Concave pentagonal gold-silver nanobipyramids, preparation method and application thereof

By preparing concave pentagonal gold-silver nanopyramids, the problem of insufficient SERS enhancement performance of anisotropic gold nanomaterials was solved, achieving high-sensitivity and stable SERS detection, which is suitable for trace molecule detection and biosensing.

CN122400549APending Publication Date: 2026-07-17XI AN JIAOTONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
XI AN JIAOTONG UNIV
Filing Date
2026-04-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing anisotropic gold nanomaterials have insufficient enhancement performance in surface-enhanced Raman scattering (SERS) detection, affecting detection sensitivity and stability.

Method used

Concave pentagonal gold-silver bipyramidal nanoparticles were prepared by adding chloroauric acid, ascorbic acid, silver nitrate and hexadecyltrimethylammonium chloride to the growth solution to control the liquid-phase growth of gold bipyramidal nanoparticle seeds, forming a structure with pentagonal pyramids at both ends and a concave middle surface, thereby regulating its crystal planes and morphology.

Benefits of technology

The concave pentagonal gold-silver nanobipyramidal nanoparticles exhibit a SERS enhancement factor of 7.12×10⁶ for rhodamine-based dyes under 633 nm laser excitation, with a minimum detection concentration as low as 10⁻⁹ M. They demonstrate stable signals and high detection sensitivity, making them suitable for trace molecule detection and biosensing.

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Abstract

本发明公开了凹面五棱金银纳米双锥及其制备方法和应用,属于纳米材料制备技术领域。将金纳米双锥种子液加入生长液中进行液相生长,通过调控生长液中氯金酸、抗坏血酸、硝酸银和十六烷基三甲基氯化铵的浓度,结合沉积‑扩散动力学调控,实现凹面五棱纳米双锥的精准可控生长。该凹面五棱金银纳米双锥具有优异的等离子体光学性质,作为SERS基底时对罗丹明6G的增强因子达7.12×106,检测限低至10‑9M,可广泛应用于SERS超灵敏检测、等离子体显色、安全标记等领域,制备方法工艺简单、条件温和、可重复性好,易于规模化生产。
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