ENVIRONMENTALLY FRIENDLY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE

Abstract

ENVIRONMENTALLY FRIENDLY COMPOSITIONS CONTAINING BIS-ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE The present disclosure relates to environmentally friendly compositions comprising 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: bis-ethylhexyloxyphenol methoxyphenyl triazine) and an environmentally friendly carrier, as well as methods of making and using such compositions Figure for abstract: none

Description

Title of the invention: ENVIRONMENTALLY FRIENDLY COMPOSITIONS CONTAINING BIS- ETHYLHEXYLOXYPHENOL METHOXYPHENYL TRIAZINE FIELD OF THE INVENTION

[0001] The present disclosure relates to environmentally friendly compositions comprising 2,4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (INCI name: bis-ethylhexyloxyphenol me-thoxyphenyl triazine) and an environmentally friendly carrier, as well as methods of making and using such compositions. DISCUSSION OF THE CONTEXT

[0002] Many cosmetic compositions contain ingredients of animal origin or natural beeswax to achieve a desired texture or desired properties in the compositions. Due to growing concerns about how these ingredients may be obtained, many consumers prefer to avoid cosmetics containing such ingredients, opting instead for products that do not rely on these ingredients.

[0003] Similarly, many customers prefer to avoid cosmetics containing non-biodegradable ingredients such as microplastics due to the potential environmental effects such ingredients can have.

[0004] However, without these ingredients, it may be difficult to achieve a desired texture for cosmetic compositions containing UV filters, or it may be difficult to achieve other desirable properties such as, for example, improved application properties in such compositions, particularly in compositions containing bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0005] Radiation with wavelengths between 290 nm and 400 nm allows tanning of the human epidermis, while radiation with wavelengths between 290 and 320 nm, called UVB rays, hinders the development of a natural tan. Exposure is also likely to cause a detrimental change in the biomechanical properties of the epidermis, resulting in the appearance of wrinkles leading to premature aging of the skin (i.e., photoaging).

[0006] UVA rays with a wavelength between 320 and 400 nm penetrate deeper into the skin than UVB rays. UVA rays cause immediate and persistent browning of the skin. Daily exposure to UVA rays, even for a short time, under normal conditions, can damage collagen fibers and elastin, which results in a change in the microrelief of the skin, the appearance of wrinkles and irregular pigmentation (spots, uneven skin tone).

[0007] Numerous studies show the need for effective protection against UVA and UVB to prevent sunburn, photoaging, and the like.

[0008] In order to obtain a high protection product, it is generally necessary to combine a large number of sunscreens and / or a large quantity of UV filters to achieve high levels of filtration efficiency.

[0009] The high levels of UV filters, however, do not lend themselves to easy preparation of stable, environmentally friendly compositions with a pleasant texture.

[0010] There remains a need in the art for improved environmentally friendly compositions that possess organic UV filters and have pleasant application properties (e.g., a non-greasy feel) and UV protective properties.

[0011] Therefore, one aspect of the present disclosure relates to environmentally friendly compositions which possess organic UV filters and have pleasant application properties (e.g., a non-greasy feel) and UV protective properties. Summary of the invention

[0012] The present disclosure relates to environmentally friendly compositions comprising bis-ethylhexyloxyphenol methoxyphenyl triazine (BEMT or bemo-trizinol) and an environmentally friendly carrier. Preferably, the compositions contain minimal amounts of animal-derived ingredients and / or microplastics, or are free of such ingredients.

[0013] The present disclosure also relates to methods for treating, caring for, protecting, improving the appearance and / or making up a keratinous material comprising the application of compositions of the present disclosure to a keratinous material in an amount sufficient to treat the keratinous material, take care of it, improve its appearance and / or make it up.

[0014] The present disclosure also relates to methods of making environmentally friendly compositions comprising the combination of bis-ethylhexyloxyphenol methoxyphenyl triazine and ingredient(s) that form an environmentally friendly carrier during formation of the compositions. Preferably, the compositions contain minimal amounts of animal-derived ingredients and / or microplastics, or are free of such ingredients.

[0015] It should be understood that both the foregoing general description and the The following detailed descriptions are exemplary and explanatory only and do not limit disclosure. DETAILED DESCRIPTION OF THE INVENTION

[0016] In the following description and the claims appended thereto, it is to be understood that the terms used have their ordinary and customary meanings in the art, unless otherwise specified.

[0017] “Approximately” as used herein means within 10% of the number indicated (e.g. “about 10%” means 9% to 11% and “about 2%” means 1.8% to 2.2%.

[0018] “A” or “an” as used herein means “at least one”

[0019] “At least one” means one or more and thus includes components in individual as well as mixtures / combinations.

[0020] As used herein, all proposed ranges are intended to include each specific point and range within the given ranges, as well as combinations of subranges therebetween. Thus, a range of 1 to 5 specifically includes whole numbers within the range 1, 2, 3, 4, and 5, as well as subranges such as 2 to 5, 3 to 5, 2 to 3, 2 to 4, 1 to 4, etc., as well as all fractional numbers within the range such as 1.2, 2.3, 3.4, etc., and subranges including such fractional numbers, such as 1.5 to 3.8, 2 to 4.3, 4.2 to 4.9, etc.

[0021] “Film former”, “film-forming polymer” or “film-forming agent” as used herein means a polymer or resin that is capable of leaving a film on the substrate to which it is applied, for example, after a solvent accompanying the film former has evaporated, been absorbed into, and / or dissipated on the substrate.

[0022] “Substituted” as used herein means comprising at least one substituent. Non-limiting examples of substituents include atoms, such as hydrogen atoms or chlorine atoms, as well as functional groups, such as hydroxyl groups, ether groups, alkoxy groups, acyloxyalkyl groups, oxyalkylene groups, polyoxyalkylene groups, carboxylic acid groups, amine groups, acylamino groups, amide groups, halogen-containing groups, ester groups, thiol groups, sulfonate groups, thiosulfate groups, siloxane groups, and polysiloxane groups. The substituent(s) may be further substituted.

[0023] “Volatile,” as used herein, means having a flash point less than about 115°C.

[0024] “Non-volatile,” as used herein, means having a flash point greater than about 115°C.

[0025] “Polymer” as used herein means a compound that is made up of at least two monomers.

[0026] “Exempt” or “substantially free” or “devoid of” as used herein means that although it is preferable that no amount of the specific component is present in the composition, it is possible that there may be very small amounts thereof in the compositions of the disclosure, provided that such amounts do not materially affect at least one, preferably most, of the beneficial properties of the compositions of the disclosure. Thus, for example, "microplastic-free" means that an effective amount (i.e., greater than trace amounts) of microplastic(s) is omitted from the composition (i.e., about 0% by weight), "substantially microplastic-free" means that microplastic(s) is / are present in amounts no greater than 0.1% by weight, and "microplastic-free" means that microplastic(s) is / are present in amounts no greater than 0.25% by weight, based on the total weight of the composition.The same nomenclature applies to all other ingredients identified throughout the application and in this paragraph such as, for example, specific UV filters and / or surfactants (the compositions in the disclosure that are “oxybenzone and / or octinoxate-free,” “substantially oxybenzone and / or octinoxate-free,” and “oxybenzone and / or octinoxate-free,” as well as “surfactant-free,” “substantially surfactant-free,” and “surfactant-free” have meanings consistent with the discussion in this paragraph), even if not specifically discussed for each identified ingredient. Discussed examples of the use of such language such as those in this paragraph are intended to be provided by way of example, not limitation.

