Single-dose cleaning agent with molded body

Abstract

The invention relates to a detergent portion, preferably suitable for use in dishwashing processes, the detergent single-dose portion comprising a water-soluble packaging and a detergent composition, wherein the detergent composition comprises at least one powder and at least one shaped body, different from the powder, which contains at least one aminocarboxylic acid and / or a salt thereof.

Description

The invention relates to a single-part detergent portion, preferably suitable for use in dishwashing processes, the single-part detergent portion comprising a water-soluble packaging and a detergent composition, wherein the detergent composition comprises at least one powder and at least one shaped body, different from the powder, which contains at least one aminocarboxylic acid and / or a salt thereof.Cleaning agents are usually present in solid form or in liquid form (or also as a running gel). In particular, liquid cleaning agents enjoy increasing consumer popularity.Solid cleaning agents have the advantage that, in contrast to liquid cleaning agents, they do not require preservatives. Liquid supply forms are becoming increasingly prevalent on the market, in particular due to their rapid solubility and associated rapid availability of the active ingredients contained. This offers the consumer the possibility of using time-shortened dishwashing programs and nevertheless of obtaining good cleaning performance.Furthermore, consumers have become accustomed to a convenient metering of pre-portioned machine cleaning agents, such as dishwashing agents, and use these products in the form of tablets (solid cleaning agents) or in the form of bags which are filled with a usually liquid cleaning agent. Single portions in water-soluble bags are enjoying increasing popularity by consumers not only because the consumer no longer comes into contact with the chemical composition, but not least because of the attractive appearance of the bags. The visual appearance of the dosage form is becoming increasingly important. In addition to a good cleaning performance and a sufficient storage stability, a good visual appearance is one of the decision reasons for the selection of a product.From the consumer's point of view, it is now desirable to combine the advantages of both forms of offer and to provide a dosage form which is improved compared with the prior art, in particular for normally liquid cleaning agents. In this case, both a single-use proportioning is to be possible and at the same time an appearance which is visually appealing to the consumer is to be achieved.It is also important for the consumer that the single-use portion has optically structured regions which do not mix and which are present cleanly and optically separated from one another. Besides the pleasing appearance, it is important that the disposable portions are simple to produce, remain stable during storage and have no leaks. In the case of single-use portions which have loose particles (such as powder), it can be observed that during production individual powder constituents unintentionally pass between / onto the regions which are necessary for closing the single-use portions. This has many disadvantages. On the one hand, the visual impression of such cleaning portions is perceived by the consumer as being dirty, unstructured and defective. Secondly, such non-clean closure regions result in non-firmly closed single-use portions which are leak-proof / have leaks. Such leaking packages may lead to the escape of the cleaning agent from the single-use portion. This is to be avoided so that neither the consumer nor the further disposable portions which are stored in the same packaging are to come into contact with the cleaning agent. In addition, leaking packaging permits comparatively high access of moisture and / or air to the ingredients in the packaging, which can reduce their effectiveness and / or lead to their adhesion, and thus lead to a reduction in the cleaning performance.Furthermore, it is necessary to separate incompatible ingredients which might otherwise react with each other. Aminocarboxylic acids or their salts, for example MGDA-containing powdery, granular components, in particular, can undergo marked discoloration under certain storage conditions by reaction with other components, which are usually contained in cleaning agents, in particular automatic dishwashing agents, and can also be produced in terms of odor.The object of the present invention is therefore to provide a dosage form for a cleaning agent which is easy to handle, stable (in particular stable in storage and transport), has good cleaning performance, is as durable as possible and requires smaller amounts of packaging material.A first subject of the present invention is therefore a single portion of a cleaning agent comprising a) a water-soluble packaging comprising a1) at least one water-soluble receiving chamber a2) a water-soluble closure element b) closing this water-soluble receiving chamber, a phosphate-free cleaning agent composition comprising b1) at least one gel phase b2) at least one powder, b3) at least one shaped body different from the powder, wherein the shaped body comprises at least one aminocarboxylic acid and / or a salt thereof.It has surprisingly been found that the incorporation of aminocarboxylic acids or salts thereof into the shaped body leads to the latter not reacting with other active substances of the detergent single portion and leading to discolorations, odor development and / or inactivation of these other active substances, so that the detergent single portions according to the invention do not lose their cleaning performance even under more difficult storage conditions, for example over a longer time (for example four weeks) and / or higher temperatures (for example 40° C.), moreover do not significantly discolor and also do not have a negative odor.The inventive cleaning agent single portions are used in particular for cleaning hard surfaces, in particular dishes and other washware. The cleaning agents according to the invention are in particular dishwashing agents, very particularly automatic dishwashing agents for use in an automatic dishwashing machine or can be used therein.The detergent single portion comprises a water-soluble package. This packaging comprises at least one water-soluble receiving chamber and a water-soluble closure element closing this water-soluble receiving chamber.It may also contain a plurality of water-soluble receiving chambers which are closed by the same or different water-soluble closure elements. According to the invention, at least one gel phase, at least one powder and at least one shaped body of the detergent composition are located with one another in a single receiving chamber. Other compartments may contain similar or different detergent compositions.Surprisingly, it has been found that single-part cleaning compositions in which at least one gel phase, at least one powder and at least one shaped body are present, the shaped body containing at least one aminocarboxylic acid and / or its salt, are particularly well suited to fulfil the wishes of the consumer with regard to visual appearance, haptics, uncomplicated handling with a simultaneous good cleaning result. They are moreover better to produce and come out with a small amount of packaging material as multi-chamber bags.According to a particular embodiment, the aminocarboxylic acid or aminocarboxylic acid salt is selected from methylglycinediacetic acid and its salts, glutaminediacetic acid and its salts as well as ethylenediaminedisuccinic acid and its salts, particularly preferred is methylglycinediacetic acid and / or its salts, particularly preferred is the trisodium salt of methylglycinediacetic acid. These aminocarboxylic acids have excellent complexing properties with simultaneously good / improved biodegradability. Since the customary administration forms are usually hygroscopic, it has surprisingly been possible, by administering them in the shaped body, to formulate the aminocarboxylic acids, in particular the methylglycinediacetic acid, in a stable manner, in particular even after prolonged storage and / or a higher storage temperature, and to minimize interactions of these with other ingredients of cleaning agents.According to a particular embodiment, the amount of aminocarboxylic acid or aminocarboxylic acid salt, based on the total weight of the shaped body, is from 20 to 65% by weight, preferably from 27 to 60% by weight, particularly preferably from 30 to 55% by weight. This leads to particularly suitable shaped bodies which can be produced / formulated / cast particularly well.According to a particular embodiment, the aminocarboxylic acid or aminocarboxylic acid salt is selected from methylglycinediacetic acid and its salts, particularly preferably the trisodium salt of methylglycinediacetic acid, and the amount thereof, based on the total weight of the molded body, is from 20 to 65 wt %, preferably from 27 to 60 wt %, particularly preferably from 30 to 55 wt %. The incorporation of higher amounts of methylglycinediacetic acid or salts thereof than those mentioned may impair the flowability of the composition, so that, when the shaped body is produced (for example by casting), the processability deteriorates, while excessively small amounts in the cleaning performance do not provide the desired results.According to a particular embodiment, the aminocarboxylic acids and / or their salts are present in the shaped body with an average particle size of ≤250 μm, preferably of ≤200 μm. The molded articles thus produced have a very favorable appearance, the surface is smooth and hardly shows cracks or fractures, which is visually appealing to the consumer and improves the processability. The separations of the aminocarboxylic acids or salts thereof during the production of the molded body is also delayed. The refusibility and thus the sustainability of the production is also improved as a result.According to a further particular embodiment, the aminocarboxylic acids and / or their salts are present in the shaped body having an average particle size of 40 to 160 μm, preferably of 50 to 150 μm. The resulting molded articles also have a very advantageous appearance because the surface is smooth and hardly shows cracks or fractures. In addition, the molded body is well recylatable. It can be melted without problems for a renewed shaping and brought back into shape. This leads to improved sustainability of production, since attempts at production of shaped bodies and residues of the shaped body mass can be reused.According to a particular embodiment, the powder, based on the total weight of the powder, comprises less than 10% by weight, preferably less than 5% by weight, in particular less than 1% by weight, of aminocarboxylic acids and / or salts thereof. As a result, unfavourable interaction of the aminocarboxylic acid with ingredients of the powder components is particularly effectively reduced and / or completely prevented.According to a particular embodiment, the shaped body comprises polyalkylene glycols, preferably polyethylene glycols. These have the advantage that they do not have a negative influence on the cleaning process and impart stability and strength to the molded body. In addition, there are no negative interactions with components of the powder or migrations from the shaped body into the powder, so that the stability of the single portion of the cleaning agent is ensured even when stored at higher temperatures / over a longer time.According to a particular embodiment, the molded body comprises polyalkylene glycols, preferably polyethylene glycols, which have a melting point of 25 to 80° C., preferably of 30 to 70° C., particularly preferably of 45 to 65° C. at normal pressure. Polyethylene glycols having average molar masses of 800 to 8000 g / mol (PEG 800 to PEG 8000) are particularly suitable. Advantageously, it facilitates the melting for producing the shaped body, as well as when using the shaped body in the rinsing process. The moldings produced in this way also have increased strength after cooling, and so the stability of the molding during transport and / or storage is likewise improved. At the same time, the stability during preproduction of the shaped body is increased, which makes the process more effective and improves stability of the pouch produced with these shaped bodies by the stable shaped bodies.According to a very particular embodiment, the shaped body comprises polyalkylene glycols, preferably polyethylene glycols, having an average molecular weight of 1000 to 10000 g / mol, preferably 2000 to 8000, particularly preferably 3000 to 6000 g / mol, for example 4000 g / mol. These components can be melted particularly well for production and rinsing processes, but are solid enough to stabilize the shaped bodies and cleaning agent bags even at elevated storage temperatures.According to a particular embodiment, the amount of polyalkylene glycols, preferably polyethylene glycols, in the shaped body is from 20 to 50% by weight, preferably from 22 to 40% by weight, particularly preferably from 25 to 35% by weight, based on the total weight of the shaped body. These proportions by weight are the structuring elements of the shaped body; if the amounts used are too small, the melts may become too soft and the solidification times of the shaped body composition may be disadvantageously prolonged, which is disadvantageous for production reasons.According to a particular embodiment, the shaped body contains surfactants, preferably nonionic surfactants. This has the particular advantage that these important ingredients of automatic dishwashing agents can now be incorporated into the formulation better than into a powder, where in particular the flowability of the powder is negatively influenced by surfactants. In particular, powders in which surfactants are incorporated, in particular in relatively large amounts, tend to stick, as a result of which the dosability of the powder into the single-use portion becomes more difficult and, in addition, the visual appearance of the single-use portion suffers. In addition, the incorporation of surfactants into the shaped body can alter the release of these during the rinsing process. For example, a final rinse surfactant can be released by a solid shaped body which dissolves at the end of the main rinse cycle only at the end of the main rinse cycle, which is advantageous for the final rinse effect.According to a particular embodiment, the amount of the surfactants, preferably of the nonionic surfactants, based on the total weight of the shaped body, is from 5 to 50% by weight, preferably from 10 to 45% by weight, more preferably from 15 to 40% by weight. Advantageously, the single-use portion with powder / shaped body can be produced better thereby, in particular if, due to an improved flowability of the powder component, the surfactants are not present in the powder. Furthermore, the surfactant content makes the molding composition more supple and improves its flowability, so that particular advantages are obtained for the simple production of the moldings.According to a particular embodiment, the proportion of anionic surfactants in the shaped body and / or in the cleaning agent portion is less than 5% by weight, particularly preferably less than 1% by weight, based in each case on the total weight of the shaped body or the cleaning agent portion. High amounts of anionic surfactants lead to increased foaming behaviour and force the presence of defoamers for use in dishwashers, many of which should be better avoided for ecological reasons.According to a particular embodiment, the nonionic surfactants are selected from alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain and end group-terminated poly(oxyalkylated) nonionic surfactants of the formula (I) R 1 O[CH 2 CH(CH 3) O] x[ CH 2 CH 2 O] y[ CH 2 CH(CH 3) O] z CH2CH(OH)R2where R1represents a linear or branched aliphatic hydrocarbon radical having 4 to 22 carbon atoms, R 2 denotes a linear or branched hydrocarbon radical having 2 to 26 carbon atoms, x and z are values from 0 to 40 and y is a value of at least 15According to a very particular embodiment, the shaped body is characterized in that it comprises a poly(oxyalkylated) nonionic surfactant of the formula (I) R 1 O[CH 2 CH(CH 3) O] x[ CH 2 CH 2 O] y[ CH 2 CH(CH 3) O] z CH2CH(OH)R2where x=0, y= at least 15 and y=0 to 40, preferably y=0, as at least one nonionic surfactant and the amount of this surfactant, based on the total weight of the shaped body, is from 5 to 50% by weight, preferably from 10 to 45% by weight, particularly preferably from 15 to 40% by weight.The use of such nonionic surfactants leads to particularly suitable shaped body compositions having good flowability and at the same time favorable solidification times.According to a particular embodiment, at least 40 wt %, preferably at least 50 wt %, more preferably at least 75 wt %, based in each case on the total weight of the surfactants comprised in the shaped body, have a melting point above 20° C. at standard pressure. Advantageously, larger amounts of high melting point surfactants impart improved strength to the shaped article. They can also be used in part as a substitute for the abovementioned polyalkylene glycols.According to a particular embodiment, the shaped body comprises at most 15% by weight, preferably at most 10% by weight, in particular preferably at most 5% by weight, based on the total weight of the shaped body, of surfactants which have a melting point below 15° C. at standard pressure. If relatively large amounts of very low viscosity surfactants are used, the strength of the shaped body is impaired and the setting time of the shaped body is increased.According to a particular embodiment, the shaped body comprises polyethylene glycols (PEG), preferably having an average molecular weight of 3000 to 7000 g / mol in an amount of 20 to 50 wt %, preferably of 22 to 40 wt %, particularly preferably of 25 to 35 wt %, and at least one nonionic surfactant in 5 to 50 wt %, preferably of 10 to 45 wt %, particularly preferably of 15 to 40 wt %, in each case based on the total weight of the shaped body. The shaped bodies produced in this way have particularly suitable strengths, solidification times and flow rates, which are particularly suitable for efficient production of such shaped bodies.According to a very particular embodiment, the shaped body comprises polyethylene glycols having an average molecular weight of 5000 to 7000 g / mol in an amount of 25 to 50 wt %, preferably of 27 to 40 wt %, particularly preferably of 29 to 36 wt % and a nonionic surfactant having a melting point of 25 to 40° C. as at least one nonionic surfactant in an amount of 5 to 40 wt %, preferably of 10 to 30 wt %, particularly preferably of 15 to 30 wt %, in each case based on the total weight of the shaped body.The shaped bodies produced in this way have very particularly suitable strengths, solidification times and flow rates, which are particularly suitable for efficient production of such shaped bodies.According to a further particular embodiment, the shaped body comprises polyethylene glycols having an average molecular weight of 3000 to 4500 g / mol in an amount of 25 to 50% by weight, preferably of 27 to 40% by weight, particularly preferably of 29 to 36% by weight, and a nonionic surfactant having a melting point of 40 or more, preferably 43 to 65° C. as at least one nonionic surfactant in an amount of 5 to 40% by weight, preferably of 10 to 30% by weight, particularly preferably of 15 to 30% by weight, based in each case on the total weight of the shaped body. These shaped bodies produced in this way also have particularly suitable strengths, solidification times and flow rates, which are particularly suitable for efficient production of such shaped bodies.According to a particular embodiment, the shaped body comprises a bleach catalyst, in particular selected from the group of the transition metal salts and transition metal complexes, in particular complexes of manganese in the oxidation state II, III, IV or V, which particularly preferably comprise the macromolecular ligands 1,4,7-trimethyl-1,4,7-triazacyclononane (Me-TACN), 1,4,7, triazacyclononane (TACN), 1,5,9-trimethyl-1,5,9-triazacyclododecane (Me-TACD), 2-methyl-1,4,7-trimethyl-1,4,7-triazacyclononane (Me / Me TACN) and / or 2-methyl-1,4,7-triazacyclononane (Me / TACN), most preferably 1,4,7-trimethyl-1,4,7-triazacyclononane (Me-TACN) or 1,2,4,7-tretramethyl-1,4,7-triazacyclonan (Me / Me-TACN), preferably in an amount of 0.000001 to 0.5 wt.