A diaphragm electrolytic cell with a spray cooling circulation system

By combining a spray cooling circulation system with a stirring assembly, the problem of poor cooling effect of electrode rods in existing electrolytic cells has been solved, achieving effective cooling of the liquid around the electrode rods and improving the cooling efficiency of the electrolytic cell.

CN120830116BActive Publication Date: 2026-07-24XINGDI XINNENG (JIANGSU) EQUIP TECH CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XINGDI XINNENG (JIANGSU) EQUIP TECH CO LTD
Filing Date
2025-08-04
Publication Date
2026-07-24

AI Technical Summary

Technical Problem

The existing method of cooling the liquid by stirring in the electrolytic cell is not effective after long-term operation and cannot effectively cool the anode and cathode rods.

Method used

A spray cooling circulation system is combined with a stirring component. The high-temperature liquid around the electrode rod is extracted by the circulation pump component and the annular pipe, cooled by the cooling auxiliary mechanism, and sprayed onto the electrode rod by the spray mechanism to further reduce its temperature.

Benefits of technology

This method effectively cools the electrode rod and the surrounding liquid, improving the efficiency of electrolytic processing.

✦ Generated by Eureka AI based on patent content.

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Patent Text Reader

Abstract

The application relates to the technical field of electrolytic cell devices, in particular to a diaphragm electrolytic cell with a spraying cooling circulation system. According to the scheme, the liquid in the electrolytic cell main body is stirred by a stirring motor and stirring blades, so that the liquid around the electrode rod cannot be accumulated for a long time, and on this basis, a spraying cooling circulation system is further arranged to be used in cooperation with the stirring assembly to perform cooling work on the electrode rod. Through the cooperation of a circulating pump assembly, an annular pipe body and a liquid suction pipe, the liquid with a high temperature around the electrode rod is sucked out, then the liquid is cooled through a cooling auxiliary mechanism, and finally the liquid is sprayed to the electrode rod through a spraying mechanism, so that the electrode rod and the liquid with a high temperature around the electrode rod are cooled. Through the cooperation of the stirring assembly and the spraying cooling circulation system, the temperature of the electrode rod and the liquid around the electrode rod is well reduced, and the electrolytic processing benefit is improved.
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Description

Technical Field

[0001] This invention relates to the field of electrolytic cell equipment technology, and in particular to a diaphragm electrolytic cell with a spray cooling circulation system. Background Technology

[0002] A Chinese patent with publication number CN218262773U discloses a cooling device for an electrolytic cell. The device includes a cell body, a diaphragm, an anode rod, and a cathode rod, as well as a cover plate disposed on top of the cell body; an agitation mechanism for agitating the liquid within the cell; a cooling mechanism for cooling the cell body; the agitation mechanism includes a pair of agitator shafts rotatably mounted within the cell body; and a drive device for driving the agitator shafts to rotate within the cell body. During electrolysis, the cooling mechanism operates to cool the cell body, and the agitation mechanism operates to agitate the liquid within the cell body, ensuring uniform cooling of the liquid.

[0003] The above-mentioned solution only involves agitating the surrounding liquid by stirring the anode and cathode rods with a stirring shaft to prevent the hot liquid from continuously cooling the area around the anode and cathode rods. Instead, it allows the cooler liquid from other areas to flow to the area around the anode and cathode rods, thus achieving a simple cooling effect. However, as the working time increases, the liquid temperature in the tank will become higher, and the cooling effect achieved by stirring alone will be poor. Further improvement and optimization are needed.

[0004] To address these issues, this invention proposes a diaphragm electrolyzer with a spray cooling circulation system. Summary of the Invention

[0005] The purpose of this invention is to provide a diaphragm electrolyzer with a spray cooling circulation system to solve the problems mentioned in the background art.

[0006] To achieve the above objectives, the present invention provides the following technical solution: a diaphragm electrolyzer with a spray cooling circulation system, comprising an electrolyzer body and a support leg disposed at the bottom of the electrolyzer body, wherein an inlet and an outlet are respectively disposed at both ends of the electrolyzer body, and a diaphragm assembly is disposed in the cavity of the electrolyzer body. A stirring assembly is provided at the bottom of the electrolytic cell body, and the electrolytic cell body is connected to a spray cooling circulation system. An electrode rod is provided at the top of the electrolytic cell body, and the spray cooling circulation system cools the electrode rod.