[0027] “UV filters” as used herein mean the active protective agents approved by a government regulatory agency such as the Food and Drug Administration (FDA) in the United States or the European Commission in Europe and include organic UV filters such as avobenzone, octocrylene, benzophenones, benzotriazoles and merocyanines, as well as mineral UV filters such as iron oxide, zinc oxide (ZnO) and titanium dioxide (TiO2).

[0028] “Anhydrous” as used herein means that the compositions of the disclosure contain less than 3% water, which means that the compositions may also contain less than 2% water, and less than 1% water, as well as be “water-free”, “substantially water-free” and “water-free” as defined above.

[0029] “Keratinous materials” refer to nails (fingernails and / or toenails), skin such as that of the body, face and eye area, scalp, keratinous fibers such as eyelashes, eyebrows and hair, and mucous membranes such as the lips.

[0030] “Physiologically acceptable” means compatible with keratinous materials and having a pleasant color, odor and feel, and which does not cause unacceptable discomfort (tingling or pulling) likely to discourage a consumer from using the composition.

[0031] “Environmentally friendly vector” means the ingredients of a com cosmetic position other than active agents, coloring agents and / or UV filters that are “environmentally friendly”. “Environmentally friendly” means that the ingredients in the carrier are not resistant to biodegradation and / or are renewable. Preferably, the “environmentally friendly” ingredients are not derived from animals. “Environmentally friendly carrier” means that the composition contains less than 3% of non-environmentally friendly ingredients, less than 2% of non-environmentally friendly ingredients and less than 1% of non-environmentally friendly ingredients, and also that it is “free of non-environmentally friendly ingredients”, “substantially free of non-environmentally friendly ingredients” and “free of non-environmentally friendly ingredients”, as defined above.

[0032] “UV protection efficiency” or “filtration efficiency” in the context of present disclosure, is evaluated from one or more of SPF, FPUVA, critical wavelength and UVA-I / UV ratio.

[0033] "SPF" (Sun Protection Factor) measures the level of protection against erythema provided by a composition. The SPF value corresponds to the ratio between the minimum erythema dose (MED) measured on skin covered with the composition and the MED measured on bare skin. The term "SPF" is known in the art of sunscreens and is defined, for example, in A new substrate to measure sunscreen protection factors throughout the ultraviolet spectrum, J. Soc. Cosmet. Chem., 40, 127-133 (May / June 1989).

[0034] The SPF (Sun Protection Factor) assessment can be carried out, for example, in vitro with a Labsphere spectrophotometer (North Sutton, NH, USA). In such an assessment, the plate is the material on which the composition under test is applied. For such an assessment, polymethyl methacrylate (PMMA) plates can be used. An example of an acceptable protocol is currently undergoing ISO accreditation as ISO Committee Draft 23675.

[0035] The evaluation of the sun protection factor (SPF) can also be carried out in vivo in accordance with the ISO 24444:2019 protocol “Cosmetics-Sun protection test methods-In-vivo determination of the sun protection factor (SPF).” It can also be determined in accordance with FDA protocols, as described in the document “Labeling and Effectiveness Testing; Sunscreen Drug Products for Over-the-Counter Human Use” published in the US Federal Register on 07 / 05 / 2011 (https: / / www.federalregister.gOv / d / 2011-14766); 21 CFR Part 352 Subpart D § 352.72, updated and revised by the 2011 publication in the Federal Register.

[0036] “UVA protection factor” (UVA protection factor) refers to a characteristic index tering the UVA protection provided by a composition. For example, the UVA factor may be measured in vivo in accordance with the "PPD" (Persistent Pigment Darkening) method of the ISO-24442:2022 protocol, measuring skin color observed 2 to 4 hours after UVA exposure. It may also be determined in accordance with FDA protocols, as described again in 21 CFR Part 352 Subpart D § 352.72 as discussed above in relation to SPF.

[0037] The assessment of UVA protection can also be measured in vitro with the Labsphere® spectrophotometer under conditions such as those discussed above in relation to SPF. The ISO 24443:2021 protocol describes such an in vitro method.

[0038] The FDA's broad spectrum test procedures, specifically the "critical wavelength" test procedures, are also available in 21 CFR Part 352 Subpart D § 352.72. In addition, the broad spectrum test procedures include the determination of the UVA1 / UV ratio as described in "Sunscreen Drug Products for Over-the-Counter-Human-Use" published in the Federal Register https: / / www.federalregister.gov / documents / 2019 / 02 / 26 / 2019-03019 / sunscreen-drug-pr oducts-for-over-the-counter-human-use. » In the assay described in the monograph, known as the Boots adaptation of the Diffey / Robson test method, a ratio is generated between the protection provided by the sunscreen product against UVA1 (340-400 nm) and the protection against total UV radiation (UVB and UVA at 290-400 nm) calculated from the absorbance curve. This UVA1 / UV ratio would represent the product's score in the in vitro test.

[0039] According to the present disclosure, the compositions of the present disclosure preferably have one or more of the following properties:

[0040] The compositions have a critical wavelength as determined by FDA critical wavelength procedures of at least 370 nm;

[0041] The compositions have an SPF value of at least 15, preferably at least 30, preferably at least 50 and preferably at least 70;

[0042] The compositions have an FPUVA / SPF ratio of at least 1 / 3, and preferably at least 2 / 5 and / or

[0043] The compositions have a UVA1 / UV ratio of 0.7 or more, preferably 0.75 or more, and preferably 0.8 or more.

[0044] “Makeup result” as used herein refers to the visual impact of a composition when applied to keratinous material such as skin. makeup result may concern the apparent color of the product after application to a keratinous material or an optical effect such as shine, the fading of fine lines and imperfections, or a concealing effect on pores or skin defects after application of the product to the keratinous material.

[0045] “Long-lasting” as used herein refers to compositions where the color or other apparent properties remain the same or substantially the same as at the time of application, as viewed by the naked eye, after an extended period of time, or after a particular stress event such as immersion in water or rubbing. “Long-lasting” may be evaluated by evaluating long-lasting properties by any method known in the art for evaluating such properties. For example, long-lasting may be evaluated by a test involving the application of a composition to a keratinous material such as skin and evaluating the color of the composition after an extended period of time. For example, the color of a composition may be evaluated immediately after application to a keratinous material such as skin, and these characteristics may then be re-evaluated and compared after a period of time.In addition, these characteristics can be evaluated relative to other compositions, such as commercially available compositions. “Long wear” can also be evaluated using in vitro methods on non-keratinous substrates such as polymethyl methacrylate (PMMA), in which properties such as color, transparency, or in vitro SPF can be evaluated before and after a period or stressor such as immersion in water, incubation at elevated temperatures, or application of an abrasive technique.

[0046] “Natural” as in the expression “natural compound” means any compound derived directly from a natural substance such as a plant without undergoing chemical modification.

[0047] “Naturally occurring compound” means any compound derived from a naturally occurring compound which has undergone one or more chemical modifications, for example by organic synthesis reaction, without the properties of the natural compound having been modified.

[0048] “Synthetic compound” means any compound that is neither a natural compound nor a compound of natural origin.

