Method and device for wastewater treatment by synergistically regulating magnetic field reinforced micro-electrolysis

Abstract

The application provides a magnetic field synergistic regulation reinforced micro-electrolysis sewage treatment method and equipment, which comprises the following steps: adjusting the hydrogen ion concentration index of sewage to obtain adjusted sewage, pumping the adjusted sewage to the water inlet of a micro-electrolysis reaction tower by using a lifting pump, making the adjusted sewage pass through the aeration device of the aeration area to be aerated, and then entering the micro-electrolysis reaction tower through a supporting layer; the magnetic field generating device is composed of the enameled copper wire coil wound outside the micro-electrolysis reaction tower and the iron-carbon micro-electrolysis filler in the tower, a magnetic field is formed in the micro-electrolysis reaction tower, and the size and direction of the magnetic field are adjusted in real time according to the water quality of the effluent; the adjusted sewage treated by the magnetic field is overflowed to the water collecting tank through the trapezoidal overflow weir, the water quality of the effluent is detected in real time by the online water quality monitoring system below the effluent outlet; the hydrogen ion concentration index of the inlet water, the magnetic field parameters and the aeration amount are adjusted in linkage to regulate the micro-electrolysis reaction conditions. The application improves the automation level and treatment efficiency of sewage treatment.

Description

Technical Field

[0001] The present invention relates to the field of wastewater treatment technology, and in particular to a method and equipment for enhancing micro-electrolysis wastewater treatment by magnetic field synergistic regulation. Background Technology

[0002] Iron-carbon micro-electrolysis technology is a wastewater treatment technology based on electrochemical oxidation-reduction reactions. It utilizes the potential difference between iron and carbon to form micro-batteries, degrading pollutants such as organic matter and heavy metals through electron transfer, adsorption, and co-precipitation. It is widely used in industrial wastewater treatment in dyeing, pharmaceuticals, and electroplating, reducing wastewater color and chemical oxygen demand, improving biodegradability, and adsorbing and reducing heavy metal ions. Current practical applications include pretreatment, micro-electrolysis reaction, solid-liquid separation, and subsequent treatment. The influent hydrogen ion concentration index needs to be adjusted to approximately 3 before being pumped into the reaction tower. The wastewater treated by micro-electrolysis is discharged through the effluent outlet to enter the next treatment structure. However, this technology has significant bottlenecks: during long-term operation, oxides such as Fe(OH)3 and Fe2O3 generated by the electrode reaction form passivation films on the surface of the packing material and inside the reactor, leading to packing caking, severely reducing treatment efficiency, and even preventing electrolysis from taking place; traditional systems rely on manual sampling and testing at regular intervals and manual adjustment of parameters such as hydrogen ion concentration index, aeration rate, and reaction time, resulting in slow response, low accuracy, and high labor costs; although a weak magnetic field can enhance the removal of pollutants by zero-valent iron, and a weak magnetic field can be formed by arranging a magnetic levitation base or magnet at the bottom of the reactor, the magnetic field is only generated at the bottom, with a limited range of effect, failing to fully utilize the magnetic field enhancement effect. To address these shortcomings, there is an urgent need for a micro-electrolysis wastewater treatment method that can effectively inhibit packing caking, achieve intelligent control, and fully utilize the magnetic field enhancement effect, in order to improve treatment efficiency, reduce operating costs, and enhance the system's automation level. Summary of the Invention

[0003] To address the aforementioned problems in the existing technology, embodiments of the present invention provide a method and equipment for enhancing micro-electrolysis wastewater treatment by magnetic field synergistic regulation.

[0004] In a first aspect, embodiments of the present invention provide a magnetic field-coordinated enhanced micro-electrolysis wastewater treatment method, comprising: Step S1: adjusting the hydrogen ion concentration index of the wastewater to obtain regulated wastewater, and pumping the regulated wastewater to the inlet of the micro-electrolysis reaction tower using a lift pump; the regulated wastewater is aerated by the aeration device in the aeration zone and then enters the micro-electrolysis reaction tower through the support layer; Step S2: using the enameled copper wire coil wound around the outside of the micro-electrolysis reaction tower and the iron-carbon micro-electrolysis packing material inside the tower to form a magnetic field generating device, and passing direct current through the device to generate a magnetic field inside the micro-electrolysis reaction tower. A magnetic field is generated, and the magnitude and direction of the magnetic field are adjusted in real time according to the hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration of the effluent; Step S3: The regulated wastewater treated by the magnetic field overflows into the collection tank through a trapezoidal overflow weir, and the hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration of the effluent are detected in real time by an online water quality monitoring system below the outlet; Step S4: Based on the detection results of Step S3, the hydrogen ion concentration index of the influent, the magnetic field parameters, and the aeration rate are adjusted in conjunction to regulate the micro-electrolysis reaction conditions.

[0005] Based on the above method embodiments, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention, wherein the magnitude and direction of the magnetic field are adjusted in real time according to the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of the effluent, includes: sending a general input / output signal to the H-bridge circuit to control the enameled copper wire coil to change the direction of the magnetic field; and sending a pulse width modulation signal to the metal oxide semiconductor field-effect transistor driving circuit to change the current on the enameled copper wire coil to adjust the magnetic field strength.