%, particularly preferably of 0.00001 to 0.3 wt.%, particularly preferably of 0.0001 to 0.25 wt.%, very particularly preferably of 0.001 to 0.1 wt.%, based on the total weight of the molded body. The presence of the bleach catalyst in the shaped body (in particular when the bleach-containing component, such as percarbonates, are formulated in powder) improves the storage stability and the performance of the detergent portion.According to a particular embodiment, the shaped body comprises a bleach activator. Bleach activators which can be used are compounds which under perhydrolysis conditions yield aliphatic peroxocarboxylic acids having preferably 1 to 10 carbon atoms, in particular 2 to 4 carbon atoms, and / or optionally substituted perbenzoic acid. Substances which carry 0- and / or N-acyl groups of the stated number of carbon atoms and / or optionally substituted benzoyl groups are suitable. Polyacylated alkylenediamines are preferred, with tetraacetylethylenediamine (TAED) having proven particularly suitable.According to a particularly preferred embodiment, the bleach activator, in particular the tetraacetylethylenediamine (TAED), is preferably in an amount of from 0.1 to 10% by weight, particularly preferably from 0.5 to 9% by weight, in particular preferably from 1.0 to 8% by weight, based on the total weight of the shaped body. The presence of the bleach activator in the shaped body (in particular when the bleach, such as percarbonates, is in powder) improves the storage stability and the performance of the detergent portion.It may be preferred if, in the single-part detergent portion, both the bleach catalyst and the bleach activator, as described in each case above, are completely present in the shaped body, while the bleach (such as, in particular, percarbonate) is completely present in the powder phase.According to a particular embodiment, the shaped body comprises a silver protectant, in particular selected from cysteine and cystine, in particular cysteine, preferably in an amount of from 0.01 to 1.5% by weight, particularly preferably from 0.1 to 1.0% by weight, in particular preferably from 0.15 to 0.8% by weight, based on the total weight of the shaped body. The presence of the silver protectant, in particular the cysteine and / or the cystine, in the molded body protects the substances sensitive to oxidation or hydrolysis, thus improving the storage stability (in particular with regard to discolorations and / or odours due to their decomposition) and the performance of the cleaning agent portion. This applies in particular when the bleach component, for example the percarbonate, is present in the powder of the single-use portion.According to a further particular embodiment, the shaped body comprises builders, in particular selected from carbonates, bicarbonates, citrates, silicates and / or salts thereof, preferably in an amount of from 0.1 to 30% by weight, particularly preferably from 0.5 to 20% by weight, particularly preferably from 1.0 to 15% by weight, based on the total weight of the shaped body. The presence of a part of the builders in the shaped body will improve the storage stability (and the performance of the detergent portion). In addition, the substances mentioned are suitable as buffers in the production of the moulding composition.According to a further embodiment, the shaped body of aminocarboxylic acids can comprise various complexing agents, in particular selected from phosphonates, particularly preferably selected from 1-hydroxyethane-1,1-diphosphonic acid and / or salts thereof, preferably in an amount of 0.01 to 30 wt %, particularly preferably from 0.1 to 25 wt %, particularly preferably from 1.0 to 20 wt %, based on the total weight of the shaped body.Preferably, the packaging of the single-part cleaning agent portion comprises exactly one water-soluble receiving chamber, exactly one water-soluble closure element, and the phosphate-free cleaning agent according to the invention.Particular features of the water soluble package will be described in more detail below. The preferred embodiments made for the production method are likewise to be understood for the single-part portion of the cleaning agent and vice versa.The water-soluble packaging comprises at least one water-soluble receiving chamber which can be formed as described by methods in the following for the method. It is formed of a water-soluble material, preferably a water-soluble shaped film or molded body, which has a trough into which the detergent composition is filled. The cleaning agent composition is at least partially accommodated in the accommodation chamber.It is not necessary here for the at least two packaging parts to be different. They can preferably be made of the same material and in the same way. In a preferred embodiment, this is two parts of a water-soluble film, in particular two parts of a water-soluble film of the same composition.In a further embodiment, the at least two packaging parts can be produced from different materials, for example from different films or from material having two different properties (for example hot and cold water-soluble films). In this embodiment, it is preferable that a water-soluble film and another packaging member produced by injection molding are combined.According to a particularly preferred embodiment of the present invention, the water-soluble packaging comprises at least one at least partially plastically deformed film. In particular, this plastic deformation of the film can be produced by methods known to the skilled worker, such as deep drawing (with and without applying a vacuum), blow molding or die forming. In particular, the water-soluble cladding comprises at least one at least partially plastically deformed film which has been produced by deep drawing.The closure element is likewise formed from water-soluble material, preferably in the form of a film. According to a particular embodiment, the closure element is separate or different from the receiving chamber before the closure of the receiving chamber.The receiving chamber is adhesively closed with the closure element at the end of the filling process. In particular, the connection between the receiving chamber and the closure element, in particular the water-soluble film, is produced by adhesive bonding, solvent sealing, water sealing or heat sealing. The inner side of the closure element is the side of the closure element facing the receiving chamber.The subject matter of the present invention comprises a water-soluble packaging and a detergent composition comprising at least one gel phase, at least one powder and at least one shaped body different from the powder and gel phase(s). The detergent composition is contained, preferably completely, in (or within) the water-soluble package. The inner side of the closure element is in contact with at least a part of the detergent composition in the single portion of the detergent. The inner side of the receiving chamber is also in contact with at least a part of the detergent composition.The use of phosphates (these are understood according to the invention to mean both the anion of phosphoric acid (orthophosphate) and the condensation products of salts of orthophosphoric acid having the general empirical formula M' n+2 P n O 3n+1 ) is virtually completely dispensed with. The detergent composition is therefore phosphate free, i.e. it contains less than 0.1 wt% phosphate(s). Preferably, the total detergent single portion contains less than 0.1 wt.% phosphate(s).Powder in the context of the present invention is understood to mean a granular mixture which is formed from a multiplicity of loose, solid particles which may in turn comprise so-called grains. A granule is a designation for the particulate constituents of powders (granules are the loose solid particles), dusts (granules are the loose solid particles), granules (loose solid particles are agglomerates of multiple granules) and other granular mixtures. When "powder" is mentioned here, it is likewise encompassed that these are also mixtures of different powders and / or different granules and / or different compacts. Correspondingly, powder also means mixtures of different powders with different granules and compacted materials. The powder preferably comprises various particles which comprise chemically different ingredients. Moreover, the optical appearance of the powder may have texture differences, such as coarse and fine particles as well as particles or areas of different colors, all or as colored speckles. However, the powder is preferably a single phase or is perceived as such in such cases as well.The powder therefore comprises solid particles as a granular mixture, which in turn preferably have a particle diameter X 50,3( volume average) of 10 to 1500 μm, more preferably of 200 μm to 1200 μm, particularly preferably of 400 μm to 1000 μm. These particle sizes can be determined by sieving or by means of a Camsizer particle size analyzer from Fa. The total number of the steps can be determined as required.Preferably, at least 80% of the particles have a particle diameter of 100 to 2000 μm, preferably of 150 μm to 1500 μm. According to a preferred embodiment, the powder comprises particles having a particle diameter X 50,3( volume average) of up to 2000 μm, in particular up to 1000 μm.According to a preferred embodiment, the powder in the context of the present invention comprises powders and / or granules and mixtures thereof.A "shaped body" in the sense of the invention is a single body which stabilizes itself in its impressed shape. This dimensionally stable body is formed from a molding compound (e.g. a composition) by bringing this molding compound into a predetermined shape in a targeted manner, e.g. by casting a flowable composition into a casting mold and subsequently curing the liquid composition, by extruding a substance mixture or by pressing a particulate premix, for example in the context of a tabletting process. The three-dimensional shape of the shaped body is basically freely selectable; its lateral surface can be designed, for example, convex, concave or planar. At the same time, however, certain spatial configurations have proven to be particularly advantageous in view of the matable nature, storage and use of the shaped bodies.More than one shaped body, for example two, three or four shaped bodies, can be contained in the single portion of the cleaning agent. The moldings may be identical in terms of their three-dimensional shape or their composition or may differ, for example, in terms of their composition or three-dimensional shape. The shaped bodies can be arranged one above the other or next to one another and will generally be in contact with one another. It is also possible for a plurality of molded bodies to be in direct contact with the closure element. If the inside of the closure element is covered to a certain extent by shaped bodies, as described below, the degree of coverage thereof relates to the coverage effected by the entirety of the shaped bodies contained in the single-part cleaning agent portion.A phase in the sense of the present invention is a spatial region in which physical parameters and / or the chemical composition are homogeneous overall. One phase differs from another phase in terms of different characteristics, for example ingredients, physical properties, external appearance, etc. Preferably, different phases can be visually distinguished. Thus, for the consumer, the gel phase is clearly distinguished from the optically coherent particulate phase formed by the powder and from the molded body. If the cleaning agent according to the invention has more than one gel phase, these can likewise be differentiated from one another in each case with the naked eye, because they differ from one another, for example, in terms of their coloring. The same applies if two or more gel phases are present. In this case too, an optical distinction of the phases is possible, for example on the basis of a difference in color or transparency. Phases within the meaning of the present invention are thus self-contained regions which can be optically distinguished from one another by the consumer with the naked eye. The individual phases can have different properties in use, such as the rate at which the phase dissolves in water and thus the rate and the sequence of release of the ingredients contained in the respective phase.It is also possible to introduce larger amounts of liquid constituents into the gel phases / shaped bodies according to the invention, which, applied or incorporated in a powder, can lead to reduced flowability, to bonds in the powder and thus to poorer processability and / or can trigger negative interactions with components of the powder.According to the invention, the shaped body can be arranged in the chamber such that it is not in direct contact with the at least one gel phase, preferably with all gel phases. Migrations, for example of solvents or other low molecular weight compounds between the shaped body and the gel phase, are thus reduced.In another embodiment, the at least one gel phase is in contact with the molded body.By introducing at least one gel phase and at least one shaped body which is different / distinguishable from gel phase and powder which are not in direct contact with one another, these active ingredients with negative interactions can be separated from one another in a meaningful and effective manner without additional and / or unnecessary separating material being required as a result. This also improves the activity of the agent or the storage stability.By such an arrangement with separate phases, negative interactions of ingredients which are incompatible with one another can be reduced advantageously by incorporating such incompatible ingredients in each case only into one of the phases, the at least one shaped body, the at least one powder or the gel phase(s). The activity of such ingredients is then retained even over a relatively long time and does not decrease over time due to the contact between the phases, which is reduced due to the phase separation.According to a preferred embodiment, the at least one gel phase and / or the shaped body have contact with the powder. In particular, both the at least one gel phase, preferably all gel phases, have contact with the powder. It is very particularly preferred if all the gel phases and the at least one shaped body have contact with the powder. In this case, the gel phases and the shaped body / bodies preferably do not have direct contact with one another. Advantageously, ingredients that are incompatible with one another can thus be introduced into a single chamber and effectively separated from one another by the distribution in the gel phases or the shaped body, so that an improvement in the storage stability and / or the cleaning performance is achieved.In a preferred embodiment, the powder is located between the at least one gel phase and the shaped body, such that the at least one, in particular the gel phase(s), has / have contact with the powder but not with the shaped body. Advantageously, ingredients that are incompatible with one another can thus be effectively separated from one another, so that an improvement in the storage stability and / or the cleaning performance is achieved.Preferably, the shaped body and the gel phase(s) are not located in the same region / the same plane of the cleaning agent single portion. Preferably, the gel phase(s) are situated at the very bottom (lowermost plane) in the sense of the filling direction of the cleaning agent single portion, the powder in the middle (middle plane) and the shaped body at the top (uppermost plane), so that it can come into direct contact with the closure means. Such single-part cleaning agent portions are obtainable in particular by the production processes described further below.According to a particularly preferred embodiment, the cleaning composition comprises at least one gel phase, at least one powder and at least one shaped body.The at least one gel phase present according to the invention in the water-soluble receiving chamber and the shaped body according to the invention are different from one another. They are at least optically separable from one another and form different phases.Preferably, the at least one gel phase is not in contact with the closure element, in particular all gel phases are not in contact with the closure element.According to a preferred embodiment, the cleaning agent single portion comprises at least one gel phase different from the molded body. The at least one gel phase is contained in the receiving chamber.The at least one gel phase and the at least one shaped body are different in their material properties and / or production methods in at least one respect and different from one another. For example, they differ in terms of their chemical composition and / or their physical properties (particularly preferably their translucency, strength, elasticity).According to a preferred embodiment, the shaped body and the at least one gel phase have different chemical compositions. In particular, the at least one shaped body differs from the at least one gel phase in the chemical composition, in particular in the type and / or amount of the ingredients contained.In particular, the at least one gel phase has a deviation, not slight, from the composition of the at least one shaped body.The at least one gel phase therefore preferably has a composition in which less than 85% by weight, preferably less than 80% by weight, in particular less than 75% by weight, of the ingredients, based on the total weight of the gel phase, are identical to the composition of the shaped body.According to a preferred embodiment, the gel phase comprises at least two, preferably at least three, particularly preferably at least four, ingredients which are not contained in the at least one shaped body and / or the at least one shaped body comprises at least two, preferably at least three, particularly preferably at least four, ingredients which are not contained in the at least one gel phase.This has the advantage that incompatible ingredients can be distributed over the different phases (gel phase(s), shaped bodies, powders) in such a way that the direct contact of these ingredients is minimized and side reactions / activity losses are reduced without additional separation measures, which are complicated in terms of process engineering, such as additional partition walls, for example, being necessary within the single portion of the cleaning agent.According to the invention, the gel phase is dimensionally stable at room temperature (20° C., 1 bar). For this purpose, a flowable mixture is used, which can be brought into a desired shape.After a certain period of time, a gel phase is obtained which remains in the predetermined shape, i.e. is dimensionally stable. This time, the solidification time, is preferably 15 minutes or less, preferably 10 minutes or less, more preferably 5 minutes or less, most preferably 2 minutes and less. The at least one gel phase is preferably elastic, in particular linear-elastic. In this case, the at least one gel phase yields to pressure, but does not deform as a result, but rather returns to the initial state after the pressure has ceased. The at least one gel phase is cut-resistant. It can be cut, for example, with a knife after solidification without further destroying it, in addition to the cut carried out. Furthermore, the at least one gel phase is in particular flexible. Due to flexibility and elasticity, it may take any shape. This also means a breaking strength, whereby good handling during production and with regard to transport and storage is made possible.The at least one gel phase is preferably elastic, while the molded body according to the invention has only a low elasticity.For the measurement of the elasticity of the at least one gel phase, a force / travel diagram was created. The composition was poured into a gel body measuring 47×19×8 mm and stored at room temperature for 12 h prior to measurement. The sample was taken in modified plastic inserts with the outer dimension 25×20×20 mm with a clearance for the mass to be measured of 10×10×20 mm. The measuring instrument used was a Lloyd LRX+(Lloyd Instruments) with a 5 kN measuring head, in which case a feed of 50 mm / min and a measurement recording at a bias voltage of 1 N (zero point) were set. As a result, the force in N necessary to