Natural sodium bentonite-based fish manure purification treatment material and preparation method thereof

By using a micro-carrier to carry the bentonite base and attach saprophytic agents, the problem of fish feces purification is solved, effective adsorption of fish feces and stabilization of water quality are achieved, and it is suitable for secondary utilization in fish farming.

CN120647101APending Publication Date: 2025-09-16XINJIANG WOYE DESERT GOVERNANCE RESEARCH INSTITUTE CO LTD +2
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Patent Information

Application Number
CN202510631963.X
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-05-16
Publication Date
2025-09-16

AI Technical Summary

Technical Problem

During fish farming, improper cleaning of fish feces leads to algae proliferation and growth of harmful microorganisms in the water, affecting the health of fish. Existing technologies are difficult to effectively purify fish feces, which affects water quality and fish growth.

Method used

A micro-carrier is used to carry a bentonite base and attach a saprophytic agent. The natural sodium-based fish manure purification treatment material formed by the micro-carrier carrying the bentonite base and then attaching the saprophytic agent can absorb fish manure and inhibit the growth of algae.

Benefits of technology

It effectively absorbs fish feces, inhibits algae growth, keeps water clean, reduces fish losses, and realizes the secondary utilization of fish feces. The water quality does not differ much, making it suitable for secondary fish farming.

✦ Generated by Eureka AI based on patent content.

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Abstract

The invention relates to a natural sodium bentonite-based fish manure purification treatment material and a preparation method thereof, and belongs to the technical field of fish manure purification treatment, and the natural sodium bentonite-based fish manure purification treatment material is prepared by adopting a micro bearing frame to bear a bentonite base and then attaching a saprophytic bacterium agent; the miniature bearing frame is prepared from the following raw materials in parts by weight: 20 to 35 parts of hydrogenated rosin, 10 to 15 parts of calcium naphthenate powder, 2 to 6 parts of azodicarbonamide powder, 40 to 55 parts of polyurethane, 5 to 10 parts of vaseline and 25 to 35 parts of volcanic rock powder. The natural sodium-based bentonite-based fish manure purification treatment material can be completely fished out by adopting a filter screen with 1.2 mm * 1.2 mm holes, the water quality difference between the natural sodium-based bentonite-based fish manure purification treatment material and secondary fishing is not large, only one kind of algae exists in water after being exposed to the sun, the effective algae removal effect is achieved, the natural sodium-based bentonite-based fish manure purification treatment material can be secondarily utilized for fish culture, and the loss of cultured fish is low.
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Description

Technical Field

[0001] The invention belongs to the technical field of fishery excrement purification and treatment, and particularly relates to a natural sodium-based bentonite-based fishery excrement purification and treatment material and a preparation method thereof. Background Art

[0002] The core of fish farming is to achieve fish breeding, feeding and stocking through scientific management, the key lies in species selection, bait management and water quality control.

[0003] In the process of fish farming, cleaning fish feces has always been a relatively important task, which is beneficial to the regulation of water quality, reducing the amount of water input in the process of fish farming, so that water can be reused for fish farming. If the fish feces are not cleaned properly, a large amount of algae will proliferate in the water, causing the number of harmful microorganisms to increase sharply, which may affect the health of the fish in the water. Harmful microorganisms can cause some fish to become sick, such as water mold disease, pepper disease, bulging eyes, congestion and descaling, head hole disease, gill rot disease, enteritis, etc. Summary of the Invention

[0004] The purpose of the present invention is to provide a natural sodium bentonite-based fish manure purification material and a preparation method thereof in order to solve the above problems.

[0005] The present invention achieves the above-mentioned purpose through the following technical solutions:

[0006] The present invention provides a natural sodium-based bentonite-based fish excrement purification and treatment material, wherein the natural sodium-based bentonite-based fish excrement purification and treatment material is prepared by using a micro-supporting frame to support the bentonite base and then attaching a saprophytic agent;

[0007] The raw materials for preparing the micro-carrier include, by weight, 20-35 parts of hydrogenated rosin, 10-15 parts of calcium naphthenate powder, 2-6 parts of azodicarbonamide powder, 40-55 parts of polyurethane, 5-10 parts of vaseline, and 25-35 parts of volcanic rock powder;

[0008] The raw materials for preparing the saprophytic agent include, by weight, 6-12 parts of Bacillus natto, 10-15 parts of Bacillus cereus, 5-12 parts of Nitrosomonas and 45-55 parts of cassava starch.

