Corrosion-resistant high-aluminum glass bead
By designing the bead core of the three-stage structure and the external layer of the multi-layer structure, the problem of reflective glass beads being easily shedded after long exposure is solved, achieving a stronger reflection effect and a longer service life.
Patent Information
- Application Number
- CN202421494738.3
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2024-06-26
- Publication Date
- 2025-04-25
- Estimated Expiration
- 2034-06-26
AI Technical Summary
Existing reflective glass beads are prone to fall off after long exposure to wind and sun exposure, affecting the reflection effect.
A corrosion-resistant high-aluminum glass bead is designed, and its bead core is composed of the first bead, the second bead and the third bead. The outer diameters of both ends are larger than the outer diameter in the middle, which increases the fixity of the glass beads. The external hierarchy includes a colloidal layer, a corrosion-resistant layer and refractive particles. The corrosion-resistant layer is composed of a liquid crystal polymer layer and a styrene butadiene rubber layer, which enhances the corrosion resistance of the glass beads.
Effectively fix the glass beads to prevent falling off, while enhancing the reflection effect, making the reflected light more concentrated and extending the service life of the glass beads.
Smart Images

Figure CN222795444U_ABST
Abstract
Description
Technical Field
[0001] The utility model relates to the technical field of glass beads, in particular to a corrosion-resistant high-aluminum glass bead. Background Art
[0002] Glass beads are a new type of material with a wide range of uses and special properties developed in recent years. This product has the advantages of light weight, low thermal conductivity, high strength, and good chemical stability. Glass beads are the most commonly used night reflective material in road marking paints for urban roads. The application of reflective glass beads in road markings is achieved through retroreflective technology: when driving at night, the lights of vehicles shine on the road markings, and the reflective glass beads contained in the paint produce a retroreflective effect on the car lights. The driver can see the markings clearly and judge the driving route, effectively avoiding traffic accidents.
[0003] A reflective glass bead for highway with publication number CN211522956U comprises a bead body, a reflective glitter sheet and a transparent varnish, wherein the reflective glitter sheet is scattered in the bead body, the surface of the bead body is coated with transparent varnish, the reflective glitter sheet is evenly kneaded in the bead body, the reflective glitter sheet is a reflective aluminum-plated sheet, and glass microbeads are a new type of material with a wide range of uses and special performance developed in recent years. In the utility model, the reflective glass beads will enter the bead body through refraction under the illumination of a light source, and will be reflected multiple times by the reflective glitter sheet in the bead body to form a shining point, so that the reflective glass beads emit a bright light under the illumination of street lamps, increase the visibility range at night, remind drivers of the edge of the road, and prevent drivers from hitting the curb, but reflective markings are usually used outdoors and exposed to the air. After a long period of wind and sun, the glass beads are easy to fall off, thereby affecting the reflective effect. Utility Model Content
[0004] The utility model aims to solve the shortcomings existing in the prior art, and comprises: a bead core; a colloid layer, wherein the colloid layer is wrapped around the outside of the bead core; a corrosion-resistant layer, wherein the corrosion-resistant layer is wrapped around the outside of the colloid layer; refractive particles, wherein the refractive particles are arranged inside the colloid layer; the bead core comprises a first bead, a second bead and a third bead connected from top to bottom, wherein the outer diameters of the first bead and the third bead are greater than the outer diameter of the second bead, and both the first bead and the third bead are spherical; the corrosion-resistant layer comprises a liquid crystal polymer layer and a styrene-butadiene rubber layer, wherein the liquid crystal polymer layer is arranged on the outside of the colloid layer, and the styrene-butadiene rubber layer is arranged on the outside of the liquid crystal polymer layer.
[0005] As a further description of the above technical solution: the refractive particles include aluminum particles, and a plurality of mirrors are distributed in a circumferential array on each end face of the aluminum particles, and a long afterglow material coating is arranged in the center of the mirror on each end face.
[0006] As a further description of the above technical solution: a plurality of refractive particles are scattered around the outside of the bead core.
[0007] As a further description of the above technical solution: the surface of the bead core has micropores, and the colloidal layer penetrates into the micropores and is fixedly connected to the bead core.
[0008] As a further description of the above technical solution: the liquid crystal polymer layer and the styrene-butadiene rubber layer are connected by hot melt adhesive.
[0009] As a further description of the above technical solution: the first bead and the third bead have the same structure.
[0010] As a further description of the above technical solution: the second bead is in the shape of a truncated cone with a concave center.