compress the molded body by 8 mm is given. Due to the elasticity of the gel phase, the initial dimensions of the gel phase are restored within a period of 15 min after the measurement has ended. Preferably, the values thus measured (for a compression of 8 mm) are between 10 N and 40 N, preferably between 15 N and 30 N.According to a further preferred embodiment, the at least one gel phase and the at least one shaped body have different elasticities. It is particularly preferred that the at least one gel phase is deformable and / or elastic, while the at least one molded body is not easily deformable and / or less elastic. A lower elasticity of a shaped body, in particular when it is directly in contact with the closure element, leads to stiffening and stabilization of the basic shape of the cleaning agent single portion. The fixing of the powder is ensured in this way without the cleaning agent single portion losing strength and structure.For the measurement of the low elasticity and / or breaking strength of the molded body, a force / travel diagram was created. A shaped body measuring 45×35×3.4 mm was produced and stored at room temperature for 12 h prior to measurement. The body to be tested is placed on the jaws of a vice in such a way that it rests stably and is located between 70 and 90% of the area of the test specimen free between the two bearing surfaces (jaws).As the measuring apparatus, a texture analyzer TA.XT plus (Stable Micro Systems Ltd.) using the software exponent (Stable Micro Systems Ltd.) having a ball body with a diameter of 19 mm was used. A pretest feed of 1 mm / sec, a test feed of 0.5 mm / s, a posttest feed of 2 mm / s and a pretest force of 5 grams were set at a distance ("distance") of 3 mm. As a result, the penetration depth of the ball body is given in mm, which is necessary for the molded body to break. The preferred molded bodies broke at a penetration depth of 0.1 mm to 1.0 mm, preferably of 0.15 mm to 0.8 mm, in particular of 0.2 to 0.6 mm, in the above-mentioned settings.According to a particularly preferred embodiment, the gel phase does not contain dibenzylidene sorbitol. According to a very particularly preferred embodiment, the gel phase does not contain a benzylidene alditol compound. According to a particularly preferred embodiment, the cleaning agents contain powders and in which at least one gel phase at least one gel phase does not contain dibenzylidene sorbitol, in particular no benzylidene alditol.According to the invention, the molded body is preferably in contact (in direct contact) with the closure element, in particular with the inner side thereof. This means that the at least one shaped body and also the at least one powder are arranged within the water-soluble packaging.The preferred arrangement according to the invention, in which the inside of the closure element is in contact with the powder to the extent of less than 10% of its surface, is advantageous for the efficient, in particular trouble-free production, strength of the closure between receiving chamber and closure element, and the optical properties of the single-use portion, since in this case there is less possibility for the powder to reach the closure surfaces, for example, in the case of deep-drawn receiving chambers, to the surfaces directly next to the formed chamber.In particular, if the closure element is a water-soluble film, it is important that the connecting surface between the receiving chamber and the closure element does not comprise any particles of the powder, since otherwise the seal between the receiving chamber and the closure element is not complete and in the worst case permeable to the detergent composition. The stability of the single-use portion, in particular during storage and / or transport, can also be improved by the powder, if it has only a slight contact with the inside of the closure element, not damaging, bulging or even puncturing the closure element at some points or scraping and / or wiping it off by means of relatively long friction. If the contact of the powder with the inner side of the closure element is reduced or avoided, the thickness of the closure element, for example the thickness of the closure film, can be selected to be smaller, which is advantageous with regard to sustainability by using less packaging material.In a particularly preferred embodiment, the cleaning agent single portions contain exactly one shaped body which, according to the invention, is arranged in such a way that it is in direct contact with the closure element. This simplifies the production of such single-use portions in that only a single molded body has to be applied, inserted or placed in some other way.According to a preferred embodiment, the shaped body according to the invention is a preformed shaped body. Such a preformed shaped body has already obtained its shape before introduction into the receiving chamber. As a result, the production of the shaped body is decoupled from the production of the single-use portion (in particular in time). The production steps of the entire single-part cleaning agent portion can thereby be carried out in a rapid sequence one after the other and do not extend through the solidification times of the shaped body which are necessary when this shaped body is produced in situ, for example is introduced into the receiving chamber as a flowable premix.It is also possible to incorporate into the shaped body, in particular those which are preformed, constituents which cannot be incorporated in gel phases, in particular those which are introduced into the receiving chamber as a flowable composition, on account of the processability of the constituents themselves, the production process of the gel phases, and / or their other material properties.Within the scope of preferred embodiments of the present invention, the inner side of the closure element is in contact with the powder to an extent of less than 8%, in particular to an extent of less than 6%, very particularly to an extent of less than 3%, of its surface. The less contact the surface of the inner side of the closure element with the powder, the more stable the cleaning agent portion is both during production and during storage.According to the invention, preferably at least one shaped body is arranged in such a way that it is in direct contact with the closure element and the inner side of the closure element is in contact with the powder to the extent of less than 10%, of its surface.According to a particularly preferred embodiment, the inner side of the closure element is not in contact with the powder. The advantages already described are greatest in this embodiment.According to a preferred embodiment, the shaped body is arranged in the chamber such that it is in direct contact with the powder. Thus, the shaped body can cover the powder well, so that it does not come into contact with the inside of the closure element and, if applicable, impairs the tightness of the closure of the single-use portion.According to a preferred embodiment, the molded body is arranged such that more than 70%, preferably more than 75%, in particular more than 80%, very particularly more than 85% of its surface is covered by the at least one molded body by more than 70%, preferably more than 75%, in particular more than 80%. This can be effected in particular by bringing the shaped body, after the powder has been introduced into the receiving chamber, from above onto or into the receiving chamber. In this case, the shaped body then covers the phase formed by the powder to a large extent and prevents, at least for the most part, the contact of the powder with the surface of the inner side of the closure element after the closure of the cleaning single portion. The above-described negative consequences of a large-area contact of the surface with the powder are thereby avoided. The closure element rests on the molded body in the case of direct contact.According to a preferred embodiment, the side of the molded body which is in contact with the closure element (contact side) has at least 70%, preferably at least 75%, in particular at least 80%, particularly preferably more than 85% of its surface area contact with the inner side of the closure element. This embodiment has the advantage that this arrangement prevents particles of the powder from being able to pass between the closure element and the shaped body after production, for example during transport. The problems of scrubbing, puncturing, etc. discussed above are thereby further reduced.Particularly preferably, this side of the molded body has a substantially full-surface contact with the closure element. "Substantially full-surface" means that at least 90% of the surface of the contact side is in direct contact with the inner side of the closure element. The closure element then rests on the molded body in the case of direct contact.It is preferred if the shaped body has at least one substantially flat side. Substantially flat in the sense of the invention means that the flat side of the molded body does not have any larger elevations or depressions. The deviation is 10% and less, preferably 5% and less. The underside, which is preferably in contact with the powder, and / or the upper side, which is in contact with the inner side of the closure element, can be substantially flat. The molded body preferably has at least one substantially flat top side and / or bottom side.The shaped bodies according to the invention preferably have a flat underside, the greatest diagonal of which is greater than the height of the shaped body. The greatest diagonal thereof is preferably more than 1.5 times, preferably more than 2 times, the height of the shaped body, the shaped body being applied with the flat underside to the surface of the powder. Such an arrangement leads to a particularly large-area covering of the inner side of the closure element without significantly reducing the space available within the receiving chamber.In a further preferred embodiment, the shaped body has an upper side which is substantially plane-parallel to the underside. Substantially plane-parallel surface means that deviations from a complete parallelism of approximately 10%, preferably 5%, are still possible. Such surfaces are produced by production deviations or specific production processes and show, for example, slightly roughened, hubbble surfaces.Such surfaces are, however, included in the invention. This configuration advantageously leads to a flat closure element (in particular a flat, water-soluble film) simply being able to be applied to a plane-parallel upper side.The underside of the shaped body is in particular in contact with the powder, the upper side with the closure element.According to a preferred embodiment, the closure element comprises a water-soluble film. The closure element is preferably a water-soluble film. Suitable water soluble films are described in more detail in connection with the methods of the present invention.Due to the arrangement according to the invention, in which as little powder as possible comes into contact with the water-soluble film closing the receiving chamber, since the aforementioned negative effects do not occur due to the powder, the thickness of the film can be reduced since there is little contact with the powder. This has the advantage that, and thus for environmentally friendly, lasting use of packaging material, a film can be selected which has a thickness which is less than that used in conventional water-soluble single-use portions.According to a particularly preferred embodiment, the water-soluble film has a thickness of 80 μm or less, preferably of 70 μm or less, in particular of 65 μm or less, in particular preferably 60 μm. Most preferably, the thickness of the film may be 55 μm or less, resulting in a significant saving in packaging material.In a further preferred embodiment, the water-soluble film which forms the closure element has a thickness which is less than the average thickness of the water-soluble receiving chamber. At this time, the average thickness of the water-soluble accommodation chamber is determined by measuring the thickness, and the arithmetic mean is formed. This also leads to a saving of material for the packaging of the single-use portion.According to a further preferred embodiment, the molded body which is in contact with the closure element has substantially the same height. The molded body is substantially the same thickness. The substantially identical height is present if the height at individual points of the molded body deviates by 10% and less, preferably by 5% and less.It is preferred if the shaped body is flat. The shaped bodies preferably have a flat underside, the greatest diagonal of which is greater than the height (=thickness) of the shaped body, the shaped body being applied with the flat underside to the surface of the powder.Corresponding shaped bodies can be produced not only in a simple manner, for example by means of casting methods or tabletting, but can also be applied mechanically to the powder in a simple manner.It is particularly preferred if the shaped body has a flat underside, the greatest diagonal of which is more than 1.5 times, preferably more than 2 times, the height of the shaped body, the shaped body being applied with the flat underside to the surface of the powder. This produces excellent coverage of the powder, especially at high coverage levels.In a very particularly preferred embodiment of the present invention, the shaped body which is in contact with the closure element has a height of 2.5 to 9 mm, preferably 2.75 to 6.0 mm, in particular 3.0 to 5.5 mm. Such shaped bodies are particularly suitable for utilizing the available space of the receiving chamber in combination with the powder and at the same time achieving the advantages of covering the powder with respect to the closure element. At the same time, the entire cleaning agent single portion is stabilized by the presence of such shaped bodies. Moldings having significantly lower heights than stated are generally more fragile, as a result of which they cannot fulfil the inventive purpose from the beginning or cannot fulfil it over the entire transport and / or storage period. Much thicker shaped bodies have the disadvantage that they leave too little space for further important components in the space utilization of the single portion of the cleaning agent, which components cannot be incorporated into the shaped body without great expense and / or loss of activity.It is preferred in particular if such (preferably substantially flat) shaped bodies of the stated thickness / height, in particular a height / thickness of 2.75 to 6.0 mm produce a high degree of coverage of the inner side of the closure element of preferably more than 80%, particularly preferably more than 85% of their surface, whereby the space provided by the receiving chamber for the various components / phases of the detergent composition is used particularly favorably without powder coming into contact to a greater extent with the closure element and leading to the already stated negative consequences, such as scrubbing, puncturing of the closure element, in particular of a closure film, are thereby further reduced.According to a particularly preferred embodiment, the molded body has an essentially flat top side and bottom side, the top side having essentially full-surface contact with the closure elements.According to a further preferred embodiment, the total weight of the single detergent portion is from 10 g to 25 g, preferably from 12 to 22 g, particularly preferably from 13 g to 20 g. Such detergent portions are suitable, on the one hand, for making good use of the metering chamber of dishwashers but not for requiring an excessively large amount of packaging material.The total weight of the powder in the single-part detergent portions according to the invention is from 12 to 22 g, is preferably from 7 g to 20 g, preferably from 8 to 15 g, particularly preferably from 10 g to 12 g.In a further embodiment, the total weight of a shaped body in the inventive cleaning agent single portions is preferably from 4 g to 8 g, preferably from 5 to 7 g.According to a further preferred embodiment, the weight ratio of powder to shaped body is from 4:1 to 1:1, preferably from 3.75:1 to 1.25:1, in particular from 3.5:1 to 1.5:1, very particularly preferably from 3.25:1 to 1.75:1. In particular, this allows the various active substances to be well distributed in powder and shaped bodies and simultaneously separated.These and other aspects, features and advantages of the invention will become apparent to those skilled in the art from a study of the following detailed description and claims. Any feature of one aspect of the invention may be used in any other aspect of the invention. Further, it is to be understood that the examples herein are intended to describe and illustrate the invention, but not to limit it, and in particular the invention is not limited to these examples. All percentages are % by weight unless otherwise stated. Numerical ranges indicated in the format "from x to y" include the above values. When several preferred numerical ranges are specified in this format, it is understood that all ranges arising from the combination of the various endpoints are also detected."At least one" as used herein means 1 or more, i.e., 1, 2, 3, 4, 5, 6, 7, 8, 9 or more. With respect to an ingredient, the specification refers to the type of ingredient and not to the absolute number of molecules. "At least one bleach catalyst" thus means, for example, at least one type of bleach catalyst, i.e. that one type of bleach catalyst or a mixture of a plurality of different bleach catalysts may be meant. Together with weight data, the data refer to all compounds of the stated type which are contained in the composition / mixture, i.e. the composition does not contain any further compounds of this type beyond the stated amount of the corresponding compounds.Where molecular weights are referred to herein, these figures always refer to the number-average molecular weight M n, unless explicitly stated otherwise. The number average molar mass can be determined, for example, by means of gel permeation chromatography (GPC) in accordance with DIN 55672-1:2007-08 using THF as eluent. The mass average molar mass M w can likewise be determined by means of GPC, as described for M n.All percentages given in connection with the compositions described herein relate, unless explicitly stated otherwise, to % by weight, in each case based on the phase in question (i.e. in each case the powder, the gel phase(s), the shaped body).Certain minimum requirements are imposed on formulations of the at least one gel phase. Thus, as already stated, the gel phase must solidify within the shortest possible time. Long solidification times would lead to a long production time and thus to high costs. According to the invention, solidification time means the period of time during which, during production, the at least one gel phase changes from a state in which it is flowable at 20° C. to a state in which it is non-flowable at room temperature and stable in shape. Room temperature is understood to mean a temperature of 20° C.Furthermore, the gel phase must be stable on storage, namely under conventional storage conditions. The gel phase according to the invention is a constituent of a cleaning agent. Cleaning agents are usually stored in a household for a certain period of time. The storage is usually carried out in the vicinity of the washing or dishwasher. For such storage, the gel phase should be stable. Thus, the gel phase should be stable, in particular even after a storage time of, for example, 4 to 12 weeks, in particular 10 to 12 weeks or longer at a temperature of up to 40° C., in particular at 30° C., in particular at 25° C. or at 20° C., and should not deform or otherwise change in consistency during this time.According to a preferred embodiment, the at least one gel phase is introduced in situ into the receiving chamber and solidifies to form gel phase(s) solid at 1 bar and 20° C., while the molded body is prefabricated, and is introduced as a solid body into the cleaning agent portion.Optically, the surface of the gel phase should differ significantly from the powder and / or the shaped body, for example, due to a distinct gloss. The surface of the powder is usually not glossy, but rather matt, glossless or dull, so that a good distinction, which makes the cleaning agent attractive to the consumer, is possible by means of a gloss. The