[0009] As a further optimization scheme of the present invention, the preparation process of the micro-carrier is as follows: (1) adding hydrogenated rosin and polyurethane to a heating container, heating at 60°C for 10 minutes to obtain a polymer mixed material, and keeping it warm at 80°C for standby use; (2) mixing calcium cyclopentaneate powder, azodicarbonamide powder and volcanic rock powder, pouring them into the polymer mixed material, stirring at 15-30r / min for 10-20 minutes to obtain an electrospinning stock solution; (3) injecting the electrospinning stock solution into a spinning machine for spinning, and stopping spinning when the cumulative spinning thickness reaches 0.01mm to obtain a silk sheet; (4) applying vaseline between two silk sheets to form a 1mm×1mm diamond isolation module, the four corners of each diamond isolation module are connected, and the diamond isolation modules are flatly distributed in a dotted manner to obtain a micro-carrier.

[0010] As a further optimized solution of the present invention, the preparation process of the bentonite base is as follows: montmorillonite, albite and kaolin are crushed and ground into powder, and the powder is passed through a 60-mesh sieve to obtain the bentonite base.

[0011] As a further optimized solution of the present invention, the preparation process of the saprophytic agent is as follows: Bacillus natto, Bacillus cereus, Nitrosomonas and cassava starch are mixed to obtain the saprophytic agent.

[0012] As a further optimization solution of the present invention, the mass ratio of montmorillonite, albite and kaolin is 3:1:1.

[0013] As a further optimized solution of the present invention, the preparation process of the volcanic rock powder is: crushing the volcanic rock, grinding it into powder, and passing it through a 60-mesh sieve to obtain the volcanic rock powder.

[0014] The present invention also provides a method for preparing a natural sodium bentonite-based fish manure purification material, comprising the following steps:

[0015] Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base;

[0016] Method for attaching saprophytic agent to micro-support frame: spray saprophytic agent on the outer surface of micro-support frame after supporting bentonite base by using sprayer.

[0017] As a further optimized solution of the present invention, 0.1 mg of saprophytic agent is sprayed on the outer surface of the micro-carrier per square centimeter.

[0018] The beneficial effects of the present invention are as follows: by adopting a micro-carrier to carry the bentonite base and then attaching a saprophytic agent, the fish feces in the fish tank can be easily adsorbed; after the fish feces are adsorbed, the bentonite base is still located in the micro-carrier and will not melt in the water; a filter with a 1.2mm×1.2mm hole can be used to remove all of the feces; and the water quality between the second salvage and the second salvage is not much different; after sun exposure, there is only one type of algae in the water, and it does not affect the cleanliness of the water much; it has an effective algae removal effect, can be reused for fish farming, and the loss of farmed fish is low. DETAILED DESCRIPTION

[0019] The present application is described in further detail below. It is necessary to point out that the following specific implementation methods are only used to further illustrate the present application and cannot be understood as limiting the scope of protection of the present application. Technicians in this field can make some non-essential improvements and adjustments to the present application based on the above application content.

[0020] Material

[0021] Unless otherwise specified, the methods used in the present invention are conventional methods known to those skilled in the art, and the reagents and other materials used are commercially available products unless otherwise specified.

[0022] Example 1

[0023] The preparation process of the micro-carrier is as follows: (1) adding 20 parts of hydrogenated rosin and 40 parts of polyurethane to a heating container, heating at 60°C for 10 minutes to obtain a polymer mixed material, and keeping it warm at 80°C for standby use; (2) mixing 10 parts of calcium cyclohexaneate powder, 2 parts of azodicarbonamide powder and 25 parts of volcanic rock powder, pouring the mixture into the polymer mixed material, and stirring at 15 rpm for 10 minutes to obtain an electrospinning stock solution; (3) injecting the electrospinning stock solution into a spinning machine for spinning, and stopping the spinning when the cumulative spinning thickness reaches 0.01 mm to obtain a silk sheet; (4) applying 5 parts of vaseline between two silk sheets to form a 1 mm × 1 mm diamond-shaped isolation module, with the four corners of each diamond-shaped isolation module connected, and the diamond-shaped isolation modules are distributed in a dotted pattern to obtain a micro-carrier;

