SPRAY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE

Abstract

SPRAY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE The present disclosure relates to spray compositions including 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine, as well as methods of making and using such compositions. Figure for abstract: none

Description

Title of the invention: SPRAY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL ME-THOXYPHENYL TRIAZINE FIELD OF THE INVENTION

[0001] The present disclosure relates to spray compositions comprising 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: bis-ethylhexyloxyphenol methoxyphenyl triazine), as well as methods of making and using such compositions. DISCUSSION OF THE CONTEXT

[0002] Radiation with wavelengths between 290 nm and 400 nm allows tanning of the human epidermis, while radiation with wavelengths between 290 and 320 nm, called UVB rays, hinders the development of a natural tan. Exposure is also likely to cause a detrimental change in the biomechanical properties of the epidermis, resulting in the appearance of wrinkles leading to premature aging of the skin (i.e., photoaging).

[0003] UVA rays with wavelengths between 320 and 400 nm penetrate deeper into the skin than UVB rays. UVA rays cause immediate and persistent browning of the skin. Daily exposure to UVA rays, even for a short time, under normal conditions, can damage collagen fibers and elastin, resulting in a change in the skin's microrelief, the appearance of wrinkles and uneven pigmentation (spots, uneven skin tone).

[0004] Numerous studies show the need for effective protection against UVA and UVB to prevent sunburn, photoaging, and the like.

[0005] In order to obtain a high protection product, it is generally necessary to combine a large number of sunscreens and / or a large quantity of UV filters to achieve high levels of filtration efficiency.

[0006] However, high levels of UV filters do not lend themselves to easy preparation of compositions with a stabilized and pleasant texture that can be sprayed. This is particularly true for compositions containing solid UV filters such as bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0007] Consumers like sprayable sunscreen compositions because they are generally easy to apply and spread during application.

[0008] There remains a need in the art for improved spray compositions containing bis-ethylhexyloxyphenol methoxyphenyl triazine which have good UV protection capabilities in addition to good application and spray use properties.

[0009] Accordingly, one aspect of the present disclosure is a spray composition containing bis-ethylhexyloxyphenol methoxyphenyl triazine which has good UV protection properties in addition to good application and use properties. Summary of the invention

[0010] The present disclosure relates to spray compositions comprising bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT). Preferably, bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT or bemotrizinol) is added to the compositions in an amount effective to protect the keratinous material from UV radiation.

[0011] The present disclosure also relates to methods of making spray compositions comprising adding bis-ethylhexyloxyphenol methoxyphenyl triazine during formation of the compositions. Preferably, bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT) is added to the compositions in an amount effective to protect the keratinous material from UV radiation.

[0012] It is understood that both the foregoing general description and the following detailed description are provided for the purpose of example and explanation only and not as a limitation of the disclosure. DETAILED DESCRIPTION OF THE INVENTION

[0013] In the following description and the claims appended thereto, it is to be understood that the terms used have their ordinary and customary meanings in the art, unless otherwise specified.

[0014] “Approximately” as used herein means within 10% of the number indicated (e.g., “about 10%” means 9% to 11% and “about 2%” means 1.8% to 2.2%.

[0015] “A” or “an” as used herein means “at least one”.

[0016] “At least one” means one or more and thus includes components in individual as well as mixtures / combinations.

[0017] As used herein, all proposed ranges are intended to include each specific point and range within the given ranges, and combinations of subranges therebetween. Thus, a range of 1 to 5 specifically includes integers in the range 1, 2, 3, 4, and 5, as well as subranges such as 2 to 5, 3 to 5, 2 to 3, 2 to 4, 1 to 4, etc., as well as all fractional numbers within the range such as 1.2, 2.3, 3.4, etc., and subranges including these fractional numbers such as 1.5 to 3.8, 2 to 4.3, 4.2 to 4.9, etc.

[0018] “Film former”, “film-forming polymer” or “film-forming agent” as used herein means a polymer or resin that is capable of leaving a film on the substrate to which it is applied, for example, after a solvent accompanying the film former has evaporated, been absorbed into, and / or dissipated on the substrate.

[0019] “Substituted” as used herein means comprising at least one substituent. Non-limiting examples of substituents include atoms, such as hydrogen atoms or chlorine atoms, as well as functional groups, such as hydroxyl groups, ether groups, alkoxy groups, acyloxyalkyl groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide groups, halogen-containing groups, ester groups, thiol groups, sulfonate groups, thiosulfate groups, siloxane groups, and polysiloxane groups. The substituent(s) may be further substituted.

[0020] “Volatile,” as used herein, means having a flash point less than about 115°C.

[0021] “Non-volatile,” as used herein, means having a flash point greater than about 115°C.

[0022] “Polymer” as used herein means a compound that is made up of at least two monomers.

[0023] “Exempt” or “substantially free” or “devoid of” as used herein means that although it is preferred that no amount of the specific component be present in the composition, it is possible for there to be very small amounts thereof in the compositions of the disclosure provided that such amounts do not materially affect at least one, preferably most, of the advantageous properties of the compositions of the disclosure. Thus, for example, "oil-free" means that an effective amount (i.e., greater than trace amounts) of oil(s) is omitted from the composition (i.e., about 0% by weight), "substantially oil-free" means that oil(s) are present in amounts not greater than 0.1% by weight, and "oil-free" means that oil(s) are present in amounts not greater than 0.25% by weight, based on the total weight of the composition.The same nomenclature applies to all other ingredients identified throughout the application and in this paragraph such as, for example, specific UV filters and / or surfactants (the compositions in the disclosure that are “oxybenzone and / or octinoxate-free,” “substantially oxybenzone and / or octinoxate-free,” and “oxybenzone and / or octinoxate-free,” as well as “surfactant-free,” “substantially surfactant-free,” and “surfactant-free” have meanings consistent with the discussion in this paragraph), even if not specifically discussed for each identified ingredient. The discussed examples of the use of such language as those in this paragraph are intended to be provided for convenience. of example, not of limitation.

[0024] “UV filters” as used herein means approved sunscreen active agents by a government regulatory agency such as the Food and Drug Administration (FDA) in the United States or the European Commission in Europe and includes organic UV filters such as avobenzone, octocrylene, benzophenones, benzotriazoles and merocyanines, as well as mineral UV filters such as zinc oxide (ZnO) and titanium dioxide (TiO2).

[0025] “Anhydrous” as used herein means that the compositions of the disclosure contain less than 3% water, which means that the compositions may also contain less than 2% water, and less than 1% water, as well as be “water-free”, “substantially water-free” and “water-free”.

[0026] “Keratinous materials” means nails (fingernails and / or toenails), skin such as the body, face and eye area, scalp, keratinous fibers such as eyelashes, eyebrows and hair, and mucous membranes such as the lips.

[0027] “Physiologically acceptable” means compatible with spraying and having a pleasant color, odor and feel, and which does not cause unacceptable discomfort (tingling or pulling) likely to discourage a consumer from using the composition.

[0028] “UV protection efficiency” or “filtration efficiency” in the context of present disclosure, is evaluated from one or more of SPF, FPUVA, critical wavelength and UVA-I / UV ratio.

[0029] "SPF" (Sun Protection Factor) measures the level of protection against erythema provided by a composition. The SPF value corresponds to the ratio between the minimum erythema dose (MED) measured on skin covered with the composition and the MED measured on bare skin. "SPF" is a term known in the art of sunscreens and is defined, for example, in A new substrate to measure sunscreen protection factors throughout the ultraviolet spectrum, J. Soc. Cosmet. Chem., 40, 127-133 (May / June 1989).

[0030] The SPF (Sun Protection Factor) assessment can be performed, for example, in vitro with a Labsphere spectrophotometer (North Sutton, NH, USA). In such an assessment, the plate is the material onto which the composition under test is applied. For such an assessment, polymethyl methacrylate (PMMA) plates can be used. An example of an acceptable protocol is currently undergoing ISO accreditation as ISO Committee Draft 23675.

