Automatic low temperature alloying process for spring

By precisely controlling the phase in the low-temperature isothermal phase region and forming a gradient metallurgical composite diffusion layer through rare earth microalloying, the problems of high-temperature tempering softening and brittle phase precipitation of the spring clips are solved, achieving hydrogen embrittlement-free, high corrosion resistance and self-healing capability, which is suitable for the automated mass production of railway spring clips.

CN122406149APending Publication Date: 2026-07-17ZHENGZHOU ZHONGYUAN LIDA NEW MATERIAL CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHENGZHOU ZHONGYUAN LIDA NEW MATERIAL CO LTD
Filing Date
2026-04-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing powder zinc infiltration technology has problems such as high-temperature tempering softening, brittle phase precipitation, microcrack generation and insufficient self-repair ability in spring clips, making it difficult to achieve automated mass production of spring clips with low-temperature preservation, no hydrogen embrittlement and high corrosion resistance.

Method used

By employing precise phase control in the low-temperature isothermal phase region, synergistic doping of multiple metal elements, and rare earth microalloying, a gradient metallurgical composite diffusion layer is formed, including an inner diffusion matrix of the Fe-Zn binary phase system, and rare earth microalloying superimposed on the phase diagram of the Zn-Al-Mg ternary zinc-rich system, forming a continuous gradient metallographic structure. This structure is further enhanced by rare earth atom solid solution, grain boundary segregation, and nano-oxide dispersion, combined with a surface self-healing mechanism.

Benefits of technology

It achieves zero degradation of the mechanical properties of the elastic clip matrix, no hydrogen embrittlement, high salt spray resistance, and self-healing capability, making it suitable for mass automated production of railway elastic clips and improving the stability and corrosion resistance of the infiltration layer.

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Abstract

本发明公开了弹条自动低温合金共渗工艺,结合 Zn‑Al‑Mg 三元富锌 380℃等温相平衡特征,引入镧、铈稀土微合金化稳相改性;在 370~395℃低温区间实现多元素活性原子梯度扩散,形成薄 Γ 过渡相、致密 δ1主耐蚀相、富锌 ζ 阳极相与 MgZn2自修复表层的复合冶金渗层。稀土弥散细化晶粒、降低扩散活化能、抑制脆性相与微裂纹;整套工艺采用全自动预处理、密闭配粉、氮气保护低温渗扩、缓冷分离及无铬钝化后处理。本发明让弹条基体强度弹性零衰减,盐雾耐受性能大幅提升,适合大规模自动化量产。
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