[0024] The bentonite base was prepared as follows: montmorillonite, albite and kaolin were crushed and ground into powder, and passed through a 60-mesh sieve to obtain a bentonite base (the mass ratio of montmorillonite, albite and kaolin was 3:1:1);

[0025] Preparation of saprophytic agent: 6 parts of Bacillus natto, 10 parts of Bacillus cereus, 5 parts of Nitrosomonas and 50 parts of cassava starch;

[0026] The volcanic rock powder is prepared by crushing and grinding the volcanic rock into powder, and passing the powder through a 60-mesh sieve to obtain the volcanic rock powder;

[0027] Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base;

[0028] Method for attaching saprophytic agent to micro-carrier: spray saprophytic agent on the outer surface of micro-carrier after supporting bentonite base by using sprayer (0.1 mg saprophytic agent is sprayed per square centimeter of outer surface of micro-carrier).

[0029] Example 2

[0030] The preparation process of the micro-carrier is as follows: (1) 30 parts of hydrogenated rosin and 48 parts of polyurethane are added to a heating container, and heated at 60°C for 10 minutes to obtain a polymer mixed material, which is then kept warm at 80°C for standby use; (2) 12 parts of calcium cyclohexaneate powder, 4 parts of azodicarbonamide powder, and 30 parts of volcanic rock powder are mixed, poured into the polymer mixed material, and stirred at 25 r / min for 15 minutes to obtain an electrospinning stock solution; (3) the electrospinning stock solution is injected into a spinning machine for spinning, and spinning is stopped when the cumulative spinning thickness reaches 0.01 mm to obtain a silk sheet; (4) 8 parts of vaseline are applied between two silk sheets to form a 1 mm × 1 mm diamond-shaped isolation module, with the four corners of each diamond-shaped isolation module connected, and the diamond-shaped isolation modules are distributed in a dotted pattern to obtain a micro-carrier;

[0031] The bentonite base was prepared as follows: montmorillonite, albite and kaolin were crushed and ground into powder, and passed through a 60-mesh sieve to obtain a bentonite base (the mass ratio of montmorillonite, albite and kaolin was 3:1:1);

[0032] Preparation process of saprophytic agent: 10 parts of Bacillus natto, 12 parts of Bacillus cereus, 9 parts of Nitrosomonas and 50 parts of cassava starch;

[0033] The volcanic rock powder is prepared by crushing and grinding the volcanic rock into powder, and passing the powder through a 60-mesh sieve to obtain the volcanic rock powder;

[0034] Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base;

[0035] Method for attaching saprophytic agent to micro-carrier: spray saprophytic agent on the outer surface of micro-carrier after supporting bentonite base by using sprayer (0.1 mg saprophytic agent is sprayed per square centimeter of outer surface of micro-carrier).

[0036] Example 3

[0037] The preparation process of the micro-carrier is as follows: (1) 35 parts of hydrogenated rosin and 55 parts of polyurethane are added to a heating container, and heated at 60°C for 10 minutes to obtain a polymer mixed material, which is kept warm at 80°C for standby use; (2) 15 parts of calcium cyclohexaneate powder, 6 parts of azodicarbonamide powder, and 35 parts of volcanic rock powder are mixed, poured into the polymer mixed material, and stirred at 30 r / min for 20 minutes to obtain an electrospinning stock solution; (3) The electrospinning stock solution is injected into a spinning machine for spinning. When the cumulative spinning thickness reaches 0.01 mm, the spinning is stopped to obtain a silk sheet; (4) 10 parts of vaseline are applied between two silk sheets to form a 1 mm × 1 mm diamond-shaped isolation module, with the four corners of each diamond-shaped isolation module connected, and the diamond-shaped isolation modules are distributed in a dotted pattern to obtain a micro-carrier;

[0038] The bentonite base was prepared as follows: montmorillonite, albite and kaolin were crushed and ground into powder, and passed through a 60-mesh sieve to obtain a bentonite base (the mass ratio of montmorillonite, albite and kaolin was 3:1:1);

[0039] Preparation of saprophytic agent: 12 parts of Bacillus natto, 15 parts of Bacillus cereus, 12 parts of Nitrosomonas and 55 parts of cassava starch;

[0040] The volcanic rock powder is prepared by crushing and grinding the volcanic rock into powder, and passing the powder through a 60-mesh sieve to obtain the volcanic rock powder;

[0041] Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base;

[0042] Method for attaching saprophytic agent to micro-carrier: spray saprophytic agent on the outer surface of micro-carrier after supporting bentonite base by using sprayer (0.1 mg saprophytic agent is sprayed per square centimeter of outer surface of micro-carrier).