[0007] Preferably, the stirring assembly includes a stirring motor, a connecting shaft, and stirring blades; the stirring motor is fixedly installed at the bottom end of the electrolytic cell body, and the stirring motor is connected to the connecting shaft, which extends through and into the inner cavity of the electrolytic cell body, and the end of the connecting shaft is provided with stirring blades.

[0008] Preferably, the spray cooling circulation system includes an annular pipe, a liquid extraction port, a connecting pipe, a supporting pipe, a circulation pump assembly, a connecting pipe, a storage tank, a return pipe, an ion membrane, a spraying mechanism, and a cooling auxiliary mechanism. The annular pipe is equidistantly arranged on one side of the connecting pipe, and a liquid extraction port is equidistantly arranged on the inner side of the annular pipe. An ion membrane is provided at the end of the liquid extraction port. A supporting pipe is provided on one side of the connecting pipe, and the other end of the supporting pipe extends to the outside of the electrolytic cell body. The end of the supporting pipe is connected to the circulation pump assembly. The circulation pump assembly is also connected to the connecting pipe. The other end of the connecting pipe is located at the top of the storage tank. A cooling auxiliary mechanism is provided in the storage tank. A return pipe is located at the bottom of the storage tank. One end of the return pipe is located at the top of the electrolytic cell body, and the end of the return pipe extends into the inner cavity of the electrolytic cell body. The return pipe in the inner cavity of the electrolytic cell body is connected to the spraying mechanism.

[0009] Preferably, the annular tube is arranged around the side of the electrode rod, and the opening of the liquid extraction tube faces the electrode rod.

[0010] Preferably, the spraying mechanism includes a guide pipe, an annular spray pipe, and spray heads; one end of the guide pipe is connected to the return pipe, and the bottom end of the guide pipe is connected to the annular spray pipe, and spray heads are equidistantly arranged on the inner side wall of the annular spray pipe.

[0011] Preferably, the annular nozzle is also arranged around the side of the electrode rod, and the annular nozzle is located above the topmost annular tube.

[0012] Preferably, the cooling auxiliary mechanism includes an installation cavity, an installation plate, a coolant inlet, a coolant outlet, a manifold, cooling branch pipes, and auxiliary accessories. The installation cavity is located on one side of the storage tank and has threaded holes. The installation plate is fitted into the installation cavity and fixed by screws. A manifold is fixedly installed on the inner side of the installation plate, and cooling branch pipes are fixedly installed at equal intervals on the side wall of the manifold. A coolant inlet and a coolant outlet are located on the outer side of the installation plate, and both the coolant inlet and outlet are connected to the manifold.

[0013] Preferably, the cooling branch pipe is provided with auxiliary accessories, including a cleaning collar, an auxiliary scraper ring, a receiving rod, a loading groove, a positioning groove, a loading ring body, a positioning protrusion, a cleaning brush, and a connecting cap; the cleaning collar is sleeved on the cooling branch pipe, and an auxiliary scraper ring is provided at one end of the cleaning collar. Adjacent cleaning collars are fixedly connected by the receiving rod. The number of sets of cleaning collars and cooling branch pipes is the same, and one cleaning collar is sleeved on one cooling branch pipe.

[0014] Preferably, a loading groove is provided on the inner side of one end of the cleaning collar, and positioning slots are symmetrically arranged in the loading groove. The loading ring body is adapted to be placed in the loading groove. Positioning protrusions are symmetrically fixed on one end of the loading ring body, and the positioning protrusions and positioning slots are positioned correspondingly and are adapted to be engaged. A cleaning brush is arranged in a ring shape on the inner side of the loading ring body. The connecting cover is attached to one end of the cleaning collar and is fixed by screws.

[0015] Preferably, the number of loading rings and cleaning rings is the same, with one loading ring placed in one cleaning ring.

