Anti-counterfeiting adhesive tape and manufacturing method thereof
By using a coating layer and a protective paint layer with specific ingredients in the anti-counterfeiting tape, the problem of poor heat resistance and wear resistance of the tape is solved, and an anti-counterfeiting tape with high heat resistance and wear resistance is achieved, which enhances the protection and bonding strength of the anti-counterfeiting information.
Patent Information
- Application Number
- CN202511172896.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2025-08-21
- Publication Date
- 2025-10-03
AI Technical Summary
Existing anti-counterfeiting tapes are easy to fall off after long-term use, have poor heat resistance and wear resistance, and can be easily destroyed by criminals through heating, and cannot effectively protect anti-counterfeiting information.
A coating layer containing H3PO4, aluminum hydroxide, copper oxide, magnesium oxide, graphene and other ingredients is used, combined with a protective paint layer and a base layer to improve the heat resistance and wear resistance of the tape, enhance the adhesion and anti-counterfeiting information protection of the printed layer.
It improves the heat resistance and wear resistance of the tape, extends its service life, enhances the protection of anti-counterfeiting information, prevents heat damage, and improves bonding strength and stability.
Smart Images

Figure CN120737752A_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of adhesive tapes, in particular to an anti-counterfeiting adhesive tape and a manufacturing method thereof. Background Art
[0002] Adhesive tape is a versatile material widely used in daily life and industry. It comes in various types, each with its own specific purpose and application. Anti-counterfeiting tape is a technology used to ensure product authenticity and protect consumer rights. It's widely used in various packaging materials. It not only protects the integrity of goods but also plays an important role in preventing counterfeiting in logistics, transportation, document packaging, and other fields. Adhesive is used in anti-counterfeiting tape.
[0003] Existing technology typically involves wrapping the outer surface of an anti-counterfeiting label with transparent tape and adhering it to the surface of an item. This can protect the label for a short period of time, but after prolonged use, the outer tape can fall off, exposing the anti-counterfeiting information and easily damaging the label. Furthermore, adhesive tape has poor heat resistance, and criminals often use a hair dryer to heat the tape, causing it to fall off and replace the anti-counterfeiting information. Furthermore, conventional anti-counterfeiting tapes have low wear and heat resistance, making them ineffective in protecting the anti-counterfeiting information. To address this issue, we provide an anti-counterfeiting tape and a method for manufacturing the same. Summary of the Invention
[0004] The purpose of the present invention is to provide an anti-counterfeiting tape and a manufacturing method thereof in response to the above technical problems, which have the advantages of high heat resistance and wear resistance.
[0005] To achieve this purpose, the present invention provides an anti-counterfeiting tape and a method for manufacturing the same, using the following technical embodiments: An anti-counterfeiting tape includes a base layer, the anti-counterfeiting tape is composed of a protective paint layer, a printing layer, a rubber coating layer and the base layer, and the composition ratio of the rubber coating layer is as follows: The components of the coating layer mainly include: H3PO4, 70-90 parts, aluminum hydroxide, 30-40 parts, copper oxide, 15-20 parts, curing agent, 10-13 parts, magnesium oxide, 40-45 parts, graphene, 5-10 parts, and deionized water, 30-40 parts.
[0006] A method for manufacturing an anti-counterfeiting tape, the specific steps of which include: (1) The method for synthesizing the rubber coating layer comprises the following steps: S1: First, prepare the raw materials. Add deionized water to H3PO4 with a density of 1.87 g / ml to obtain a phosphoric acid solution with a density of 1.70 g / ml. S2: heating the phosphoric acid solution, adding aluminum hydroxide during the heating process, and waiting for the aluminum hydroxide to be completely dissolved to obtain a compound solution; S3: Continuing to heat the compound solution for a high-temperature reaction, adding copper oxide, a curing agent, magnesium oxide, and graphene during the heating process, and stirring evenly to obtain a colloid; S4: Cool and dry the colloid to obtain a coating material.
