A cobalt-nickel boride nanosheet electrocatalytic material and a preparation method thereof

By growing cobalt-nickel boride nanosheets in situ at low temperature on a nickel foam substrate, the problem of difficult control of catalyst morphology and structure in existing technologies has been solved, achieving highly efficient bifunctional electrocatalytic performance and stability, simplifying the production process and reducing energy consumption.

CN122406296APending Publication Date: 2026-07-17CHINA JILIANG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHINA JILIANG UNIV
Filing Date
2026-06-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for preparing bifunctional catalysts using materials such as nickel-boron and cobalt-boron are difficult to precisely control the microstructure and structure of the catalysts, resulting in insufficient exposure of active sites and low mass transfer efficiency. In particular, the release of bubbles is not smooth at high current densities, which limits the reaction kinetics.

Method used

A one-step reduction method was used to grow cobalt-nickel boride nanosheets in situ at low temperature on a nickel foam substrate. By controlling the dropping rate of sodium borohydride solution and the reaction temperature, a vertically aligned, ultrathin and uniformly distributed nanosheet structure was formed. Combined with the nickel foam substrate, a robust three-dimensional self-supporting structure was formed, which enhanced the electron transport channels and interfacial bonding.

Benefits of technology

The specific surface area of ​​the catalyst was significantly increased, exposing more active sites and improving the efficiency of hydrogen evolution and oxygen evolution reactions. The material maintained structural integrity and activity stability during long-term electrocatalytic cycling, reducing production costs and energy consumption.

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Abstract

本发明公开了一种硼化钴镍纳米片电催化材料及其制备方法,采用泡沫镍为基体,采用镍和钴的混合盐溶液,通过一步还原法将CoNiB负载在泡沫镍上,还原剂为硼氢化钠,通过控制硼氢化钠与金属盐的摩尔比、添加速度调控催化剂的形貌,获得了具有垂直排列片状微观结构的自支撑电极CoNiB / N,本发明的硼化钴镍纳米片电催化材料及其制备方法,生产工艺简单,成本低,通过片状结构增加了反应的活性位点,有利于析氢过程中气体的释放,大幅度提高析氢和析氧反应的催化活性,具有优异的电催化性能。
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