[0016] Compared with the prior art, the beneficial effects of the present invention are: The diaphragm electrolyzer designed in this invention includes an electrolyzer body and support legs located at the bottom of the electrolyzer body. An inlet and an outlet are respectively located at both ends of the electrolyzer body. A diaphragm assembly is installed within the cavity of the electrolyzer body. A stirring assembly is located at the bottom of the electrolyzer body, and the electrolyzer body is connected to a spray cooling circulation system. Electrode rods are located at the top of the electrolyzer body, and the spray cooling circulation system cools the electrode rods. This design, on the one hand, uses a stirring motor to drive the stirring blades to stir the liquid in the electrolyzer body, preventing the hot liquid around the electrode rods from being stirred for extended periods. Over time, a spray cooling circulation system is installed in conjunction with a stirring assembly to cool the electrode rod. Through the combined use of a circulation pump assembly, annular pipe, and liquid extraction port, the high-temperature liquid surrounding the electrode rod is extracted. This liquid is then cooled by a cooling auxiliary mechanism, and finally sprayed onto the electrode rod by a spray mechanism to cool both the electrode rod and the surrounding high-temperature liquid. The combined use of the stirring assembly and the spray cooling circulation system effectively lowers the temperature of the electrode rod and the surrounding liquid, thus positively impacting the efficiency of electrolytic processing. Attached Figure Description

[0017] Figure 1 This is a schematic diagram of the front side connection of the diaphragm electrolyzer structure of the present invention; Figure 2 for Figure 1Enlarged schematic diagram of the structural connection at point A in the middle; Figure 3 This is a schematic diagram of the rear connection of the diaphragm electrolyzer structure of the present invention; Figure 4 for Figure 3 Enlarged schematic diagram of the structural connection at point B; Figure 5 This is a schematic diagram of the internal structure connection plane of the diaphragm electrolyzer of the present invention; Figure 6 This is a bottom view of the internal structure of the diaphragm electrolyzer of the present invention. Figure 7 for Figure 6 Enlarged schematic diagram of the structural connection at point C; Figure 8 This is an exploded view of the connection between the liquid storage tank and the cooling auxiliary mechanism in the spray cooling circulation system of the present invention. Figure 9 for Figure 8 Enlarged schematic diagram of the structural connection at point D; Figure 10 This is a schematic diagram of the cooling auxiliary mechanism structure of the present invention; Figure 11 This is a right-side exploded view of the auxiliary accessory structure connection of the present invention; Figure 12 for Figure 11 Enlarged schematic diagram of the structural connection at point E in the middle; Figure 13 This is a right-side exploded view of the auxiliary accessory structure connection of the present invention; Figure 14 for Figure 13 Enlarged schematic diagram of the structural connection at point F.

[0018] In the diagram: 1. Electrolytic cell body; 2. Support leg; 3. Liquid inlet; 4. Discharge outlet; 5. Electrode rod; 6. Diaphragm assembly; 7. Stirring motor; 801. Connecting shaft; 802. Stirring blade; 803. Annular tube; 901. Liquid extraction port; 902. Connecting tube; 903. Supporting tube; 904. Circulation pump assembly; 905. Connecting pipe; 906. Storage tank; 907. Return pipe; 908. Ion diaphragm; 909. Flow guide pipe; 1001. Annular nozzle; 1002. 1003 Spray head, 1101 Mounting cavity, 1102 Mounting plate, 1103 Coolant inlet, 1104 Coolant outlet, 1105 Manifold fitting, 1106 Cooling branch pipe, 1201 Cleaning collar, 1202 Auxiliary scraper ring, 1203 Receiving rod, 1204 Loading groove, 1205 Positioning slot, 1206 Loading ring body, 1207 Positioning protrusion, 1208 Cleaning brush, 1209 Connecting cover. Detailed Implementation

[0019] The technical solutions in the embodiments of the present invention will be clearly and completely described below. All other embodiments obtained by those skilled in the art without inventive effort are within the scope of protection of the present invention.