[0007] (2) The method for manufacturing the protective paint layer comprises the following steps: S5: Raw material preparation, acrylic acid, polyurethane, epoxy resin, quartz sand, calcium powder, dispersant, foaming agent, thickener, water; S6: adding quartz sand, calcium powder and water into the sand mill for cyclic grinding and mixing; S7: adding the ground slurry into a paint mixing bucket and stirring, adding acrylic acid, polyurethane, and epoxy resin during the stirring process and stirring again to obtain a compound; S8: adding a dispersant, a foaming agent, and a thickener to the compound, continuing to stir, and drying after stirring to obtain a protective paint.
[0008] (3) Prepare the base layer, select kraft paper as the tape base layer, dry the base layer, and apply the coating material on the surface of the base layer to form a coating layer; (4) preparing a non-woven fabric and printing the anti-counterfeiting information on the non-woven fabric as a printing layer, and laminating the non-woven fabric printed with the anti-counterfeiting information on the side of the adhesive layer away from the kraft paper; (5) Applying a protective paint on the side of the printed layer away from the adhesive layer, and drying the protective paint to form a protective paint layer; (6) Dry and collect to obtain the anti-counterfeiting tape, Preferably, in step S4, the proportion of the protective paint layer is: 30-40 parts of acrylic acid, 50-55 parts of polyurethane, 40-45 parts of epoxy resin, 20-25 parts of quartz sand, 10-13 parts of calcium powder, 2-5 parts of dispersant, 3-6 parts of foaming agent, 2-5 parts of thickener, and 15-20 parts of water.
[0009] Preferably, the curing agent is any one of organic anhydride, imidazole, organic amine, and polymer.
[0010] Preferably, in step S3, the high temperature reaction temperature is 240-260° C., the time is 90 min, and the pressure is lower than 2.5 MPa.
[0011] Preferably, in step S6, the grinding is performed in a grinder, the cooling water temperature in the grinder is maintained at 5-20° C., and the grinding rate is 5-10 L / min.
[0012] Preferably, in step S7, the stirring is magnetic stirring, and the parameters of the magnetic stirring are: temperature 50~70°C, speed 700~900r / min, and time 2~3 hours. Preferably, in step S8, the drying temperature is 40° C. and the drying time is 4-6 hours.
[0013] Preferably, in step (5), the drying temperature is 20-30° C. and the drying time is 24 hours.
[0014] The present invention has at least the following beneficial effects: In the present invention, the anti-counterfeiting tape uses an innovative material as a coating layer in an ordinary anti-counterfeiting tape, thereby improving the high-temperature resistance of the entire tape and having the characteristics of being environmentally friendly and non-toxic; In the present invention, a curing agent is added to the coating material to enhance the properties of the coating material, thereby improving the intermolecular distance, morphology, thermal stability, and chemical stability, and shortening the curing time and curing temperature of the colloid; In the present invention, the overall adhesive layer uses H3PO4 and aluminum hydroxide as main materials, phosphoric acid provides higher adhesion for the adhesive layer, and aluminum hydroxide improves the overall high temperature resistance; In the present invention, a protective paint layer is applied to the outermost layer of the anti-counterfeiting tape to increase the wear resistance of the anti-counterfeiting information on the printed layer and to extend the service life of the tape as a whole.
[0015] Other advantages, objectives and features of the present invention will be reflected in part from the following description and will be understood by those skilled in the art through study and practice of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS
[0016] Figure 1 This is a molecular structure diagram of the reaction between phosphoric acid and aluminum hydroxide in an anti-counterfeiting tape and a method for manufacturing the same according to the present invention; Figure 2 This is a molecular structure diagram of the compound after the reaction of an anti-counterfeiting adhesive tape and a manufacturing method thereof of the present invention; Figure 3 This is a comparative relationship diagram of friction force testing in Example 1 of an anti-counterfeiting tape and a method for manufacturing the same according to the present invention; Figure 4 A comparative relationship diagram of heat-resistant temperature tests in Example 1 of an anti-counterfeiting tape and a method for manufacturing the same according to the present invention; Figure 5 A comparison chart of the heat resistance and wear resistance tests in Example 2 of an anti-counterfeiting tape and a method for manufacturing the same according to the present invention; Figure 6 A comparative relationship diagram of heat-resistant temperature tests in Example 3 of an anti-counterfeiting tape and a method for manufacturing the same according to the present invention; Figure 7 A comparison diagram of the heat resistance and wear resistance tests in Example 3 of an anti-counterfeiting tape and a method for manufacturing the same according to the present invention. DETAILED DESCRIPTION
[0017] In order to make the purpose, technical embodiments and advantages of the present invention more clearly understood, the present invention is further described in detail below in conjunction with the embodiments. It should be understood that the specific embodiments described herein are only used to explain the present invention and are not intended to limit the present invention.
