Method for preparing ferroelectric bixing pottery by multi-field coupling microbial mineralization and application

By optimizing the preparation process of ferroelectric Nixing ceramics through targeted modification of microbial communities and multi-field coupling technology, the efficient generation of ferroelectric precursors and dynamic control of dopants were achieved, improving the spontaneous polarization intensity and temperature response of the product. This solved the problems of generation efficiency and structural controllability of ferroelectric Nixing ceramics in the existing technology, and is suitable for efficient material aging and rapid water molecule cluster conversion.

CN122403932APending Publication Date: 2026-07-17GUANGXI ACAD OF SCI
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Patent Information

Application Number
CN202610621895.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing microbial mineralization preparation technology for ferroelectric Nixing pottery, the microbial metabolic pathway is fixed, the generation efficiency and structural controllability of ferroelectric precursors are poor, and chemical doping and microwave radiation do not form a dynamic synergy, resulting in uneven dispersion of dopants, insufficient ferroelectric phase transformation, and single product function, which makes it difficult to meet the needs of efficient material aging and rapid water molecule cluster transformation.

Method used

A composite bacterial agent was formulated using a targeted modified microbial community. Combined with microwave and ultrasonic multi-field coupling technology, a doping system of hydroxyapatite, nano-barium titanate, and poly-N-isopropylacrylamide was introduced. By optimizing the activity of microbial enzymes through gene editing, the targeted synthesis of ferroelectric precursors and the dynamic regulation of dopants were achieved, forming a gradient-distributed ferroelectric structure.

Benefits of technology

It enhances the spontaneous polarization intensity and temperature response capability of ferroelectric Nixing pottery, promotes the adaptive adjustment of the material aging process, improves the mechanical properties and aging efficiency of the finished product, and solves the problems of brittleness and easy breakage of traditional Nixing pottery.

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Abstract

本发明属于高性能坭兴陶制备技术领域,其公开了一种多场耦合微生物矿化制备铁电坭兴陶的方法及应用,其先将白泥、红泥和羟基磷灰石按比例混合经过干法球磨、超声分散和湿法球磨后得到泥料;同时取贝莱斯芽孢杆菌进行基因编辑得到定向改造工程菌,再与纺锤形赖氨酸芽胞杆菌、希瓦氏菌混合得到复合工程菌剂;将泥料、复合工程菌剂、液体培养基和液体电子供体混合后在微波和超声波的作用下培养,将培养得到的微生物矿化泥料加入纯水和由羟基磷灰石、纳米钛酸钡、聚N‑异丙基丙烯酰胺混合得到的复合掺杂剂,然后球磨和干燥后揉练塑形成坯料,再将坯料在微波和超声波作用下烧结得到铁电坭兴陶,其具有优良的铁电性能和力学性能,可用于辅助物料陈化。
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