[0011] The above technical solution has the following advantages or beneficial effects:
[0012] The utility model designs the bead core into a three-section structure consisting of a first bead body, a second bead body and a third bead body, and the outer diameters of the two ends are larger than the outer diameter in the middle, so that when the glass bead is embedded in the marking line, the third bead body can be completely embedded in the base marking line, the marking line wraps the second bead body, and the outer diameter of the second bead body is smaller than the outer diameter of the third bead body, so that the end of the glass bead cannot escape from the marking line, thereby effectively fixing the glass bead and preventing the glass bead from falling off. At the same time, the first bead body and the third bead body are both spherical in design, so that the emission surface is larger and the reflection surface is gently curved, so that the glass bead can make the reflected light more concentrated relative to the spherical surface under the premise of ensuring a larger reflection range, so that the reflection effect is stronger. BRIEF DESCRIPTION OF THE DRAWINGS
[0013] Figure 1 This is a schematic diagram of the structure of glass beads in one embodiment of the utility model;
[0014] Figure 2 It is a cross-sectional view of a glass bead in one embodiment of the utility model;
[0015] Figure 3 for Figure 1 Schematic diagram of the structure of the corrosion-resistant layer in the glass beads;
[0016] Figure 4 for Figure 1 Schematic diagram of the structure of refractive particles in glass beads.
[0017] Legend:
[0018] 1. Bead core; 2. Colloidal layer; 3. Corrosion-resistant layer; 4. Refractive particles; 101. First bead; 102. Second bead; 103. Third bead; 31. Liquid crystal polymer layer; 32. Styrene-butadiene rubber layer; 41. Aluminum particles; 42. Mirror surface; 43. Long afterglow material coating. DETAILED DESCRIPTION
[0019] The following will be combined with the drawings in the embodiments of the utility model to clearly and completely describe the technical solutions in the embodiments of the utility model. Obviously, the described embodiments are only part of the embodiments of the utility model, not all of the embodiments. Based on the embodiments in the utility model, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the utility model.
[0020] In the description of the present invention, it should be noted that the terms "vertical", "up", "down", "horizontal", etc. indicate orientations or positional relationships based on the orientations or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific orientation, be constructed and operated in a specific orientation, and therefore cannot be understood as a limitation on the present invention.
[0021] In the description of the present invention, it is also necessary to explain that, unless otherwise clearly specified and limited, the terms "set", "set", "connected", and "connected" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection, or it can be indirectly connected through an intermediate medium, or it can be the internal communication of two components. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.
[0022] like Figure 1-4 As shown, the utility model is a corrosion-resistant high-aluminum glass bead, comprising: a bead core 1; a colloid layer 2, the colloid layer 2 is wrapped around the outside of the bead core 1; a corrosion-resistant layer 3, the corrosion-resistant layer 3 is wrapped around the outside of the colloid layer 2; refractive particles 4, the refractive particles 4 are arranged inside the colloid layer 2; the bead core 1 comprises a first bead 101, a second bead 102 and a third bead 103 connected from top to bottom, the outer diameters of the first bead 101 and the third bead 103 are greater than the outer diameter of the second bead 102, and the first bead 101 and the third bead 103 are both spherical; the corrosion-resistant layer 3 comprises a liquid crystal polymer layer 31 and a styrene-butadiene rubber layer 32, the liquid crystal polymer layer 31 is arranged on the outside of the colloid layer 2, and the styrene-butadiene rubber layer 32 is arranged on the outside of the liquid crystal polymer layer 31.
[0023] In this embodiment, the bead core 1 is designed to be a three-section structure consisting of a first bead body 101, a second bead body 102 and a third bead body 103, and the outer diameters of the two ends are larger than the outer diameter in the middle, so that when the glass bead is embedded in the marking line, the third bead body 103 can be completely embedded in the base marking line, and the marking line wraps the second bead body 102, and the outer diameter of the second bead body 102 is smaller than the outer diameter of the third bead body 103, so that the end of the glass bead cannot escape from the marking line, so that the glass bead can be effectively fixed to prevent it from falling off. At the same time, the first bead body 101 and the third bead body 103 are both spherical in design, so that their emitting surface is larger and the reflecting surface is gently curved, so that the glass bead can make the reflected light more concentrated relative to the spherical surface while ensuring a larger reflection range, so that the reflection effect is stronger.
[0024] Among them, the liquid crystal polymer layer 31 has the advantages of high strength, outstanding heat resistance, chemical corrosion resistance, and weather aging resistance, and the styrene-butadiene rubber layer 32 has the advantages of wear resistance, heat resistance, and aging resistance, so that the corrosion-resistant layer 3 enhances the corrosion resistance of the glass beads and can extend the service life of the glass beads.
[0025] like Figure 1 and Figure 2 As shown, specifically, the refractive particles 4 include aluminum particles 41, and a plurality of mirror surfaces 42 are circumferentially arrayed on each end surface of the aluminum particles 41, and a long afterglow material coating 43 is provided in the center of the mirror surface 42 on each end surface, and a plurality of refractive particles 4 are scattered around the outer side of the bead core 1; the long afterglow material coating 43 on the refractive particles 4 can absorb energy during the day and emit light at night, and the light is refracted to all directions through the mirror surface 42 of the aluminum particles 41, so that pedestrians on the road can also see the road markings clearly, and at the same time, when a motor vehicle is driving at night, the light shining on the refractive particles 4 of the reflective glass beads can be easily reflected by the mirror surface 42 to facilitate the driver to see the road markings and prevent the motor vehicle from driving into the wrong lane.