[0018] The application principle of the present invention is described in detail below with reference to the accompanying drawings.
[0019] refer to Figure 1-7 , an anti-counterfeiting tape, including a base layer, the anti-counterfeiting tape is composed of a protective paint layer, a printing layer, a coating layer and a base layer, and the composition ratio of the coating layer is as follows: The components of the coating layer mainly include: H3PO4, 70-90 parts, aluminum hydroxide, 30-40 parts, copper oxide, 15-20 parts, curing agent, 10-13 parts, magnesium oxide, 40-45 parts, graphene, 5-10 parts, and deionized water, 30-40 parts.
[0020] A method for manufacturing an anti-counterfeiting tape, the specific steps of which include: (1) The method for synthesizing the rubber coating layer comprises the following steps: S1: First, prepare the raw materials. Add deionized water to H3PO4 with a density of 1.87 g / ml to obtain a phosphoric acid solution with a density of 1.70 g / ml. S2: heating the phosphoric acid solution, adding aluminum hydroxide during the heating process, and waiting for the aluminum hydroxide to be completely dissolved to obtain a compound solution; S3: Continuing to heat the compound solution for a high-temperature reaction, adding copper oxide, a curing agent, magnesium oxide, and graphene during the heating process, and stirring evenly to obtain a colloid; S4: Cool and dry the colloid to obtain a coating material.
[0021] (2) The method for manufacturing the protective paint layer comprises the following steps: S5: Raw material preparation, acrylic acid, polyurethane, epoxy resin, quartz sand, calcium powder, dispersant, foaming agent, thickener, water; S6: adding quartz sand, calcium powder and water into the sand mill for cyclic grinding and mixing; S7: adding the ground slurry into a paint mixing bucket and stirring, adding acrylic acid, polyurethane, and epoxy resin during the stirring process and stirring again to obtain a compound; S8: adding a dispersant, a foaming agent, and a thickener to the compound, continuing to stir, and drying after stirring to obtain a protective paint.
[0022] (3) Prepare the base layer, select kraft paper as the tape base layer, dry the base layer, and apply the coating material on the surface of the base layer to form a coating layer; (4) preparing a non-woven fabric and printing the anti-counterfeiting information on the non-woven fabric as a printing layer, and laminating the non-woven fabric printed with the anti-counterfeiting information on the side of the adhesive layer away from the kraft paper; (5) Applying a protective paint on the side of the printed layer away from the adhesive layer, and drying the protective paint to form a protective paint layer; (6) Dry and collect to obtain the anti-counterfeiting tape, Among them, in step S4, the proportion of the protective paint layer is: 30-40 parts of acrylic acid, 50-55 parts of polyurethane, 40-45 parts of epoxy resin, 20-25 parts of quartz sand, 10-13 parts of calcium powder, 2-5 parts of dispersant, 3-6 parts of foaming agent, 2-5 parts of thickener, and 15-20 parts of water.
[0023] The curing agent is any one of organic acid anhydrides, imidazoles, organic amines, and polymers.
[0024] Wherein, in step S3, the temperature of the high temperature reaction is 240-260° C., the time is 90 min, and the pressure is lower than 2.5 MPa.
[0025] In step S6, the grinding machine performs grinding, the cooling water temperature in the grinding machine is maintained at 5-20° C., and the grinding rate is 5-10 L / min.
[0026] In step S7, the stirring is magnetic stirring, and the parameters of the magnetic stirring are: temperature 50-70°C, speed 700-900 r / min, and time 2-3 hours. Wherein, in step S8, the drying temperature is 40° C. and the drying time is 4-6 hours.