[0031] The assessment of the sun protection factor (SPF) can also be carried out in vivo in accordance with the protocol ISO 24444:2019 “Cosmetics-Sun protection test methods-In-vivo determination of the sun protection factor (SPF). It can also be determined according to FDA protocols as described in the document “Labeling and Effectiveness Testing; Sunscreen Drug Products for Over-the-Counter Human Use” published in the US Federal Register on 07 / 05 / 2011 (https: / / www.federalregister.gOv / d / 2011-14766); 21 CFR Part 352 Subpart D § 352.72, updated and revised by the 2011 publication in the Federal Register.

[0032] “UVA protection factor” (UVA protection factor) refers to a characteristic index tering the UVA protection provided by a composition. For example, the UVA factor may be measured in vivo in accordance with the "PPD" (Persistent Pigment Darkening) method of the ISO-24442:2022 protocol, measuring skin color observed 2 to 4 hours after UVA exposure. It may also be determined in accordance with FDA protocols, as described again in 21 CFR Part 352 Subpart D § 352.72 as discussed above in relation to SPF.

[0033] UVA protection assessment can also be measured in vitro with the Labsphere® spectrophotometer under conditions such as those discussed above in relation to SPF. The ISO 24443:2021 protocol describes such an in vitro method. Broad spectrum test procedures, in particular “critical wavelength” test procedures, are also available in 21 CFR Part 352 Subpart D § 352.72. In addition,

[0034] The FDA's broad spectrum test procedures include determining the UVA1 / UV ratio as described in "Sunscreen Drug Products for Over-the-Counter-Human-Use" published in the Federal Register https: / / www.federalregister.gov / documents / 26 / 02 / 2019 / 2019-03Q19 / sunscreen-drug-pr oducts-for-over-the-counter-human-use." In the assay described in the monograph, known as the Boots adaptation of the Diffey / Robson test method, a ratio is generated between the protection provided by the sunscreen product against UVA1 (340-400 nm) and the protection against total UV radiation (UVB and UVA at 290-400 nm) calculated from the absorbance curve. This UVA1 / UV ratio would represent the product's score in the in vitro test.

[0035] According to the present disclosure, the compositions of the present disclosure preferably have one or more of the following properties:

[0036] The compositions have a critical wavelength, as determined by FDA critical wavelength procedures, of at least 370 nm;

[0037] The compositions have an SPF value of at least 15, preferably at least 30, preferably at least 50 and preferably at least 70;

[0038] The compositions have an FPUVA / SPF ratio of at least 1 / 3, and preferably at least 2 / 5; and / or

[0039] The compositions have a UVA1 / UV ratio of 0.7 or more, preferably 0.75 or more, and preferably 0.8 or more.

[0040] "Makeup result" as used herein relates to the visual impact of a composition when applied to a keratinous material such as skin. The makeup result may relate to the apparent color of the product after application to a keratinous material or an optical effect such as shine, the blurring of fine lines and imperfections, or a concealing effect on pores or defects after application of the product to the keratinous material.

[0041] “Long-lasting,” as used herein, refers to compositions where the color or other apparent properties remain the same or substantially the same as at the time of application, as viewed by the naked eye, after an extended period of time, or after a particular stress event such as immersion in water or rubbing. “Long-lasting” may be evaluated by assessing long-lasting properties by any method known in the art for assessing such properties. For example, long-lasting may be evaluated by a test involving the application of a composition to a keratinous material such as skin and evaluating the color of the composition after an extended period of time. For example, the color of a composition may be evaluated immediately following application to a keratinous material such as skin, and these characteristics may then be re-evaluated and compared after a period of time.In addition, these characteristics can be evaluated relative to other compositions, such as commercially available compositions. “Long wear” can also be evaluated using in vitro methods on non-keratinous substrates such as polymethyl methacrylate (PMMA), in which properties such as color, transparency, or in vitro SPF can be evaluated before and after a period or stressor such as immersion in water, incubation at elevated temperatures, or application of an abrasive technique.

[0042] “Natural” as in the expression “natural compound” means any compound derived directly from a natural substance such as a plant without undergoing chemical modification.

[0043] “Naturally occurring compound” means any compound derived from a naturally occurring compound which has undergone one or more chemical modifications, for example by organic synthesis reaction, without the properties of the natural compound having been modified.

[0044] “Synthetic compound” means any compound that is neither a natural compound nor a compound of natural origin.

[0045] “Room temperature” means approximately 20 to 25°C.

[0046] “Atmospheric pressure” means approximately 760 mmHg, i.e. approximately 105 pascals.

[0047] “UV filter” and “sunscreen agent” are used interchangeably in this request.

[0048] “UV efficacy” and “UV protection” are used interchangeably interchangeable in this application.

[0049] The compositions and methods of the present disclosure may comprise, consist of, or consist essentially of the essential elements and limitations of the disclosure described herein, as well as any additional or optional ingredients, components, or limitations described herein or otherwise useful. For example, the UV (ultraviolet) absorbing system of the compositions of the disclosure may "consist essentially of" bis-ethylhexyloxyphenol methoxyphenyl triazine alone, or bis-ethylhexyloxyphenol methoxyphenyl triazine in combination with zinc, titanium, and / or cerium oxides, and / or one or more organic UV filters.

[0050] For the purposes of the present disclosure, the "fundamental and novel property" associated with the compositions, components and methods which "consist essentially of" the identified ingredients or actions is "spray angle, droplet distribution and / or product spray volume".

[0051] “Good application and use properties,” as used herein, refers to to the expected properties of a spray composition when dispensed from a suitable spray package. Desired characteristics in a spray composition which may be referred to herein as "use properties" include suitable spray angle, droplet distribution and product spray volume.

[0052] “Spray angle” or “spray cone angle” as used herein re presents the spray angle created when an actuator on the spray package is engaged to cause dispensing of the product from the packaging component. The spray angle can be measured visually by photographic examination of the droplets as they exit the packaging component. Alternatively, the spray angle can be determined by measuring the diameter of the spray pattern created on a vertical surface when the package is sprayed at a known distance from the vertical surface. The spray angle can be calculated as twice the inverse cosine of half the diameter of the spray pattern divided by the distance of the packaging component from the vertical surface.

[0053] “Droplet distribution” as used herein refers to a property of a spray composition when sprayed from a packaging component. Distribution may be assessed visually in terms of homogeneity or droplet size and distribution by spraying a spray composition at a controlled distance from a vertical surface and examining the droplet pattern created when the actuator is engaged for a predetermined time. Alternatively, droplet distribution may be measured at using laser detection equipment such as a Malvern Spraytec spray particle size analyzer, in which the droplet distribution can be reported as a volume or size distribution.

[0054] “Product spray volume” as used herein for the purpose of describing the Good use properties of a spray composition refers to the amount of product per unit time that is dispensed from a spray package, and is used interchangeably with "Product Spray Quantity". Product spray volume may be determined volumetrically or gravimetrically and is recorded as the amount of product dispensed over a controlled period of time.

[0055] The compositions of the present disclosure may be in any form suitable for use as a personal care composition, such as a stick, a paste, a cream, an anhydrous composition, an aqueous / alcohol-based composition, an emulsion (oil-in-water, water-in-oil, multiple emulsion such as oil-in-water-in-oil), a nanoemulsion, a thixotropic gel, a liquid, etc. These compositions may be used for any personal care purpose in cosmetic and / or dermatological products such as, for example, sunscreen, foundation, lip balms, lipsticks, concealers, mascaras, leave-in hair products, eye shadows, powders, etc.

[0056] Reference is made herein to trade names of materials including, but not limited to, materials such as polymers and optional components. The materials are not intended to be limited to the materials described and referenced by a certain trade name herein. Equivalent materials (e.g., those obtained from a different source under a different catalog name or (reference) number) to those referenced by a trade name may be substituted and used in the methods described and claimed herein.

[0057] All percentages and ratios are, unless otherwise indicated, calculated by weight. All percentages are, unless otherwise indicated, calculated based on the total weight of a composition. All levels of component or composition refer to the active level of that component or composition, and are exclusive of impurities, e.g., residual solvents or by-products, which may be present in commercially available sources.

[0058] All US patents or patent applications disclosed herein are expressly incorporated by reference in their entirety. Spray composition

[0059] According to the present disclosure, spray compositions comprising a UV (ultraviolet) absorbing system comprising 4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) are provided. Such spray compositions may be in any suitable form, and may be capable of being sprayed by any spraying means such as a pump spray device or an aerosol spray device. For aerosol spraying, the spray compositions of the present disclosure preferably comprise at least one propellant to facilitate atomization of the composition.

