A solid, matte composition comprising a specific non-polar hydrocarbon oil, a lipophilic clay, and the process for its application.

Abstract

Title: MATTE SOLID COMPOSITION COMPRISING A PARTICULAR NON-POLAR HYDROCARBONATE OIL, A LIPOPHILIC CLAY, AND METHOD FOR IMPLEMENTING IT. The present invention relates to a matte solid cosmetic composition, preferably in stick form, intended for application to the skin and / or lips, comprising: * at least 5% by weight, relative to the total weight of the composition, of at least one first non-polar hydrocarbon oil, saturated or unsaturated, preferably saturated, linear or branched, preferably branched, in C14-C19, * at least one mineral or organic filler comprising at least one lipophilic clay-type filler comprising at least one quaternary ammonium group, said lipophilic clay-type filler being present at a content of between 1 and 3% by weight, relative to the total weight of the composition, * at least one second oil selected from non-volatile hydrocarbon oils, polar or non-polar, different from the first oil.or non-volatile silicones, *at least one silicone elastomer in a form carried in at least one oil identical or different from the first or second oil. It also relates to a makeup and / or skin and / or lip care process, consisting of applying said composition.

Description

Title of the invention: MATTE SOLID COMPOSITION COMPRISING A PARTICULAR NON-POLAR HYDROCARBONATE OIL, A LIPOPHILIC CLAY, AND A METHOD FOR IMPLEMENTING IT

[0001] The present invention relates to solid compositions whose deposit has a matte appearance, for the makeup and / or care of keratinous materials, more particularly of the lips, comprising at least 5% by weight of a particular nonpolar hydrocarbon oil and a lipophilic clay comprising at least one quaternary ammonium group as a filler, as well as a process implementing said composition.

[0002] Compositions intended for application, particularly to the lips, and providing a matte finish after application, are well known in the cosmetics field and are most often characterized by high levels of volatile oils and / or fillers. The high volatile oil content further increases the content of solid particles in the deposit, such as fillers and pigments, once the composition has been applied and dried. Regarding the fillers used in compositions providing a matte finish, organic particles are often found, particularly polymeric ones such as nylon, polytetrafluoroethylene, polyethylene, silicone resins or elastomers, or mineral ones, such as kaolin or silica. These fillers allow, among other things, for the partial absorption of remaining oily compounds, whether they originate from the composition itself or from the surface to which it is applied (sebum).With the high levels of volatile oils and solid particles in matte formulas, the content of non-volatile oils is consequently significantly reduced in the residue after application and drying. This is why matte formulas are generally considered by users to be uncomfortable or even uncomfortable once applied, often resulting in a sensation of lip dryness. Furthermore, in recent years, a new trend has clearly emerged among consumers who are focusing less exclusively, but still nonetheless, on the performance of makeup formulas. Indeed, increasing attention is being paid to the ingredients used in cosmetic formulations, particularly the presence of microplastics.However, as previously mentioned, achieving a matte effect often depends on the presence of high levels of fillers, particularly organic ones, especially polymers. Since such fillers are considered microplastics, it is desirable... Restricting, or even avoiding, their use in compositions with a matte finish is advisable. On the other hand, replacing organic fillers with mineral fillers, such as clays or silicas, is not a completely acceptable solution either, as these fillers further increase the feeling of dryness of the coating once applied. They can also impair the ease of application, making the process significantly more difficult.

[0003] We are therefore still looking for solid compositions with a matte finish that are easy to apply, more comfortable to wear, and have a limited drying effect on the lips. We also want to be able to have compositions in which it is possible to eliminate the presence of microplastics or reduce their use, without loss of effectiveness, particularly in terms of matte finish.

[0004] These and other objectives are achieved by the present invention, which therefore relates to compositions comprising: * at least 5% by weight, relative to the total weight of the composition, of at least one first nonpolar hydrocarbon oil, saturated or unsaturated, preferably saturated, linear or branched, preferably branched, in C14-C19, * at least one mineral or organic filler comprising at least one lipophilic clay-type filler comprising at least one quaternary ammonium group, said lipophilic clay-type filler being present at a content of between 1 and 3% by weight, relative to the total weight of the composition, *at least one second non-volatile oil chosen from among hydrocarbon, polar or non-polar non-volatile oils, different from the first oil, or silicone non-volatile oils, * at least one silicone elastomer in a form carried in at least one oil, identical or different to the first or second oil.

[0005] It also relates to a makeup and / or care process, in which the previously defined composition is applied to human keratinous materials, in particular to the lips.

[0006] The present invention provides a stable, solid composition, particularly in stick form, that is easily applied to the lips, resulting in a precise, homogeneous, matte deposit that does not migrate. The resulting deposit also offers improved comfort, notably in that it is less drying to the lips. Furthermore, the deposit exhibits good color retention over time (up to 10 hours).

[0007] These and other advantages of the present invention will become more apparent upon reading the description and examples that follow.

[0008] Note that in the rest of the description, unless otherwise indicated, the bounds indicated for a domain are included in that domain.

[0009] The expressions "at least one" and "several" are used interchangeably.

[0010] Furthermore, the sum of the quantities of the ingredients in the composition represents 100% by weight, relative to the total weight of the composition. Protocol for measuring hardness

[0011] The hardness of the composition is measured according to the following protocol: The stick is kept at 20°C for 16 hours before the hardness measurement. Hardness is measured at 20°C using the "butter wire" method, which involves cutting a stick of product, preferably cylindrical, transversely with a rigid tungsten wire 0.25 mm in diameter, moving the wire relative to the stick at a speed of 100 mm / min. Measurements are taken at least 10 mm from the sample holder. The hardness of the samples, expressed in grams, is measured, for example, using a static fragility tester (breakmeter - Industrial Electronics). The measurement is repeated three times and then averaged. The hardness is the average of the three values ​​read using the apparatus mentioned above.

[0012] According to this measurement method, the composition according to the invention preferably has a hardness at 20°C and at atmospheric pressure of between 80 and 200 g, more particularly 100 to 190 g, preferably 120 to 170 g. Gloss measurement protocol

[0013] The brightness of the composition is measured according to the following protocol: After being heated to between 95-98°C, the lipstick is spread on a black and white background contrast card (Ref byko-chart, unvarnished N2C), measuring: 194x260 mm (7.6 x 10.25 in), to a thickness of 500 µm using an automatic spreader (Ref byko-drive, Model: DOA-P504-BN) whose cylinder is preheated using a heating plate at 50°C. Gloss is measured at 85° using a glossmeter (Ref micro-TRI-gloss, BYK). The brightness value is obtained by averaging three measurements taken at three different points on the contrast card.

[0014] The composition is considered matte within the meaning of the invention, when the gloss value is less than 70, and preferably less than 30. FIRST OIL

[0015] As previously stated, the composition according to the invention includes at least a first nonpolar hydrocarbon oil, saturated or unsaturated, preferably saturated, linear or branched, preferably branched, in C14-C19.

[0016] For the purposes of this invention, "nonpolar hydrocarbon oil" means a hy- drocarbonate consisting solely of carbon and hydrogen atoms.

[0017] Furthermore, the term "oil" refers, in the context of the invention, to a compound that is not soluble in water, liquid at 20°C and atmospheric pressure (1.013.105 Pa).

[0018] More particularly, the first oil is chosen from the following oils, alone or in mixture (INCI name): Tetradecane, Hexadecane, Isohexadecane, Octadecane, C15-19 Alkane, and even more preferably the oil is isohexadecane.

[0019] These oils are notably available under the trade names Arlamol HD by Croda; Permethyl 101A by Presperse Corp; Isohexadecane by INEOS; Parafol 14, Parafol 16-97, Parafol 18-97 by Sasol GmbH; Gemseal 40 by Total; Emogreen L15, Emogreen L19 by SEPPIC among others.

[0020] The composition according to the invention further has a first oil content of at least 5% by weight, more particularly at least 10% by weight, relative to the total weight of the composition. Preferably, the first oil content is between 10 and 25% by weight, more particularly between 15 and 20% by weight, relative to the total weight of the composition. SECOND NON-VOLATILE OIL

[0021] The composition according to the invention comprises at least a second non-volatile oil, polar or non-polar hydrocarbon, different from the first oil, or silicone non-volatile.

[0022] The term "non-volatile oil" refers to fatty compounds, insoluble in water, liquid at 20°C and atmospheric pressure (1.013 x 10⁵ Pa), whose vapor pressure at 20°C is non-zero and less than 2.66 Pa, more particularly less than or equal to 0.13 Pa. By way of example, the vapor pressure can be measured according to the static method or by the isothermal thermogravimetric effusion method, according to the vapor pressure (OECD Standard 104).

[0023] By "hydrocarbon oil" is meant an oil formed essentially, or even composed, of carbon and hydrogen atoms, and also comprising at least one oxygen atom, and possibly nitrogen. These oils are therefore distinct from silicone oils. They may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

[0024] By "siliconized oil" is meant an oil containing at least one silicon atom, and in particular containing Si-O groups.

[0025] According to a particular embodiment of the invention, the content of second non-volatile oil(s) varies from 10 to 35% by weight, preferably from 15 to 35% by weight, relative to the total weight of the composition. POLAR NON-VOLATILE HYDROCARBONATE OIL

[0026] A polar hydrocarbon oil within the meaning of the invention comprises, in addition to carbon and hydrogen atoms, at least one oxygen or nitrogen atom, and preferably at least one oxygen atom.

[0027] Among the non-volatile polar hydrocarbon oils suitable for implementing the invention, the following oils may be mentioned in particular: - alcohols in the form of C10-C26, preferably monohydroxylated; - ethers of formula ROR', carbonates of formula RO(CO)OR', formulas in which, identical or not, the groups R, R' represent a hydrocarbon group comprising at most 16 carbon atoms, saturated or not, branched or not, preferably in C3-Ci6; - non-volatile hydrocarbon ester oils comprising one or more ester functions and comprising at least one hydrocarbon group, linear or branched, saturated, unsaturated or aromatic, the total number of carbon atoms preferably being at least 12; - their mixtures. Alcohols in the C10-C26 range

[0028] The alcohols are more particularly fatty alcohols. They comprise a saturated or unsaturated, linear or branched hydrocarbon radical, comprising 10 to 26 carbon atoms, preferably comprising 10 to 24 carbon atoms, and more preferably 12 to 22 carbon atoms. They are preferably monohydroxylated.

[0029] Preferably, the said alcohol(s) are chosen from lauric alcohol, isostearyl alcohol, oleic alcohol, 2-butyloctanol, 2-undecyl pentadecanol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol and mixtures thereof, and preferably octyldodecanol. Non-volatile oils, ether or carbonate

[0030] Among suitable non-volatile hydrocarbon oils, mention may be made of ethers of formula ROR', carbonates of formula RO(CO)OR', formulas in which, identical or not, the groups R, R' represent a hydrocarbon group comprising at most 16 carbon atoms, saturated or not, branched or not, preferably in C3-C16.

[0031] Preferably, the oil or oils may be chosen from: - dicaprylyl ether, - dipropyl carbonate, diethylhexyl carbonate, dicaprylyl carbonate, Cl4-15 dialkyl carbonate,

[0032] Non-volatile hydrocarbon oils with ester function(s)

[0033] The non-volatile hydrocarbon oil may also comprise at least one oil chosen more particularly from hydrocarbon compounds comprising one or more ester functions and comprising at least one hydrocarbon group, linear or branched, saturated, unsaturated or aromatic, the total number of carbon atoms preferably being at least 12. In addition, the ester oil may optionally include one or more ether or hydroxyl functions.

[0034] Among suitable ester oils, one can mention mono and die esters possibly comprising one or two ether groups; triesters, linear or branched, saturated, unsaturated or aromatic, possibly comprising one to three ether groups; tetraesters; polyesters obtained by condensation of dimer and / or trimer of unsaturated fatty acid and diol; esters and polyesters of mono- or dicarboxylic acid and diol dimer or monoalcohols; vegetable oils, as well as mixtures thereof.

