Separation of rare earth elements using supported membrane solvent extraction

HK40073202BActive Publication Date: 2026-07-17UT BATTELLE LLC

Patent Information

Authority / Receiving Office
HK · HK
Patent Type
Patents
Current Assignee / Owner
UT BATTELLE LLC
Filing Date
2022-10-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are difficult to efficiently separate and recover rare earth elements from waste permanent magnets, especially the light rare earth elements Nd and Pr from the heavy rare earth element Dy. Furthermore, traditional methods suffer from problems such as the use of numerous chemicals, environmental pollution, and high energy consumption.

Method used

A loaded membrane solvent extraction method is adopted, which utilizes hollow fiber membrane modules and phosphorus-based chelating extractant Cyanex 572. By flowing aqueous feed solution and stripping solution inside and outside the hollow fiber, the selective extraction and separation of rare earth elements are achieved, avoiding equilibrium limitation and emulsion formation.

Benefits of technology

It achieves high-purity separation and recovery of rare earth elements, especially Dy, with a purity of over 99.5%, reducing chemical usage and energy consumption, minimizing environmental pollution, and is suitable for the treatment of highly polluting waste.

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Abstract

Systems and methods for the recovery and separation of rare earth elements (REEs) are provided. The systems and methods include REE-supported membrane solvent extraction and the separation of light and heavy REEs recovered from waste permanent magnets and other electronic waste. In the supported membrane solvent extraction, an organic phase consisting of an extractant and an organic solvent is immobilized within the pores of a hollow fiber. An aqueous feed solution and a stripping solution flow along the shell side and lumen side of the hollow fiber, respectively. The extractant acts as a carrier to selectively transport certain rare earth metal ions from the feed side to the stripping side. The rare earth metals are simultaneously back-extracted into the stripping solution, allowing the process to proceed continuously without equilibrium limitations.
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