[0043] Comparative Example 1

[0044] The preparation process of the micro-carrier is as follows: (1) 30 parts of hydrogenated rosin and 48 parts of polyurethane are added to a heating container, and heated at 60°C for 10 minutes to obtain a polymer mixed material, which is then kept warm at 80°C for standby use; (2) 12 parts of calcium cyclohexaneate powder and 34 parts of volcanic rock powder are mixed, poured into the polymer mixed material, and stirred at 25 r / min for 15 minutes to obtain an electrospinning stock solution; (3) the electrospinning stock solution is injected into a spinning machine for spinning, and spinning is stopped when the cumulative spinning thickness reaches 0.01 mm to obtain a silk sheet; (4) 8 parts of vaseline are applied between two silk sheets to form a 1 mm × 1 mm diamond-shaped isolation module, with the four corners of each diamond-shaped isolation module connected, and the diamond-shaped isolation modules are distributed in a dotted pattern to obtain a micro-carrier;

[0045] The bentonite base was prepared as follows: montmorillonite, albite and kaolin were crushed and ground into powder, and passed through a 60-mesh sieve to obtain a bentonite base (the mass ratio of montmorillonite, albite and kaolin was 3:1:1);

[0046] Preparation process of saprophytic agent: 10 parts of Bacillus natto, 12 parts of Bacillus cereus, 9 parts of Nitrosomonas and 50 parts of cassava starch;

[0047] The volcanic rock powder is prepared by crushing and grinding the volcanic rock into powder, and passing the powder through a 60-mesh sieve to obtain the volcanic rock powder;

[0048] Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base;

[0049] Method for attaching saprophytic agent to micro-carrier: spray saprophytic agent on the outer surface of micro-carrier after supporting bentonite base by using sprayer (0.1 mg saprophytic agent is sprayed per square centimeter of outer surface of micro-carrier).

[0050] Comparative Example 2

[0051] The preparation process of the micro-carrier is as follows: (1) 30 parts of hydrogenated rosin and 48 parts of polyurethane are added to a heating container, and heated at 60°C for 10 minutes to obtain a polymer mixed material, which is kept warm at 80°C for standby use; (2) 12 parts of calcium cyclohexaneate powder and 34 parts of azodicarbonamide powder are mixed, poured into the polymer mixed material, and stirred at 25 r / min for 15 minutes to obtain an electrospinning stock solution; (3) the electrospinning stock solution is injected into a spinning machine for spinning, and the spinning is stopped when the cumulative spinning thickness reaches 0.01 mm to obtain a silk sheet; (4) 8 parts of vaseline are applied between two silk sheets to form a 1 mm × 1 mm diamond-shaped isolation module, the four corners of each diamond-shaped isolation module are connected, and the diamond-shaped isolation modules are distributed in a dotted pattern to obtain a micro-carrier;

[0052] The bentonite base was prepared as follows: montmorillonite, albite and kaolin were crushed and ground into powder, and passed through a 60-mesh sieve to obtain a bentonite base (the mass ratio of montmorillonite, albite and kaolin was 3:1:1);

[0053] Preparation process of saprophytic agent: 10 parts of Bacillus natto, 12 parts of Bacillus cereus, 9 parts of Nitrosomonas and 50 parts of cassava starch;

[0054] The volcanic rock powder is prepared by crushing and grinding the volcanic rock into powder, and passing the powder through a 60-mesh sieve to obtain the volcanic rock powder;

[0055] Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base;

[0056] Method for attaching saprophytic agent to micro-carrier: spray saprophytic agent on the outer surface of micro-carrier after supporting bentonite base by using sprayer (0.1 mg saprophytic agent is sprayed per square centimeter of outer surface of micro-carrier).

