosmetic can be obtained in all cases.

[0215] Examples

[0216] Manufacturing examples, examples and comparative examples of the cosmetic of the present invention are shown below to specifically illustrate the present invention. The present invention is not limited by the following examples. Further, unless otherwise specified, "%" of the composition described below means "mass%". The total mass of each example is set to 100 mass%, and the mass% of each component is represented, and the compounding amount is the compounding amount of the compounded product described. The bonding order of the siloxane is not limited by the following. It should be noted that the surface tension is a value measured at 25 °C by the Wilhelmy method using a surface tension meter (manufactured by Kyowa Interface Science Co., Ltd., device name: DY-700). In the formula, n-Bu represents n-butyl. The terminal that is not bonded and not particularly described in the formula is "-CH3", and the terminal of the double bond is "CH2=CH2-".

[0217] [Manufacturing Example 1]

[0218] Charge the following formula into the reactor

[0219] [Chemical Formula 10]

[0220]

[0221] 144 g of the compound represented, 0.05 g of an ethanol solution (0.5%) of chloroplatinic acid divinyl disiloxane complex were made to 80°C while stirring. 100 g of 1,1,1,3,5,5,5-heptamethyltrisiloxane was dropped therein to keep the temperature below 100°C, and it was cured at 100°C for 5 hours. Using 1 1H-NMR, disappearance of the hydrosilyl group was confirmed. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 25.6 mN / m. In addition, there was no change in weight at 25°C in air, and it was non-volatile.

[0222] [Chemical Formula 11]

[0223]

[0224] [Production Example 2]

[0225] In a reactor, 431 g of the compound represented by the following formula

[0226] [Chemical Formula 12]

[0227]

[0228] and 0.08 g of an ethanol solution (0.5%) of chloroplatinic acid divinyl disiloxane complex were made to 80°C while stirring. 350 g of 1,1,1,3,5,5,5-heptamethyltrisiloxane was dropped therein to keep the temperature below 100°C, and it was cured at 100°C for 5 hours. Using 1 1H-NMR, disappearance of the hydrosilyl group was confirmed. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 24.2 mN / m. In addition, there was no change in weight at 25°C in air, and it was non-volatile.

[0229] [Chemical Formula 13]

[0230]

[0231] [Production Example 3]

[0232] In a reactor, the compound represented by the following formula

[0233] [Chemical Formula 14]

[0234]

[0235] 520 g of the represented compound and 0.1 g of an ethanol solution (0.5%) of chloroplatinic acid divinyldisiloxane complex were heated to 80°C with stirring. 160 g of tetramethyldisiloxane was added dropwise thereto while maintaining the temperature below 100°C, and the mixture was cured at 100°C for 5 hours. The disappearance of the hydrosilyl group was confirmed by 1 1H-NMR. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 25.5 mN / m. In addition, there was no change in weight at 25°C in air, and it was non-volatile.

[0236] [Chemical Formula 15]

[0237]

[0238] [Production Example 4]

[0239] 1200 g of the compound represented by the following formula and 0.1 g of an ethanol solution (0.5%) of chloroplatinic acid divinyldisiloxane complex were placed in a reactor and heated to 80°C with stirring.

[0240] [Chemical Formula 16]

[0241]

[0242] 550 g of the methylhydrosiloxane represented by the following formula was added dropwise thereto while maintaining the temperature below 100°C, and the mixture was cured at 100°C for 5 hours. The disappearance of the hydrosilyl group was confirmed by

[0243] [Chemical Formula 17]

[0244]

[0245] 1H-NMR. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 27.0 mN / m. In addition, there was no change in weight at 25°C in air, and it was non-volatile. 1 1H-NMR. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 27.0 mN / m. In addition, there was no change in weight at 25°C in air, and it was non-volatile.

[0246] [Chemical Formula 18]

[0247]

[0248] [Production Example 5]

[0249] 1200 g of the compound represented by the following formula and 0.1 g of an ethanol solution (0.5%) of chloroplatinic acid divinyldisiloxane complex were placed in a reactor and heated to 80°C with stirring.

[0250] [Chemical Formula 19]

[0251]

[0252] 690 g of the represented compound, 0.2 g of an ethanol solution (0.5%) of chloroplatinic acid divinyl disiloxane complex, and while stirring, the temperature was made 80°C. Dropwise added thereto was 280 g of methylhydrogensiloxane represented by the following formula while maintaining the temperature below 100°C, and it was cured at 100°C for 5 hours. The disappearance of the hydrosilyl group was confirmed by

[0253] [Chemical formula 20]

[0254]

[0255] 1H-NMR. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 27.9 mN / m. In addition, the weight did not change at 25°C in air and it was non-volatile. 1 1H-NMR confirmed the disappearance of the hydrosilyl group. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 27.9 mN / m. In addition, the weight did not change at 25°C in air and it was non-volatile.

