Cleaning and care composition with dandruff removing, itching relieving and repairing effects and preparation method of cleaning and care composition
By combining active peptides and plant extracts, this product addresses the shortcomings of existing shampoos and conditioners in treating mild acne-like scalp problems by providing dandruff relief, itch relief, and repair. It achieves comprehensive scalp care, particularly in repairing the scalp barrier and balancing the scalp's microecological balance.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2026-01-15
- Publication Date
- 2026-03-10
AI Technical Summary
Existing shampoos and conditioners have limited effectiveness in relieving dandruff and itching when dealing with scalp problems accompanied by mild acne-like symptoms. They also do not adequately repair the scalp barrier or balance the scalp's microecology, resulting in a failure to fundamentally improve scalp sensitivity and localized redness and swelling.
It uses a combination of active peptides, plant extracts, antibacterial agents and conditioning agents, including palmitoyl tetrapeptide-10, Clematis chinensis extract, piroctone olamine salt and dihydroamaryl anthranilic acid, which work synergistically to remove dandruff, relieve itching and repair the scalp barrier function.
It achieves highly effective dandruff removal and itch relief for the scalp, while significantly improving the scalp barrier function, reducing dandruff production, relieving scalp itching and mild folliculitis symptoms, and providing a comprehensive scalp care solution.
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Abstract
Description
Technical Field
[0001] This invention belongs to the field of daily chemical technology, specifically relating to a shampoo and conditioner composition that has both dandruff-removing, itch-relieving, and repairing effects, and its preparation method. Background Technology
[0002] As consumers pay increasing attention to scalp health, shampoos and conditioners that combine dandruff removal, itch relief, and scalp repair have become mainstream market demands. Currently, most mainstream shampoos and conditioners, especially those for dandruff removal and itch relief, primarily focus on inhibiting Malassezia, relieving scalp itching, and reducing visible dandruff. However, for the increasingly common complex scalp problems accompanied by mild acne-like symptoms such as pimples, redness, and mild folliculitis, the repairing effects of traditional formulas are insufficient. Existing products often focus on a single dandruff removal or oil control approach, using a large number of chemical dandruff-removing agents (while combined with soothing ingredients can address the basic issues, their effects on repairing the scalp barrier integrity, specifically alleviating inflammation around the hair follicles, and maintaining long-term microecological balance are limited. This results in many consumers experiencing reduced dandruff after use, but without fundamental improvement in scalp sensitivity, localized redness, or hair follicle discomfort.
[0003] Therefore, a shampoo and conditioner combination that can simultaneously eliminate dandruff and relieve itching, and is suitable for scalps with acne, redness, and mild folliculitis, is needed. Through the synergistic combination of active ingredients, it can achieve excellent dandruff and itching relief while also having excellent repairing effects, thus comprehensively addressing scalp problems with complex symptoms. This is of great significance in meeting consumers' urgent need for deep scalp care. Summary of the Invention
[0004] The purpose of this invention is to provide a shampoo and conditioner composition and its preparation method that have the functions of removing dandruff, relieving itching and repairing skin, thereby solving the problem of poor dandruff removal, relieving itching and repairing skin in existing shampoo and conditioner compositions.
[0005] The objective of this invention can be achieved through the following technical solutions: The first aspect of this invention provides a shampoo and conditioner composition that combines dandruff removal, itch relief, and repairing effects, comprising the following raw materials: Active peptides, plant extracts, antibacterial agents, conditioning agents, emulsifiers, solvents.
[0006] As a preferred embodiment of the present invention, the active peptide includes at least one of palmitoyl pentapeptide-4, palmitoyl tetrapeptide-10, palmitoyl tripeptide-1, tetrapeptide-1, and tripeptide-1.
[0007] Preferably, the active polypeptide comprises palmitoyl tetrapeptide-10 and tetrapeptide-1; Palmitoyl tetrapeptide-10 can upregulate the expression levels of corneodesmosin and filaggrin, promote normal maturation of the stratum corneum, reduce scale shedding caused by abnormal differentiation, thereby improving scalp barrier function and assisting in dandruff removal. Oxidative products on the scalp can damage the structural integrity of keratinocytes and accelerate the process of barrier damage, thereby aggravating the invasion of Malassezia furfur and inducing abnormal shedding of keratin. Tetrapeptide-1 has the ability to scavenge free radicals and reduce oxidative stress, which can effectively reduce the irritation of scalp by oxidative products, cut off the external inducing pathway of dandruff production from the root, and achieve the effect of dandruff removal.