molded body, on the other hand, is preferably not transparent.A disadvantage would be a change in volume or shrinkage during storage, since the acceptance of the product by the consumer would be low as a result. Leakage of liquid or sweating of constituents out of the gel phase is also undesirable. Here too, on the one hand, the visual impression is of relevance. The stability of the gel phase can be influenced by the escape of liquid, such as solvent, for example, so that the constituents are no longer contained stably and the washing or cleaning action can thereby also be influenced.It is preferred that the single cleaning agent portion contains two or more, preferably three or more, gel phases different from the molded body in the chamber. The gel phases can be optically identical or differ in design or color. Furthermore, a plurality of gel phases may be present in the cleaning agent portion, the chemical composition of which gel phases differs by the presence or absence of one or more active substances. Preferably, however, the chemical composition remains substantially the same. Above all, however, the gel phases are still different from the at least one shaped body.A substantially identical chemical composition of the gel phases with one another is present if the chemical composition of the gel phases with one another is at least 85% by weight of the constituents identical to one another. Preferably, ingredients can be changed in a range from 0.001 to 14 wt %, preferably from 0.01 to 10 wt %, particularly preferably from 0.1 to 7 wt % of the ingredients, based on the total weight of the respective gel phase. This has the advantage that the properties of the gel phases, in particular the processing properties, do not change to such an extent that the production and processing conditions change significantly. Larger changes in the composition of the gel phases than described above have a negative effect on such properties, in particular on the processing properties, such as e.g. solidification time.One or optionally more gel phases can moreover preferably be translucent (translucent) or transparent, resulting in a good optical impression. Preferably, the transmission of the gel phase (without dye) is in a range between 100% and 20%, between 100% and 30%, in particular between 100% and 40%. To measure the light transmittance (transmission), the transmittance in % at 600 nm to water was determined as a reference at 20° C. For this purpose, the mass was poured into the 11 mm round cuvettes provided and, after 12 h storage time at room temperature, was measured for a long time in a LICO 300 color measurement system. In this case, for example, all or none of the gel phases can be transzulen or transparent. The presence of opaque and translucent gel phases in the cleaning agent single portion is preferred according to the invention.According to a preferred embodiment, a plurality of gel phases are arranged next to one another in the receiving chamber. The gel phases are preferably not in direct contact with one another.According to a particularly preferred embodiment, three or four gel phases different from the molded body are arranged in the receiving chamber.Furthermore, it is preferred that the at least one powder and the at least one gel phase are in direct / direct contact with one another. In this case there should be no negative interaction between the ingredients of the powder and the gel phase(s). Here, no negative interaction means, for example, that no ingredients or solvents pass from one phase into the other, or that the stability, in particular storage stability, preferably at storage temperature of 4 weeks and 30° C., and / or the aesthetic nature of the product in any form, for example by color change, formation of moist-acting edges, blurring boundary between the two phases or the like, is impaired.Surprisingly, it has been found that particularly good storage stability is achieved if the gel phase is low in water. Low water in the context of the present invention means that small amounts of water can be used for preparing the at least one gel phase. The proportion of water in the gel phase is in particular 20% by weight or less, preferably 15% by weight or less, particularly 12% by weight or less, in particular between 10 and 5% by weight. The data in % by weight are based on the total weight of the gel phase.According to a further embodiment, the gel phase, the powder and / or the shaped body is substantially anhydrous. This means that the gel phase is preferably substantially free of water. "Substantially free" here means that the various phases may contain small amounts of water. This water can be introduced into the phase, for example, by a solvent or as water of crystallization or on the basis of reactions of constituents of the phase with one another. The proportion of water in the respective phase is in this embodiment 4.9% by weight or less, 4% by weight or less, preferably 2% by weight or less, in particular 1% by weight or less, particularly 0.5% by weight or less, in particular 0.1% by weight or 0.05% by weight or less. The figures in % by weight relate to the total weight of the respective phase (gel phase, powder, shaped body).According to a particularly preferred embodiment, the weight of all gel phases is from 0.1 g and 4 g, preferably from 0.4 to 3 g, particularly preferably from 0.7 to 2.5 g.In particular in single-part detergent portions which have a total weight of 12 to 22 g, particularly preferably of 13 g to 20 g, and have at least one shaped body having a total weight of 4 to 8, in particular of 5 to 7 g, and also powder in a total weight of 8 to 15 g, particularly preferably of 10 g to 12 g, the weight of all gel phases is 0.4 to 3 g, in particular preferably 0.7 to 2.5 g.According to a further preferred embodiment, the weight ratio of the shaped body to the gel phase(s) (sum of all gel phases) is from 8:1 to 1:2, preferably from 6:1 to 1:1, in particular from 4.5:1 to 1.5:1, very particularly preferably from 4:1 to 1.75:1. Such ratios lead to particularly good utilization of the various phases within the single detergent portion.In a further embodiment of the present invention, it is preferred that the weight ratio of the powder to the gel phase (or to the sum / to the total weight of all gel phases) is from 20:1 to 1:1, preferably from 12:1 to 1.5:1, in particular from 10:1 to 2:1, very particularly preferably from 8:1 to 2.5:1.The gel phase comprises at least one gelling agent. The at least one gel phase preferably comprises water-soluble polymer from the group of the optionally acetalized polyvinyl alcohols (PVOH) and copolymers thereof.Copolymers of polyvinyl alcohol in the sense of the invention are preferably copolymers of polyvinyl alcohol with other monomers, in particular copolymers with anionic monomers. Suitable anionic monomers are preferably vinylacetic acid, alkyl acrylates, maleic acid and derivatives thereof, in particular monoalkyl maleates (in particular monomethyl maleate), dialkyl maleates (in particular dimethyl maleate), maleic anhydride, fumaric acid and derivatives thereof, in particular monoalkyl fumarate (in particular monomethyl fumarate), dialkyl fumarate (in particular dimethyl fumarate), fumaric anhydride, itaconic acid and derivatives thereof, in particular monomethyl itaconate, dialkyl itaconate, dimethyl itaconate, itaconic anhydride, citraconic acid (methyl maleic acid) and derivatives thereof, monoalkyl citraconic acid (in particular methyl itraconate), dialkyl citraconic acid (dimethyl itraconate), citraconic anhydride, mesaconic acid (methyl fumaric acid) and derivatives thereof, monoalkylmesaconate, dialkylmesaconate, Mesaconic anhydride, glutaconic acid and derivatives thereof, monoalkyl gluconate, dialkyl gluconate, glutaconic anhydride, vinyl sulfonic acid, alkyl sulfonic acid, ethylene sulfonic acid, 2-acrylamido-1-methylpropanesulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid, 2-methylacrylamido-2-methylpropanesulfonic acid, 2-sulfoethyl acrylate and combinations thereof and the alkali metal salts or esters of the abovementioned monomers.The copolymers of PVOH are particularly preferably selected from copolymers of polyvinyl alcohol with a monomer, in particular selected from the group of monoalkyl maleates (in particular monomethyl maleate), dialkyl maleates (in particular dimethyl maleate), maleic anhydride and combinations thereof, and the alkali metal salts or esters of the abovementioned monomers. The values stated for polyvinyl alcohols themselves apply to the suitable molar masses,According to a very particularly preferred embodiment, the at least one gel phase comprises polyvinyl alcohol and / or optionally acetalized polyvinyl alcohols, referred to below as PVOH. These gel phases thus produced are particularly high-melting, dimensionally stable (even at 40° C.) and do not change their shape, or change it only insignificantly, even when stored. In particular, they are also poorly reactive with a view to a direct negative interaction with constituents of the powder. PVOH can in particular also produce low-water or anhydrous gel phases without difficulty. When PVOH is used as polymer for the at least one gel phase, thin-viscosity melts are obtained at 110-120° C., which can thereby be processed particularly easily; in particular, the filling of the gel phase into the water-soluble casing can be carried out quickly and accurately without sticking taking place or the quantity being incorrectly dosed. Furthermore, these gel phases adhere particularly well to the water-soluble cladding, in particular if it is likewise made of PVOH. This is optically advantageous. Due to the rapid solidification of the at least one gel phase with PVOH, the further processing of the gel phases can take place particularly quickly. Furthermore, the good solubility of the gel phases produced is particularly favorable for the overall solubility of the cleaning agent.According to the invention, the gel phase comprises PVOH in a proportion of about 5 wt % to 40 wt %, in particular of 7 wt % to 35 wt %, preferably of 8.5 wt % to 25 wt %. Significantly lower proportions of PVOH do not lead to the formation of stable gel phase. The values are in each case based on the total weight of the gel phase(s).Polyvinyl alcohols are thermoplastics which are produced as white to yellowish powders, usually by hydrolysis of polyvinyl acetate. Polyvinyl alcohols (PVOH) are resistant to almost all anhydrous organic solvents. Preference is given to polyvinyl alcohols having a molar mass of from 30 000 to 60 000 g / mol.In the context of the present invention, it is preferred that the at least one gel phase comprises polyvinyl alcohol, the degree of hydrolysis of which is preferably 70 to 100 mol %, in particular 80 to 90 mol %, particularly preferably 81 to 89 mol % and in particular 82 to 88 mol %.Preference is given to polyvinyl alcohols which have, as pale yellowish powders or granules with degrees of polymerization in the range from about 100 to 2500 (molar masses of about 4000 to 100,000 g / mol) and degrees of hydrolysis of 80 to 99 mol %, preferably of 80 to 90 mol %, in particular of 87 to 89 mol %, for example 88 mol %, and which accordingly still comprise a residual content of acetyl groups (acetalized polyvinyl alcohol).PVOH powders having the above-mentioned properties which are suitable for use in the at least one gel phase are marketed, for example, under the designation Mowiol® or Poval® by Kuraray. The Poval® grades, in particular grades 3-83, 3-88 and preferably 4-88 and Mowiol® 4-88 from Kuraray are particularly suitable.The water solubility of polyvinyl alcohol can be altered by post-treatment with aldehydes (acetalization) or ketones (ketalization). Polyvinyl alcohols have proven to be particularly preferred and particularly advantageous because of their extremely good cold water solubility, which are acetalized or ketalized with the aldehyde or keto groups of saccharides or polysaccharides or mixtures thereof. The reaction products of polyvinyl alcohol and starch are to be used as extremely advantageous. Furthermore, the water solubility can be changed by complexation with Ni or Cu salts or by treatment with dichromates, boric acid, borax and can thus be adjusted specifically to desired values.According to the invention, the at least one gel phase can further comprise anionic polymers or copolymers having builder properties. The polymers listed below can, if appropriate additionally, also be present in at least one of the other phases of the cleaning agent. This is preferably a polycarboxylate. Polycarboxylate used is preferably a copolymeric polyacrylate, preferably a sulfopolymer, preferably a copolymeric polysulfonate, preferably a hydrophobically modified copolymeric polysulfonate. The copolymers may have two, three, four or more different monomer units. Preferred copolymeric polysulfonates contain, in addition to monomer(s) containing sulfonic acid groups, at least one monomer from the group of unsaturated carboxylic acids.Unsaturated carboxylic acid(s) used with particular preference are unsaturated carboxylic acids of the formula R 1( R 2) C=C(R 3) COOH in which R 1 to R 3 independently of one another, are -H, -CH 3, a straight-chain or branched saturated alkyl radical having 2 to 12 carbon atoms, a straight-chain or branched, mono- or polyunsaturated alkenyl radical having 2 to 12 carbon atoms, alkyl or alkenyl radicals substituted by -NH2, -OH or -COOH, as defined above, or are -COOH or -COOR 4 where R 4 is a saturated or unsaturated, The hydrocarbon radical is a straight-chain or branched hydrocarbon radical having 1 to 12 carbon atoms.Particularly preferred unsaturated carboxylic acids are acrylic acid, methacrylic acid, ethacrylic acid, α-chloroacrylic acid, α-cyanoacrylic acid, crotonic acid, α-phenylacrylic acid, maleic acid, maleic anhydride, fumaric acid, itaconic acid, citraconic acid, methylenemalonic acid, sorbic acid, cinnamic acid or mixtures thereof. It is of course also possible to use the unsaturated dicarboxylic acids.In the case of monomers containing sulphonic acid groups, those of the formula R 5( R 6) C=C(R 7)- X-SO 3 H are preferred, in which R 5 to R 7 independently of one another, represents -H, -CH 3, a straight-chain or branched saturated alkyl radical having 2 to 12 carbon atoms, a straight-chain or branched, mono- or polyunsaturated alkenyl radical having 2 to 12 carbon atoms, alkyl or alkenyl radicals substituted by -NH 2, - OH or -COOH or represents -COOH or -COOR 4 where R 4 represents a saturated or unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, unsaturated, A straight-chain or branched hydrocarbon radical having 1 to 12 carbon atoms, and X is an optionally present spacer group selected from -(CH 2)n- where n=0 to 4, -COO-(CH 2)k- where k=1 to 6, -C(O)-NH-C(CH 3)2-, - C(O)-NH-C(CH 3)2- CH 2- and -C(O)-NH-CH(CH 3)- CH 2-.Preferred among these monomers are those of the formulae H 2 C=CH-X-SO 3 H, H 2 C=C(CH 3)- X-SO 3 H or HO 3 S-X-(R 6) C=C(R 7)- X-SO 3 H in which R 6 and R7 are selected independently of one another from -H, -CH3, -CH2CH3, ch_ner78_ch_ner79_ch_ner80_und -CH(CH 3)2 and X represents an optionally present spacer group selected from -(CH 2)n- where n=0 to 4, -COO-(CH 2)k- where k=1 to 6, -C(O)-NH-C(CH 3)2-, - C(O)-NH-C(CH 3)2- CH 2- and -C(O)-NH-CH(CH 3)- CH 2-.Particularly preferred monomers containing sulfonic acid groups are 1-acrylamido-1-propanesulfonic acid, 2-acrylamido-2-propanesulfonic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, 2-methacrylamido-2-methyl-1-propanesulfonic acid, 3-methacrylamido-2-hydroxypropanesulfonic acid, allylsulfonic acid, methallylsulfonic acid, allyloxybenzenesulfonic acid, methallyloxybenzenesulfonic acid, 2-hydroxy-3-(2-propenyloxy)propanesulfonic acid, 2-methyl-2-propene-1-sulfonic acid, styrenesulfonic acid, vinylsulfonic acid, 3-sulfopropyl acrylate, 3-sulfopropyl methacrylate, sulfomethacrylamide, sulfomethylmethacrylamide and mixtures of the acids mentioned or water-soluble salts thereof. In the polymers, the sulfonic acid groups can be present wholly or partly in neutralized form, that is to say that the acidic hydrogen atom of the sulfonic acid group in some or all of the sulfonic acid groups can be replaced by metal ions, preferably alkali metal ions and in particular by sodium ions. The use of partially or fully neutralized copolymers containing sulfonic acid groups is preferred according to the invention.The monomer distribution of the copolymers preferably used according to the invention is preferably in each case 5 to 95% by weight, particularly preferably the proportion of the monomer containing sulfonic acid groups is 50 to 90% by weight and the proportion of the monomer containing carboxylic acid groups is 10 to 50% by weight, in the case of copolymers which contain only monomers containing carboxylic acid groups and monomers containing sulfonic acid groups, the monomers here preferably being selected from the abovementioned. The molar mass of the sulfo copolymers preferably used according to the invention can be varied in order to adapt the properties of the polymers to the desired end use. Preferred cleaning agents are characterized in that the copolymers have molar masses of 2000 to 200 000 g·mol -1, preferably of 4000 to 25 000 g·mol -1 and in particular of 5000 to 15 000 g·mol -1.In a further preferred embodiment, the copolymers comprise, in addition to carboxyl group-containing monomer and sulfonic acid group-containing monomer, also at least one nonionic, preferably hydrophobic monomer. The use of these hydrophobically modified polymers has in particular been able to improve the final rinse performance of dishwashing detergents according to the invention.Particularly preferably, the at least one gel phase further comprises an anionic copolymer, wherein a copolymer comprising i) carboxylic acid group-containing monomers ii) sulfonic acid group-containing monomers iii) non-ionic monomers, in particular hydrophobic monomers, is used as anionic copolymer.The nonionic monomers used are preferably monomers of the general formula R 1( R 2) C=C(R 3)- X-R 4 in which R 1 to R 3 independently of one another, denote -H, -CH 3 or -C 2 H 5 X denotes an optionally present spacer group selected from -CH 2-, - C(O)O- and -C(O)-NH-, and R_NER107represents a straight-chain or branched saturated alkyl radical having 2 to 22 carbon atoms or an unsaturated, unsaturated, saturated or unsaturated, unsaturated, unsaturated, hydroxyl radical, preferably, aromatic radicals having 6 to 22 carbon atoms.Particularly preferred nonionic monomers are butene, isobutene, pentene, 3-methylbutene, 2-methylbutene, cyclopentene, hexene, hexene-1, 2-methylpentene-1, 3-methylpentene-1, cyclohexene, methylcyclopentene, cycloheptene, methylcyclohexene, 2,4,4-trimethylpentene-1, 2,4,4-trimethylpentene-2,2,3-dimethylhexene-1, 2,4-dimethylhexene-1, 2,5-dimethylhexene-1, 3,5-dimethylhexene-1, 4,4-dimethylhexane-1, ethylcyclohexyne, 1-octene, α-olefins having 10 or more carbon atoms, such as 1-decene, 1-dodecene, 1-hexadecene, 1-octadecene and C 22- α-olefin, 2-Styrene, α-methylstyrene, 3-methylstyrene, 4-propylstyrene, 4-cyclohexylstyrene, 4-dodecylstyrene, 2-ethyl-4-benzylstyrene, 1-vinylnaphthalene, 2-vinylnaphthalene, methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, pentyl acrylate, hexyl acrylate, methyl methacrylate, N-(methyl)acrylamide, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, N-(2-ethylhexyl)acrylamide, octyl acrylate, octyl methacrylate, N-(octyl)acrylamide, lauryl acrylate, lauryl methacrylate, N-(lauryl)acrylamide, stearyl acrylate, stearyl methacrylate, N-(stearyl)acrylamide, behenyl acrylate, Behenyl methacrylate and N-(behenyl)acrylamide or mixtures thereof, in particular acrylic acid, ethyl acrylate, 2-acrylamido-2-methylpropanesulfonic acid (AMPS) and mixtures thereof.According to the invention, the at least one gel phase can also comprise further polymers. Preference is given here to the presence of polyalkylene glycols, in particular polyethylene glycols, in the gel phase.Polyethylene glycols with an average molar mass of between about 100 and 8000 are particularly suitable. The abovementioned polyethylene glycols are particularly preferably used in amounts of from 1 to 40% by weight, preferably from 5 to 35% by weight, in particular from 10 to 30% by weight, for example from 15 to 25, preferably in each case based on the total weight of the gel phase.Surprisingly, it has been found that PVOH together with anionic polymers or copolymers, in particular with