A washable antibacterial nylon fabric and a preparation method thereof

By introducing N-hydroxymethyl groups onto the surface of nylon fabrics and forming an antibacterial film through interfacial polymerization of PEI and TMC, and combining the amino reduction and coordination effects of PEI to achieve in-situ deposition of nano-silver, the problems of weak binding force and poor washability of antibacterial agents on nylon fabrics are solved, thereby improving the antibacterial durability and breathability of nylon fabrics.

CN122406540APending Publication Date: 2026-07-17YANGZHOU JIYUAN TEXTILE

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
YANGZHOU JIYUAN TEXTILE
Filing Date
2026-05-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing antibacterial finishing technologies for nylon fabrics suffer from weak binding force of antibacterial agents, poor washability, and difficulty in effectively loading nano-silver, which affects the breathability and hand feel of the fabric and cannot meet the long-term antibacterial requirements.

Method used

A two-bath stepwise process was adopted, in which N-hydroxymethyl groups were introduced on the surface of nylon fibers through formaldehyde activation treatment, and an antibacterial film was formed by interfacial polymerization of polyethyleneimine (PEI) and trimesoyl chloride (TMC). In-situ deposition of nano-silver was achieved by means of amino reduction and coordination of PEI.

Benefits of technology

This invention achieves highly washable antibacterial nylon fabric with long-lasting antibacterial effect and photodynamic antibacterial efficacy, while maintaining the fabric's hand feel and breathability, and improving the binding strength and washability of the antibacterial agent.

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Abstract

本发明公开了一种耐洗抗菌锦纶织物及其制备方法,制备方法首先通过甲醛活化处理,在锦纶纤维表面引入N‑羟甲基反应位点;其次,将锦纶织物采用聚乙烯亚胺(PEI)与均苯三甲酰氯(TMC)二浴法进行处理,实现纤维表面通过界面聚合形成抗菌膜;最后,借助PEI分子中氨基还原与配位作用,实现纤维表面纳米银原位沉积。本发明采用二浴法分步处理,实现PEI与TMC在纤维表面的界面聚合,通过“先吸附后键合”的分步策略形成连续稳定的抗菌膜结构,同时借助PEI中氨基的还原与配位双重作用,实现纳米银原位还原和稳定负载,赋予锦纶织物暗处长效抗菌效果和短时间光动力抗菌功效,同时提升耐洗性能。
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