Separation, enrichment and extraction device for antibiotics in water body

Abstract

The utility model discloses a device for separating, enriching and extracting antibiotics in water, and relates to the technical field of antibiotic extraction.The device comprises a PH value adjusting device, a filtering device, an extracting device, an evaporating device and a cooling device.According to the device, the PH value adjusting device and the filtering device are arranged, so that the stability of the PH value in the water before the antibiotics are extracted is guaranteed; impurities possibly affecting the extraction efficiency in the water body are filtered out, the extraction effect is further guaranteed, the extraction efficiency is improved, the extracted antibiotics are purified and enriched through the evaporation device, the next step of antibiotic detection is facilitated, the cooling device is arranged, the solvent is recycled, direct emission of the gasified solvent is avoided, the environment is protected, and resources are saved. Finally, the PH value adjusting device, the filtering device, the extraction device, the evaporation device and the cooling device are connected through a first pipeline, a second pipeline, a third pipeline and a fourth pipeline, the operation process is simplified, and the extraction operation time is saved.

Description

Technical Field

[0001] This utility model relates to the field of antibiotic extraction technology, specifically to a device for separating, enriching, and extracting antibiotics in water. Background Technology

[0002] Since their discovery in the 20th century, antibiotics have been widely used in animal disease prevention and control, animal husbandry and aquaculture, and human medicine. Because antibiotics degrade slowly, they remain in the environment for a long time. Through the food chain, they accumulate in plants, animals, and humans, reaching high concentrations. This long-term accumulation in plants, animals, and humans poses a great threat to human health. Therefore, it is necessary to extract and test antibiotics in water bodies.

[0003] In existing technologies, extraction technology utilizes the principle of solubility difference between two immiscible solvents to transfer the solute from one solvent to another, thereby achieving purification. For example, CN216785770U is an extraction device for separating and enriching antibiotics in aquaculture water. It includes a workbench and an extraction chamber. The extraction chamber is fixedly connected to the top outer wall of the workbench, and support legs are fixedly connected to the four corners of the bottom outer wall of the workbench. A rotating motor is fixedly connected to the bottom outer wall of the workbench via a first motor frame. The output end of the rotating motor is fixedly connected to the bottom outer wall of the rotating shaft via a coupling. The temperature inside the extraction chamber is kept stable through a set air valve pipe, a heating motor, and a cooling motor, which is conducive to extraction. However, different water bodies have different pH values, and impurities in the water may affect the extraction efficiency. Furthermore, the extracted antibiotics and solvents need to be separated. This technology cannot solve all the technical problems. Summary of the Invention

[0004] The purpose of this invention is to provide a device for separating, enriching, and extracting antibiotics in water, so as to solve the problems mentioned in the background art.

[0005] To achieve the above objectives, this utility model provides the following technical solution: a device for separating, enriching, and extracting antibiotics in water, comprising: a pH adjustment device on the left side, a first pipe connected to the lower right side of the pH adjustment device, a filter device connected to the other end of the first pipe, a second pipe connected to the lower right side of the filter device, an extraction device connected to the other end of the second pipe, a third pipe on the right side of the extraction device, an evaporation device at the other end of the third pipe, a fourth pipe connected to the top right side of the evaporation device, and a condensation device at the other end of the fourth pipe.

[0006] Furthermore, the pH adjustment device includes: a pH adjustment tank, an acid tank and an alkali tank arranged side by side on the left side of the pH adjustment tank, the acid tank being connected to the pH adjustment tank via an acid pipe and a metering pump, the alkali tank being connected to the pH adjustment tank via an alkali pipe and a metering pump, a water inlet on the top left side of the pH adjustment tank, a first rotary motor at the top center, the output end of the first rotary motor being connected to a first stirring rod, the other end of the first stirring rod penetrating the pH adjustment tank and fixed to the bottom of the pH adjustment tank via a first bearing seat, and a pH detection probe on the top right side of the pH adjustment tank, the pH detection probe being controlled and connected to the metering pump.

[0007] Furthermore, the filtration device includes, from top to bottom, a pebble layer, a ceramic pellet layer, and a quartz sand layer.

[0008] Furthermore, the extraction device includes: an extraction main tank, a nitrogen inlet on the top left side of the extraction main tank, a second rotary motor at the top center, a second stirring rod connected to the output end of the second rotary motor, the other end of the second stirring rod passing through the extraction main tank and fixed to the bottom of the extraction main tank by a second bearing seat, an extraction liquid tank on the top right side of the extraction main tank, a temperature regulating device in the middle of the right side of the extraction main tank, and a drain outlet at the bottom.

[0009] Furthermore, the temperature regulating device includes: a temperature sensor, a heater, and a cooler.