[0049] “Room temperature” means approximately 20 to 25°C.

[0050] “Atmospheric pressure” means approximately 760 mmHg, i.e. approximately 105 pascals.

[0051] “UV filter” and “sunscreen agent” are used interchangeably in this request.

[0052] The terms “UV efficacy”, “UV protection” and “UV efficacy” are used interchangeably in the present application.

[0053] The compositions and methods of the present disclosure may comprise, consist of, or consist essentially of, the essential elements and limitations of the disclosure described herein, together with any additional or optional ingredients, components, or limitations described herein or otherwise useful. For example, the UV (ultraviolet) absorbing system of the compositions of the disclosure may “consist essentially of” bis-ethylhexyloxyphenol methoxyphenyl triazine and one or more additional organic UV filters identified herein.

[0054] For the purposes of this disclosure, the "fundamental and novel property" associated with the compositions, components and methods that "consist essentially of" the identified ingredients or actions is "environmental friendliness."

[0055] The compositions of the present disclosure may be in any form suitable for use as a personal care composition, such as a stick, paste, cream, anhydrous composition, emulsion (oil in water, water in oil, multiple emulsion such as oil in water in oil), nanoemulsion, gel, liquid, solid, etc. These compositions may be used for any personal care purpose in cosmetic and / or dermatological products such as, for example, sunscreen, foundation, lip balms, lipsticks, concealers, mascaras, leave-in hair products, eye shadows, powders, etc.

[0056] Reference is made herein to trade names of materials including, but not limited to, materials such as polymers and optional components. The materials are not intended to be limited by the materials described and referenced by a certain trade name herein. Equivalent materials (e.g., those obtained from a different source under a different catalog name or (reference) number) to those referenced by a trade name may be substituted and used in the methods described and claimed herein.

[0057] All percentages and ratios are, unless otherwise indicated, calculated by weight. All percentages are, unless otherwise indicated, calculated based on the total weight of a composition. All levels of component or composition refer to the active level of that component or composition, and are exclusive of impurities, e.g., residual solvents or by-products, which may be present in commercially available sources.

[0058] All US patents or patent applications disclosed herein are expressly incorporated by reference in their entirety. Composition

[0059] Bis-ethylhexyloxyphenol methoxyphenyl triazine

[0060] According to the present disclosure, compositions comprising a UV (ultraviolet) absorbing system comprising 4-bis-{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazine (name INCI: bis-ethylhexyloxyphenol methoxyphenyl triazine) are proposed.

[0061] According to preferred embodiments, the UV absorbing system comprises at least 5% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 15% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 20% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 30% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 40% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 50% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 70% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, preferably at least 80% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, and preferably at least 90% by weight of bis-ethylhexyloxyphenol methoxyphenyl triazine, all weights based on the total weight of the UV absorbing system.The “UV absorbing system” contains all the organic and / or mineral UV filters present in the composition.

[0062] According to preferred embodiments, bis-ethylhexyloxyphenol methoxyphenyl triazine is present in compositions of the present disclosure in an effective UV absorbing amount, such as about 0.1% to about 10% by weight based on the total weight of the composition, about 1% to about 10% by weight, about 2.5% to about 8%, and about 4% to about 6% by weight, including all intermediate ranges and sub-ranges such as, for example, about 4.5% to about 10% by weight, and about 1% to about 8% by weight, about 1% to about 6% by weight, about 5.5% to about 8% by weight, about 5.7% to about 9% by weight, etc., all weights being based on the total weight of the composition. Additional sunscreen agents

[0063] According to preferred embodiments of the present disclosure, compositions optionally further comprising at least one additional UV filter (in addition to bis-ethylhexyloxyphenol methoxyphenyl triazine) selected from the group consisting of organic UV filters and inorganic UV filters such as zinc oxides, cerium oxides, titanium oxides and mixtures thereof are provided. Preferably, the at least one inorganic UV filter is coated, for example with a silicone-based coating. An example of such a silicone-based coating is hydrogen dimethicone, an exemplary product being hydrogen dimethicone-coated zinc oxide such as ZNO-C-DMC2 available from Kobo Products. Passivated inorganic UV filters, such as passivated zinc oxide, are suitable for use in the compositions of the present disclosure.

[0064] The additional organic UV filter(s) may be hydrophilic or lipophilic. “Hydrophilic organic UV filter” means an organic UV filter water-soluble or water-dispersible organic UV filter (in colloidal form). “Lipophilic organic UV filter” means a UV filter that is dissolved or dispersed in colloidal form in a liquid fatty phase.

[0065] Suitable organic UV filters may be chosen from the following non-exhaustive list of compounds: cinnamic compounds; anthranilate compounds; para-aminobenzoic acid compounds, salicylic compounds; dibenzoylmethane compounds; camphor compounds; benzophenone compounds; [3,[3-diphenylacrylate] compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; benzalmalonate compounds, including those cited in US patent 5,624,663; benzimidazole derivatives; imidazoline compounds; bis-benzoazolyl compounds as described in patents EP669323 and US 2,463,264; methylene bis(hydroxyphenylbenzotriazole) compounds as described in applications US 5,237,071, US 5,166,355, GB2303549, DE197 26 184 and EP893119; benzoxazole compounds as described in patent applications EP0832642, EP1027883, EP1300137 and DE10162844;polymer filters and silicone filters such as those described in particular in application WO 93 / 04665; alkylstyrene-derived dimers such as those described in patent application DE19855649; 4,4-diarylbutadiene compounds such as those described in applications EP0967200, DE19746654, DE19755649, EP-A-1008586, EPI 133980 and EP133981, and mixtures thereof. Preferably, the lipophilic organic UV filters are chosen from salicylic compounds, dibenzoylmethane compounds, benzylidene camphor compounds; benzophenone compounds; triazine compounds other than bis-ethylhexyloxyphenol methoxyphenyl triazine; benzotriazole compounds; as well as other categories of compounds identified herein; and mixtures thereof. ;

[0066] Reference may specifically be made to suitable salicylic compounds including Homosalate (homomentyl salicylate), for example marketed under the trademark "Eusolex HMS" by Rona / EM Industries; and ethylhexyl salicylate, for example marketed under the trademark "Neo Heliopan OS" by Symrise; and glycol salicylate. Other examples of salicylate compounds include phenyl salicylate; dipropylene glycol salicylate, for example marketed under the trademark "Dipsal" by Scher; and TEA salicylate, for example marketed under the trademark "Neo Heliopan TS" by Symrise.

[0067] Examples of suitable [3,[3-diphenylacrylate] compounds include Octocrylene, for example marketed under the trademark "Uvinul N539" by BASF; and Etocrylene, for example marketed under the trademark "Uvinul N35" by BASF.

[0068] Suitable anthranilic compounds may include methyl anthranilates, marketed for example under the trademark "Neo Heliopan MA" by Symrise.

[0069] Examples of dibenzoylmethane compounds include butyl methoxydibenzoylmethane, for example marketed under the trademark "Parsol 1789" by DSM; and isopropyl dibenzoylmethane.