sulfopolymers, also leads to the formation of gel phases with insensitive surfaces. Corresponding surfaces can be touched by the end user without material remaining adhering to the hands. No material removal takes place even in a packaging. Preferably, therefore, the gel phase comprises PVOH and an anionic copolymer / polymer. The proportion of the anionic polymer is preferably 1 wt % to 35 wt %, in particular 3 wt % to 30 wt %, particularly 4 wt % to 25 wt %, preferably 5 wt % to 20 wt %, for example 10 wt %, based on the total weight of the gel phase. Sulfopolymers also ensure an excellent gloss of the surface. In addition, fingerprints are not retained either. Therefore, the proportion of sulfopolymers, in particular of sulfopolymers with AMPS as sulfonic acid group-containing monomer, for example Acusol 590, Acusol 588 or Sokalan CP50, is preferably 1 wt. % to 25 wt. %, in particular 3 wt. % to 15 wt. %, particularly 4 wt. % to 12 wt. %, preferably 5 wt. % to 10 wt. %, based on the weight of the gel phase. In a particularly preferred embodiment, the at least one gel phase therefore comprises PVOH and a sulfopolymer and at least one polyhydric alcohol.A very particularly preferred embodiment relates to at least one gel phase or gel phases which contains / contain polyvinyl alcohol as polymer as described above in combination with polyethylene glycols. Particular preference is given to using polyethylene glycols having an average molar mass of between about 100 and about 2000 g / mol, preferably between 200 and 1000 g / mol, particularly preferably between 300 and 800 g / mol, for example around 400 g / mol of INCI: PEG400) in combination with polyvinyl alcohol.In particular, it is advantageous that the at least one gel phase comprising polyvinyl alcohol additionally comprise polyethylene glycols having an average molar mass of about 300 to 800 g / mol in amounts of 10 to 30% by weight, based on the total weight of the at least one gel phase. Surprisingly, it has been found that the addition of polyethylene glycols, in particular those having average molar masses of up to 800 g / mol, to the at least one gel phase leads to an acceleration of the solidification time of the gel phases. This is of great advantage in particular for the production-technology sequences, since the further processing of the gel phases in the solidified state can be carried out much more quickly and thus generally more cost-effectively.The at least one gel phase particularly preferably comprises at least one alkanetriol and / or at least one alkanediol, preferably at least one C 3- to C 6- alkanetriol and / or at least one C 3- to C 5- alkanediol as polyhydric alcohol. Preferably, it comprises an alkanetriol and an alkanediol as at least one polyhydric alcohol. Particular preference is given to a gel phase which comprises at least one (optionally acetalized) PVOH, and also a C 3- to C 5- alkanediol and a C 3- to C 6- alkanetriol.Surprisingly, it has been found that particularly short solidification times can be achieved when a corresponding triol (alkanetriol) is combined with a corresponding diol (alkanediol). The gel phases obtained are also transparent and have a glossy surface which provides an appealing visual impression of the cleaning agent according to the invention. The terms diol and alkanediol are used interchangeably herein. The same applies to triol and alkane triol.The amount of alkanediols and / or alkanetriols used in gel phases according to the invention is preferably at least 45 wt %, in particular 55 wt % or more. Preferred quantity ranges here are from 5 wt. % to 75 wt. %, in particular from 10 wt. % to 70 wt. %, based on the total weight of the gel phase.The C 3- to C 6- alkanetriol is particularly preferably glycerol and / or 2-ethyl-2-(hydroxymethyl)-1,3-propanediol (also referred to as 1,1,1-trimethylolpropane). The C 3- to C 5- alkanediol is preferably 1,3-propanediol and / or 1,2-propanediol. Surprisingly, it has been found that the chain length of the diol and, in particular, the position of the OH groups have an influence on the transparency of the gel phase. The OH groups of the diol are therefore preferably not arranged on directly adjacent C atoms. In particular, three or four carbon atoms, in particular 3 carbon atoms, are located between the two OH groups of the diol. The diol is particularly preferably 1,3-propanediol. Surprisingly, it has been found that particularly good results are achieved with mixtures comprising glycerol and 1,3-propanediol and / or 1,2-propanediol.If glycerol is present in the gel phase as alkanetriol, the proportion of glycerol, based on the total weight of the gel phase, is preferably 5 wt % to 70 wt %, in particular 10 wt % to 65 wt %, particularly 20 wt % to 40 wt %.If a plurality of alkanediols are optionally present in the gel phase, the proportion of alkanediols, based on the total weight of the gel phase, is preferably 5 wt % to 70 wt %, in particular 7 wt % to 65 wt %, particularly 10 wt % to 40 wt %.If the gel phase comprises at least one alkanediol, in particular 1,3-propanediol or 1,2-propanediol, the proportion of alkanediol, in particular 1,3-propanediol or 1,2-propanediol, based on the total weight of the gel phase, is preferably 5 wt % to 70 wt %, in particular 10 wt % to 65 wt %, particularly 20 wt % to 45 wt %. If 1,3-propanediol is contained in the gel phase, the proportion of 1,3-propanediol, based on the total weight of the gel phase, is in particular 10 wt. % to 65 wt. %, particularly 20 wt. % to 45 wt. %. Particular preference is given to a gel phase which comprises 20 to 45% by weight of 1,3-propanediol and / or 1,2-propanediol and 10% by weight to 65% by weight of glycerol, based in each case on the total weight of the gel phase.It has been found that in these regions rapid solidification at 20° C. of a gel phase is possible, and the phases obtained are storage-stable and transparent. In particular, the proportion of glycerin has an effect on the curing time.If the at least one gel phase according to the invention comprises a C 3- to C 6- alkanetriol and a C 3- to C 5- alkanediol, the weight ratio thereof is preferably 3:1 to 2:1. Surprisingly, it has been found that, at these weight ratios, storage-stable, glossy, transparent gel phases can be obtained within short solidification times at 20° C. of 10 minutes or less.Very particularly preferred embodiments of the present invention comprise the at least one gel phase phase 8 to 20% by weight of PVOH, 15 to 30% by weight of 1,3-propanediol, 30 to 40% by weight of glycerol, 5 to 15% by weight of polyacrylate copolymer containing sulfonic acid groups, and also 2-15% by weight of polyethylene glycol (preferably having an average molar mass of 200-600 g / mol), % by weight, in each case based on the total weight of the gel phase.The cleaning agent according to the invention preferably comprises at least one surfactant. This surfactant is selected from the group of anionic, nonionic and cationic surfactants.The detergent of the invention may also contain mixtures of a plurality of surfactants selected from the same group.According to the invention, the powder, the shaped body and / or optionally the gel phase(s) each comprise at least one surfactant. However, it is also possible for only the powder phase, the gel phase or the shaped body to comprise at least one surfactant. If at least two phases (powder, shaped bodies and / or gel phase(s)) comprise a surfactant, then these are preferably surfactants which differ from one another. However, it is also possible for the powder phase, shaped body and / or gel phase to have the same surfactant or surfactants. According to the invention, the at least one powder and / or at least one gel phase preferably comprise at least one nonionic surfactant. As nonionic surfactants, it is possible to use any nonionic surfactants known to the skilled worker. Preference is given to using low-foaming nonionic surfactants, especially alkoxylated, especially ethoxylated, low-foaming nonionic surfactants. These are specified in more detail below.A further class of nonionic surfactants preferably used, which are used either as the sole nonionic surfactant or in combination with other nonionic surfactants, are alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain.Also suitable are non-ionic surfactants of the amine oxide type, for example N-cocoalkyl-N,N-dimethylamine oxide and N-tallowalkyl-N,N-dihydroxyethylamine oxide, and of the fatty acid alkanolamides. The amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, especially not more than half thereof.With particular preference, the inventive cleaning compositions, in particular automatic dishwashing cleaning compositions, comprise nonionic surfactants from the group of alkoxylated alcohols. Nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and on average 1 to 12 mol of ethylene oxide (EO) per mol of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or can contain linear and methyl-branched radicals in a mixture, as are usually present in oxo alcohol radicals. In particular, however, alcohol ethoxylates with linear radicals from alcohols of native origin having 12 to 18 carbon atoms, for example from coconut alcohol, palm alcohol, tallow fatty alcohol or oleyl alcohol, and on average 2 to 8 mol of EO per mol of alcohol are preferred. Preferred ethoxylated alcohols include, for example, C 12-14- alcohols with 3 EO or 4 EO, C 8-11- alcohol with 7 EO, C 13-15- alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12-18- alcohols with 3 EO, 5 EO or 7 EO and mixtures thereof, such as mixtures of C 12-14- alcohol with 3 EO and C 12-18- alcohol with 5 EO.Preferred alcohol ethoxylates have a narrowed homolog distribution (narrow range ethoxylates, NRE). In addition to these nonionic surfactants, fatty alcohols having more than 12 EO can also be used. Examples thereof are tallow fatty alcohol having 14 EO, 25 EO, 30 EO or 40 EO.Ethoxylated nonionic surfactants which have been obtained from C 6-20- monohydroxyalkanols or C 6-20- alkyl phenols or C 16-20- fatty alcohols and more than 12 mol, preferably more than 15 mol and in particular more than 20 mol ethylene oxide per mol alcohol are particularly preferably used. A particularly preferred nonionic surfactant is obtained from a straight-chain fatty alcohol having 16 to 20 carbon atoms (C 16-20- alcohol), preferably a C 18- alcohol and at least 12 mol, preferably at least 15 mol and in particular at least 20 mol of ethylene oxide. Of these, the so-called narrow range ethoxylates are particularly preferred.Surfactants preferably to be used originate from the groups of alkoxylated non-ionic surfactants, in particular ethoxylated primary alcohols and mixtures of these surfactants with structurally complicated surfactants such as polyoxypropylene / polyoxyethylene / polyoxypropylene ((PO / EO / PO) surfactants). Such (PO / EO / PO) nonionic surfactants are furthermore distinguished by good foam control.Within the scope of the present invention, particularly preferred nonionic surfactants have proven to be the low-foaming nonionic surfactants which have alternating ethylene oxide and alkylene oxide units. Among these, surfactants having EO-AO-EO-AO blocks are again preferred, one to ten EO or AO groups each being bonded to one another before a block of the other groups follows. Preference is given here to nonionic surfactants of the general formula in which R 1 is a straight-chain or branched, saturated or else polyunsaturated C 6-24- alkyl or alkenyl radical; each group R 2 or R 3 is independently selected from -CH 3, - CH 2 CH 3, - CH 2 CH 2- CH3, -CH(CH3)2 and the indices w, x, y, z are independently of one another integers from 1 to 6.Preferred nonionic surfactants of the above formula can be prepared by known methods from the corresponding alcohols R 1- OH and ethylene oxide or alkylene oxide. The radical R 1 in the above formula may vary depending on the origin of the alcohol. If native sources are used, the radical R 1 has an even number of carbon atoms and is generally unbranched, with the linear radicals being preferred from alcohols of native origin having 12 to 18 C atoms, for example from coconut, palm, tallow fat or oleyl alcohol. Alcohols obtainable from synthetic sources are, for example, the Guerbet alcohols or 2-methyl-branched or linear and methyl-branched radicals in a mixture, as are usually present in oxo alcohol radicals. Regardless of the type of alcohol used to prepare the nonionic surfactants present in the compositions, nonionic surfactants are preferred in which R 1 in the above formula represents an alkyl radical having 6 to 24, preferably 8 to 20, particularly preferably 9 to 15 and in particular 9 to 11 carbon atoms.Suitable alkylene oxide unit which is present in the preferred nonionic surfactants in alternation with the ethylene oxide unit is, in addition to propylene oxide, in particular butylene oxide. However, other alkylene oxides in which R 2 or R 3 are selected independently of one another from -CH 2 CH 2- CH 3 or -CH(CH 3)2 are also suitable. Preference is given to using nonionic surfactants of the above formula in which R 2 or R 3 is a radical -CH 3, w and x are, independently of one another, values of 3 or 4 and y and z are, independently of one another, values of 1 or 2.Further nonionic surfactants preferably used are nonionic surfactants of the general formula R 1 O(AlkO) x M(OAlk) y OR 2, where R 1 and R 2 independently of one another are a branched or unbranched, saturated or unsaturated, optionally hydroxylated alkyl radical having 4 to 22 carbon atoms; Alk is a branched or unbranched alkyl radical having 2 to 4 carbon atoms; x and y independently of one another are values between 1 and 70; and M is an alkyl radical from the group consisting of CH 2, CHR 3, CR 3 R 4, CH 2 CHR 3 and CHR 3 CHR 4 where R 3 and R 4 independently of one another are a branched or unbranched, saturated or unsaturated alkyl radical having 1 to 18 carbon atoms.Preference is given here to nonionic surfactants of the general formula R 1- CH(OH)CH 2- O(CH 2 CH 2 O) x CH 2 CHR(OCH 2 CH 2)y- CH 2 CH(OH)-R 2, where R, R_NER190 and R_NER191 are each independently of the other an alkyl radical or alkenyl radical having 6 to 22 carbon atoms; x and y are each independently of the other values between 1 and 40.Preference is given here in particular to compounds of the general formula R 1- CH(OH)CH 2- O(CH 2 CH 2 O) x CH 2 CHR(OCH 2 CH 2)y O-CH 2 CH(OH)-R 2, in which R is a linear, saturated alkyl radical having 8 to 16 carbon atoms, preferably 10 to 14 carbon atoms, and n and m independently of one another have values of 20 to 30. Corresponding compounds can be obtained, for example, by reaction of alkyldiols HO-CHR-CH 2- OH with ethylene oxide, with subsequent reaction with an alkyl epoxide to close off the free OH functions, with formation of a dihydroxy ether.Preferred nonionic surfactants here are those of the general formula R 1- CH(OH)CH 2 O-(AO) w-( AO) x-( A"O) y-( A"'O) z- R 2, in whichR 1 is a straight-chain or branched, saturated or mono- or polyunsaturated C 6-24- alkyl or alkenyl radical;R 2 is hydrogen or a linear or branched hydrocarbon radical having 2 to 26 carbon atoms;A, A', A" and A"' independently of one another represent a radical from the group -CH 2 CH 2, - CH 2 CH 2- CH 2, - CH 2- CH(CH 3), - CH 2- CH 2- CH 2- CH2, -CH2-CH(CH3)-CH2-, -CH2-CH(CH2-CH3),w, x, y and z are values between 0.5 and 120, where x, y and / or z can also be 0.By adding the abovementioned nonionic surfactants of the general formula R 1- CH(OH)CH 2 O-(AO) w-( A'O) x-( A"O) y-( A"'O) z- R 2, also referred to below as "mixed hydroxy ethers", it is surprisingly possible to improve the cleaning performance of preparations according to the invention significantly, both in comparison with surfactant-free systems and in comparison with systems which comprise alternative nonionic surfactants, for example from the group of polyalkoxylated fatty alcohols.Preference is given in particular to those end group-terminated poly(oxyalkylated) nonionic surfactants which, according to the following formula have, in addition to a radical R 1, which is linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having 2 to 30 carbon atoms, preferably having 4 to 22 carbon atoms, also a linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radical R 2 having 1 to 30 carbon atoms, where n is values between 1 and 90, preferably values between 10 and 80 and in particular values between 20 and 60. Particularly preferred are surfactants of the above formula wherein R 1 is C 7 to C 13, n is an integer from 16 to 28, and R 2 is C 8 to C 12.Particularly preferred surfactants are those of the formula R 1 O[CH 2 CH(CH 3) O] x[ CH 2 CH 2 O] y CH 2 CH(OH)R 2, in which R 1 represents a linear or branched aliphatic hydrocarbon radical having 4 to 18 carbon atoms or mixtures thereof, R_NER3-denotes a linear or branched hydrocarbon radical having 2 to 26 carbon atoms or mixtures thereof and x represents values between 0.5 and 1.5 and y represents a value of at least 15. The group of these nonionic surfactants includes, for example, the C 2-26 fatty alcohol (PO) 1-( EO) 15-40-2- hydroxyalkyl ethers, in particular also the C 8-10 fatty alcohol (PO) 1-( EO) 22-2- hydroxydecyl ethers.Particular preference is furthermore given to those end group-capped poly(oxyalkylated) nonionic surfactants of the formula R 1 O[CH 2 CH 2 O] x[ CH 2 CH(R 3) O] y CH 2 CH(OH)R 2, in which R 1 and R2each independently represents a linear or branched, saturated or mono- or polyunsaturated hydrocarbon radical having 2 to 26 carbon atoms, R3each independently is selected from -CH3, -CH2CH3, -ch_ner279_ch_ner280_-ch 3, -ch(ch_ner281_)_ner282_, but preferably -CH 3 and x and y independently of one another are values between 1 and 32, very particular preference being given to non-surfactants where R is 3= - CH 3 and values for x from 15 to 32 and y from 0.5 and 1.5.Further preferred non-ionic surfactants that can be used are the end group-capped poly(oxyalkylated) non-ionic surfactants of the formula R 1 O[CH 2 CH(R 3) O] x[ CH 2]k CH(OH)[CH 2]j OR 2, in which R 1 and R 2 are linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having 1 to 30 carbon atoms, R 3 is H or a methyl, ethyl, n-propyl, isopropyl, n-butyl, 2-Butyl or 2-methyl-2-butyl radical, x are values between 1 and 30, k and j are values between 1 and 12, preferably between 1 and 5.When the value x>2, each R 3 in the above formula R 1 O[CH 2 CH(R 3) O] x[ CH 2]k CH(OH)[CH 2]j OR 2 may be different. R 1 and R 2 are preferably linear or branched, saturated or unsaturated, aliphatic or aromatic hydrocarbon radicals having 6 to 22 carbon atoms, particular preference being given to radicals having 8 to 18 carbon atoms. For the radical R 3 particular preference is given to H, -CH 3 or -CH 2 CH 3. Particularly preferred values for x are in the range from 1 to 20, in particular from 6 to 15.As described above, each R 3 in the above formula may be different if x > 2. As a result, the alkylene oxide unit in the square bracket can be varied. For example, if x is 3, the radical R 3 can be selected to form ethylene oxide (R 3= H) or propylene oxide (R 3= CH 3) units which can be joined together in any order, for example (EO)(PO)(EO), (EO)(EO)(PO), (EO)(EO)(EO), (PO)(EO)(PO), (PO)(PO)(EO) and (PO)(PO)(PO). The value 3 for x has been chosen here as an example and can be quite larger, wherein the range of variation increases with increasing x values and includes, for example, a large number of (EO) groups, combined with a small number of (PO) groups, or vice versa.Particularly preferred end group-capped poly(oxyalkylated) alcohols of the above formula have values of k=1 and j=1 so that the above formula is simplified to R 1 O[CH 2 CH(R 3) O] x CH 2 CH(OH)CH 2 OR 2. In the latter formula, R 1, R 2 and R 3 are as defined above and x is numbers from 1 to 30, preferably from 1 to 20 and in particular from 6 to 18. Finally, the nonionic surfactants of the general formula R 1- CH(OH)CH 2 O-(AO) w- R 2 in whichR 1 is a straight-chain or branched, saturated or mono- or polyunsaturated C 6-24-alkyl or alkenyl radical;R 2 is a linear or branched hydrocarbon radical having 2 to 26 carbon atoms;a is a radical from the group consisting of CH 2 CH 2, CH 2 CH 2 CH 2, CH 2 CH(CH 3), preferably CH 2 CH 2 andw is a value between 1 and 120, preferably 10 to 80, in particular 20 to 40.The group of these nonionic surfactants includes, for example, the C 4-22 fatty alcohol (EO) 10-80-2- hydroxyalkyl ethers, in particular also the C 8-12 fatty alcohol (EO) 