[0006] Based on the above method embodiments, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention includes the following: the metal oxide semiconductor field effect transistor driving circuit changes the output power of the aeration pump according to the received pulse width modulation signal, thereby adjusting the aeration volume of the aeration head at the bottom of the aeration zone, and the aeration pump is connected to the aeration head through an aeration pipe.

[0007] Based on the above method embodiments, the magnetic field-coordinated regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention includes the following: sending a general input / output signal to a solid-state relay to control the opening and closing of the automatic dosing device for the hydrogen ion concentration index in the hydrogen ion concentration index regulating tank, thereby regulating the dosing of the hydrogen ion concentration index in the influent.

[0008] Based on the above method embodiments, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention includes an online water quality monitoring system comprising: a hydrogen ion concentration index sensor, a conductivity sensor, a chemical oxygen demand sensor, and a heavy metal ion concentration sensor, and the reaction conditions are regulated according to the simulated signals detected by the online water quality monitoring system.

[0009] Based on the above method embodiments, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention further includes, after regulating the micro-electrolysis reaction conditions: when it is necessary to replace the iron-carbon micro-electrolysis packing of the micro-electrolysis reaction tower, the packing outlet is opened after shutdown to clean the packing; when it is necessary to repair the pipeline or aeration head in the aeration area, the pipeline inspection port is opened after shutdown for repair.

[0010] Secondly, embodiments of the present invention provide a magnetic field-coordinated enhanced micro-electrolysis wastewater treatment system, comprising: a hydrogen ion concentration index regulating tank for holding wastewater; an automatic dosing device for adjusting the hydrogen ion concentration index of the wastewater; a booster pump for delivering the wastewater to the inlet; an aeration head for aerating the wastewater; an aeration pump for providing aeration gas to the aeration head; a magnetic field generating device for regulating the intensity and direction of the magnetic field around the wastewater; an online water quality monitoring system for monitoring the water quality of the wastewater; and an STM32 main control chip integrated within the online water quality monitoring system for loading corresponding programs to implement the magnetic field-coordinated enhanced micro-electrolysis wastewater treatment method as described in any of the foregoing method embodiments.

[0011] Thirdly, embodiments of the present invention provide a magnetic field-coordinated enhanced micro-electrolysis wastewater treatment device, comprising: a first main module for implementing step S1: adjusting the hydrogen ion concentration index of wastewater to obtain regulated wastewater, and pumping the regulated wastewater to the inlet of the micro-electrolysis reaction tower using a lift pump; the regulated wastewater is aerated by the aeration device in the aeration zone and then enters the micro-electrolysis reaction tower through the support layer; a second main module for implementing step S2: using the enameled copper wire coil wound around the outside of the micro-electrolysis reaction tower and the iron-carbon micro-electrolysis packing inside the tower to form a magnetic field generating device, and passing direct current through the device to generate a magnetic field inside the micro-electrolysis reaction tower. A magnetic field is generated, and the magnitude and direction of the magnetic field are adjusted in real time according to the hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration of the effluent. The third main module is used to implement step S3: the regulated wastewater treated by the magnetic field overflows into the collection tank through a trapezoidal overflow weir, and the hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration of the effluent are detected in real time by an online water quality monitoring system below the outlet. The fourth main module is used to implement step S4: based on the detection results of step S3, the hydrogen ion concentration index of the influent, the magnetic field parameters, and the aeration rate are adjusted in a coordinated manner to regulate the micro-electrolysis reaction conditions.

[0012] Fourthly, embodiments of the present invention provide an electronic device, comprising:

[0013] At least one processor, at least one memory, and a communication interface; wherein,

[0014] The processor, memory, and communication interface communicate with each other;

[0015] The memory stores program instructions that can be executed by the processor. The processor calls the program instructions to execute the magnetic field-coordinated control enhanced micro-electrolysis wastewater treatment method provided by any of the various implementations of the first aspect.

[0016] Fifthly, embodiments of the present invention provide a non-transitory computer-readable storage medium storing computer instructions that cause a computer to execute the magnetic field-coordinated enhanced micro-electrolysis wastewater treatment method provided by any of the various implementations of the first aspect.

[0017] The magnetic field-coordinated enhanced micro-electrolysis wastewater treatment method and equipment provided in this invention, by winding coils around the outside of the micro-electrolysis reaction tower and forming a variable magnetic field with packing as the iron core, weakens the passivation film and caking phenomenon on the packing surface, thereby increasing the pollutant removal rate by 20% to 30% and shortening the reaction time by 10% to 35%. The online water quality monitoring system at the effluent end monitors parameters such as hydrogen ion concentration index and chemical oxygen demand in real time, and combined with intelligent linkage adjustment of dosing, magnetic field and aeration devices, achieves stable and precise control of hydrogen ion concentration index. Compared with traditional manual control, the pollutant removal rate is increased by 30% to 40%, the reaction time is shortened by 20% to 30%, the labor cost and system complexity are reduced, and the automation level and treatment efficiency of wastewater treatment are improved. Attached Figure Description

[0018] To more clearly illustrate the technical solutions in the embodiments of the present invention or the prior art, the drawings used in the description of the embodiments or the prior art will be briefly introduced below. Obviously, the drawings described below are some embodiments of the present invention. For those skilled in the art, other drawings can be obtained based on these drawings without creative effort.

