A method and system for staged desorption of dioxins from fly ash and synergistic treatment of flue gas

By treating fly ash with dechlorination and catalyst passivation, combined with staged preheating and air atmosphere desorption, and using an incinerator for co-processing, the problems of high cost and high energy consumption in dioxin treatment of fly ash have been solved, achieving efficient removal and resource utilization.

CN121607400BActive Publication Date: 2026-05-26TONGJI UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TONGJI UNIV
Filing Date
2026-01-30
Publication Date
2026-05-26

AI Technical Summary

Technical Problem

In existing fly ash treatment technologies, high concentrations of dioxins limit resource utilization, inert atmosphere desorption is costly and energy-intensive, high-temperature air atmosphere desorption equipment suffers severe wear and heavy metal volatilization, and dioxins are severely de novo synthesized under medium-temperature air atmosphere, resulting in poor desorption effects. Furthermore, flue gas purification systems require large investments and have high operating costs.

Method used

By dechlorinating and/or passivating fly ash with catalysts, preheating and desorption in stages, utilizing the short residence time of air atmosphere in the sensitive temperature zone, and co-processing with incinerator, dioxin de novo synthesis is avoided. Indirect heat exchange preheating and waste heat utilization are adopted to reduce energy consumption and suppress heavy metal volatilization.

Benefits of technology

It achieves efficient removal of dioxins from fly ash, reduces operating costs and energy consumption, extends equipment life, reduces environmental risks and transportation costs, and is applicable to various pre-treatment fly ash, offering good flexibility.

✦ Generated by Eureka AI based on patent content.

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Abstract

This invention discloses a method and system for staged desorption of dioxins from fly ash and co-treatment of flue gas in the field of solid waste treatment technology. The method includes collecting fly ash generated from flue gas treatment from a fly ash silo; subjecting the fly ash to dechlorination and / or catalyst passivation treatment to obtain pretreated fly ash; preheating the pretreated fly ash to obtain preheated fly ash; and performing thermal desorption treatment on the preheated fly ash in an air atmosphere. This invention, by performing dechlorination and / or catalyst passivation treatment on the fly ash, reduces the chlorine source and passivation catalyst. By employing indirect heat exchange for waste heat preheating, it avoids dioxin re-adsorption, effectively inhibits de novo dioxin synthesis, achieves efficient desorption in an air atmosphere, avoids the use of inert gases, significantly reduces the operating cost of flue gas treatment, and effectively realizes the reduction, harmlessness, and resource recovery of fly ash.
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