[0060] Suitable examples of acceptable composition forms include, but are not limited to, anhydrous compositions, aqueous / alcohol-based compositions, and emulsions having either an exterior aqueous phase (e.g., oil-in-water (o / w) emulsion) or an exterior oily phase (e.g., water-in-oil (w / o) emulsion). Such exemplary composition forms will be discussed in more detail below in connection with ingredients useful in such composition forms.

[0061] Preferred spray compositions of the present disclosure are fluid. "Fluid" particularly refers to a composition that is not solid at room temperature (25°C) and whose viscosity can be measured. The term "fluid" refers to a liquid composition that flows under its own weight at room temperature (25°C) and atmospheric pressure. Advantageously, a fluid composition according to the present disclosure has a complex rigidity modulus G* of less than 1000 Pa, preferably less than 400 Pa, preferably less than 200 Pa.

[0062] Preferably, the composition has, at 25°C, a viscosity of between 0.1 and 25 Pa.s and preferably between 0.5 and 22 Pa.s. A suitable method for measuring the viscosity is generally carried out at 25°C, using a Rheomat RM 180 viscometer equipped with a No. 3 rod or a No. 4 rod, depending on the working recommendations, the measurement being carried out after 10 minutes of rotation of the rod in the composition (after which a stabilization of the viscosity and the rotation speed of the rod is observed), at a speed of 200 rpm.

[0063] The spray compositions of the present disclosure may also not be fluid at room temperature and atmospheric pressure, but become fluid when a high shear rate is applied. Spray compositions that are fluid under high shear rate conditions are preferably sprayed using spray packages designed to exclude mixing of the spray composition and propellant. Examples of suitable spray packages include "bag-on-valve" packages and may comprise an outer canister and an inner bag, wherein the inner bag contains the spray composition and the space between the inner bag and the outer canister is pressurized using of any gas at a predetermined pressure. In such a "valve-to-bag" package, an actuator is connected so that when the actuator is engaged, the gas pressure between the outer canister and the inner bag is capable of compressing the inner bag and dispensing the spray composition.

[0064] Preferably, spray compositions suitable for dispensing via a bag valve package should be flowable (less than 0.1 Pa.s) at high shear rates (about 1000 / s). B is-ethylhexyloxyphenol methoxyphenyl triazine

[0065] According to the present disclosure, spray compositions comprising a UV (ultraviolet) absorbing system comprising 4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine) are provided.

[0066] According to preferred embodiments, the UV absorbing system comprises at least 5% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 15% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 20% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 30% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 40% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 50% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 70% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 80% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, and preferably at least 90% by weight bis-ethylhexyloxyphenol methoxyphenyl triazine, all weights based on the total weight of the UV absorbing system.The “UV absorbing system” contains all the organic UV filters and / or all the mineral UV filters present in the composition.

[0067] According to preferred embodiments, bis-ethylhexyloxyphenol methoxyphenyl triazine is present in the compositions of the present disclosure in an effective UV absorbing amount such as, for example, from about 0.1% to about 10% by weight based on the total weight of the composition, from about 1% to about 10% by weight, from about 2.5% to about 8% by weight, and from about 4% to about 6% by weight, including all intermediate ranges and sub-ranges such as, for example, from about 4.5% to about 10% by weight, and from about 1% to about 8% by weight, from about 1% to about 6% by weight, from about 5.5% to about 8% by weight, from about 5.7% to about 9% by weight, etc., all weights being based on the total weight of the composition. Additional sunscreen agents

[0068] According to preferred embodiments of the present disclosure, spray compositions optionally further comprising at least one additional UV filter (in addition to bis-ethylhexyloxyphenol methoxyphenyl triazine) selected from the group consisting of organic UV filters and mineral UV filters such as zinc oxides, cerium oxides, titanium oxides and mixtures thereof are provided.

[0069] The additional organic UV filter(s) may be hydrophilic or lipophilic. “Hydrophilic organic UV filter” means a water-soluble organic UV filter or a water-dispersible organic UV filter (in colloidal form). “Lipophilic organic UV filter” means a UV filter which is dissolved or dispersed in colloidal form in a liquid fatty phase.

[0070] Suitable organic UV filters may be chosen from the following non-exhaustive list of compounds: cinnamic compounds; anthranilate compounds; para-aminobenzoic acid compounds, salicylic compounds; dibenzoylmethane compounds; camphor compounds; benzophenone compounds; [3,[3-diphenylacrylate] compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; benzalmalonate compounds, including those cited in US patent 5,624,663; benzimidazole derivatives; imidazoline compounds; bis-benzoazolyl compounds as described in patents EP669323 and US 2,463,264; methylene bis(hydroxyphenylbenzotriazole) compounds as described in applications US 5,237,071, US 5,166,355, GB2303549, DE197 26 184 and EP893119; benzoxazole compounds as described in patent applications EP0832642, EP1027883, EP1300137 and DE10162844;polymer filters and silicone filters such as those described in particular in application WO 93 / 04665; alkylstyrene-derived dimers such as those described in patent application DE19855649; 4,4-diarylbutadiene compounds such as those described in applications EP0967200, DE19746654, DE19755649, EP-A-1008586, EPI 133980 and EP133981, and mixtures thereof. Preferably, the lipophilic organic UV filters are chosen from salicylic compounds, dibenzoylmethane compounds, benzylidene camphor compounds; benzophenone compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; as well as other categories of compounds identified herein; and mixtures thereof. ;

[0071] Specific reference may be made to suitable salicylic compounds including Homosalate (homomentyl salicylate), marketed for example under the trademark "Eusolex HMS" by Rona / EM Industries; and ethylhexyl salicylate, marketed for example under the trademark "Neo Heliopan OS" by Symrise and glycol salicylate. Other examples of compounds Salicylate include phenyl salicylate; dipropylene glycol salicylate, for example marketed under the brand name “Dipsal” by Scher; and TEA salicylate, for example marketed under the brand name “Neo Heliopan TS” by Symrise.

[0072] Examples of suitable [3,[3-diphenylacrylate] compounds include Octocrylene, for example marketed under the trademark "Uvinul N539" by BASF; and Etocrylene, for example marketed under the trademark "Uvinul N35" by BASF.

[0073] Suitable anthranilic compounds may include menthyl anthranilates, marketed for example under the trademark "Neo Heliopan MA" by Symrise.

[0074] Examples of dibenzoylmethane compounds include butyl methoxydibenzoylmethane, for example marketed under the trademark "Parsol 1789" by DSM; and isopropyl dibenzoylmethane.

[0075] Suitable cinnamic compounds include ethylhexyl methoxycinnamate, sold for example under the trademark "Parsol MCX" by DSM; isopropyl methoxycinnamate; isopropoxyl methoxycinnamate; isoamyl methoxycinnamate, sold for example under the trademark "Neo Heliopan E 1000" by Symrise; cinoxate (2-ethoxyethyl-4-methoxycinnamate); DEA methoxycinnamate; diisopropyl methylcinnamate; and glyceryl ethylhexanoate dimethoxycinnamate.

[0076] Examples of camphor compounds include benzylidenecamphor derivatives: 3-benzylidenecamphor, for example sold under the trademark "Mexoryl SD" by Chimex; 4-methylbenzylidenecamphor, for example sold under the trademark "Eusolex 6300" by Merck; benzylidenecamphor sulfonic acid, for example sold under the trademark "Mexoryl SL" by Noveal; benzalkonium camphor methosulfate, for example sold under the trademark "Mexoryl SO" by Noveal; terephthalylidene di-camphor sulfonic acid, for example sold under the trademark "Mexoryl SX" by Noveal; and polyacrylamidomethyl-benzylidenecamphor, for example sold under the trademark "Mexoryl SW" by Noveal.

