Method for rolling super austenitic stainless steel
The method optimizes the steel rolling process by selecting appropriate billet dimensions, controlling temperature and rolling forces, and adjusting the number of rolling passes to successfully roll super austenitic stainless steel to thin and wide specifications, achieving high quality and a high success rate.
Patent Information
- Application Number
- EP2020866991
- Authority / Receiving Office
- EP · EP
- Patent Type
- Patents
- Current Assignee / Owner
- Priority Date
- 2019-09-23
- Filing Date
- 2020-06-19
- Publication Date
- 2025-01-22
- Estimated Expiration
- 2040-06-19
AI Technical Summary
Existing steel rolling processes face challenges in rolling super austenitic stainless steel to extremely thin and wide specifications due to high deformation resistance, leading to excessive rolling pressure, poor plate shape, and inability to produce quality goods.
A method for rolling super austenitic stainless steel involving optimized billet selection, steel burning, descaling, rolling, and straightening processes, which includes reducing the number of rolling passes, controlling temperature differences, and adjusting rolling forces to achieve successful rolling of steel plates with specifications of up to 8.5 mm thickness and 2610 mm width.
The method successfully rolls steel plates with specifications of 8.5 mm thickness and 2510 to 2610 mm width, achieving a stable plate shape and a high rolling success rate of 95.4%, while also expanding the rolling capabilities to include N08904 stainless steel with a thickness of 10.0 mm and widths ranging from 2620 to 2980 mm.
Abstract
Description
TECHNICAL FIELD
[0001] The present invention belongs to the technical field of steel rolling, and in particular, relates to a method for rolling super austenitic stainless steel.BACKGROUND
[0002] NAS 254NM (equivalent to UNS N08367) is high corrosion resistant stainless steel containing high chromium and high molybdenum. The specifications of this grade of steel still maintain good corrosion resistance even in the harsh environments of high temperature, seawater or flue gas and desulfurization equipment. It can be on a par with Hastelloy alloys and titanium plates under some environments, and it is highly economical stainless steel with high corrosion resistance.
[0003] N08367 contains 21% of Cr and 6% of Mo, so the deformation resistance thereof in a high temperature range is 2.5 to 3 times larger than that of ordinary grades of steel. When thin specification rolling is conducted to a low temperature section, a rolling pressure is too large, and as the width increases, the load is further increased. According to the existing rolling processes, extremely thin specification rolling cannot be conducted, rolling interrupting or a poor plate shape occurs, and quality goods cannot be obtained. CN 107 419 194 A discloses a rolling of a superaustenitic stainless steel.SUMMARY
[0004] Purpose of the invention: in order to overcome the problems of failing to roll due to too large load, extremely poor plate shape and failing to obtain quality goods when thin specification super austenitic stainless steel is rolled in the art, the present invention provides a method for rolling super austenitic stainless steel. This method rolls super austenitic stainless steel with the specifications of a thickness of below 10 mm and a width of above 2500 mm.
[0005] The technical solution is defined in the independent claim.
[0006] Beneficial effects: through technical optimization of the billet selection, the steel burning process, the descaling process, the steel rolling process and the straightening process in the method, rolling of super austenitic stainless steel with the specifications of a thickness of below 10 mm and a width of above 2500 mm may be achieved, and a steel plate with an N08367 grade of steel with the specifications of a thickness of 8.5 mm and widths of 2510 mm and 2610 mm is rolled successfully. This specification is the widest specification in the world under this thickness, filling a gap in a width range of 2510 to 2610 mm for the N08367 grade of steel at the thickness of 8.5 mm, moreover, a rolled plate shape is stable, and a rolling success rate reaches 95.4%. In addition, N08904 stainless steel with a thickness of 10.0 mm and a width range of 2620 to 2980 mm is further rolled successfully.DETAILED DESCRIPTION OF THE EMBODIMENTS
[0007] A method for rolling super austenitic stainless steel, including the following steps.(1) Billet selection:
[0008] Deformation resistance of the super austenitic stainless steel at a high temperature is 2.5 to 3 times that of ordinary products. Ultra-wide and thin specifications are developed in selection of billet types. In order to ensure a rolling success rate, the minimum number of passes is adopted. It is necessary to ensure that in a case of meeting rolling thickness requirements, a minimum billet design principle is adopted, namely a minimum thickness billet loadable into a heating furnace.