[0070] Suitable cinnamic compounds include ethylhexyl methoxycinnamate, sold for example under the trademark "Parsol MCX" by DSM; isopropyl methoxycinnamate; isopropoxyl methoxycinnamate; isoamyl methoxycinnamate, sold for example under the trademark "Neo Heliopan E 1000" by Symrise; cinoxate (2-ethoxyethyl-4-methoxycinnamate); DEA methoxycinnamate; diisopropyl methylcinnamate; and glyceryl ethylhexanoate dimethoxycinnamate.

[0071] Examples of camphor compounds include benzylidenecamphor derivatives: 3-benzylidenecamphor, for example sold under the trademark "Mexoryl SD" by Chimex; 4-methylbenzylidenecamphor, for example sold under the trademark "Eusolex 6300" by Merck; benzylidenecamphor sulfonic acid, for example sold under the trademark "Mexoryl SL" by Noveal; benzalkonium camphor methosulfate, for example sold under the trademark "Mexoryl SO" by Noveal; terephthalylidene di-camphor sulfonic acid, for example sold under the trademark "Mexoryl SX" by Noveal; and polyacrylamidomethyl-benzylidenecamphor, for example sold under the trademark "Mexoryl SW" by Noveal.

[0072] Suitable benzophenone compounds include benzophenone-1 (2,4-dihydroxybenzophenone), such as that marketed under the trademark "Uvinul 400" by BASF; benzophenone-2 (Tetrahydroxybenzophenone), such as that marketed under the trademark "Uvinul D50" by BASF; benzophenone-3 (2-hydroxy-4-methoxybenzophenone) or oxybenzone, such as that marketed under the trademark "Uvinul M40" by BASF; benzophenone-4 (hydroxymethoxy benzophonene sulfonic acid), such as that marketed under the trademark "Uvinul MS40" by BASF; benzophenone-5 (Hydroxymethoxy benzophenone sulfonate sodium); benzophenone-6 (dihydroxy dimethoxy benzophenone), such as that marketed under the brand name “Helisorb 11” by Norquay; benzophenone-8, such as that marketed under the brand name “Spectra-Sorb UV-24” by American Cyanamid;benzophenone-9 (disodium dihydroxy dimethoxy benzophenonedisulfonate), such as that marketed under the trademark “Uvinul DS-49” by BASF; and benzophenone-12, and n-hexyl 2-(4-diethylamino-2-hydroxybenzoyl)benzoate (such as that marketed under the trademark “UVINUL A+” by BASF). ;

[0073] Examples of triazine compounds include diethylhexyl butamido triazone, such as than that marketed under the brand name “Uvasorb HEB” by the company Sigma 3V; 2,4,6-tris(dineopentyl 4'-aminobenzalmalonate)-s-triazine, bis-ethylhexyloxyphenol methoxyphenyl triazine, such as that marketed under the brand name “TINOSORB S” by BASF and ethylhexyl triazone, such as that marketed under the brand name “UVTNUL T150” by BASF.

[0074] Suitable benzotriazole compounds include phenylbenzotriazole derivatives: 2-(2H-benzotriazol-2-yl)-6-dodecyl-4-methylpheno, branched and linear, and those described in USP 5240975.

[0075] Suitable benzalmalonate compounds include dineopentyl 4'-methoxybenzalmalonate and polyorganosiloxane comprising benzalmalonate functional groups, such as polysilicone-15, such as that marketed under the trademark "Parsol SLX" by Hoffmann-LaRoche.

[0076] Examples of benzimidazole compounds include, in particular, phenylbenzimidazole derivatives such as phenylbenzimidazole sulfonic acid, such as that marketed, in particular, under the trademark "Eusolex 232" by Merck, and disodium phenyl dibenzimidazole tetrasulfonate, such as that marketed under the trademark "Neo Heliopan AP" by Symrise.

[0077] Suitable imidazoline compounds include ethylhexyl dimethoxybenzylidene dioxoimidazoline propionate.

[0078] Examples of bis-benzoazolyl compounds include the compounds described in EP-669,323 and US Patent No. 2,463,264.

[0079] Suitable para-aminobenzoic acid compounds include PABA (p-aminobenzoic acid), ethyl PABA, ethyl dihydroxypropyl PABA, pentyl dimethyl PABA, ethylhexyl dimethyl PABA, such as that marketed under the trademark "Escalol 507" by ISP, glyceryl PABA, and PEG-25 PABA, such as that marketed under the trademark "Uvinul P25" by BASF.

[0080] Suitable methylene bis-(hydroxyphenylbenzotriazol) compounds include 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-methyl-phenol], such as that marketed under the trademark "Mixxim BB / 200" by Fairmount Chemical, 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol], such as that marketed in micronized form in aqueous dispersion under the trademark "Tinosorb M" by BASF or under the trademark "Mixxim BB / 100" by Fairmount Chemical, and derivatives as described in U.S. Pat. Nos. 5,237,071 and 5,166,355, GB-2,303,549, DE-197 26 184 and EP-893 119, and drometrizole tri-siloxane, such as that marketed under the brand name “Silatrizole” by Rhodia Chimie or “Mexoryl XL” by L'Oréal.

[0081] Examples of benzoxazole compounds include 2,4-bis[5-l(dimethylpropyl)benzoxazol-2-yl-(4-phenyl)imino]-6-(2-ethylhexyl)imino- 1,3,5-triazine, such as that marketed under the brand name Uvasorb K2A by Sigma 3V.

[0082] Suitable examples of protective polymers and protective silicones include the silicones described in WO 93 / 04665.

[0083] Suitable α-alkylstyrene-derived dimers include the dimers described in DE-19855649.

[0084] Examples of 4,4-diarylbutadiene compounds include 1,1-dicarboxy(2,2'-dimethylpropyl)-4,4-diphenylbutadiene.

[0085] According to preferred embodiments, the compositions of the present disclosure further comprise at least one additional organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Ho-mosalate, Octocrylene, and mixtures thereof. In such embodiments, the UV absorbing system may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine and (2) at least one organic UV filter selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate, Octocrylene, and mixtures thereof.

[0086] According to other preferred embodiments, however, the compositions of the present disclosure are "free", "substantially free" or "lacking", as defined above, one or more additional organic UV filters selected from the group consisting of Avobenzone (butyl methoxydibenzoylmethane), Octisalate (ethylhexyl salicylate), Ensulizole (phenylbenzimidazole sulfonic acid), Homosalate and Octocrylene, with preferably two or more, preferably three or more, preferably four or more, or preferably all five of these sunscreen agents.

[0087] According to preferred embodiments, the compositions of the present disclosure are “free”, “substantially free” or “lacking”, as defined above, one or more additional organic UV filters selected from the group consisting of OXYBENZONE (benzophenone-3), OCTINOXATE (ethylhexyl methoxycinnamate), ETHYLHEXYL TRIAZONE, DROMETRIZOLE TRISILOXANE, METHYLENE BIS-BENZOTRIAZOLYL TETRAMETHYLBUTYL PHENOL, HEXYL DIE-THYLAMINO HYDROXYBENZOYL BENZOATE, DIETHYLHEXYL BUTAMIDO TRIAZONE, ISOAMYL P-METHOXYCINNAMATE, POLY-SILICONE-15, 4-METHYLBENZYLIDENE CAMPHOR, PHENYL DIBENZL MIDAZOLE TETRASULFONATE DISODIUM, METHOXYPROPYLAMINO CYCLOHEXENYLIDENE ETHOXYETHYLCYA-NOACETATE, preferably two or more, preferably three or more, preferably four or more, etc., and preferably “free”, “substantially free” or “devoid” of all such sunscreen agents.

