Improvements in or relating to organic compounds

Abstract

Disclosed is an encapsulation composition comprising at least one core-shell microcapsule. The at least one core-shell microcapsule comprises a core containing at least one perfume ingredient and a shell surrounding the core. The shell comprises a thermosetting resin formed by reaction of a polyfunctional amine containing at least one amino group with at least one polyfunctional isocyanate. The shell further comprises a cationic polymer comprising a quaternary ammonium group. The shell further comprises a polymeric stabilizer comprising fully or partially dissociated carboxylic acid groups. The nominal molar ratio of amino groups and quaternary ammonium groups to carboxylic acid groups is 0.9 to 1.1, preferably 0.95 to 1.08, more preferably 1.00 to 1.06.

Description

[Technical field]

[0001] The present invention relates to an encapsulation composition comprising at least one core-shell microcapsule. The invention also relates to a method for obtaining the encapsulation composition, as well as to the use of such an encapsulation composition for obtaining a consumer product. [Background technology]

[0002] The demand for encapsulated perfume continues to grow across all categories of consumer products, including personal care, household care, and specifically laundry care products. As a result, formulators are being challenged to incorporate perfume-containing microcapsules into ever more diverse product types and in ever more challenging (e.g., aggressive or extractive) media.

[0003] This growing customer demand reflects the increasing importance of scent to consumers of personal care, household care and fabric care products: scent provides olfactory cues that convey a sense of freshness and cleanliness to consumers, thus strengthening their confidence in the efficacy of such products.

[0004] There are many points at which consumers may interact with a consumer product before, during, and after a cleaning or treatment experience. As an example, in the case of a laundry product, interaction points during the cleaning experience may encompass the freshness experience a consumer receives when opening a container of a fabric care product; or when opening a washer or dryer after washing or drying; or the freshness experience associated with ironing, folding, or handling freshly washed clothes or linens. If a laundry product can delight consumers at these interaction moments, it can transform a tedious household chore into a more pleasant experience, fostering brand loyalty and creating moments of delight that encourage repurchases of the product.

[0005] Microencapsulation technology offers the possibility to control the spatiotemporal release of fragrance during the cleansing or treatment experience, thus helping to create the aforementioned consumer benefits.

[0006] A wide variety of encapsulation vehicles and perfume ingredients suitable for the preparation of encapsulated perfume compositions have been proposed in the art. Encapsulation vehicles proposed in the art include synthetic resins made from polyamides, polyureas, polyurethanes, polyacrylates, melamine-derived resins, or mixtures thereof; or naturally occurring polymers such as gelatin or polysaccharides.

[0007] For suitable core materials, in principle, all perfume ingredients on the perfumer's palette can be incorporated to some degree into core-shell microcapsules. However, it is generally accepted that certain physicochemical characteristics of a perfume ingredient, most notably its clog P, affect whether and to what extent it can be encapsulated, and, when encapsulated, its tendency to remain in the core without substantial leakage during storage. In the hands of a skilled formulator, careful selection of both shell and core materials can result in microencapsulated perfumes that are stable in many consumer products and can modulate the release of fragrance over time.

[0008] However, even when using a combination of relatively stable shell chemistry and well-designed perfume formulations in the core, formulators face the problem of colloidal stability of the microcapsules in various target products, especially those with different pH. Colloidally unstable microcapsules tend to aggregate and eventually phase separate from the products in which they are dispersed. Furthermore, colloidal instability can lead to undesirable changes in flow properties such as viscosity of the product.

[0009] WO 2019 / 121736 A1 discloses core-shell microcapsules comprising a polymeric stabilizer combining a polymeric surfactant and an aminosilane, and various shell-forming materials selected from the group consisting of monomers, prepolymers and precondensates. Although these microcapsules offer desirable properties in terms of stability with respect to fragrance leakage and fragrance release, they may suffer from colloidal instability, such as aggregation, in consumer products containing ionic surfactants.

[0010] As a result, there remains a need for improved encapsulation technologies that are colloidally stable in a variety of products over a wide pH range, yet perform on treated surfaces such as fabrics and keratinous surfaces. Summary of the Invention

[0011] These problems are solved by the subject matter of the independent claims. In a first aspect, the present invention provides an encapsulation composition comprising at least one core-shell microcapsule. The at least one core-shell microcapsule comprises a core containing at least one perfume ingredient and a shell surrounding the core. The shell comprises a thermosetting resin formed by reaction of a polyfunctional amine containing at least one amino group with at least one polyfunctional isocyanate. The shell further comprises a cationic polymer containing a quaternary ammonium group, and a polymeric stabilizer containing fully or partially dissociated carboxylic acid groups. The nominal molar ratio of amino groups and quaternary ammonium groups to carboxylic acid groups is 0.8 to 1.1, preferably 0.9 to 1.08, more preferably 1.00 to 1.06.

[0012] "Nominal molar ratio" means a molar ratio calculated based on the total amount of materials involved in the system. In the context of the present invention, the nominal molar ratio of amino groups and quaternary ammonium groups to carboxylic acid groups is calculated based on the total amount of amino groups, quaternary ammonium groups and carboxylic acid groups present in the system.

[0013] In particular, the above molar ratios are calculated by calculating the total number of amino equivalents present in the composition, including primary, secondary, tertiary and quaternary amines, and the total number of carboxyl equivalents. For polyethyleneimines (see below), the calculation can be simplified by taking into account the average number of ethyleneimines involved per polyethyleneimine chain, i.e., by dividing the average molecular weight of the polymer by the molecular weight of the ethyleneimine.

[0014] In addressing the problems of the prior art, the Applicant has discovered that microcapsules having an optimal balance between amino and quaternary ammonium groups on the one hand, and fully or partially dissociated carboxylic acid groups on the other hand, do not exhibit aggregation or phase separation, and also exhibit optimal colloidal stability in a wide range of compositions, especially products with a wide range of surfactant and pH conditions.

[0015] Furthermore, the Applicant has found that if this ratio is less than 0.8, the microcapsules have a tendency to form aggregates in the presence of cationic surfactants over a wide range of pH, whereas if this ratio is greater than 1.1, the microcapsules have a tendency to form aggregates in the presence of anionic surfactants over a wide range of pH.

[0016] Furthermore, the applicant has surprisingly found that when the molar ratio of amino groups and quaternary ammonium groups to carboxylic acid groups is below 0.8, the volume-median diameter of the microcapsules increases dramatically and is no longer suitable for the purposes of the present invention.

[0017] The at least one polyfunctional isocyanate may be selected from organic isocyanates in which the isocyanate groups are bound to organic residues (RN=C=O or R-NCO). In the context of the present invention, a polyisocyanate (or polyfunctional isocyanate) is an organic isocyanate having two or more (e.g. 3, 4, 5, etc.) isocyanate groups in the molecule. Suitable polyisocyanates are illustratively aromatic, arylaliphatic, cycloaliphatic or aliphatic.

[0018] An anionically modified polyisocyanate contains at least two isocyanate groups and at least one functional group that is anionic or anionogenic. An "anionogenic functional group" is a group that can become anionic depending on the chemical environment, for example pH. Suitable anionic or anionogenic groups are, for example, carboxylic acid groups, sulfonic acid groups, phosphonic acid groups and salts thereof.

[0019] In the context of the present invention, the anionically modified polyisocyanate (hereinafter referred to as "anionically modified polyisocyanate (A)") may contain one or more sulfonic acid groups or salts thereof. Suitable salts may be sodium, potassium or ammonium salts. Ammonium salts are preferred.

