Linear piezoelectric thin film material based on undoped ceria and method for preparing the same

By guiding it along in an undoped cerium oxide film <111> Crystalline growth, utilizing alternating atomic layers to excite charge shift, solves the lattice disorder problem of traditional cerium oxide doped materials, achieving high linearity and hysteresis-free piezoelectric response, and expanding the application of piezoelectric materials.

CN122421660APending Publication Date: 2026-07-17FOSHAN UNIVERSITY
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Patent Information

Application Number
CN202610695842.6
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies achieve linear piezoelectric response by doping cerium oxide materials to disrupt the centrosymmetric structure, resulting in lattice disorder and electrical losses, which limits their application in high-precision micro/nano electromechanical systems.

Method used

By utilizing the lattice matching relationship between the substrate and the bottom electrode in an undoped cerium oxide thin film, the film is guided along... <111> Crystalline growth excites charge shifts caused by alternating atomic layers, achieving a linear piezoelectric response.

Benefits of technology

It achieves high linearity and hysteresis-free piezoelectric response, broadens the selection range of piezoelectric materials, and is suitable for high-precision sensing and actuation fields.

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Abstract

本发明涉及一种基于未掺杂氧化铈(CeO₂)的线性压电薄膜材料及其制备方法。制备方法的特点如下:(1)选取洁净的刚性或柔性载体为衬底,选择性制备缓冲层薄膜与下电极,设计并优化其与氧化铈薄膜的界面匹配特性;(2)采用物理气相沉积等清洁镀膜工艺,调控镀膜参数以获得高质量氧化铈薄膜。如此获得的氧化铈薄膜材料具有以下特点:(1)晶体结构为中心对称的萤石结构;(2)氧化铈薄膜晶体的<111>取向与薄膜法向z轴平行;(3)具有线性的正向压电特性与线性的反向压电特性,无压电迟滞现象,压电系数d33范围为5‑50 pm / V。本发明发现了中心对称结构未掺杂氧化铈半导体的压电性质,拓展了压电半导体材料种类,为基于氧化铈的半导体器件性能提升奠定了基础,具备广阔的应用潜力与发展前景。
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