[0077] Suitable benzophenone compounds include benzophenone-1 (2,4-dihydroxybenzophenone), such as that marketed under the trademark "Uvinul 400" by BASF; benzophenone-2 (tetrahydroxybenzophenone), such as that marketed under the trademark "Uvinul D50" by BASF; benzophenone-3 (2-hydroxy-4-methoxybenzophenone) or oxybenzone, such as that marketed under the trademark "Uvinul M40" by BASF; benzophenone-4 (hydroxymethoxybenzophenone sulfonic acid), such as that marketed under the trademark "Uvinul MS40" by BASF; benzophenone-5 (hydroxymethoxybenzophenone sodium sulfonate); benzophenone-6 (dihydroxy dimethoxy benzophenone), such as such as that marketed under the brand name “Helisorb 11” by Norquay; benzophenone-8, such as that marketed under the brand name “Spectra-Sorb UV-24” by American Cyanamid; benzophenone-9 (Disodium dihydroxy dimethoxy benzophenonedisulfonate), such as that marketed under the brand name “Uvinul DS-49” by BASF; and benzophenone-12, and n-hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (such as that marketed under the trade name UVINULA+ by BASF).

[0078] Examples of triazine compounds include diethylhexyl butamido triazone, such as that marketed under the trademark "Uvasorb HEB" by the company Sigma 3V; 2,4,6-tris(dineopentyl 4'-aminobenzalmalonate)-s-triazine, bis-ethylhexyloxyphenol methoxyphenyl triazine, such as that marketed under the trademark “TINOSORB S” by BASF and ethylhexyl triazone, such as that marketed under the brand name “UVTNUL T150” by BASF.

[0079] Suitable benzotriazole compounds include phenylbenzotriazole derivatives: 2-(2H-benzotriazol-2-yl)-6-dodecyl-4-methylpheno, branched and linear and those described in USP 5240975.

[0080] Suitable benzalmalonate compounds include dineopentyl 4'-methoxybenzalmalonate, and polyorganosiloxane comprising benzalmalonate functional groups, such as polysilicone-15, as marketed under the trademark "Parsol SLX" by Hoffmann-LaRoche.

[0081] Examples of benzimidazole compounds include, in particular, phenylbenzimidazole derivatives such as phenylbenzimidazole sulfonic acid, such as that marketed in particular under the trademark "Eusolex 232" by Merck, and disodium phenyl dibenzimidazole tetrasulfonate, such as that marketed under the trademark "Neo Heliopan AP" by Symrise.

[0082] Suitable imidazoline compounds include ethylhexyl dimethoxy-benzylidene dioxoimidazoline propionate.

[0083] Examples of bis-benzoazolyl compounds include the compounds described in EP-669,323 and US Patent No. 2,463,264.

[0084] Suitable para-aminobenzoic acid compounds include PABA (p-aminobenzoic acid), ethyl PABA, ethyl dihydroxypropyl PABA, pentyl dimethyl PABA, ethylhexyl dimethyl PABA, such as that marketed under the trademark "Escalol 507" by ISP, glyceryl PABA and PEG-25 PABA, such as that marketed under the trademark "Uvinul P25" by BASF.

[0085] Suitable methylene bis-(hydroxyphenylbenzotriazol) compounds include 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-methyl-phenol], such as that marketed under the trademark "Mixxim BB / 200" by Fairmount Chemical, 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol], such as that marketed in micronized form in aqueous dispersion under the brand name “Tinosorb M” by BASF or under the brand name “Mixxim BB / 100” by Fairmount Chemical, and derivatives as described in US patents Nos. 5,237,071 and 5,166,355, GB-2,303,549, DE-197 26 184 and EP-893,119, and drometrizole trisiloxane, such as that marketed under the brand name “Silatrizole” by Rhodia Chimie or - “Mexoryl XL” by L'Oréal.

[0086] Examples of benzoxazole compounds include 2,4-bis[5-l(dimethylpropyl)benzoxazol-2-yl-(4-phenyl)imino]-6-(2-ethylhexyl)imino-1,3,5-triazine, such as that marketed under the brand name Uvasorb K2A by Sigma 3V.

[0087] Suitable examples of shielding polymers and shielding silicones include the silicones described in WO 93 / 04665.

[0088] Suitable α-alkylstyrene derived dimers include the dimers described in DE-19855649.

[0089] Examples of 4,4-diarylbutadiene compounds include 1,1-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene.

[0090] According to preferred embodiments, the compositions of the present disclosure further comprise at least one additional organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Ho-mosalate, Octocrylene, and mixtures thereof. In such embodiments, the UV absorbing system may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine and (2) at least one organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate, Octocrylene, and mixtures thereof.

[0091] According to other preferred embodiments, however, the compositions of the present disclosure are "free", "substantially free" or "lacking", as defined above, one or more additional organic UV filters selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate and Octocrylene, preferably two or more, preferably three or more, preferably four or more, or preferably all five of these five sunscreen agents.

[0092] According to preferred embodiments, the compositions of the present disclosure are "free", "substantially free" or "devoid", as defined above, of one or more additional organic UV filters selected from the group consisting of OXYBENZONE (benzophenone-3), OCTINOXATE (methoxycinnamate ethylhexyl), ETHYLHEXYL TRIAZONE, DROMETRIZOLE TRISILOXANE, METHYLENE BIS-BENZOTRIAZOLYL TETRAMETHYLBUTYL PHENOL, HEXYL DIE-THYLAMINO HYDROXYBENZOYL BENZOATE, DIETHYLHEXYL BUTAMIDO TRIAZONE, ISOAMYL P-METHOXYCINNAMATE, POLY-SILICONE-15, 4-METHYLBENZYLIDENE CAMPHOR, DISODIUM PHENYL DIBENZOL MIDAZOLE TETRASULFONATE, METHOXYPROPYLAMINO CYCLOHEXENYLIDENE ETHOXYETHYLCYA-NOACETATE, preferably two or more, preferably three or more, preferably four or more, etc., and preferably "free", "substantially free" or "lacking" of all these sunscreen agents.

[0093] According to preferred embodiments, the compositions of the present disclosure are "free", "substantially free" or "lacking", as defined above, OXYBENZONE (benzophenone-3) and / or OCTINOXATE (ethylhexyl methoxycinnamate).

[0094] If present in the compositions of the present disclosure, the at least one additional UV filter is preferably present in the compositions of the present disclosure in an amount of at least about 5% by weight, preferably at least about 10% by weight, preferably at least about 12% by weight, preferably at least about 14% by weight, and preferably at least about 15% by weight, with the upper end of the range of additional UV filter present preferably being about 40% by weight (e.g., about 5-40%, about 10-40%, about 12-40%, etc.), preferably about 30% by weight (e.g., about 5-30%, about 10-30%, about 12-30%, etc.), preferably about 25% by weight (e.g., about 5-25%, about 10-25%, about 12 to 25%, etc.), and preferably about 20% by weight (e.g., about 5 to 20%, about 10 to 20%, about 12 to 20%, etc.), all weights being based on the total weight of the composition.

[0095] According to preferred embodiments, the compositions of the present disclosure comprise 10% or less by weight relative to the total weight of the composition of additional UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight relative to the total weight of the composition.

[0096] According to preferred embodiments, the compositions of the present disclosure comprise 10% or less by weight relative to the total weight of the composition of additional organic UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight relative to the total weight of the composition. relative to the total weight of the composition.

[0097] According to preferred embodiments, the UV absorbing system of the compositions of the present disclosure may "consist of" or "consist essentially of" bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0098] According to preferred embodiments, the UV absorbing system of the compositions of the present disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) zinc oxides, titanium oxides and / or cerium oxides.

[0099] According to preferred embodiments, the UV absorbing system of the compositions of the present disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) additional organic UV filter(s).

[0100] According to preferred embodiments, the present disclosure contemplates omitting one or more of the specific UV filters discussed above from the UV absorbing system of the compositions of the present disclosure. For example, octocrylene and / or octinoxate may be omitted from the compositions. A similar omission of one or more of the specific UV filters discussed is therefore contemplated.