[0020] Preferably, the anionically modified polyisocyanate (A) is obtained by reaction of a polyisocyanate with 2-(cyclohexylamino)-ethanesulfonic acid and / or 3-(cyclohexylamino)-propanesulfonic acid.

[0021] More preferably, the anionically modified polyisocyanate (A) is obtained by reaction of a polyisocyanate with 2-(cyclohexylamino)-ethanesulfonic acid and / or 3-(cyclohexylamino)-propanesulfonic acid, wherein the polyisocyanate is selected from hexamethylene diisocyanate, tetramethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, 2,4- and 2,6-toluylene diisocyanate and isomeric mixtures thereof, diphenylmethane diisocyanate, biurets, allophanates and / or isocyanurates of said polyisocyanates.

[0022] The anionically modified polyisocyanate (A) can be chosen in each case from anionically modified hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, isocyanurate of hexamethylene diisocyanate and mixtures thereof.

[0023] Preferably, the anionically modified polyisocyanate (A) has: an average isocyanate functionality of at least 1.8, - content of isocyanate groups (calculated as NCO; molecular weight = 42) from 4.0 to 26.0% by weight, - a content of sulfonate groups (calculated as SO3; molecular weight = 80) between 0.1 and 7.7% by weight, and optionally, a content of ethylene oxide units (calculated as C2H2O; molecular weight = 44) bound in the polyether chain of 0 to 19.5% by weight, where the polyether chain contains, on statistical average, 5 to 55 ethylene oxide units.

[0024] In particular, the anionically modified polyisocyanate (A) can be chosen from anionically modified hexamethylene diisocyanate, anionically modified hexamethylene diisocyanate, anionically modified isocyanurate of hexamethylene diisocyanate and mixtures thereof.

[0025] In a particularly preferred embodiment, the anionically modified polyisocyanate (A) may conform to formula I: [ka] Formula I represents a commercially available anionically modified polyisocyanate that is a modified isocyanurate of hexamethylene diisocyanate, sold under the trademark Bayhydur® XP2547 by Covestro.

[0026] In a particular embodiment of the present invention, a non-ionic polyisocyanate, referred to herein as "polyisocyanate (B)", can be used. Nonionic polyisocyanates (B) are 1,6-diisocyanatohexane, 1,5-diisocyanato-2-methylpentane, 1,5-diisocyanato-3-methylpentane, 1,4-diisocyanato-2,3-dimethylbutane, 2-ethyl-1,4-diisocyanatobutane, 1,5-diisocyanatopentane, 1,4-diisocyanatobutane, 1,3-diisocyanatopropane, 1,10-diisocyanato It may be selected from the group consisting of isocyanatodecane, 1,2-diisocyanatocyclobutane, bis(4-isocyanatocyclohexyl)methane, 3,3,5-trimethyl-5-isocyanatomethyl-1-isocyanatocyclohexane, isophorone diisocyanate (IPDI), hexamethylene 1,6 diisocyanate (HDI), and hydrogenated 4,4 diphenylmethane diisocyanate (HMDI).

[0027] The polyisocyanate (B) can also be a non-ionic oligomer based on the abovementioned isocyanate monomers, such as homopolymers, such as 1,6-diisocyanatohexane. All these monomers and oligomers are sold under the trade name Desmodur by Covestro AG.

[0028] Preferably, the non-ionic polyisocyanate (B) is chosen from hexamethylene diisocyanate, tetramethylene diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, 2,4- and 2,6-toluylene diisocyanate and their isomeric mixtures, 2,4'- and 4,4'-diphenylmethane diisocyanate and their isomeric mixtures, xylylene diisocyanate (for example Desmodur quix 175 sold by Covestro), optionally trimethylolpropane (TMP) adducts (for example commercially available under the trademark Takenate D-110N), biurets, allophanates and / or isocyanurates of the aforementioned polyisocyanates or mixtures thereof.

[0029] A preferred commercially available non-ionic polyisocyanate (B) is dicyclohexylmethane diisocyanate, sold especially under the trademark Desmodur W1 by Covestro AG. A preferred commercially available non-ionic polyisocyanate (B) is hexamethylene diisocyanate, especially that sold under the trademark Desmodur N3200 by Covestro AG. A preferred commercially available non-ionic polyisocyanate (B) is isophorone diisocyanate, sold inter alia under the trademark Desmodur Z by Covestro AG.

[0030] These polyisocyanates have the advantage of being non-aromatic and therefore more sustainable, and less susceptible to oxidation, while being highly reactive with polyamines and having a molecular structure suitable for forming impermeable encapsulating resins.

[0031] In the context of the present invention, the at least one polyfunctional isocyanate may comprise, preferably consist of, an anionically modified polyisocyanate (A) and a nonionic polyisocyanate (B).

[0032] In a preferred embodiment of the present invention, the at least one polyfunctional isocyanate comprises, preferably consists of, an anionically modified polyisocyanate (A) selected from anionically modified hexamethylene diisocyanate, anionically modified isophorone diisocyanate, anionically modified dicyclohexylmethane-4,-4'-diisocyanate, anionically modified isocyanurates of hexamethylene diisocyanate and mixtures thereof, and a non-ionic polyisocyanate (B) selected from hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, anionically modified isocyanurates of hexamethylene diisocyanate and mixtures thereof.

[0033] The weight ratio of the anionic modified polyisocyanate (A) to the nonionic polyisocyanate (B) can be in the range of 0.05 to 0.5, preferably 0.07 to 0.25. These weight ratios provide the resin with the highest impermeability and are therefore most suitable for encapsulation.

[0034] In the context of the present invention, the term "polyfunctional amine containing at least one amino group" refers to an amine containing at least two groups capable of reacting with NCO groups, where at least one group capable of reacting with NCO groups is a primary or secondary amino group. If the polyfunctional amine contains only one primary or secondary amino group, it will contain one or more additional functional groups capable of reacting with NCO groups in a polymerization reaction. The groups of the polyfunctional amine reactive towards NCO groups are preferably selected from hydroxyl groups and primary or secondary amino groups. The reaction of NCO groups with amino groups results in the formation of urea groups. The reaction of NCO groups with OH groups results in the formation of urethane groups. However, the reaction with OH groups often requires a catalyst. The amount of polyfunctional amine introduced is usually in molar excess with respect to the stoichiometric amount required to convert free isocyanate groups.

[0035] The multifunctional amines can be selected from diamines, triamines, tetramines, and higher multifunctional amines, aminoalcohols, melamines, ureas, hydrazines, polymeric polyamines, and mixtures thereof. Suitable diamines are, for example, 1,2-ethylenediamine, 1,3-propylenediamine, 1,4-diaminobutane, 1,5-diaminopentane, 1,6-diaminohexane, 1,3-diamino-1-methylpropane, 1,4-diaminocyclohexane, piperazine or mixtures thereof.

[0036] Suitable amino alcohols are, for example, 2-aminoethanol, 2-(N-methylamino)ethanol, 3-aminopropanol, 4-aminobutanol, 1-ethylaminobutan-2-ol, 2-amino-2-methyl-1-propanol, 4-methyl-4-aminopentan-2-ol or mixtures thereof.

[0037] Suitable polymeric polyamines are in principle linear or branched polymers having at least two primary or secondary amino groups. In addition, these polymers can have tertiary amino groups in the polymer chain.

