Lithium-rich lithium iron phosphate composite material, preparation method thereof, positive plate and lithium ion battery

By coating the outer surface of lithium iron phosphate material with a composite layer of alumina and carbon, the problems of material conductivity and structural stability were solved, resulting in a lithium-ion battery with high energy density and good cycle performance.

CN122417853APending Publication Date: 2026-07-17HEFEI GUOXUAN HIGH TECH POWER ENERGY
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Patent Information

Application Number
CN202610737693.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium iron ferrite materials suffer from low intrinsic conductivity, poor structural stability, and high residual alkali content on the surface, resulting in poor processing performance and limited release capacity.

Method used

A composite coating layer of alumina and carbon materials is used to coat the outer surface of the lithium iron ferrite core. A dense coating layer is formed by atomic layer deposition technology. The thickness and mass ratio of the coating layer are controlled. Combined with an inorganic carbon source, side reactions are avoided during high-temperature sintering, thereby improving the electrical conductivity and structural stability of the material.

Benefits of technology

It significantly improves the electrical conductivity and structural stability of lithium iron phosphate composite materials, reduces the residual alkali content on the surface, and enhances the energy density and cycle performance of the battery.

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Abstract

本发明提供了一种富锂铁酸锂复合材料及其制备方法、正极片、锂离子电池。该富锂铁酸锂复合材料包括富锂铁酸锂内核和包覆在富锂铁酸锂内核外表面的包覆层;富锂铁酸锂内核的化学式为Li5FeO4;包覆层包括氧化铝和碳材料。本发明的富锂铁酸锂复合材料在不规则富锂铁酸锂颗粒的外表面包覆了均匀且致密的包覆层,该包覆层能够提高富锂铁酸锂复合材料的电导率、结构稳定性以及减少表面残碱的含量,从而提高电池的电化学性能。
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