Fluorine preparation electrolyte preparation device

Abstract

The utility model belongs to the technical field of fluorine-making electrolyte, and particularly relates to a fluorine-making electrolyte preparation device which comprises a base, an electrolysis tank is arranged on the base, a feeding pipeline is arranged on the top wall of the electrolysis tank in a penetrating mode, gas outlet pipelines are arranged on the two sides of the feeding pipeline, and the gas outlet pipelines are arranged on the top wall of the electrolysis tank in a penetrating mode. An electrolysis assembly is arranged in the electrolysis box, the stirring assembly comprises a first motor, the first motor is fixedly arranged on the base, the first motor is in transmission connection with a stirring unit, and the stirring unit is arranged in the electrolysis box. The electrolysis assembly comprises an anode electrolysis rod, a cathode electrolysis rod and a partition plate, electrolyte enters the electrolysis box from the feeding pipeline, when appropriate electrolyte is added, the electrolyte is stirred through the stirring assembly, and electrolysis is conducted through the electrolysis assembly after stirring is completed. And the materials are fully stirred and mixed through the stirring assembly, and the electrolysis efficiency is improved.

Description

Technical Field

[0001] The utility model belongs to the technical field of fluorine electrolyte preparation, and particularly relates to a device for preparing fluorine electrolyte. Background Technique

[0002] The electrolytic fluorine production technology is one of the main methods for industrial production of fluorine gas. At present, the medium-temperature electrolytic fluorine production technology is widely used, and it uses nickel ions (Ni2+) as the active ions to eliminate the phenomena of anode polarization and cathode polarization.

[0003] Chinese Patent with publication number CN111962093A discloses an electrolytic fluorine production stirring device and method. An electrolytic fluorine production stirring device includes an electrolytic cell. The interior of the electrolytic cell includes an anode, a cathode, and a partition board. The partition board is located between the anode and the cathode. The electrolytic cell is divided into an anode area and a cathode area with the partition board as the dividing line. The characteristic is that an air inlet pipe is additionally arranged at the bottom of the electrolytic cell. One end of the air inlet pipe passes through the side wall of the electrolytic cell and is located in the cathode area, and the other end is connected to a high-pressure gas output device. This device uses high-pressure nitrogen gas to stir the electrolyte. The fluorine gas and hydrogen gas generated by electrolysis are mixed with nitrogen gas, which increases the subsequent process of removing nitrogen and reduces the overall production efficiency. Content of the Utility Model

[0004] The purpose of the utility model is to provide a device for preparing fluorine electrolyte for the above-mentioned existing technical problems, so as to fully stir the electrolyte and improve the electrolysis efficiency.

[0005] In view of this, the utility model provides a device for preparing fluorine electrolyte, including a base. An electrolytic box is arranged on the base. A feeding pipeline penetrates through the top wall of the electrolytic box. Air outlet pipelines are arranged on both sides of the feeding pipeline. The air outlet pipelines penetrate through the top wall of the electrolytic box. An electrolysis component is arranged inside the electrolytic box. It further includes: The stirring component includes a first motor. The first motor is fixedly arranged on the base. The first motor is transmission-connected with a stirring unit. The stirring unit is arranged inside the electrolytic box.

[0006] In this technical solution, the electrolysis component includes an anode electrolytic rod, a cathode electrolytic rod, and a partition board. The partition board is arranged between the anode electrolytic rod and the cathode electrolytic rod. The electrolyte enters the electrolytic box through the feeding pipeline. When appropriate electrolyte is added, the electrolyte is stirred by the stirring component. After stirring is completed, electrolysis is carried out by the electrolysis component. Since the electrolyte is composed of two or more chemical reagents, it is fully stirred and mixed by the stirring component to improve the electrolysis efficiency.

[0007] In the above technical solution, further, the stirring unit includes a first stirring paddle, the first stirring paddle is rotatably arranged below the partition plate, the first stirring paddle pushes the electrolyte to both sides, and two second stirring paddles are rotatably arranged on both sides of the first stirring paddle.