[0038] The polymeric polyamine is preferably selected from polyalkyleneamines, polyvinylamines, polyetheramines and mixtures thereof. More preferably, the polymeric polyamine is selected from polyalkyleneimines, especially polyethyleneimines.

[0039] Preferably, the polymeric polyamine has a weight average molecular weight of at least 300 g / mol, more preferably 500 to 2,000,000 g / mol, particularly preferably 700 to 1,000,000 g / mol, and even more particularly preferably 800 to 500,000 g / mol.

[0040] In a preferred embodiment, the polyfunctional amine comprises, and preferably consists of, at least one polyethyleneimine. Polyethyleneimine has the general formula H2N(CH2CH2NH) n H, where n is an integer >1 (n=2: diethylenetriamine; n=3: triethylenetetramine; n=4: tetraethylenepentamine). These are sometimes also called polyethyleneamines or polyalkylenepolyamines. The polyethyleneimines may also be long chain polyethyleneimines.

[0041] In the process according to the invention, polyethyleneimines are preferably used which have a molecular weight of at least 500 g / mol, preferably 600-30 000 or 650-25 000 g / mol, and in particular 700-10 000 g / mol or 850-5 000 g / mol.

[0042] The polyfunctional amine can be a polyethyleneimine containing the following repeating units: [ka] During the ceremony, x is 8 to 1500, preferably 10 to 1000; y is 0 to 10, preferably 0 to 5, in particular 0; z is 2+y. With these polyethyleneimines good results can be achieved, especially with regard to leakage of the extraction medium. A preferred polyethyleneimine is a linear polyethyleneimine, in which x is 8 to 1500, y is 0, and z is 2.

[0043] A preferred commercially available polyethyleneimine is sold by BASF SE under the trademark Lupasol, particularly Lupasol G100. Preferably, the weight ratio of polyfunctional amine to polyfunctional isocyanate is between 0.05 and 1, preferably between 0.1 and 0.5, and even more preferably between 0.15 and 0.25. These weight ratios provide the resin with high encapsulation efficiency.

[0044] The shell of at least one microcapsule additionally comprises a polymeric stabilizer containing fully or partially dissociated carboxylic acid groups, which may be formed by a combination of a polymeric emulsifier containing carboxylic acid groups and at least one aminosilane.

[0045] The polymeric stabilizers of the present invention stabilize the dispersed oil droplets by ensuring that the droplets do not coalesce and remain well suspended in the dispersion medium. Thus, the polymeric stabilizers help create a stable and versatile platform on which different shell-forming chemicals can be attached to the perfume oil droplets to form novel core-shell microcapsules.

[0046] Particularly suitable polymeric surfactants for the purpose of the present invention include copolymers that are the reaction product of maleic anhydride and olefinic monomers such as ethylene, isobutylene or styrene. Examples of such copolymers include poly(ethylene-co-maleic anhydride), poly(isobutylene-co-maleic anhydride) and poly(styrene-co-maleic anhydride). Particularly preferred copolymers are poly(ethylene-co-maleic anhydride), a commercial grade of which is available under the trade name ZeMac E400. Maleic anhydride copolymers may be used alone or alternatively a combination of maleic anhydride copolymers may be used.

[0047] The maleic anhydride copolymers may be used in the present invention in their hydrolyzed form, where the anhydride may be in the form of its free acid, or its salt, or mixtures thereof.

[0048] When using maleic anhydride copolymers, it is especially preferred to pre-hydrolyze them before use in the emulsification process. Hydrolysis can be achieved by dissolving maleic anhydride in an aqueous medium, optionally at elevated temperature, for example about 85-90°C, for a suitable time interval. Typically, 2 hours is a suitable time interval to effect hydrolysis. When the polymer dissolves under these conditions, the pH of the solution typically falls below 3, which can indicate that hydrolysis has occurred. Furthermore, infrared spectroscopy revealed the disappearance of typical absorption bands corresponding to anhydride groups.

[0049] As defined above, the hydrolyzed form of the maleic anhydride copolymer can be presented as the free acid, or as a salt form, or as a mixture of the free acid and the salt. The relative amounts of free acid and salt depend on the pH of the aqueous medium. More specifically, the maleic anhydride copolymer is employed in aqueous solutions at a pH of about 2 to about 7, more specifically about 4 to about 5, where the maleic anhydride copolymer exhibits optimal emulsifier properties.

[0050] The hydrolyzed form of the maleic anhydride copolymer may be presented as a mixture of its free acid and salt forms with monovalent counterions, such as lithium, sodium, potassium or ammonium counterions. Alternatively, the polymeric surfactant may be selected from polysaccharides having carboxyl groups, including polysaccharides containing uronic acid units, especially hexuronic acid units. Polysaccharides having uronic acid units, especially hexuronic acid units, are widely available in nature.

[0051] The hexuronic acid unit may be selected from the group consisting of a galacturonic acid unit, a glucuronic acid unit, in particular a 4-O-methyl-glucuronic acid unit, a guluronic acid unit and a mannuronic acid unit.

[0052] In a specific embodiment of the invention, the shell comprises a polymeric stabilizer formed by a combination of a polymeric surfactant and at least one aminosilane, preferably by a combination of 3-aminopropyltriethoxysilane and at least one of poly(ethylene-co-maleic anhydride) and poly(styrene-co-maleic anhydride).

[0053] In a further embodiment of the invention, the polymeric surfactant is selected from the group consisting of poly(acrylic acid) and its copolymers, poly(methacrylic acid) and its copolymers, hydrolyzed or partially hydrolyzed poly(maleic acid) and its copolymers, pectin, acacia gum, carboxymethylcellulose, alginate, hyaluronic acid, xanthan gum, gellan gum, and salts thereof with monovalent alkali metals.

[0054] The silanes employed in the preparation of the polymer stabilizer are represented by the formula II [ka] wherein R1, R2 and R3 are independently a C1-C4 linear or branched alkyl or alkene, particularly methyl or ethyl, and R4 is a C1-C 12 Preferably, the functional group is a C1-C4 linear or branched alkyl or alkene. Particularly preferred are aminosilanes. Thus, the functional group can be an amine, in particular a primary, secondary or tertiary amine.

[0055] When the functional group is a primary amine, it can be a terminal primary amine. R4 is preferably a linear terminal primary aminoalkyl residue of C1-C8, even more preferably C1-C4. Particular aminosilanes in this category are selected from the group consisting of aminomethyltriethoxysilane, 2-aminoethyltriethoxysilane, 3-aminopropyltriethoxysilane, 4-aminobutyltriethoxysilane, 5-aminopentyltriethoxysilane, 6-aminohexyltriethoxysilane, 7-aminobutyltriethoxysilane and 8-aminooctyltriethoxysilane, most preferably 3-aminopropyltriethoxysilane.

[0056] The aminosilane and polymeric surfactant combined to form the polymeric stabilizer may be combined in widely varying amounts, however, it is preferred that the weight ratio of the aminosilane to the polymeric surfactant, particularly the maleic anhydride copolymer, is from 1 to 20, preferably from 1.5 to 10, and even more preferably from 2.5 to 3.5.

[0057] The aminosilane may also be a bipodal aminosilane. By "bipodal aminosilane" is meant a molecule that contains at least one amino group and two residues, each of which has at least one alkoxysilane moiety.