[0010] Furthermore, the evaporation device includes, from top to bottom, a gas-liquid separation chamber, an evaporation chamber, and a liquid settling chamber. The top of the gas-liquid separation chamber has a gas outlet connected to a condensation device via a fourth pipe. The evaporation chamber has a heat exchange tube and a liquid settling tube inside, and a heat medium inlet and a heat medium outlet on the outside. The heat exchange tube and the liquid settling tube pass through the evaporation chamber, with one end extending into the gas-liquid separation chamber and the other end connected to the liquid settling chamber. The liquid settling chamber has an antibiotic outlet on the left side.

[0011] Furthermore, the condensation device includes a condensation chamber and a liquid collection chamber. The condensation chamber is equipped with a condensation pipe inside and a coolant inlet and a coolant outlet on the outside. One end of the condensation pipe is connected to a fourth pipe, and the other end extends into the liquid collection chamber. The bottom of the liquid collection chamber is equipped with a solvent outlet.

[0012] Compared with the prior art, the beneficial effects of this utility model are as follows: By setting up a pH adjustment device and a filtration device, this utility model ensures the stability of the pH value in the water before antibiotic extraction and filters out impurities in the water that may affect the extraction efficiency, further ensuring the extraction effect and improving the extraction efficiency. By setting up an evaporation device, the extracted antibiotics are purified and enriched, which facilitates the next step of antibiotic detection. By setting up a cooling device, the solvent is recovered, avoiding the direct discharge of vaporized solvent, protecting the environment and saving resources. Finally, the pH adjustment device, filtration device, extraction device, evaporation device and cooling device are connected through the first, second, third and fourth pipes, simplifying the operation process and saving extraction operation time. Attached Figure Description

[0013] Figure 1 This is the front view of the present utility model;

[0014] Figure 2 This is a schematic diagram of the pH adjustment device of this utility model;

[0015] Figure 3 This is a top view of the pH adjustment device of this utility model;

[0016] Figure 4 This is a schematic diagram of the filter device of this utility model;

[0017] Figure 5 This is a schematic diagram of the extraction device of this utility model;

[0018] Figure 6 This is a schematic diagram of the temperature regulating device of this utility model;

[0019] Figure 7 This is a schematic diagram of the evaporation device of this utility model;

[0020] Figure 8 This is a schematic diagram of the condensation device of this utility model;

[0021] In the diagram: 1. pH adjustment device; 2. First pipe; 3. Filtration device; 4. Second pipe; 5. Extraction device; 6. Third pipe; 7. Evaporation device; 8. Fourth pipe; 9. Condensation device; 101. pH adjustment tank; 102. Acid tank; 103. Alkali tank; 104. Water inlet; 105. First rotary motor; 106. First stirring rod; 107. First bearing seat; 108. pH detection probe; 301. Pebble layer; 302. Ceramsite layer; 303. Quartz sand layer; 501. Main extraction tank; 502. Nitrogen inlet; 503. Second rotary motor; 504. Second stirring rod. 505. Second bearing housing; 506. Extraction liquid tank; 507. Temperature control device; 508. Drain outlet; 509. Temperature sensor; 510. Heater; 511. Refrigerator; 701. Gas-liquid separation chamber; 702. Evaporation chamber; 703. Liquid settling chamber; 704. Gas outlet; 705. Heat exchange tube; 706. Liquid settling tube; 707. Heat medium inlet; 708. Heat medium outlet; 709. Antibiotic outlet; 901. Condensation chamber; 902. Liquid collection chamber; 903. Condensation tube; 904. Coolant inlet; 905. Coolant outlet; 906. Solvent outlet. Detailed Implementation

[0022] To enable those skilled in the art to better understand the technical solutions of this utility model, the technical solutions in the embodiments of this utility model will be clearly and completely described below with reference to the accompanying drawings and specific embodiments.

[0023] Please refer to Figure 1-8 This utility model provides a device for separating, enriching, and extracting antibiotics in water, comprising: a pH adjustment device 1 on the left side, a first pipe 2 connected to the lower right side of the pH adjustment device 1, a filter device 3 connected to the other end of the first pipe 2, a second pipe 4 connected to the lower right side of the filter device 3, an extraction device 5 connected to the other end of the second pipe 4, a third pipe 6 on the right side of the extraction device 5, an evaporation device 7 on the other end of the third pipe 6, a fourth pipe 8 connected to the top right side of the evaporation device 7, and a condensation device 9 connected to the other end of the fourth pipe 8.