[0019] Figure 1 This is a schematic diagram of the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in an embodiment of the present invention;

[0020] Figure 2 This is a schematic diagram of the structure of the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment device provided in an embodiment of the present invention;

[0021] Figure 3 A schematic diagram of the physical structure of an electronic device provided in an embodiment of the present invention;

[0022] Figure 4 This is a schematic diagram of the structure of the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment system provided in an embodiment of the present invention;

[0023] Figure 5 This is a schematic diagram of the structure of the automatic dosing device for hydrogen ion concentration index provided in an embodiment of the present invention. Detailed Implementation

[0024] To make the objectives, technical solutions, and advantages of the embodiments of the present invention clearer, the technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings. Obviously, the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of the present invention. In addition, the technical features of the various embodiments or individual embodiments provided by the present invention can be arbitrarily combined to form feasible technical solutions. Such combinations are not constrained by the order of steps and / or structural composition patterns, but must be based on the ability of those skilled in the art to implement them. When the combination of technical solutions is contradictory or cannot be implemented, it should be considered that such combination of technical solutions does not exist and is not within the scope of protection claimed by the present invention. If there are step numbers in the following embodiments, they are only set for ease of explanation and do not limit the order between steps. The execution order of each step in the embodiments can be adaptively adjusted according to the understanding of those skilled in the art.

[0025] This invention provides a magnetic field-coordinated enhanced micro-electrolysis wastewater treatment method, see [link to relevant documentation]. Figure 1The method includes: Step S1: Adjusting the hydrogen ion concentration index of wastewater to obtain regulated wastewater, and pumping the regulated wastewater to the inlet of the micro-electrolysis reaction tower using a lift pump. After being aerated by the aeration device in the aeration area, the regulated wastewater enters the micro-electrolysis reaction tower through the support layer; Step S2: Using the enameled copper wire coil wound around the outside of the micro-electrolysis reaction tower and the iron-carbon micro-electrolysis packing inside the tower, a magnetic field generating device is constructed. Direct current is passed through the micro-electrolysis reaction tower to form a magnetic field, and the magnitude and direction of the magnetic field are adjusted in real time according to the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of the effluent; Step S3: The regulated wastewater treated by the magnetic field overflows into the collection tank through a trapezoidal overflow weir. The hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of the effluent are detected in real time by an online water quality monitoring system below the outlet; Step S4: Based on the detection results of Step S3, the influent hydrogen ion concentration index, magnetic field parameters and aeration rate are adjusted in conjunction to regulate the micro-electrolysis reaction conditions.

[0026] A coil is wound around the outside of the micro-electrolysis reactor tower, using the micro-electrolysis packing material inside the tower as the iron core. Direct current is applied to generate a magnetic field, and the magnitude and direction of this magnetic field are periodically changed to enhance the pollutant degradation ability of the micro-electrolysis packing material. Related online water quality monitoring systems are installed at the inlet and outlet to monitor parameters such as hydrogen ion concentration, conductivity, chemical oxygen demand, and heavy metal ion concentration in real time. An intelligent integrated system is used to adjust the influent hydrogen ion concentration, magnetic field magnitude and direction, and aeration effect based on the effluent water quality, thereby improving wastewater treatment quality. To enhance the reactivity of the iron-carbon micro-electrolysis packing material and prevent caking, the iron-carbon micro-electrolysis reactor specifically involves: winding a coil around the outside of the reactor tower, using the micro-electrolysis packing material inside as the iron core; and applying direct current to create a widespread magnetic field inside the tower. The magnitude and direction of the magnetic field are periodically changed to reduce caking and passivation, thus improving the micro-electrolysis reaction treatment effect.

[0027] The intelligent control system linked to pollutant degradation efficiency is specifically designed as follows: sensors for detecting hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration are installed at the effluent end to monitor the effluent water quality parameters of the wastewater treatment device in real time. Based on the monitoring results, analog signals are transmitted to the STM32 main control chip in real time. According to the embedded control algorithm program, general input / output signals and pulse width modulation signals are issued to coordinate and adjust the key reaction condition control devices in the system, including the automatic dosing device for hydrogen ion concentration index, the strength and direction of the magnetic field, and the output power of the aeration pump, thereby realizing an efficient and intelligent integrated control process for water quality treatment.

[0028] Based on the above method embodiments, as an optional embodiment, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention, wherein the magnitude and direction of the magnetic field are adjusted in real time according to the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of the effluent, includes: sending a general input / output signal to the H-bridge circuit to control the enameled copper wire coil to change the direction of the magnetic field; sending a pulse width modulation signal to the metal oxide semiconductor field effect transistor driving circuit to change the current on the enameled copper wire coil and adjust the magnetic field strength.