[0020] Example 1: Please refer to Figures 1-14 A diaphragm electrolyzer with a spray cooling circulation system includes an electrolyzer body 1 and a support leg 2 disposed at the bottom of the electrolyzer body 1. An inlet 3 and a outlet 4 are respectively disposed at both ends of the electrolyzer body 1. A diaphragm assembly 6 is disposed in the cavity of the electrolyzer body 1. A stirring assembly is disposed at the bottom of the electrolyzer body 1 and the electrolyzer body 1 is connected to the spray cooling circulation system. An electrode rod 5 is disposed at the top of the electrolyzer body 1 and the spray cooling circulation system cools the electrode rod 5.

[0021] This design, on the one hand, uses the stirring motor 801 to drive the stirring blades 803 to stir the liquid in the electrolytic cell body 1, preventing the hot liquid around the electrode rod 5 from accumulating for a long time. Furthermore, a spray cooling circulation system is installed in conjunction with the stirring assembly to cool the electrode rod 5. Through the cooperation of the circulation pump assembly 905, the annular pipe 901, and the liquid extraction port 902, the hot liquid around the electrode rod 5 is extracted. The liquid is then cooled by a cooling auxiliary mechanism. An ion separator 909 is installed at the end of the liquid extraction port 902, which further cools the liquid during extraction. During liquid circulation cooling, active ions in the liquid are blocked to prevent them from being lost with the liquid. Finally, the liquid is sprayed onto the electrode rod 5 through a spray mechanism to cool the electrode rod 5 and the surrounding high-temperature liquid. The stirring assembly includes a stirring motor 801, a connecting shaft 802, and stirring blades 803. The stirring motor 801 is fixedly installed at the bottom of the electrolytic cell body 1 and is connected to the connecting shaft 802. The connecting shaft 802 extends through and into the inner cavity of the electrolytic cell body 1, and the end of the connecting shaft 802 is provided with stirring blades 803.

[0022] While the liquid in the electrolytic cell body 1 is stirred by the stirring assembly, the spray cooling circulation system also operates simultaneously. When extracting liquid from the electrolytic cell body 1, multiple annular tubes 901 are equidistantly arranged around the electrode rod 5, and multiple liquid extraction ports 902 are provided inside the annular tubes 901. The purpose is to directly extract the liquid with higher temperature around the electrode rod 5. The extracted liquid enters the storage tank 907, and is then cooled by the cooling auxiliary mechanism in the storage tank 907. Finally, it enters the inner cavity of the electrolytic cell body 1 and is cooled by the spray head 1 inside the annular spray pipe 1002. The 003 system sprays and cools the liquid, which then flows back into the main body 1 of the electrolytic cell. It also cools the liquid around the electrode rod 5. The spray cooling circulation system includes an annular pipe 901, a liquid extraction port 902, a connecting pipe 903, a support pipe 904, a circulation pump assembly 905, a connecting pipe 906, a storage tank 907, a return pipe 908, an ion separator 909, a spray mechanism, and a cooling auxiliary mechanism. The annular pipe 901 is equidistantly arranged on one side of the connecting pipe 903, and the liquid extraction port 902 is equidistantly arranged on the inner side of the annular pipe 901. The connecting pipe 903... A support pipe 904 is provided on the side, with one end extending to the outside of the electrolytic cell body 1. The end of the support pipe 904 is connected to a circulation pump assembly 905, which is also connected to a connecting pipe 906. The other end of the connecting pipe 906 is located at the top of a storage tank 907, which contains a cooling auxiliary mechanism. A return pipe 908 is located at the bottom of the storage tank 907, with one end at the top of the electrolytic cell body 1 and the other end extending into the inner cavity of the electrolytic cell body 1. The return pipe 908 within the inner cavity of the electrolytic cell body 1 is connected to the spray system. The mechanism is connected; the annular tube 901 is arranged around the side of the electrode rod 5, and the opening of the liquid extraction port 902 faces the electrode rod 5; the spraying mechanism includes a guide tube 1001, an annular spray pipe 1002 and a spray head 1003; one end of the guide tube 1001 is connected to the return pipe 908, and the bottom end of the guide tube 1001 is connected to the annular spray pipe 1002. Spray heads 1003 are equidistantly arranged on the inner wall of the annular spray pipe 1002; the annular spray pipe 1002 is also arranged around the side of the electrode rod 5, and the annular spray pipe 1002 is located above the topmost annular tube 901.