[0256] [Chemical formula 21]

[0257]

[0258] [Production Example 6]

[0259] 220 g of the compound represented by the following formula and 0.08 g of an ethanol solution (0.5%) of chloroplatinic acid divinyl disiloxane complex were charged into a reactor, and while stirring, the temperature was made 80°C. 220 g of 1,1,1,3,5,5,5-heptamethyltrisiloxane was dropwise added thereto while maintaining the temperature below 100°C, and it was cured at 100°C for 5 hours. The disappearance of the hydrosilyl group was confirmed by

[0260] [Chemical formula 22]

[0261]

[0262] 1H-NMR. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane having the following structure was obtained. The surface tension of the obtained organopolysiloxane was 24.3 mN / m. In addition, the weight did not change at 25°C in air and it was non-volatile. 1 1H-NMR confirmed the disappearance of the hydrosilyl group. The reaction solution was stripped under reduced pressure at 140°C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane having the following structure was obtained. The surface tension of the obtained organopolysiloxane was 24.3 mN / m. In addition, the weight did not change at 25°C in air and it was non-volatile.

[0263] [Chemical formula 23]

[0264]

[0265] [Production Example 7]

[0266] 220 g of the compound represented by the following formula and 0.08 g of an ethanol solution (0.5%) of chloroplatinic acid divinyl disiloxane complex were charged into a reactor, and while stirring, the temperature was made 80°C. 220 g of 1,1,1,3,5,5,5-heptamethyltrisiloxane was dropwise added thereto while maintaining the temperature below 100°C, and it was cured at 100°C for 5 hours. The disappearance of the hydrosilyl group was confirmed by

[0267] [Chemical formula 24]

[0268]

[0269] 440 g of the represented compound, 0.1 g of an ethanol solution (0.5%) of chloroplatinic acid divinyldisiloxane complex were made to 80 °C with stirring. Dropwise added thereto was 410 g of a methylhydrogensiloxane represented by the following formula

[0270] [Chemical formula 25]

[0271]

[0272] while maintaining the temperature below 100 °C, and curing was carried out at 100 °C for 5 hours. The disappearance of the hydrosilyl group was confirmed by 1 1H-NMR. The reaction solution was stripped under reduced pressure at 140 °C to remove unreacted substances and the like, and a pale yellow transparent organopolysiloxane represented by the following formula was obtained. The surface tension of the obtained organopolysiloxane was 26.5 mN / m. In addition, there was no change in weight at 25 °C in air and it was non-volatile.

[0273] [Chemical formula 26]

[0274]

[0275] n-Bu is n-butyl.

[0276] The organopolysiloxanes obtained in Production Examples 1 and 2 were evaluated as follows.

[0277] [Solubility test of organopolysiloxane, volatile organosilicon and ethylhexyl methoxycinnamate (organic ultraviolet absorber)]

[0278] A solubility test of the organopolysiloxanes obtained in Production Examples 1 and 2 with a volatile organosilicon and ethylhexyl methoxycinnamate (organic ultraviolet absorber) was carried out. The results are shown in Table 1.

[0279] (Evaluation method)

[0280] The organopolysiloxanes obtained in Production Examples 1 and 2, undecamethylpentasiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-96L-2cs) as a volatile organosilicon, and ethylhexyl methoxycinnamate (sometimes denoted as OMC) were taken in the mass ratios shown in Table 1, shaken and mixed at room temperature, and the dissolution state the next day was observed. The dissolution states are shown below.

[0281] ○: Dissolved, uniformly dispersed

[0282] ×: Separated

[0283] [Table 1]

[0284]

[0285] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-96L-2cs

[0286] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-56A

[0287] As shown in Table 1, it can be seen that the organopolysiloxanes obtained in Production Examples 1 and 2 of the present invention have compatibility equal to or higher than that of the diphenylsilanoxy phenyltrimethylpolysiloxane (compatibilizer) used in the past and higher than that of octylmethylpolysiloxane when the volatile silicone and ethylhexyl methoxycinnamate are uniformly mixed.

[0288] [Solubility Test of Organopolysiloxane and Oil-Based Component Solid at 25°C]

[0289] The solubility of the organopolysiloxanes obtained in Production Examples 1 and 2 in the oil-based component solid at 25°C was evaluated by the method shown below. The evaluation results are shown in Table 2.