[0009] Specifically, the minimum thickness billet loadable into the heating furnace is determined according to a minimum billet thickness that can be measured by a laser detector in the heating furnace. A minimum thickness is 115 mm. When a steel plate with the specifications of a thickness of 8.5 mm and a width of 2610 mm is rolled, a billet with a thickness of 115 mm, a width of 1780 mm and a length of 2610 mm is adopted. For an original billet with a thickness of 142 mm, cogging treatment is first conducted to a thickness of 115 mm, so as to reduce a total number of rolling passes in subsequent processes.(2) A steel burning process:
[0010] By utilizing the characteristic of easy oxidization at a high temperature of the super austenitic stainless steel, steel burning is conducted on the billet at 1250°C to 1270°C. Meanwhile, a temperature difference between upper and lower surfaces of the billet is strictly controlled to be 25°C to 35°C, ensuring that head warping will not happen to the steel plate in a rolling process. Moreover, positions of upper and lower beams are adjusted to ensure a middle position in the steel burning process, improving a temperature uniformity of the steel plate.(3) A descaling process:
[0011] By utilizing the characteristic of non-easy oxidization at the high temperature of the super austenitic stainless steel, a process mode that descaling must be conducted in a normal production process of a steel billet is broken, descaling operation is not conducted on the billet during rough descaling and rolling mill fine descaling, and the temperature difference between the upper and lower surfaces is maintained, preventing head warping of the steel plate caused by descaling.(4) A steel rolling process:
[0012] A final rolling temperature is required to be above 850°C, avoiding a sharp increase in deformation resistance below 850°C.
[0013] According to the maximum distribution of rolling torque and rolling force, 12 passes of rolling are adopted, breaking the limitation that 9 passes of rolling must be adopted for the thin specification in traditional processes.
[0014] Moreover, a reduction in the last two passes of rolling is less than 0.8 mm, avoiding that due to too large reduction, a roll gap for a rolling mill exceeds an equipment limit during actual rolling, resulting in difficult rolling. Meanwhile, it is ensured that a roll gap parameter for the rolling mill is set to be not less than 3.5 mm, avoiding that when the roll gap parameter for the rolling mill is set to be too small, a CVC rolling mill cannot move due to rolling force, resulting in that it cannot move in place.
[0015] A second-level model system optimizes a coefficient under different thicknesses according to the deformation resistance at different temperatures, and meanwhile, adjusts a certain specific pass separately. That is, in order to ensure the measurement accuracy of a thickness gauge, the thermal expansion coefficient of this stainless steel under different passes is adjusted separately according to the deformation resistance at different temperatures. Specifically, the coefficient is adjusted from 1.0132×10 -2< to 1.0133×10 -2< at 873°C, and the coefficient is adjusted from 1.02 84 × 10 -2< to 1.0285 × 10 -2< at 880°C, ensuring the accuracy of thickness self-learning correction by a second-level model.
[0016] (5) A straightening process: in a multi-pass straightening mode by a pre-straightening machine, a straightening pressure is increased by 1000 to 1500 tons according to plate shape conditions. If straightening force is too small, it will have no effect. If the straightening force is too large, it will exceed the equipment limit. During operation, pressing down 0.1 mm will increase about 100 tons of pressure, which corresponds to manually pressing down a roll gap by 1 to 1.5 mm.