[0008] Further, the palmitoyl tetrapeptide-10 is 0.01-0.012 parts by weight, and the tetrapeptide-1 is 0.6-0.12 parts by weight.
[0009] As a preferred embodiment of the present invention, the plant extract includes at least one of tea extract, Clematis chinensis extract, Chamomile extract and Sophora flavescens root extract.
[0010] Preferably, the plant extract includes *Clematis chinensis* extract, which contains active ingredients such as flavonoids and quinones (e.g., henna quinone). It can destroy the cell wall and cell membrane structure of fungi through multi-target action, thereby inhibiting the biosynthesis of ergosterol in fungi and exerting a significant antibacterial effect. In addition, *Clematis chinensis* extract can also effectively antagonize histamine H1 receptors, thus having an antipruritic effect.
[0011] Furthermore, the amount of the *Clematis chinensis* extract is 0.7-1.1 parts by weight.
[0012] As a preferred embodiment of the present invention, the antibacterial agent includes at least one of piroctone ethanolamine salt and quaternary ammonium salt-73.
[0013] Preferably, the antibacterial agent comprises pyrrolidone ethanolamine salt and quaternary ammonium salt-73; Piroctone olamine salt has a broad-spectrum bactericidal effect against fungi and molds, especially against Malassezia furfur, a key pathogen that causes dandruff. Piroctone olamine salt can effectively disrupt its energy metabolism, inhibit its growth and reproduction, and exert a bactericidal effect. The mechanism of action of Quaternium-73 is mainly to disrupt the cell membranes of bacteria and fungi, promote bacterial cell degeneration and accelerate maturation. Furthermore, Quaternium-73 can inhibit common harmful bacteria on the scalp, such as Propionibacterium acnes and Staphylococcus aureus, at low concentrations, demonstrating a highly effective antibacterial effect.
[0014] Furthermore, the amount of pyrrolidone ethanolamine salt is 1.5-3 parts by weight, and the amount of quaternary ammonium salt-73 is 0.6-1 parts by weight.
[0015] As a preferred embodiment of the present invention, the conditioning agent includes at least one of dihydroammyl o-aminobenzoic acid, retinyl palmitate, pyridoxine tripalmitate and tocopheryl acetate.
[0016] Preferably, the conditioner comprises dihydroamaryl-o-aminobenzoic acid and pyridoxine tripalmitate; Dihydroamaryl anthranilic acid is an active ingredient derived from oats. It is a newly emerging ingredient for scalp use in recent years. It can inhibit the NF-κB signaling pathway, regulate the inflammatory response of the scalp microenvironment, and has the effects of relieving skin itching, reducing inflammation and reducing skin redness and swelling. Pyridoxine tripalmitate is a derivative of vitamin B6. It can regulate sebaceous glands and reduce sebum accumulation. It can easily penetrate the stratum corneum of the scalp and act on sebaceous gland cells to reduce excessive sebum secretion and thus promote the growth of pathogenic bacteria such as Propionibacterium acnes and Malassezia, which can induce acne or folliculitis.
[0017] Furthermore, the dihydroamaryl-o-aminobenzoic acid is 1.8-3.5 parts by weight, and the pyridoxine tripalmitate is 0.7-1 parts by weight.
[0018] As a preferred embodiment of the present invention, the emulsifier includes at least one of cocamidopropyl betaine, cetearyl alcohol, and cocoyl glucoside.
[0019] Preferably, the emulsifier includes cocamidopropyl betaine and cetearyl alcohol.
[0020] Furthermore, the amount of cocamidopropyl betaine is 6-10 parts by weight, and the amount of cetearyl alcohol is 2-3 parts by weight.
[0021] As a preferred embodiment of the present invention, the solvent includes deionized water, anhydrous ethanol, propylene glycol, and olive fruit oil.
[0022] Furthermore, the deionized water comprises 65-70 parts by weight, anhydrous ethanol comprises 2-3 parts by weight, propylene glycol comprises 4-7 parts by weight, and olive fruit oil comprises 4-5 parts by weight.