[0035] * Mono- or di-esters, linear or branched, saturated, unsaturated or aromatic, comprising more particularly from 12 to 80 carbon atoms, and possibly one or two ether groups. Among compounds of this type, one may cite monoesters or diesters obtained from monocarboxylic or dicarboxylic fatty acids, saturated or unsaturated, in particular comprising from 4 to 28, preferably from 4 to 24 carbon atoms, possibly comprising at least one free hydroxyl group, on the one hand, and from monoalcohols or polyols, saturated or unsaturated, comprising from 2 to 26, in particular from 3 to 24 carbon atoms, and 1 to 6 hydroxyl groups, on the other hand; the number of carbon atoms being at least 12, preferably at least 16. In addition, the ester may optionally comprise one or two ether groups and possibly one or two hydroxyl groups. Examples include octyl-2-dodecyl neopentanoate, isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, isostearyl heptanoate, cetostearyl octanoate, cetyl octanoate, tridecyl octanoate, isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate, hexyl laurate, 2-hexyldecyl laurate, 2-ethylhexyl palmitate, isopropyl palmitate, ethyl palmitate, 2-octyldecyl palmitate, isopropyl myristate, and myristate of 2-Octyldodecyl, isopropyl stearate, butyl stearate, octyl stearate, octyl-2-dodecyl stearate, glycerin stearate, isopropyl isostearate, isostearyl isostearate, isostearyl behenate, isocetyl stearate, mixtures of esters of capric acid, caprylic acid and coconut alcohol (Ci2-Ci8 alcohols), octyl-2-dodecyl erucate, oleyl erucate,Isostearyl lactate, octyl hydroxy stearate, octyldodecyl hydroxystearate, diisostearyl malate, isocetyl stearoyl stearate, diisostearyl adipate, or mixtures thereof. We can also mention the esters, optionally hydroxylated, of a C2-C8 mono- or polycarboxylic acid and a C2-C8 alcohol. In particular, monoesters of a C2-C8 carboxylic acid and a C2-C8 alcohol, optionally hydroxylated; and the diesters of a C2-C8 dicarboxylic acid and a C2-C8 alcohol, optionally hydroxylated; such as diisopropyl adipate, bis (2-ethylhexyl) adipate, dibutyl adipate, bis (2-ethylhexyl) succinate. We can also mention esters of monocarboxylic acids, saturated or unsaturated, particularly those comprising 4 to 28 carbon atoms, linear or branched, saturated, unsaturated or aromatic, and of diols, especially glycols, particularly C2-C5, of glycerol or polyglycerol. Examples include propylene glycol monoisostearate, propylene glycol monoricinoleate, neopentylglycol dicaprate, neopentylglycol diheptanoate, propylene glycol dioctanoate, diethylene glycol dii-sononanoate, polyglyceryl-2 diisostearate, polyglyceryl-3 diisostearate, ethylene glycol dibenzoate, diethylene glycol dibenzoate, propylene glycol dibenzoate, dipropylene glycol dibenzoate, and mixtures thereof.

[0036] *Linear or branched triesters, saturated, unsaturated or aromatic, comprising up to 80 carbon atoms, optionally comprising one to three ether groups. Suitable for the invention are esters obtained from mono- or polycarboxylic acids, linear or branched, saturated, unsaturated or aromatic, optionally hydroxylated, in C2-C40, preferably in C4-C40 and from polyols or monoalcohols in C2-C40, preferably in C3-C40; said polyesters optionally comprising at least one free hydroxyl group. One can, for example, use triacetin, as well as triglycerides of saturated or unsaturated fatty acids, in C4-C36, more particularly in C8-C20, linear or branched, saturated or unsaturated, such as triglycerides of heptanoic or octanoic acids, in particular, one can cite saturated triglycerides such as Caprylic / Capric Triglyceride, for example such as the products marketed under the DUB MCT range by the company Stéarinerie Dubois, glyceryl triheptanoate, glyceryl trioctanoate, triglycerides of acid in Ci8 36 such as those marketed under the reference DUB TGI 24 marketed by Stéarineries Dubois), glyceryl triisostearate. We can also mention glycerol or polyglycerol triesters and monocarboxylic acids such as polyglycerol-2 triisostearate, glyceryl-2 tridecyl tetradecanoate. As an example, one can also mention oils containing three ester groups, possibly hydroxylated or acetylated, of an acid containing three carboxylic groups, in the C2-C9 range, possibly hydroxylated, and of a monoalcohol in the C2-C20 range. Examples include citric acid esters such as triethyl citrate, trioctyl citrate, tributyl citrate, acetyl tributyl citrate, as well as trimellitate. of tridecyl, as well as their mixtures.

[0037] * Tetraesters comprising in particular 35 to 80 carbon atoms, comprising possibly one to three ether groups, such as pentaerythritol or polyglycerol tetraesters and a monocarboxylic acid, for example such as pentaerythrityl tetrapelargonate, pentaerythrityl tetraisostearate, pentaerythrityl tetraiso-nonanoate, polyglyceryl-2 tetraisostearate or pentaerythrityl tetradecanoate.

[0038] * Polyesters obtained by condensation of fatty acid dimers and / or trimers unsaturated and diol such as those described in patent application FR 0 853 634, such as in particular dilinoleic acid and 1,4-butanediol. Examples include the polymer marketed by Biosynthis under the name Viscoplast 14436H (INCI name: Dilinoleic Acid / Butanediol Copolymer), or copolymers of polyols and diacid dimers, and their esters, such as Hailucent ISDA, INCI name Polyglyceryl-2 Isostearate / Dimer Dilinoleate Copolymer.

[0039] * Esters of diol or polyol dimers and mono- and / or dicarboxylic acids. Examples include diol and fatty acid esters and diol and dicarboxylic acid dimer esters, in particular those that can be obtained from a dicarboxylic acid dimer derived in particular from the dimerization of an unsaturated fatty acid, especially in C8 to C34, especially in Ci2 to C22, especially in Ci6 to C20, and more particularly in Ci8, such as dilinoleic diacid and dilinoleic diol dimer esters, with INCI names Dimer Dilinoleyl Dimer Dilinoleate, for example such as those marketed by Nippon Fine Chemical under the trade names Lusplan DD-DA5® and DD-DA7®. Esters obtained by esterification of a polyol, at least one monocarboxylic acid, and at least one dicarboxylic acid are also suitable, as described in particular in US patent 7317068. The polyol more particularly comprises 2 to 20 carbon atoms and 2 to 8 hydroxyl groups, preferably pentaerythritol. More particularly, the monocarboxylic acid comprises 4 to 30 carbon atoms, more particularly 6 to 22 carbon atoms, preferably stearic, isostearic, caprylic, capric acids, or combinations thereof. As for the dicarboxylic acid, linear or branched, saturated, unsaturated, or aromatic, it more particularly comprises 4 to 10 carbon atoms, and preferably adipic acid.Examples include Pentaerythrityl Isostearate / Caprate / Caprylate / Adipate, marketed notably under the name Crodamol L by the company Croda, and Pentaerythrityl Adipate / Caprate / Caprylate / Heptanoate marketed under the name Lexfeel 700 EX-LO-MB by the company Inolex.

[0040] * vegetable oils such as castor oil, olive oil, oil coconut oil, jojoba oil, ximenia oil, pracaxi oil, oil of coriander seed, macadamia oil, passionflower oil, argan oil, sesame oil, sunflower oil, grapeseed oil, avocado oil, rosa canina oil, apricot kernel oil, flaxseed oil, sweet almond oil, cottonseed oil, soybean oil, rapeseed oil, peanut oil, kaya oil, marula oil, camelina oil, wheat germ oil, corn oil, corn germ oil, rice bran oil, alfalfa oil, poppy oil, pumpkin oil, squash oil, hazelnut oil, blackcurrant oil, evening primrose oil, millet oil barley oil, quinoa oil, rye oil, safflower oil, candlenut oil, meadowfoam oil, black cumin oil, buriti oil, sandalwood oil, babassu oil, the liquid fraction of shea butter, and the liquid fraction of cocoa butter, as well as mixtures thereof

[0041] Preferably, an oil is chosen from among castor oil, olive oil, coconut oil, jojoba oil, ximenia oil, macadamia oil, sesame oil, sunflower oil, grapeseed oil, avocado oil, apricot kernel oil, linseed oil, sweet almond oil, cottonseed oil, soybean oil, rapeseed oil, peanut oil, wheat germ oil, corn germ oil, rice bran oil, alfalfa oil, safflower oil, meadowfoam oil, the liquid fraction of shea butter, and the liquid fraction of cocoa butter, as well as mixtures thereof.

[0042] Preferably, the polar hydrocarbon oil(s) are chosen from: - vegetable oils, in particular those that have just been listed; - ester oils, possibly hydroxylated, comprising 1 to 4 ester functions, at least one of which, linear or branched, saturated, unsaturated or aromatic, comprises at least 12 carbon atoms; - their mixtures.

[0043] Preferably, the composition according to the invention comprises at least one polar hydrocarbon non-volatile oil.

[0044] More particularly, if the composition contains them, the content of polar non-volatile hydrocarbon oil(s) varies from 1 to 35% by weight, preferably from 1 to 25% by weight, relative to the total weight of the composition. According to an advantageous embodiment of the present invention, the composition comprises from 1 to 15% by weight, preferably from 2 to 8% by weight, and even more particularly from 3 to 6% by weight, relative to the total weight of the composition. NON-VOLATILE HYDROCARBONATE NON-POLAR OIL

[0045] By "nonpolar oil" in the context of the present invention, we mean an oil selected from among hydrocarbons, that is to say from compounds comprising only carbon and hydrogen atoms.

[0046] More specifically, non-polar, non-volatile hydrocarbon oil, different from or The first oils mentioned above can be chosen from linear or branched hydrocarbons of mineral, vegetable or synthetic origin, such as, for example: - paraffin oil, - squalane, particularly of plant origin, - isoeicosane, - mixtures of linear, saturated hydrocarbons, more particularly mixtures whose INCI names are for example the following: Cl8-21 Alkane, C21-28 Alkane, such as for example the Gemseal 60, Gemseal 120 products marketed by Total, - polybutenes, hydrogenated or not, such for example products from the Indopol range marketed by the company Ineos Oligomers, - Polyisobutenes, hydrogenated or not, such as, for example, the non-volatile compounds in the Parléam® range marketed by Nippon Oil & Fat, - Polydecenes, hydrogenated or not, such as, for example, non-volatile compounds in the Silkflo range marketed by Ineos, and Dekanex by IMCD, - and their mixtures.

[0047] Preferably, the composition according to the invention comprises at least one non-polar hydrocarbon non-volatile oil.

[0048] More particularly, if the composition contains it, the content of non-volatile non-polar hydrocarbon oil(s) varies from 1 to 10% by weight, preferably from 2 to 8% by weight, even more particularly from 3 to 6% by weight, relative to the total weight of the composition. NON-VOLATILE SILICONE OIL

[0049] As regards non-volatile silicone oils, the latter may be non-phenylated, or phenylated comprising or not at least one dimethicone fragment.

[0050] The term “phenylated” specifies that said oil includes in its structure at least one phenyl radical.

[0051] The term "dimethicone fragment" refers to a divalent siloxane group in which the silicon atom bears two methyl radicals, this group not being located at one or both ends of the molecule. It can be represented by the following formula: -(Si(CH3)2-O)-.

[0052] Preferably, silicones do not contain a C2-C3 alkylene oxide group, nor a glycerol group.

[0053] Among non-volatile, non-phenylated silicones, examples include polydimethylsiloxanes (INCI name: DIMETHICONE), alkyldimethicones comprising at least one alkyl group in the C2-C24 position, such as cetyldimethicone, and mixtures thereof. These oils are marketed, in particular, under the name DOWSIL 2502 Cosmetic Fluid by Dow Chemical; and Abil Wax 9801 by the company Evonik. Among the polydimethysilocxanes (dimethicone), we can mention the products of the Xiameter PMX-200 Silicone Fluid range marketed by Dow Chemical Company; the products of the Belsil DM range by the Wacker company, the products of the Mirasil DM range by the Elkem Silicones company, among others.

[0054] Among the non-volatile phenyl silicones comprising at least one dimethicone fragment, the following compounds with INCI names may be cited: Trimethylsiloxyphenyl Dimethicone, Diphenyl Dimethicone, Tetramethyl Tetraphenyl Trisiloxane, and mixtures thereof. Such oils are marketed, in particular, under the names Belsil PDM by Wacker; Mirasil P-DPDM by Elkem Silicones; KF-53, KF-54 by Shin Etsu; and Silshine 150 Fluid by Momentive Performance Materials.

[0055] With regard to phenylated silicone non-volatile oils, devoid of dimethicone fragment(s), examples include compounds with the following INCI names: Phenyl trimethicone, Trimethyl Pentaphenyl Trisiloxane, alone or in mixtures. These products are notably marketed by Dow Chemical Company under the name DOWSIL 556 Cosmetic Grade Fluid; by Elkem Silicones as Mirasil PTM; by Jeen International Corporation as Jessilc PTMF; and by Momentive Performance Materials as SF 1550 Fluid.

[0056] Preferably, the composition according to the invention comprises at least one non-polar hydrocarbon non-volatile oil.

[0057] More particularly, the content of non-volatile silicone oil(s) varies from 1 to 35% by weight, preferably from 1 to 30% by weight, preferably from 10 to 25% by weight, relative to the total weight of the composition. ADDITIONAL VOLATILE OILS

[0058] The composition according to the invention may optionally include at least one additional oil chosen from among volatile hydrocarbon oils, different from the first oils mentioned above, or silicone oils.