[0057] Comparative Example 3

[0058] The preparation process of the micro-carrier is as follows: (1) 30 parts of hydrogenated rosin and 48 parts of polyurethane are added to a heating container, and heated at 60°C for 10 minutes to obtain a polymer mixed material, which is then kept warm at 80°C for standby use; (2) 12 parts of calcium cyclohexaneate powder, 4 parts of azodicarbonamide powder, and 30 parts of volcanic rock powder are mixed, poured into the polymer mixed material, and stirred at 25 r / min for 15 minutes to obtain an electrospinning stock solution; (3) the electrospinning stock solution is injected into a spinning machine for spinning, and spinning is stopped when the cumulative spinning thickness reaches 0.01 mm to obtain a silk sheet; (4) 8 parts of vaseline are applied between two silk sheets to form a 1 mm × 1 mm diamond-shaped isolation module, with the four corners of each diamond-shaped isolation module connected, and the diamond-shaped isolation modules are distributed in a dotted pattern to obtain a micro-carrier;

[0059] The bentonite base was prepared as follows: montmorillonite, albite and kaolin were crushed and ground into powder, and passed through a 60-mesh sieve to obtain a bentonite base (the mass ratio of montmorillonite, albite and kaolin was 3:1:1);

[0060] Preparation of saprophytic agent: 10 parts of Bacillus natto, 12 parts of Bacillus cereus and 9 parts of Nitrosomonas;

[0061] The volcanic rock powder is prepared by crushing and grinding the volcanic rock into powder, and passing the powder through a 60-mesh sieve to obtain the volcanic rock powder;

[0062] Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base;

[0063] Method for attaching saprophytic agent to micro-carrier: spray saprophytic agent on the outer surface of micro-carrier after supporting bentonite base by using sprayer (0.1 mg saprophytic agent is sprayed per square centimeter of outer surface of micro-carrier).

[0064] Comparative Example 4

[0065] The bentonite base was prepared as follows: montmorillonite, albite and kaolin were crushed and ground into powder, and passed through a 60-mesh sieve to obtain a bentonite base (the mass ratio of montmorillonite, albite and kaolin was 3:1:1);

[0066] Preparation process of saprophytic agent: 10 parts of Bacillus natto, 12 parts of Bacillus cereus, 9 parts of Nitrosomonas and 50 parts of cassava starch;

[0067] The bentonite base is mixed with a saprophytic agent to obtain a natural sodium-based bentonite-based fish manure purification and treatment material.

[0068] Performance testing

[0069] ① Experimental conditions

[0070] 1. Select 7 glass fish tanks of the same size, place the same number and size of koi of the same species in each of the 7 glass fish tanks, feed them with the same dose of fish food every day, and remove the fish after 10 days;

[0071] 2. The natural sodium bentonite-based fish excrement purification materials prepared by the methods of Examples 1-3 and Comparative Examples 1-4 were divided into 7 groups and placed into 7 experimental fish tanks. After 3 days, the changes in the fish excrement adsorption rate and water quality in each fish tank were observed;

[0072] The observation results are shown in the following table

[0073]

[0074]

[0075] As can be seen from the above table, the natural sodium bentonite-based fish excrement purification materials prepared by the methods of Examples 1-3 are used in fish excrement purification, and Example 2 is relatively excellent in terms of fish excrement adsorption rate.

[0076] ② Experimental conditions

[0077] 1. The fish tank and the materials in it after the experiment in step ① are activated

[0078] 2. Use a filter with 1.2mm x 1.2mm holes to salvage the solid matter in the fish tank. After salvaging, observe the turbidity of the water. The turbidity is represented by A.

[0079] 3. Use a filter with 0.6mm x 0.6mm holes to salvage the solid matter in the fish tank. After salvaging, observe the turbidity of the water. The turbidity is represented by B.

[0080] 4. Move the fish tank after the second salvage to a sunny outdoor area and observe the growth of green algae in the tank after 12 days.

[0081] The observation results are shown in the following table

[0082]

[0083]

[0084] As can be seen from the above table, in Examples 1-3, the water was already relatively clear during the first salvage, and the water was clear after the second salvage, with only one type of green algae. The water had a high transparency and could be used a second time for fish farming.

