Carbon-titanium-based wave-absorbing rubber patch
The carbon-titanium based microwave absorbing rubber patch with a multi-layer structure design solves the problems of customization and insufficient performance of existing microwave absorbing materials, realizes flexible application and a variety of excellent properties, is suitable for engineering and daily life, and is environmentally friendly and economical.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2025-04-07
- Publication Date
- 2026-03-27
AI Technical Summary
Existing microwave absorbing materials are expensive and require customized design, which limits their application in the general public. They also lack a variety of excellent properties such as high absorption rate over a wide frequency band, lightweight, high temperature resistance, moisture resistance, and corrosion resistance.
A carbon-titanium based microwave absorbing rubber patch was designed, which adopts a multi-layer structure, including a microwave absorbing rubber layer, a temperature-resistant and corrosion-resistant film layer, and a self-cleaning film layer. It is prepared by electrospinning and magnetron sputtering technology. The material can be flexibly cut and shaped, and has the properties of microwave absorption, temperature resistance, corrosion resistance and self-cleaning.
It enables flexible application of materials, reduces usage costs, improves equipment stability and safety, possesses a variety of excellent properties, is suitable for engineering applications and daily life, and is both environmentally friendly and economical.
Smart Images
Figure CN224054668U_ABST
Abstract
Description
TECHNICAL FIELD
[0001] The utility model belongs to wave -absorbing material technical field, specifically relates to a carbon titanium base wave -absorbing rubber patch. BACKGROUND
[0002] With the rapid development of electronic technology, mobile communication, computer and household appliance and other electronic products are increasingly popular, and people's living environment is suffering from increasingly serious electromagnetic pollution. At the same time, the increasing number of high-rise buildings in the city further deteriorates the electronic environment. Reducing electromagnetic interference has become the focus of global electronic industry. As a kind of material that can convert electromagnetic wave into other forms of energy, wave -absorbing material can effectively control its propagation, reduce reflection and suppress interference, thereby playing an important role in electromagnetic wave management.
[0003] However, the application of wave -absorbing material at present mainly concentrates in high -end field, and the popular field is less applied. The reason is that the existing wave -absorbing material is mostly expensive, and is usually customized design for specific application, and presents the characteristics of 'one thing one use one design'. This not only consumes a lot of manpower and material resources, but also limits its application in wider field. In engineering application, in addition to requiring wave -absorbing material to have high absorption rate to electromagnetic wave in a wide frequency band, it also requires it to have light weight, high temperature resistance, moisture resistance, corrosion resistance and other excellent properties. INVENTION CONTENTS
[0004] In order to overcome the defects existing in the prior art, the utility model provides a rubber patch that is not limited to shape and application range, and can be cut according to requirements, which aims to reduce the harm of electromagnetic radiation to equipment and human body, improve system performance, eliminate redundant electric wave in intelligent electronic system, protect privacy, security and confidentiality, eliminate electromagnetic interference, improve the stability and safety of equipment, and can be freely cut according to the actual application scene requirements, not limited by the size of the application object, so as to realize flexible application of materials. In addition, the material can be recycled after use, which not only meets the environmental protection concept, but also reduces the use cost. More importantly, it has wave -absorbing, light weight, high temperature resistance, moisture resistance, corrosion resistance, self -cleaning and other excellent properties, which can meet the strict requirements of wave -absorbing material in engineering application, daily life and other fields, and play the role of controlling electromagnetic wave propagation, reducing reflection and suppressing interference.
[0005] In order to achieve the above-mentioned purpose of the application, the utility model provides a kind of carbon titanium base wave-absorbing rubber paste, which is composed of first structure layer, second structure layer, third structure layer, fourth structure layer and fifth structure layer;The first structure layer is the middle layer, and the upper and lower sides thereof are the second structure layer and the third structure layer respectively, the side of the second structure layer away from the first structure layer is the fourth structure layer, and the side of the third structure layer away from the first structure layer is the fifth structure layer;The upper and lower surfaces of the first structure layer are tightly connected with the second structure layer and the third structure layer respectively, the other side of the second structure layer is tightly connected with the fourth structure layer, and the other side of the third structure layer is tightly connected with the fifth structure layer;The first structure layer is a wave-absorbing rubber layer, the second structure layer and the third structure layer are temperature-resistant and corrosion-resistant layers, and the fourth structure layer and the fifth structure layer are hydrophobic and oleophobic self-cleaning coatings.