[0058] In a specific embodiment of the present invention, at least one bimodal aminosilane has formula III. [ka]

[0059] In the above formula III, X is -NR 1 -, -NR 1 -CH2-NR 1 -, -NR 1 -CH2-CH2-NR 1 -, -NR 1 -CO-NR 1 -,or [ka] Represents.

[0060] In the above formula III, R 1 R each independently represents H, CH3 or C2H5. 2 R each independently represents a linear or branched alkylene group having 1 to 6 carbon atoms. 3 R each independently represents a linear or branched alkyl group having 1 to 4 carbon atoms. 4 each independently represents H or a linear or branched alkyl group having 1 to 4 carbon atoms. f represents 0, 1 or 2.

[0061] Bimodal aminosilanes are particularly advantageous in forming stable oil-water interfaces compared to conventional silanes. Examples of bimodal aminosilanes include, but are not limited to, bis(3-(triethoxysilyl)propyl)amine, N,N'-bis(3-(trimethoxysilyl)propyl)urea, bis(3-(methyldiethoxysilyl)propyl)amine, N,N'-bis(3-(trimethoxysilyl)propyl)ethane-1,2-diamine, bis(3-(methyldimethoxysilyl)propyl)-N-methylamine, and N,N'-bis(3-(triethoxysilyl)propyl)piperazine.

[0062] The bimodal aminosilane can be a secondary aminosilane. The use of a secondary bimodal aminosilane instead of a primary aminosilane reduces the reactivity of the polymeric stabilizer to electrophilic species, especially aldehydes. Thus, benefit agents that contain high levels of aldehydes can be encapsulated with less tendency for adverse interactions between the core-forming material and the shell-forming material.

[0063] The secondary aminosilane can be bis(3-(triethoxysilyl)propyl)amine. This particular secondary aminosilane has the advantage that upon polycondensation of the ethoxysilane groups, it releases ethanol instead of the more toxic and less preferred methanol.

[0064] In a specific embodiment of the invention, the polymeric stabilizer is formed by combining a polymeric surfactant containing carboxylic acid groups with at least one aminosilane, preferably by combining 3-aminopropyltriethoxysilane with at least one of poly(ethylene-co-maleic anhydride) and poly(styrene-co-maleic anhydride).

[0065] The weight ratio of the polymer stabilizer to the thermosetting resin is preferably 0.4 to 0.9, and even more preferably 0.45 to 0.75. The shell of the microcapsule additionally comprises a cationic polymer that contains quaternary ammonium groups.

[0066] The cationic polymer may be derived from at least one monomer having quaternary ammonium functionality. In particular, the cationic monomer may be selected from the group consisting of quaternized dimethylaminoethyl acrylate (ADAME), quaternized dimethylaminoethyl methacrylate (MADAME), dimethyldiallylammonium chloride (DADMAC), acrylamidopropyltrimethylammonium chloride (APTAC) and methacrylamidopropyltrimethylammonium chloride (MAPTAC).

[0067] The cationic polymers may additionally be derived from water-soluble vinyl monomers, more particularly non-ionic monomers selected from the group consisting of acrylamide, methacrylamide, N-isopropylacrylamide, N,N-dimethylacrylamide, N-methylol acrylamide, N-vinylformamide, N-vinylacetamide, N-vinylpyridine and / or N-vinylpyrrolidone.

[0068] The applicant has found that the quaternary ammonium groups are preferably provided by a cationic polymer, more preferably by a cationic copolymer, and even more preferably by a cationic block copolymer that includes a non-cationic comonomer. Without being bound by theory, the applicant believes that the cationic polymer has the advantage that (i) it extends in the aqueous cleaning or rinsing solution, and (ii) it maximizes the number of contacts with the substrate, thereby ensuring better deposition and persistence of the microcapsules on the substrate. Furthermore, the cationic copolymer that includes a non-cationic comonomer has the advantage that it is more flexible than a cationic homopolymer, and is therefore suitable for maximizing the interactions between the polymer and the microcapsules and between the polymer and the substrate.

[0069] In a preferred embodiment, the cationic polymer is a block copolymer comprising a quaternary ammonium group and at least one comonomer that is not cationic. Block copolymers in which both types of monomers are arranged in distinct sequences are expected to provide an optimal balance between chain extension in aqueous media and anchoring onto a substrate.

[0070] In a specific embodiment of the invention, the cationic polymer is selected from the group consisting of polyquaternium-2 (poly(bis[2-chloroethyl]ether-alt-1,3-bis[3-(dimethylamino)propyl]urea) copolymer), polyquaternium-4 (hydroxyethylcellulose dimethyldiallylammonium chloride copolymer), polyquaternium-5 (poly(acrylamide-b-methacrylyloxyethyltrimethylammonium methosulfate) copolymer), polyquaternium-6 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-7 (poly(acrylamide-co-diallyldimethyl-ammonium chloride) copolymer), polyquaternium-9 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-10 (hydroxyethylcellulose dimethyldiallylammonium chloride copolymer), polyquaternium-11 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-12 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-13 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-14 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-15 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-16 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-17 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-18 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-19 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-20 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-21 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), polyquaternium-22 (poly(meth cellulose-2-hydroxyethyltrimethylammonium chloride copolymer), polyquaternium-11 (poly(vinylpyrrolidone-co-dimethylaminoethyl methacrylate) copolymer), polyquaternium-12 (poly(ethyl methacrylate-co-abietyl methacrylate-co-methacrylyloxyethyltrimethylammonium dimethyl sulfate) terpolymer), polyquaternium-13 (poly(ethyl methacrylate-co-oleyl methacrylate-co-methacrylyloxyethyltrimethylammonium dimethyl sulfate) terpolymer), polyquaternium-14 (poly(methacryloyloxy)-ethyl]-N,N,N-trimethylammonium methosulfate) homopolymer), polyquaternium-15 (poly(acrylamide-co-methacrylyloxyethyltrimethylammonium chloride) copolymer),

[0071] Polyquaternium-16 (poly(vinylpyrrolidone-co-vinylimidazanium chloride) terpolymer), Polyquaternium-17, (adipic acid, dimethylaminopropylamine and dichloroethylether terpolymer), Polyquaternium-18 (azelaic acid, dimethylaminopropylamine and dichloroethylether terpolymer), Polyquaternium-19 (quaternized copolymer of poly(vinyl alcohol) and 2,3-epoxy-propylamine copolymer), Polyquaternium-22 (poly( Polyquaternium-28 (Poly(vinylpyrrolidone-co-methacrylamidopropyltrimethylammonium chloride) copolymer), Polyquaternium-29 (Chitosan modified with 2,3-dihydroxypropyl-2-hydroxy-3-(trimethylammonio)propyl ether, chloride), Polyquaternium-32 (Poly(acrylamide-co-methacryloyloxyethyltrimethylammonium chloride) copolymer),