[0085] ③ Experimental conditions

[0086] 1. The fish tank and the materials in the fish tank after the experiment in step ② are activated

[0087] 2. Stock 100 koi of similar size in a fish tank. After 60 days, record the number of koi surviving. The experimental results are shown in the following table.

[0088] project Koi survival rate Example 1 90% Example 2 95% Example 3 90% Comparative Example 1 82% Comparative Example 2 80% Comparative Example 3 76% Comparative Example 4 73%

[0089] The above-described embodiments merely illustrate several implementations of the present invention. While the descriptions are relatively specific and detailed, they should not be construed as limiting the scope of the present invention. It should be noted that a person skilled in the art would be able to make numerous variations and improvements without departing from the spirit of the present invention, and all such variations and improvements fall within the scope of protection of the present invention.

Claims

1. A natural sodium bentonite-based fish manure purification material, characterized in that: The natural sodium bentonite-based fish manure purification and treatment material is prepared by using a micro-support frame to support the bentonite base and then attaching a saprophytic agent; The raw materials for preparing the micro-carrier include, by weight, 20-35 parts of hydrogenated rosin, 10-15 parts of calcium naphthenate powder, 2-6 parts of azodicarbonamide powder, 40-55 parts of polyurethane, 5-10 parts of vaseline, and 25-35 parts of volcanic rock powder; The raw materials for preparing the saprophytic agent include, by weight, 6-12 parts of Bacillus natto, 10-15 parts of Bacillus cereus, 5-12 parts of Nitrosomonas and 45-55 parts of cassava starch.

2. A natural sodium bentonite-based fish manure purification material according to claim 1, characterized in that: The preparation process of the micro-carrier is as follows: (1) adding hydrogenated rosin and polyurethane into a heating container, heating at 60°C for 10 minutes to obtain a polymer mixed material, and keeping the temperature at 80°C for later use; (2) mixing calcium cyclohexaneate powder, azodicarbonamide powder and volcanic rock powder, pouring the mixture into the polymer mixture, and stirring at 15-30 rpm for 10-20 min to obtain an electrospinning solution; (3) injecting the electrospinning solution into the spinning machine to perform spinning, and stopping spinning when the cumulative thickness of the spinning reaches 0.01 mm to obtain a silk sheet; (4) Vaseline is applied between two silk sheets to form a 1mm×1mm diamond-shaped isolation module. The four corners of each diamond-shaped isolation module are connected, and the diamond-shaped isolation modules are distributed in a dotted pattern to obtain a micro-carrier.

3. The natural sodium bentonite-based fish manure purification material according to claim 1, characterized in that: The preparation process of the bentonite base is as follows: montmorillonite, albite and kaolin are crushed and ground into powder, and the powder is passed through a 60-mesh sieve to obtain the bentonite base.

4. The natural sodium bentonite-based fish manure purification material according to claim 1, characterized in that: The preparation process of the saprophytic agent is as follows: Bacillus natto, Bacillus cereus, Nitrosomonas and cassava starch are mixed to obtain the saprophytic agent.

5. The natural sodium bentonite-based fish manure purification material according to claim 1, characterized in that: The mass ratio of the montmorillonite, albite and kaolin is 3:1:

1.

6. A natural sodium bentonite-based fish manure purification material according to claim 1, characterized in that: The preparation process of the volcanic rock powder is as follows: crushing the volcanic rock, grinding it into powder, and passing it through a 60-mesh sieve to obtain the volcanic rock powder.

7. A method for preparing the natural sodium bentonite-based fish manure purification material according to any one of claims 1 to 6, characterized in that: The following steps are involved: Method for carrying bentonite base on a micro-carrier: injecting the bentonite base into the micro-carrier and cutting it into 1.5mm×2mm rectangular pieces by hot melt cutting, so that the micro-carrier carries the bentonite base; a 1mm×1mm diamond-shaped isolation module between the two pieces of silk is used to carry the bentonite base; Method for attaching saprophytic agent to micro-support frame: spray saprophytic agent on the outer surface of micro-support frame after supporting bentonite base by using sprayer.

8. The method for preparing the natural sodium bentonite-based fish manure purification material according to claim 7, characterized in that: The outer surface of the micro-carrier is sprayed with 0.1 mg of saprophytic agent per square centimeter.