[0023] A second aspect of the present invention provides a method for preparing a shampoo and conditioner composition that has both dandruff-removing, anti-itch, and repairing effects, comprising the following steps: Step 1: Mix olive fruit oil and pyridoxine tripalmitate to obtain mixture A. Mix antibacterial agent, remaining conditioning agent, anhydrous ethanol and propylene glycol and stir under controlled temperature to obtain mixture B. Step 2: Mix the emulsifier and stir under controlled temperature to obtain mixture C; Step 3: Add mixture C, mixture A, and mixture B to the remaining solvent in sequence, and stir under controlled temperature (I). Finally, add the remaining raw materials and stir under controlled temperature (II). Homogenize the mixture under controlled speed, and then discharge the product to obtain the washing and care composition.
[0024] As a preferred embodiment of the present invention, the temperature of the temperature-controlled stirring in step 1 is 45-50℃ and the time is 15-30min.
[0025] As a preferred technical solution of the present invention, the temperature of the temperature-controlled stirring in step 2 is 70-75℃ and the time is 10-15min.
[0026] As a preferred embodiment of the present invention, the temperature of the temperature-controlled stirring I in step 3 is 50-55℃ and the time is 10-15 min; the temperature of the temperature-controlled stirring II is 30-35℃ and the time is 10-15 min; the homogenization speed is 2000-2500 rpm and the time is 5-10 min.
[0027] The third aspect of the present invention provides an application of a shampoo and conditioner composition that has the functions of removing dandruff, relieving itching, and repairing skin, wherein the shampoo and conditioner composition is added at 3-5% of the total mass of the shampoo and conditioner.
[0028] The beneficial effects of this invention are: (1) The main factors causing dandruff and itching on the scalp include the growth of pathogenic microorganisms on the scalp, damage to the scalp barrier function, stimulation of the scalp by external factors, and scalp sensitivity and itching. Therefore, this invention uses a combination of piroctone olamine salt, palmitoyl tetrapeptide-10, tetrapeptide-1 and herb extract to achieve the effect of dandruff removal and itch relief. The combination of chemical components and plant extracts makes up for the limitations of single components, achieving more efficient and gentler scalp care.
[0029] (2) Dihydroamaryl anthranilic acid has the effect of regulating the inflammatory response of the scalp microenvironment, pyridoxine tripalmitate has the effect of reducing excessive sebum secretion and thus promoting the growth of harmful bacteria, while quaternary ammonium salt-73 has the effect of inhibiting common harmful bacteria on the scalp; therefore, the combination of the above three ingredients has an excellent synergistic repair ability for scalps with symptoms such as acne, redness and swelling and mild folliculitis. Detailed Implementation
[0030] The technical solutions of the present invention will be clearly and completely described below with reference to the embodiments of the present invention. Obviously, the described embodiments are only some embodiments of the present invention, and not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative effort are within the scope of protection of the present invention.
[0031] The extract of Clematis armandii used in this invention, catalog number JTSWJHS1488, was purchased from Xi'an Juntian Biotechnology Co., Ltd.; the dihydroamaryl-o-aminobenzoic acid used was purchased from Zhuhai Bairui Pharmaceutical Technology Co., Ltd.; further details will not be provided below.
[0032] Example 1 A shampoo and conditioner composition that combines dandruff removal, itch relief, and repairing effects includes the following raw materials: Active peptides, plant extracts, antibacterial agents, conditioning agents, emulsifiers, solvents; The active polypeptide comprises 0.01 parts by weight of palmitoyl tetrapeptide-10 and 0.36 parts by weight of tetrapeptide-1; The plant extract includes 1.1 parts by weight of Clematis chinensis extract; The antibacterial agent comprises 1.5 parts by weight of piroctone ethanolamine salt and 1 part by weight of quaternary ammonium salt-73; The conditioning agent comprises 1.8 parts by weight of dihydroamaryl-o-aminobenzoic acid and 1 part by weight of pyridoxine tripalmitate; The emulsifier comprises 8 parts by weight of cocamidopropyl betaine and 2 parts by weight of cetearyl alcohol; The solvent comprises 69.73 parts by weight of deionized water, 2 parts by weight of anhydrous ethanol, 7 parts by weight of propylene glycol and 4.5 parts by weight of olive fruit oil. The preparation method of the shampoo and conditioner composition with anti-dandruff, anti-itch, and repairing effects includes the following steps: Step 1: Mix olive fruit oil and pyridoxine tripalmitate to obtain mixture A. Mix antibacterial agent, remaining conditioning agent, anhydrous ethanol and propylene glycol and stir at 47.5℃ for 30 minutes to obtain mixture B. Step 2: Mix the emulsifier and stir at 70°C for 10 minutes to obtain mixture C; Step 3: Add mixture C, mixture A, and mixture B to the remaining solvent in sequence, and stir at 55°C for 10 minutes. Finally, add the remaining raw materials, and stir at 30°C for 10 minutes. Homogenize at 2500 rpm for 7.5 minutes, and then discharge the product to obtain the washing and care composition.