[0072] Polyquaternium-33 (Poly(acrylamide-co-acryloyloxyethyl trimethylammonium chloride) copolymer), Polyquaternium-34 (1,3-dibromopropane and N,N-diethyl-N',N'-dimethyl-1,3-propanediamine copolymer), Polyquaternium-35 (Poly(methacryloyloxyethyl trimethylammonium-co-methacryloyloxyethyl dimethylacetylammonium methosulfate) copolymer), Polyquaternium-36 (Poly(butyl methacrylate-co-methacryloyloxyethyl dimethylamine-co-methacryloyloxyethyl-trimethylammonium dimethyl sulfate) terpolymer), Polyquaternium-37 (Poly(methacryloyloxyethyl trimethylammonium chloride) homopolymer) ), Polyquaternium-39 (Poly(acrylic acid-co-acrylamide-co-diallyl-dimethylammonium chloride) terpolymer), Polyquaternium-42 (Poly[oxyethylene(dimethylimino)ethylene(dimethylimino)ethylene dichloride) copolymer), Polyquaternium-43 (Poly(acrylamide-co-acrylamidopropyltrimethylammonium chloride-co-2-amidopropylacrylamidosulfonate-co-dimethylaminopropylamine) copolymer), Polyquaternium-44 (Poly(vinylpyrrolidone-co-imidazolinium) copolymer), Polyquaternium-45 (Poly([N-methyl-N-ethoxyglycine]-methacrylate-co-methacryloyloxyethyl-trimethylammonium dimethyl sulfate) copolymer),

[0073] Polyquaternium-46 (poly(vinylcaprolactam-co-vinylpyrrolidone-co-vinylimidazolium methosulfate) terpolymer) and Polyquaternium-47 (poly(acrylic acid-co-methacrylamidopropyltrimethylammonium chloride-co-methylacrylate) terpolymer). Preferably, the cationic polymer is selected from Polyquaternium-22 (poly(acrylic acid-co-dimethyldiallylammonium chloride) copolymer) and Polyquaternium-39 (poly(acrylic acid-co-acrylamide-co-diallyl-dimethylammonium chloride) terpolymer).

[0074] Examples of commercially available polyquaterniums are available under the names Merquat, e.g., from Merck, such as Merquat 100 (Polyquaternium 6), Merquat 740 (Polyquaternium 7), Merquat 281 (Polyquaternium 22), and Merquat 2001 (Polyquaternium 47).

[0075] In a preferred embodiment, the cationic polymer has an average molecular weight of less than 500'000 g / mol, preferably less than 250'000 g / mol, even more preferably less than 100'000 g / mol, for example less than 75'000 g / mol, or less than 50'000 g / mol. However, it is also preferred that the average molecular weight of the cationic polymer is greater than 5'000 g / mol, more preferably greater than 10'000 g / mol. A cationic polymer with a higher average molecular weight may increase the viscosity of both the microcapsule slurry and the consumer product containing the microcapsules. If the cationic polymer is too small, the ability of the copolymer to colloidally stabilize the microcapsules may be reduced.

[0076] In addition to the polymeric stabilizer, fully or partially dissociated carboxylic acid groups may also be provided by the cationic polymers described herein above that include (meth)acrylic acid comonomers.

[0077] In a specific embodiment, the level of shell material in the at least one core-shell microcapsule is from 2% to 25% by weight, preferably from 5% to 20% by weight, more preferably from 10% to 15% by weight, based on the total weight of the at least one core-shell microcapsule.

[0078] In a specific embodiment, the microcapsules according to the invention have a volume-median diameter Dv(50) of 1 to 50 μm, preferably 5 to 35 μm, and even more preferably 8 to 20 μm. Microcapsules with a diameter larger than 50 μm may have the disadvantage of being visible in the product. Furthermore, for a given microcapsule volume, a large number of microcapsules may not be enough to ensure a homogeneous distribution of the microcapsules in the product or a homogeneous deposition of the microcapsules on the substrate. Conversely, microcapsules that are too small have a high surface to volume ratio, which reduces the stability with respect to leakage of the encapsulated perfume ingredients in the product substrate.

[0079] The microcapsules according to the present invention may be in the form of a slurry, in which the core-shell microcapsules are dispersed or suspended in an aqueous phase.

[0080] In a specific embodiment, the slurry has a solids content of 20% to 60% by weight, preferably 35% to 45% by weight. The solids content of the slurry is typically measured by using a thermobalance operating at 120° C. The solids content, expressed as a weight percent of the initial slurry adhered to the balance, is measured at the point where the rate of weight change induced by drying falls below 0.1% / min.

[0081] In a particular embodiment of the present invention, the perfume ingredient is selected from the group consisting of: ACETYL ISOEUGENOL((E)-2-METHOXY-4-(PROP-1-EN-1-YL) PHENYL ACETATE);ADOXAL(2,6,10-TRIMETHYLUNDEC-9-ENAL);AGRUMEX(2-(TERT-BUTYL)HEXYL CYCLOATANE);ALDEHYDE C 10 DECYLIC(DECANAL);ALDEHYDE C 11 MOA(2-METHYLDECANAL);ALDEHYDE C 11 UNDECYLENIC(UNDEC-10-ENAL);ALDEHYDE C 110 UNDECYLIC(UNDECANAL);ALDEHYDE C 12 LAURIC(DODECANAL);ALDEHYDE C 12 MNA PURE(2-METHYLUNDECANAL);ALDEHYDE C 8 OCTYLIC(OCTANAL);ALDEHYDE C 9 ISONONYLIC(3,5,5-TRIMETHYLHEXANAL);ALDEHYDE C 9 NONYLIC FOOD GRADE(Nonanal);ALDEHYDE C 90 NONENYLIC((E)-Nona-2-enal);ALDEHYDE ISO C 11((E)-Undec-9-enal);ALDEHYDE MANDARINE((E)-Dodec-2-enal);ALLYL AMYL GLYCOLATE(Prop-2-enyl 2-(3-methylbutoxy)acetate);ALLYL CAPROATE(Prop-2-enyl hexanoate);ALLYL CYCLOHEXYL PROPIONATE(Prop-2-enyl 3-cyclohexylpropanoate);ALLYL OENANTHATE(Prop-2-enyl heptanoate);

[0082] AMBER CORE (1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol);AMBERKETAL (3,8,8,11a-tetramethyldodecahydro-1H-3,5a-epoxynaphtho[2,1-c]oxepin);AMBERMAX (1,3,4,5,6,7-hexahydro-beta,1,1,5,5-pentamethyl-2H-2,4a-methanonaphthalene-8-ethanol);AMBRETTOLIDE ((Z)-oxacycloheptadec-10-en-2-one);AMBROFIX ((3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran);AMYL BUTYRATE(PENTYL BUTANOATE);AMYL CINNAMIC ALDEHYDE((Z)-2-BENZYLIDENEHEPTANAL);AMYL SALICYLATE(PENTYL 2-HYDROXYBENZOATE);ANETHOLE SYNTHETIC((E)-1-METHOXY-4-(PROP-1-EN-1-YL)BENZENE);ANISYL ACETATE(4-METHOXYBENZYL ACETATE);APHERMATE(1-(3,3-DIMETHYLCYCLOHEXYL)ETHYLFORMATE);AUBEPINE PARA CRESOL (4-methoxybenzaldehyde);AURANTIOL ((E)-methyl 2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate);BELAMBRE ((1R,2S,4R)-2'-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4'-[1,3]dioxane]);