[0290] (Evaluation Method)

[0291] An oil-based component solid at 25°C and the organopolysiloxane or other silicone obtained in Production Examples 1 and 2 were taken at a mass ratio of 1:9, heated at 90°C for 20 minutes, and the dissolution state was visually observed. The evaluation was carried out according to the following criteria, and the results were recorded in Table 2.

[0292] ◎: Uniform dissolution

[0293] △: Uniform dispersion (turbid)

[0294] ×: Separation

[0295] [Table 2]

[0296]

[0297] As shown in Table 2, it can be seen that the organopolysiloxanes obtained in Production Examples 1 and 2 of the present invention have solubility equal to or higher than that of the compatibilizer used in the past and exceeding it when uniformly mixed with the oil-based component solid at 25°C.

[0298] The effects of the present invention are shown below using Examples and Comparative Examples related to cosmetics.

[0299] [Examples 1 and 2, Comparative Examples 1 to 3] W / O Type Sunscreen Milk

[0300] For Examples 1 and 2, the organopolysiloxanes obtained in Production Examples 1 and 2 were used. For Comparative Examples 1 to 3, the organopolysiloxanes obtained in Production Examples 1 and 2 were not used, and a W / O type sunscreen milk was produced according to the following production method. The compositions of Examples 1 and 2 and Comparative Examples 1 to 3 are shown in Table 3.

[0301] [Table 3]

[0302]

[0303] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Diphenylsilanoxy phenyl trimethyl polysiloxane

[0304] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 70 - 80% dimethyl polysiloxane + 20 - 30% dimethyl polysiloxane / (PEG-10 / 15) crosslinked polymer (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 80 - 85% diphenylsilanoxy phenyl trimethyl polysiloxane + 15 - 20% crosslinked phenyl-modified dimethyl polysiloxane (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: Cetyl PEG / PPG-10 / 1 dimethyl polysiloxane

[0305] [Production Method]

[0306] Stir Components 1 to 12 and mix until homogeneous. Separately, dissolve Components 13 to 16 uniformly in Component 17, gently add the above mixture of Components 1 to 12, stir, and make an emulsion. Fill it into a specified container to obtain a W / O type sunscreen milk.

[0307] For the obtained W / O type sunscreen milk, a usage test was conducted by a panel of 10 experts for (1) feeling of lightness, (2) good spreadability, (3) smoothness of the film, and (4) non-glaring, and the evaluation was carried out using the following scoring. The average score of the evaluation was calculated, and the results are shown in Table 4 based on the following evaluation criteria.

[0308] In addition, the state of the cosmetic after standing at 40°C for one month (5) and the state of the cosmetic after standing at 5°C for one month (6) were observed. The results are shown in Table 4.

[0309] (Scoring)

[0310] 5 points: Very good

[0311] 4 points: Good

[0312] 3 points: Ordinary

[0313] 2 points: Slightly poor

[0314] 1 point: Poor

[0315] For the obtained average score, it is judged with ○× according to the following criteria.

[0316] (Evaluation Criteria)

[0317] ◎: The average score is 4.5 or more.

[0318] ○: The average score is more than 3.5 and less than 4.5.

[0319] △: The average score is more than 2.5 and less than 3.5.

[0320] ×: The average score is more than 1.5 and less than 2.5.

[0321] ××: The average score is less than 1.5.

[0322] [Table 4]

[0323]

[0324] As shown in Table 4, it was confirmed that the sunscreen milks of Examples 1 and 2 are sunscreen milks that are light in feeling, have good spreadability, have a smooth makeup film, and are not eye-stinging, as compared with Comparative Examples 1 and 3. In addition, it was also found to be a sunscreen milk with excellent storage stability. Although the sunscreen milk of Comparative Example 2 had a good feeling result, the storage stability was a poor result.

[0325] [Examples 3 and 4, Comparative Examples 4 and 5] Stick-type W / O foundation

[0326] For Examples 3 and 4, the organopolysiloxanes obtained in Production Examples 1 and 2 were used, and for Comparative Examples 4 and 5, the organopolysiloxanes obtained in Production Examples 1 and 2 were not used, and a stick-type W / O foundation was produced according to the following production method. The compositions of Examples 3 and 4 and Comparative Examples 4 and 5 are shown in Table 5.

[0327] [Table 5]

[0328]

[0329] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Diphenylsilanoxy phenyl trimethyl polysiloxane

[0330] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: Mixture of 70 - 80% dimethyl polysiloxane + 20 - 30% (dimethyl polysiloxane / polyglycerol-3) crosslinked polymer (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 polydimethylsilanyloxyethyl dimethyl polysiloxane (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-9909-treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (Note 5) Manufactured by Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethyl polysiloxane / methyl polysiloxane silsesquioxane) crosslinked polymer

[0331] [Manufacturing Method]

[0332] A: Mix components 11 - 14 in a part of component 5 and disperse with a roll mill.