[0027] Wherein, in step (5), the drying temperature is 20-30°C and the drying time is 24 hours.
[0028] Among them, the anti-counterfeiting tape of the present invention uses innovative materials as the glue layer in the ordinary anti-counterfeiting tape to improve the high temperature resistance of the tape as a whole, has environmental protection and non-toxic characteristics, adds a curing agent to the glue layer material to increase the characteristics of the glue layer material, so that its intermolecular distance, morphology, thermal stability, and chemical stability are all improved, shortening the curing time and curing temperature of the colloid, the overall glue layer uses H3PO4 and aluminum hydroxide as the main materials, phosphoric acid provides higher adhesion for the glue layer, aluminum hydroxide improves the overall high temperature resistance, and a protective paint layer is applied to the outermost layer of the anti-counterfeiting tape to increase the wear resistance of the printed layer anti-counterfeiting information, thereby improving the service life of the tape as a whole, after the anti-counterfeiting tape is affixed, as the adhesive solidifies, the reaction gradually slows down, and when the glue layer is fully solidified, the reaction stops. The result of the reaction is that the surface of the sticker partially dissolves, and simultaneously produces the deposition of metallic copper, forming a mutually penetrating transition layer on the sticker surface, so that the sticker and the adhesive are tightly combined on the sticker surface, thereby increasing the bonding strength. After high-temperature treatment, a copper oxide layer forms on the surface. The copper oxide acts as a "bridge" between the adhesive and the adhered material, allowing them to bond tightly together and enhancing the bond strength. Within the adhesive, copper oxide is a discrete phase, serving as a foundation for the growth of hydrogen phosphate, forming a star-shaped aggregate that interpenetrates and holds the entire adhesive together. Aluminum phosphate adhesives are acidic mixtures composed of phosphoric acid (aluminum dihydrogen phosphate (Al(H2PO4)3)), water, and phosphoric acid. Aluminum dihydrogen phosphate is a thermosetting binder that forms a strong bond with oxides. Concentrated phosphoric acid primarily forms a structure based on PO4 tetrahedrons, connected by oxygen bridges to form a polyphosphate mixture. As the temperature rises, the degree of polymerization (n) increases, forming a large molecular network structure.
[0029] The molecular formula of the polyphosphoric acid mixture is Hn+2(PnO3n+1), assuming n=4, that is, H6P4O13 Example 1: An anti-counterfeiting tape includes a base layer, the anti-counterfeiting tape is composed of a protective paint layer, a printing layer, a rubber coating layer and the base layer, and the composition ratio of the rubber coating layer is as follows: The components of the coating layer mainly include: H3PO4, 80 parts, aluminum hydroxide, 40 parts, copper oxide, 20 parts, curing agent, 10 parts, magnesium oxide, 405 parts, graphene, 5 parts, and deionized water, 30 parts.
[0030] A method for manufacturing an anti-counterfeiting tape, the specific steps of which include: (1) The method for synthesizing the rubber coating layer comprises the following steps: S1: First, prepare the raw materials. Add deionized water to H3PO4 with a density of 1.87 g / ml to obtain a phosphoric acid solution with a density of 1.70 g / ml. S2: heating the phosphoric acid solution, adding aluminum hydroxide during the heating process, and waiting for the aluminum hydroxide to be completely dissolved to obtain a compound solution; S3: Continuing to heat the compound solution for a high-temperature reaction, adding copper oxide, a curing agent, magnesium oxide, and graphene during the heating process, and stirring evenly to obtain a colloid; S4: Cool and dry the colloid to obtain a coating material.
[0031] (2) The method for manufacturing the protective paint layer comprises the following steps: S5: Raw material preparation, acrylic acid, polyurethane, epoxy resin, quartz sand, calcium powder, dispersant, foaming agent, thickener, water; S6: adding quartz sand, calcium powder and water into the sand mill for cyclic grinding and mixing; S7: adding the ground slurry into a paint mixing bucket and stirring, adding acrylic acid, polyurethane, and epoxy resin during the stirring process and stirring again to obtain a compound; S8: adding a dispersant, a foaming agent, and a thickener to the compound, continuing to stir, and drying after stirring to obtain a protective paint.