[0101] The addition of particular UV filters in a spray composition of the present disclosure may affect the addition of other ingredients in the spray composition to obtain a suitable product. For example, the addition of solid mineral UV filters may result in the addition of dispersing agents such as, for example, polyhydroxystearic acid. Furthermore, since bis-ethylhexyloxyphenol methoxyphenyl triazine is typically in powder (solid) form, bis-ethylhexyloxyphenol methoxyphenyl triazine is generally solubilized in a suitable solvent during formation of the composition. Such solvent selection, alone or in combination with the selection of additional UV filters for addition to the composition, may result in the selection of particular surfactants or emulsifiers based on the final composition of the aqueous and / or oil phase of the composition. Oil

[0102] According to preferred embodiments of the present disclosure, compositions further comprising at least one oil are provided. "Oil" refers to a substance that is hydrophobic and lipophilic, and is a liquid at about room temperature (20-25°C) and about atmospheric pressure (760 mm Hg).

[0103] Suitable oils include volatile and / or non-volatile oils. These oils may be any acceptable oil, including, but not limited to, silicone oils and / or hydrocarbon oils.

[0104] According to certain embodiments, the compositions of the present disclosure include preferably take one or more volatile silicone oils. Examples of such volatile silicone oils include linear or cyclic silicone oils having from 2 to 7 silicon atoms, these silicones being optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms. Specific oils that may be used in the disclosure include octamethyltetrasiloxane, deca-methylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane and mixtures thereof. Other volatile oils that may be used include KF 96A with a viscosity of 6 cSt, a commercial product from Shin Etsu having a flash point of 94 °C. Preferably, volatile silicone oils have a flash point of at least 40°C.

[0105] Non-limiting examples of volatile silicone oils are listed in Table 1 below.

[0106] [Table 1]

[0107] [Tableauxl] Compound Flash point (°C) Viscosity (cSt) Octyltrimethicone Hexyhrimethicone Decamethylcyclopentasiloxane (cyclopentasiloxane or D5) Octamethylcyclotetrasiloxane (cyclotetramethylisiloxane or D4) Dodecamethylcyclohexasilaxane (D6) Decamethyletrasiloxane (14) Shin Etsu KF-96 A PDMS (polydimethylisiloxane) DC 200 (1.5 cSt) Dow Corning PDMS DC 200 (2cSt) 93 79 72 55 93 63 94 56 87 1.2 1.2 4.2 2.5 7 1.7 6 1.5 2

[0108] Further, a volatile linear silicone oil may be employed in the present disclosure. Suitable volatile linear silicone oils include those described in U.S. Patent No. 6,338,839 and WO03 / 042221, the contents of which are incorporated herein by reference. In one embodiment, the volatile linear silicone oil is decamethyltetrasiloxane. In another embodiment, the decamethyltetrasiloxane is further combined with another solvent more volatile than the decamethyltetrasiloxane.

[0109] According to certain embodiments of the present disclosure, the composition preferably comprises one or more non-silicone volatile oils which may be selected from volatile hydrocarbon oils, volatile esters and ethers. volatile. Examples of such volatile non-silicone oils include, but are not limited to, volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof and in particular, branched C8-C16 alkanes such as C8-C16 isoalkanes (also known as isoparaffins), isohexadecane, isododecane, isodecane, and for example, oils sold under the trade names Isopar or Permethyl. Preferably, the volatile non-silicone oils have a flash point of at least 40°C.

[0110] Non-limiting examples of volatile non-silicone oils are given in Table 2 below. [YES] [Table 2]

[0112] [T ableaux2] COMPOUND FLASH POINT (°C) Isododecane 43 Propylene glycol n-Butyl ether 60 Ethyl 3-Ethoxypropionate 58 Propylene glycol methyl ether acetate 46 Isopar L (Cn-Ci3 isoparaffin) 62 Isopar H (Cn-Ci2 isoparaffin) 56

[0113] According to certain embodiments of the present disclosure, the composition comprises at least one non-volatile oil. Examples of non-volatile oils that may be used in the present disclosure include, but are not limited to, polar oils such as, for example:

[0114] - esters and ethers, in particular fatty acids, such as oils of formulas R1COOR2, in which RI represents the residue of a fatty acid having from 8 to 29 carbon atoms, and R2 represents a hydrocarbon chain, branched or not, containing from 3 to 30 carbon atoms, such as for example Purcellin oil, isononyl isononanoate, isopropyl myristate, 2-ethylhexyl palmitate, 2-octyldodecyl stearate, 2-octyldodecyl erucate, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, octylhydroxystearate, octyldodecyl hydroxystearate, diisostearylmalate, triisocetyl citrate, heptanoates, octanoates, decanoates of fatty alcohol; polyol esters, such as propylene glycol dioctanoate, neopentyl glycol diheptanoate and diethylene glycol diiso-nonanoate;triglycerides such as caprylic / capric acid triglycerides, for example those sold by the company Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by the company Dynamit Nobel; and pentaerythritol esters such as pentaerythrityl tetraisostearate or dipentaerythrityl pentaiso-nonanoate; ;

[0115] - ethers containing from 10 to 40 carbon atoms;

[0116] - liquid C8 to C26 fatty alcohols, for example oleyl alcohol, alcohol cetyl alcohol, stearyl alcohol, octyldodecanol and cetearyl alcohol;

[0117] - hydrocarbon oils of animal origin, such as perhydrosqualene;

[0118] - hydrocarbon oils of vegetable origin, such as liquid triglycerides fatty acids having from 4 to 10 carbon atoms such as triglycerides of heptanoic or octanoic acids, for example, sunflower oil, corn oil, soybean oil, cucurbit oil, grape seed oil, sesame oil, hazelnut oil, apricot oil, macadamia oil, ara oil, sunflower oil, castor oil, avocado oil, triglycerides of caprylic / capric acids, such as those sold by the company Stéarineries Dubois or those sold under the names Miglyol 810, 812, and 818, by the company Dynamit Nobel, coco-caprylate / caprate (esterified oil of coconut oil), jojoba oil, shea butter oil; and

[0119] - their mixtures.

[0120] Further, examples of non-volatile oils that may be used in the present disclosure include, but are not limited to, non-polar oils such as branched and unbranched hydrocarbons, particularly Vaseline (petrolatum), paraffin oil, squalane, squalene, hydrogenated polyisobutene, hydrogenated polydecene, polybutene, mineral oil, pentahydrosqualene, and mixtures thereof.

[0121] According to certain embodiments of the present disclosure, the compositions of the present disclosure may comprise at least one non-volatile silicone oil. Suitable examples of such silicone oils include, but are not limited to, non-volatile silicone fluids such as, for example, polyalkyl (aryl) siloxanes. Suitable polyalkyl siloxanes include, but are not limited to, polydimethyl siloxanes, which have the CTFA designation dimethicone, polydiethyl siloxane, phenyl trimethicone, trimethyl pentaphenyl trisiloxane, phenyldimethicone, phenyltrimethylsi-loxydiphenylsiloxane, diphenyldimethicone and diphenylmethyldiphenyltrisiloxane, and the siloxanes disclosed in the U.S. patent application publication No. 2004 / 0126350, the full disclosure of which is incorporated herein by reference. Specific examples of suitable high viscosity silicone oils include, but are not limited to, Wacker's 15 M 30 PCR (500 cSt) or Wacker's Belsil PDM 1000 (1000 cSt) and Dow Corning 200 (350 cSt) (values ​​in parentheses represent viscosities at 25°C).

[0122] Particularly preferred oils include, but are not limited to, one or more of the following: diisopropyl sebacate, C12-15 alkyl benzoate, phenethyl benzoate, isopropyl lauroyl sarcosinate, diisopropyl adipate, dibutyl adipate, dicaprylyl carbonate, dicaprylate / dicaprate, coco glycerides, Caprylic / capric triglyceride, isopropyl myristate, isopropyl palmitate, coco caprylate / caprate, ethylhexyl palmitate, isononyl isononanoate, octyldodecanol, isohexadecane, isododecane, dicaprylyl ether, C15-19 alkane, dii-isopropyl adipate, dicaprylyl ether, and mixtures thereof.