[0029] Based on the above method embodiments, as an optional embodiment, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention includes the following: the metal oxide semiconductor field effect transistor driving circuit changes the output power of the aeration pump according to the received pulse width modulation signal, thereby adjusting the aeration volume of the aeration head at the bottom of the aeration zone, and the aeration pump is connected to the aeration head through an aeration pipe.

[0030] Based on the above method embodiments, as an optional embodiment, the magnetic field coordinated regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention includes the linkage adjustment of the influent hydrogen ion concentration index, which includes: sending a general input / output signal to a solid-state relay to control the opening and closing of the automatic dosing device for the hydrogen ion concentration index in the hydrogen ion concentration index adjustment tank, and adjusting the dosing of the influent hydrogen ion concentration index.

[0031] Based on the above method embodiments, as an optional embodiment, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention includes an online water quality monitoring system comprising: a hydrogen ion concentration index sensor, a conductivity sensor, a chemical oxygen demand sensor, and a heavy metal ion concentration sensor, and the reaction conditions are regulated according to the simulated signals detected by the online water quality monitoring system.

[0032] Based on the above method embodiments, as an optional embodiment, the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method provided in this embodiment of the invention further includes, after regulating the micro-electrolysis reaction conditions: when it is necessary to replace the iron-carbon micro-electrolysis packing of the micro-electrolysis reaction tower, the packing outlet is opened after shutdown to clean the packing; when it is necessary to repair the pipeline or aeration head in the aeration area, the pipeline inspection port is opened after shutdown for repair.

[0033] The magnetic field-coordinated enhanced micro-electrolysis wastewater treatment method provided in this invention uses a coil wound around the outside of the micro-electrolysis reaction tower to form a variable magnetic field with packing material as the iron core. This weakens the passivation film and caking phenomenon on the surface of the packing material, increasing the pollutant removal rate by 20% to 30% and shortening the reaction time by 10% to 35%. The online water quality monitoring system at the effluent end monitors parameters such as hydrogen ion concentration index and chemical oxygen demand in real time. Combined with intelligent linkage adjustment of dosing, magnetic field and aeration devices, stable and precise control of hydrogen ion concentration index is achieved. Compared with traditional manual control, the pollutant removal rate is increased by 30% to 40%, the reaction time is shortened by 20% to 30%, the labor cost and system complexity are reduced, and the automation level and treatment efficiency of wastewater treatment are improved.

[0034] This invention provides a magnetic field-coordinated enhanced micro-electrolysis wastewater treatment system, see [link to relevant documentation]. Figure 4 The system includes: a hydrogen ion concentration index regulating tank for holding wastewater; an automatic dosing device for adjusting the hydrogen ion concentration index of the wastewater; a booster pump for delivering wastewater to the inlet; an aeration head for aerating the wastewater; an aeration pump for supplying aeration gas to the aeration head; a magnetic field generator for controlling the intensity and direction of the magnetic field around the wastewater; an online water quality monitoring system for monitoring the water quality of the wastewater; and an STM32 main control chip integrated into the online water quality monitoring system for loading corresponding programs to implement the magnetic field synergistic regulation enhanced micro-electrolysis wastewater treatment method as described in any of the aforementioned method embodiments.

[0035] See Figure 4 After the physicochemical properties of the wastewater are adjusted in the hydrogen ion concentration index regulating tank 13, it is pumped to the inlet 7 by the lift pump 12. From the inlet 7, the wastewater is introduced into the aeration zone 16. In the aeration zone 16, the wastewater passes through the support layer 5 under the action of the aeration device 19 and is then sent to the micro-electrolysis reaction zone 17. In the micro-electrolysis reaction zone 17, the wastewater reacts with the iron-carbon micro-electrolysis packing 1 under the magnetic field generated by the magnetic field generator 3, resulting in treated wastewater. The treated wastewater overflows. After passing through the trapezoidal overflow weir 9 at the upper end of the micro-electrolysis reaction zone 17, the wastewater overflows through the trapezoidal overflow weir 9 and reaches the collection tank 18. The treated wastewater is then fed into the outlet 8 through the collection tank 18. The online water quality monitoring system 4 below the outlet 8 detects the effluent water quality. Based on the measured data, the online water quality monitoring system 4 intelligently integrates and adjusts the micro-electrolysis reaction-related indices of the hydrogen ion concentration index automatic dosing device 30, aeration pump 11, and magnetic field generating device 3, thereby achieving automatic adjustment of reaction-related indices within a second-level cycle.

[0036] The magnetic field generating device 3 includes a micro-electrolysis packing 1 in an iron-carbon micro-electrolysis reaction tower as the iron core of the magnetic field generating device, and an enameled copper wire coil 2 wound around the outside of the micro-electrolysis reaction tower. The enameled copper wire coil 2 is connected to a MOS drive circuit 25 and an H-bridge circuit 24. The MOS drive circuit 25 and the H-bridge circuit 24 are connected to an STM32 main control chip 23 in an online water quality monitoring system 4 to receive a general input / output signal 28 and a pulse width modulation signal 29. When the H-bridge circuit 24 receives the general input / output signal 28, it controls the enameled copper wire coil 2 to change the direction of the magnetic field. When the MOS drive circuit 25 receives the pulse width modulation signal 29, it changes the current on the enameled copper wire coil 2 to achieve the purpose of intelligently adjusting the magnitude and direction of the magnetic field according to the effluent water quality.

