Composite activation method for improving activity of blast furnace slag containing titanium

By employing a graded composite activation method, deep grinding and alkali activation or grinding aid-assisted grinding and alkali activation are used for blast furnace slags with different titanium contents. This solves the problem of improving the activity of high-titanium slag and achieves efficient and economical resource utilization.

CN122403797APending Publication Date: 2026-07-17JIUQUAN IRON & STEEL (GRP) CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JIUQUAN IRON & STEEL (GRP) CO LTD
Filing Date
2026-05-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient to effectively enhance the activity of titanium-containing blast furnace slag. Single methods suffer from high energy consumption and low efficiency, especially for high-titanium slag, where mechanical activation efficiency is low and chemical activation effect is limited.

Method used

A graded composite activation method is adopted, and the titanium content is graded according to the titanium content. Low titanium slag is treated by deep grinding and alkali activation, while high titanium slag is treated by grinding aid to assist deep grinding and alkali activation, combining the synergistic effect of physical grinding and chemical activation.

Benefits of technology

It significantly improved the activity index of slag, increasing the low-titanium slag from 73.2% to 97% and the high-titanium slag from 58.2% to 76%, meeting or exceeding national standards, reducing grinding energy consumption, and achieving efficient and economical resource utilization.

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Abstract

本发明公开了一种提升含钛高炉矿渣活性的复合激发方法,属于冶金固废资源化利用技术领域。该方法首先检测矿渣中TiO₂含量,并据此分级:对于TiO₂≤5%的低钛渣,采用“粉磨至比表面积≥450 m² / kg +外掺0.2%~0.5% NaOH”的复合激发;对于TiO₂>5%的高钛渣,采用“添加0.3%~0.5%醇铵类助磨剂共同粉磨至比表面积≥500 m² / kg +外掺0.2%~0.5% NaOH”的复合激发。本发明通过分级策略和“物理‑化学”协同激发,特别是针对高钛渣引入助磨剂,有效克服了钙钛矿等惰性相的阻碍,大幅提升了含钛矿渣的活性,解决了其资源化利用的难题,工艺简单,易于工业化实施。
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