[0123] Preferred oils for solubilizing bis-ethylhexyloxyphenol methoxyphenyl triazine include, but are not limited to, diisopropyl sebacate, C12-15 alkyl benzoate, phenethyl benzoate, isopropyl lauroyl sarcosinate, dibutyl adipate, butyloctyl salicylate, dicaprylyl carbonate, di-caprylate / dicaprate, cocoglycerides, caprylic / capric triglyceride, isopropyl myristate, isopropyl palmitate, coco caprylate / caprate, ethylhexyl palmitate, and mixtures thereof. Particularly preferred oils are C12-15 alkyl benzoate, phenethyl benzoate, isopropyl lauroyl sarcosinate, dibutyl adipate and butyloctyl salicylate, with C12-15 alkyl benzoate being most preferred.

[0124] According to preferred embodiments, the spray compositions of the present disclosure comprise a bis-ethylhexyloxyphenol methoxyphenyl triazine solubilizing system comprising at least one solvent which is present in the system in an amount effective to solubilize the bis-ethylhexyloxyphenol methoxyphenyl triazine such that the composition is suitable for use as a spray composition and can be used as such. Preferably, the at least one solvent is selected from the oils discussed in the preceding paragraph.

[0125] According to preferred embodiments, the at least one oil is present in the compositions of the present disclosure in an amount ranging from about 1% to about 50% by weight, more preferably from about 5 to about 40% by weight, and most preferably from about 10% to about 35% by weight, based on the total weight of the composition, including all intermediate ranges and sub-ranges such as, for example, 15% to 40%, 20% to 45%, etc.

[0126] According to preferred embodiments, the compositions of the present disclosure are anhydrous.

[0127] According to preferred embodiments, the compositions of the present disclosure are in the form of an emulsion and contain at least one oily phase. Aqueous Phase

[0128] The compositions of the present disclosure may also optionally contain water. When the compositions of the present disclosure contain water, they are preferably in the form of an emulsion. Preferably, when the compositions of the present disclosure contain water, they are in the form of an emulsion containing an external aqueous phase such as an oil-in-oil emulsion. water (O / W) or a water-in-oil-in-water (W / O / W) emulsion, or an emulsion containing an external oil phase such as a water-in-oil (W / O) emulsion or an oil-in-water-in-oil (O / W / O) emulsion. Preferably, when in the form of an emulsion, the oil phase may contain silicone oils (e.g., Si / W or W / Si emulsion) or hydrocarbon oils. Where present, water is preferably present in an amount of from about 10% to about 80% by weight, preferably from about 20% to about 70% by weight, preferably from about 35% to about 65% by weight, including all intermediate ranges and sub-ranges, all weights being based on the total weight of the composition.

[0129] According to preferred embodiments, however, the compositions of the present disclosure are water-free, substantially water-free, or water-free as defined herein. Preferably, the compositions of the present disclosure are anhydrous.

[0130] If present in compositions of the present disclosure, the aqueous phase may comprise at least one water-soluble organic solvent that is liquid at room temperature and atmospheric pressure. For example, such at least one water-soluble organic solvent may include:

[0131] - triethyl citrate;

[0132] - C1-C5 monoalcohols having a C1-C5 alkane chain and a single function hydroxyl (OH). Suitable C1-C5 monohydric alcohols include methanol, ethanol, propanol, isopropanol, butanol, and mixtures thereof;

[0133] - polyols (compounds having 2 or more hydroxyl groups) having, for example, 2 with 20 carbon atoms, preferably from 2 to 6 carbon atoms, such as for example glycerol, diglycerol, propylene glycol, isoprene glycol, dipropylene glycol, butylene glycol, hexylene glycol, 1,3-propanediol, pentylene glycol, simple sugars and water-soluble polyalkylene glycols;

[0134] - and their mixtures.

[0135] According to preferred embodiments, the at least one water-soluble organic solvent is selected from the group consisting of ethanol, dipropylene glycol, butylene glycol, propanediol and propylene glycol, and mixtures thereof.

[0136] Where appropriate, the water-soluble organic solvent(s) is / are preferably present in the compositions of the present disclosure in a total amount ranging from 0.5% to about 40% by weight, preferably from about 3% to about 30% by weight, and most preferably from about 5% to about 20% by weight, based on the total weight of the composition, including all intermediate ranges and sub-ranges, such as 2% to 15%, 2% to 25%, 7.5% to 30%, etc.

[0137] According to preferred embodiments wherein the composition of the present disclosure is an alcohol-based composition, such compositions contain preferably at least one C1-C5 monohydric alcohol in an amount of from about 10% to about 80% by weight, preferably from about 25% to about 75% by weight, and preferably from about 40% to about 70% by weight, all weights being based on the total weight of the composition, including all intermediate ranges and sub-ranges. Additional optional ingredients

[0138] The compositions of the present disclosure may also optionally further include at least one additive or auxiliary commonly used in spray compositions and known to those skilled in the art as being capable of being incorporated into such compositions.Such additives or auxiliaries may be selected from coloring agents, film formers, waxes, color protecting agents such as piperidinol compounds, SPF enhancers such as diethylhexyl syringylidenemalonate, ethylhexyl methoxycrylene and octyl butyl salicylate, thixotropic agents (e.g., clays), fillers, preservatives, perfumes, surfactants, antioxidants, free radical scavengers, spreading agents, dispersing agents, antifoaming agents, neutralizing agents, stabilizing agents, active ingredients selected from essential oils, moisturizing agents, vitamins, actives, proteins, ceramides, plant extracts, fibers and the like, wetting agents, and mixtures thereof. However, preferably, the compositions of the present disclosure are "free", "substantially free" or "devoid" of such additives. Coloring agent.

[0139] According to preferred embodiments, spray compositions optionally further comprising at least one coloring agent are provided. Preferably, the at least one coloring agent is selected from the group consisting of soluble dyes, pigments, pearlescent agents and glitters.

[0140] The expression "soluble dyes" must be understood as referring to organic, inorganic or organometallic compounds, soluble in the composition according to the disclosure and intended to color said composition.

[0141] Suitable dyes are, for example, Sudan Red, DC Red 17, DC Green 6, [3-carotene, soybean oil, Sudan Brown, DC Yellow 11, DC Violet 2, DC Orange 5 and Quinoline Yellow.

[0142] The term “nacres” should be understood as referring to iridescent particles of any shape, in particular produced by certain molluscs in their shell or by synthetic means.

[0143] The term "pigments" should be understood as referring to inorganic or organic, white or colored particles of any shape, insoluble in the composition according to the disclosure and intended to color said composition.

[0144] The pigments can be white or colored, inorganic and / or organic. Among inorganic pigments, including titanium dioxide, optionally surface-treated, zirconium or cerium oxides, as well as zinc, iron (black, yellow or red) or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and iron blue, metal powders such as aluminum powder, copper powder.

[0145] Among the organic pigments, mention may be made of carbon black, type D and C pigments and lakes based on cochineal carmine, barium, strontium, calcium, aluminum.

[0146] Mention may also be made of effect pigments such as particles comprising a natural or synthetic organic or inorganic substrate, for example glass, acrylic resins, polyester, polyurethane, polyethylene terephthalate, ceramics, aluminas and optionally coated with metallic substances such as aluminum, gold, copper, bronze, or metallic oxides such as titanium dioxide, iron oxide, chromium oxide, inorganic or organic pigments, and mixtures thereof.

[0147] The pearlescent pigments may be chosen, for example, from silica, titanium dioxide and mica based pigments, including, for example, mica based pigments sold under the trade name Spectrval by Merck KGaA, white pearlescent pigments such as mica coated with titanium, or bismuth oxychloride, colored pearlescent pigments such as titanium mica coated with iron oxides, titanium mica coated with ferric blue and chromium oxide in particular, titanium mica coated with an organic pigment of the aforementioned type and pearlescent pigments based on bismuth oxychloride.

[0148] Pigments with goniochromatic properties may be used, in particular liquid crystals or multi-layer pigments.

[0149] It is also possible to use optical brighteners or fibers optionally coated with optical brighteners.

[0150] Preferably, the at least one coloring agent is present in the compositions of the present disclosure in an amount effective to provide visible color to the spray after application of the composition to the spray, preferably ranging from about 0.1% to about 50% by weight, preferably from about 0.2% to about 40% by weight, preferably from about 0.5% to about 25%, preferably from about 5% to about 25%, and preferably from about 5% to about 20% by weight based on the weight of the composition, including all intermediate ranges and sub-ranges such as, for example, 2% to 15%, 25% to 50%, 3% to 8%, etc. Wax

[0151] According to preferred embodiments of the present disclosure, compositions optionally further comprising at least one wax are provided. Preferably, the at least one wax has a melting point of at least 40°C, preferably at least 50°C, and preferably at least 60°C.