[0033] Example 2 A shampoo and conditioner composition that combines dandruff removal, itch relief, and repairing effects includes the following raw materials: Active peptides, plant extracts, antibacterial agents, conditioning agents, emulsifiers, solvents; The active polypeptide comprises 0.011 parts by weight of palmitoyl tetrapeptide-10 and 0.6 parts by weight of tetrapeptide-1; The plant extract includes 0.7 parts by weight of Clematis chinensis extract; The antibacterial agent comprises 2.2 parts by weight of piroctone ethanolamine salt and 0.6 parts by weight of quaternary ammonium salt-73; The conditioning agent comprises 3.5 parts by weight of dihydroamaryl-o-aminobenzoic acid and 0.7 parts by weight of pyridoxine tripalmitate; The emulsifier comprises 6 parts by weight of cocamidopropyl betaine and 2.5 parts by weight of cetearyl alcohol; The solvent comprises 71.689 parts by weight of deionized water, 2.5 parts by weight of anhydrous ethanol, 4 parts by weight of propylene glycol and 5 parts by weight of olive fruit oil. The preparation method of the shampoo and conditioner composition with anti-dandruff, anti-itch, and repairing effects includes the following steps: Step 1: Mix olive fruit oil and pyridoxine tripalmitate to obtain mixture A. Mix antibacterial agent, remaining conditioning agent, anhydrous ethanol and propylene glycol and stir at 45°C for 15 minutes to obtain mixture B. Step 2: Mix the emulsifier and stir at 75°C for 12.5 minutes to obtain mixture C; Step 3: Add mixture C, mixture A, and mixture B to the remaining solvent in sequence, and stir at 50°C for 12.5 min. Finally, add the remaining raw materials, and stir at 305°C for 103 min. Homogenize at 2000 rpm for 5 min, and then discharge the material to obtain the finished washing and care composition.
[0034] Example 3 A shampoo and conditioner composition that combines dandruff removal, itch relief, and repairing effects includes the following raw materials: Active peptides, plant extracts, antibacterial agents, conditioning agents, emulsifiers, solvents; The active polypeptide comprises -0.012 parts by weight of palmitoyl tetrapeptide-10 and 0.12 parts by weight of tetrapeptide-1; The plant extract includes 0.9 parts by weight of Clematis chinensis extract; The antibacterial agent comprises 3 parts by weight of piroctone ethanolamine salt and 0.8 parts by weight of quaternary ammonium salt-73; The conditioning agent comprises 2.65 parts by weight of dihydroamaryl-o-aminobenzoic acid and 0.85 parts by weight of pyridoxine tripalmitate; The emulsifier comprises 10 parts by weight of cocamidopropyl betaine and 3 parts by weight of cetearyl alcohol; The solvent comprises 66.168 parts by weight of deionized water, 3 parts by weight of anhydrous ethanol, 5.5 parts by weight of propylene glycol and 4 parts by weight of olive fruit oil. The preparation method of the shampoo and conditioner composition with anti-dandruff, anti-itch, and repairing effects includes the following steps: Step 1: Mix olive fruit oil and pyridoxine tripalmitate to obtain mixture A. Mix antibacterial agent, remaining conditioning agent, anhydrous ethanol and propylene glycol and stir at 50°C for 22.5 min to obtain mixture B. Step 2: Mix the emulsifier and stir at 72.5℃ for 15 minutes to obtain mixture C; Step 3: Add mixture C, mixture A, and mixture B to the remaining solvent in sequence, and stir at 52.5℃ for 15 minutes. Finally, add the remaining raw materials, stir at 32.5℃ for 15 minutes, and homogenize at 2250 rpm for 10 minutes. Discharge the material to obtain the finished washing and care composition.