[0032] (3) Prepare the base layer, select kraft paper as the tape base layer, dry the base layer, and apply the coating material on the surface of the base layer to form a coating layer; (4) preparing a non-woven fabric and printing the anti-counterfeiting information on the non-woven fabric as a printing layer, and laminating the non-woven fabric printed with the anti-counterfeiting information on the side of the adhesive layer away from the kraft paper; (5) Applying a protective paint on the side of the printed layer away from the adhesive layer, and drying the protective paint to form a protective paint layer; (6) Dry and collect to obtain the anti-counterfeiting tape, Among them, in step S4, the proportion of the protective paint layer is: 30-40 parts of acrylic acid, 50-55 parts of polyurethane, 40-45 parts of epoxy resin, 20-25 parts of quartz sand, 10-13 parts of calcium powder, 2-5 parts of dispersant, 3-6 parts of foaming agent, 2-5 parts of thickener, and 15-20 parts of water.
[0033] The curing agent is any one of organic acid anhydrides, imidazoles, organic amines, and polymers.
[0034] The experimental results show that: The anti-counterfeiting tape manufactured in Example 1 has ultra-high heat resistance, a long service life, and high wear resistance. Example 1 maintains a high wear resistance and a long service life at room temperature. The wear resistance strength is comparable to that of transparent tape, polyvinyl chloride tape, and BOPP tape. Figure 3The heat resistance of the anti-counterfeiting tape manufactured in Example 1 has also been greatly improved, which is nearly 10 times higher than that of the transparent tape substrate. The specific heat resistance is compared with that of polyvinyl chloride tape and BOPP tape. Figure 4 shown.
[0035] The experimental data of Example 1 are compared with those of transparent tape, polyvinyl chloride tape and BOPP tape, see Table 1.
[0036] Table 1. Parameter analysis data of transparent tape, polyvinyl chloride tape, and BOPP tape related to Example 1
[0037] Example 2: An anti-counterfeiting tape includes a base layer. The anti-counterfeiting tape is composed of a printing layer, a coating layer, and the base layer. The composition ratio of the coating layer is as follows: The components of the coating layer mainly include: H3PO4, 80 parts, aluminum hydroxide, 40 parts, copper oxide, 20 parts, curing agent, 10 parts, magnesium oxide, 405 parts, graphene, 5 parts, and deionized water, 30 parts.
[0038] A method for manufacturing an anti-counterfeiting tape, the specific steps of which include: (1) The method for synthesizing the rubber coating layer comprises the following steps: S1: First, prepare the raw materials. Add deionized water to H3PO4 with a density of 1.87 g / ml to obtain a phosphoric acid solution with a density of 1.70 g / ml. S2: heating the phosphoric acid solution, adding aluminum hydroxide during the heating process, and waiting for the aluminum hydroxide to be completely dissolved to obtain a compound solution; S3: Continuing to heat the compound solution for a high-temperature reaction, adding copper oxide, a curing agent, magnesium oxide, and graphene during the heating process, and stirring evenly to obtain a colloid; S4: Cool and dry the colloid to obtain a coating material.
[0039] (2) Prepare the base layer, select kraft paper as the tape base layer, dry the base layer, and apply the adhesive layer material on the surface of the base layer to form an adhesive layer; (3) preparing a non-woven fabric and printing the anti-counterfeiting information on the non-woven fabric as a printing layer, and laminating the non-woven fabric printed with the anti-counterfeiting information on the side of the adhesive layer away from the kraft paper; (4) Dry and collect until the anti-counterfeiting tape is The curing agent is any one of organic acid anhydrides, imidazoles, organic amines, and polymers.
[0040] The experimental results show that: The anti-counterfeiting tape manufactured in Example 2 has improved heat resistance and wear resistance compared to the transparent tape. Example 2 maintains high stability at high temperatures. The specific high temperature resistance and wear resistance are compared with those of Example 1, polyvinyl chloride tape and BOPP tape. Figure 5 As shown, the anti-counterfeiting tape of Example 1 and the anti-counterfeiting tape of Example 2 were manufactured respectively, and a high-temperature friction test was performed on the tape surfaces.