[0088] According to preferred embodiments, the compositions of the present disclosure are "free", "substantially free" or "lacking", as defined above, OXYBENZONE (benzophenone-3) and / or OCTINOXATE (ethylhexyl methoxy cinnamate).

[0089] If present in the compositions of the present disclosure, the at least one additional UV filter is preferably present in the compositions of the present disclosure in an amount of at least about 5% by weight, preferably at least about 10% by weight, preferably at least about 12% by weight, preferably at least about 14% by weight, and preferably at least about 15% by weight, with the upper end of the range of the additional UV filter present preferably being about 40% by weight (e.g., about 5-40%, about 10-40%, about 12-40%, etc.), preferably about 30% by weight (e.g., about 5-30%, about 10-30%, about 12-30%, etc.), preferably about 25% by weight (e.g., about 5-25%, about 10-25%, about 12-25%, etc.), and preferably about 20% by weight (e.g. about 5-20%, about 10-20%, about 12-20%, etc.), all weights being based on the total weight of the composition.

[0090] According to preferred embodiments, the compositions of the present disclosure comprise 10% or less by weight relative to the total weight of the composition of additional UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight relative to the total weight of the composition.

[0091] According to preferred embodiments, the compositions of the present disclosure comprise 10% or less by weight relative to the total weight of the composition of additional organic UV filters, preferably less than 5% by weight relative to the total weight of the composition, preferably less than 3% by weight relative to the total weight of the composition, and preferably less than 1% by weight relative to the total weight of the composition.

[0092] According to preferred embodiments, the UV absorbing system of the compositions of the present disclosure may "consist of" or "consist essentially of" bis-ethylhexyloxyphenol methoxyphenyl triazine.

[0093] According to preferred embodiments, the UV absorbing system of the compositions of the present disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) zinc oxides, titanium oxides and / or cerium oxides.

[0094] According to preferred embodiments, the UV absorbing system of the compositions of the present disclosure may "consist of" or "consist essentially of" (1) bis-ethylhexyloxyphenol methoxyphenyl triazine, and (2) additional organic UV filter(s).

[0095] According to preferred embodiments, the present disclosure contemplates omitting one or more of the specific UV filters discussed above from the UV absorbing system of the compositions of the present disclosure. For example, octocrylene and / or octinoxate may be omitted from the compositions. A similar omission of one or more of the specific UV filters discussed is thus contemplated. Oil

[0096] According to preferred embodiments of the present disclosure, compositions further comprising at least one oil are provided. "Oil" refers to a substance that is hydrophobic and lipophilic, and is a liquid at about room temperature (20-25°C) and about atmospheric pressure (760 mm Hg).

[0097] Suitable oils include volatile and / or non-volatile oils. These oils may be any acceptable oil, including, but not limited to, silicone oils and / or hydrocarbon oils.

[0098] According to certain embodiments, the compositions of the present disclosure preferably comprise one or more volatile silicone oils. Examples of such volatile silicone oils include linear or cyclic silicone oils having from 2 to 7 silicon atoms, these silicones being optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms. Specific oils that may be used in the disclosure include octamethyltetrasiloxane, deca-methylcyclopentasiloxane, dodecamethylcyclohexasiloxane, heptamethyloctyltrisiloxane, hexamethyldisiloxane, decamethyltetrasiloxane, dodecamethylpentasiloxane and mixtures thereof. Other volatile oils that may be used include KF 96A with a viscosity of 6 cSt, a commercial product from Shin Etsu having a flash point of 94°C. Preferably, volatile silicone oils have a flash point of at least 40°C.

[0099] Non-limiting examples of volatile silicone oils are listed in Table 1 below.

[0100] [Tableauxl] Compound Flash point (°C) Viscosity (cSt) Octyltrimethicone 93 1.2 Hexyltrimethicone 79 1.2 Decamethylcyclopentasiloxane 72 4.2 (cyclopentasiloxane or D5) 55 2.5 Octamethylcyclotetrasiloxane 93 7 (cyclotetramethylsiloxane or D4) 63 1.7 Dodecamethylcyclohexasiloxane (D6) 94 6 Decamethyltetrasiloxane (L4) 56 1.5 Shin Etsu KF-96 A PDMS (polydimethylsiloxane) DC 200 (1.5 cSt) Dow Corning PDMS DC 200 (2 cSt) Dow Corning 87 2

[0101] Further, a volatile linear silicone oil may be employed in the present disclosure. Suitable volatile linear silicone oils include those described in U.S. Patent No. 6,338,839 and WO03 / 042221, the contents of which are incorporated herein by reference. In one embodiment, the volatile linear silicone oil is decamethyltetrasiloxane. In another embodiment, the decamethyltetrasiloxane is further combined with another solvent more volatile than the decamethyltetrasiloxane.

[0102] According to certain embodiments of the present disclosure, the composition preferably comprises one or more non-silicone volatile oils and may be selected from volatile hydrocarbon oils, volatile esters and volatile ethers. Examples of such volatile non-silicone oils include, but are not limited to, volatile hydrocarbon oils having from 8 to 16 carbon atoms and mixtures thereof and in particular, C8-C16 branched alkanes such as C8-C16 isoalkanes (also known as isoparaffins), isohexadecane, isododecane, isodecane, and for example, oils sold under the trade names Isopar or Permethyl. Preferably, the volatile non-silicone oils have a flash point of at least 40°C.

[0103] Non-limiting examples of volatile non-silicone oils are given in Table 2 below.

[0104] [Tables2] Compound Flash point (°C) Isododecane 43 Propylene glycol N-butyl ether 60 Ethyl 3-ethoxypropionate 58 Propylene glycol methyl ether acetate 46 Isopar L (Cn-Cu isoparaffin) 62 Isopar H (Cn-Ci2 isoparaffin) 56

[0105] According to certain embodiments of the present disclosure, the composition comprises at least one non-volatile oil. Examples of non-volatile oils that may be used in the present disclosure include, but are not limited to, polar oils such as, for example:

[0106] - esters and ethers, in particular fatty acids, such as oils of formulas R1COOR2, in which RI represents the residue of a fatty acid having from 8 to 29 carbon atoms, and R2 represents a hydrocarbon chain, branched or not, containing from 3 to 30 carbon atoms, such as for example Purcellin oil, isononyl isononanoate, isopropyl myristate, 2-ethylhexyl palmitate, 2-octyldodecyl stearate, 2-octyldodecyl erucate, isostearyl isostearate; hydroxylated esters such as isostearyl lactate, octylhydroxystearate, octyldodecyl hydroxystearate, diisostearylmalate, triisocetyl citrate, heptanoates, octanoates, decanoates of fatty alcohol; polyol esters, such as propylene glycol dioctanoate, neopentyl glycol diheptanoate and diethylene glycol diiso-nonanoate;triglycerides such as caprylic / capric acid triglycerides, for example those sold by the company Stearineries Dubois or those sold under the names Miglyol 810, 812 and 818 by the company Dynamit Nobel; and pentaerythritol esters such as pentaerythrityl tetraisostearate or dipentaerythrityl pentaiso-nonanoate; ;

[0107] - ethers containing from 10 to 40 carbon atoms;

[0108] - liquid C8 to C26 fatty alcohols, for example oleyl alcohol, alcohol cetyl, stearyl alcohol and cetearyl alcohol;

[0109] - hydrocarbon oils of animal origin, such as perhydrosqualene;

[0110] - hydrocarbon oils of vegetable origin, such as liquid triglycerides of fatty acids having from 4 to 10 carbon atoms such as triglycerides of heptanoic or octanoic acids, for example, sunflower oil, corn oil, soybean oil, cucurbit oil, grape seed oil, sesame oil, hazelnut oil, apricot oil, macadamia oil, ara oil, sunflower oil, castor oil, avocado oil, triglycerides of caprylic / capric acids, such as those sold by the company Stéarineries Dubois or those sold under the names Miglyol 810, 812, and 818, by Dynamit Nobel Company, coco-caprylate / caprate (esterified oil of coconut oil), jojoba oil, shea butter oil; and [YES] - their s mixture s.

