System and method for the hydrogenation of 1,4-butynediol to 1,4-butanediol

By using three different catalysts and a temperature control device in the BDO hydrogenation process via the acetylene-aldehyde method, the problem of catalyst carbon buildup is solved, catalyst life is extended, and production efficiency and product quality are improved.

CN122399676APending Publication Date: 2026-07-17SHANGHAI DIYANG CHEMICAL TECHNOLOGY CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
SHANGHAI DIYANG CHEMICAL TECHNOLOGY CO LTD
Filing Date
2026-04-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing BDO hydrogenation process using the acetylene-aldehyde method, the catalyst deactivates rapidly due to carbon buildup, resulting in short catalyst life, low production efficiency, and reduced product quality.

Method used

By employing three catalysts with different properties to precisely control reaction conditions in two reaction stages, the formation of aldehyde intermediates and the deposition of carbon precursors are suppressed through the short residence time and high catalyst conversion rate in the first stage, and the temperature control device and modified auxiliary agent carrier noble metal catalyst in the second stage.

Benefits of technology

Extend catalyst life, reduce unplanned shutdowns, improve production stability and product quality, and reduce production costs.

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Abstract

本发明涉及加氢技术领域,具体提供一种1,4‑丁炔二醇加氢制备1,4‑丁二醇的系统和方法,本发明系统包括第一阶段反应系统、第二阶段反应系统和温控装置,第一阶段反应系统包括第一反应器和换热装置,第一反应器内设置有第一催化剂装填区,第二阶段反应系统包括第二反应器,换热装置设置在第一反应器和第二反应器之间,第二反应器内设置第二催化剂装填区和第三催化剂装填区,二者相邻设置,温控装置用于对第三催化剂装填区的温度进行调控。本发明还提供了制备1,4‑丁二醇的方法,包括:S1第一阶段反应;S2第二阶段反应。通过本发明的应用,可以有效减少催化剂积碳发生,从而使催化剂的使用寿命得到显著延长。
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