Sn-based catalysts, their preparation methods, applications, and a method for the electrocatalytic synthesis of formic acid in alkali-free metal salt electrolytes.

By constructing a membrane electrode assembly using Sn-based catalysts and nickel hydroxide catalysts, and using water as a medium for the electrocatalytic synthesis of formic acid, the problems of selectivity and high energy consumption in the electrocatalytic reduction of carbon dioxide were solved, and efficient and simplified formic acid production was achieved.

CN122303943APending Publication Date: 2026-06-30HUNAN UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUNAN UNIV
Filing Date
2026-04-21
Publication Date
2026-06-30

AI Technical Summary

Technical Problem

Existing technologies struggle to selectively and efficiently electrocatalytically reduce carbon dioxide to formic acid under mild conditions, and traditional methods suffer from complex product separation, high energy consumption, and numerous byproducts.

Method used

By employing Sn-based catalysts, a membrane electrode assembly was constructed by preparing Sn-based catalysts with heterostructures of crystalline and amorphous phases and combining them with a nickel hydroxide catalyst. Formic acid was then synthesized electrocatalystically using water as a medium, simplifying the process and improving selectivity.

Benefits of technology

It enables efficient and continuous production of high-purity formic acid with low energy consumption, simplifies the process flow, improves product selectivity and reaction efficiency, and reduces the working potential of the electrolyzer.

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Abstract

This invention discloses a Sn-based catalyst, its preparation method, applications, and a method for the electrocatalytic synthesis of formic acid in an alkali-free metal salt electrolyte. The Sn-based catalyst comprises a crystalline stannous sulfide phase and an amorphous stannous oxide phase, with the crystalline stannous sulfide phase and the amorphous stannous oxide phase forming a heterostructure. The aforementioned Sn-based catalyst can improve the selectivity of specific products in the electrocatalytic reduction of carbon dioxide.
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