[0023] The extracted liquid enters the storage tank 907 and is primarily cooled by the cooling branch pipe 1106. The cooling auxiliary mechanism includes a mounting cavity 1101, a mounting plate 1102, a coolant inlet 1103, a coolant outlet 1104, a manifold 1105, the cooling branch pipe 1106, and auxiliary accessories. The mounting cavity 1101 is located on one side of the storage tank 907 and has threaded holes. The mounting plate 1102 is fitted into the mounting cavity 1101 and secured with screws. A manifold 1105 is fixedly installed on the inner side of the plate 1102, and cooling branch pipes 1106 are fixedly installed at equal intervals on the side wall of the manifold 1105. A coolant inlet 1103 and a coolant outlet 1104 are provided on the outer side of the plate 1102. Both the coolant inlet 1103 and the coolant outlet 1104 are connected to the manifold 1105. That is, the extracted liquid enters the storage tank 907 through the connecting pipe 906, is cooled by the cooling branch pipes 1106, and then flows back to the inner cavity of the electrolytic cell body 1 through the return pipe 908 at the bottom of the storage tank 907.

[0024] To further improve the cooling effect of the cooling branch pipe 1106 on the liquid, on the one hand, coolant is introduced through the coolant inlet 1103, then flows through the manifold 1105 and the cooling branch pipe 1106, and finally flows out from the coolant outlet 1104 on the other side of the mounting plate 1102. The coolant introduced through the coolant inlet 1103 creates a flowing cooling effect on the cooling branch pipe 1106, carrying away the heat from the liquid entering the liquid storage tank 907. On the other hand, under long-term cooling operation, to ensure the cooling performance of the cooling branch pipe 1106, i.e. Over prolonged use, scale may form on the surface of the cooling branch pipe 1106. This scale formation negatively impacts the cooling effect of the cooling branch pipe 1106. Therefore, this solution utilizes auxiliary accessories to clean the scale on the cooling branch pipe 1106. These accessories include a cleaning collar 1201, an auxiliary scraper ring 1202, a receiving rod 1203, a loading groove 1204, a positioning slot 1205, a loading ring body 1206, a positioning protrusion 1207, a cleaning brush 1208, and a connecting cap 120. 9; A cleaning collar 1201 is fitted onto the cooling branch pipe 1106, and an auxiliary scraper ring 1202 is provided at one end of the cleaning collar 1201. Adjacent cleaning collars 1201 are fixedly connected by a supporting rod 1203. The number of sets of cleaning collars 1201 and cooling branch pipes 1106 is the same, and one cleaning collar 1201 is fitted onto one cooling branch pipe 1106. A loading groove 1204 is provided on the inner side of one end of the cleaning collar 1201, and positioning slots 1205 are symmetrically arranged in the loading groove 1204. The loading ring body 1206 is adapted to fit in the loading groove 1205. The loading ring 1206 is placed in the loading slot 1204. A positioning protrusion 1207 is symmetrically fixed at one end of the loading ring 1206. The positioning protrusion 1207 and the positioning slot 1205 are positioned correspondingly and are fitted together. A cleaning brush 1208 is arranged in a ring shape on the inner side of the loading ring 1206. A connecting cover 1209 is attached to one end of the cleaning collar 1201 and is fixed by screws. The number of loading rings 1206 and cleaning collars 1201 is the same. One loading ring 1206 is placed in one cleaning collar 1201.