[0017] By adopting the above method, the rolling of an N08367 grade of steel successfully break the width to 2610 mm. Specific implementation of a rolling schedule is shown in Table 1: Table 1 Rolling schedule table of N08367 with a thickness of 8.5 mmRotating steelOutlet thickness mmWidth mmLength mmRoll gap mmReduction mmReduction rate %Rolling force kNTorque Kn / mBiting speed m / sRolling speed m / sY97.732656.391.9191.2917.8715.467627786911.501.50N80.702659.422.3174.2617.0317.437626384721.751.75N64.662662.272.8858.1716.0419.887659982531.751.75N49.822664.873.7343.2314.8422.957749580322.002.53N36.032667.195.1628.3513.7927.688664686802.252.80N26.812668.066.9319.949.2225.597987965992.003.03N20.032667.599.2713.536.7825.287674954882.003.48N15.172665.6412.239.154.8624.257274144591.503.73N12.132662.6215.306.723.4420.036760933622.504.33N10.272659.6318.085.371.8715.406327325622.504.63N9.092657.7720.424.860.7811.475765619392.254.82N8.642656.7821.487.500.454.95325717222.254.98N8.642655.8021.4833.640.000.00005.25.20
[0018] Rolling specifications and success rates are shown in Table 2: Table 2 Rolling pass rates of N08367 with a thickness of 8.5 mmRolling specifications (thickness*width) mm*mmTotal number of rolled blocksNumber of successfully rolled blocksPass rate8.5*25101717100%8.5*2610706694.3%Sum878395.4%
[0019] Performance index requirements of the grade of steel and specifications are shown in Table 3: Table 3 Performance index requirements of N08367 with a thickness of 8.5 mm0.2% yield strength (N / mm 2< )Tensile strength (N / mm 2< )Elongation (%)Hardness (HRB)≥310≥690≥30≤241
[0020] Actual performance indexes of the grade of steel and specifications are shown in Table 4: Table 4 Actual performance indexes of N08367 with a thickness of 8.5 mmPerformance index0.2% yield strength (N / mm 2< )Tensile strength (N / mm 2< )Elongation (%)Hardness (HRB)Hot rolled plate 8.5 mm43976245211
[0021] It can be seen that by adopting the rolling method of the present invention, the steel that meets the performance index requirements of the N08367 with the thickness of 8.5 mm can be rolled, and a higher success rate is achieved.
[0022] Moreover, by adopting the above method, the limit specifications of 10*2620 mm, 10*2820 mm, 10*2980 mm, etc., of the same series of grade of steel N08904 are successfully developed. Rolling specifications and success rates thereof are shown in Table 5: Table 5 Rolling pass rates of N08904 with a thickness of 10.0 mmRolling specifications (thickness*width) mm*mmTotal number of rolled blocksNumber of successfully rolled blocksPass rate10.0*262088100%10.0*28201010100%10.0*298022100%Sum2020100%
[0023] Performance index requirements of the grade of steel and specifications are shown in Table 6: Table 6 Performance index requirements of N08904 with a thickness of 10.0 mm0.2% yield strength (N / mm 2< )Tensile strength (N / mm 2< )Elongation (%)Hardness (HRB)≥220≥490≥35≤90
[0024] Actual performance indexes of the grade of steel and specifications are shown in Table 7: Table 7 Actual performance indexes of N08904 with a thickness of 10.0 mmPerformance index0.2% yield strength (N / mm 2< )Tensile strength (N / mm 2< )Elongation (%)Hardness (HRB)10.0 mm2455984880
[0025] It can be seen that by adopting the rolling method of the present invention, the steel that meets the performance index requirements of the N08904 with the thickness of 10.0 mm can be rolled, and a higher success rate is also achieved.
Claims
1. A method for rolling super austenitic stainless steel with the specifications of a thickness of below 10 mm and a width of above 2500 mm, comprising the following steps: (1) selecting a minimum thickness billet loadable into a heating furnace, wherein the minimum thickness is 115 mm; (2) conducting steel heating on the billet at 1250° C to 1270° C, and controlling a temperature difference between upper and lower surfaces to be 25° C to 35° C; (3) not conducting descaling operation on the billet, and maintaining the temperature difference between the upper and lower surfaces, so that a temperature of the upper surface is higher than that of the lower surface; (4) controlling a final rolling temperature to be above 850° C; adopting 12 passes of rolling, wherein a reduction in the last two passes of rolling is less than 0.8 mm; and ensuring that a roll gap parameter for a rolling mill is set to be not less than 3.5 mm; during rolling, according to deformation resistance at different temperatures, optimizing a thermal expansion coefficient under different thicknesses, and adjusting the thermal expansion coefficient of this stainless steel under different passes separately, wherein, when a temperature is below 873° C, the thermal expansion coefficient of the stainless steel is set to be1.0133×10-2, and when the temperature is higher than 873° C and below 880° C, the thermal expansion coefficient of the stainless steel is set to be 1.0285×10-2; and (5) in a multi-pass straightening mode by a pre-straightening machine to ensure straightness of a final plate shape a roll gap is pressed down manually by 1 to 1.5 mm according to plate shape conditions.
2. The method for rolling the super austenitic stainless steel according to claim 1, wherein cogging treatment is adopted for an original billet greater than a design thickness of 115 mm to make the original billet reach the design thickness for billet selection.
Citation Information
Patent Citations
Rolling method of heat-resistant austenitic stainless steel
CN104275350A