[0037] The aeration device includes an aeration pump 11 installed outside the reaction tower, an aeration head 10 located at the bottom of the aeration area 16 inside the micro-electrolysis reaction tower, and an aeration pipe 6 connecting the aeration pump 11 and the aeration head 10. In addition, the aeration pump 11 is connected to the MOS drive circuit 25 by an electrical circuit, and the MOS drive circuit 25 is connected to the STM32 main control chip 23 in the online water quality monitoring system 4 to receive the pulse width modulation signal 29. When the MOS drive circuit 25 receives the pulse width modulation signal 29, it will change the output power of the aeration pump to achieve the purpose of intelligently adjusting the aeration volume according to the effluent water quality.

[0038] An automatic hydrogen ion concentration index dosing device 30 is installed on the inner wall of the hydrogen ion concentration index regulating tank 13. (See attached image) Figure 5 The automatic hydrogen ion concentration index dosing device 30 is connected to a solid-state relay 4 via a circuit. The solid-state relay 4 is connected to the STM32 main control chip 23 in the online water quality monitoring system 4 to receive general input / output signals 28. When the solid-state relay 26 receives the general input / output signals 28, it will control the opening and closing of the automatic hydrogen ion concentration index dosing device 30 to achieve the purpose of intelligently adjusting the hydrogen ion concentration index value according to the effluent water quality.

[0039] Regarding aeration control, the detection status of the chemical oxygen demand (COD) sensor 21 and the heavy metal ion concentration sensor 22 is as follows: If either the COD or the heavy metal ion concentration in the water exceeds a preset threshold, an analog signal 27 is generated. When this analog signal 27 is transmitted to the STM32 main control chip 23, the STM32 main control chip 23 sends a pulse width modulation (PWM) signal 29. After the PWM signal 29 is transmitted to the MOS drive circuit 25, the aeration rate of the aeration pump 11 is increased, and the aeration rate is controlled between 1.5-3 L / min. If both the COD and the heavy metal ion concentration in the water are within the normal threshold range, no signal is emitted, and the aeration rate remains at the current state.

[0040] Regarding aeration control, the detection status of the chemical oxygen demand sensor 21 and the heavy metal ion concentration sensor 22 is as follows: if either the chemical oxygen demand or the heavy metal ion concentration in the water exceeds a preset threshold, an analog signal 27 is generated. When the analog signal 27 is transmitted to the STM32 main control chip 23, the STM32 main control chip 23 sends a pulse width modulation signal 29. After the pulse width modulation signal 29 is transmitted to the MOS drive circuit 25, the aeration rate of the aeration pump 11 is increased, and the aeration rate is controlled between 1.5-3 L / min.

[0041] If the chemical oxygen demand and heavy metal ion concentrations in the water are both within the normal threshold range, no signal will be emitted, and the aeration rate will remain at its current state.

[0042] When the treated wastewater passes through the online water quality monitoring system 4 below the outlet 8, the hydrogen ion concentration index sensor 19 installed in the online water quality monitoring system 4 detects the treated wastewater and generates an analog signal 27. The analog signal 27 is transmitted to the STM32 main control chip 23, which then issues a general-purpose input / output signal 28. This signal 28 is transmitted to the solid-state relay 26 to issue a command to adjust the hydrogen ion concentration index based on the effluent water quality. Specifically, if the detected hydrogen ion concentration index is greater than a preset threshold (e.g., 3), the analog signal 27 is generated. When this analog signal 27 is transmitted to the STM32 main control chip 23, the STM32 main control chip 23 issues a GPIO signal 28. When the GPIO signal 28 is transmitted to the solid-state relay 26, it sends a signal to activate the acidic solution dosing function of the automatic dosing device 30, which controls the hydrogen ion concentration index value.

[0043] If the water quality hydrogen ion concentration index is detected to be less than a preset threshold (e.g., 3), an analog signal 27 is generated. When the analog signal 27 is transmitted to the STM32 main control chip 23, the STM32 main control chip 23 sends a GPIO signal 28. When the GPIO signal 28 is transmitted to the solid-state relay 26, it sends a signal to control the automatic dosing device 30 of the hydrogen ion concentration index to start the alkaline solution dosing function.

[0044] If the water hydrogen ion concentration index is detected to be within the preset threshold range, no signal will be emitted, and the automatic dosing device 30 will remain in the off state.

[0045] When the iron-carbon micro-electrolysis packing 1 located in the micro-electrolysis reaction zone 17 needs to be replaced, the entire device should be shut down, and the packing outlet 14 should be opened for packing removal. When the various pipes and aeration heads 10 located in the aeration zone 16 need to be repaired or replaced, the entire device should be shut down, and the pipeline inspection port 15 should be opened for repair.