[0059] The term "volatile oil" refers to an oil having a non-zero vapor pressure, at ambient temperature and atmospheric pressure, ranging in particular from 2.66 Pa to 40,000 Pa, in particular up to 13,000 Pa, and more particularly up to 1300 Pa. SILICONE OILS

[0060] Examples of volatile silicone oils include, in particular, dimethicone with a viscosity of less than 5 cSt (5 x 10³ mm² / s, measured in particular according to the ASTM D-445 standard), octamethyl cyclotetrasiloxane, decamethyl cyclopentasiloxane, dodecamethyl cyclohexasiloxane, heptamethyl hexyltrisiloxane, heptamethyloctyl trisiloxane, hexamethyl disiloxane, octamethyl trisiloxane, and de- camethyl tetrasiloxane, dodecamethyl pentasiloxane, and mixtures thereof. VOLATILE OILS HYDROCARBONS

[0061] Among volatile hydrocarbon oils, preferably nonpolar, examples include volatile hydrocarbon oils having from 8 to fewer than 14 carbon atoms and mixtures thereof, and in particular: - branched alkanes such as isoalkanes (also called isoparaffins) such as isododecane, isodecane, and for example the oils sold under the trade name Isopar, marketed by the company ExxonMobil, - linear alkanes, preferably for example such as the mixture of n-decane (CIO) and n-dodecane (C12) sold by Biosynthis under the reference Vegelight silk, the n-dodecane (C12) sold by Sasol respectively under the references Parafol 12-97, the undecane-tridecane mixture (Cetiol UT), the mixtures of n-undecane (Cil) and n-tridecane (C13) obtained in examples 1 and 2 of application WO2008 / 155059 of the Cognis Company and their mixtures.

[0062] More particularly, if the composition includes it, the content of volatile additive oil(s) is less than or equal to 25% by weight, preferably less than or equal to 10% by weight, even more preferably less than or equal to 5% by weight, even more particularly less than or equal to 2% by weight, relative to the total weight of the composition. CHARGES

[0063] As previously stated, the composition according to the invention comprises at least one filler, among which is / which is at least one lipophilic clay comprising at least one ammonium group, at a content of between 1 and 3% by weight, relative to the total weight of the composition.

[0064] The filler, different from the aforementioned lipophilic clay, is chosen from mineral fillers, organic fillers, and mixtures thereof.

[0065] The term "charge" refers to a particle of organic or mineral nature, colorless or white, solid, of any shape, insoluble in the medium of the composition at ambient temperature and atmospheric pressure. These charges are advantageously dispersed in the composition. LIPOPHILE CLAY

[0066] The term “lipophilic clay” means any clay that is liposoluble or lipodispersible in an oily phase.

[0067] Clay refers to a material based on hydrated silicates and / or aluminosilicates with a lamellar structure.

[0068] Clays can be natural or synthetic and are made lipophilic by treatment with an alkyl ammonium salt such as an ammonium halide, such such as, for example, an ammonium chloride in C22-C1O form, with or without an aromatic group. In particular, one can cite halides, such as chlorides, of stearalkonium, benzalkonium or di-alkyl dimethyl ammonium, for example distearyl dimethyl ammonium.

[0069] The clay may be selected from bentonites, hectorites and montmorillonites, beidellites, saponites, nontronites, sepiolites, biotites, attapulgites, vermiculites and zeolites. Preferably, the clay is selected from hectorites and bentonites.

[0070] The lipophilic hectorite suitable for implementing the invention can be selected from among the modified hectorites with the following INCI names: Disteardimonium hectorite, Stearalkonium Hectorites, Quaternium-18 Hectorite, alone or in mixtures. Preferably, the composition includes Disteardimonium hectorite.

[0071] The lipophilic bentonite suitable for implementing the invention can be chosen from the following INCI bentonites: Quaternium-18 bentonites, Stearalkonium Bentonites, Quaternium-18 / Benzalkonium Bentonite, alone or in mixtures.

[0072] Preferably, the lipophilic clay comprising at least one quaternary ammonium group is in powder form. More particularly, it is not used in an activated form. Thus, the lipophilic clay comprising at least one quaternary ammonium group is not in a form pre-dispersed in a solvent chosen, for example, from among C1-C2 alcohols, such as methanol, ethanol; propylene carbonate, triethyl citrate, and mixtures thereof.

[0073] Among the modified hectorites usable within the scope of the invention, the following may be mentioned: *among Disteardimonium Hectorite: Bentone 38V CG; *among the Stearalkonium Hectorite: the Bentone 27V; marketed by the company Elementis Specialties.

[0074] Among the modified bentonites usable within the scope of the invention, the following may be mentioned, alone or in mixtures: *among the quatemium-18 bentonites: Bentone 34 marketed by Elementis Specialties; Claytone 40, Tixogel VP marketed by BYK Additives Inc; *among the Stearalkonium Bentonites, Tixogel VZ, Claytone AF, Claytone APA marketed by BYK Additives Inc; *among the Quatemium-18 / Benzalkonium Bentonite: Claytone HT marketed by BYK Additives Inc.

[0075] According to a preferred embodiment, the lipophilic clay-type filler comprising at least one quaternary ammonium group is selected from lipophilic hectorites comprising at least one quaternary ammonium group, in particular the disteardimonium hectorite.

[0076] As previously stated, the content of lipophilic clay comprising at least one quaternary ammonium group varies from 1 to 3% by weight, relative to the total weight of the composition. DIFFERENT CHARGES OF LIPOPHILE CLAY

[0077] According to a particular embodiment of the invention, the composition comprises a mineral and / or organic filler content of between 1 and 12% by weight, preferably between 1 and 10% by weight, relative to the total weight of the composition. MINERAL CHARGES

[0078] The term “mineral filler” means any compound whose chemical structure does not include a carbon atom, regardless of the presence of a coating on said filler.

[0079] The charges are in the form of particles and are distinct from the coloring materials which will be described below.

[0080] The fillers used in the compositions according to the present invention may be particles of lamellar, globular, spherical, fibrous, or any other intermediate shape between these defined forms. The fillers may be spherical, that is to say, comprising at least one generally rounded portion, in particular defining at least one portion of a sphere, preferably internally defining a concavity or a hollow (sphere, globules, bowls, horseshoe, etc.), or lamellar.

[0081] According to a particular embodiment of the invention, the charges more particularly have an average particle size (expressed as volume average diameter - D[0.5]) of at least 1 pm, preferably at least 2 pm, advantageously between 2 and 15 pm. The particle size can be measured by laser diffraction using a commercial particle size analyzer of the Mastersizer 3000 type, from Malvern. (see also ISO 13320).

[0082] The fillers used in the composition according to the invention may or may not be surface-coated, and in particular, they may be coated with a hydrophobic treatment agent, particularly one that promotes the dispersion and compatibility of the filler within the composition. The hydrophobic treatment agent may be selected from silicones, particularly silanes; fluorinated derivatives; fatty acids such as stearic acid; metallic soaps such as aluminum dimyristate, aluminum salt of hydrogenated tallow glutamate; amino acids; N-acylated amino acids or their salts; lecithin, isopropyl trisostearyl titanate, and mixtures thereof. The N-acylated amino acids may comprise an acyl group having from 8 to 22 carbon atoms, such as, for example, a 2-ethylhexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl, cocoyl. The salts of these compounds can be aluminum, magnesium, calcium, zirconium, zinc, sodium, or potassium salts. The amino acid can be, for example, lysine, glutamic acid, or alanine. The term alkyl(e) mentioned in the compounds cited above refers specifically to an alkyl group having from 1 to 30 carbon atoms, preferably having from 5 to 16 carbon atoms.

[0083] Such charges are advantageously chosen from among:

[0084] - Silica (INCI name: Silica), preferably in the form of particles spherical, such as porous silica microspheres sold under the name Silica Beads SB-700 by Myoshi; "Sunsphere H51", "Sunsphere H33" by Asahi Glass; amorphous silica microspheres coated with polydimethyl-siloxane sold under the name "SA Sunsphere H 33", "SA Sunsphere H53" by Asahi Glass; hollow silica microspheres.

[0085] - Perlite such as that marketed by the company World Minerals under the name commercial name Perlite P1430, Perlite P2550, Perlite P2040, or OpTiMatTM 1430 OR or 2550 OR. Europerl EMP-2 and Europerl 1 by the company Imerys.

[0086] - Zeolites such as the products marketed by the company Zeochem under the names ZeoFlair 300, Zeoflair 200, Zeoflair 100, X-MOL and X-MOL MT.

[0087] - Calcium magnesium carbonate particles such as those commercially available by Imerys under the name Calcidol, by LCW (Sensient) under the name Carbomat, by Omya under the name Omyacare S 60-AV. Calcium carbonate, magnesium carbonate, magnesium hydrogen carbonate, and hydroxyapatite are also suitable.

[0088] - Kaolin and talc particles, for example, marketed under the ranges Imercare, Imercare Pharma; Luzenac Pharma by the company Imerys; Rose Talc by the company Nippon Talc.

[0089] - Natural or synthetic mica, such as the product with the INCI name Synthetic Fluor- phlogopite, and marketed under the names RonaFlair Silk Mica by Merck, Sericite PHN by Presperse, NHS-100 and NHS-150 by Myoshi Kasei, those marketed under the names PDM-NSO or FNK-100 by Topy.

[0090] - Boron nitride; silica and titanium dioxide composites, such as the series TSG® marketed by Nippon Sheet Glass; bismuth oxychloride;

[0091] - Glass or ceramic microcapsules; such as, for example, particles borosilicate.

[0092] - their mixtures.

[0093] Preferably, the composition according to the invention comprises, as a mineral filler, kaolin, mica, and optionally silica, as well as mixtures thereof.

[0094] According to a particularly advantageous embodiment of the invention, the mineral filler content represents from 1 to 12% by weight, preferably from 1 to 10% by weight, relative to the total weight of the composition. ORGANIC LOADS

[0095] By "organic charge" we mean, in the sense of the invention, solid particles of at least one hydrocarbon compound, silicone compound, or combinations thereof, regardless of their coating.

[0096] The fillers are in the form of particles and may also be surface treated or not, by means of compounds such as those described above in the context of mineral fillers.

[0097] The fillers used in the compositions according to the present invention may be of lamellar, globular, spherical, fibrous, or any other intermediate form between these defined forms. The fillers may be spherical, that is to say, comprising at least one generally rounded portion, in particular defining at least one portion of a sphere, preferably internally defining a concavity or a hollow (sphere, globules, bowls, horseshoe, etc.), or lamellar.

[0098] Suitable loads include:

[0099] - Micronized waxes, natural or synthetic.

[0100] - Metallic soaps derived from carboxylic organic acids having from 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms, for example, zinc, magnesium or lithium stearate, zinc laurate, magnesium myristate.

[0101] - Natural organic materials such as polysaccharide powders, and in particular particularly starch powders, in particular corn, wheat or rice starches, crosslinked or not, starch powders crosslinked by octenylsuccinate anhydride, marketed under the name Dry-Flo® by the company National Starch, waxy corn starch powders such as those marketed under the names C* GEL 04201 by the company Cargill, Corn Starch B by the company Roquette, and Organic Corn Starch by the company Draco Natural Products.

[0102] - Cellulose, particularly in the form of spherical particles, such as products of the Cellulobeads D-10, Cellulobeads D-5 and Cellulobeads USF type marketed by the company Daito Kasei Kogyo.

[0103] - N-acylated amino acids with C8-C22 carbon atoms, the amino acid can be For example, lysine, glutamic acid, alanine, preferably lysine. One example is lauroyl lysine, marketed notably under the names Amihope LL by Ajinomoto or Corum 5105 by Corum.

[0104] - Acrylic (co)polymer particles, and their derivatives, in particular: * of polymethyl methacrylate (INCI name Methyl Methacrylate Crosspolymer), sold under the name Covabead LH85 by the company Sensient, or as Polymethyl Methacrylate, under the names Sepimat P by the company SEPPIC, Mi-crosphere M-100® by the company Matsumoto Yushi-Seiyaku; * of methyl polymethacrylate / ethylene glycol dimethacrylate (INCI name Methyl Methacrylate / Glycol Dimethacrylate Crosspolymer) sold under the name Dow Corning 5640 Microsponge Skin Oil Adsorber by the company Dow Corning; * crosslinked acrylate (INCI name: Acrylates Crosspolymer) marketed, for example, under the name Ganzpearl GMP-0820 by the company Ganz Chemical, * of allyl polymethacrylate / ethylene glycol dimethacrylate sold under the name Poly-Pore L200, Poly-Pore E200 by Amcol Health and Beauty Solutions Inc., * of ethylene glycol dimethacrylate / lauryl methacrylate copolymer (INCI name: Lauryl Methacrylate / Glycol Dimethacrylate Crosspolymer) sold under the name Polytrap 6603 Adsorber by Amcol Health and Beauty Solutions Inc.; * of crosslinked acrylate / alkyl acrylate copolymer (INCI name: Acrylates / Ethylhexyl Acrylate Crosspolymer) sold under the name Techpolymer ACP-8C by the company Sekisui Plastics, * ethylene-acrylate copolymer, such as that marketed under the name Flobeads® by Sumitomo Seika Chemicals.

[0105] - acrylonitrile (co)polymer particles, in particular hollow particles expanded products sold under the name Expancel by Akzo Nobel, or microspheres marketed under the name Micropearl F 80 ED® by Matsumoto.

[0106] - Polyurethane particles, for example sold under the designations D- 400, D-800 (INCI name: HDI / Trimethylol Hexyllactone Crosspolymer (and) Silica), CS-400 (INCI name: HDI / PPG / Polycaprolactone Crosspolymer (and) Silica), by the Toshiki company.