[0112] Further, examples of non-volatile oils that may be used in the present disclosure include, but are not limited to, non-polar oils such as branched and unbranched hydrocarbons, particularly Vaseline (petrolatum), paraffin oil, squalane, squalene, hydrogenated polyisobutene, hydrogenated polydecene, polybutene, mineral oil, pentahydro squalene, and mixtures thereof.

[0113] According to certain embodiments of the present disclosure, the compositions of the present disclosure comprise at least one non-volatile silicone oil. Suitable examples of such silicone oils include, but are not limited to, non-volatile silicone fluids such as, for example, polyalkyl (aryl) siloxanes. Suitable polyalkyl siloxanes include, but are not limited to, polydimethyl siloxanes, which have the CTFA designation dimethicone, polydiethyl siloxane, phenyl trimethicone, trimethyl pentaphenyl trisiloxane, phenyldimethicone, phenyltrimethylsi-loxydiphenylsiloxane, diphenyldimethicone and diphenylmethyldiphenyltrisiloxane, and the siloxanes disclosed in the U.S. patent application publication No. 2004 / 0126350, the full disclosure of which is incorporated herein by reference. Specific examples of suitable high viscosity silicone oils include, but are not limited to, Wacker's 15 M 30 PCR (500 cSt) or Wacker's Belsil PDM 1000 (1000 cSt) and Dow Corning 200 (350 cSt) (values ​​in parentheses represent viscosities at 25°C).

[0114] Particularly preferred oils include, but are not limited to, one or more of the following: diisopropyl sebacate, C12-15 alkyl benzoate, isopropyl lau-roylsarcosinate, dicaprylyl carbonate, dicaprylate / dicaprate, coco glycerides, caprylic / capric triglyceride, isopropyl myristate, isopropyl palmitate, coco caprylate / caprate, ethylhexyl palmitate, isononyl isononanoate, octyldodecanol, dicaprylyl ether, C15-19 alkane, diisopropyl adipate, dicaprylyl ether and mixtures thereof.

[0115] According to preferred embodiments, the compositions of the present disclosure comprise a bis-ethylhexyloxyphenol methoxyphenyl triazine solubilizing system comprising at least one solvent which is present in the system in an amount effective to solubilize the bis-ethylhexyloxyphenol methoxyphenyl triazine such that the composition is suitable for use as a composition containing effective amounts of bis-ethylhexyloxyphenol methoxyphenyl triazine and can be used as such. Preferably, the at least one solvent is selected among the oils mentioned in the previous paragraph.

[0116] According to preferred embodiments, the oil system of the compositions of the present disclosure may "consist of" or "consist essentially of" C12-15 alkyl benzoate and / or caprylic / capric triglyceride and / or dii-isopropyl sebacate and / or isopropyl palmitate.

[0117] According to preferred embodiments, C12-15 alkyl benzoate and / or caprylic / capric triglyceride and / or diisopropyl sebacate and / or isopropyl palmitate are present in compositions of the present disclosure in an amount, individually or collectively, of preferably at least 10% by weight, preferably at least 20% by weight, preferably at least 30% by weight, preferably at least 40% by weight, preferably at least 50% by weight (collectively), preferably at least 60% by weight (collectively) and preferably at least 70% by weight (collectively), all weights being relative to the total weight of the composition.

[0118] According to preferred embodiments, the compositions of the present disclosure may further optionally comprise at least one natural oil. The natural oil or oils are oils recovered or extracted from foods, and / or preferably oils recovered from plants or other plant life (as opposed to oils that are derived from natural sources by reactions and are not "natural oils" as used herein). For example, vegetable oils include glyceride triesters, which are generally triesters of fatty acids and glycerol, the fatty acids of which may have varying chain lengths from C4 to C24, wherein these chains may be saturated or unsaturated and linear or branched.

[0119] Non-limiting examples of suitable natural oil(s) include olive oil, sweet almond oil, coconut oil, avocado oil, wheat germ oil, sunflower oil, grape seed oil, sesame oil, corn oil, apricot oil, castor oil, shea oil, soybean oil, palm oil, rapeseed oil, cottonseed oil, hazelnut oil, macadamia oil, jojoba oil, alfalfa oil, poppy seed oil, pumpkin seed oil, cucurbitaceae oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, Rye oil, safflower oil, candlenut oil, passion fruit oil, rosehip oil, etc., including oils derived from the above-mentioned seeds and including mixtures thereof. Castor (seed) oil is particularly preferred.

[0120] Preferably, where appropriate, the at least one natural oil is present in an amount of from about 0.1% to about 20% by weight, preferably from 0.25% to about 15% by weight, preferably from about 0.5% to about 10% by weight, and preferably from about 1% to about 5% by weight, based on the total weight of the composition. position, including all intermediate ranges and sub-ranges.

[0121] According to preferred embodiments, the at least one oil is present in the compositions of the present disclosure in an amount ranging from about 10% to about 80% by weight, more preferably from about 25% to about 75% by weight, and most preferably from about 40% to about 70% by weight, based on the total weight of the composition, including all ranges and sub-ranges within these ranges such as, for example, 50% to 75%, 35% to 67%, etc.

[0122] According to preferred embodiments, the compositions of the present disclosure are anhydrous. Aqueous Phase

[0123] The compositions of the present disclosure may also optionally contain water. When the compositions of the present disclosure contain water, they are preferably in the form of an emulsion. Preferably, when the compositions of the present disclosure contain water, they are in the form of an emulsion containing an external aqueous phase such as an oil-in-water (O / W) emulsion or a water-in-oil-in-water (W / O / W) emulsion, or an emulsion containing an external oil phase such as a water-in-oil (W / O) emulsion or an oil-in-water-in-oil (O / W / O) emulsion. Preferably, when in the form of an emulsion, the oil phase may contain silicone oils (e.g., Si / W or W / Si emulsion) or hydrocarbon oils.Where present, water is preferably present in an amount of about 10% to about 80% by weight, preferably about 20% to about 70% by weight, preferably about 35% to about 65% by weight, including all intermediate ranges and sub-ranges, all weights being based on the total weight of the composition.

[0124] However, according to preferred embodiments, the compositions of the present disclosure are water-free, substantially water-free, or water-free as defined herein. Preferably, the compositions of the present disclosure are anhydrous.