[0008] In the above technical solution, further, the stirring assembly further includes a first roller, a second roller and a third roller. The first roller passes through the inner wall of the electrolysis tank and is coaxially connected to the first stirring paddle. The second roller passes through the inner wall of the electrolysis tank and is coaxially connected to the second stirring paddle. The third roller is coaxially connected to the output end of the second motor. Belt pulleys are coaxially and fixedly arranged on the first roller, the second roller and the third roller, and transmission belts are connected between two adjacent and close belt pulleys.

[0009] In this technical solution, the first motor rotates to drive the belt pulley to rotate. Through the transmission of the transmission belt, all the belt pulleys rotate, and the belt pulley drives the first stirring paddle and the second stirring paddle to rotate. The first stirring paddle stirs the electrolyte under the partition plate and pushes it to both sides of the anode electrolysis rod and the cathode electrolysis rod. The second stirring paddle stirs the electrolyte pushed by the first stirring paddle, so as to fully stir the electrolyte in the tank.

[0010] In the above technical solution, further, a reflux structure is further included. The reflux structure is arranged in the air outlet pipe, and the reflux structure is connected with a condensation assembly, and the condensation assembly is arranged outside the electrolysis tank.

[0011] In the above technical solution, further, the reflux structure includes a fixing block, the fixing block is fixedly arranged on the inner wall of the ventilation pipe in a circumferential array, a condensation pipe reflux pipe is fixedly arranged on the fixing block, the bottom of the condensation reflux pipe extends into the electrolysis tank, and the condensation reflux pipe is hollow.

[0012] In the above technical solution, further, the condensation assembly includes a heat exchanger. The heat exchanger is fixedly arranged on the base. A refrigerant pipe and a heat medium pipe are connected to the top of the heat exchanger. The refrigerant pipe passes through the side wall of the ventilation pipe and is connected to the condensation reflux pipe, and the heat medium pipe passes through the side wall of the ventilation pipe and is connected to the condensation reflux pipe.

[0013] In this technical solution, a cooling medium is output from the heat exchanger to the refrigerant pipe, and the cooling medium flows into the condensation reflux pipe along the refrigerant pipe for heat exchange. After the heat exchange is completed, the cooling medium flows back into the heat exchanger along the heat medium pipe for cooling circulation. The heat exchanger is a well-known prior art and will not be described in detail. The cooling medium reduces the surface temperature of the condensation reflux pipe. When the electrolytically generated fluorine gas and hydrogen gas pass through the air outlet pipe, due to the low surface temperature of the condensation reflux pipe, the vaporized hydrogen fluoride mixed in the fluorine gas and hydrogen gas is cooled and liquefied and adheres to the surface of the condensation reflux pipe, and the liquefied hydrogen fluoride flows back into the electrolysis tank along the surface of the condensation reflux pipe.

[0014] In the above technical solution, further, the overall shape of the first stirring paddle is S-shaped.

[0015] In this technical solution, when the first stirring paddle rotates, the overall S-shaped setting of the first stirring paddle can better push the electrolyte to both sides.

[0016] The beneficial effects of the present utility model are as follows:

[0017] 1. By providing a stirring device, the electrolyte in the electrolysis tank can be fully stirred and mixed, improving the electrolysis efficiency.

[0018] 2. The stirring unit in the electrolysis tank includes a first stirring paddle and a second stirring paddle. The first stirring paddle is located below the partition plate, and the second stirring paddle is arranged on both sides of the first stirring paddle. The first stirring paddle stirs the electrolyte under the partition plate and pushes it to both sides of the anode electrolysis rod and the cathode electrolysis rod. The second stirring paddle stirs the electrolyte pushed by the first stirring paddle, thereby fully stirring the electrolyte in the tank.

[0019] 3. By providing a reflux structure and a condensation component, the cooling medium reduces the surface temperature of the condensation reflux pipe. When the electrolytically generated fluorine gas and hydrogen gas pass through the gas outlet pipe, due to the low surface temperature of the condensation reflux pipe, the vaporized hydrogen fluoride mixed in the fluorine gas and hydrogen gas is cooled and liquefied and adheres to the surface of the condensation reflux pipe. The liquefied hydrogen fluoride flows back into the electrolysis tank along the surface of the condensation reflux pipe. Description of the Drawings

[0020] Figure 1 is a schematic structural diagram of the present utility model;

[0021] Figure 2 is a partially sectional structural diagram;

[0022] Figure 3 is a sectional structural diagram;

[0023] Figure 4 is a schematic structural diagram of the stirring assembly;

[0024] Figure 5 is a schematic structural diagram of the condensation component;

[0025] Figure 6 is a sectional structural diagram of the reflux structure.

