A method for removing green glue on surface of UHMWPE fiber by ion liquid-supercritical CO2 synergism

By using the synergistic effect of ionic liquids and supercritical CO2, the problem of efficient removal of adhesive from the surface of UHMWPE fibers was solved, enabling efficient and environmentally friendly fiber reuse while maintaining good fiber performance. The solvent is regenerable, and production costs are reduced.

CN122406531APending Publication Date: 2026-07-17GUANGDONG XIONGSU TECH GRP CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
GUANGDONG XIONGSU TECH GRP CO LTD
Filing Date
2026-06-16
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies struggle to efficiently remove thermosetting epoxy adhesive layers from the surface of UHMWPE fibers without damaging their intrinsic properties. Traditional methods suffer from environmental pollution, low efficiency, fiber damage, or high costs.

Method used

A method combining ionic liquids and supercritical CO2 is employed to achieve efficient removal of thermosetting epoxy adhesive layers through pre-swelling of composite ionic liquids and mechanical exfoliation by ultrasonic cavitation force, combined with the physical swelling effect of supercritical CO2.

Benefits of technology

It achieves efficient removal of thermosetting epoxy adhesive layers with an adhesive removal rate of over 95%, maintains good fiber properties, is environmentally friendly, uses renewable solvents, and significantly reduces production costs.

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Abstract

本发明公开了一种离子液体‑超临界CO2协同作用的UHMWPE纤维表面胶绿色去除方法,属于高分子材料回收再利用技术领域。该方法包括:将1‑乙基‑3‑甲基咪唑乙酸盐与1,8‑二氮杂双环[5.4.0]十一碳‑7‑烯混合,得复合离子液体;将含胶UHMWPE纤维下脚料置于容器中,加入复合离子液体浸没,加热浸渍预溶胀;通入二氧化碳,同时开启超声,在超声与超临界二氧化碳协同作用下进行除胶处理;泄压后冲洗干燥,得到除胶后的UHMWPE纤维。本发明利用复合离子液体对胶层的预溶胀作用,结合超临界CO2的低粘高渗透性及超声的空化效应,在不损伤纤维基体的前提下高效、绿色去除表面胶层,无有机溶剂残留,工艺环保。
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