[0152] Suitable examples of waxes that may be included in the compositions of the present disclosure include those generally used in the cosmetic field, such as, for example, synthetic waxes, silicone waxes, fatty alcohol waxes, waxes of natural origin, etc.

[0153] Specific waxes of natural origin include, in particular, beeswax and vegetable waxes, and include waxes such as carnauba wax, candelilla wax, ouricoury wax, Japan wax, sunflower wax, cork fiber wax or sugarcane wax, bran (rice) wax, montan wax, paraffin wax, lignite wax or microcrystalline wax, ceresin or ozokerite, with beeswax, carnauba wax and bran (rice) wax being preferred.

[0154] Examples of silicone waxes, if any, include, but are not limited to, silicone waxes such as alkyl- or alkoxydimethicones having an alkyl or alkoxy chain ranging from 10 to 45 carbon atoms, poly(di)methylsiloxane esters which are solid at 30°C and have at least 10 carbon atoms in the ester chain, di(1,1,1-trimethylolpropane tetrastearate), which is sold or manufactured by Heterene under the name HEST 2T-4S; alkylated silicone acrylate copolymer waxes comprising at least 40 mol% of siloxy units having the formula (R2R'SiO i / 2)x(R"SiO3 / 2)y, where x and y have a value of 0.05 to 0.95, R is an alkyl group having 1 to 8 carbon atoms, an aryl group, a carbinol group, or an amino group, R is a monovalent hydrocarbon having 9 to 40 carbon atoms, R" is a monovalent hydrocarbon group having 1 to 8 carbon atoms, an aryl group such as those disclosed in US patent application2007 / 0149703, the entire contents of which are incorporated by reference, a particular example being C30-C45 alkyldimethylsilyl polypro-pylsilsesquioxane; and mixtures thereof.

[0155] The fatty alcohol waxes preferably contain from about 8 to about 30 carbon atoms, preferably from about 12 to about 28 carbon atoms, and preferably from about 14 to about 24 carbon atoms, including, but not limited to, 8 to 24 carbon atoms, 12 to 16 carbon atoms, 16 to 22 carbon atoms, etc. The fatty alcohol wax may be saturated or unsaturated, straight or branched. Examples include cetyl alcohol, stearyl alcohol, behenyl alcohol, and mixtures thereof.Other examples of suitable fatty alcohol waxes include waxes including natural components (such as one or more natural oils) and fatty alcohol components such as, for example, hydrogenated stearyl olive ester, commercially available from the supplier Sophim under the trade name Phytowax Olive 18 L 57, and hydrogenated myristyl olive ester, commercially available from the supplier Sophim under the trade name Phytowax Olive 14 L48.

[0156] Optionally, the at least one wax is preferably present in an amount of about 0.5% to about 30% by weight, preferably about 1% to about 25% by weight, preferably about 2.5% to about 25% by weight, and preferably about 5% to about 20% by weight, including all intermediate ranges and sub-ranges such as, for example, about 1% to about 12% by weight, about 2% to about 10% by weight, about 15% to about 25% by weight, and about 2% to about 8% by weight, all weights being based on the total weight of the composition.

[0157] According to certain embodiments, the composition contains less than 10% by weight of beeswax, preferably less than 5% by weight of beeswax, preferably less than 2.5% by weight of beeswax, or is preferably "substantially free", "lacking" or "free" of beeswax as defined above.

[0158] According to certain embodiments, the composition contains less than 10% by weight of synthetic wax, preferably less than 5% by weight of synthetic wax, preferably less than 2.5% by weight of synthetic wax, or is preferably "substantially free", "lacking" or "free" of synthetic wax as defined above.

[0159] According to certain embodiments, the composition less than 10% by weight of silicone wax, preferably less than 5% by weight of silicone wax, preferably less than 2.5% by weight of silicone wax, or is preferably "substantially free", "lacking" or "free" of silicone wax as defined above. Thixotropic agent

[0160] According to certain embodiments, the compositions of the present disclosure may also optionally further include at least one thixotropic agent. The at least one thixotropic agent may be selected, for example, from hydrophilic or organophilic clays, hydrophilic or hydrophobic fumed silicas, elastomeric organopolysiloxanes, and mixtures thereof.

[0161] Clays are silicates containing a cation that may be selected from calcium, magnesium, aluminum, sodium, potassium, and lithium cations, and mixtures thereof. As used herein, the term "hydrophilic clay" refers to a clay capable of swelling in water; this clay swells in water and upon hydration forms a colloidal dispersion.

[0162] Examples of such products include, but are not limited to, smectite family clays such as montmorillonites, hectorites, bentonites, beidellites and saponites, vermiculite family clays, stevensite and chlorites.

[0163] These clays can be of natural or synthetic origin.

[0164] Non-limiting examples of hydrophilic clays include smectites such as saponites, hectorites, montmorillonites, bentonites and beidellites and, in at least one embodiment, synthetic hectorites (also known as laponites), for example, the products sold by Laporte Company under the names Laponite XLG, Laponite RD and Laponite RDS (these products include, for example, sodium magnesium silicates and sodium lithium magnesium silicates); bentonites, for example, the product sold under the name Bentone HC by Rheox Company; magnesium aluminum silicates, which may be hydrated, for example, the products sold by Vanderbilt Company under the names Veegum Ultra, Veegum HS and Veegum DGT, and calcium silicates, such as the product in synthetic form sold by the company under the name Micro-cel C.

[0165] Organophilic clays are clays modified with chemical compounds that make the clay capable of swelling in solvent media.

[0166] The clay may be selected, for example, from montmorillonite, bentonite, hectorite, atapulgite, sepiolite and mixtures thereof. In one embodiment, the clay is selected from bentonite and hectorite.

[0167] The chemical compound used to modify the organophilic clay may be selected, for example, from quaternary amines, tertiary amines, amine acetates, imidazolines, amine soaps, fatty sulfates, alkyl aryl sulfonates, amine oxides, and mixtures thereof.

[0168] Suitable organophilic clays include, but are not limited to, stearalkonium clays such as stearalkonium hectorite and stearalkonium bentonites such as those sold as Bentone 27V by Elementis, Tixogel LG by United Catalyst, and Claytone AF and Claytone APA by Southern Clay; quatemium-18 bentonites such as those sold as Bentone 3, Bentone 38, Bentone 27 V CG, and Bentone 38V by Elementis, Tixogel VP by United Catalyst, and Claytone 34, Claytone 40, and Claytone XL by Southern Clay; and quaternium-18 / benzalkonium bentonites such as those sold under the names Claytone HT and Claytone PS by the Southern Clay company.

[0169] Hydrophilic fumed silicas can be obtained by high-temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, producing a finely divided silica. Hydrophilic silicas have a large number of silanol groups on their surface. Such hydrophilic silicas are sold, for example, under the names Aerosil 130®, Aerosil 200®, Aerosil 255®, Aerosil 300® and Aerosil 380® by the company Degussa, and Cab-O-Sil HS-5®, Cab-O-Sil EH-5®, Cab-O-Sil LM-130®, Cab-O-Sil MS-55® and Cab-O-Sil M-5® by the company Cabot.

[0170] Hydrophobic fumed silicas can be obtained by modifying the surface of the silica via a chemical reaction which generates a reduction in the number of silanol groups, these groups being optionally substituted, for example, by hydrophobic groups.

[0171] The hydrophobic groups may be chosen, for example, from:

[0172] - trimethylsiloxyl groups, which can be obtained by treatment of silica sublimed in the presence of hexamethyldisilazane. Silicas treated in this way are known as "silica silylate" according to the CTFA (6th edition, 1995). They are sold, for example, under the references Aerosil R812® by the company Degussa, and Cab-O-Sil TS-530® by the company Cabot,

[0173] - dimethylsilyloxyl or polydimethylsiloxane groups, which can be obtained in particular by treatment of the sublimed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. The silicas thus treated are known under the name of “Silica dimethyl silylate” according to the CTFA (6th edition, 1995). They are sold, for example, under the references Aerosil R972® and Aerosil R974® by the company Degussa, and CAB-O-SIL TS-610® and CAB-O-SIL TS-720® by the company Cabot.