[0046] The various embodiments of this invention are implemented through programmed processing using a device with processor functionality. Therefore, in practical engineering, the technical solutions and functions of the various embodiments of this invention can be encapsulated into various modules. Based on this reality, and building upon the above embodiments, this invention provides a magnetic field-coordinated enhanced micro-electrolysis wastewater treatment device, which is used to execute the magnetic field-coordinated enhanced micro-electrolysis wastewater treatment method in the above method embodiments. See also... Figure 2 The device includes: a first main module for implementing step S1: adjusting the hydrogen ion concentration index of wastewater to obtain regulated wastewater, which is then pumped to the inlet of the micro-electrolysis reaction tower using a lift pump. The regulated wastewater is aerated by the aeration device in the aeration zone and then enters the micro-electrolysis reaction tower through the support layer. A second main module for implementing step S2: using the enameled copper wire coil wound around the outside of the micro-electrolysis reaction tower and the iron-carbon micro-electrolysis packing material inside the tower to form a magnetic field generating device, applying direct current to generate a magnetic field inside the micro-electrolysis reaction tower, and adjusting the magnetic field based on the hydrogen ion concentration index of the effluent. The first main module controls the magnitude and direction of the magnetic field in real time by adjusting the hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration; the second main module implements step S3: the regulated wastewater treated by the magnetic field overflows into the collection tank through a trapezoidal overflow weir, and the hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration of the effluent are detected in real time by an online water quality monitoring system below the outlet; the third main module implements step S4: based on the detection results of step S3, the hydrogen ion concentration index of the influent, the magnetic field parameters, and the aeration rate are adjusted in conjunction to regulate the micro-electrolysis reaction conditions.

[0047] The magnetic field-coordinated enhanced micro-electrolysis wastewater treatment device provided in this embodiment of the invention adopts... Figure 2 Several modules within the system utilize coils wound around the outside of the micro-electrolysis reaction tower to create a variable magnetic field with packing material as the iron core. This weakens the passivation film and caking phenomenon on the packing surface, increasing pollutant removal rate by 20% to 30% and shortening reaction time by 10% to 35%. The online water quality monitoring system at the effluent end monitors parameters such as hydrogen ion concentration index and chemical oxygen demand in real time. Combined with intelligent linkage adjustment of dosing, magnetic field, and aeration devices, it achieves stable and precise control of hydrogen ion concentration index. Compared with traditional manual control, pollutant removal rate is increased by 30% to 40%, and reaction time is shortened by 20% to 30%. This reduces labor costs and system complexity, and improves the automation level and treatment efficiency of wastewater treatment.

[0048] It should be noted that the apparatus in the device embodiments provided by the present invention can be used not only to implement the methods in the above method embodiments, but also to implement the methods in other method embodiments provided by the present invention. The difference lies only in the setting of corresponding functional modules. Its principle is basically the same as that of the above device embodiments provided by the present invention. As long as those skilled in the art, based on the above device embodiments and referring to the specific technical solutions in other method embodiments, obtain corresponding technical means and technical solutions composed of these technical means by combining technical features, and improve the apparatus in the above device embodiments while ensuring the practicality of the technical solutions, they can obtain corresponding device-type embodiments for implementing the methods in other method-type embodiments. For example:

[0049] Based on the above-described device embodiments, as an optional embodiment, the magnetic field-coordinated enhanced micro-electrolysis wastewater treatment device provided in this embodiment of the invention further includes: a first submodule, used to implement and real-time control of the magnitude and direction of the magnetic field according to the hydrogen ion concentration index, conductivity, chemical oxygen demand, and heavy metal ion concentration of the effluent, including: sending a general input / output signal to the H-bridge circuit to control the enameled copper wire coil to change the direction of the magnetic field; and sending a pulse width modulation signal to the metal oxide semiconductor field-effect transistor driving circuit to change the current magnitude on the enameled copper wire coil and adjust the magnetic field strength.

[0050] Based on the above-described device embodiments, as an optional embodiment, the magnetic field-coordinated regulation enhanced micro-electrolysis wastewater treatment device provided in this embodiment of the invention further includes: a second sub-module, used to realize the linkage adjustment of the influent aeration volume, including: the metal oxide semiconductor field-effect transistor driving circuit changes the output power of the aeration pump according to the received pulse width modulation signal, thereby adjusting the aeration volume of the aeration head at the bottom of the aeration zone, wherein the aeration pump is connected to the aeration head through an aeration pipe.

[0051] Based on the above-described device embodiments, as an optional embodiment, the magnetic field-coordinated regulation enhanced micro-electrolysis wastewater treatment device provided in this embodiment of the invention further includes: a third sub-module, used to realize the linkage regulation of the influent hydrogen ion concentration index, including: sending a general input / output signal to a solid-state relay to control the opening and closing of the automatic dosing device for the hydrogen ion concentration index in the hydrogen ion concentration index regulation tank, and adjusting the dosing of the influent hydrogen ion concentration index.

[0052] Based on the above-described device embodiments, as an optional embodiment, the magnetic field-coordinated regulation enhanced micro-electrolysis wastewater treatment device provided in this embodiment of the invention further includes: a fourth sub-module for implementing the online water quality monitoring system, including: a hydrogen ion concentration index sensor, a conductivity sensor, a chemical oxygen demand sensor, and a heavy metal ion concentration sensor, which regulates the reaction conditions based on the analog signals detected by the online water quality monitoring system.