[0041] The experimental data of Example 2 are compared with those of Example 1, see Table 2.
[0042] Table 2, Parameter analysis data related to Example 2 and Example 1
[0043] Example 3: An anti-counterfeiting tape includes a base layer, the anti-counterfeiting tape is composed of a protective paint layer, a printing layer, a rubber coating layer and the base layer, and the composition ratio of the rubber coating layer is as follows: The components of the coating layer mainly include: H3PO4, 80 parts, copper oxide, 20 parts, curing agent, 10 parts, magnesium oxide, 405 parts, graphene, 5 parts, and deionized water, 30 parts.
[0044] A method for manufacturing an anti-counterfeiting tape, the specific steps of which include: (1) The method for synthesizing the rubber coating layer comprises the following steps: S1: First, prepare the raw materials. Add deionized water to H3PO4 with a density of 1.87 g / ml to obtain a phosphoric acid solution with a density of 1.70 g / ml. S2: Continuing to heat the compound solution for a high-temperature reaction, adding copper oxide, a curing agent, magnesium oxide, and graphene during the heating process, and stirring evenly to obtain a colloid; S3: Cool and dry the colloid to obtain a coating layer material.
[0045] (2) The method for manufacturing the protective paint layer comprises the following steps: S4: Raw material preparation, acrylic acid, polyurethane, epoxy resin, quartz sand, calcium powder, dispersant, foaming agent, thickener, water; S5: adding quartz sand, calcium powder and water into the sand mill for cyclic grinding and mixing; S6: adding the ground slurry into a paint mixing bucket and stirring, adding acrylic acid, polyurethane, and epoxy resin during the stirring process and stirring again to obtain a compound; S7: adding a dispersant, a foaming agent, and a thickener to the compound, continuing to stir, and drying after stirring to obtain a protective paint.
[0046] (3) Prepare the base layer, select kraft paper as the tape base layer, dry the base layer, and apply the coating material on the surface of the base layer to form a coating layer; (4) preparing a non-woven fabric and printing the anti-counterfeiting information on the non-woven fabric as a printing layer, and laminating the non-woven fabric printed with the anti-counterfeiting information on the side of the adhesive layer away from the kraft paper; (5) Applying a protective paint on the side of the printed layer away from the adhesive layer, and drying the protective paint to form a protective paint layer; (6) Dry and collect to obtain the anti-counterfeiting tape, Among them, in step S4, the proportion of the protective paint layer is: 30-40 parts of acrylic acid, 50-55 parts of polyurethane, 40-45 parts of epoxy resin, 20-25 parts of quartz sand, 10-13 parts of calcium powder, 2-5 parts of dispersant, 3-6 parts of foaming agent, 2-5 parts of thickener, and 15-20 parts of water.
[0047] The curing agent is any one of organic acid anhydrides, imidazoles, organic amines, and polymers.
[0048] The experimental results show that: The anti-counterfeiting tape manufactured in Example 3 has improved heat resistance and wear resistance compared to the transparent tape. Example 3 maintains high stability at high temperatures. The specific high temperature resistance is compared with that of Example 1 and Example 2. Figure 6 As shown, the anti-counterfeiting tapes of Example 1, Example 2, and Example 3 were respectively manufactured and tested, and a high-temperature friction test was performed on the surface of the tapes. The specific experimental data are compared. Figure 7 .
[0049] The experimental data of Example 3 is compared with those of Example 1 and Example 2, see Table 3.
[0050] Table 3, Parameter analysis data related to Example 3, Example 1 and Example 2
[0051] The present invention provides an anti-counterfeiting tape and a method for manufacturing the same. The resulting EPDM composition exhibits high heat resistance and tensile strength, and magnesium oxide is used as an activator, replacing zinc oxide to prevent the product from containing zinc. The above embodiments are intended to illustrate, not limit, the technical embodiments of the present invention. Persons skilled in the art may reasonably modify or make equivalent substitutions to the present invention. However, any modifications or partial substitutions that do not depart from the spirit and scope of the present invention are intended to be encompassed by the claims of the present invention.
