New optical device for using the synergistic effect of photonic nanojet and plasmons for signal and resolution enhancement in spectroscopy

EP4751111A1Pending Publication Date: 2026-06-03RUDJER BOSKOVIC INST

Patent Information

Authority / Receiving Office
EP · EP
Patent Type
Applications
Current Assignee / Owner
RUDJER BOSKOVIC INST
Filing Date
2024-07-18
Publication Date
2026-06-03

AI Technical Summary

Technical Problem

Existing Raman spectroscopy methods, such as SERS and TERS, face challenges with reproducibility, cost, and complexity, while photonic nanojet methods offer lower enhancement levels but are simpler and more reproducible.

Method used

The development of a nano-engineered microsphere (NMS) that combines the synergistic effects of photonic nanojets and plasmons, enhancing Raman spectroscopy signals through a mechanically fixed and controlled dielectric microsphere with incorporated nanoelements.

Benefits of technology

NMERS achieves extremely high signal enhancement, up to three orders of magnitude higher than SERS or TERS, with improved reproducibility and reduced costs, while maintaining high resolution and simplicity of use.

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Abstract

An optical device called NMS (nano-engineered microsphere) is developed, which consists of an optical microsphere with a built in nanoelement. By illuminating the microsphere, a photonic nanojet is created that illuminates the nanoelement at the tip of which plasmons are excited. The nanoelement can be, for example, a metal nanocone whose base is built in a microsphere, and plasmons are excited at the tip, or a nanowire with a metal tip. The microsphere can contain a cavity that offers additional protection for the nanoelement and can cause higher enhancement. When used, for example, in Raman spectroscopy, which we call NMERS (nano-engineered microsphere enhanced Raman spectroscopy), the joint action of the photonic nanojet and plasmon leads to a combined enhancement of Raman scattering, and if the sample is mapped, the resolution of the mapping is also improved. NMERS offers some improvements over the best enhancement methods so far such as SERS and TERS, and NMS can be used in a variety of other microscopic and spectroscopic applications.
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