[0035] Comparative Example 1 Compared with Example 1, the difference is that piroctone ethanolamine salt is not added, and the missing weight is made up by palmitoyl tetrapeptide-10, tetrapeptide-1 and Clematis chinensis extract in a mass ratio of 0.01:0.36:1.1, while the rest remain unchanged.
[0036] Comparative Example 2 Compared with Example 1, the difference is that palmitoyl tetrapeptide-10 is not added, and the missing weight is made up by piroctone olamine salt, tetrapeptide-1 and Clematis chinensis extract in a mass ratio of 1.5:0.36:1.1, while the rest remain unchanged.
[0037] Comparative Example 3 Compared with Example 1, the difference is that tetrapeptide-1 is not added, and the missing weight is made up by piroctone olamine salt, palmitoyl tetrapeptide-10 and Clematis chinensis extract in a mass ratio of 1.5:0.01:1.1, while the rest remain unchanged.
[0038] Comparative Example 4 Compared with Example 1, the difference is that the extract of Clematis chinensis is not added, and the missing weight is made up by piroctone olamine salt, palmitoyl tetrapeptide-10 and tetrapeptide-1 in a mass ratio of 1.5:0.01:0.36, while the rest remain unchanged.
[0039] Comparative Example 5 Compared with Example 1, the difference is that dihydroamaryl-o-aminobenzoic acid is not added, and the missing weight is made up by pyridoxine tripalmitate and quaternary ammonium salt-73 in a mass ratio of 1:1, while the rest remain unchanged.
[0040] Comparative Example 6 Compared with Example 1, the difference is that pyridoxine tripalmitate is not added, and the missing weight is made up by dihydroamaryl o-aminobenzoic acid and quaternary ammonium salt-73 in a mass ratio of 1.8:1, while the rest remain unchanged.
[0041] Comparative Example 7 Compared with Example 1, the difference is that quaternary ammonium salt-73 is not added, and the missing weight is made up by dihydroamaryl o-aminobenzoic acid and pyridoxine tripalmitate in a mass ratio of 1.8:1, while the rest remain unchanged.
[0042] Test case Malassezia furfur can cause folliculitis, tinea versicolor, and is closely related to dandruff and scalp health; while Propionibacterium acnes can cause folliculitis, acne, pimples, and other scalp problems. Therefore, in this test case, Malassezia furfur and Propionibacterium acnes were prepared with sterile PBS buffer to a concentration of 5×10⁻⁶. 6 The bacterial suspension at CFU / mL was subjected to an inhibition zone test using the Oxford cup method: Prepare sample solutions with a mass fraction of 1% using deionized water for the washing and conditioning compositions obtained in Examples 1-3 and Comparative Examples 1-7 respectively; take 100 μL of bacterial suspension on the surface of the solidified culture medium, spread it evenly with a sterile spreader, cover the culture dish, and let it stand at 20°C for 10 min; gently invert a sterile Oxford cup on the surface of the culture medium, add sample solution until the liquid surface is parallel to the surface of the Oxford cup, and incubate in an incubator at 37°C for 18 h; Criteria for judging inhibition zone results: An inhibition zone diameter >20mm indicates extreme sensitivity, denoted as ++++. 15-20mm is considered highly sensitive, indicated by +++. 10-15mm is considered moderately sensitive, indicated by ++. <10mm indicates low sensitivity, indicated as +; 0mm indicates no antibacterial effect, represented as -; The results are shown in Table 1.
[0043] Table 1. Diameter of inhibition zone Both Malassezia furfur and Propionibacterium acnes showed better inhibition zone diameters in Examples 1-3 compared to those in Comparative Examples 1-7. This indicates that the combination of piroctone olamine salt, palmitoyl tetrapeptide-10, tetrapeptide-1, and Clematis chinensis extract in this invention can exert anti-dandruff and antipruritic effects; while the combined use of dihydroamaryl anthranilic acid, pyridoxine tripalmitate, and quaternary ammonium salt-73 has excellent antibacterial effects against Propionibacterium acnes, which causes scalp problems such as folliculitis, acne, and pimples, and can effectively repair scalps with symptoms such as pimples, redness, and mild folliculitis.
