A nanoparticle modified biof / tio2 composite photoanode material and preparation and application thereof

By loading BiOF nanoparticles onto a TiO2 nanotube array, a BiOF/TiO2 composite photoanode material is formed, which solves the problems of narrow light absorption and recombination of photogenerated carriers in TiO2, improves visible light response and electron separation efficiency, and enhances the metal corrosion resistance.

CN122406235APending Publication Date: 2026-07-17INST OF OCEANOLOGY - CHINESE ACAD OF SCI
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Patent Information

Application Number
CN202510059404.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-01-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

TiO2 photocatalytic materials suffer from narrow light absorption characteristics under visible light and severe recombination of photogenerated carriers, resulting in low photocatalytic efficiency and making them difficult to apply effectively in the field of metal corrosion protection.

Method used

BiOF nanoparticles were loaded onto a TiO2 nanotube array via a hydrothermal method to form a BiOF/TiO2 composite photoanode material. The narrow bandgap characteristics of BiOF were utilized to enhance the visible light response and suppress photogenerated carrier recombination.

Benefits of technology

It significantly improves the photocatalytic efficiency of TiO2 under visible light, prolongs the lifetime of photogenerated electrons, enhances the corrosion resistance of metals, and is suitable for humid and highly corrosive environments.

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Abstract

本发明涉及复合膜光阳极材料,特别是一种纳米颗粒修饰的BiOF / TiO2复合光阳极材料及制备和应用。制备方法为通过水热法在所述TiO2纳米管阵列上负载BiOF纳米颗粒。本发明复合膜作为光阳极应用于阴极保护时,与传统的纯TiO2材料相比,具有显著的优势。其设计能有效提高可见光的吸收和利用率,并增强光生载流子的分离效率,从而显著降低304不锈钢的电极电位,提升整体光电化学阴极保护性能。
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