[0026] The markings in the figures are shown as:

[0027] 1. Electrolysis tank; 2. Base; 3. Exhaust pipe; 4. Feeding pipe; 5. Condensation component; 6. Stirring component; 7. Condensation return pipe; 8. Heat medium pipe; 9. Refrigerant pipe; 10. Fixed block; 12. Liquid exchanger; 13. Electrolysis component; 14. Anode electrolysis rod; 15. Cathode electrolysis rod; 16. Partition board; 17. First stirring paddle; 18. Second stirring paddle; 19. First motor; 20. Belt pulley; 21. Transmission belt; 22. First roller; 23. Second roller; 24. Third roller. Detailed implementation mode

[0028] The technical solutions in the embodiments of the present application will be clearly described below with reference to the accompanying drawings in the embodiments of the present application. Obviously, the described embodiments are only a part of the embodiments of the present application, rather than all the embodiments. Based on the embodiments in the present application, all other embodiments obtained by those of ordinary skill in the art belong to the scope of protection of the present application.

[0029] In the description of the present application, it should be noted that the terms used here are only for describing specific implementation modes, rather than intending to limit the exemplary implementation modes according to the present application. For the convenience of description, the dimensions of each part shown in the drawings are not drawn according to the actual proportional relationship. Technologies, methods, and devices known to those of ordinary skill in the relevant field may not be discussed in detail, but should be regarded as part of the authorization specification when appropriate. In all the examples shown and discussed here, any specific value should be interpreted as merely exemplary, rather than as a limitation. Therefore, other examples of the exemplary embodiments may have different values. It should be noted that similar reference numerals and letters indicate similar items in the following drawings. Therefore, once an item is defined in one drawing, it does not need to be further discussed in subsequent drawings.

[0030] It should be noted that the terms "first", "second", etc. in the description and claims of the present application are used to distinguish similar objects, rather than to describe a specific order or sequence. It should be understood that such data can be interchanged under appropriate circumstances so that the embodiments of the present application can be implemented in an order other than those illustrated or described here, and the objects distinguished by "first", "second", etc. are usually of the same category, and do not limit the number of objects. For example, the first object can be one or more. In addition, "and / or" in the description and claims means at least one of the connected objects, and the character " / " generally means an "or" relationship between the associated objects before and after.

[0031] It should be noted that in the description of the present application, the orientation or positional relationship indicated by the orientation terms such as "front, rear, upper, lower, left, right", "lateral, vertical, perpendicular, horizontal" and "top, bottom" is usually based on the orientation or positional relationship shown in the drawings. It is only for the convenience of describing the present application and simplifying the description. Without contrary explanation, these orientation terms do not indicate and imply that the device or element referred to must have a specific orientation or be constructed and operated in a specific orientation. Therefore, it should not be construed as a limitation on the protection scope of the present application; the orientation terms "inner, outer" refer to the inside and outside relative to the contour of each component itself.

[0032] It should be noted that in the present application, the term "comprising", "including" or any other variant thereof is intended to cover non-exclusive inclusion, so that a process, method, article or device comprising a series of elements includes not only those elements but also other elements not expressly listed, or elements inherent to such process, method, article or device. Without further limitation, an element defined by the statement "comprising one..." does not exclude the presence of additional identical elements in the process, method, article or device comprising that element. In addition, it should be pointed out that the scope of the methods and devices in the embodiments of the present application is not limited to performing functions in the order shown or discussed, and may also include performing functions in a substantially simultaneous manner or in the reverse order according to the functions involved. For example, the described method may be performed in a different order than described, and various steps may be added, omitted, or combined. Additionally, features described with reference to certain examples may be combined in other examples.