[0026] like Figure 1 and Figure 2 As shown, specifically, the surface of the bead core 1 has micropores, the colloid layer 2 penetrates into the micropores and is fixedly connected to the bead core 1, the liquid crystal polymer layer 31 and the styrene-butadiene rubber layer 32 are connected by hot melt adhesive, the first bead 101 and the third bead 103 have the same structure, and the second bead 102 is a truncated cone with a concave middle portion.
[0027] Working principle: The staff designed the bead core 1 into a three-section structure consisting of a first bead body 101, a second bead body 102 and a third bead body 103, and the outer diameters of the two ends are larger than the outer diameter in the middle, so that when the glass bead is embedded in the marking line, the third bead body 103 can be completely embedded in the base marking line, and the marking line wraps the second bead body 102, and the outer diameter of the second bead body 102 is smaller than the outer diameter of the third bead body 103, so that the end of the glass bead cannot escape from the marking line, thereby effectively fixing the glass bead and preventing it from falling off. At the same time, the first bead body 101 and the third bead body 103 are both spherical in design, so that their emitting surface is larger and the reflecting surface is gently curved, so that the glass bead can make the reflected light more concentrated relative to the spherical surface while ensuring a larger reflection range, thereby achieving a stronger reflection effect.
[0028] It should be noted that, in this article, relational terms such as first and second, etc. are only used to distinguish one entity or operation from another entity or operation, and do not necessarily require or imply any such actual relationship or order between these entities or operations. Moreover, the terms "include", "comprise" or any other variants thereof are intended to cover non-exclusive inclusion, so that a process, method, article or device including a series of elements includes not only those elements, but also other elements not explicitly listed, or also includes elements inherent to such process, method, article or device.
[0029] The preferred embodiments of the utility model disclosed above are only used to help explain the utility model. The preferred embodiments do not describe all the details in detail, nor do they limit the utility model to the specific implementation methods described. Obviously, many modifications and changes can be made according to the content of this specification. This specification selects and specifically describes these embodiments in order to better explain the principles and practical applications of the utility model, so that technicians in the relevant technical field can well understand and use the utility model. The utility model is limited only by the claims and their full scope and equivalents.
Claims
1. A corrosion-resistant high-aluminum glass bead, characterized in that: include: Bead core (1); A colloid layer (2), wherein the colloid layer (2) is wrapped around the outside of the bead core (1); A corrosion-resistant layer (3), wherein the corrosion-resistant layer (3) is wrapped around the outside of the colloid layer (2); Refractive particles (4), the refractive particles (4) being arranged inside the colloidal layer (2); The bead core (1) comprises a first bead (101), a second bead (102) and a third bead (103) connected from top to bottom, the outer diameters of the first bead (101) and the third bead (103) are greater than the outer diameter of the second bead (102), and the first bead (101) and the third bead (103) are both spherical; The corrosion-resistant layer (3) comprises a liquid crystal polymer layer (31) and a styrene-butadiene rubber layer (32); the liquid crystal polymer layer (31) is arranged outside the colloid layer (2); and the styrene-butadiene rubber layer (32) is arranged outside the liquid crystal polymer layer (31).
2. The corrosion-resistant high-aluminum glass beads according to claim 1, characterized in that: The refractive particles (4) include aluminum particles (41), each end surface of the aluminum particles (41) is provided with a plurality of mirror surfaces (42) distributed in a circumferential array, and a long afterglow material coating (43) is provided in the center of the mirror surface (42) on each end surface.
3. The corrosion-resistant high-aluminum glass beads according to claim 1, characterized in that: A plurality of refractive particles (4) are distributed around the outer side of the bead core (1).
4. The corrosion-resistant high-aluminum glass beads according to claim 3, characterized in that: The surface of the bead core (1) is provided with micropores, and the colloid layer (2) penetrates into the micropores and is fixedly connected to the bead core (1).
5. The corrosion-resistant high-aluminum glass beads according to claim 1, characterized in that: The liquid crystal polymer layer (31) and the styrene-butadiene rubber layer (32) are connected via hot melt adhesive.
6. The corrosion-resistant high-aluminum glass beads according to claim 1, characterized in that: The first bead (101) and the third bead (103) have the same structure.
7. The corrosion-resistant high-aluminum glass beads according to claim 1, characterized in that: The second bead (102) is in the shape of a truncated cone with a concave center.
Citation Information
Patent Citations
Reflective glass bead for roads
CN211522956U