[0125] If present in compositions of the present disclosure, the aqueous phase may comprise at least one water-soluble organic solvent that is liquid at room temperature and atmospheric pressure. For example, such at least one water-soluble organic solvent may include:

[0126] - triethyl citrate;

[0127] - C1-C5 monoalcohols having a C1-C5 alkane chain and a single function hydroxyl (OH). Suitable C1-C5 monohydric alcohols include methanol, ethanol, propanol, isopropanol, butanol, and mixtures thereof;

[0128] - polyols (compounds having 2 or more hydroxyl groups) having, for example, 2 with 20 carbon atoms, preferably from 2 to 6 carbon atoms, such as, for example, glycerol, diglycerol, propylene glycol, isoprene glycol, di-propylene glycol, butylene glycol, hexylene glycol, 1,3-propanediol, pentylene glycol, simple sugars and water-soluble polyalkylene glycols;

[0129] - and mixtures thereof.

[0130] According to preferred embodiments, the at least one water-soluble organic solvent is selected from the group consisting of ethanol, dipropylene glycol, butylene glycol, propanediol and propylene glycol, and mixtures thereof.

[0131] Where appropriate, the water-soluble organic solvent(s) is / are preferably present in the compositions of the present disclosure in a total amount ranging from 0.5% to about 40% by weight, preferably from about 3% to about 30% by weight, and most preferably from about 5% to about 20% by weight, based on the total weight of the composition, including all intermediate ranges and sub-ranges, such as 2% to 15%, 2% to 25%, 7.5% to 30%, etc. Additional optional ingredients

[0132] The compositions of the present disclosure may also optionally further include at least one additive or auxiliary commonly used in cosmetic compositions and known to those skilled in the art as being capable of being incorporated into such compositions.These additives or auxiliaries may be selected from sugar fatty acid ester gelling agents, lipophilic acrylate thickening agents, water-soluble gums, film formers, coloring agents (e.g., dyes and pigments), waxes, thixotropic agents (e.g., clays), fillers, preservatives, perfumes, surfactants, antioxidants, free radical scavengers, spreading agents, dispersing agents, antifoaming agents, neutralizing agents, stabilizing agents, active ingredients selected from essential oils, moisturizing agents, vitamins, actives, proteins, ceramides, plant extracts, fibers and the like, wetting agents, and mixtures thereof. However, preferably, the compositions of the present disclosure are "free," "substantially free," or "devoid" of such additives.

[0133] According to preferred embodiments, compositions optionally further comprising at least one sugar fatty acid ester gelling agent are provided. Any sugar-based compound esterified with at least one fatty acid may be used in accordance with the present disclosure.

[0134] Sugar-based compounds include, but are not limited to, compounds containing at least one glucose and / or fructose monomer, including sucrose. These compounds include not only sugar monomers (e.g., glucose and fructose), but also polymeric forms of such monomers such as, for example, dextrin and fructooligosaccharides.

[0135] Suitable fatty acids for the production of an esterified compound include, but are not limited to, acidic compounds containing at least C8 (8 carbon atoms) (e.g., octanoic acid). Preferably, suitable fatty acids for the esterification of sugar-based compounds contain from 8 to 32 carbon atoms, preferably from 10 to 26 carbon atoms, preferably from 12 to 22 carbon atoms, and preferably from 16 to 18 carbon atoms, including saturated and unsaturated, branched and unbranched fatty acids, such as, for example, octanoic acid, ethylhexylic acid, stearic acid, palmitic acid, oleic acid, palmitoleic acid, etc.

[0136] Suitable specific examples of fatty acid ester gelling agents suitable for use in accordance with the present disclosure include, but are not limited to, dextrin fatty acid esters such as dextrin palmitate, dextrin stearate, and dextrin 2-ethylhexanoate / palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; and fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate and fructooligosaccharide 2-ethylhexanoate.

[0137] According to preferred embodiments, the at least one sugar fatty acid ester gelling agent, if any, is present in the compositions of the present disclosure in an amount such as, for example, from about 0.1% to about 30% by weight based on the total weight of the composition, from about 1% to about 25% by weight, from about 5% to about 20% by weight, and from about 7.5% to about 17.5% by weight, including all intermediate ranges and sub-ranges such as, for example, from about 4.5% to about 10% by weight, and from about 12% to about 18% by weight, from about 11% to about 16% by weight, from about 5.5% to about 18% by weight, from about 7.7% to about 19% by weight, etc., all weights being based on the total weight of the composition. Lipophilic acrylate-based thickening agent

[0138] According to the present disclosure, compositions optionally further comprising at least one lipophilic acrylate-based thickening agent are provided. Preferably, if present, the at least one lipophilic acrylate-based thickening agent comprises a monomer containing a crystallizable chain selected from the group consisting of C8-C36 alkyl (meth)acrylates, preferably C10-C30 alkyl (meth)acrylates, and preferably C14-C22 alkyl (meth)acrylates, such as, for example, poly(stearyl acrylate) and poly(behenyl acrylate).

[0139] Suitable examples of lipophilic acrylate thickening agents include, but are not limited to, polymers having the INCI name "Poly C10-C30 alkyl acrylate", for example, Intelimer (TM) products from Air Products, for example, Intelimer H4. Other examples include Intelimer (TM) IPA 13-1 or the Intelimer (TM) IPA 13-6 product. More generally, at least one lipophilic acrylate-based thickening agent may be a polymer disclosed in US patent application 2007 / 0264204, the entire contents of which are incorporated herein by reference. A particularly preferred lipophilic acrylate-based thickening agent is C12-22 alkyl acrylate / hydroxyethyl acrylate copolymer.

[0140] According to preferred embodiments, the at least one lipophilic acrylate-based thickening agent, if any, is preferably present in the compositions of the present disclosure in an amount ranging from about 0.1% to about 10% by weight, preferably from about 0.25% to about 5% by weight, preferably from about 0.5% to about 4% by weight, and preferably from about 0.75% to about 3% by weight, all weights being based on the total weight of the composition, including all intermediate ranges and sub-ranges such as, for example, from 0.05, 0.06, 0.07, 0.08, 0.09, 1.0, 2.0, 3.0, 4.0 to 5.0 weight percent, including sub-ranges including any of these amounts. Water-soluble gum

[0141] According to preferred embodiments, the compositions of the present disclosure may further optionally comprise at least one water-soluble natural gum. Preferred water-soluble natural gums include, but are not limited to, guar, acacia (Senegal) gum, xanthan, gum arabic, tragacanth, locust bean gum, agar-agar, and mixtures thereof. Acacia (Senegal) gum is preferred.

[0142] Preferably, if present, the at least one water-soluble natural gum is present in an amount ranging from about 0.1% to about 20% by weight, preferably from about 0.5% to about 10% by weight, preferably from about 0.75% to about 7.5% by weight, and preferably from about 1% to about 5% by weight, based on the total weight of the composition, including all intermediate ranges and sub-ranges.

[0143] A person skilled in the art will take care to choose the optional additional additives and / or their quantity so that the advantageous properties of the composition according to the disclosure are not, or not substantially, compromised by the intended addition.

[0144] It goes without saying that the composition of the disclosure must be cosmetically or dermatologically acceptable, i.e. it must contain a non-toxic, physiologically acceptable carrier. The composition may be in any dosage form normally employed in the cosmetic and dermatological fields which is suitable for topical administration as discussed above.