[0107] - Siliconized polymer particles, advantageously selected from: * silicone resin particles such as those with the INCI name Polymethylsilses-quioxane, notably marketed under the name Tospearl, in particular Tospearl 145 A, by the company Momentive Performance Materials, * silicone elastomer particles coated with silicone resin, in particular silsesquioxane resin, such as the products marketed under the name KSP-100, KSP-101, KSP-102, KSP-103, KSP-104, KSP-105 (INCI name: Vinyl Di-methicone / Methicone Silsesquioxane Crosspolymer), or KSP-300 (INCI name: Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer) by the company Shin Etsu; *silicone elastomer particles such as products marketed under the name Dowsil 9506 Cosmetic Powder, by the company Dow Corning (INCI name: Dimethicone / Vinyl Dimethicone Crosspolymer); * Methylsilanol / Silicate Crosspolymer particles, for example in the form of bowls such as those marketed under the name TAK-110 by the company Takemoto Oil & Fat.

[0108] - Polyamide particles, such as Nylon®, in particular Nylon 12, Nylon 6 / 12; like the nylon powders sold under the names Orgasol 2002 EXS NAT COS, Orgasol 4000 EXD NAT COS Caresse, by the company Arkema.

[0109] - Tetrafluoroethylene (Teflon®) polymer particles.

[0110] Preferably, if the composition includes it, the organic charge can be chosen from cellulose particles, C8-C22 N-acylated amino acid particles such as lauroyl-lysine, as well as mixtures thereof, and even more preferably cellulose particles.

[0111] According to a particular embodiment of the invention, the organic filler content represents 1 to 10% by weight, relative to the total weight of the composition.

[0112] According to a particularly advantageous embodiment of the present invention, the composition may not include polymeric organic fillers, which are considered microplastics. It should be noted that, for the purposes of this invention, "microplastics" means solid, shape-stable polymer particles comprising carbon atoms in the polymer backbone, of synthetic origin or of chemically modified natural origin, insoluble in water (i.e., less than 2 g / L; OECD Directive 105), and smaller than 5 mm in size (and smaller than 15 mm for fibers). "Shape-stable" means particles that remain solid in the composition and after its use. For example, polymer particles that form a film in the composition or during its use are not considered to be shape-stable.Preferably, the composition according to the invention may not include particles of acrylic polymers or copolymers, acrylonitril, polyurethane, polyamides, tetrafluoroethylene polymers, or silicone polymers, as described above. If, however, it does include such particles, their content would preferably be less than 5% by weight, more particularly less than 2% by weight, and advantageously less than 1% by weight, relative to the total weight of the composition. Preferably, if the composition does include such particles, the content of the aforementioned microplastic-type organic fillers would be less than or equal to 0.01% by weight, relative to the total weight of the composition, and most advantageously, the composition would be free of them.

[0113] Preferably, the composition may comprise at least one mineral filler The composition may be chosen from kaolin, mica, and possibly silica, and mixtures thereof. It may also include at least one organic filler, particularly cellulose, C8-C22 N-acylated amino acids such as lauroyl lysine, and mixtures thereof. Preferably, the organic filler is chosen from cellulose.

[0114] The total content of filler(s) (therefore taking into account the lipophilic clay comprising at least one quaternary ammonium group described previously), advantageously represents from 1 to 15% by weight, more particularly from 5 to 15% by weight, and even more particularly between 7 and 13% by weight, relative to the total weight of the composition. SILICONE ELASTOMER

[0115] The composition according to the invention further comprises at least one silicone elastomer carried in at least one oil identical or different from the first or second oil.

[0116] For the purposes of this invention, "carried" means that the silicone elastomer is supplied to the composition in a pre-dispersed form in at least one oil. More particularly, the elastomer is in the form of a homogeneous mixture of elastomer particles dispersed in said oil, stable for at least 24 hours at 20°C. Preferably, this elastomer is in the form of a gel in at least one first oil. In particular, a silicone elastomer powder suspended in at least one such oil is not considered, for the purposes of this invention, to be an organopolysiloxane elastomer carried in at least one oil.

[0117] The terms "silicone elastomer," "siliconized elastomer," or "polyorganosiloxane elastomer" refer to a cross-linked, flexible, deformable organopolysiloxane with viscoelastic properties, particularly the consistency of a sponge or a soft sphere. Its modulus of elasticity is such that this material resists deformation and has a limited capacity for extension and contraction. This material is capable of returning to its original shape after stretching.

[0118] In these gels, the organopolysiloxane particles can be spherical or non-spherical particles.

[0119] The silicone elastomer present in the composition according to the invention is preferably a non-emulsifying silicone elastomer.

[0120] The term "non-emulsifying" defines silicone elastomers not containing a hydrophilic chain, and in particular not containing polyoxyalkylene motifs (in particular polyoxyethylene or polyoxypropylene), nor polyglyceryl motifs.

[0121] Thus, the silicone elastomer can be obtained by addition crosslinking reaction of diorganopolysiloxane containing at least one hydrogen bonded to silicon and diorgano-polysiloxane having ethylenic unsaturated groups bonded to silicon, or of hydrocarbon chain having an ethylenic unsaturation at each end, particularly in the presence of platinum catalyst; or by condensation crosslinking dehydrogenation reaction between a hydroxyl-terminated diorganopolysiloxane and a diorganopolysiloxane containing at least one hydrogen bonded to silicon, particularly in the presence of an organotin; or by condensation crosslinking reaction of a hydroxyl-terminated diorganopolysiloxane and a hydrolyzable organopolysilane; or by thermal crosslinking of organopolysiloxane, particularly in the presence of organoperoxide catalyst; or by crosslinking of organopolysiloxane by high-energy radiation such as gamma rays, ultraviolet rays, electron beam.

[0122] Preferably, the organopolysiloxane elastomer is obtained by addition crosslinking reaction (A) of diorganopolysiloxane containing at least two hydrogens each bonded to a silicon, and (B) of diorganopolysiloxane having at least two ethylenic unsaturated groups bonded to silicon, in particular in the presence (C) of platinum catalyst, as for example described in application EP-A-295886.

[0123] In particular, the organopolysiloxane elastomer can be obtained by reaction of dimethylpolysiloxane with dimethylvinylsiloxy terminations and methylhydrogenopolysiloxane with trimethylsiloxy terminations, in the presence of platinum catalyst.

[0124] Compound (A) is the basic reagent for the formation of organopolysiloxane elastomer and crosslinking is carried out by addition reaction of compound (A) with compound (B) in the presence of catalyst (C).

[0125] Compound (A) is in particular an organopolysiloxane having at least two hydrogen atoms bonded to distinct silicon atoms in each molecule.

[0126] Compound (A) may have any molecular structure, including a linear chain structure or a branched chain structure or a cyclic structure.

[0127] Compound (A) may have a viscosity at 25°C ranging from 1 to 50,000 centistokes, in particular to be well miscible with compound (B).

[0128] The organic groups bonded to the silicon atoms of compound (A) may be alkyl groups such as methyl, ethyl, propyl, butyl, octyl; substituted alkyl groups such as 2-phenylethyl, 2-phenylpropyl, 3,3,3-trifluoropropyl; aryl groups such as phenyl, tolyl, xylyl; substituted aryl groups such as phenylethyl; and substituted monovalent hydrocarbon groups such as an epoxy group, a carboxylate ester group, or a mercapto group.

[0129] Compound (A) can thus be chosen from trimethylsiloxy-terminated methylhydrogenopolysiloxanes, trimethylsiloxane-methylhydrogenosiloxane-terminated dimethylsiloxane copolymers, and dimethylsiloxane-methylhydrogenosiloxane cyclic copolymers.

[0130] Compound (B) is advantageously a diorganopolysiloxane having at least two lower alkenyl groups (for example, at C2-C4); the lower alkenyl group may be selected from vinyl, allyl, and propenyl groups. These groups The lower alkenyl groups can be located at any position of the organopolysiloxane molecule but are preferably located at the ends of the organopolysiloxane molecule. The organopolysiloxane (B) can have a branched-chain, linear-chain, cyclic, or network structure, but the linear-chain structure is preferred. Compound (B) can have a viscosity ranging from the liquid to the gum-like state. Preferably, compound (B) has a viscosity of at least 100 centistokes at 25 °C.

[0131] Besides the aforementioned alkenyl groups, the other organic groups bonded to the silicon atoms in the compound (B) may be alkyl groups such as methyl, ethyl, propyl, butyl or octyl; substituted alkyl groups such as 2-phenylethyl, 2-phenylpropyl or 3,3,3-trifluoropropyl; aryl groups such as phenyl, tolyl or xylyl; substituted aryl groups such as phenylethyl; and substituted monovalent hydrocarbon groups such as an epoxy group, a carboxylate ester group, or a mercapto group.

[0132] Organopolysiloxanes (B) may be selected from methylvinylpolysiloxanes, methylvinylsiloxane-dimethylsiloxane copolymers, dimethylpolysiloxanes with dimethylvinylsiloxy terminations, dimethylsiloxane-methylphenylsiloxane copolymers with dimethylvinylsiloxy terminations, dimethylsiloxane-diphenylsiloxane-methylvinylsiloxane copolymers with dimethylvinylsiloxy terminations, dimethylsiloxane-methylvinylsiloxane copolymers with trimethylsiloxy terminations, dimethylsiloxane-methylphenylsiloxane-methylvinylsiloxane copolymers with trimethylsiloxy terminations, methyl(3,3,3-trifluoropropyl)-polysiloxane with dimethylvinylsiloxy terminations, and copolymers dimethylsiloxane-methyl(3,3,3-trifluoropropyl)siloxane with dimethylvinylsiloxy endings.

[0133] In particular, the organopolysiloxane elastomer can be obtained by reaction of dimethylpolysiloxane with dimethylvinylsiloxy terminations and methylhydrogenopolysiloxane with trimethylsiloxy terminations, in the presence of platinum catalyst.

[0134] Advantageously, the sum of the number of ethylenic groups per molecule of compound (B) and the number of hydrogen atoms bonded to silicon atoms per molecule of compound (A) is at least 5.

[0135] It is advantageous that compound (A) be added in such an amount that the molecular ratio between the total amount of hydrogen atoms bonded to silicon atoms in compound (A) and the total amount of all ethylenic unsaturating groups in compound (B) is in the range of 1.5 / 1 to 20 / 1.

[0136] Compound (C) is the catalyst for the crosslinking reaction, and is in particular chloroplatinic acid, chloroplatinic acid-olefin complexes, chloroplatinic acid-alkenylsiloxane complexes, chloroplatinic acid-diketone complexes, black platinum, and platinum on support.

[0137] The catalyst (C) is preferably added from 0.1 to 1,000 parts by weight, better from 1 to 100 parts by weight, as pure platinum metal for 1,000 parts by weight of the total quantity of compounds (A) and (B).

[0138] Non-emulsifying elastomers are described in particular in patents EP 242 219, EP 295 886, EP 765 656 and in application JP-A-61-194009.

[0139] In particular, the silicone elastomer used in the present invention is selected from the following INCI name compounds: Dimethicone Crosspolymer, Dimethicone / Vinyl Dimethicone Crosspolymer, Dimethicone / Lauryl Dimethicone Crosspolymer, Dimethicone / Vinyltrimethylsiloxysilicate Crosspolymer, Dimethicone Crosspolymer-3, and preferably from Dimethicone Crosspolymer.

[0140] As mentioned previously, the elastomer present in the composition according to the invention is in a form carried in an oil which may be identical or different from the first and second oils, as well as the additional oils, described previously and to whose descriptions reference may be made.

[0141] Thus, the oil is chosen from among silicone oils, from among polar or non-polar hydrocarbon oils, volatile or non-volatile, preferably non-volatile.

[0142] According to a first embodiment of the invention, the oil is chosen from among volatile, linear or cyclic silicone oils, preferably linear.

[0143] According to a second embodiment, the oil is chosen from non-volatile phenylated or non-phenylated silicone oils, in particular with the following INCI names: Dimethicone, Methyl Trimethicone, Phenyl Methicone, Phenyl Dimethicone and Phenyl Trimethicone, preferably a linear silicone oil chosen from those of the Dimethicone type, in particular with a viscosity at 25°C ranging from 5 to 500 at 25°C.

[0144] According to a final particular embodiment of the invention, the oil is chosen from volatile hydrocarbon oils, for example isododecane, or non-volatile polar oils such as esters, such as triethylhexanoin and vegetable oils.

[0145] As non-emulsifying elastomers, those sold under the names KSG-6, KSG-15, KSG-16, KSG-016F, KSG-18A, KSG-41, KSG-42, KSG-43, KSG-44, USG-102, USG-103, USG-105, USG-106 and USG-107A, by the company Shin Etsu, can be used in particular; Dowsil DC9040 Silicone Elastomer Blend, Dowsil DC9041 Silicone Elastomer Blend, Dowsil 9045 Silicone Elastomer Blend, Dowsil 9350 Elastomer Blend, Dowsil 9546 Silicone Elastomer Blend, Dowsil EL-9240 Silicone Elastomer Blend, Dowsil EL-9241 Silicone Elastomer Blend, Dowsil EL-9140 DM Silicone Elastomer Blend, by Dow Chemical Company; SFE 839 Gel by Momentive Performance Materials.