[0024] The pH adjustment device 1 includes: a pH adjustment tank 101, an acid tank 102 and an alkali tank 103 arranged side by side on the left side of the pH adjustment tank 101, the acid tank 102 being connected to the pH adjustment tank 101 via an acid pipe and a metering pump, and the alkali tank 103 being connected to the pH adjustment tank 101 via an alkali pipe and a metering pump, a water inlet 104 being provided on the top left side of the pH adjustment tank 101, a first rotary motor 105 being provided at the top center, the output end of the first rotary motor 105 being connected to a first stirring rod 106, the other end of the first stirring rod 106 penetrating the pH adjustment tank 101 and being fixed to the bottom of the pH adjustment tank 101 via a first bearing seat 107, and a pH detection probe 108 being provided on the top right side of the pH adjustment tank 101, the pH detection probe 108 being controlled and connected to the metering pump.

[0025] The filter device 3 includes, from top to bottom, a pebble layer 301, a ceramic granule layer 302, and a quartz sand layer 303.

[0026] The extraction device 5 includes: an extraction main tank 501, a nitrogen inlet 502 on the top left side of the extraction main tank 501, a second rotary motor 503 in the middle of the top, an output end of the second rotary motor 503 connected to a second stirring rod 504, the other end of the second stirring rod 504 passing through the extraction main tank 501 and fixed to the bottom of the extraction main tank 501 by a second bearing seat 505, an extraction liquid tank 506 on the top right side of the extraction main tank 501, a temperature regulating device 507 in the middle of the right side of the extraction main tank 501, and a drain outlet 508 at the bottom.

[0027] The temperature regulating device 507 includes a temperature sensor 509, a heater 510, and a cooler 511.

[0028] The evaporation device 7 includes, from top to bottom, a gas-liquid separation chamber 701, an evaporation chamber 702, and a liquid settling chamber 703. The top of the gas-liquid separation chamber 701 has a gas outlet 704 connected to a condensation device 9 via a fourth pipe 8. The evaporation chamber 702 has a heat exchange tube 705 and a liquid settling tube 706 inside, and a heat medium inlet 707 and a heat medium outlet 708 on the outside. The heat exchange tube 705 and the liquid settling tube 706 pass through the evaporation chamber 702, with one end extending into the gas-liquid separation chamber 701 and the other end connected to the liquid settling chamber 703. The left side of the liquid settling chamber 703 has an antibiotic outlet 709.

[0029] The condensation device 9 includes a condensation chamber 901 and a liquid collection chamber 902. The condensation chamber 901 is provided with a condensation pipe 903 inside and a coolant inlet 904 and a coolant outlet 905 on the outside. One end of the condensation pipe 903 is connected to the fourth pipe 8, and the other end extends into the liquid collection chamber 902. The bottom of the liquid collection chamber 902 is provided with a solvent outlet 906.

[0030] When using this invention, the water from which antibiotics are to be extracted is added to the pH adjusting device 1 through the water inlet 104. The pH value of the water is detected by the pH detection probe 108 to see if it is within the set range. If it is not within the preset range, the pH value of the water is adjusted by the acid tank 102 and the alkali tank 103. Preferably, a first stirring rod 106 is provided in the pH adjusting device 1 to stir the water, so that the water is better mixed with the acid and alkali solutions. The first stirring rod 106 is powered by a first rotary motor 105 and is fixed in the pH adjusting tank 101 by a first bearing seat 107. After adjustment by the pH adjusting device 1, the pH value is adjusted to a higher value. Water with a set H value enters the filtration device 3 through the first pipe 2. After passing through three layers of filtration—pebble layer 301, ceramsite layer 302, and quartz sand layer 303—the water enters the extraction device 5 through the second pipe 4. Impurities are filtered out by the filtration device 3 to prevent them from affecting the extraction efficiency. After entering the main extraction tank 501, the extraction liquid is added to the main extraction tank 501 by the extraction liquid tank 506, and the second rotary motor 503 is turned on. The second stirring rod 504 stirs the water, mixing it with the extraction liquid. Antibiotics are transferred from the water into the extraction liquid. After extraction, the mixture is allowed to stand for a period of time. The extract phase is separated from the water. Preferably, during the extraction process, the temperature inside the extraction tank 501 is adjusted by the temperature regulating device 507. After separation, since the extract phase is a light phase, it remains above the water. Then, nitrogen is added into the extraction tank 501 through the nitrogen inlet 502 to blow the extract phase into the third pipe 6. The extract phase enters the evaporation device 7 through the third pipe 6. The evaporation device 7 achieves continuous heating through the hot medium circulation via the hot medium inlet 707 and the hot medium outlet 708. The extract phase passes through the liquid settling pipe 706 and undergoes a heat exchange reaction with the hot medium. Because the solvent of the extract phase has a low boiling point and the antibiotic has a high boiling point, some of the solvent vapors... The solvent is discharged from the gas outlet 704 and enters the condenser 9 through the fourth pipe 8. Some of the unvaporized liquid enters the liquid settling chamber 703 through the liquid settling pipe 706. Due to the vaporization of the solvent in the evaporator 7, the pressure inside the tank changes, resulting in a siphon effect. The unvaporized liquid passes through the heat exchange pipe 705 and circulates for heat exchange until the solvent and antibiotic are separated. The antibiotic settles into the liquid settling chamber and is discharged through the antibiotic outlet 709. The gaseous solvent enters the condenser 903, reacts with the coolant, liquefies, and enters the liquid collection chamber 902 through the condenser 903. After the solvent is cooled, it is discharged through the solvent outlet 906.