[0033] Embodiment 1:

[0034] In view of this, this embodiment provides a device for preparing fluorine electrolyte. As Figure 1 shown, it includes a base 2, an electrolysis tank 1 is arranged on the base 2, a feeding pipeline 4 penetrates through the top wall of the electrolysis tank 1, air outlet pipelines 3 are arranged on both sides of the feeding pipeline 4, the air outlet pipelines 3 penetrate through the top wall of the electrolysis tank 1, and an electrolysis assembly 13 is arranged inside the electrolysis tank 1. It further includes: a stirring assembly 6 includes a first motor 19, the first motor 19 is fixedly arranged on the base 2, the first motor 19 is transmission-connected with a stirring unit, and the stirring unit is arranged inside the electrolysis tank 1. The electrolysis assembly 13 includes an anode electrolysis rod 14, a cathode electrolysis rod 15 and a partition plate 16. The partition plate 16 is arranged between the anode electrolysis rod 14 and the cathode electrolysis rod 15. The electrolyte enters the electrolysis tank 1 from the feeding pipeline 4. When appropriate electrolyte is added, the electrolyte is stirred by the stirring assembly 6, and after the stirring is completed, electrolysis is carried out by the electrolysis assembly 13. Since the electrolyte is composed of two or more chemical reagents, it is fully stirred and mixed by the stirring assembly 6 to improve the electrolysis efficiency.

[0035] As Figure 4 shown, the stirring unit includes a first stirring paddle 17, the first stirring paddle 17 is rotatably arranged below the partition plate 16, the first stirring paddle 17 pushes the electrolyte to both sides, and two second stirring paddles 18 are rotatably arranged on both sides of the first stirring paddle 17. The stirring assembly 6 further includes a first roller 22, a second roller 23 and a third roller 24. The first roller 22 passes through the inner wall of the electrolysis tank 1 and is coaxially connected to the first stirring paddle 17. The second roller 23 passes through the inner wall of the electrolysis tank 1 and is coaxially connected to the second stirring paddle 18. The third roller 24 is coaxially connected to the output end of the second motor. Pulley 20 is coaxially and fixedly arranged on the first roller 22, the second roller 23 and the third roller 24, and a transmission belt 21 is connected between two adjacent and close pulleys 20. The rotation of the first motor 19 drives the pulley 20 to rotate. Through the transmission of the transmission belt 21, all the pulleys 20 rotate, and the pulley 20 drives the first stirring paddle 17 and the second stirring paddle to rotate. The first stirring paddle 17 stirs the electrolyte under the partition plate 16 and pushes it to both sides of the anode electrolysis rod 14 and the cathode electrolysis rod 15. The second stirring paddle 18 stirs the electrolyte pushed by the first stirring paddle 17, so as to fully stir the electrolyte in the tank.

[0036] Embodiment 2:

[0037] This embodiment provides a fluorine production electrolysis configuration device, which, in addition to including the technical solutions of the above embodiments, further has the following technical features.

[0038] As Figure 5 shown, it further includes a reflux structure, the reflux structure is arranged in the air outlet pipe, and the reflux structure is connected to a condensation assembly 5, and the condensation assembly 5 is arranged outside the electrolysis tank 1.

[0039] As Figure 6 shown, the reflux structure includes a fixing block 10, the fixing block 10 is fixedly arranged on the inner wall of the ventilation pipe in a circumferential array, a condensation pipe reflux pipe is fixedly arranged on the fixing block 10, the bottom of the condensation reflux pipe 7 extends into the electrolysis tank 1, and the condensation reflux pipe 7 is hollow.

[0040] As Figure 5 shown, the condensation assembly 5 includes a heat exchanger 12, the heat exchanger 12 is fixedly arranged on the base 2, the top of the heat exchanger 12 is connected with a refrigerant pipe 9 and a heat medium pipe 8, the refrigerant pipe 9 passes through the side wall of the ventilation pipe and is connected to the condensation reflux pipe 7, and the heat medium pipe 8 passes through the side wall of the ventilation pipe and is connected to the condensation reflux pipe 7.