[0146] The silicone elastomer content, expressed as active material, varies from 1 to 5% by weight, preferably from 2.5 to 4.5% by weight, very advantageously between 3 and 4% by weight, relative to the total weight of the composition. WAXES

[0147] The composition according to the invention preferably comprises at least one wax.

[0148] For the purposes of this invention, "wax" means a lipophilic compound, solid at room temperature (25°C), with a reversible solid / liquid change of state, having a melting point greater than or equal to 30°C and up to 120°C.

[0149] For the purposes of the invention, the melting temperature corresponds to the temperature of the most endothermic peak observed in thermal analysis (DSC) as described in ISO 11357-3; 1999. The melting point of the wax can be measured using a differential scanning calorimeter (DSC), for example the calorimeter sold under the name "DSC Q2000" by TA Instruments with the "TA Universal Analysis" software.

[0150] The measurement protocol is as follows: A 5 mg sample of wax is placed in a crucible and subjected to a first temperature increase from -20°C to 120°C, at a heating rate of 10°C / minute, then is cooled from 120°C to -20°C at a cooling rate of 10°C / minute and finally subjected to a second temperature increase from -20°C to 120°C at a heating rate of 5°C / minute. During the second temperature rise, the melting point of the solid fat is measured, corresponding to the temperature of the most endothermic peak of the observed melting curve, representing the variation of the difference in absorbed power as a function of temperature. The enthalpy of fusion of the wax (AHf) can also be measured, corresponding to the integral of the entire melting curve obtained. This enthalpy of fusion of the wax is the amount of energy required to change the compound from a solid to a liquid state. It is expressed in J / g.

[0151] Waxes may be siliconed and preferably hydrocarbon-based. They may also be of vegetable, mineral, animal and / or synthetic origin.

[0152] In particular, the waxes have a melting temperature preferably greater than or equal to 35°C and better greater than or equal to 40°C. NON-POLAR WAXES

[0153] By "nonpolar hydrocarbon wax", in the context of the present invention, means a wax consisting solely of carbon and hydrogen atoms and free from heteroatoms, such as for example N, O, Si, P....

[0154] Examples of non-polar waxes suitable for the invention include hydrocarbon waxes such as microcrystalline waxes, paraffin waxes, ozokerite, polymethylene waxes, polyethylene waxes, Fischer-Tropsch waxes (or Synthetic Wax), and micro-waxes, particularly polyethylene. POLAR HYDROCARBONATE WAXES

[0155] Polar waxes can in particular be hydrocarbon-based.

[0156] For the purposes of this invention, "polar hydrocarbon wax" means a wax whose chemical structure is essentially formed, or even composed, of carbon and hydrogen atoms, and comprising at least one heteroatom, more particularly selected from oxygen, possibly nitrogen, or mixtures thereof. It may thus contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

[0157] As a hydrocarbon polar wax, a wax chosen from ester waxes and alcohol waxes is preferred.

[0158] According to the invention, "ester wax" means a wax comprising at least one ester function. Ester waxes may also be hydroxylated.

[0159] By "alcohol wax", according to the invention, a wax comprising at least one alcohol function, that is to say comprising at least one free hydroxyl (OH) group.

[0160] In particular, it can be used as an ester wax, alone or in mixtures: (i) Waxes of the formula RiCOOR2, in which Ri and R2 represent linear, branched, or cyclic aliphatic chains with a number of atoms ranging from 6 to 50, particularly from 10 to 50, which may contain a heteroatom such as, for example, oxygen or nitrogen, and whose melting point ranges, more specifically, from 30 to 120°C. In particular, an alkyl (hydroxystearyloxy)stearate in C2O-C4O (the alkyl group comprising 20 to 40 carbon atoms), alone or in a mixture, or an alkyl stearate in C2O-C4O, can be used as an ester wax. Such waxes are sold, in particular, under the names "Kester Wax K 82 P®", "Hydroxypolyester K 82 P®", "Kester Wax K 80 P®", or "Kester Wax K82H" by the company Koster Keunen. Stearyl heptanoate and stearyl caprylate and their mixtures can also be used. ii) di-(trimethyloi-1,1,1-propane tetrastearate, iii) diester waxes of a dicarboxylic acid of general formula R3-(-OCO-R4-COO-R5), wherein R3 and R5 are identical or different, preferably identical, and represent a C4-C30 alkyl group, and R4 represents a linear or branched C4-C30 aliphatic group, which may or may not contain one or more unsaturates. Preferably, the C4-C30 aliphatic group is linear and unsaturated. (iv) We can also mention waxes obtained by catalytic hydrogenation of animal or vegetable oils having, in particular, linear or branched fatty chains in the C8-C32 range, for example, hydrogenated jojoba oil, hydrogenated sunflower oil, hydrogenated castor oil, hydrogenated coconut oil, as well as waxes obtained by hydrogenation of esterified castor oil with cetyl alcohol, such as those sold in the Phytowax Castor range, for example Phytowax Castor 22L73®, or waxes obtained by hydrogenation of esterified olive oil with alcohol Stearyl waxes, such as those in the Phytowax Olive range, for example Phytowax Olive 18L57, marketed by the company Sophim. Such waxes are described in particular in application FR2792190. (v) Waxes corresponding to partial or total esters, preferably total, of a saturated, possibly hydroxylated, C16-C3O carboxylic acid with glycerol. By total esters, it is understood that all the hydroxyl groups of glycerol are esterified. Examples include trihydroxystearine (or glyceryl trihydroxystearate), tristearine (or glyceryl tristearate), and tribehenin (or glyceryl tribehenate), alone or in mixtures. Suitable compounds include triesters of glycerol and 12-hydroxystearic acid, or of hydrogenated castor oil, such as Thixcin R and Thixcin E, marketed by Elementis Specialties. vi) We can also mention waxes of animal or vegetable origin, such as beeswax, synthetic beeswax, camauba wax, candelilla wax, rice bran wax, Ouricury wax, Alfa wax, cork fiber wax, sugar cane wax, Japanese wax, sumac wax, montan wax, orange wax, laurel wax, sunflower wax, particularly refined. vii) We can also mention hydrocarbon waxes, polyoxyalkylated or polyglycerolated, natural or synthetic, of animal or vegetable origin; the number of oxyalkylated units (in C2-C4) can vary from 2 to 100, the number of glycerol units can vary from 1 to 20. By way of example, we can mention polyoxyethylenated beeswaxes, such as PEG-6 beeswax, PEG-8 beeswax; polyoxyethylenated carnauba waxes, such as PEG-12 carnauba; lanolin waxes, hydrogenated or not, polyoxyethened or polyoxypropylenated, such as PEG-30 lanolin, PEG-75 lanolin; PPG-5 lanolin wax glyceride; polyglycerol beeswax, including polyglyceryl-3 Beewax, the Acacia Decurrens / Jojoba / Sunflower Seed Wax / Polyglyceryl-3 Esters blend, polyglycerol vegetable waxes such as mimosa, jojoba, sunflower waxes, and their blends (Acacia Decurrens / Jojoba / Sunflower Seed Wax Polyglyceryl-3 Esters). SILICONE WAXES

[0161] By "siliconized wax" is meant a wax comprising at least one silicon atom, and in particular comprising Si-O groups.

[0162] Examples of silicone waxes include mixtures containing a compound of the type C30-45 Alkyldimethylsilyl Polypropylsilsesquioxane (INCI name), such as Dow Corning SW-8005 C30 Resin Wax, marketed by Dow Corning. Examples also include mixtures containing a compound of the type C30-45 Alkyl Methicone (INCI name), such as Dow Corning® AMS-C30 Cosmetic Wax. Beeswax is another example. silicone-coated.

[0163] Preferably, if the composition includes it, the wax is chosen from among hydrocarbon waxes. More particularly, it is chosen from among non-polar waxes; polar hydrocarbon waxes such as waxes of animal or vegetable origin, waxes of animal or vegetable origin obtained by catalytic hydrogenation of animal or vegetable oils; as well as mixtures thereof; and preferably from among non-polar hydrocarbon waxes, such as, for example, polyethylene wax, microcrystalline wax, synthetic wax, as well as from among polar hydrocarbon waxes such as, in particular, hydrogenated jojoba oil.

[0164] Preferably, the wax content varies advantageously from 6 to 18% by weight, in particular from 8 to 15% by weight, relative to the total weight of the composition. PASTY HYDROCARBON COMPOUNDS

[0165] The composition according to the invention preferably comprises at least one pasty hydrocarbon compound.

[0166] For the purposes of this invention, "pasty compound" means a lipophilic fatty compound with a reversible solid / liquid phase change, comprising a liquid fraction and a solid fraction at a temperature of 20°C. Thus, a pasty compound may have a starting melting point below 20°C.

[0167] The melting point of the pasty fat is determined according to the same principle as that detailed previously for waxes. In the case of a pasty compound, however, the measurement protocol is as follows: A 5 mg sample of pasty fat placed in a crucible is subjected to a first temperature increase from -20°C to 100°C, at a heating rate of 10°C / minute, then is cooled from 100°C to -20°C at a cooling rate of 10°C / minute and finally subjected to a second temperature increase from -20°C to 100°C at a heating rate of 5°C / minute. The melting point of the pasty fat is the temperature value corresponding to the peak of the curve representing the variation of the difference in absorbed power as a function of temperature. It should be noted that the liquid fraction by weight of the pasty fat at room temperature is equal to the ratio of the enthalpy of fusion consumed at room temperature to the enthalpy of fusion of the pasty fat. The enthalpy of fusion of a fat in a paste form is the enthalpy consumed by the fat to change from a solid to a liquid state. A fat in a paste form is said to be in a solid state when its entire mass is in crystalline solid form. A fat in a paste form is said to be in a liquid state when its entire mass is in liquid form. The enthalpy of fusion of a fat in a paste form is the amount of energy required to change the fat in a paste form from a solid to a liquid state. It is expressed in J / g. The enthalpy of fusion of the pasty fat is equal to the value to be made under the curve of the obtained thermogram.

[0168] Preferably, this or these pasty hydrocarbon compound(s) are chosen from:

[0169] - vegetable butters, such as mango butter, such as that which marketed under the reference Lipex® 203 by the company AARHUSKARLSHAMN, shea butter, in particular that whose INCI name is BUTYROSPERMUM PARKII BUTTER, such as that marketed under the reference Sheasoft® by the company AARHUSKARLSHAMN, cupuacu butter (Rain forest RF3410 from the company Beraca Sabara), murumuru butter (RAIN FOREST RF3710 from the company Beraca Sabara), cocoa butter, babassu butter such as that marketed under the name Cropure® Babassu by Croda, as well as orange wax such, for example, that which is marketed under the reference Orange Peel Wax by the company Koster Keunen,

[0170] - vegetable oils that are totally or partially hydrogenated, such as by for example hydrogenated soybean oil, hydrogenated coconut oil, hydrogenated rapeseed oil, mixtures of hydrogenated vegetable oils such as the mixture of hydrogenated vegetable oil of soybean, coconut, palm and rapeseed, for example the mixture marketed under the reference Akogel® by the company AARHUSKARLSHAMN (INCI name HYDROGENATED VEGETABLE OIL), partially hydrogenated isomerized trans jojoba oil manufactured or marketed by the company Desert Whale under the commercial reference Iso-Jojoba-50®, partially hydrogenated olive oil such as, for example, the compound marketed under the reference Beurrolive by the company Soliance;

[0171] - hydrogenated castor oil esters and fatty acids in C16-C22, in particular isostearic acid such as SALACOS HCIS (VL) sold by NISSHIN OIL;

[0172] - esters resulting from the condensation of a linear or branched dicarboxylic acid, preferably saturated, in C6-C10 and of diglycerol ester and carboxylic monoacids, possibly hydroxylated, linear or branched, preferably saturated, in C6-C20, in particular the diester obtained by condensation of adipic acid and a mixture of diglycerol esters with a mixture of C6-C20 fatty acids such as stearic acid, capric acid, stearic acid, isostearic acid and 12-hydroxystearic acid, in particular marketed under the reference SOFTISAN® 649 by the company Cremer Oleo. (INCI name: BIS-DIGLYCERYL POLYACYLADIPATE-2);

[0173] - triglycerides of fatty acids, saturated or unsaturated, linear or branched, even typically mono- or poly-hydroxylated, preferably Ci2-Ci8, possibly hydrogenated (totally or partially); such as, for example, glycerides of acids saturated fats C12-C18 marketed under the name Softisan 100® by the company Cremer Oleo (INCI name: HYDROGENATED COCO-GLYCERIDES);

[0174] - diol dimer esters, or polyol esters, and diacid dimer esters such as example :

[0175] * the dimer esters of dilinoleic alcohol and dilinoleic acid whose groups hydroxyls are esterified by a mixture of phytosterols, behenyl alcohol and isostearyl alcohol, for example the ester sold under the name Plandool G by the company Nippon Fine Chemical (INCI name: BIS-BEHENYL / ISOSTEARYL / PHYTOSTERYL DIMER DILINOLEYL DIMER DILINOLEATE);

[0176] * esters of dilinoleic acid and a mixture of phytosterols, isopropyl alcohol tearyl, cetyl alcohol, stearyl alcohol and behenyl alcohol, for example the ester sold under the name Plandool H or Plandool S by the company Nippon Fine Chemical (INCI name: PHYTOSTERYL / ISOSTEARYL / CETYL / STEARYL / BEHENYL DIMER DILINOLEATE);

[0177] * hydrogenated castor oil esters and dilinoleic acid dimer, such as those sold under the names RISOCAST-DA-L or RISOCASTDA-H by the company KOKYU ALCOHOL KOGYO (INCI name: HYDROGENATED CASTOR OIL DIMER DILINOLEATE).