[0044] In the description of this specification, the references to terms such as "an embodiment," "example," "specific example," etc., indicate that a specific feature, structure, material, or characteristic described in connection with that embodiment or example is included in at least one embodiment or example of the present invention. In this specification, the illustrative expressions of the above terms do not necessarily refer to the same embodiment or example. Furthermore, the specific features, structures, materials, or characteristics described may be combined in any suitable manner in one or more embodiments or examples.
[0045] The above description is merely an example and illustration of the concept of the present invention. Those skilled in the art can make various modifications or additions to the specific embodiments described or use similar methods to replace them, as long as they do not deviate from the concept of the invention or exceed the scope defined in the claims, they should all fall within the protection scope of the present invention.
Claims
1. A shampoo and conditioner composition with the effects of dandruff removal, itching relief and repair, characterized in that, The composition comprises the following raw material ingredients: active polypeptide, plant extract, antibacterial agent, conditioning agent, emulsifier, solvent.
2. The shampoo and conditioner composition with the effects of dandruff removal, itching relief and repair according to claim 1, characterized in that, The active polypeptide comprises 0.01-0.012 parts by weight of palmitoyl tetrapeptide-10 and 0.6-0.12 parts by weight of tetrapeptide-1.
3. The shampoo and conditioner composition with anti-dandruff, anti-itch, and repairing effects according to claim 1, characterized in that, The plant extract comprises 0.7-1.1 parts by weight of Herba Lycopodii extract.
4. The shampoo and conditioner composition with the effects of dandruff removal, itching relief and repair according to claim 1, characterized in that, The antibacterial agent comprises 1.5-3 parts by weight of piroctone olamine and 0.6-1 part by weight of quaternary ammonium salt-73.
5. The shampoo and conditioner composition with the effects of dandruff removal, itching relief and repair according to claim 1, characterized in that, The conditioning agent comprises 1.8-3.5 parts by weight of dihydro avenacyl anthranilic acid and 0.7-1 part by weight of pyridoxine tri-palmitate. 6.The shampoo and conditioner composition with the effects of dandruff removal, itch relief and hair care according to claim 1, wherein the composition further comprises a plant extract. The emulsifier comprises 6-10 parts by weight of cocamidopropyl betaine and 2-3 parts by weight of cetyl stearyl alcohol.
7. The shampoo and conditioner composition with the effects of dandruff removal, itching relief and repair according to claim 1, characterized in that, The solvent comprises 65-70 parts by weight of deionized water, 2-3 parts by weight of anhydrous ethanol, 4-7 parts by weight of propylene glycol, and 4-5 parts by weight of olive fruit oil.
8. A method for preparing the shampoo and conditioner composition with the effects of dandruff removal, itch relief and repair according to any one of claims 1-7, characterized in that, The composition comprises the following steps: Step 1: Mix the olive fruit oil and pyridoxine tri-palmitate to obtain mixture A, and mix the antibacterial agent, the remaining conditioning agent, anhydrous ethanol, and propylene glycol and control temperature stirring to obtain mixture B; Step 2: Mix the emulsifier and control temperature stirring to obtain mixture C; Step 3: Add mixture C, mixture A, and mixture B to the remaining solvent in sequence and control temperature stirring I, finally add the remaining raw materials and control temperature stirring II, control speed homogenization, discharge, and the finished product of the washing and protecting composition is obtained.
9. The method for preparing the shampoo and conditioner composition with the effects of dandruff removal, itch relief and repair according to claim 1, characterized in that, The temperature of the control temperature stirring in step 1 is 45-50°C, and the time is 15-30 min; the temperature of the control temperature stirring in step 2 is 70-75°C, and the time is 10-15 min; the temperature of the control temperature stirring I in step 3 is 50-55°C, and the time is 10-15 min; the temperature of the control temperature stirring II is 30-35°C, and the time is 10-15 min; the speed of the homogenization is 2000-2500 rpm, and the time is 5-10 min.
10. The use of the shampoo and conditioner composition with the effects of dandruff removal, itching relief and repair according to any one of claims 1-7, characterized in that, The washing and protecting composition is added at 3-5% of the total mass of the washing and protecting product.