22-2- hydroxydecyl ethers and the C 4-22 fatty alcohol (EO) 40-80-2- hydroxyalkyl ethers.The at least one first and / or the at least one gel phase preferably comprises at least one nonionic surfactant, preferably a nonionic surfactant from the group of the mixed hydroxy ethers, wherein the proportion by weight of the nonionic surfactant based on the total weight of the gel phase is preferably 0.5% by weight to 30% by weight, preferably 5% by weight to 25% by weight and in particular 10% by weight to 20% by weight.In a further preferred embodiment, the nonionic surfactant of the first and / or gel phase is selected from nonionic surfactants of the general formula R 1- O(CH 2 CH 2 O) x CR 3 R 4( OCH 2 CH 2)y O-R 2, in which R 1 and R_NER365 are each independently of one another an alkyl radical or alkenyl radical having 4 to 22 carbon atoms; R 3 and R 4 independently of one another, are H or an alkyl radical or alkenyl radical having 1 to 18 carbon atoms and x and y independently of one another are values between 1 and 40.Preference is given here in particular to compounds of the general formula R 1- O(CH 2 CH 2 O) x CR 3 R 4( OCH 2 CH 2)y O-R 2, in which R 3 and R4represent H and the indices x and y independently of one another assume values from 1 to 40, preferably from 1 to 15.Particular preference is given in particular to compounds of the general formula R 1- O(CH 2 CH 2 O) x CR 3 R 4( OCH 2 CH 2)y O-R 2, in which the radicals R 1 and R_NER391 independently of one another represent saturated alkyl radicals having 4 to 14 carbon atoms and the indices x and y independently of one another assume values from 1 to 15 and in particular from 1 to 12.Preference is furthermore given to those compounds of the general formula R 1- O(CH 2 CH 2 O) x CR 3 R 4( OCH 2 CH 2)y O-R 2, in which one of the radicals R 1 and R2branched.Very particular preference is given to compounds of the general formula R 1- O(CH 2 CH 2 O) x CR 3 R 4( OCH 2 CH 2)y O-R 2, in which the indices x and y independently of one another assume values from 8 to 12.The indicated C chain lengths and degrees of ethoxylation or degrees of alkoxylation of the nonionic surfactants represent statistical averages which can be an integer or a fractional number for a specific product. On account of the preparation processes, commercial products of the formulae mentioned usually consist not of an individual representative but of mixtures, as a result of which averages and numbers fractional as a result can be obtained both for the C chain lengths and for the degrees of ethoxylation or alkoxylation.It goes without saying that the abovementioned nonionic surfactants (nonionic surfactants) can be used not only as individual substances but also as surfactant mixtures of two, three, four or more surfactants.Particular preference is given to those nonionic surfactants which have a melting point above room temperature. Nonionic surfactant(s) having a melting point above 20° C., preferably above 25° C., particularly preferably between 25 and 60° C., and in particular between 26.6 and 43.3° C., is / are particularly preferred.Suitable nonionic surfactants which have melting or softening points in the temperature range mentioned are, for example, low-foaming nonionic surfactants which can be solid or highly viscous at room temperature. If nonionic surfactants which are highly viscous at room temperature are used, it is preferred that they have a viscosity above 20 Pa·s, preferably above 35 Pa·s and in particular above 40 Pa·s. Nonionic surfactants which have a wax-like consistency at room temperature are also preferred.The nonionic surfactant which is solid at room temperature preferably has propylene oxide units (PO) in the molecule. Preferably, such PO units constitute up to 25 wt %, more preferably up to 20 wt %, and most preferably up to 15 wt %, of the total molecular weight of the nonionic surfactant. Particularly preferred nonionic surfactants are ethoxylated monohydroxyalkanols or alkyl phenols which additionally have polyoxyethylene-polyoxypropylene block copolymer units. The alcohol or alkylphenol part of such nonionic surfactant molecules preferably constitutes more than 30% by weight, more preferably more than 50% by weight and in particular more than 70% by weight, of the total molar mass of such nonionic surfactants. Preferred agents are characterized in that they contain ethoxylated and propoxylated nonionic surfactants in which the propylene oxide units in the molecule make up up up to 25 wt %, preferably up to 20 wt % and in particular up to 15 wt % of the total molar mass of the nonionic surfactant.Further particularly preferably used nonionic surfactants having melting points above room temperature contain 40 to 70% of a polyoxypropylene / polyoxyethylene / polyoxypropylene block polymer blend which contains 75% by weight of an inverted block copolymer of polyoxyethylene and polyoxypropylene with 17 mol of ethylene oxide and 44 mol of propylene oxide and 25% by weight of a block copolymer of polyoxyethylene and polyoxypropylene initiated with trimethylolpropane and containing 24 mol of ethylene oxide and 99 mol of propylene oxide per mol of trimethylolpropane.In a preferred embodiment, the proportion by weight of the nonionic surfactant relative to the total weight of the single-part detergent portion is from 0.1 to 20% by weight, particularly preferably from 0.5 to 15% by weight, in particular from 1.5 to 10% by weight.Suitable anionic surfactants in the dishwashing detergents are all anionic surface-active substances. These are characterized by a water-solubilizing anionic group, such as a carboxylate, sulfate, sulfonate or phosphate group, and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Suitable anionic surfactants are preferably present in the form of the sodium, potassium and ammonium salts and of the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group, but zinc, manganese(II), magnesium, calcium or mixtures thereof can also serve as counterions.Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule.Instead of the said surfactants or in combination with them, cationic and / or amphoteric surfactants, such as betaines or quaternary ammonium compounds, can also be used. It is preferred, however, that no cationic and / or amphoteric surfactants are used.Preferred cleaning agents according to the invention are further characterized in that they contain less than 5.0% by weight of anionic surfactant in the at least one powder phase, the at least one shaped body and / or the at least one gel phase, in particular in the powder phase, very particularly preferably in the entire cleaning agent, since the addition of anionic surfactants has proven to be disadvantageous with regard to the phase properties, in particular their hardness, friability (abrasion behavior) and post-curing behavior.Substances which also serve as ingredients of cosmetic agents are referred to below, if appropriate, according to the International Nomenclature Cosmetic Ingredient (INCI) nomenclature. Chemical compounds bear an INCI name in English language. The INCI names are given in the International Cosmetic Ingredient Dictionary and Handbook, 7th Edition (1997), edited by The Cosmetic, Toiletry and Fragrance Association (CTFA), Washington, D.C. (USA). The specification CAS means that the following numerical sequence is a designation of the chemical abstract service.The cleaning agents according to the invention contain the ingredients known to the skilled person, in particular those for automatic dishwashing agents, such as builder substances, bleaches, bleach activators, bleach catalysts, enzymes, in particular proteases and / or amylases, and also dispersion polymers. In addition, pH adjusters, glass corrosion inhibitors, further solvents, thickeners, sequestrants, electrolytes, corrosion inhibitors, in particular silver preservatives, glass corrosion inhibitors, foam inhibitors, dyes, fragrances (in particular in the powder), additives for improving the run-off and drying behavior, preservatives, antimicrobial active ingredients (disinfectants) can be present in amounts of usually not more than 5 wt %.The cleaning agent according to the invention comprises at least one powder and at least one gel phase. The cleaning agent may have one, two, three or more powders different from one another, which are present as separate phases; likewise, it may have one, two, three or more gel phases present separately from one another, which may be the same or may be distinguishable with regard to colour, shape and / or chemical composition. The cleaning agent particularly preferably comprises a shaped body, a powder and at least two gel phases. Furthermore, an embodiment is preferred in which the cleaning agent single portion comprises a powder, a shaped body and three or four gel phases.According to the invention, the at least one powder and the at least one gel phase are contiguous to one another over the full or partial area. It is preferred that the two phases are immediately adjacent to each other. If the at least one powder and the at least one gel phase directly border one another over their full or partial area, stability is important in addition to the shortest possible solidification time of the at least one gel phase. Stability here means that constituents contained in the gel phase do not pass into the at least one powder phase, but rather, even after prolonged storage, the powders and the at least one gel phase are present optically separate from one another and do not interact with one another, such as, for example, diffusion of liquid constituents from one phase into the other phase or reaction of constituents of one phase with those in the other phase. Surprisingly, it has been found that this can be made possible by a gel phase which comprises glycerol, at least one C 3- to C 5- alkanediol, or glycerol, PVOH and at least one C 3- to C 5- alkanediol.In a particularly preferred embodiment, the inventive cleaning agent single portion in the receiving chamber comprising the inventive cleaning agent composition comprising at least one powder, at least one shaped body different from the powder and at least one gel phase does not comprise any phases which are liquid at 20° C., 1 bar. The phases present (powders, shaped bodies and gel phase(s)) are solid at 20° C., 1 bar in order to avoid mixing and / or dissolution of individual active substances and / or phases and to give rise to the advantages realized by the present invention. If liquid phases are actually desired, these must be accommodated in other chambers of the single-part detergent portion.The present application further relates to a method for cleaning hard surfaces, in particular dishes, in which the surface is processed in a manner known per se using a cleaning agent according to the invention. In particular, the surface is brought into contact with the cleaning agent according to the invention. The cleaning is effected in particular with a cleaning machine, preferably with a dishwasher.The present invention also relates to the use of a cleaning agent for cleaning hard surfaces, in particular dishes, in particular in automatic dishwashers.The present application relates in a preferred embodiment to automatic dishwashing agents. Automatic dishwashing agents in accordance with this application are compositions which can be used for cleaning soiled dishes in an automatic dishwashing process. The automatic dishwashing agents according to the invention thus differ, for example, from the automatic final rinse agents, which are always used in combination with automatic dishwashing agents and do not develop their own cleaning effect.The present application further provides a method for producing a previously described single portion of the cleaning agent according to the invention, comprising the following steps i) providing a water-soluble receiving chamber; ii) introducing at least one gel phase into the receiving chamber; iii) filling at least one powder into the receiving chamber; iv) applying a shaped body to the powder; v) closing the filled receiving chamber with a water-soluble closure element.A number of different methods are suitable for producing the water-soluble receiving chamber, including the pouring or compacting of water-soluble, optionally washing- or cleaning-active substances or substance mixtures. However, due to the high process efficiency, injection molding of water-soluble material and, in particular, deep drawing of water-soluble films to provide the water-soluble accommodation chamber are preferred.The water-soluble material or film forming the receiving chamber may comprise one or more structurally different water-soluble polymer(s). Particularly suitable water-soluble polymer(s) are water-soluble polymers from the group of (optionally acetalized) polyvinyl alcohols (PVOH) and copolymers thereof.Water-soluble films for producing the water-soluble packaging are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range from 10,000 to 1,000,000 gmol -1, preferably from 20,000 to 500,000 gmol -1, particularly preferably from 30,000 to 100,000 gmol -1 and in particular from 40,000 to 80,000 gmol -1.The preparation of the polyvinyl alcohol and polyvinyl alcohol copolymers typically involves the hydrolysis of intermediate polyvinyl acetate. Preferred polyvinyl alcohols and polyvinyl alcohol copolymers have a degree of hydrolysis of 70 to 100 mol %, preferably 80 to 90 mol %, particularly preferably 81 to 89 mol % and in particular 82 to 88 mol %.Preferred polyvinyl alcohol copolymers comprise, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters. Particularly preferably, such polyvinyl alcohol copolymers contain, in addition to vinyl alcohol, sulfonic acids such as 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), acrylic acid, methacrylic acid, acrylic esters, methacrylic esters or mixtures thereof; among the esters, C 1-4- alkyl esters or hydroxyalkyl esters are preferred. Other suitable monomers are ethylenically unsaturated dicarboxylic acids, for example itaconic acid, maleic acid, fumaric acid and mixtures thereof.Suitable water-soluble films for use in the water-soluble packaging according to the invention are films which are sold by the company MonoSol LLC, for example under the name M8630, M8720, M8310, C8400 or M8900. Other suitable films include Solublon® PT, Solublon® GA, Solublon® KC, or Solublon® KL film from Aicello Chemical Europe GmbH, or VF-HP film from Kuraray, as well as the Hi-Selon Series from Mitsubishi Chemical Corporation.The water-soluble films can contain additional active substances or fillers as further ingredients, but also plasticizers and / or solvents, in particular water.The group of further active ingredients includes, for example, materials which protect the ingredients of the laundry detergent enclosed by the film material from decomposition or deactivation by light irradiation. Antioxidants, UV absorbers and fluorescent dyes have proven particularly suitable here.Examples of plasticizers which can be used are glycerol, ethylene glycol, diethylene glycol, propanediol, 2-methyl-1,3-propanediol, sorbitol or mixtures thereof.To reduce their coefficients of friction, the surface of the water-soluble film of the detergent portion unit may optionally be powdered with fine powder. Sodium aluminosilicate, silica, talc and amylose are examples of suitable powders.The single-part cleaning agent portions according to the invention comprise at least one powder and at least one shaped body different from the powder, wherein powder and shaped body are supplemented by at least one gel phase in a preferred embodiment. As described above, the gel phase is different from the powder and the molded body.The gel phase is preferably introduced into the receiving chamber before the powder. The number of gel phases introduced into the receiving chamber can vary. For example, in step ii) of the method, only a single gel phase can be introduced into the receiving chamber. Alternatively and because of the increase in the regulatory degrees of freedom and the improved product optics, in step ii) two gel phases or three gel phases or four gel phases can be introduced into the receiving chamber. The two, three, four or more gel phases preferably differ in terms of their composition and comprise, for example, different active substances, have different active substance contents or different colors.If more than one gel phase, i.e. for example two or three or four gel phases, are introduced into the receiving chamber in step ii), these two or three or four gel phases are preferably introduced into the receiving chamber in such a way that they are not in direct contact with one another. This procedure avoids undesired reactions between individual active ingredients contained in the different gel phases and improves the optical properties of the product.In step iii) of the method, at least one powder is introduced into the receiving chamber. If one or more gel phases have been introduced into the receiving chamber in the preceding step, the powder is preferably introduced into the receiving chamber in step iii) in such a way that the surface of the gel phase(s) facing the opening of the receiving chamber is completely covered with powder.For the efficient filling of the receiving chambers with the powder, it has proven advantageous if the powder has a flowability of greater than 40%, preferably of greater than 50%, in particular of greater than 60%, based on the standard.The flowability of the powder relates to its ability to free flow under its own weight. The flowability is determined by measuring the outflow time of 1000 ml of detergent powder from a standardized trickle test funnel which is initially closed at its outflow direction and has an outflow of 16.5 mm diameter by measuring the time for complete outflow of the granular mixture, in particular of the pulverulent phase, preferably of the powder and / or granulate, for example of the powder after opening of the outflow, and comparing it with the outflow speed (in seconds) of a standard test sand whose outflow speed is defined as 100%. The defined sand mixture for calibrating the shower apparatus is dry sea sand. Sea sand with a particle diameter of 0.4 to 0.8 mm is used, available for example from Carl Roth, Germany CAS-No. [14808-60-7]. For drying, the sea sand is dried for 24 h at 60° C. in a drying cabinet on a plate at a maximum layer height of 2 cm, before the measurement.Preferred embodiments of the powders according to the invention have an angle of pouring / embankment of 26 to 35, 27 to 34, 28 to 33, the angle of pouring being determined according to the method mentioned below after 24 h after the preparation of the granular mixture of the solid composition, in particular of the pulverulent solid phase, preferably of the powder and / or granulate, and storage at 20° C. Such angle of inertia have the advantage that the filling of the cavities with the at least one solid phase can take place comparatively quickly and precisely.To determine the angle of pouring (or also called angle of slope) of the powder, a powder funnel with 400 ml content and a drain with a diameter of 25 mm is suspended just in a stand. The hopper is moved upwards at a speed of 80 mm / min by means of a knurl wheel to be operated manually, so that the granular mixture, in particular the powdered phase, preferably the powder and / or granulate, e.g. the powder, runs out. This forms a so-called bulk cone. The cone height and cone diameter are determined for the individual particulate phases. The angle of slope is calculated from the quotient of the height of the cone and the diameter of the cone *100.Particularly suitable powders are those which have a flowability in % to the above-specified standard test substance of greater than 40%, preferably greater than 50, in particular greater than 55%, particularly preferably greater than 60%, in particular preferably between 63% and 80%, for example between 65% and 75%. Particularly suitable are granular mixtures of a solid composition, in particular powders and / or granules which have a flowability in % to the above-specified standard test substance of greater than 40%, preferably greater than 45%, in particular greater than 50%, particularly preferably greater than 55%, in particular preferably greater than 60%, the flowability being measured at 20° C. for 24 h after the production of the powder and storage.Lower values for flowability are rather not suitable, since from the process standpoint, precise metering of the powder is necessary. In particular, the