[0031] Although embodiments of the present invention have been shown and described, it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. Based on the embodiments of the present invention, it will be understood by those skilled in the art that all other embodiments obtained by making various changes, modifications, substitutions and alterations to these embodiments without departing from the principles and spirit of the present invention and without creative effort are within the scope of protection of the present invention.

Claims

1. A device for separating and enriching antibiotics in a water body, characterized in that, include: A pH adjustment device (1) is provided on the left side. The lower right side of the pH adjustment device (1) is connected to a first pipe (2). The other end of the first pipe (2) is connected to a filter device (3). The lower right side of the filter device (3) is connected to a second pipe (4). The other end of the second pipe (4) is connected to an extraction device (5). A third pipe (6) is provided on the right side of the extraction device (5). An evaporation device (7) is provided on the other end of the third pipe (6). A fourth pipe (8) is connected to the top right side of the evaporation device (7). The other end of the fourth pipe (8) is connected to a condenser device (9).

2. The apparatus for separation and concentration of antibiotics from water bodies according to claim 1, characterized in that, The pH adjustment device (1) includes: a pH adjustment tank (101), an acid tank (102) and an alkali tank (103) are arranged side by side on the left side of the pH adjustment tank (101), the acid tank (102) is connected to the pH adjustment tank (101) through an acid pipe and a metering pump, the alkali tank (103) is connected to the pH adjustment tank (101) through an alkali pipe and a metering pump, a water inlet (104) is provided on the left side of the top of the pH adjustment tank (101), a first rotary motor (105) is provided at the middle of the top, the output end of the first rotary motor (105) is connected to a first stirring rod (106), the other end of the first stirring rod (106) passes through the pH adjustment tank (101) and is fixed to the bottom of the pH adjustment tank (101) through a first bearing seat (107), a pH detection probe (108) is provided on the right side of the top of the pH adjustment tank (101), and the pH detection probe (108) is connected to the metering pump.

3. The apparatus for the separation and concentration of antibiotics in water bodies according to claim 2, characterized in that, The filtration device (3) includes, from top to bottom, a pebble layer (301), a ceramic granule layer (302), and a quartz sand layer (303).

4. The apparatus for the separation and concentration of antibiotics in water bodies according to claim 3, characterized in that, The extraction device (5) includes: an extraction main tank (501), a nitrogen inlet (502) on the top left side of the extraction main tank (501), a second rotary motor (503) in the middle of the top, the output end of the second rotary motor (503) connected to a second stirring rod (504), the other end of the second stirring rod (504) passing through the extraction main tank (501) and fixed to the bottom of the extraction main tank (501) by a second bearing seat (505), an extraction liquid tank (506) on the top right side of the extraction main tank (501), a temperature regulating device (507) in the middle of the right side of the extraction main tank (501), and a drain outlet (508) at the bottom.

5. The apparatus for the separation and concentration of antibiotics in water bodies according to claim 4, characterized in that, The temperature regulating device (507) includes a temperature sensor (509), a heater (510), and a cooler (511).

6. The apparatus for the separation and concentration of antibiotics in water bodies according to claim 5, characterized in that, The evaporation device (7) includes, from top to bottom, a gas-liquid separation chamber (701), an evaporation chamber (702), and a liquid settling chamber (703). The top of the gas-liquid separation chamber (701) is provided with a gas outlet (704) which is connected to a condensation device (9) through a fourth pipe (8). The evaporation chamber (702) is provided with a heat exchange tube (705) and a liquid settling tube (706) inside, and a heat medium inlet (707) and a heat medium outlet (708) on the outside. The heat exchange tube (705) and the liquid settling tube (706) pass through the evaporation chamber (702), with one end extending into the gas-liquid separation chamber (701) and the other end connected to the liquid settling chamber (703). The liquid settling chamber (703) is provided with an antibiotic outlet (709) on the left side.

7. The apparatus for the separation and concentration of antibiotics from water bodies according to claim 6, characterized in that, The condensation device (9) includes a condensation chamber (901) and a liquid collection chamber (902). The condensation chamber (901) is provided with a condensation pipe (903) inside and a coolant inlet (904) and a coolant outlet (905) on the outside. One end of the condensation pipe (903) is connected to the fourth pipe (8), and the other end extends into the liquid collection chamber (902). The bottom of the liquid collection chamber (902) is provided with a solvent outlet (906).

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