[0006] The first structure layer is a Ti3C2T X nanometer wave-absorbing sheet (Ti3C2T X , which is a kind of MXene material). The second structure layer and the third structure layer are polyurethane films containing hydrated titanium dioxide, i.e. mixed films of hydrated titanium dioxide and polyurethane; wherein the polyurethane is a solvent, and the titanium dioxide plays a functional role.
[0007] By adopting the above-mentioned structure design scheme of carbon titanium base wave-absorbing rubber paste, the wave-absorbing layer, temperature-resistant and corrosion-resistant film layer and self-cleaning film layer are arranged in sequence from the center to the outside in a central symmetric manner. As the name implies, the wave-absorbing rubber layer is the main material, which has the performance of wave-absorbing and anti-electromagnetic interference, and is in the form of rubber; the temperature-resistant and corrosion-resistant film layer (temperature-resistant and corrosion-resistant layer) can withstand a certain degree of high temperature and has corrosion resistance; the self-cleaning film layer (hydrophobic and oleophobic self-cleaning coating) has a certain self-cleaning effect, can make water on its surface slide quickly, and has a certain moisture resistance.
[0008] In the above technical solution, further, the first structure layer is prepared by electrospinning technology. The layers are connected by chemical reaction, which can ensure the density of the connection between the layers. The wave-absorbing rubber layer of the first structure layer is mainly to disperse the titanium carbide (Ti3C2T X nanometer wave-absorbing sheet (which can be self-made or purchased) in the rubber formula agent (select black rubber raw material), uniformly dispersed, and form rubber sheet and rubber block by electrospinning technology or other rubber sheet forming technology. The thickness of this structure layer is prepared according to demand and is not limited.
[0009] Further, the second structure layer and the third structure layer are respectively arranged on the surface of the first structure layer by magnetron sputtering technology. The second structure layer and the third structure layer are temperature-resistant and corrosion-resistant film layers. A titanium dioxide hydrate solution is dispersed in polyurethane varnish, and the second structure layer and the third structure layer are formed on the surface of the first structure layer by magnetron sputtering technology. After the second structure layer and the third structure layer are solidified, the fourth structure layer and the fifth structure layer are prepared.
[0010] Further, the fourth structure layer is arranged on the surface of the second structure layer away from the first structure layer by magnetron sputtering or coating technology; and the fifth structure layer is arranged on the surface of the third structure layer away from the first structure layer by magnetron sputtering or coating technology. The fourth structure layer and the fifth structure layer are self-cleaning film layers, which are mainly hydrophobic and oleophobic self-cleaning transparent coatings. Raw materials can be directly purchased from the market. The self-cleaning coating is formed on the surface of the second structure layer and the third structure layer by magnetron sputtering or coating technology to form a transparent network hydrophobic and oleophobic layer.
[0011] The above-mentioned carbon-titanium-based wave-absorbing rubber patch is prepared and applied as follows: Figure 1 As shown in the accompanying drawings, the carbon-titanium-based wave-absorbing rubber patch includes a first structure layer, a second structure layer, a third structure layer, a fourth structure layer, and a fifth structure layer 5. The drawings are only schematic and do not represent the shape and thickness of the structure layers.
[0012] The first structure layer is a wave-absorbing rubber, which is mainly prepared by uniformly dispersing titanium carbide (Ti3C2T X ) nano wave-absorbing sheets (which can be self-prepared or purchased) in a rubber formula agent (black rubber raw materials are selected), and then forming a rubber sheet or a rubber block by electrospinning technology or other rubber sheet forming technology. The thickness of the structure layer is not limited and can be prepared according to requirements.