[0083] BENZALDEHYDE;BENZYL ACETATE;BENZYL ACETONE;BENZYL BENZOATE;BENZYL SALICYLATE;BERRYFLOR (ETHYL 6-ACETOXYHEXANOATE);BICYCLO NONALACTONE;BOISAMBRENE FORTE ((ETHOXYMETHOXY)-CYCLODODECANE);BOISIRIS ((1S,2R,5R)-2-ETHOXY-2,6,6-TRIMETHYL-9-METHYLENEBICYCLO[3.3.1]NONANE);BORNEOL CRYSTALS ((1S,2S,4S)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTANE-2-OL);BORNYL ACETATE((2S,4S)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTANE-2-YL ACETATE);BOURGEONAL(3-(4-(TERT-BUTYL)PHENYL)PROPANAL);BUTYL BUTYRO LACTATE(1-BUTOXY-1-OXOPROPAN-2-YL BUTANOAATE);BUTYL CYCLOHEXYL ACETATE PARA(4-(TERT-BUTYL)CYCLOHEXYL ACETATE);BUTYL QUINOLINE SECONDARY(2-(2-METHYLPROPYL)QUINOLINE);CAMPHOR SYNTHETIC((1S,4S)-1,7,7-TRIMETHYLBICYCLO[2.2.1]Heptan-2-one;CARVACROL(5-isopropyl-2-methylphenol);CARVONE LAEVO((5R)-2-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-one);CASHMERAN(1,1,2,3,3-pentamethyl-2,3,6,7-tetrahydro-1H-inden-4(5H)-one);CASSYRANE(5-tert-butyl-2-methyl-5-propyl-2H-furan);CEDRENE((1S,8aR)-1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro-1H-5,8a-methanoazulene);CEDRYL ACETATE((1S,6R,8aR)-1,4,4,6-TETRAMETHYLOCTAHYDRO-1H-5,8a-METHANOAZULEN-6-YL ACETATE);CEDRYL METHYL ETHER((1R,6S,8aS)-6-METHOXY-1,4,4,6-TETRAMETHYLOCTAHYDRO-1H-5,8a-METHANOAZULENE);CETONE V((E)-1-(2,6,6-TRIMETHYLCYCLOHEX-2-EN-1-YL)HEPTA-1,6-DIEN-3-ONE);.

[0084] CINNAMIC ALCOHOL SYNTHETIC((E)-3-Phenylprop-2-en-1-ol);CINNAMIC ALDEHYDE((2E)-3-Phenylprop-2-enal);CINNAMYL ACETATE((E)-3-Phenylprop-2-en-1-yl acetate);CIS JASMONE((Z)-3-Methyl-2-(pent-2-en-1-yl)cyclopent-2-enone);CIS-3-HEXENOL((Z)-Hex-3-en-1-ol);CITRAL TECH((E)-3,7-Dimethylocta-2,6-dienal);CITRATHAL R((Z)-1,1-Diethoxy-3,7-Dimethylocta-2,6-diene);CITRONELLAL(3,7-Dimethylocta-6-enal);CITRONELLOL EXTRA(3,7-DIMETHYLOCTA-6-EN-1-OL);CITRONELLYL ACETATE(3,7-DIMETHYLOCTA-6-EN-1-YL ACETATE);CITRONELLYL FORMATE(3,7-DIMETHYLOCTA-6-EN-1-YL FORMATE);CITRONELLYL NITRILE(3,7-DIMETHYLOCTA-6-ENE NITRILE);CLONAL(DODECANE NITRILE);CORANOL(4-CYCLOHEXYL-2-METHYLBUTANE-2-OL);COSMONE((Z)-3-METHYLCYCLOTETRADECA-5-ENONE);COUMARIN PURE CRYSTALS(2H-CHROMEN-2-ONE);CRESYL ACETATE PARA((4-METHYLPHENYL)ACETATE);CRESYL METHYL ETHER PARA(1-METHYL-4-METHYLBENZENE);CUMIN NITRILE(4-ISOPROPYLBENZONITRILE);CYCLAL C(2,4-Dimethylcyclohex-3-ene-1-carbaldehyde);CYCLAMEN ALDEHYDE EXTRA(3-(4-isopropylphenyl)-2-methylpropanal);CYCLOGALBANATE(ALLYL 2-(CYCLOHEXYLOXY)ACETATE);CYCLOHEXYL ETHYL ACETATE(2-CYCLOHEXYL ETHYL ACETATE);CYCLOHEXYL SALICYLATE(CYCLOHEXYL 2-HYDROXYBENZOATE);CYCLOMYRAL(8,8-Dimethyl-1,2,3,4,5,6,7,8-Octahydronaphthalene-2-carbaldehyde);CYMENE PARA(1-Methyl-4-propan-2-ylbenzene);

[0085] DAMASCENONE((E)-1-(2,6,6-trimethylcyclohexa-1,3-dien-1-yl)but-2-en-1-one);DAMASCONE ALPHA((E)-1-(2,6,6-trimethylcyclohexa-2-en-1-yl)but-2-en-1-one);DAMASCONE DELTA(1-(2,6,6-trimethyl-1-cyclohex-3-enyl)but-2-en-1-one);DECALACTONE GAMMA(5-Hexyloxolan-2-one);DECENAL-4-TRANS((E)-Deca-4-enal);DELPHONE(2-Pentylcyclopentanone);DELTA-3 CARENE((1S,6S)-3,7,7-Trimethylbicyclo[4.1.0]hept-3-ene);DIHEXYL FUMARATE(DIHEXYL-BUTA-2-ENEDIOATE);DIHYDRO ANETHOLE(1-METHOXY-4-PROPYLBENZENE);DIHYDRO JASMONE(3-METHYL-2-PENTYLCYCLOPENT-2-ENONE);DIHYDRO MYRCENOL(2,6-DIMETHYLOCTA-7-EN-2-OL);DIMETHYL ANTHRANILATE(METHYL 2-(METHYLAMINO)BENZOATE);DIMETHYL BENZYL CARBINOL DIMETHYL BENZYL CARBINOL(2-METHYL-1-PHENYLPROPAN-2-OL);DIMETHYL BENZYL CARBINYL ACETATE(2-METHYL-1-PHENYLPROPAN-2-YL ACETATE);DIMETHYL BENZYL CARBINYL BUTYRATE(2-METHYL-1-PHENYLPROPAN-2-YL BUTANOAATE);DIMETHYL OCTENONE(4,7-dimethyloct-6-en-3-one);DIMETOL(2,6-dimethylheptan-2-ol);DIPENTENE(1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene);

[0086] DIPHENYL OXIDE;DODECALACTONE DELTA(6-Heptyltetrahydro-2H-pyran-2-one);DODECALACTONE GAMMA(5-Octyloxolan-2-one);DODECENAL((E)-Dodec-2-enal);DUPICAL((E)-4-((3aS,7aS)-Hexahydro-1H-4,7-methanoinden-5(6H)-ylidene)butanal);EBANOL((E)-3-Methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol);ESTERLY(Ethylcyclohexylcarboxylate);ETHYL ACETATE;ETHYL ACETOACETATE;ETHYL 3-Oxobutanoate CINNAMATE(ETHYL 3-PHENYLPROP-2-ENOATE);ETHYL HEXANOATE;ETHYL LINALOO((E)-3,7-DIMETHYLNONA-1,6-DIEN-3-OL);ETHYL LINALYL ACETATE((Z)-3,7-DIMETHYLNONA-1,6-DIEN-3-YL ACETATE);ETHYL MALTOL(2-ETHYL-3-HYDROXY-4H-PYRAN-4-ONE);ETHYL METHYL-2-BUTYRATE(ETHYL 2-METHYLBUTYRATE);ETHYL OCTANOATE;ETHYL OENANTHATE;ETHYL PHENYL GLYCIDATE(ETHYL 3-PHENYLOXIRANE-2-CARBOXYLATE);ETHYL SAFRANATE(ETHYL 2,6,6-TRIMETHYLCYCLOHEXA-1,3-DIEN-1-CARBOXYLATE);