[0333] B: Heat and dissolve components 1 - 4, the remaining part of component 5, components 6 - 10, and 15, and mix them.

[0334] C: Mix components 16 and 17 and heat them.

[0335] D: Slowly add the mixture obtained in C to the mixture obtained in B and stir to form an emulsion.

[0336] E: Add the mixture obtained in A to the emulsion obtained in D, stir, pour into a mold, cool and solidify to obtain a stick - shaped W / O type foundation.

[0337] For the obtained stick - shaped W / O type foundation, regarding (1) good spreadability, (2) smoothness of the film, (3) non - glaring property, (4) lightness of the makeup film, a professional evaluation group of 10 women was used for the usage test, and the following scoring was used for evaluation. The average score of the evaluation was calculated, and based on the following evaluation criteria, the results are shown in Table 6.

[0338] In addition, regarding (5) the state of the cosmetic after being left standing at 40°C for one month and (6) the state of the cosmetic after being left standing at 5°C for one month, observations were also made. The results are shown in Table 6.

[0339] (Scoring)

[0340] 5 points: Very good

[0341] 4 points: Good

[0342] 3 points: Ordinary

[0343] 2 points: Slightly poor

[0344] 1 point: Poor

[0345] For the obtained average score, according to the following criteria, it is judged with ○×.

[0346] (Evaluation Criteria)

[0347] ◎: The average score is 4.5 points or more

[0348] ○: The average score is more than 3.5 points and less than 4.5 points

[0349] △: The average score is more than 2.5 points and less than 3.5 points

[0350] ×: The average score is more than 1.5 points and less than 2.5 points

[0351] ××: Less than 1.5 points on average

[0352] [Table 6]

[0353]

[0354] As can be seen from Table 6, it is confirmed that the foundations of Examples 3 and 4 are foundations with good spreading, smoothness, non-glaring, and a light film feeling after coating compared with Comparative Example 4. In addition, it is also known that the foundation has excellent storage stability. Although the foundation of Comparative Example 5 has a good result in terms of feeling, it has a poor result in terms of storage stability.

[0355] [Example 5] Sunscreen lotion (shaken)

[0356]

[0357]

[0358] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 80-90% diphenylsilanoxy phenyl trimethyl polysiloxane + 10-20% (dimethyl polysiloxane / phenyl vinyl dimethyl polysiloxane) crosslinked polymer

[0359] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 polydimethylsiloxanylethyl dimethyl polysiloxane

[0360] (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: A solution of 70% cyclopentasiloxane + 30% (acrylate / dimethyl polysiloxane) copolymer

[0361] (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethyl polysiloxane / methyl polysiloxane silsesquioxane) crosslinked polymer

[0362] (Note 5) Manufactured by Shin-Etsu Chemical Co., Ltd.: A cyclopentasiloxane dispersion of 40% fine titanium oxide

[0363] (Note 6) Manufactured by Shin-Etsu Chemical Co., Ltd.: A cyclopentasiloxane dispersion of 60% fine zinc oxide

[0364] (Manufacturing method)

[0365] A: Mix Components 1 to 10 uniformly.

[0366] B: Add Component 11 to the mixture obtained in A and disperse it uniformly.

[0367] C: Add Components 14 to 17 to Component 18 and dissolve.

[0368] D: The mixture obtained in C was slowly added to B. After emulsification, Components 12 and 13 were added to obtain a sunscreen lotion.

[0369] It was found that the sunscreen lotion obtained as described above spreads easily, is dry and non-sticky, and shows no changes due to temperature or time. Its usability and stability are both excellent.

[0370] [Example 6] Sunscreen

[0371]

[0372]

[0373] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: lauryl polyglyceryl-3 polydimethylsiloxane oxyethyl dimethyl polysiloxane

[0374] (Manufacturing method)

[0375] A: Components 1 to 9 were uniformly mixed.

[0376] B: Components 10 to 13 were uniformly dissolved in Component 14.

[0377] C: The mixture obtained in B was slowly added to the mixture obtained in A with stirring, and emulsified to obtain a sunscreen.

[0378] It was found that the sunscreen obtained as described above has a delicate texture, spreads easily, is moist and fresh, and is non-sticky, so it has no sense of abrasion at all and its usability is very good. In addition, it was found that there are no changes due to temperature or time, and its stability is also excellent.