[0178] Preferably, if the composition includes them, the paste compound(s) are chosen from vegetable butters, partially hydrogenated vegetable oils, esters from the condensation of a linear or branched dicarboxylic acid in C6-Ci0 and ester of diglycerol and monocarboxylic acids, possibly hydroxylated, linear or branched, in C6-C20, triglycerides of fatty acids, saturated or unsaturated, linear or branched, possibly mono or polyhydroxylated, preferably Ci2-Ci8, and mixtures thereof.

[0179] Even more preferably, if the composition includes them, the paste compound(s) are chosen from vegetable butters, partially hydrogenated vegetable oils, compounds with INCI names BIS-DIGLYCERYL POLYACYLADIPATE-2 and HYDROGENATED COCO-GLYCERIDES, BIS-BEHENYL / ISOSTEARYL / PHYTOSTERYL DIMER DILINOLEYL DIMER DILINOLEATE, PHYTOSTERYL / ISOSTEARYL / CETYL / STEARYL / BEHENYL DIMER DILINOLEATE, HYDROGENATED CASTOR OIL DIMER DILINOLEATE, and mixtures thereof.

[0180] If the composition includes them, preferably their content varies from 6 to 20% by weight, in particular from 8 to 15% by weight, relative to the total weight of the composition. COLORING MATERIALS

[0181] According to a particular embodiment of the invention, the composition comprises at least one coloring material, synthetic, natural or of natural origin.

[0182] The colouring material may be chosen from coated or uncoated pigments, the fat-soluble dyes, and their mixtures PIGMENTS

[0183] “Pigments” means white or colored particles, mineral or organic, insoluble in an aqueous medium, intended to color the composition and / or the resulting deposit.

[0184] According to a particular embodiment, the pigments used according to the invention are chosen from mineral pigments.

[0185] The term "mineral pigment" means any pigment that meets the definition in the Ullmann Encyclopedia under the chapter on inorganic pigments. Examples of mineral pigments useful in the present invention include zirconium or cerium oxides, as well as zinc, iron (black, yellow, or red), or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue, titanium dioxide, and metallic powders such as aluminum powder and copper powder. The following mineral pigments may also be used: Ta2O5, Ti3O5, Ti2O3, TiO, and ZrO2 in mixtures with TiO2, ZrO2, Nb2O5, CeO2, and ZnS.

[0186] The size of the pigment used in the present invention is generally greater than 100 nm and can be up to 10 µm, preferably from 200 nm to 5 µm, and more preferably from 300 nm to 1 µm. According to a particular embodiment of the invention, the pigments have a size characterized by a D

[50] greater than 100 nm and can be up to 10 µm, preferably from 200 nm to 5 µm, and more preferably from 300 nm to 1 µm. The sizes are measured by laser diffraction using a commercial particle size analyzer of the MasterSizer 3000® type from Malvem, allowing the particle size distribution of all the particles to be determined over a wide range from 0.01 µm to 1000 µm. The data are processed based on the classical Mie scattering theory. This theory is best suited for size distributions ranging from submicron to multi-micron, it allows us to determine an "effective" particle diameter.This theory is notably described in the work of Van de Hulst, HC, "Light Scattering by Small Particles", Chapters 9 and 10, Wiley, New York, 1957. D

[50] represents the maximum size that 50% of the particles have by volume.

[0187] In the context of the present invention, the mineral pigments are more particularly iron oxide and / or titanium dioxide. By way of example, titanium dioxide and iron oxide coated with aluminum stearoyl glutamate, for example, marketed under the reference NAI® by MIYOSHI KASEI, may be cited more particularly.

[0188] As mineral pigments that can be used in the invention, nacres can also be mentioned. By "mother-of-pearl," we mean colored particles of any shape, iridescent or no, in particular, produced by certain molluscs in their shell or synthesized and which exhibit a color effect through optical interference. Pearlescent pigments can be chosen from pearlescent pigments, such as titanium mica coated with iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic dye, as well as bismuth oxychloride-based pearlescent pigments. They can also consist of mica particles on the surface of which at least two successive layers of metal oxides and / or organic colorants are superimposed. We can also cite, as an example of mother-of-pearl, natural mica covered with titanium dioxide, iron oxide, natural pigment or bismuth oxychloride. Mother-of-pearl can more specifically possess a yellow, pink, red, bronze, orange, brown, gold and / or copper color or reflection.

[0189] Among the pigments that can be used according to the invention, we can also mention those with an optical effect different from a simple conventional tint effect, that is to say unified and stabilized such as produced by classic coloring materials, such as monochromatic pigments. For the purposes of the invention, "stabilized" means free from any color variability effect with the angle of observation or in response to a change in temperature. For example, this material can be chosen from metallic-reflecting particles, goniochromatic coloring agents, diffracting pigments, thermochromic agents, optical brighteners, and, in particular, interference fibers. Of course, these different materials can be combined in such a way as to produce the simultaneous manifestation of two effects, or even a new effect according to the invention.

[0190] According to a particular mode, the composition according to the invention comprises at least one uncoated pigment.

[0191] According to another particular embodiment, the composition according to the invention comprises at least one pigment coated with at least one lipophilic or hydrophobic compound. This type of pigment is particularly advantageous. Insofar as they are treated with a hydrophobic compound, they exhibit a predominant affinity for an oily phase, which can then carry them. The coating may also comprise at least one additional non-lipophilic compound. For the purposes of the invention, "coating" of a pigment according to the invention generally refers to the total or partial surface treatment of the pigment by a surfactant, absorbed, adsorbed or grafted onto said pigment.

[0192] Surface-treated pigments can be prepared using surface treatment techniques of a chemical, electronic, mechano-chemical or mechanics well known to the skilled craftsman. Commercial products can also be used. The surfactant can be absorbed, adsorbed, or grafted onto the pigments by solvent evaporation, chemical reaction, and the formation of a covalent bond. In one variation, the surface treatment consists of coating the pigments. The coating can represent from 0.1% to 20% by weight, and in particular from 0.5% to 5% by weight, of the total weight of the coated pigment. The coating can be achieved, for example, by adsorption of a liquid surfactant onto the surface of solid particles by simple mixing under agitation of the particles and said surfactant, possibly hot, prior to the incorporation of the particles into the other ingredients of the makeup or skincare composition. The coating can be achieved, for example, by a chemical reaction between a surfactant and the surface of solid pigment particles, creating a covalent bond between the surfactant and the particles. This method is described in US patent 4,578,266. Chemical surface treatment may involve diluting the surfactant in a volatile solvent, dispersing the pigments in this mixture, and then slowly evaporating the volatile solvent so that the surfactant is deposited on the surface of the pigments. According to a particular embodiment of the invention, the pigments can be coated according to the invention by at least one compound selected from silicone surfactants; fluorinated surfactants; fluoro-siliconized surfactants; metallic soaps; N-acylated amino acids or their salts; lecithin and its derivatives; isopropyl trisostearyl titanate; isostearyl sebacate; natural vegetable or animal waxes; polar synthetic waxes; fatty esters; phospholipids; and mixtures thereof. According to a particular embodiment of the invention, the pigments can be coated by a hydrophilic compound.

[0193] According to a particular mode, the colouring material is an organic, synthetic, natural or naturally derived pigment. By "organic pigment," we mean any pigment that meets the definition in the Ullmann encyclopedia in the chapter on organic pigments. Organic pigments can be chosen from among the following compounds: nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, and quinophthalone.

[0194] The organic pigment(s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, blue of phthalocyanine, sorghum red, blue pigments coded in the Color Index under references CI 42090, 69800, 69825, 73000, 74100, 74160, yellow pigments coded in the Color Index under references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005, green pigments coded in the Color Index under references CI 61565, 61570, 74260, orange pigments coded in the Color Index under references CI 11725, 15510, 45370, 71105, red pigments coded in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470, and the pigments obtained by oxidative polymerization of indolic, phenolic derivatives as described in patent FR 2 679 771.

[0195] The pigments can also be in the form of composite pigments as described in patent EP 1 184 426. These composite pigments can be composed in particular of particles comprising an inorganic core covered at least partially with an organic pigment and at least one binder ensuring the fixation of the organic pigments on the core.

[0196] The pigment can also be a lacquer. By lacquer, we mean insolubilized dyes adsorbed onto insoluble particles, the whole thus obtained remaining insoluble during use. Examples of inorganic substrates on which dyes are adsorbed include alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate, and aluminum. Among the organic colorants, we can mention cochineal carmine. We can also mention the products known under the following names: D&C Red 21 (CI 45 380), D&C Orange 5 (CI 45 370), D&C Red 27 (CI 45 410), D&C Orange 10 (CI 45 425), D&C Red 3 (CI 45 430), D&C Red 4 (CI 15 510), D&C Red 33 (CI 17 200), D&C Yellow 5 (CI 19 140), D&C Yellow 6 (CI 15 985), D&C Green (CI 61 570), D&C Yellow 1 O (CI 77 002), D&C Green 3 (CI 42 053), D&C Blue 1 (CI 42 090). Examples of lacquers include the product known as D&C Red 7 (CI 15 850 :1). FAT-SOLUBLE DYES

[0197] For the purposes of this invention, "liposoluble colorant" means any compound, generally organic, natural or synthetic, soluble in an oily phase or solvents miscible with the oily phase and capable of coloring. Examples of suitable fat-soluble dyes for the invention include, for example, DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudanese red, Sudanese brown. As an illustration of natural fat-soluble colorants, we can particularly mention carotenes such as [3-carotene, a-carotene, lycopene; quinoline yellow; xanthophylls such as astaxanthin, antheraxanthin, citranaxanthin, cryptoxanthin, canthaxanthin, diatomoxanthin, flavoxanthin, fucoxanthin, lutein, rhodoxanthin, rubixanthin, siphonaxanthin, violaxanthin, zeaxanthin; annatto; curcumin; quinizarin (Ceres Green BB, D&C Green No. 6, CI 61565, 1,4-Di-p-Toluidinoanthraquinone, Green No. 202, Quinzaine Green SS) and chlorophylls.

[0198] According to a preferred embodiment of the invention, the composition comprises from 0.01 to 20% by weight, in particular from 1 to 15% by weight, and even more particularly from 3 to 15% by weight of coloring matter(s), relative to the total weight of the composition. The composition may also be free of coloring matter(s). WATER

[0199] The composition according to the invention may optionally include water. Preferably, the water content does not exceed 5% by weight, and more preferably does not exceed 2% by weight, relative to the total weight of the composition. Even more advantageously, the water content, if the composition includes water, does not exceed 1% by weight, in particular does not exceed 0.5% by weight, and even more particularly does not exceed 0.2% by weight, relative to the total weight of the composition. OPTIONAL ADJUVANTS

[0200] Within the framework of the present invention, the composition may further contain at least one optional adjuvant chosen from those commonly used in the cosmetic field, in particular for makeup and / or skin and lip care compositions.

[0201] Examples include lipophilic mineral thickening agents, organic thickeners such as dextrin esters; preservatives; antioxidants; complexing agents; solvents; active ingredients; perfumes; etc.

[0202] Among the lipophilic mineral thickeners, which are distinct from the mineral fillers mentioned above, we can cite the compounds chosen from those with the following INCI names: Silica Silylate, Silica Dimethyl Silylate, as well as their mixtures.

[0203] These adjuvants and their concentrations must be such that they do not modify the desired property of the composition of the invention.

[0204] These optional adjuvants may be present at a content of up to 15% by weight, relative to the total weight of the composition.

[0205] The following examples will help to better understand the invention, without however, it may have a limiting character.

[0206] Raw materials are named by their chemical name or INCI name.