[0087] ETHYL VANILLIN(3-Ethoxy-4-hydroxybenzaldehyde);ETHYLENE BRASSYLATE(1,4-Dioxacycloheptadecane-5,17-dione);EUCALYPTOL((1s,4s)-1,3,3-Trimethyl-2-oxabicyclo[2.2.2]octane);EUGENOL(4-Allyl-2-methoxyphenol);EVERNYL(Methyl 2,4-dihydroxy-3,6-dimethylbenzoate);FENCHYL ACETATE((2S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-yl acetate);FENCHYL ALCOHOL((1S,2R,4R)-1,3,3-trimethylbicyclo[2.2.1]heptan-2-ol);FENNALDEHYDE(3-(4-methoxyphenyl)-2-methylpropanal);FIXAMBRENE(3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan);FIXOLIDE(1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethanone);FLORALOZONE (3-(4-ethylphenyl)-2,2-dimethylpropanal);FLORHYDRAL(3-(3-isopropylphenyl)butanal);FLORIDILE((E)-undec-9-enenitrile);FLOROCYCLENE((3aR,6S,7aS)-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-ylpropanoate);FLOROPAL(2,4,6-trimethyl-4-phenyl-1,3-dioxane);FLOROSA HC(tetrahydro-4-methyl-2-(2-methylpropyl)-2H-pyran-4-ol);

[0088] FRESKOMENTHE(2-(sec-butyl)cyclohexanone);FRUCTONE(ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate);FRUITATE((3aS,4S,7R,7aS)-ethyl octahydro-1H-4,7-methanoindene-3a-carboxylate);FRUTONILE(2-methyldecanenitrile);GALBANONE PURE(1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one);GARDENOL(1-phenylethyl acetate);GARDOCYCLENE((3aR,6S,7aS)-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl 2-methylpropanoate);GERANIOL((E)-3,7-dimethylocta-2,6-dien-1-ol);GERANYL ACETATE((E)-3,7-dimethylocta-2,6-dien-1-yl acetate);GERANYL CROTONATE((E)-3,7-dimethylocta-2,6-dien-1-yl but-2-enoate);GERANYL ISOBUTYRATE((E)-3,7-dimethylocta-2,6-dien-1-yl 2-methylpropanoate);GIVESCONE(ethyl 2-ethyl-6,6-dimethylcyclohex-2-enecarboxylate);

[0089] HABANOLIDE((E)-OXACYCLOHEXADECA-12-EN-2-ONE);HEDIONE(METHYL 3-OXO-2-PENTYLCYCLOPENTANEACETATE);HELIOTROPINE CRYSTALS(BENZO[d][1,3]DIOXOLE-5-CARBALDEHYDE);HERBANATE((2S)-ETHYL 3-ISOPROPYLBICYCLO[2.2.1]HEPTA-5-ENE-2-CARBOXYLATE);HEXENAL-2-TRANS((E)-HEX-2-ENAL);HEXENOL-3-CIS((Z)-HEX-3-EN-1-OL);HEXENYL-3-CIS ACETATE((Z)-HEX-3-EN-1-YL ACETATE);HEXENYL-3-CIS BUTYRATE((Z)-HEX-3-EN-1-YL BUTANOAATE);HEXENYL-3-CIS ISOBUTYRATE((Z)-HEX-3-EN-1-YL 2-METHYLPROPANOATE);HEXENYL-3-CIS SALICYLATE((Z)-HEX-3-EN-1-YL 2-HYDROXYBENZOATE);HEXYL ACETATE;HEXYL BENZOATE;HEXYL BUTYRATE;HEXYL CINNAMIC ALDEHYDE((E)-2-BENZYLIDENEOCTANAL);HEXYL ISOBUTYRATE(HEXYL 2-METHYLPROPANOATE);HEXYL SALICYLATE(HEXYL 2-HYDROXYBENZOATE);HYDROXYCITRONELLAL(7-HYDROXY-3,7-DIMETHYLOCTANAL);INDOFLOR(4,4a,5,9b-TETRAHYDROINDENO[1,2-D][1,3]DIOXINE);INDOLE PURE(1H-indole);INDOLENE(8,8-di(1H-indol-3-yl)-2,6-dimethyloctan-2-ol);

[0090] IONONE BETA((E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-one);IRISANTHEME((E)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one);IRISONE ALPHA((E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one);IRONE ALPHA((E)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one);ISO E SUPER(1-(2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethanone);ISOAMYL ACETATE(3-METHYLBUTYL ACETATE);ISOAMYL BUTYRATE(3-METHYLBUTYL BUTANOAATE);ISOBUTYL METHOXY PYRAZINE(2-METHYLPROPYL 3-METHOXYPYRAZINE);ISOCYCLOCITRAL(2,4,6-TRIMETHYLCYCLOHEX-3-ENECARBALDEHYDE);ISOEUGENOL((E)-2-METHOXY-4-(PROP-1-EN-1-YL)PHENOL);ISOJASMONE B 11(2-HEXYLCYCLOPENT-2-EN-1-ONE);

[0091] ISOMENTHONE DL(2-ISOPROPYL-5-METHYLCYCLOHEXANONE);ISONONYL ACETATE(3,5,5-TRIMETHYLHEXYL ACETATE);ISOPROPYL METHYL-2-BUTYRATE(ISOPROPYL 2-METHYL BUTANATE);ISOPROPYL QUINOLINE(6-ISOPROPYL QUINOLINE);ISORALDEINE((E)-3-METHYL-4-(2,6,6-TRIMETHYLCYCLOHEX-2-EN-1-YL)BUTA-3-EN-2-ONE);JASMACYCLENE((3aR,6S,7aS)-3a,4,5,6,7,7a-HEXAHYDRO-1H-4,7-METHANOINDEN-6-YL ACETATE);JASMONE CIS((Z)-3-methyl-2-(pent-2-en-1-yl)cyclopent-2-enone);JASMONYL(3-butyl-5-methyltetrahydro-2H-pyran-4-yl acetate);JASMOPYRANE FORTE(3-pentyltetrahydro-2H-pyran-4-yl acetate);JAVANOL((1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyl)methanol);KOAVONE((Z)-3,4,5,6,6-pentamethylhept-3-en-2-one);LAITONE(8-isopropyl-1-oxaspiro[4.5]decan-2-one);LEAF ACETAL((Z)-1-(1-ethoxyethoxy)hex-3-ene);LIFFAROME((Z)-hex-3-en-1-yl methyl carbonate);LILIAL(3-(4-(tert-butyl)phenyl)-2-methylpropanal);

[0092] #N / ALINALOOL(3,7-dimethylocta-1,6-dien-3-ol);LINALOOL OXIDE(2-(5-methyl-5-vinyltetrahydrofuran-2-yl)propan-2-ol);LINALYL ACETATE(3,7-dimethylocta-1,6-dien-3-yl acetate);MAHONIAL((4E)-9-hydroxy-5,9-dimethyl-4-decenal);MALTOL(3-hydroxy-2-methyl-4H-pyran-4-one);MALTYL ISOBUTYRATE(2-METHYL-4-OXO-4H-PYRAN-3-YL 2-METHYLPROPANOATE);MANZANATE(ETHYL 2-METHYLPENTANOATE);MAYOL((4-ISOPROPYLCYCLOHEXYL)METHANOL);MEFROSOL(3-METHYL-5-PHENYLPENTAN-1-OL);MELONAL(2,6-DIMETHYLHEPTA-5-ENAL);#N / A#N / AMERCAPTO-8-METHANE-3-ONE;METHYL ANTHRANILATE(METHYL 2-AMINOBENZOATE);METHYL BENZOATE(METHYL BENZOATE);METHYL CEDRYL KETONE(1-((1S,8aS)-1,4,4,6-TETRAMETHYL-2,3,3a,4,5,8-HEXAHYDRO-1H-5,8a-METHANOAZULEN-7-YL)ETHANONE);METHYL CINNAMATE(METHYL 3-PHENYLPROP-2-ENOATE);METHYL DIANTILIS(2-ETHOXY-4-(METHOXYMETHYL)PHENOL);METHYL DIHYDRO ISOJASMONATE(METHYL 2-HEXYL-3-OXOCYCLOPENTANE-1-CARBOXYLATE);