[0379] [Example 7] Sunscreen

[0380]

[0381]

[0382] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: a mixture of 65 - 75% mineral oil + 25 - 35% (PEG-15 / dodecyldimethyl polysiloxane) crosslinked polymer

[0383] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: a mixture of 80 - 90% diphenylsilanoxy phenyl trimethyl polysiloxane + 10 - 20% (dimethyl polysiloxane / phenyl vinyl dimethyl polysiloxane) crosslinked polymer

[0384] (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: cetyl PEG / PPG-10 / 1 dimethyl polysiloxane

[0385] (Note 4) Shin-Etsu Chemical Co., Ltd.: Cyclopentasiloxane solution of 50% trimethylsilyloxy silicic acid

[0386] (Manufacturing method)

[0387] A: Uniformly mix Components 1 - 9.

[0388] B: Uniformly dissolve Components 10 - 13 in Component 14.

[0389] C: Slowly add the mixture obtained in B to the mixture obtained in A under stirring and emulsify to obtain a sunscreen.

[0390] The sunscreen obtained as described above spreads easily, is moist and non-sticky, and in addition, the film is uniform and has high water repellency, so the makeup lasts well, and thus the UV protection effect also persists. In addition, it is found that there are no changes due to temperature or time, and the usability and stability are both very excellent.

[0391] [Example 8] Non-aqueous mousse-like foundation

[0392]

[0393]

[0394] (Note 1) Shin-Etsu Chemical Co., Ltd.: Mixture of 75 - 85% cyclopentasiloxane + 15 - 25% (dimethylpolysiloxane / (PEG - 10 / 15)) cross-linked polymer

[0395] (Note 2) Fumed silica with surface hydrophobization treatment, manufactured by NIPPON AEROSIL CO., LTD.: Aerosil R - 972

[0396] (Note 3) Shin-Etsu Chemical Co., Ltd.: KF - 9909 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black

[0397] (Note 4) Shin-Etsu Chemical Co., Ltd.: Triethoxysilylethyl polydimethylsiloxysilylethyl hexyl dimethylpolysiloxane

[0398] (Note 5) Shin-Etsu Chemical Co., Ltd.: Cyclopentasiloxane solution of 50% trimethylsilyloxy silicic acid

[0399] (Note 6) Shin-Etsu Chemical Co., Ltd.: Polysiloxane - 1 cross-linked polymer

[0400] (Note 7) Shin-Etsu Chemical Co., Ltd.: Polymethylsilsesquioxane

[0401] (Manufacturing method)

[0402] Components 1 to 10 were uniformly mixed by roll processing. Components 11 to 17 were added to the mixture and mixed to be uniform, obtaining a non-aqueous rubbed filamentous foundation.

[0403] It was confirmed that the appearance of the non-aqueous rubbed filamentous foundation obtained as described above was firmly solidified into a rubbed filamentous form, spread easily, did not stick, had no greasy feeling, had excellent usability, and the makeup retention was also very good. In addition, there was no exudation of oil due to temperature or aging, and the stability was also excellent.

[0404] [Example 9]

[0405] Non-aqueous anti-wrinkle eye cream

[0406]

[0407] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 70 - 80% dimethylpolysiloxane + 20 - 30% (dimethylpolysiloxane / (PEG - 10 / 15)) crosslinked polymer

[0408] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 70 - 80% mineral oil + 20 - 30% (vinyldimethylpolysiloxane / lauryldimethylpolysiloxane) crosslinked polymer

[0409] (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 90 - 96% cyclopentasiloxane + 4 - 10% (dimethylpolysiloxane / vinyldimethylpolysiloxane) crosslinked polymer

[0410] (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: Ethylmethylpolysiloxane

[0411] (Note 5) Manufactured by Shin-Etsu Chemical Co., Ltd.: (Vinyldimethylpolysiloxane / methylpolysiloxane silsesquioxane) crosslinked polymer

[0412] (Note 6) Manufactured by Shin-Etsu Chemical Co., Ltd.: A 20% solution of dimethylpolysiloxane (high polymerization) in cyclopentasiloxane

[0413] (Manufacturing method)

[0414] A: Components 1 to 8 were uniformly mixed to obtain a non-aqueous anti-wrinkle eye cream.

[0415] It was found that the non-aqueous anti-wrinkle eye cream obtained as described above spread easily, did not stick, had no greasy feeling, gave a moist and skin-friendly usability, and at the same time had no changes due to temperature or aging, and the stability was also excellent.

[0416] [Example 10] Rinse-off type facial mask cosmetic

[0417]

[0418] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Polyglycerin-3 disiloxane dimethylpolysiloxane

[0419] (Manufacturing method)

[0420] A: Mix Components 1 - 3 and 8.

[0421] B: After uniformly mixing Components 5 - 7 and 10, mix and stir Components 4 and 9.

[0422] C: Add the mixture obtained in A to the mixture obtained in B, emulsify to obtain a paste-type rinse-off facial mask cosmetic.