[0145] These auxiliary additives may be present in the composition in a proportion of 0% to 99% (such as 0.01% to 90%) relative to the total weight of the composition and further such as 0.1% to 50% by weight (where applicable), including all intermediate ranges and sub-ranges.

[0146] In accordance with the present disclosure, the compositions of the present disclosure may be a stand-alone product (for use alone), or they may be a product for use in conjunction with another composition, for example, it may be a base coat composition (makeup base), a color coat composition or a top coat composition (overcoat). It is to be understood that when compositions of the present disclosure are applied to keratinous materials in the form of any of such compositions, such application may comprise one or more layers of the product.Thus, for example, the application of at least one color coat composition may comprise one or more color coats; the application of the at least one topcoat composition may comprise one or more topcoats; the application of the at least one basecoat composition may comprise one or more basecoats. Preferably, such basecoat, colorcoat, and topcoat compositions contain three or fewer layers of compositions, preferably two or fewer layers of compositions, and preferably a single layer of compositions.

[0147] During application of the compositions of the present disclosure, the base coat (if any) is typically applied directly to the keratinous material, the color coat is typically applied either directly to the keratinous material (if no base coat is present) or to a previously applied base coat, and the top coat (if any) is typically applied to a color coat.

[0148] According to preferred embodiments of the present disclosure, methods of treating, protecting, improving the appearance, caring for and / or making up a keratinous material by applying compositions of the present disclosure to the keratinous material in an amount sufficient to treat the keratinous material, improve its appearance, care for it and / or make it up, are provided.

[0149] Preferably, the "making up" of the keratinous material includes the application of a composition comprising the at least one coloring agent to the keratinous material in an amount sufficient to provide color and / or an optical effect to the keratinous material.

[0150] Preferably, "protecting" the keratinous material includes applying a composition of the present disclosure to protect the keratinous material from damage resulting from exposure to UV rays.

[0151] According to the preceding embodiments, the compositions of the present disclosure are applied topically to the keratinous material in an amount sufficient to treat the keratinous material, improve its appearance, care for it and / or or make it up. The compositions may be applied to the desired area as needed, preferably once or twice daily, more preferably once daily, and then preferably allowed to dry before subjecting them to contact such as with clothing or other objects (e.g., clothing or a topcoat). Preferably, the composition is allowed to dry for about 1 minute or less, more preferably for about 45 seconds or less.

[0152] According to preferred embodiments of the present disclosure, methods of making environmentally friendly compositions comprising the combination of bis-ethylhexyloxyphenol methoxyphenyl triazine and ingredient(s) that form an environmentally friendly carrier during formation of the compositions are provided. Preferably, the compositions contain minimal amounts of animal-derived ingredients and / or microplastics, or are free of such ingredients.

[0153] The present disclosure also contemplates pre-packaged kits and / or materials suitable for consumer use containing one or more compositions according to the present disclosure, alone or in combination with makeup products such as base coats, top coats, makeup remover compositions, etc. The packaging and application device for any subject of the disclosure may be chosen and manufactured by persons skilled in the art on the basis of their general knowledge, and adapted according to the nature of the composition to be packaged. Indeed, the type of device to be used may be in particular linked to the consistency of the composition, in particular to its viscosity; it may also depend on the nature of the constituents present in the composition, for example the presence of volatile compounds.

[0154] Unless otherwise indicated, all numbers expressing amounts of ingredients, reaction conditions, and so forth used in the patent specification and claims are to be understood as being modified in all instances by the term "about." Accordingly, unless otherwise indicated, the numerical parameters set forth in the following patent specification and appended claims are approximations which may vary depending on the desired properties sought to be achieved by the present disclosure.

[0155] Although the numerical ranges and parameters defining the general scope of the disclosure are approximations, the numerical values ​​indicated in the specific examples are reported as accurately as possible. However, any numerical value inherently contains certain errors necessarily resulting from the standard deviation found in their respective measurements. The following examples are intended to illustrate the disclosure without limiting its scope. Percentages are given on a weight basis. Example 1

[0156] [Tables3] ENVIRONMENTALLY FRIENDLY LOTION EPS 50 ISOPROPYL MYRISTATE 7.00 TOCOPHEROL 0.10 ALCOHOL DENAT. 5.00 WATER QS XANTHAN GUM 0.20 AVOBENZONE 3.00 SODIUM HYALURONATE 0.02 GLYCERIN 3.00 OCTISALATE 5.00 CROSSLINKED POLYMER ACRYLATES / C10-30 ALKYL ACRYLATE 0.20 TRIETHANOL AMINE QS C12-15 ALKYL BENZOATE 5.00 CAPRYLYL GLYCOL 0.50 CAPRYLIC / CAPRIC TRIGLYCERIDE 4.00 DIISOPROPYL SEBACATE 3.00 ACRYLATES COPOLYMER 2.00 BEMOTRIZINOL 6.00 PROPANEDIOL 3.00 TRISODIUM ETHYLENEDIAMINE DL SUCCINATE 0.31 STARCH ACETATE OXIDE 1.00 COPERNICIA CERIFERA (CARNAUBA) WAX 1.00 C12-22 ALKYL ACRYLATE / HYDROXYETHYLACRYLATE COPOLYMER 1.00 Example 2

[0157] [Tables4] ECO-FRIENDLY OIL SPF30 TOCOPHEROL 0.25 ISOPROPYL PALMITATE QS PARFUM 0.50 ALCOHOL DENAT. 8.00 OCTISALATE 22.00 AVOBENZONE 4.50 DIISOPROPYL SEBACATE 8.00 ETHYLENEDIAMINE / STEARYL DIMER DILINOLEATE COPOLYMER 1.50 BEMOTRIZINOL 5.00 DICAPRYLYL CARBONATE 2.00 C12-15 ALKYL BENZOATE 2.00 SQUALANE 1.00 HOMOSALATE 10.00

Claims

Claims

1. Composition comprising bemotrizinol and an environmentally friendly carrier.

2. Composition according to claim 1, wherein the composition has: - a critical wavelength of at least 370 nm; and / or - an FPUVA / SPF ratio of at least 1 / 3; and / or - a UVA1 / UV ratio of 0.7 or more.

3. A composition according to any preceding claim, wherein the composition also has an SPF value of at least 30.

4. A composition according to any preceding claim, wherein the composition is free from mineral UV filters and / or microplastics.

5. A composition according to any preceding claim, wherein the environmentally friendly carrier comprises an oil system comprising C12-15 alkyl benzoate, caprylic / capric triglyceride, diisopropyl sebacate, isopropyl palmitate or a mixture thereof.

6. A composition according to any preceding claim, wherein the C12-15 alkyl benzoate and / or caprylic / capric triglyceride and / or diisopropyl sebacate, and / or isopropyl palmitate are present in an amount ranging from about 25% to about 75% by weight relative to the total weight of the composition.

7. Composition according to any one of the preceding claims, further comprising at least one passivated mineral UV filter.

8. A composition according to any preceding claim, wherein the composition is free of oxybenzone and / or octinoxate.

9. A composition according to any preceding claim, wherein the composition is anhydrous.

10. Composition according to any one of the preceding claims, further comprising at least one coloring agent and / or at least one active agent.