[0207] The quantities indicated are as a percentage by weight of raw materials, except unless otherwise stated. EXAMPLES EXAMPLE 1

[0208] The following composition was prepared, the list of ingredients and their contents are summarized in the table below:

[0209] [Tables 1] Ingrédients Composition 1 Composition comparative A Disteardimonium Hectorite (BENTONE 38 VCG RHEOLOGICAL ADDITIVE; Elementis Specialties) 2,0 2,0 Hydrogenated Polyisobutene (Parleam, Nippon Oil & Fats) 3,9 3,9 Polyethylene (PERFORMALENE 500-L POLYETHYLENE, Nucera Solutions) 3,9 3,9 Bis-Diglyceryl Polyacyladipate-2 (SOFTISAN 649, Cremer Oleo) 9,3 9,3 Isohexadecane (Ineos) 18,8 Isododecane (Ineos) 18,8 Mica (MEARLMICA SV ; BASF) 3,0 3,0 Hydrogenated Jojoba OiL (JOJOBA WAX FLAKES, Desert Whale) 4,5 4,5 Isostearyl Isostearate 2,4 2,4 Trimethylsiloxyphenyl Dimethicone (Belsil PDM 1000, Wacker) 3,1 3,1 Tridecyl Trimellitate 3,4 3,4 Silica (SOLESPHERE H 51, AGC-Si Tech) 2,0 2,0 Antioxydant qs qs Dimethicone (and) Dimethicone Crosspolymer (DOWSIL EL-9241 DM SILICONE ELASTOMER BLEND;Dow Chemical) 25.0 25.0 Paraffin (and) Microcrystalline Wax (and) Synthetic Wax (PARACERA 30540, Paramelt) 2.6 2.6 Kaolin (IMERCARE 04K, Imerys) 3.0 3.0 Red 7 (and) Isopropyl Titanium Triisosteate (and) Triethoxysilylethyl Polydimethylsiloxyethyl Dimethicone 2.8 2.8 Yellow 6 Lake (and) Isopropyl Titanium Triisostearate 10.2 10.2; (and) Triethoxysilylethyl Polydimethylsiloxyethyl Dimethicone Preparation method:

[0210] 1. The oils (Hydrogenated Polyisobutene, Isostearyl) are mixed together while stirring. Isostearate, Tridecyl Trimellitate, Trimethylsiloxyphenyl Dimethicone) and the paste compound (Bis-Diglyceryl Polyacyladipate-2). 2. Once a homogeneous mixture has been obtained, the pigments are added while stirring and the mixture is heated to 45°C. 3. When the mixture is homogeneous, the isohexadecane or isododecane is added, while stirring.

[0211] 4. After homogenization of the mixture, the fillers (Kaolin, Silica, Distear- are added dimonium Hectorite, Mica) with stirring. 5. The whole is heated to 90°C and the waxes (polyethylene, hydrogenated jojoba oil) are introduced, then the silicone elastomer, under agitation. 6. After obtaining a homogeneous mixture, it is poured into molds and allowed to cool before unmolding and packaging the resulting lipstick tubes. Evaluation of compositions:

[0212] [Tables2] Composition 1 Comparative Composition A Hardness 134 g 150 g Gloss 24 0.8 Appearance of the stick Homogeneous without defects Homogeneous without defects Application Easy in a homogeneous, covering, intense, very matte finish with good long-lasting wear Very difficult to apply, difficult to blend, limited coverage, homogeneous and covering, intense, very matte, with good long-lasting wear Comfort Comfortable, does not dry out the lips Uncomfortable, very drying EXAMPLE 2

[0213] The following composition was prepared, the list of ingredients and their contents are summarized in the table below:

[0214] [Tables3] Ingrédients Composition 2 Disteardimonium Hectorite (BENTONE 38 VCG RHEOLOGICAL ADDITIVE; Elementis Specialties) 2 Hydrogenated Polyisobutene (Parleam, Nippon Oil & Fats) 3,9 Polyethylene (PERFORMALENE 500-L POLYETHYLENE, Nucera Solutions) 3,9 Bis-Diglyceryl Polyacyladipate-2 (SOFTISAN 649, Cremer Oleo) 9,3 Isohexadecane (Ineos) 18,8 Mica (MEARLMICA SV ; BASF) 3,0 Hydrogenated Jojoba Oil (JOJOBA WAX FLAKES, Desert Whale) 4,5 Isostearyl Isostearate 2,4 Trimethylsiloxyphenyl Dimethicone (Belsil PDM 1000, Wacker) 3,1 Tridecyl Trimellitate 3,4 Cellulose (CELLULOBEADS USF ; Daito Kasei Kogyo) 2,0 Antioxydant qs Dimethicone (and) Dimethicone Crosspolymer (DOWSIL EL-9241 DM SILICONE ELASTOMER BLEND;Dow Chemical) 25.0 Paraffin (and) Microcrystalline Wax (and) Synthetic Wax (PARACERA 30540, Paramelt) 2.6 Kaolin (IMERCARE 04K, Imerys) 3.0 Red 7 (and) Isopropyl Titanium Triisostearate (and) Triethoxysi-lylethyl Polydimethylsiloxyethyl Dimethicone 2.8 Yellow 6 Lake (and) Isopropyl Titanium Triisostearate (and) Trie-thoxysilylethyl Polydimethylsiloxyethyl Dimethicone 10.2; Preparation method:

[0215] 1. The oils (Hydrogenated Polyisobutene, Isostearyl) are mixed together while stirring. Isostearate, Tridecyl Trimellitate, Trimethylsiloxyphenyl Dimethicone) and the paste compound (Bis-Diglyceryl Polyacyladipate-2). 2. Once a homogeneous mixture has been obtained, the pigments are added while stirring and the mixture is heated to 45°C. 3. When the mixture is homogeneous, the isohexadecane is added while stirring.

[0216] 4. After homogenizing the mixture, the fillers (Kaolin, Cellulose, Dis- are added teardimonium Hectorite, Mica) with stirring. 5. The whole is heated to 90°C and the waxes (polyethylene, hydrogenated jojoba oil) are introduced, then the silicone elastomer, under agitation. 6. After obtaining a homogeneous mixture, it is poured into molds and allowed to cool before unmolding and packaging the resulting lipstick tubes. Evaluation of compositions:

[0217] [Tables4] Composition 2 Hardness 126 g Gloss 22 Stick Appearance Homogeneous without defects Application Easy to apply in a homogeneous, covering, intense, very matte finish, with good durability Comfort Comfortable, non-drying or slightly drying EXAMPLE 3

[0218] The following composition has been prepared, the list of ingredients and their contents are summarized in the table below:

[0219] [Tables5] Ingrédients Composition 3 Disteardimonium Hectorite (BENTONE 38 VCG RHEOLOGICAL ADDITIVE; Elementis Specialties) 2 Hydrogenated Polyisobutene (Parleam, Nippon Oil & Fats) 3,9 Polyethylene (PERFORMALENE 500-L POLYETHYLENE, Nucera Solutions) 3,9 Bis-Diglyceryl Polyacyladipate-2 (SOFTISAN 649, Cremer Oleo) 9,3 Isohexadecane (Ineos) 18,8 Mica (MEARLMICA SV ; BASF) 3,0 Hydrogenated Jojoba Oil (JOJOBA WAX FLAKES, Desert Whale) 4,5 Isostearyl Isostearate 2,4 Trimethylsiloxyphenyl Dimethicone (Belsil PDM 1000, Wacker) 3,1 Tridecyl Trimellitate 3,4 Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer (KSP-100; Shin-Etsu) 2,0 Antioxydant qs dimethicone (and) Dimethicone Crosspolymer (DOWSIL EL-9241 DM SILICONE ELASTOMER BLEND;Dow Chemical) 25.0 Paraffin (and) Microcrystalline Wax (and) Synthetic Wax (PARACERA 30540, Paramelt) 2.6 Kaolin (IMERCARE 04K, Imerys) 3.0 Red 7 (and) Isopropyl Titanium Triisostearate (and) Triethoxysi-lylethyl Polydimethylsiloxyethyl Dimethicone 2.8 Yellow 6 Lake (and) Isopropyl Titanium Triisostearate (and) Trie-thoxysilylethyl Polydimethylsiloxyethyl Dimethicone 10.2; Preparation method:

[0220] 1. The oils (Hydrogenated Polyisobutene, Isostearyl) are mixed together while stirring. Isostearate, Tridecyl Trimellitate, Trimethylsiloxyphenyl Dimethicone) and the paste compound (Bis-Diglyceryl Polyacyladipate-2). 2. Once a homogeneous mixture has been obtained, the pigments are added while stirring and the mixture is heated to 45°C. 3. When the mixture is homogeneous, the isohexadecane is added while stirring.

[0221] 4. After homogenization of the mixture, the fillers (Kaolin, Distear- dimonium Hectorite, KSP-100, Mica) under agitation. 5. The whole is heated to 90°C and the waxes (polyethylene, hydrogenated jojoba oil) are introduced, then the silicone elastomer, under agitation. 6. After obtaining a homogeneous mixture, it is poured into molds and allowed to cool before unmolding and packaging the resulting lipstick tubes. Evaluation of compositions:

[0222] [Tableauxô] Composition 3 Hardness 134 g Gloss 68 Stick Appearance Homogeneous without defects Application Easy to apply in a homogeneous, covering, intense, matte finish with good durability Comfort Comfortable, non-drying or slightly drying EXAMPLE 4

[0223] The following composition was prepared, the list of ingredients and their contents are summarized in the table below:

[0224] [Tables?] Ingrédients Composition 4 Disteardimonium Hectorite (BENTONE 38 VCG RHEOLOGICAL ADDITIVE; Elementis Specialties) 2 Hydrogenated Polyisobutene (Parleam, Nippon Oil & Fats) 5.5 Polyethylene (PERFORMALENE 500-L POLYETHYLENE, Nucera Solutions) 3,9 Bis-Diglyceryl Polyacyladipate-2 (SOFTISAN 649, Cremer Oleo) 13 Isohexadecane (Ineos) 10 Mica (MEARLMICA SV ; BASF) 3,0 Hydrogenated Jojoba Oil (JOJOBA WAX FLAKES, Desert Whale) 4,5 Isostearyl Isostearate 3.3 Trimethylsiloxyphenyl Dimethicone (Belsil PDM 1000, Wacker) 4.3 Tridecyl Trimellitate 4.7 Silica (SOLESPHERE H 51, AGC-Si Tech) 2.0 Antioxidant qs Dimethicone (and) Dimethicone Crosspolymer (DOWSIL EL-9241 DM SILICONE ELASTOMER BLEND; Dow Chemical) 25.0 Paraffin (and) Microcrystalline Wax (and) Synthetic Wax (PARACERA 30540, Paramelt) 2.6 Kaolin (IMERCARE 04K, Imerys) 3.0 Red 7 (and) Isopropyl Titanium Triisostearate (and) Triethoxysi-lylethyl Polydimethylsiloxyethyl Dimethicone 2.8 Yellow 6 Lake (and) Isopropyl Titanium Triisostearate (and) Trie-thoxysilylethyl Polydimethylsiloxyethyl Dimethicone 10.2. Preparation method:

[0225] 1. The oils (Hydrogenated Polyisobutene, Isostearyl Isostearate, Tridecyl Trimellitate, Trimethylsiloxyphenyl Dimethicone) and the paste compound (Bis-Diglyceryl Polyacyladipate-2) are mixed under agitation. 2. Once the homogeneous mixture is obtained, the pigments are added while stirring and the mixture is heated to 45°C. 3. When the mixture is homogeneous, the isohexadecane is added while stirring.

[0226] 4. After homogenization of the mixture, the fillers (Kaolin, Distear- dimonium Hectorite, KSP-100, Mica) under agitation. 5. The whole is heated to 90°C and the waxes (polyethylene, hydrogenated jojoba oil) are introduced, then the silicone elastomer, under agitation. 6. After obtaining a homogeneous mixture, it is poured into molds and allowed to cool before unmolding and packaging the resulting lipstick tubes. Evaluation of compositions:

[0227] [Tables8] Composition 3 Hardness 181g Gloss 27 Stick Appearance Homogeneous without defects Application Easy to apply in a homogeneous, covering, intense, very matte finish, with good durability Comfort Comfortable, non-drying or slightly drying EXAMPLE 5

[0228] The following comparative composition was prepared, the list of ingredients and contents of which are summarized in the table below:

[0229] [Tables9] Ingrédients Composition B Comparative Isododecane (and) Disteardimonium Hectorite (and) Propylene Carbonate (BENTONE GEL ISD V, Elementis Specialties) 2,0 Hydrogenated Polyisobutene (Parleam, Nippon Oil & Fats) 3,9 Polyethylene (PERFORMALENE 500-L POLYETHYLENE, Nucera Solutions) 3,9 Bis-Diglyceryl Polyacyladipate-2 (SOFTISAN 649, Cremer Oleo) 9,3 Isohexadecane (Ineos) 18,8 Mica (MEARLMICA SV ; BASF) 3,0 Hydrogenated Jojoba Oil (JOJOBA WAX FLAKES, Desert Whale) 4,5 Isostearyl Isostearate 2,4 Trimethylsiloxyphenyl Dimethicone (Belsil PDM 1000, Wacker) 3,1 Tridecyl Trimellitate 3,4 Silica (SOLESPHERE H 51, AGC-Si Tech) 2,0 Antioxydant qs Dimethicone (and) Dimethicone Crosspolymer (DOWSIL EL-9241 DM SILICONE ELASTOMER BLEND; Dow Chemical) 25,0 Paraffin (and) Microcrystalline Wax (and) Synthetic Wax (PARACERA 30540, Paramelt) 2,6 Kaolin (IMERCARE 04K, Imerys) 3,0 Red 7 (and) Isopropyl Titanium Triisostearate (and) Triethoxysi-lylethyl Polydimethylsiloxyethyl Dimethicone 2.8 Yellow 6 Lake (and) Isopropyl Titanium Triisostearate (and) Trie-thoxysilylethyl Polydimethylsiloxyethyl Dimethicone 10.2. Preparation method:

[0230] 1. The oils (Hydrogenated Polyisobutene, Isostearyl) are mixed together while stirring. Isostearate, Tridecyl Trimellitate, Trimethylsiloxyphenyl Dimethicone) and the paste compound (Bis-Diglyceryl Polyacyladipate-2) with activated hectorite (BENTONE GEL ISD V). 2. Once a homogeneous mixture is obtained, the pigments are added while stirring and It is heated to 45°C. 3. When the mixture is homogeneous, the isohexadecane is added while stirring.