[0052] The contents not described in detail in this specification belong to the prior art known to professional and technical personnel in this field.
Claims
1. An anti-counterfeiting tape comprising a base layer, characterized in that: The anti-counterfeiting tape consists of a protective paint layer, a printing layer, a rubber coating layer and a base layer. The composition ratio of the rubber coating layer is as follows: The ingredients of the coating layer mainly include: H3PO4, 70-90 parts, aluminum hydroxide, 30-40 parts, copper oxide, 15-20 parts, curing agent, 10-13 parts, magnesium oxide, 40-45 parts, graphene, 5-10 parts, and deionized water, 30-40 parts.
2. A method for manufacturing an anti-counterfeiting tape, characterized in that: The specific operation steps include: (1) The synthesis method of the coating layer includes the following steps: S1: First, prepare the raw materials and add deionized water to H3PO4 with a density of 1.87g / ml to obtain a phosphoric acid solution with a density of 1.70g / ml; S2: heating the phosphoric acid solution, adding aluminum hydroxide during the heating process, and waiting for the aluminum hydroxide to be completely dissolved to obtain a compound solution; S3: Continuing to heat the compound solution for a high-temperature reaction, adding copper oxide, a curing agent, magnesium oxide, and graphene during the heating process, and stirring evenly to obtain a colloid; S4: Cool and dry the colloid to obtain a coating material. (2) The method for manufacturing the protective paint layer comprises the following steps: S5: Raw material preparation: acrylic acid, polyurethane, epoxy resin, quartz sand, calcium powder, dispersant, foaming agent, thickener, water; S6: adding quartz sand, calcium powder and water into the sand mill for cyclic grinding and mixing; S7: adding the ground slurry into a paint mixing bucket and stirring, adding acrylic acid, polyurethane, and epoxy resin during the stirring process and stirring again to obtain a compound; S8: Add dispersant, foaming agent, and thickener to the compound, continue stirring, and dry after stirring to obtain a protective paint. (3) Prepare a base layer, select kraft paper as the tape base layer, dry the base layer, and apply a coating material on the surface of the base layer to form a coating layer; (4) Prepare a non-woven fabric, print the anti-counterfeiting information on the non-woven fabric, and attach the non-woven fabric printed with the anti-counterfeiting information to the side of the adhesive layer away from the kraft paper as the printing layer; (5) Apply a protective paint on the side of the printing layer away from the coating layer, and dry the protective paint to form a protective paint layer; (6) Dry and collect to obtain the anti-counterfeiting tape.
3. The method for manufacturing an anti-counterfeiting tape according to claim 2, characterized in that: In step S5, the protective paint layer comprises the following ingredients: 30-40 parts of acrylic acid, 50-55 parts of polyurethane, 40-45 parts of epoxy resin, 20-25 parts of quartz sand, 10-13 parts of calcium powder, 2-5 parts of dispersant, 3-6 parts of foaming agent, 2-5 parts of thickener, and 15-20 parts of water.
4. The anti-counterfeiting tape according to claim 1, characterized in that: The curing agent is any one of organic acid anhydride, imidazole, organic amine, and polymer.
5. The method for manufacturing an anti-counterfeiting tape according to claim 1, characterized in that: In step S3, the high temperature reaction temperature is 240-260° C., the time is 90 min, and the pressure is lower than 2.5 MPa.
6. The method for manufacturing an anti-counterfeiting tape according to claim 2, characterized in that: In step S6, the grinding machine performs grinding, the cooling water temperature in the grinding machine is maintained at 5-20°C, and the grinding rate is 5-10 L / min.
7. The method for manufacturing an anti-counterfeiting tape according to claim 2, characterized in that: In step S7, the stirring is magnetic stirring, and the parameters of the magnetic stirring are: temperature 50-70° C., rotation speed 700-900 r / min, and time 2-3 hours.
8. The method for manufacturing an anti-counterfeiting tape according to claim 2, characterized in that: In step S8, the drying temperature is 40° C. and the drying time is 4-6 hours.
9. The method for manufacturing an anti-counterfeiting tape according to claim 2, characterized in that: In step (5), the drying temperature is 20-30°C and the drying time is 24 hours.