[0423] It can be seen that the rinse-off facial mask cosmetic obtained as described above spreads easily during coating, has excellent cleaning effect, and after rinsing, has a feeling of moistness, non-stickiness, and smooth skin, has a very excellent usability, and also has excellent stability.

[0424] [Example 11] Eye shadow

[0425]

[0426] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Methyltrimethylpolysiloxane

[0427] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: A solution of 60% isododecane + 40% (acrylate / dimethylpolysiloxane) copolymer

[0428] (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: (Acrylate / stearyl acrylate / dimethylpolysiloxane methacrylate) copolymer

[0429] (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: Polysiloxane-22

[0430] (Note 5) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 70 - 80% isododecane + 20 - 30% (PEG-15 / dimethyldodecylpolysiloxane) crosslinked polymer

[0431] (Note 6) Fumed silica with surface hydrophobization treatment, manufactured by NIPPON AEROSIL CO., LTD.: Aerosil R-972

[0432] (Note 7) Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, Y: yellow

[0433] (Note 8) Manufactured by Shin-Etsu Chemical Co., Ltd.: Triethoxysilylethyl polydimethylsilanyloxyethyl hexyl dimethylpolysiloxane

[0434] (Manufacturing method)

[0435] A: Mix components 1 - 9 and disperse them evenly.

[0436] B: Add components 10 - 16 to the mixture obtained in A and disperse them evenly to obtain an eye shadow.

[0437] The eye shadow obtained as described above is also easily removable, spreads smoothly, and has a non-greasy and non-powdery feel when applied. In addition, it has been confirmed to have good water resistance, water repellency, and sweat resistance, good makeup retention, is not prone to smudging, and has no changes due to temperature variations or over time, indicating excellent stability.

[0438] [Example 12] Eyeliner

[0439]

[0440] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Dimethylpolysiloxane (6 cs)

[0441] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 75 - 85% isododecane + 15 - 25% (vinyl dimethicone / methicone) crosspolymer (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 polydimethylsiloxysethyl dimethicone

[0442] (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: Hydrogen dimethylpolysiloxane

[0443] (Manufacturing method)

[0444] A: Heat and mix components 1 - 6, and add component 7, then disperse evenly.

[0445] B: Heat and dissolve components 8 - 10.

[0446] C: Slowly add the mixture obtained in B to the mixture obtained in A with stirring, and emulsify to obtain an eyeliner.

[0447] It can be seen that the eyeliner obtained as described above spreads smoothly, has no greasy or powdery feel, gives a moist and refreshing application feel, has good water resistance, water repellency, and sweat resistance, good makeup retention, is not prone to smudging, has no changes due to temperature or over time, and has excellent stability.

[0448] [Example 13] W / O Cleansing Cream

[0449]

[0450] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Diphenyldimethylpolysiloxane (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: PEG-10 dimethylpolysiloxane

[0451] A: Heat and mix Components 1 to 8.

[0452] B: Heat and dissolve Components 9 to 12 and 14.

[0453] C: Slowly add the mixture obtained in B to the mixture obtained in A with stirring, emulsify, cool, and add Component 13 to obtain a W / O makeup remover cream.

[0454] It can be seen that the W / O makeup remover cream obtained as described above has a delicate texture, spreads easily, is non-sticky, has no greasy feeling, gives a moist, fresh and cool feeling during use, and at the same time has a high makeup removal effect, no changes caused by temperature or time, and excellent stability.

[0455] [Example 14] Cream Lipstick

[0456]

[0457] (Note 1) Manufactured by Chiba Kosan Co., Ltd.: Rheopearl TT

[0458] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: A solution of 70% cyclopentasiloxane + 30% (acrylate / dimethylpolysiloxane) copolymer

[0459] (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 65 - 75% glyceryl triisooctanoate + 25 - 35% (vinyl dimethylpolysiloxane / lauryl dimethylpolysiloxane) crosslinked polymer

[0460] (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxysilylethyl dimethylpolysiloxane

[0461] (Manufacturing method)

[0462] A: Mix Component 9 in a part of Component 2, disperse using a roll mill, and then heat and mix the resulting dispersion with Component 1, the remaining part of Component 2, and Components 3 to 6.

[0463] B: Heat Components 7 and 8, add them to the mixture obtained in A, emulsify, and then cool.

[0464] C: Add Component 10 to the emulsion obtained in B to obtain a cream lipstick.

[0465] The obtained cream lipstick spreads easily, is non-sticky, has no greasy feeling, and forms a film with good staying power on the lips.