[0174] The at least one thixotropic agent, if any, may preferably be present in the composition in an amount ranging from 0.05 percent by weight, for example, preferably from about 0.05 percent to about 15 percent by weight, preferably from about 0.5 percent to about 10 percent by weight, and preferably from about 0.75 percent to about 5 percent by weight, all weights being relative to the total weight of the composition, including all intermediate ranges and sub-ranges such as, for example, 1% to 3%, 0.5% to 7%, 5% to 15%, etc. Charges

[0175] According to certain embodiments, the compositions of the present disclosure may also optionally further include at least one filler.

[0176] Suitable examples of fillers include mineral or organic particles of any shape, sheet-like, spherical, or oblong, regardless of crystallographic shape (e.g., sheet, cubic, hexagonal, orthorhombic, etc.).Examples of suitable polymers include talc, mica, kaolin, polyamide (Nylon®) (Orgasol® from Atochem), poly-[3-alanine and polyethylene powders, tetrafluoroethylene polymer powders (Teflon®), lauroyl-lysine, starch, boron nitride, acrylic acid copolymers (Polytrap® from Dow Corning) and silicone resin microbeads (Tospearls® from Toshiba, for example), polyorganosiloxane elastomer particles, precipitated calcium carbonate, magnesium carbonate and hydrocarbonate, hydroxyapatite, glass or ceramic microcapsules, metal soaps derived from organic carboxylic acids having 8 to 22 carbon atoms, preferably 12 to 18 carbon atoms, for example zinc, magnesium or lithium stearate, laurate zinc, magnesium myristate.

[0177] The at least one filler, if any, is preferably present in an amount ranging from about 0.01% to about 15% by weight, preferably from about 0.1% to about 5% by weight, preferably from about 0.5% to about 2.5%, all weights being relative to the total weight of the nail compositions, including all intermediate ranges and sub-ranges.

[0178] A person skilled in the art will take care to choose the optional additional additives and / or their quantity so that the advantageous properties of the composition according to the disclosure are not, or not substantially, compromised by the intended addition.

[0179] It goes without saying that the composition of the disclosure must be cosmetically or dermatologically acceptable, i.e. it must contain a non-toxic, physiologically acceptable carrier. The composition may be in any dosage form normally employed in the cosmetic and dermatological fields which is suitable for topical administration as discussed above.

[0180] These auxiliary additives may be present in the composition in a proportion of 0% to 99% (such as 0.01% to 90%) based on the total weight of the composition and further such as 0.1% to 50% by weight (where applicable), including all intermediate ranges and sub-ranges.

[0181] According to preferred embodiments of the present disclosure, methods of protecting, improving the appearance of, and / or making up a keratinous material by applying spray compositions of the present disclosure to the keratinous material in an amount sufficient to protect the keratinous material, improve its appearance, and / or make it up are provided. Preferably, "making up" the keratinous material includes applying a composition comprising at least one coloring agent to the keratinous material in an amount sufficient to make up the keratinous material.

[0182] Preferably, "protecting" the keratinous material includes applying a composition of the present disclosure to the keratinous material in an amount sufficient to protect the keratinous material from damage resulting from exposure to UV rays.

[0183] According to the preceding embodiments, the compositions of the present disclosure are applied topically to the keratinous material in an amount sufficient to protect the keratinous material, improve its appearance, care for it and / or make it up. The compositions may be applied to the desired area as needed, preferably once or twice daily, more preferably once daily, and then preferably allowed to dry before subjecting them to contact such as with clothing or other objects (e.g., clothing or a topcoat). Preferably, the composition is allowed to dry for about 1 minute or less, more preferably for about 45 seconds or less.

[0184] According to preferred embodiments of the present disclosure, methods of Protection of keratinous material from UV rays comprising applying spray compositions of the present disclosure to keratinous material in an amount sufficient to protect the keratinous material from UV rays are provided.

[0185] According to preferred embodiments of the present disclosure, methods of making spray compositions comprising adding bis-ethylhexyloxyphenol methoxyphenyl triazine during formation of the compositions are provided. Preferably, bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT) is added to the compositions in an amount effective to protect the keratinous material from UV radiation.

[0186] The present disclosure also contemplates kits and / or pre-packaged materials suitable for consumer use containing one or more compositions according to the present disclosure, alone or in combination with other consumer care products such as makeup products such as base coats, top coats, makeup remover compositions, etc. The packaging and application device for any subject of the disclosure may be selected and manufactured by persons skilled in the art on the basis of their general knowledge, and adapted according to the nature of the composition to be packaged. Indeed, the type of device to be used may be in particular linked to the consistency of the composition, in particular to its viscosity; it may also depend on the nature of the constituents present in the composition, such as the presence of volatile compounds.

[0187] Unless otherwise indicated, all numbers expressing amounts of ingredients, reaction conditions, etc., used in the patent specification and claims are to be understood as being modified in all cases by the term "about". Accordingly, unless otherwise indicated, the numerical parameters presented in the following patent specification and appended claims are approximations which may vary depending on the desired properties sought to be achieved by the present disclosure.

[0188] Although the numerical ranges and parameters defining the general scope of the disclosure are approximations, the numerical values ​​indicated in the specific examples are reported as accurately as possible. However, any numerical value inherently contains certain errors necessarily resulting from the standard deviation found in their respective measurements. The following examples are intended to illustrate the disclosure without limiting its scope. Percentages are given on a weight basis. Example 1

[0189] [Tables3] INGREDIENT(S) SUNSCREEN SPRAY (% by weight) Octisalate (UV FILTER) 2.88 Homosalate (UV FILTER) 9.6 Avobenzone (UV FILTER) 2.68 Bemotrizinol (UV FILTER) 3.46 EMULSIFIERS 2.33 EMOLLIENTS <2 VITAMINS & PRESERVATIVES <2 Polyurethane-35 & Stearyl Alcohol (POLYMERS & THICKENER-SIZERS) 2.62 HUMECTANT 3 WATER QS Example 2

[0190] [Tables4] INGREDIENT(S) SPRAY SPF50 (% by weight) Avobenzone (UV FILTER) 3 Octisalate (UV FILTER) 4.5 Bemotrizinol (UV FILTER)Oc 6 Ensulizole (UV FILTER) 0.5 C12-22 Alkyl Acrylate / Hydroxyethyl Acrylate Copolymer (THICKENER) 2 ADDITIONAL THICKENERS 0.25 OILS / EMOLLIENTS 22 WATER QS VITAMINS & PRESERVATIVES <2 GLYCOLS / HUMECTANTS 7 C1-C5 MONO ALCOHOL 5 Example 3

[0191] [Tables5] INGREDIENT(S) ANHYDROUS SPRAY SPF30 (% by weight) Avobenzone (UV FILTER) 3 Octisalate (UV FILTER) 5 Bemotrizinol (UV FILTER) 5 OIL / EMOLLIENT QS VITAMINS AND ACTIVE INGREDIENTS <2 Ethylenediamine / stearyl dimer dilinoleate copolymer (POLYMER) 3 C1-C5 monoalcohol 8

Claims

Claims

1. A spray composition comprising bemotrizinol, wherein bemotrizinol is present in the composition in an amount effective to protect the skin against UV rays.

2. A composition according to claim 1, wherein the composition comprises 10% or less by weight relative to the total weight of the composition of additional UV filters, preferably 10% or less by weight relative to the total weight of the composition of additional organic UV filters.

3. Composition according to any one of the preceding claims, in which the composition is free of mineral UV filters.

4. A composition according to any preceding claim, further comprising a propellant.

5. A composition according to any preceding claim, wherein the composition is fluid.

6. A composition according to any preceding claim, wherein the composition is in the form of an emulsion.

7. A composition according to any preceding claim, wherein the composition is anhydrous.

8. Composition according to any one of the preceding claims, further comprising at least one C1-C5 monoalcohol.

9. A composition according to any preceding claim, further comprising at least one active agent.

10. A composition according to any preceding claim, wherein the composition is non-greasy upon application to the skin.