values greater than 50%, in particular greater than 55%, preferably greater than 60% (wherein the measurement of the flowability is carried out 24 h after the production of the powder and storage at 20° C.) have proven advantageous since the good meterability of the granular mixture, in particular of the powder phases, preferably of the powders and / or granules, e.g. powder, results in only slight fluctuations in the metered amount or the composition. The more precise metering leads to a constant product performance, economic losses due to overdosing being avoided in this way. It is furthermore advantageous that the granular mixture, in particular the powdered phase, preferably the powder and / or granulate, e.g. the powder, can be readily metered, thus achieving a more rapid course of the metering process. Furthermore, such good flowability better prevents the powder from reaching the part of the water-soluble envelope which is necessary for producing the sealed seam.The filling degree of the receiving chamber is preferably above 60% by volume, in particular above 70% by volume, following step iii).In step iv) following step iii), the shaped body is applied to the powder. This is preferably effected in such a way that the surface of the powder facing the opening of the receiving chamber is covered by the molded body to an extent of more than 75%, preferably to an extent of more than 75%, preferably to an extent of more than 75%, in particular to an extent of more than 80% and very particularly preferably to an extent of more than 85%.The application in step iv) can be obtained by applying preformed shaped bodies or by applying them in situ by solidification of a flowable melt or a flowable gel.The shaped body applied to the powder in step iv) is preferably preformed, i.e. is not obtained in situ in step iv) by solidification of a flowable melt or a flowable gel.The three-dimensional shape of the shaped body is basically freely selectable; its side surfaces can be designed, for example, convex, concave or planar. At the same time, however, certain spatial configurations have proven to be particularly advantageous in view of the matable nature and processing of the shaped bodies.The shaped bodies used in step iv) preferably have a flat underside, the greatest diagonal of which is greater than the height of the shaped body, the shaped body being applied with the flat underside to the surface of the powder. Corresponding shaped bodies can be produced not only in a simple manner, for example by means of casting methods or tabletting, but can also be applied mechanically to the powder in a simple manner. It is preferred if the shaped body in step iv) has a flat underside, the greatest diagonal of which is more than 1.5 times, preferably more than 2 times, the height of the shaped body, the shaped body being applied with the flat underside to the surface of the powder.For the manufacturing ability, for example with regard to demolding the molded body from a casting mold, it has proven advantageous if the underside of the gel body has no corners. Preferred gel bodies are therefore characterized by oval undersides or alternatively by ellipsoidal or round, preferably round undersides. Corresponding shaped bodies with a non-angular underside are also preferred by many consumers because of their optics. Preferred are therefore, for example, those shaped bodies which have an underside and an upper side which are connected to one another by a cylindrical lateral surface.In Preferred Process Variantsthe shaped body in step iv) has an oval bottom side and the shaped body is applied with the flat bottom side to the surface of the powder, orthe shaped body in step iv) has an ellipsoidal or round, preferably a round, underside and the shaped body is applied with the round underside to the surface of the powder.Advantages with regard to the use of space during production and packaging can be realized by angular shaped bodies. If the shaped bodies are cast, for example, in the form of sheets which are subsequently cut into shaped bodies, angular undersides are advantageous since such shaped bodies can be cut without the occurrence of residual quantities. In an alternative embodiment of the method, the shaped bodies used in step iv) therefore have angular undersides, in particular triangular, quadrangular or hexagonal undersides, and are applied to the surface of the powder with these undersides. For further processing or packaging, it can be advantageous if the shaped body has an angular underside with rounded corners.With regard to the production, packaging and use of the detergent portion units, it has additionally proven advantageous if the shaped body applied to the powder with its underside in step iv) has an upper side which is plane-parallel to the underside.In a first preferred geometric embodiment, the molded body has an underside and an upper side which have the same geometric shape, wherein the underside and the upper side have the same surface area. Corresponding shaped bodies can be produced in a simple manner, as already described above, for example by casting sheets and subsequently cutting the sheets to form individual gel bodies. During the application, preferably application, to the powder in step iv), these shaped bodies can additionally be spatially oriented in a simpler manner by being laid out than shaped bodies with a lower body symmetry. This applies in particular to shaped bodies which simultaneously have an upper side which is plane-parallel to the underside. Examples of such shaped bodies are circular cylinders, elliptical cylinders, parallelepipeds, rhombohedrons, straight or oblique prisms, cuboids or cubes. The group of circular cylinders and elliptical cylinders again includes the perpendicular circular cylinders and elliptical cylinders and the oblique circular cylinders and elliptical cylinders. Because of their simple production by separation from a plate, molded bodies in the form of vertical circular cylinders, vertical elliptical cylinders, straight prisms, straight cuboids or cubes are preferred.In an alternative embodiment, the molded body has an underside and an upper side which have the same geometric shape, wherein the underside and the upper side have different surface sizes. Corresponding shaped bodies may be preferred on account of their attractive appearance or their optimized fit with at the same time comparatively simple production. Examples of such shaped bodies are circular cylinders or elliptical cylinders with a convex or concave underside and a planar upper side or with a planar underside and a convex or concave upper side. Further examples are truncated cones or truncated pyramids.In order to realize the reduced contact surface between powder and inner side of the closure element, which is characteristic of the subject matter of the application, it is preferred in step iv) to place a shaped body on the powder, the underside of which shaped body has an outline which simulates the opening surface of the receiving chamber and the underside of the shaped body is applied to the surface of the powder.A two-dimensional shape, in this case the contour of the underside of the molded body, is referred to as replication, which shape is equal to the two-dimensional shape of a further surface, in this case the contour of the opening surface of the receiving chamber, for example in terms of the number of corners present or the ratio of the side lengths or the radii of curvature of the sides or corners.If, in step iv), a shaped body is applied to the powder, the underside of which has an outline which simulates the outline of the opening area of the receiving chamber, this shaped body generally has an outline area for its underside which is smaller than the outline area of the receiving chamber opening. In preferred process variants, the shaped body in step iv) therefore has a bottom side, the contour of which is obtained from the contour of the opening surface of the receiving chamber by reduction by a factor of from 0.75 to 0.98, the shaped body being applied with the bottom side to the surface of the powder.The filling degree of the receiving chamber is preferably above 85% by volume, in particular above 94% by volume, after step iv).The filled water-soluble receiving chamber is preferably sealed with a water-soluble film in step v).When the water-soluble accommodation chamber provided in step i) is obtained by deep drawing a first water-soluble film and sealed with a second water-soluble film in step v), it is preferable that the second water-soluble film has a thickness smaller than that of the first water-soluble film to reduce the amount of the film used.In such a case, the first water-soluble film preferably has a thickness of 60 to 2000 μm and the second water-soluble film has a thickness of 40 to 120 μm. It is particularly preferred if the second water-soluble film has a thickness of 80 μm or less, preferably of 70 μm or less, in particular of 65 μm or less, very particularly preferably of 55 μm or less. Such small film thicknesses can be realized in the method according to the invention, despite the filling of the water-soluble receiving chamber with powder, without loss of mechanical stability of the single portion of the cleaning agent, for example caused by the piercing of the closure film by individual powder particles, even when shrink methods are used, since the closure film is only in very little contact with the powder due to the use of the applied molded body.In view of the mechanical stability of the single portion of the cleaning agent with at the same time little use of packaging agents, it is preferred if the ratio of the thickness of the first water-soluble film to the thickness of the second water-soluble film is from 3:1 to 1:1, preferably from 2.5:1 to 1.1:1, in particular from 2:1 to 1.2:1.To improve the product chemistry and product appearance, the sealed filled receiving chamber is heated after step v) in a further step vi) for a period of time of 0.5 to 20 seconds to temperatures above 120° C., preferably to temperatures in the range of 140 to 220° C. The heat treatment shrinks the water-soluble packaging material used, in particular the water-soluble film used. The cleaning agent single portion increases in stability and penetration of the powder between the molded body and the inside of the closure element is prevented.In summary, this application provides, inter alia, the following articles: 1. single-part detergent composition comprising a) a water-soluble packaging comprising a1) at least one water-soluble receiving chamber a2), a water-soluble closure element b) closing this water-soluble receiving chamber, a phosphate-free detergent composition comprising b1) at least one gel phase b2), at least one powder, b3) at least one shaped body different from the powder, wherein the shaped body comprises at least one aminocarboxylic acid and / or a salt thereof. 2. detergent single portion according to item 1, characterized in that the aminocarboxylic acid is selected from methylglycinediacetic acid and its salts, glutaminediacetic acid and its salts, and ethylenediaminedisuccinic acid and its salts, particularly preferably methylglycinediacetic acid and its salts. 3.A single cleaning agent portion according to one of the preceding points, characterized in that the amount of the aminocarboxylic acid or the aminocarboxylic acid salt thereof, based on the total weight of the molded body, is from 20 to 65 wt.%, preferably from 22 to 60 wt.%, particularly preferably from 26 to 55 wt.%. 4. single cleaning agent portion according to one of the preceding points, characterized in that the aminocarboxylic acid or the aminocarboxylic acid salt is selected from methylglycinediacetic acids and their salts, particularly preferably the trisodium salt of methylglycinediacetic acid, and the amount thereof, based on the total weight of the molded body, is from 20 to 65 wt %, preferably from 27 to 60 wt %, particularly preferably from 30 to 55 wt %. 5. single cleaning agent portion according to one of the preceding points, characterized in that the aminocarboxylic acids and / or their salts are present in the shaped body with an average particle size of ≤250 μm, preferably of ≤200 μm. 6.A single cleaning agent portion according to any of the preceding points, characterized in that the aminocarboxylic acids and / or their salts are present in the shaped body having an average particle size of 40 to 160 μm, preferably of 50 to 150 μm. 7. single cleaning agent portion according to one of the preceding points, characterized in that the powder, based on the total weight of the powder, contains less than 10 wt %, preferably less than 5 wt %, in particular less than 1 wt %, aminocarboxylic acids and / or their salts. 8. detergent single portion according to one of the preceding points, characterized in that the shaped body comprises polyalkylene glycols, preferably polyethylene glycols. 9. cleaning agent single portion according to item 8, characterized in that the molded body comprises polyalkylene glycols, preferably polyethylene glycols, which have a melting point of 25 to 80° C., preferably of 30 to 70° C., particularly preferably of 45 to 65° C. at normal pressure. 10. detergent single portion according to either of Items 8 and 9, characterized in that the shaped body comprises polyalkylene glycols, preferably polyethylene glycols, having an average molecular weight of 1000 to 10000 g / mol, preferably 2000 to 8000, particularly preferably 3000 to 6000 g / mol, for example 4000 g / mol. 11.Single-part detergent composition according to any of the above items 8 to 10, characterized in that the amount of polyalkylene glycols, preferably polyethylene glycols, in the shaped body is from 20 to 50% by weight, preferably from 22 to 40% by weight, in particular preferably from 25 to 35% by weight, based on the total weight of the shaped body. 12.A single cleaning agent portion according to one of the preceding points, characterised in that the shaped body contains surfactants, preferably non-ionic surfactants. 13.Single cleaning agent portion according to item 12, characterized in that the amount of the surfactants, preferably nonionic surfactants, based on the total weight of the shaped body, is from 5 to 50% by weight, preferably from 10 to 45% by weight, in particular preferably from 15 to 40% by weight. 14. cleaning agent single portion according to any of the above items 12 to 13, characterized in that the proportion of anionic surfactants in the shaped body and / or in the cleaning agent portion is less than 5 wt %, particularly preferably less than 1 wt %, in each case based on the total weight of the shaped body or the cleaning agent portion. 15. detergent single portion according to any of the above items 12 to 14, characterized in that the nonionic surfactants are selected from alkoxylated, preferably ethoxylated or ethoxylated and propoxylated fatty acid alkyl esters, preferably poly(oxyalkylated) nonionic surfactants of the formula R 1 O[CH 2 CH(CH 3) O] x[ CH 2 CH 2 O] y[ CH 2 CH(CH 3) O] z CH2CH(OH)R_NER #1_where R_NER #1_represents a linear or branched aliphatic hydrocarbon radical having 4 to 22 carbon atoms, R_NER #2_represents a linear or branched hydrocarbon radical having 2 to 26 carbon atoms, x and z are values from 0 to 40 and y is a value of at least 15. single detergent portion according to any of the above items 12 to 15, characterized in that the shaped body comprises a poly(oxyalkylated) nonionic surfactant of the formula R 1 O[CH 2 CH 2 O] x[ CH 2 CH(R 3) O] y CH 2 CH(OH)R 2, as at least one nonionic surfactant and the amount of this surfactant, based on the total weight of the shaped body, is from 5 to 50% by weight, preferably from 10 to 45% by weight, particularly preferably from 15 to 40% by weight. 17.Single-part detergent portion according to any of the above items 12 to 16, characterized in that at least 40 wt %, preferably at least 50 wt %, particularly preferably at least 75 wt %, based in each case on the total weight of the surfactants comprised in the shaped body, have a melting point above 20° C. at standard pressure. 18. Single cleaning agent portion according to any of the above items 12 to 17, characterized in that the molded body comprises at most 15 wt.-%, preferably at most 10 wt.-%, particularly preferably at most 5 wt.-%, based on the total weight of the molded body, surfactants which have a melting point below 15°C at normal pressure. 19.Single-part cleaning agent portion according to any of the above items 12 to 18, characterized in that the molded body comprises PEG, preferably with an average molecular weight of 3000 to 7000 g / mol in an amount of 20 to 50 wt %, preferably of 22 to 40 wt %, particularly preferably of 25 to 35 wt %, and at least one nonionic surfactant in 5 to 50 wt %, preferably of 10 to 45 wt %, particularly preferably of 15 to 40 wt %, in each case based on the total weight of the molded body. 20.A single cleaning agent portion according to any one of the preceding items 12 to 19, characterised in that the shaped body comprises polyethylene glycols with an average molecular weight of 5000 to 7000 g / mol in an amount of 25 to 50 wt.%, preferably 27 to 40 wt.%, particularly preferably 29 to 36 wt.% and a non-ionic surfactant with a melting point of 25 to 40 °C as at least one non-ionic surfactant in an amount of 5 to 40 wt.%, preferably 10 to 30 wt.%, particularly preferably 15 to 30 wt.%, in each case based on the total weight of the shaped body. 21.The single cleaning agent portion according to any one of the above items 12 to 20, characterized in that the molded body comprises polyethylene glycols having an average molecular weight of 3000 to 4500 g / mol in an amount of 25 to 50 wt %, preferably 27 to 40 wt %, particularly preferably 29 to 36 wt % and a nonionic surfactant having a melting point of 40 or more, preferably 43 to 65° C. as at least one nonionic surfactant in an amount of 5 to 40 wt %, preferably 10 to 30 wt %, particularly preferably 15 to 30 wt %, in each case based on the total weight of the molded body. 22.A single detergent portion according to any of the preceding points, characterized in that the shaped body comprises a bleach catalyst, in particular selected from the group of the transition metal salts and transition metal complexes, in particular complexes of manganese in the oxidation state II, III, IV or V, which particularly preferably comprises the macromolecular ligands 1,4,7-trimethyl-1,4,7-triazacyclononane (Me-TACN), 1,4,7, triazacyclononane (TACN), 1,5,9-trimethyl-1,5,9-triazacyclododecane (Me-TACD), 2-methyl-1,4,7-trimethyl-1,4,7-triazacyclononane (Me / Me TACN) and / or 2-methyl-1,4,7-triazacyclononane (Me / TACN), The compound according to the invention is especially preferably a compound comprising 1,4,7-trimethyl-1,4,7-triazacyclononane (Me-TACN) or 1,2,4,7-tretramethyl-1,4,7-triazacyclonan (Me / Me-TACN), preferably in an amount of 0.000001 to 0.5% by weight, particularly preferably of 0.00001 to 0.3% by weight, particularly preferably of 0.0001 to 0.25% by weight, very particularly preferably of 0.001 to 0.1% by weight, based on the total weight of the shaped body. 23.Single-part detergent portion according to any of the preceding points, characterized in that the shaped body comprises a bleach activator, preferably selected from the group of polyacylated alkylenediamines, in particular TAED, preferably in an amount of from 0.1 to 10% by weight, particularly preferably from 0.5 to 9% by weight, in particular preferably from 1.0 to 8% by weight, based on the total weight of the shaped body. 24.Single cleaning agent portion according to one of the preceding points, characterized in that the shaped body comprises a silver protectant, in particular selected from cysteine and cystine, in particular cysteine, preferably in an amount of 0.01 to 1.5 wt.%, particularly preferably of 0.1 to 1.0 wt.%, in particular preferably of 0.15 to 0.8 wt.