[0053] Based on the above-described device embodiments, as an optional embodiment, the magnetic field-coordinated regulation enhanced micro-electrolysis wastewater treatment device provided in this embodiment of the invention further includes: a fifth sub-module, used to, after regulating the micro-electrolysis reaction conditions, further includes: when it is necessary to replace the iron-carbon micro-electrolysis packing material of the micro-electrolysis reaction tower, opening the packing material outlet after shutdown to clean the packing material; when it is necessary to repair the pipes or aeration heads in the aeration area, opening the pipeline inspection port after shutdown for repair.

[0054] The method in this embodiment of the invention is implemented using an electronic device; therefore, it is necessary to introduce the relevant electronic device. For this purpose, this embodiment of the invention provides an electronic device, such as... Figure 3 As shown, the electronic device includes at least one processor, a communications interface, at least one memory, and a communications bus, wherein the at least one processor, the communications interface, and the at least one memory communicate with each other via the communications bus. The at least one processor can invoke logical instructions stored in the at least one memory to execute all or part of the steps of the methods provided in the foregoing method embodiments.

[0055] Furthermore, when the logical instructions in at least one of the aforementioned memories can be implemented as software functional units and sold or used as independent products, they can be stored in a computer-readable storage medium. Based on this understanding, the technical solution of the present invention, in essence, or the part that contributes to the prior art, or a part of the technical solution, can be embodied in the form of a software product. This computer software product is stored in a storage medium and includes several instructions to cause a computer device (which may be a personal computer, server, or network device, etc.) to execute all or part of the steps of the methods described in the various method embodiments of the present invention. The aforementioned storage medium includes various media capable of storing program code, such as USB flash drives, portable hard drives, read-only memory (ROM), random access memory (RAM), magnetic disks, or optical disks.

[0056] The device embodiments described above are merely illustrative. The units described as separate components may or may not be physically separate. The components shown as units may or may not be physical units; that is, they may be located in one place or distributed across multiple network units. Some or all of the modules can be selected to achieve the purpose of this embodiment according to actual needs. Those skilled in the art can understand and implement this without any creative effort.

[0057] Through the above description of the embodiments, those skilled in the art can clearly understand that each embodiment can be implemented by means of software plus necessary general-purpose hardware platforms, and of course, it can also be implemented by hardware. Based on this understanding, the above technical solutions, in essence or the part that contributes to the prior art, can be embodied in the form of a software product. This computer software product can be stored in a computer-readable storage medium, such as ROM / RAM, magnetic disk, optical disk, etc., and includes several instructions to cause a computer device (which may be a personal computer, server, or network device, etc.) to execute the methods described in the various embodiments or some parts of the embodiments.

[0058] The flowcharts and block diagrams in the accompanying drawings illustrate the architecture, functionality, and operation of possible implementations of systems, methods, and computer program products according to various embodiments of the present invention. Based on this understanding, each block in a flowchart or block diagram may represent a module, segment, or portion of code containing one or more executable instructions for implementing a specified logical function. It should also be noted that in some alternative implementations, the functions marked in the blocks may occur in a different order than those shown in the drawings. For example, two consecutive blocks may actually be executed substantially in parallel, or sometimes in reverse order, depending on the functions involved. It should also be noted that each block in the block diagrams and / or flowcharts, and combinations of blocks in the block diagrams and / or flowcharts, can be implemented using a dedicated hardware-based system that performs the specified function or action, or using a combination of dedicated hardware and computer instructions.

[0059] It should be noted that the terms "comprising," "including," or any other variations thereof are intended to cover non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements includes not only those elements but also other elements not expressly listed, or elements inherent to such a process, method, article, or apparatus. Unless otherwise specified, an element defined by the phrase "comprising..." does not exclude the presence of other identical elements in the process, method, article, or apparatus that includes said element. Any expressions such as "predetermined threshold," "preset threshold," etc., without specifying a particular value, can be determined by those skilled in the art through simple experimentation or appropriate adjustments.

[0060] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, and not to limit them; although the present invention has been described in detail with reference to the foregoing embodiments, those skilled in the art should understand that modifications can still be made to the technical solutions described in the foregoing embodiments, or equivalent substitutions can be made to some of the technical features; and these modifications or substitutions do not cause the essence of the corresponding technical solutions to deviate from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims

1. A magnetic field synergistically regulated enhanced micro-electrolysis wastewater treatment method, characterized in that, Comprise: Step S1: adjust the sewage hydrogen ion concentration index to obtain the adjusted sewage, use the lifting pump to pump the adjusted sewage to the water inlet of the micro electrolysis reaction tower, the adjusted sewage is aerated by the aeration device of the aeration area, and then enters the micro electrolysis reaction tower through the supporting layer;Step S2: using the enameled copper wire coil wound outside the micro electrolysis reaction tower and the iron-carbon micro electrolysis filler in the tower, a magnetic field generating device is formed, a magnetic field is formed in the micro electrolysis reaction tower by passing direct current, and the size and direction of the magnetic field are adjusted in real time according to the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of the effluent;Step S3: the adjusted sewage treated by the magnetic field is overflowed to the water collecting tank through the trapezoidal overflow weir, and the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of the effluent are detected in real time by the online water quality monitoring system below the effluent outlet;Step S4: based on the detection results of step S3, the hydrogen ion concentration index of the influent, the magnetic field parameters and the aeration amount are adjusted in linkage to control the micro electrolysis reaction conditions.