[0025] During cleaning, first remove the mounting plate 1102, then remove the cooling branch pipe 1106. Next, pull the cleaning collar 1201 to allow the auxiliary scraper ring 1202 on the front of the cleaning collar 1201 to scrape away the scale on the surface of the cooling branch pipe 1106. Simultaneously, the cleaning brush 1208, located on the inner side wall of the loading ring 1206, also provides a cleaning effect on the surface of the cooling branch pipe 1106. That is, after the auxiliary scraper ring 1202 removes the scale from the surface of the cooling branch pipe 1106, if any fine residue remains, it can be cleaned again by the cleaning brush 1208. After cleaning, the cooling branch pipe 1106 is then... During installation and use, the cleaning collar 1201 needs to be slid back to its initial position, i.e., near the manifold 1105. During prolonged use, the cleaning brush 1208 also needs to be cleaned to ensure its cleanliness and thus its ability to clean the cooling branch pipe 1106. The loading ring 1206 is placed in the loading groove 1204 at one end of the cleaning collar 1201, and is initially positioned by the engagement of the positioning protrusion 1207 with the positioning slot 1205. Removing the loading ring 1206 means removing the cleaning brush 1208, i.e., placing the loading ring 1206 back into the loading groove 1204. After initial positioning, the loading ring 1206 is limited by the connecting cap 1209. Specifically, the connecting cap 1209 is tightly fitted to the end of the cleaning ring 1201 with the loading groove 1204, and fixed with screws. This achieves the installation and fixation of the loading ring 1206, thus completing the installation of the cleaning brush 1208. Therefore, when cleaning the cleaning brush 1208 is required, it can be cleaned according to the actual situation. For example, when it is necessary to disassemble the loading ring 1206 to clean the cleaning brush 1208, the cleaning ring 1201 is slid off the cooling branch pipe 1106, and the exposed cleaning brush is directly cleaned. Cleaning 1208 is sufficient; if cleaning is difficult or a new cleaning brush 1208 needs to be replaced, first, the connecting cover 1209 needs to be removed. After removing the connecting cover 1209, the loading ring 1206 can be taken out from the loading slot 1204. After cleaning the cleaning brush 1208, it can be installed by placing the loading ring 1206 in the loading slot 1204 and making the positioning protrusion 1207 at one end of the loading ring 1206 engage with the positioning slot 1205 in the loading slot 1204. Finally, the connecting cover 1209 can be installed and fixed to limit the loading ring 1206.

[0026] Although embodiments of the invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made to these embodiments without departing from the principles and spirit of the invention, the scope of which is defined by the appended claims and their equivalents.

Claims

1. A diaphragm electrolyzer with a spray cooling circulation system, comprising an electrolyzer body (1) and a support leg (2) disposed at the bottom of the electrolyzer body (1), wherein an inlet (3) and a outlet (4) are respectively disposed at both ends of the electrolyzer body (1), and a diaphragm assembly (6) is disposed in the tank cavity of the electrolyzer body (1). Its features are: A stirring assembly is provided at the bottom of the electrolytic cell body (1), and the electrolytic cell body (1) is connected to a spray cooling circulation system. An electrode rod (5) is provided at the top of the electrolytic cell body (1), and the spray cooling circulation system cools the electrode rod (5). The spray cooling circulation system includes an annular pipe (901), a liquid extraction port (902), a connecting pipe (903), a supporting pipe (904), a circulation pump assembly (905), a connecting pipe (906), a liquid storage tank (907), a return pipe (908), an ion exchange membrane (909), a spray mechanism, and a cooling auxiliary mechanism. The annular pipe (901) is equidistantly arranged on one side of the connecting pipe (903), and the liquid extraction port (902) is equidistantly arranged on the inner side of the annular pipe (901). An ion exchange membrane (909) is provided at the end of the liquid extraction port (902). A supporting pipe (904) is provided on one side of the connecting pipe (903), and the other side of the supporting pipe (904) is... One end extends to the outside of the electrolytic cell body (1), and the end of the support pipe (904) is connected to the circulation pump assembly (905). The circulation pump assembly (905) is also connected to the connecting pipe (906). The other end of the connecting pipe (906) is located at the top of the storage tank (907). The storage tank (907) is equipped with a cooling auxiliary mechanism. A return pipe (908) is located at the bottom of the storage tank (907). One end of the return pipe (908) is located at the top of the electrolytic cell body (1), and the end of the return pipe (908) extends into the inner cavity of the electrolytic cell body (1). The return pipe (908) located in the inner cavity of the electrolytic cell body (1) is connected to the spraying mechanism. The annular tube (901) is arranged around the side of the electrode rod (5), and the opening of the liquid extraction tube (902) faces the electrode rod (5).

