A CeTix-mof derived bimetallic based catalyst, its preparation method and use

By preparing CeTix-MOF-derived bimetallic catalysts at low temperatures, a highly efficient hydrogen storage material catalyst was constructed, which solved the problems of framework structure destruction and insufficient active sites caused by high-temperature calcination, and improved the stability of the catalyst and the dissociation and diffusion ability of hydrogen molecules.

CN122399786APending Publication Date: 2026-07-17GUILIN UNIV OF ELECTRONIC TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
GUILIN UNIV OF ELECTRONIC TECH
Filing Date
2026-04-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the prior art, the framework structure of metal-organic framework (MOF) materials is destroyed during high-temperature calcination, resulting in a reduction in specific surface area, insufficient exposure of active sites, disordered defect distribution, and difficulty in constructing multiphase heterogeneous interfaces, which limits the improvement of hydrogen storage catalytic performance.

Method used

A CeTix-MOF-derived bimetallic catalyst was prepared by calcining the CeTix-MOF precursor at a relatively low temperature (350℃) to form a porous carbon-supported titanium oxide composite structure, retaining part of the framework structure, thus constructing a high specific surface area and excellent catalytic performance, suitable for dehydrogenation modification of lithium aluminum hydride (LiAlH4) system.

Benefits of technology

This achieves the dissociation and diffusion of hydrogen molecules, improves the stability and activity of the catalyst, reduces energy consumption, and avoids high-temperature sintering.

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Abstract

本发明属于储氢材料技术领域,具体涉及一种CeTix‑MOF衍生双金属基催化剂的制备方法,包括以下步骤:(1)配制溶液A:钛酸四丁酯溶于乙醇中,超声分散,得到溶液A;(2)配制溶液B:对苯二甲酸与硝酸铈溶于去离子水,超声至溶解,得到溶液B;(3)将溶液A滴入溶液B中,搅拌均匀后,反应,离心分离,洗涤,真空干燥,得到CeTix‑MOF;(4)将CeTix‑MOF前驱体放入氢氩混合气氛中,升温煅烧保温,得到CeTix‑MOF衍生双金属基催化剂。本发明还提供CeTix‑MOF衍生双金属基催化剂及其应用。本发明的催化剂在较低温度即可实现MOF向活性复合结构的转变,降低能耗并避免高温烧结,适用于氢化铝锂体系的脱氢改性,解決过渡金属催化剂分散性差、易团聚、载体副反应导致产氢量下降等问题。
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