2. The magnetic field synergistically reinforced micro-electrolysis wastewater treatment method according to claim 1, characterized in that, The size and direction of the magnetic field are adjusted in real time according to the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of the effluent, including: sending a general input and output signal to the H bridge circuit to control the enameled copper wire coil to change the direction of the magnetic field; sending a pulse width modulation signal to the metal oxide semiconductor field effect transistor drive circuit to change the current size on the enameled copper wire coil and adjust the magnetic field strength.

3. The magnetic field synergistically reinforced micro-electrolysis wastewater treatment method according to claim 2, characterized in that, The aeration amount of the influent is adjusted in linkage, including: the metal oxide semiconductor field effect transistor drive circuit changes the output power of the aeration pump according to the received pulse width modulation signal, and then adjusts the aeration amount of the aeration head at the bottom of the aeration area, and the aeration pump is connected with the aeration head through the aeration pipeline.

4. The magnetic field synergistically reinforced micro-electrolysis wastewater treatment method according to claim 3, characterized in that, The hydrogen ion concentration index of the influent is adjusted in linkage, including: sending a general input and output signal to the solid state relay to control the opening and closing of the hydrogen ion concentration index automatic dosing device on the inner wall of the hydrogen ion concentration index adjusting tank to adjust the dosing of the hydrogen ion concentration index of the influent.

5. The magnetic field synergistically reinforced micro-electrolysis wastewater treatment method according to claim 4, characterized in that, The online water quality monitoring system comprises: a hydrogen ion concentration index sensor, a conductivity sensor, a chemical oxygen demand sensor and a heavy metal ion concentration sensor, and the reaction conditions are adjusted according to the analog signals detected by the online water quality monitoring system.

6. The magnetic field synergistically reinforced micro-electrolysis wastewater treatment method according to claim 5, characterized in that, After the micro electrolysis reaction conditions are adjusted, when it is necessary to replace the iron-carbon micro electrolysis filler of the micro electrolysis reaction tower, the filler is removed after the machine is stopped; when it is necessary to repair the pipeline or aeration head of the aeration area, the pipeline is repaired after the machine is stopped.

7. A magnetic field synergistically regulated enhanced micro-electrolysis sewage treatment system, characterized in that, Comprise: A hydrogen ion concentration index adjusting tank for containing sewage; A hydrogen ion concentration index value automatic dosing device for adjusting the hydrogen ion concentration index of the sewage; A lifting pump for pumping the sewage to the water inlet; An aeration head for aerating the sewage; an aeration pump for providing aeration gas for the aeration head; a magnetic field generating device for adjusting the magnetic field strength and direction of the sewage; The online water quality monitoring system is used for monitoring the water quality of sewage; the STM32 master control chip is integrated in the online water quality monitoring system and is used for loading a corresponding program to realize the magnetic field synergistic regulation and control enhanced micro-electrolysis sewage treatment method as claimed in any one of claims 1 to 6.

8. A magnetic field synergistically regulated reinforced micro-electrolysis wastewater treatment device, characterized in that, The method comprises the following steps: The first main module is used for realizing step S1: adjusting the hydrogen ion concentration index of sewage to obtain adjusted sewage, using a lifting pump to pump the adjusted sewage to the water inlet of a micro-electrolysis reaction tower, and after the adjusted sewage is aerated by an aeration device in an aeration area, the adjusted sewage enters the micro-electrolysis reaction tower through a supporting layer; the second main module is used for realizing step S2: using a copper wire coil wrapped outside the micro-electrolysis reaction tower and iron-carbon micro-electrolysis filler in the tower to form a magnetic field generating device, inputting direct current to form a magnetic field inside the micro-electrolysis reaction tower, and real-time regulating the size and direction of the magnetic field according to the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of effluent; the third main module is used for realizing step S3: the adjusted sewage after the magnetic field treatment is overflowed to a water collecting tank through a trapezoidal overflow weir, and the hydrogen ion concentration index, conductivity, chemical oxygen demand and heavy metal ion concentration of effluent are detected in real time by an online water quality monitoring system below the water outlet; the fourth main module is used for realizing step S4: based on the detection results of step S3, the hydrogen ion concentration index of the water inlet, the magnetic field parameters and the aeration amount are adjusted in linkage to regulate the micro-electrolysis reaction conditions.

9. An electronic device, comprising: The method comprises the following steps: At least one processor, at least one memory and a communication interface; wherein The processor, memory and communication interface communicate with each other; The memory stores program instructions executable by the processor, and the processor calls the program instructions to execute the method as claimed in any one of claims 1 to 6.

10. A non-transitory computer-readable storage medium, comprising: The non-transitory computer readable storage medium stores computer instructions, and the computer instructions enable the computer to execute the method as claimed in any one of claims 1 to 6.

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