[0013] The second structure layer and the third structure layer are temperature-resistant and corrosion-resistant film layers. A titanium dioxide hydrate solution with a concentration of 0.5-2 mol / L is dispersed in polyurethane varnish with a mass fraction of 20%-40%, and then the second structure layer and the third structure layer are respectively formed on the upper and lower surfaces of the first structure layer by magnetron sputtering technology. The thickness of the second structure layer and the third structure layer is 100-500 μm. After the second structure layer and the third structure layer are dried, the next structure layer is constructed.
[0014] The fourth structure layer and the fifth structure layer are self-cleaning film layers, which are mainly hydrophobic and oleophobic self-cleaning transparent coatings. Raw materials can be directly purchased from the market. The self-cleaning coating is formed on the surface of the second structure layer and the third structure layer by magnetron sputtering or coating technology to form a transparent network hydrophobic and oleophobic layer. The thickness of the fourth structure layer and the fifth structure layer is 50-200 μm.
[0015] The carbon titanium-based wave-absorbing rubber patch is made, and when applied, a suitable colloid is selected to adhere the rubber patch to a device or equipment that needs to be applied; the rubber patch can be cut and trimmed according to the needs of the application scene to facilitate adhesion and use.
[0016] Compared with the prior art, the utility model has the beneficial effects that:
[0017] The carbon titanium-based wave-absorbing rubber patch has a unique multi-layer structure design, which perfectly combines the high performance of the wave-absorbing material and the plasticity of the rubber. The first structure layer deeply integrates the characteristics of the wave-absorbing material and the rubber, which not only facilitates the user to cut according to the actual use demand, but also effectively reduces or even avoids the interference of electromagnetic waves. The second structure layer and the third structure layer significantly improve the temperature resistance and corrosion resistance of the material, so that it can maintain stable performance in complex environments. The fourth structure layer and the fifth structure layer endow the material with self-cleaning ability, which can effectively prevent water and dirt, further enhance the practicality and durability of the material, and also have many excellent properties such as wave-absorbing, light weight, temperature resistance, humidity resistance, corrosion resistance, etc.
[0018] The carbon titanium-based wave-absorbing rubber patch not only has the ability to resist electromagnetic wave interference, but also has many properties such as temperature resistance, corrosion resistance, and self-cleaning. The flexibility and plasticity of the rubber greatly expand the application scene, and can meet the use demand of different users in diversified environments. It can be cut and trimmed at any time according to different application scenes, and can be taken down and reused after use, which greatly reduces the use cost and improves the economy and environmental protection of the material, providing an efficient, economical and environmentally friendly solution for electromagnetic wave management. BRIEF DESCRIPTION OF DRAWINGS
[0019] Figure 1 The utility model relates to a carbon titanium-based wave-absorbing rubber patch structure sectional view;
[0020] In the drawing: 1-first structure layer;2-second structure layer;3-third structure layer;4-fourth structure layer;5-fifth structure layer;11-carbon titanium (Ti3C2T X ) nanometer wave-absorbing sheet. DETAILED DESCRIPTION
[0021] In order to make the purpose, technical scheme and advantages of the utility model more clear and obvious, the utility model will be further described in detail below combined with specific embodiments. It should be understood that the specific embodiments described here are only used to explain the utility model, and are not used to limit the utility model.
[0022] The present application is described in the specification of the utility model with reference to the embodiments disclosed herein; however, it should be understood that the embodiments disclosed herein are merely examples of the present application that can be implemented in various, alternative forms. In the following description, a plurality of operating parameters and components are described in the embodiments conceived. These specific parameters and components are merely examples in the specification and do not mean limitation.