2. The diaphragm electrolyzer with a spray cooling circulation system according to claim 1, characterized in that: The stirring assembly includes a stirring motor (801), a connecting shaft (802), and a stirring blade (803). The stirring motor (801) is fixedly installed at the bottom of the electrolytic cell body (1), and the stirring motor (801) is connected to the connecting shaft (802). The connecting shaft (802) extends through and into the inner cavity of the electrolytic cell body (1), and the end of the connecting shaft (802) is provided with a stirring blade (803).

3. The diaphragm electrolyzer with a spray cooling circulation system according to claim 1, characterized in that: The spraying mechanism includes a guide pipe (1001), an annular spray pipe (1002), and spray heads (1003); one end of the guide pipe (1001) is connected to the return pipe (908), and the bottom end of the guide pipe (1001) is connected to the annular spray pipe (1002). Spray heads (1003) are equidistantly arranged on the inner side wall of the annular spray pipe (1002).

4. The diaphragm electrolyzer with a spray cooling circulation system according to claim 3, characterized in that: The annular nozzle (1002) is also arranged around the side of the electrode rod (5), and the annular nozzle (1002) is located above the topmost annular tube (901).

5. The diaphragm electrolytic cell with a spray cooling circulation system according to claim 1, characterized in that: The cooling auxiliary mechanism includes a mounting cavity (1101), a mounting plate (1102), a coolant inlet (1103), a coolant outlet (1104), a manifold (1105), a cooling branch pipe (1106), and auxiliary accessories. The mounting cavity (1101) is located on one side of the reservoir (907), and a threaded hole is provided in the mounting cavity (1101). The mounting plate (1102) is fitted and snapped into the mounting cavity (1101), and the mounting plate (1102) is open to the cooling system. The mounting plate (1102) is fixed with screws. A manifold (1105) is fixedly installed on the inner side of the mounting plate (1102). Cooling branch pipes (1106) are fixedly installed at equal intervals on the side wall of the manifold (1105). A coolant inlet (1103) and a coolant outlet (1104) are provided on the outer side of the mounting plate (1102). Both the coolant inlet (1103) and the coolant outlet (1104) are connected to the manifold (1105).

6. The diaphragm electrolyzer with a spray cooling circulation system according to claim 5, characterized in that: The cooling branch pipe (1106) is provided with auxiliary accessories, including a cleaning collar (1201), an auxiliary scraper ring (1202), a receiving rod (1203), a loading groove (1204), a positioning slot (1205), a loading ring body (1206), a positioning protrusion (1207), a cleaning brush (1208), and a connecting cap (1209). The cleaning collar (1201) is sleeved on the cooling branch pipe (1106), and an auxiliary scraper ring (1202) is provided at one end of the cleaning collar (1201). Adjacent cleaning collars (1201) are fixedly connected by the receiving rod (1203). The number of sets of cleaning collars (1201) and cooling branch pipes (1106) is the same, and one cleaning collar (1201) is sleeved on one cooling branch pipe (1106).

7. The diaphragm electrolytic cell with a spray cooling circulation system according to claim 6, characterized in that: A loading groove (1204) is provided on the inner side of one end of the cleaning collar (1201). A positioning slot (1205) is symmetrically provided in the loading groove (1204). The loading ring body (1206) is adapted to be placed in the loading groove (1204). A positioning protrusion (1207) is symmetrically fixed at one end of the loading ring body (1206). The positioning protrusion (1207) and the positioning slot (1205) are positioned correspondingly and are adapted to be engaged. A cleaning brush (1208) is provided in a ring shape on the inner side of the loading ring body (1206). The connecting cover (1209) is attached to one end of the cleaning collar (1201) and is fixed by screws.

8. The diaphragm electrolyzer with a spray cooling circulation system according to claim 7, characterized in that: The loading ring (1206) and the cleaning ring (1201) are set in the same number of groups, with one loading ring (1206) placed in one cleaning ring (1201).