[0466] [Example 15] Mascara

[0467]

[0468] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyaethyl Dimethicone

[0469] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: A solution of 60% isododecane + 40% (acrylate / dimethylpolysiloxane) copolymer

[0470] (Note 3) Manufactured by Chiba Flour Milling Co., Ltd.: Rheopearl TT

[0471] (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: (acrylate / behenyl acrylate / dimethylpolysiloxane methacrylate) copolymer

[0472] (Note 5) Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-9909-treated colored inorganic pigment, B: black

[0473] (Manufacturing method)

[0474] A: Mix components 1 to 3 evenly.

[0475] B: Heat and stir components 4 to 10 to dissolve them, add the mixture obtained in A and the pulverized components 11, 12, 13, mix to be uniform and then cool.

[0476] The mascara obtained as described above is non-sticky, spreads easily, is easy to apply to the eyelashes, and has very good makeup retention.

[0477] [Example 16] Makeup Remover

[0478]

[0479] (Manufacturing method)

[0480] A: Mix components 1 to 6 evenly.

[0481] B: Stir and dissolve components 7 and 8, add them to the mixture obtained in A, mix to be uniform, and obtain the makeup remover.

[0482] The makeup remover obtained as described above is non-sticky, spreads easily to form a uniform oil film, and has a very high cleaning effect.

[0483] [Example 17] Deodorant Stick

[0484]

[0485]

[0486] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Cetyl PEG / PPG-10 / 1 Dimethicone

[0487] (Manufacturing method)

[0488] A: Heat and dissolve Components 2 to 4, 7 to 10, and mix them.

[0489] B: Uniformly mix Components 1 and 5 in A, and use a mixer to uniformly disperse and mix them.

[0490] C: Add Component 6 and mix uniformly.

[0491] D: Cast into a mold and cool to solidify.

[0492] The deodorant stick obtained as described above has no excessive dry feeling or sticky feeling, and has excellent persistence of deodorant effect and excellent stability.

[0493] [Example 18] Non-aqueous deodorant cream

[0494]

[0495]

[0496] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: A mixture of 90 - 96% cyclopentasiloxane + 4 - 10% (dimethylpolysiloxane / vinyl dimethylpolysiloxane) cross-linked polymer

[0497] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: (Vinyl dimethylpolysiloxane / methyl polysilsesquioxane) cross-linked polymer

[0498] (Manufacturing method)

[0499] A: Heat Components 1 to 8 and mix them uniformly.

[0500] B: Uniformly mix Component 9 in A, and use a mixer to uniformly disperse and mix them.

[0501] C: Add Components 10 to 12 to the mixture obtained in B and mix them uniformly.

[0502] D: Add Component 13 to C, mix uniformly, and then fill into a container.

[0503] The non-aqueous deodorant cream obtained as described above spreads very smoothly, has good spreading property, has no excessive dry feeling or sticky feeling, and is a non-aqueous deodorant cream with excellent persistence of deodorant effect.

[0504] [Example 19] Hair oil

[0505]

[0506] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: A solution of 50% trimethylsilyloxy silicic acid in cyclopentasiloxane

[0507] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: Dimethylpolysiloxane (colloid dissolved matter)

[0508] (Manufacturing method)

[0509] A: Components 1 to 8 were uniformly mixed to obtain a hair oil.

[0510] The hair oil obtained as described above is a hair oil that spreads easily and imparts luster and smoothness to the hair.

[0511] [Example 20] Stick Lipstick

[0512]

[0513] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Cyclopentasiloxane solution of 50% trimethylsilyloxy silicic acid

[0514] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: Mixture of 65 - 75% glyceryl triisooctanoate + 25 - 35% alkyl-branched / crosslinked dimethylpolysiloxane

[0515] (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxysilylethyl dimethylpolysiloxane

[0516] (Manufacturing method)

[0517] A: Component 11 was mixed in a part of Component 2, dispersed using a roll mill, and the resulting dispersion was heated and mixed together with Component 1, the remaining part of Component 2, and Components 3 to 10.

[0518] B: It was cast into a mold and cooled and solidified to obtain a stick lipstick.

[0519] The obtained stick lipstick has good spreadability, forms a uniform film, and also has high water repellency, making it a lipstick with good makeup retention. In addition, it is known to be a lipstick with excellent storage stability.