%, based on the total weight of the shaped body. 25.Single cleaning agent portion according to one of the preceding points, characterized in that the shaped body comprises builders, in particular selected from carbonates, bicarbonates, citrates and / or salts thereof, preferably in an amount of 0.1 to 30 wt %, particularly preferably of 0.5 to 20 wt %, in particular preferably of 1.0 to 15 wt %, based on the total weight of the shaped body. 26.Single-part detergent composition according to one of the preceding points, characterized in that the shaped body of aminocarboxylic acids comprises different complexing agents, in particular selected from phosphonates, particularly preferably hydroxyethylene diphosphonate, preferably 0.01 to 30 wt %, particularly preferably from 0.1 to 25 wt %, particularly preferably from 1.0 to 20 wt %, based on the total weight of the shaped body. 27. detergent single portion according to any of the preceding points, characterized in that the at least one shaped body is arranged in the chamber such that it is in direct contact with the closure element and the inner side of the closure element is in contact with the powder to an extent of less than 10%, preferably to an extent of less than 8%, in particular to an extent of less than 6%, very particularly to an extent of less than 3%, of its surface. 28. cleaning agent single portion according to one of the preceding points, characterized in that the inner side of the closure element is not in contact with the powder. 29. cleaning agent single portion according to one of the preceding points, characterized in that the inside of the closure element is covered by the at least one shaped body to an extent of more than 70%, preferably to an extent of more than 75%, in particular to an extent of more than 80%, very particularly to an extent of more than 85% of its surface. 30.Single cleaning agent portion according to one of the preceding points, characterized in that the side of the shaped body which is in contact with the closure element has at least 70%, preferably at least 75%, in particular at least 80%, particularly preferably more than 85% of its surface area in contact with the inner side of the closure element. 31. cleaning agent single portion according to item 31, characterized in that the side of the molded body which is in contact with the closure element has substantially full-surface contact with the closure element. 32. cleaning agent single portion according to one of the preceding points, characterized in that the shaped body has an upper side substantially plane-parallel to the lower side. 33. detergent single portion according to any of the preceding points, characterized in that the closure element is a water-soluble film. 34. detergent single portion according to item 34, characterized in that the water-soluble film has a thickness of 80 μm or less, preferably of 70 μm or less, in particular of 65 μm or less, very particularly preferably of 55 μm or less. 35. detergent single portion according to item 34 or 35, characterized in that the water-soluble film constituting the closure member has a thickness less than the average thickness of the water-soluble accommodation chamber. 36. cleaning agent single portion according to one of the preceding points, characterized in that the shaped body which is in contact with the closure element has a substantially identical height. 37. cleaning agent single portion according to one of the preceding points, characterized in that the molded body has at least one substantially flat side, preferably a substantially flat top side and / or bottom side. 38.A single portion of cleaning agent according to any one of the preceding points, characterized in that the shaped body which is in contact with the closure element has a height of 2.5 to 9 mm, preferably 2.75 to 6.0 mm, in particular 3.0 to 5.5 mm. 39. detergent single portion according to any of the preceding points, characterized in that the shaped body is substantially non-elastic. 40th Single-part cleaning agent portion according to one of the preceding points, characterized in that the molded body has a low breaking strength under compressive load, which preferably, determined in a force-path arrangement with a spherical body (diameter d=19 mm, nominal distance=3 mm, test feed speed of 0.5 mm / s and a pretest force of 5 grams, has a penetration depth of 0.1 mm to 1.0 mm, preferably of 0.15 mm to 0.8 mm, in particular of 0.2 to 0.6 mm. 41. detergent single portion according to any of the preceding items, characterized in that the powder comprises particles having a particle diameter of up to 2000 μm, in particular up to 1000 μm, and / or at least 80% of the particles have a particle diameter of 100 to 2000 μm, preferably 150 μm to 1500 μm. 42. detergent single portion according to any of the preceding points, characterized in that the total weight of the detergent single portion is from 10 g to 25 g, preferably from 12 to 22 g, particularly preferably from 13 g to 20 g. 43. detergent single portion according to any of the preceding points, characterized in that the total weight of the powder is from 7 g to 20 g, preferably from 8 to 15 g, particularly preferably from 10 g to 12 g. 44. single cleaning agent portion according to one of the preceding points, characterized in that the total weight of a shaped body is from 4 g to 8 g, preferably from 5 to 7 g. 45. detergent single portion according to any of the above items, characterized in that the weight ratio of powder to shaped body is from 4:1 to 1:1, preferably from 3.75:1 to 1.25:1, in particular from 3.5:1 to 1.5:1, very particularly preferably from 3.25:1 to 1.75:1. 46. detergent single portion according to any of the preceding points, characterized in that the chamber contains exactly one phase comprising a powder and exactly one shaped body. 47. Cleaning agent single portion according to one of the preceding points, characterized in that at least one gel phase different from the molded body is contained in the chamber. 48 Single cleaning agent portion according to item 48, characterized in that two gel phases different from the molded body are contained in the chamber. 49. cleaning agent single portion according to item 48, characterized in that three gel phases different from the molded body are contained in the chamber. 50.A single cleaning agent portion according to item 48, characterized in that four gel phases different from the molded body are contained in the chamber. 51 A single cleaning agent portion according to any one of the preceding claims, characterized in that the shaped body is arranged in the chamber such that it is not in direct contact with the at least one gel phase. 52 Single cleaning agent portion according to one of the items 1 to 51, characterized in that the at least one gel phase is in contact with the molded body. 53. detergent single portion according to any of the preceding points, characterized in that the at least one gel phase is a gel phase which is solid at 20° C. and 1 bar. 54. Single detergent portion according to any of the preceding points, characterized in that the at least one gel phase comprises water-soluble polymer from the group of (optionally acetalized) polyvinyl alcohols and copolymers thereof. 55. Single detergent portion according to item x-1, characterized in that the at least one gel phase, (optionally acetalized) polyvinyl alcohols and copolymers thereof comprise in an amount of 8.5 to 25 wt %, based on the total weight of the gel phase. 56. detergent single portion according to any of the preceding points, characterized in that the weight of all gel phases is from 0.1 g and 4 g, preferably from 0.4 to 3 g, particularly preferably from 0.7 to 2.5 g. 57. Cleaning agent single portion according to any one of the preceding points, characterised in that the weight ratio of the shaped body to the gel phase(s) (sum of all gel phases) is from 8:1 to 1:2, preferably from 6:1 to 1:1, in particular from 4.5:1 to 1.5:1, very particularly preferably from 4:1 to 1.75:1. 58 Single cleaning agent portion according to one of the preceding points, characterized in that the weight ratio of the powder to the gel phase (sum of all gel phases) is from 20:1 to 1:1, preferably from 12:1 to 1.5:1, in particular from 10:1 to 2:1, very particularly preferably from 8:1 to 2.5:1. 59 The single detergent portion according to any of the preceding items, characterized in that no phases contained in the chamber are liquid at 20°C and / or the detergent contains no more than 5 wt% anionic surfactant, based on the total weight of the detergent composition. 60th Cleaning agent single portion according to one of the preceding points, characterized in that the at least one gel phase and / or the shaped body have contact with the powder. 61. use of a single-part detergent portion according to any of the items 1 to 60 in an automatic dishwashing process. 62 A method for producing a detergent portion unit in a water-soluble packaging according to any of items 1 to 60, comprising the following steps i) providing a water-soluble receiving chamber; ii) optionally introducing at least one gel phase into the receiving chamber; iii) filling at least one powder into the receiving chamber; iv) placing a shaped body comprising at least one aminocarboxylic acid and / or a salt thereof onto the powder; v) closing the filled receiving chamber with a water-soluble closure element. 63. The method according to item 62, wherein the water-soluble accommodation chamber is obtained by injection molding a water-soluble material. 64th The method according to item 62, wherein the water-soluble accommodation chamber is obtained by deep drawing a water-soluble film. 65. The method according to any one of the preceding items 62 to 64, wherein the water-soluble receiving chamber and / or the water-soluble closure element comprises water-soluble polymer from the group of (optionally acetalized) polyvinyl alcohols (PVOH) and copolymers thereof. 66th The method according to any one of the above items 62 to 65, wherein in step ii) a gel phase is introduced into the receiving chamber. 67th The method according to any one of the above items 62 to 65, wherein in step ii) two gel phases are introduced into the receiving chamber. 68th Method according to one of the above items 62 to 65, wherein three gel phases are introduced into the receiving chamber in step ii). 69 The method according to any one of the above items 62 to 65, wherein in step ii) four gel phases are introduced into the receiving chamber 70 The method according to any one of the above items 67 to 69, wherein the two or three or four gel phases are introduced into the receiving chamber such that they are not in direct contact with each other. 71th The method according to any one of the above Items 62 to 70, wherein the powder in Step iii) is filled into the accommodating chamber such that the surface of the gel phase(s) facing the opening of the accommodating chamber is completely covered with powder. 72th Method according to any of the above items 62 to 71, wherein the powder has a flowability of greater than 40%, preferably of greater than 50%, in particular of greater than 60%, based on the standard. 73. Method according to one of the above items 62 to 72, wherein the receiving chamber following step iii) has a filling degree above 60% by volume, preferably above 70% by volume. 74 The process according to any of the above items 62 to 73, wherein the shaped body in step iv) is placed on the powder in such a way that the surface of the powder facing the opening of the receiving chamber is covered by the shaped body to an extent of more than 75%, preferably more than 75%, preferably more than 75%, in particular more than 80% and very particularly preferably more than 85%. 75 The method of any of the preceding Items 62-74, wherein the shaped article is preformed in step iv) (and / or is not produced in situ by the incorporation of a flowable component). 76th Method according to any of the above items 62 to 75, wherein the shaped body in step iv) has a flat underside, the greatest diagonal of which is greater than the height of the shaped body, and the shaped body is placed with the flat underside on the surface of the powder. 77 The method according to any one of the above items 62 to 76, wherein the shaped body in step iv) has a flat bottom side, the greatest diagonal of which is more than 1.5 times, preferably more than 2 times, the height of the shaped body, and the shaped body is placed with the flat bottom side on the surface of the powder. 78th Method according to one of the above points 62 to 77, wherein the shaped body in step iv) has an oval bottom side and the shaped body is placed with the flat bottom side on the surface of the powder. 79 Method according to any of the above items 62 to 77, wherein the shaped body in step iv) has an ellipsoidal or round, preferably a round bottom side and the shaped body is placed with the round bottom side on the surface of the powder. 80th Method according to one of the above points 62 to 77, wherein the shaped body in step iv) has an angular underside, preferably an angular underside with rounded corners, and the shaped body is placed with the angular, preferably angular underside with rounded corners on the surface of the powder. 81 The method according to any one of the preceding Items 62 to 77, wherein the shaped body in step iv) has a triangular, quadrangular or hexagonal bottom side and the shaped body is placed with the triangular, quadrangular or hexagonal bottom side on the surface of the powder. 82 Method according to one of the above points 62 to 81, wherein the shaped body in step iv) has an upper side which is plane-parallel to the underside and the underside is placed on the surface of the powder. 83 The process according to any of the above items 62 to 82, wherein the shaped body in step iv) has a bottom side and a top side which are connected to one another by a cylindrical shell surface and the shaped body is placed with the bottom side onto the surface of the powder. 84th Method according to one of the above items 62 to 83, wherein the shaped body in step iv) has a bottom side, the contour of which is reproduced from the opening surface of the receiving chamber, and the shaped body is placed with the bottom side on the surface of the powder. 85 The method according to any one of the above Items 62 to 84, wherein the molded body in Step iv) has a bottom surface whose outline is obtained from the outline of the opening surface of the accommodation chamber by a reduction by a factor of 0.75 to 0.98, and the molded body is placed with the bottom surface on the surface of the powder. 86th Method according to one of the above items 62 to 85, wherein the receiving chamber following step iv) has a degree of filling above 85 vol.-%, preferably above 94 vol.-%. 87 The method according to any one of the above Items 62 to 86, wherein the water-soluble accommodation chamber is sealed with a water-soluble film in Step v). 88th The method according to any one of the above Items 62 to 87, wherein the water-soluble accommodation chamber is obtained by deep drawing a first water-soluble film, and is sealed with a second water-soluble film in step v), and the second water-soluble film has a thickness smaller than that of the first water-soluble film. 89. The method of any of the above Items 62 to 88, wherein the first water-soluble film has a thickness of 60 to 200 μm and the second water-soluble film has a thickness of 40 to 120 μm. 90th Method according to item 89, wherein the second water-soluble film has a thickness of 80 μm or less, preferably of 70 μm or less, in particular of 65 μm or less, very particularly preferably of 55 μm or less. 91 The method according to item 89 or 90, wherein the ratio of the thickness of the first water-soluble film to the thickness of the second water-soluble film is from 3:1 to 1:1, preferably from 2.5:1 to 1.1:1, in particular from 2:1 to 1.2:1. 92th Process according to one of the above items 87 to 91, wherein the sealed filled receiving chamber after step v) is heated in a further step vi) for a period of time of 0.5 to 20 seconds to temperatures above 120° C., preferably to temperatures in the range of 140 to 220° C.Examples:From the molding compounds shown in Table 1, molded articles having a weight of 6 g, a thickness of 3.5 mm and a size of 45 x 36 mm, corner radius R 1=10 and corner radius R 2=5 were prepared by casting the compound into a corresponding mold. Table 1: Shaped-body casting compositions (data in % by weight of active substance) Table 1: Shaped-body casting compositions (data in % by weight of active substance)PEG40002520PEG6000003030Soda soda anhydrous, sodium carbonate anhydrous00100Nonionic surfactant, ethoxylated fatty alcohol with melting point > 25 °C37,53000End group-capped polyethoxlated fatty alcohol according to formula (I), melting point > 30°C0102025Trilon® M powder ex BASF (% AS)32,5264540Surface after solidification<=20min3min and less3-4 min3-4 minDosabilityOnly short stirring time, easily pourable at 66° CThe casting process was very easily castable at 63° CThe gel is readily meterable at 75° C., readily flowable, homogeneous gelThe composition is more readily meterable and flowable than IIIObservation: ObservationSoft castingsParticularly smooth surfaceParticularly smooth surfaceParticularly smooth surfaceReferences included in the specificationThis list of documents cited by the applicant has been produced in an automated manner and is only included for the better information of the reader. The list is not part of the German patent application or utility model application. The DPMA does not take any adhesion for any faults or omissions.Cited Non-Patent LiteratureDIN 55672-1:2007-08

[0122] International Cosmetic Ingredient Dictionary and Handbook, 7th Edition (1997

[0219]

Claims

A single-part detergent composition comprising a) a water-soluble packaging comprising a1) at least one water-soluble receiving chamber a2), a water-soluble closure element b) closing this water-soluble receiving chamber, a phosphate-free detergent composition comprising b1) at least one gel phase b2) at least one powder, b3) at least one shaped body different from the powder, wherein the shaped body comprises at least one aminocarboxylic acid and / or a salt thereof.Single detergent portion according to Claim 1, characterized in that the aminocarboxylic acid or a salt thereof is selected from methylglycinediacetic acid and its salts, glutaminediacetic acid and its salts and ethylenediaminedisuccinic acid and its salts, particularly preferably methylglycinediacetic acid and its salts.Single-part detergent portion according to any of the preceding claims, characterized in that the amount of the aminocarboxylic acid or of the aminocarboxylic acid salt thereof, based on the total weight of the shaped body, is from 20 to 65% by weight, preferably from 22 to 60% by weight, in particular preferably from 26 to 55% by weight.Single-part detergent composition according to any of the preceding claims, characterized in that the shaped body comprises polyalkylene glycols, preferably polyethylene glycols, which have a melting point of from 25 to 80°C, preferably from 30 to 70°C, particularly preferably from 45 to 65°C, at normal pressure, and / or the amount of the polyalkylene glycols, preferably polyethylene glycols, in the shaped body is from 20 to 50% by weight, preferably from 22 to 40% by weight, particularly preferably from 25 to 35% by weight, based on the total weight of the shaped body.Single-part detergent composition according to any of the preceding claims, characterized in that the shaped body comprises surfactants, preferably nonionic surfactants, preferably in an amount, based on the total weight of the shaped body, of from 5 to 50% by weight, preferably from 10 to 45% by weight, in particular preferably from 15 to 40% by weight.Single-part detergent portion according to any of the preceding claims, characterized in that at least 40% by weight, preferably at least 50% by weight, more preferably at least 75% by weight, based in each case on the total weight of the surfactants comprised in the shaped body, have a melting point above 20°C at standard pressure.Single-part cleaning agent portion according to one of the preceding claims, characterized in that the total weight of the powder is from 7 g to 20 g, preferably from 8 to 15 g, particularly preferably from 10 g to 12 g and / or the total weight of the shaped body is from 4 g to 8 g, preferably from 5 to 7 g.Single-part detergent composition according to any of the preceding claims, characterized in that no phases present in the chamber are liquid at 20°C and / or the detergent contains no more than 5% by weight of anionic surfactant, based on the total weight of the detergent composition.Single-part detergent portion according to any of the preceding claims, characterized in that the shaped body is arranged in the chamber such that it is not in direct contact with the at least one gel phase.Use of a single detergent portion according to any one of claims 1 to 9 in an automatic dishwashing process.