[0231] 4. After homogenizing the mixture, the fillers (Kaolin, Silica, Mica) are added under agitation. 5. The whole is heated to 90°C and the waxes (polyethylene, hydrogenated jojoba oil) are introduced, then the silicone elastomer, under agitation. 6. After obtaining a homogeneous mixture, it is poured into molds and allowed to cool before unmolding and packaging the resulting lipstick tubes. Evaluation of compositions:

[0232] [TableauxlO] Composition 4 (comparative) Hardness 252 g Gloss 6.5 Appearance of the stick Homogeneous without defects Application Very hard stick, difficult to apply, slow to apply, the resulting coating is very matte Comfort Uncomfortable, drying Example 6

[0233] The following composition has been prepared, the list of ingredients and their contents are summarized in the table below:

[0234] [Tables 11] Ingrédients Composition 5 Disteardimonium Hectorite (BENTONE 38 VCG RHEOLOGICAL ADDITIVE; Elementis Specialties) 1.5 Hydrogenated Polyisobutene (Parleam, Nippon Oil & Fats) 7.2 Polyethylene (PERFORMALENE 500-L POLYETHYLENE, Nucera Solutions) 1.2 Bis-Diglyceryl Polyacyladipate-2 (SOFTISAN 649, Cremer Oleo) 17 Isohexadecane (Ineos) 6 Mica (MEARLMICA SV ; BASF) 3 Hydrogenated Jojoba Oil (JOJOBA WAX FLAKES, Desert Whale) 4,5 Isostearyl Isostearate 4.3 Trimethylsiloxyphenyl Dimethicone (Belsil PDM 1000, Wacker) 5.5 Tridecyl Trimellitate 6.1 Silica (SOLESPHERE H 51, AGC-Si Tech) 4 Antioxydant qs Dimethicone (and) Dimethicone Crosspolymer (DOWSIL EL-9241 DM SILICONE ELASTOMER BLEND; Dow Chemical) 25 Paraffin (and) Microcrystalline Wax (and) Synthetic Wax (PARACERA 30540, Paramelt) 6.1 Kaolin (IMERCARE 04K, Imerys) 3 Red 7 (and) Isopropyl Titanium Triisostearate (and) Triethoxysi-lylethyl Polydimethylsiloxyethyl Dimethicone 0.5 Iron Oxides (and) Isopropyl Titanium Triisostearate (and) Triethoxy-silylethyl Polydimethylsiloxyethyl Dimethicone 4.2. Preparation method:

[0235] 1. The oils (Hydrogenated Polyisobutene, Isostearyl) are mixed together while stirring. Isostearate, Tridecyl Trimellitate, Trimethylsiloxyphenyl Dimethicone) and the paste compound (Bis-Diglyceryl Polyacyladipate-2). 2. Once a homogeneous mixture has been obtained, the pigments are added while stirring and the mixture is heated to 45°C. 3. When the mixture is homogeneous, the isohexadecane is added while stirring.

[0236] 4. After homogenization of the mixture, the fillers (Kaolin, Distear- dimonium Hectorite, KSP-100, Mica) under agitation. 5. The whole is heated to 90°C and the waxes (polyethylene, hydrogenated jojoba oil) are introduced, then the silicone elastomer, under agitation. 6. After obtaining a homogeneous mixture, it is poured into molds and allowed to cool before unmolding and packaging the resulting lipstick tubes. Evaluation of compositions:

[0237] [Tables 12] Composition 5 Hardness 176 g Gloss 35 Stick Appearance Homogeneous, flawless Application The composition applies easily in a matte finish with good durability Comfort Comfortable, non-drying

Claims

Demands

1. A matte solid cosmetic composition, preferably in stick form, intended for application to the skin and / or lips, comprising * at least 5%, preferably at least 10% by weight, relative to the total weight of the composition, of at least one first nonpolar hydrocarbon oil, saturated or unsaturated, preferably saturated, linear or branched, preferably branched, in C14-C19, * at least one mineral or organic filler comprising at least one lipophilic clay-type filler comprising at least one quaternary ammonium group, said lipophilic clay-type filler being present at a content of between 1 and 3% by weight, relative to the total weight of the composition, the lipophilic clay-type filler not being pre-dispersed, * at least one second oil selected from non-volatile hydrocarbon oils, polar or non-polar, different from the first oil, or silicone non-volatile oils,*at least one silicone elastomer in a form carried in at least one oil, identical or different from the first or second oil.

2. Composition according to the preceding claim, characterized in that the first oil is selected from the following oils, alone or in mixture (INCI name): Tetradecane, Hexadecane, Isohexadecane, Octadecane, C15-19 Alkane, preferably isohexadecane.

3. Composition according to any one of the preceding claims, characterized in that the first oil content is between 10 and 25% by weight, more particularly between 15 and 20% by weight, relative to the total weight of the composition.

4. Composition according to any one of the preceding claims, characterized in that the lipophilic clay-type filler is selected from hectorites comprising at least one quaternary ammonium group, bentonites comprising at least one quaternary ammonium group, or mixtures thereof, and preferably from Disteardimonium Hectorite, Stearalkonium Hectorite, Quaternium-18 Hectorite, and mixtures thereof, and even more preferably Disteardimonium Hectorite.

5. Composition according to any one of the preceding claims, characterized in that the hectorite-type filler is not pre-dispersed in gel form in a solvent chosen for example from C1-C2 alcohols, propylene carbonate, triethyl citrate, and mixtures thereof.

6. A composition according to any one of the preceding claims, characterized in that the composition may comprise: * at least one mineral filler selected from silica particles (INCI name: Silica), preferably in the form of spherical particles; kaolin; mica; talc; perlite; boron nitride; calcium carbonate; magnesium carbonate; magnesium hydrogen carbonate; hydroxyapatite, and mixtures thereof; preferably from kaolin, mica and optionally silica, and mixtures thereof; * at least one organic filler selected from polyethylene, lauroyl lysine, starch, cellulose; polyamide particles, polyurethane particles, acrylonitrile (co)polymer particles, polytetrafluoroethylene particles, acrylic acid (co)polymer particles; silicone resin particles, silicone elastomers optionally coated with silicone resin, Methylsilanol / Silicate Crosspolymer particles;synthetic or natural micronized waxes; metallic soaps derived from carboxylic organic acids having 8 to 22 carbon atoms; glass or ceramic microcapsules; or mixtures thereof; preferably cellulose, C8-C22 N-acylated amino acids, mixtures thereof; * mixtures thereof.

7. Composition according to any one of the preceding claims, characterized in that the content of mineral and / or organic filler(s) varies from 1 to 12% by weight, more particularly from 1 to 10% by weight, relative to the total weight of the composition.

8. A composition according to any one of the preceding claims, characterized in that the second oil is selected from polar non-volatile hydrocarbon oils such as C10-C26 alcohols; ethers of formula ROR', carbonates of formula RO(CO)OR', formulas in which, whether identical or not, the R, R' groups represent a hydrocarbon group comprising at most 16 carbon atoms, saturated or unsaturated, branched or unbranched; oils comprising one or more ester functions and comprising at least one hydrocarbon group, linear or branched, saturated, unsaturated, or aromatic, the total number of carbon atoms being at least 12; the ester oil optionally comprising one or more ether or hydroxyl functions, as well as mixtures thereof; and preferably from oils vegetable oils; ester oils, possibly hydroxylated, comprising 1 to 4 ester functions, at least one of which, linear or branched, saturated, unsaturated or aromatic, comprises at least 12 carbon atoms; mixtures thereof.

9. Composition according to any one of the preceding claims, characterized in that the content of polar non-volatile hydrocarbon oil(s) varies from 1 to 35% by weight, preferably from 1 to 15% by weight, preferably from 2 to 8% by weight, relative to the total weight of the composition.

10. Composition according to any one of the preceding claims, characterized in that the second oil is selected from non-polar hydrocarbon non-volatile oils selected from paraffin oil; squalane, in particular of vegetable origin; isoeicosane; mixtures of linear, saturated hydrocarbons, more particularly C21-C28; polybutenes, hydrogenated or not; polyisobutenes, hydrogenated or not; polydecenes, hydrogenated or not, and mixtures thereof.

11. Composition according to any one of the preceding claims, characterized in that the content of non-volatile non-polar hydrocarbon oil(s) varies from 1 to 10% by weight, preferably from 2 to 8% by weight, even more particularly from 3 to 6% by weight, relative to the total weight of the composition.

12. Composition according to any one of the preceding claims, characterized in that the second oil is selected from non-volatile silicone oils selected from dimethicone, alkyldimethicone in which the alkyl group is in C2-C24, phenyl silicones selected from Phenyl trimethicone, Diphenylsiloxy Phenyl Tri-methicone; Trimethyl Pentaphenyl Trisiloxane; Trimethylsiloxyphenyl Dimethicone; Diphenyl Dimethicone; Tetramethyl Tetraphenyl Trisiloxane; and mixtures thereof.

13. Composition according to any one of the preceding claims, characterized in that the content of non-volatile silicone oil(s) varies from 1 to 35% by weight, more particularly from 1 to 30% by weight, preferably from 10 to 25% by weight, relative to the total weight of the composition.

14. Composition according to any one of the preceding claims, characterized in that the content of second non-volatile oil(s) varies from 10 to 35% by weight, preferably from 15 to 35% by weight, relative to the total weight of the composition.

15. Composition according to any one of the preceding claims, characterized in that the silicone elastomer is in the form of a gel.

16. Composition according to any one of the preceding claims, characterized in that the silicone elastomer is selected from the following: Di-methicone Crosspolymer; Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer; Dimethicone / Vinyl Dimethicone Crosspolymer; Dimethicone / Vinyltrimethylsoloxysilicate Crosspolymer, as well as mixtures thereof, and preferably the Dimethicone Crosspolymer.

17. Composition according to any one of the preceding claims, characterized in that the silicone elastomer content, expressed as active material, varies from 1 to 5% by weight, preferably from 2.5 to 4.5% by weight, most advantageously between 3 and 4% by weight, relative to the total weight of the composition.

18. Composition according to any one of the preceding claims, characterized in that it optionally comprises at least one additional volatile oil selected from nonpolar hydrocarbon oils comprising from 8 to less than 14 carbon atoms; linear or cyclic silicone oils and mixtures thereof; the content of additional volatile oil(s), if the composition comprises any, is more particularly less than or equal to 25% by weight, preferably less than or equal to 10% by weight, even more preferably less than or equal to 2% by weight, relative to the total weight of the composition.

19. Composition according to any one of the preceding claims, characterized in that the composition optionally comprises water, in a content less than or equal to 2% by weight, more particularly less than or equal to 1% by weight, advantageously less than or equal to 0.5% by weight, relative to the total weight of the composition.

20. Composition according to any one of the preceding claims, characterized in that the composition comprises at least one colouring material in particular selected from pigments, mother-of-pearls, and mixtures thereof.

21. A composition according to any one of the preceding claims, characterized in that the composition comprises at least one wax selected from nonpolar hydrocarbon waxes such as microcrystalline waxes, paraffin waxes, ozokerite, polymethylene waxes, Fischer-Tropsch type waxes (or Synthetic Wax), polyethylene waxes, mixtures thereof; from polar hydrocarbon waxes such as alcohol waxes, ester waxes, in particular of vegetable origin, their mixtures; silicone waxes; and their mixtures.

22. Composition according to the preceding claim, characterized in that the wax content varies from 6 to 18% by weight, in particular from 8 to 15% by weight, relative to the total weight of the composition.

23. Composition according to any one of the preceding claims, characterized in that it comprises at least one pasty hydrocarbon compound, preferably selected from vegetable butters, partially hydrogenated vegetable oils, esters resulting from the condensation of a linear or branched C6-CiO dicarboxylic acid and an ester of diglycerol and monocarboxylic acids, optionally hydroxylated, linear or branched, in C6-C2O, triglycerides of fatty acids, saturated or unsaturated, linear or branched, optionally mono- or polyhydroxylated, preferably Ci2-Ci8, and mixtures thereof, and preferably selected from vegetable butters, partially hydrogenated vegetable oils, compounds with INCI names Bis-Diglyceryl Polyacyladipate-2 and Hydrogenated Coco-Glycerides, Bis-Behenyl / Isostearyl / Phy-tosteryl Dimer Dilinoleyl Dimer Dilinoleate, Phytosteryl / Isostearyl / Cetyl / Stearyl / Behenyl Dimer Dilinoleate,Hydrogenated Castor Oil Dimer Dilinoleate, and mixtures thereof.

24. Composition according to the preceding claim, characterized in that the content of the paste compound varies from 6 to 20% by weight, in particular from 8 to 15% by weight, relative to the total weight of the composition.

25. A method for makeup and / or skin and / or lip care, consisting of applying the composition according to any one of the preceding claims.