[0520] [Example 21] Water-Isolated W / O Foundation

[0521]

[0522] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Mixture of 80% diphenylsilanoxy phenyl trimethyl polysiloxane + 20% dimethylpolysiloxane / (PEG-10 / 15)) crosslinked polymer

[0523] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: Mixture of 85% diphenylsilanoxy phenyl trimethyl polysiloxane + 15% (dimethylpolysiloxane / phenyl vinyl dimethylpolysiloxane) crosslinked polymer

[0524] (Note 3) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Dimethicone Silylethyl Dimethicone

[0525] (Note 4) Manufactured by Shin-Etsu Chemical Co., Ltd.: Lauryl Polyglyceryl-3 Dimethicone Silylethyl Dimethicone

[0526] (Note 5) Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-9909 Treated Colored Inorganic Pigment, W: White · R: Red · Y: Yellow · B: Black

[0527] (Note 6) Manufactured by Shin-Etsu Chemical Co., Ltd.: AES-3083 Treatment

[0528] (Manufacturing Method)

[0529] Preparation of oil phase: Uniformly mix Components 1 to 6.

[0530] Preparation of water phase: Uniformly mix Components 13 to 16.

[0531] Preparation of paste phase: Mix Components 8 to 12 in Components 6 to 7 and disperse using a three-roll mill.

[0532] Add the water phase to the oil phase smoothly for phase transfer, emulsify and then mix the pastes to obtain a water-separated W / O foundation.

[0533] The usability, water-separating property, and spreadability of the obtained water-separated W / O foundation were confirmed to be good.

[0534] [Example 22] Hair Treatment Cream

[0535]

[0536] (Note 1) Manufactured by Shin-Etsu Chemical Co., Ltd.: Mixture of 80 - 90% Diphenylsilanoxy Phenyl Trimethylpolysiloxane + 10 - 20% (Dimethylpolysiloxane / Phenyl Vinyl Dimethylpolysiloxane) Crosslinked Polymer

[0537] (Note 2) Manufactured by Shin-Etsu Chemical Co., Ltd.: Aminopropyl Dimethylpolysiloxane

[0538] (Manufacturing Method)

[0539] A: Heat Components 6 to 9 to 70°C and mix uniformly.

[0540] B: Heat Components 1 to 5 to 70°C and mix uniformly.

[0541] C: Add the mixture obtained in B to the mixture obtained in A, emulsify, cool slowly, and then add Components 10 and 11 to obtain a hair treatment cream.

[0542] The obtained hair cream has good usability and spreadability, and excellent storage stability.

[0543] It should be noted that the present invention is not limited to the above-described embodiments. The above-described embodiments are illustrative, and technical solutions having substantially the same constitution as the technical idea described in the patent claims of the present invention and achieving the same effects are included within the technical scope of the present invention.

Claims

1. A cosmetic composition containing an organopolysiloxane represented by the following formula (1): [Chemical formula 1] In the formula, R 1 is independently an alkyl group having 1 to 16 carbon atoms, R 2 is an organic group represented by the following formula (2), R 3 is R 1 or R 2 , x is an integer from 0 to 50, y is an integer from 0 to 50, and one or more of R 2 or R 3 are organic groups represented by the general formula (2). When y = 0, at least one R 3 is R 2 . Furthermore, the bonding of the siloxane units enclosed by the above x and y can be block or random, [Chemical formula 2] In formula (2), R 4 is a hydrogen atom or a methyl group, Q is an organic group selected from the linking groups represented by the following formulas (3) to (6): [Chemical formula 3] In the above formula (5), s is an integer from 0 to 3, t is an integer from 0 to 3, and the bonding of each oxyalkylene group may be block or random. When Q is the group of formula (3), m = 8 and n is an integer from 1 to 22. When Q is the group of formula (4), m is an integer from 1 to 10 and n is an integer from 7 to 22. When Q is the group of formula (5), m is an integer from 1 to 10 and n is an integer from 7 to 22. When Q is the group of formula (6), m is an integer from 1 to 10 and n is an integer from 7 to 22.

2. The cosmetic according to claim 1, wherein, The surface tension of the organopolysiloxane is 28 mN / m or less and it is non-volatile.

3. The cosmetic composition according to claim 1, further comprising an organic ultraviolet absorber.

4. The cosmetic according to claim 3, wherein, The organic ultraviolet absorber is one or more selected from ethylhexyl methoxycinnamate, diethylamino hydroxybenzoyl hexyl benzoate, octyl salicylate, polysiloxane-15, tert-butyl methoxydibenzoylmethane, benzophenone, methylene bis-benzotriazolyl tetramethylbutylphenol, bis-ethylhexyloxyphenol methoxyphenyl triazine, and octocrylene.

5. The cosmetic composition according to any one of claims 1 to 4, further comprising an oily component that is solid at 25°C.

6. The cosmetic according to claim 5, wherein, The oily component that is solid at 25°C is one or more selected from polyethylene, purified ceresin, natural ceresin, candelilla wax, carnauba wax, beeswax, microcrystalline wax, stearyl alcohol, behenyl alcohol, and cetyl alcohol.

Images