[0023] In the description of the utility model, it should be understood that the orientation or positional relationship indicated by the terms "center", "longitudinal", "transverse", "upper", "lower", "front", "rear", "left", "right", "vertical", "horizontal", "top", "bottom", "inner", "outer" and the like is based on the orientation or positional relationship shown in the drawings, and is only for the convenience of describing the utility model and simplifying the description, and does not mean or imply that the devices or elements indicated must have a particular orientation, be constructed and operated in a particular orientation, and therefore cannot be understood as a limitation on the utility model. In addition, the terms "first", "second" and the like are only for descriptive purposes and cannot be understood as indicating or implying relative importance or implicitly indicating the number of the technical features indicated. Therefore, the features limited by "first", "second" and the like can explicitly or implicitly include one or more features. In the description of the utility model, unless otherwise stated, the meaning of "a plurality of" is two or more.
[0024] Embodiments
[0025] The utility model discloses a kind of carbon titanium base wave-absorbing rubber stickers, section view as Figure 1 It is composed of first structure layer 1, second structure layer 2, third structure layer 3, fourth structure layer 4 and fifth structure layer 5;First structure layer 1 is middle layer, and its upper and lower two sides are second structure layer 2 and third structure layer 3 respectively, the side of second structure layer 2 away from first structure layer 1 is fourth structure layer 4, and the side of third structure layer 3 away from first structure layer 1 is fifth structure layer 5;First structure layer 1 is wave-absorbing rubber layer, second structure layer 2 and third structure layer 3 are temperature-resistant corrosion-resistant layer, fourth structure layer 4 and fifth structure layer 5 are hydrophobic oil-repellent self-cleaning layer.
[0026] Specifically, by using the above structure design scheme, in a central symmetric manner, wave-absorbing rubber layer, temperature-resistant corrosion-resistant layer and hydrophobic oil-repellent self-cleaning layer are sequentially arranged from the center to the outside. Among them, the wave-absorbing rubber layer has the performance of absorbing wave and resisting electromagnetic interference, and is in the form of rubber;Temperature-resistant corrosion-resistant layer can resist high temperature to a certain extent and has corrosion resistance;Hydrophobic oil-repellent self-cleaning layer has a certain self-cleaning effect, can make water on the surface quickly slide off, and has a certain moisture resistance.
[0027] In a specific embodiment, Figure 1The shape and thickness of the carbon-titanium-based wave-absorbing rubber patch are not limited to this.
[0028] In an embodiment, the first structure layer 1 is Ti3C2T X The wave-absorbing rubber layer of the nanosheet 11.
[0029] In an embodiment, the first structure layer 1 is prepared by electrospinning technology.
[0030] Specifically, the purchased Ti3C2T X The nanosheet 11 is dispersed in black rubber raw materials to form a rubber sheet or a rubber block by electrospinning technology or other molding technology.
[0031] In an embodiment, the second structure layer 2 and the third structure layer 3 are respectively arranged on the surface of the first structure layer 1 by magnetron sputtering.
[0032] In an embodiment, the temperature-resistant and corrosion-resistant layer is a polyurethane film.
[0033] In an embodiment, a 0.5-2 mol / L concentration of hydrated titanium dioxide solution is dispersed in a polyurethane varnish, and the mass fraction of titanium dioxide is 20%-40%, and then the second structure layer 2 and the third structure layer 3 are respectively formed on the surface of the first structure layer 1 by magnetron sputtering technology.
[0034] In an embodiment, the thickness of the second structure layer 2 and the third structure layer 3 is 100-500 μm.
[0035] In an embodiment, the fourth structure layer 4 is arranged on the surface of the second structure layer 2 away from the first structure layer 1 by magnetron sputtering or coating technology; and the fifth structure layer 5 is arranged on the surface of the third structure layer 3 away from the first structure layer 1 by magnetron sputtering or coating technology.
[0036] In an embodiment, the thickness of the fourth structure layer 4 and the fifth structure layer 5 is 50-200 μm.
[0037] Specifically, the fourth structure layer 4 and the fifth structure layer 5 are mainly hydrophobic and oleophobic self-cleaning transparent coatings, and the raw materials can be directly purchased from the market. The self-cleaning coating is arranged on the surface of the second structure layer 2 and the third structure layer 3 by magnetron sputtering or coating technology to form a transparent network hydrophobic and oleophobic layer.