[0041] The cooling medium is output from the liquid changer 12 to the refrigerant pipe 9. The cooling medium enters the inside of the condensation return pipe 7 along the refrigerant pipe 9 for temperature exchange. After the temperature exchange is completed, the cooling medium returns to the liquid changer 12 along the heat medium pipe 8 for cooling circulation. The cooling medium reduces the surface temperature of the condensation return pipe 7. When the fluorine gas and hydrogen gas generated by electrolysis pass through the gas outlet pipe 3, due to the low surface temperature of the condensation return pipe 7, the vaporized hydrogen fluoride mixed in the fluorine gas and hydrogen gas is cooled and liquefied and adheres to the surface of the condensation return pipe 7. The liquefied hydrogen fluoride flows back into the electrolysis tank 1 along the surface of the condensation return pipe 7.

[0042] The overall shape of the first stirring paddle 17 is S-shaped. When the first stirring paddle 17 rotates, the overall S-shaped setting of the first stirring paddle 17 can better push the electrolyte to both sides.

[0043] The embodiments of the present application have been described above in conjunction with the accompanying drawings. Without conflict, the embodiments and features in the embodiments of the present application can be combined with each other. The present application is not limited to the above specific embodiments. The above specific embodiments are merely illustrative and not restrictive. Under the inspiration of the present application, those of ordinary skill in the art can also make many forms without departing from the purpose of the present application and the scope protected by the claims, and all of them fall within the protection scope of the present application.

Claims

1. An apparatus for preparing a fluorine electrolyte, comprising a base (2), an electrolysis tank (1) is provided on the base (2), a feed pipe (4) penetrates through the top wall of the electrolysis tank (1), air outlet pipes (3) are provided on both sides of the feed pipe (4), the air outlet pipes (3) penetrate through the top wall of the electrolysis tank (1), and an electrolysis assembly (13) is arranged inside the electrolysis tank (1), characterized in that , also includes: The stirring assembly (6) comprises a first motor (19), wherein the first motor (19) is fixedly arranged on the base (2), and the first motor (19) is transmission-connected to a stirring unit, and the stirring unit is arranged in the electrolytic box (1).

2. The fluorine electrolyte preparation device according to claim 1, wherein The stirring unit comprises a first stirring paddle (17), the first stirring paddle (17) is rotatably arranged below the partition plate (16), two second stirring paddles (18) are rotatably arranged on both sides of the first stirring paddle (17), and the first stirring paddle (17) pushes the electrolyte to both sides.

3. The fluorine-based electrolyte preparation device according to claim 1, wherein The stirring assembly (6) further comprises a first roller (22), a second roller (23) and a third roller (24); the first roller (22) passes through the inner wall of the electrolytic box (1) and is coaxially connected to the first stirring paddle (17); the second roller (23) passes through the inner wall of the electrolytic box (1) and is coaxially connected to the second stirring paddle (18); the third roller (24) is coaxially connected to the output end of the second motor; the first roller (22), the second roller (23) and the third roller (24) are all coaxially fixed with pulleys (20); and a transmission belt (21) is connected between two adjacent pulleys (20).

4. A device for preparing a fluorine electrolyte according to claim 1, characterized in that It also comprises a reflux structure, which is arranged in the gas outlet pipe (3), and the reflux structure is connected to a condensation component (5), and the condensation component (5) is arranged outside the electrolysis box (1).

5. A fluorine electrolyte preparation device according to claim 4, characterized in that, The reflux structure comprises a fixed block (10), wherein the fixed blocks (10) are fixedly arranged in a circumferential array on the inner wall of the ventilation duct, and a condensation reflux pipe (7) is fixedly arranged on the fixed block (10), wherein the bottom of the condensation reflux pipe (7) extends into the interior of the electrolytic box (1), and the condensation reflux pipe (7) is a hollow structure.

6. The fluorine-based electrolyte preparation device according to claim 5, wherein The condensing assembly (5) includes a fluid changer (12), which is fixedly mounted on a base (2). A refrigerant pipe (9) and a heat medium pipe (8) are connected to the top of the fluid changer (12). The refrigerant pipe (9) passes through the side wall of the ventilation duct to connect to the condensation return pipe (7), and the heat medium pipe (8) passes through the side wall of the ventilation duct to connect to the condensation return pipe (7).

7. The fluorine-based electrolyte preparation device according to claim 6, characterized in that, The overall shape of the first stirring paddle (17) is S-shaped.

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