[0038] In an embodiment, a suitable colloid can be selected to adhere the carbon-titanium-based wave-absorbing rubber patch to the device to be applied.
[0039] Specifically, the rubber patch can be adjusted in shape and size according to the use scene, and is directly cut and pasted, so that the operation is convenient and fast. For example, in order to reduce the harm of electromagnetic radiation to equipment and human body, the rubber patch can be pasted on the outer surface or inner wall of the equipment; in order to improve the system performance, the rubber patch can be pasted in the internal of the electronic system; in order to protect privacy and security, the rubber patch can be pasted on the inner wall or outer wall of the security box; in the electromagnetic compatibility technology research, the rubber patch can be pasted on the part where electromagnetic interference needs to be eliminated, and the application scene is wide, and various demands can be met.
[0040] The above is the example embodiment disclosed by the utility model, and the sequence of the above utility model embodiment disclosed is only for description, not representing the advantages and disadvantages of the embodiment. However, it should be noted that the discussion of the above any embodiment is only exemplary, and is not intended to imply that the scope (including claims) of the utility model embodiment disclosed is limited to these examples, and various changes and modifications can be made without departing from the scope defined by the claims. The functions, steps and / or actions of the method claims of the disclosed embodiments described herein need not be performed in any particular order. In addition, although the elements of the utility model embodiments disclosed can be described or claimed in individual form, they can also be understood as plural unless explicitly limited to singular.
[0041] Those skilled in the art should understand that the discussion of any embodiment above is only exemplary, and is not intended to imply that the scope (including claims) of the utility model embodiments disclosed is limited to these examples; under the idea of the utility model embodiments, the technical features in the above embodiments or different embodiments can also be combined, and there are many other changes of different aspects of the utility model embodiments as described above, and they are not provided in details for simplicity. Therefore, any omission, modification, equivalent replacement, improvement, etc. made within the spirit and principles of the utility model embodiments should be included in the protection scope of the utility model embodiments.
Claims
1. A carbon titanium-based wave-absorbing rubber patch, characterized in that, The carbon titanium-based wave-absorbing rubber patch is composed of a first structural layer (1), a second structural layer (2), a third structural layer (3), a fourth structural layer (4) and a fifth structural layer (5); The first structural layer (1) is a middle layer, and the upper and lower sides thereof are the second structural layer (2) and the third structural layer (3) respectively, the side of the second structural layer (2) away from the first structural layer (1) is the fourth structural layer (4), and the side of the third structural layer (3) away from the first structural layer (1) is the fifth structural layer (5); The first structural layer (1) is a wave-absorbing rubber layer, the second structural layer (2) and the third structural layer (3) are temperature-resistant and corrosion-resistant layers, and the fourth structural layer (4) and the fifth structural layer (5) are hydrophobic and oleophobic self-cleaning coating layers. The first structural layer (1) is a Ti3C2T X The wave-absorbing rubber layer of the nano wave-absorbing sheet; the second structural layer (2) and the third structural layer (3) are polyurethane films containing hydrated titanium dioxide.
2. The carbon titanium-based wave-absorbing rubber patch of claim 1, wherein, The first structural layer (1) is prepared by electrospinning technology. 3.The carbon titanium-based wave-absorbing rubber patch of claim 1, wherein, The second structural layer (2) and the third structural layer (3) are respectively arranged on the surface of the first structural layer (1) by magnetron sputtering.
4. The carbon titanium-based wave-absorbing rubber patch of claim 1, wherein, The fourth structural layer (4) is arranged on the surface of the second structural layer (2) away from the first structural layer (1) by magnetron sputtering or coating, and the fifth structural layer (5) is arranged on the surface of the third structural layer (3) away from the first structural layer (1) by magnetron sputtering or coating.
5. The carbon titanium-based wave-absorbing rubber patch of claim 1, wherein, The thicknesses of the second structural layer (2) and the third structural layer (3) are 100-500 μm respectively, and the thicknesses of the fourth structural layer (4) and the fifth structural layer (5) are 50-200 μm respectively.