[0093] METHYL HEPTENONE PURE(6-METHYLHEPTA-5-EN-2-ONE);METHYL LAITONE(8-METHYL-1-OXASPIRO[4.5]DECAN-2-ONE);METHYL NONYL KETONE(UNDECA-2-ONE);METHYL OCTYNE CARBONATE(METHYL NONA-2-YNOATE);METHYL PAMPLEMOUSSE(6,6-DIMETHYL-2,5,5-TRIMETHYLHEX-2-ENE);METHYL SALICYLATE(METHYL 2-HYDROXYBENZOATE);MUSCENONE((Z)-3-METHYLCYCLOPENTADECA-5-ENONE);MYRALDENE(4-(4-METHYLPENT-3-EN-1-YL)CYCLOHEX-3-ENECARBALDEHYDE);MYRCENE(7-METHYL-3-METHYLENEOCTA-1,6-DIENE);MYSTIKAL(2-METHYLUNDECANOIC ACID);NECTARYL(2-(2-(4-METHYLCYCLOHEX-3-EN-1-YL)PROPYL)CYCLOPENTANONE);NEOBERGAMATE FORTE(2-METHYL-6-METHYLENEOCTA-7-EN-2-YL ACETATE);NEOCASPIRENE EXTRA(10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene);NEOFOLIONE((E)-methylnon-2-enoate);NEROLEX((2Z)-3,7-dimethylocta-2,6-dien-1-ol);NEROLIDOL((Z)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol);

[0094] NEROLIDYLE((Z)-3,7,11-TRIMETHYLDODECA-1,6,10-TRIEN-3-YL ACETATE);NEROLINE CRYSTALS(2-ETHOXYNAPHTHALENE);NEROLIONE(1-(3-METHYLBENZOFURAN-2-YL)ETHANONE);NERYL ACETATE((Z)-3,7-DIMETHYLOCTA-2,6-DIEN-1-YL ACETATE);NIRVANOLIDE((E)-13-METHYLOXACYCLOPENTADECA-10-EN-2-ONE);NONADIENAL((2E,6Z)-NONA-2,6-DIENAL);NONADIENOL-2,6((2Z,6E)-2,6-NONADIEN-1-OL);NONADYL(6,8-DIMETHYLNONAN-2-OL);NONALACTONE GAMMA(5-PENTYLOXOLAN-2-ONE);NONENAL-6-CIS((Z)-NONA-6-ENAL);NONENOL-6-CIS((Z)-NONA-6-EN-1-OL);NOPYL ACETATE(2-(6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-EN-2-YL)ETHYL ACETATE);NYMPHEAL(3-(4-(2-METHYLPROPYL)-2-METHYLPHENYL)PROPANAL);OCTALACTONE DELTA(6-PROPYLTETRAHYDRO-2H-PYRAN-2-ONE);METHYL HEXYL KETONE(OCTAN-2-ONE);ORANGER CRYSTALS(1-(2-NAPHTHYL)-ETHANONE);ORIVONE(4-(TERT-PENTYL)CYCLOHEXANONE);PANDANOL((2-METHOXYETHYL)BENZENE);

[0095] PARA TERT BUTYL CYCLOHEXYL ACETATE(4-(tert-butyl)cyclohexyl acetate);PARADISAMIDE(2-ethyl-N-methyl-N-(m-tolyl)butanamide);PEACH PURE(5-heptyldihydrofuran-2(3H)-one);PELARGENE(2-methyl-4-methylene-6-phenyltetrahydro-2H-pyran);PELARGOL(3,7-dimethyloctan-1-ol);PEONILE(2-cyclohexylidene-2-phenylacetonitrile);PETALIA(2-cyclohexylidene-2-(o-tolyl)acetonitrile);PHARAONE(2-cyclohexylhepta-1,6-dien-3-one);PHENOXY ETHYL ISOBUTYRATE(2-(phenoxy)ethyl 2-methylpropanoate);PHENYL ACETALDEHYDE(2-PHENYL-ETHANAL);PHENYL ETHYL ACETATE(2-PHENYLETHYL ACETATE);PHENYL ETHYL ALCOHOL(2-PHENYLETHYL ETHANOL);PHENYL ETHYL ISOBUTYRATE(2-PHENYLETHYL 2-METHYLPROPANOATE);PHENYL ETHYL PHENYL ACETATE(2-PHENYLETHYL 2-PHENYLETHYL ACETATE);PHENYL PROPYL ALCOHOL(3-PHENYLPROPAN-1-OL);PINENE ALPHA(2,6,6-TRIMETHYLBICYCLO[3.1.1]HEPT-2-ENE);PINENE BETA(6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane);PINOACETALDEHYDE(3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal);PIVAROSE(2,2-dimethyl-2-phenylethylpropanoate);

[0096] POMAROSE((2E,5E)-5,6,7-trimethylocta-2,5-dien-4-one);POMELOL(2,4,7-trimethyl-6-octen-1-ol);PRECYCLEMONE B(1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-enecarbaldehyde);PRENYL ACETATE(3-methylbut-2-en-1-yl acetate);PRUNOLIDE(5-pentyldihydrofuran-2(3H)-one);RADJANOL SUPER((E)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol);RASPBERRY KETONE(4-(4-hydroxyphenyl)butan-2-one);RHUBAFURAN(2,4-dimethyl-4-phenyltetrahydrofuran);ROSACETOL(2,2,2-trichloro-1-phenylethyl acetate);ROSALVA(dec-9-en-1-ol);ROSE OXIDE(4-methyl-2-(2-methylprop-1-en-1-yl)tetrahydro-2H-pyran);ROSE OXIDE CO(4-methyl-2-(2-methylprop-1-en-1-yl)tetrahydro-2H-pyran);ROSYFOLIA(1-methyl-2-(5-methylhex-4-en-2-yl)cyclopropylmethanol);ROSYRANE SUPER(4-methylene-2-phenyltetrahydro-2H-pyran);SAFRALEINE(2,3,3-trimethyl-1-indanone);SAFRANAL(2,6,6-trimethylcyclohexa-1,3-dienecarbaldehyde);SANDALORE EXTRA(3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol);SCENTAURUS CLEAN(ethyl (Z)-2-acetyl-4-methyltridec-2-enoate);

[0097] SERENOLIDE(2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate);SILVANONE SUPRA(cyclopentadecanone, hexadecanolide);SILVIAL(2-methyl-3-[4-(2-methylpropyl)phenyl]propanal);SPIROGALBANONE(1-(spiro[4.5]dec-6-en-7-yl)pent-4-en-1-one);STEMONE((E)-5-methylheptan-3-one oxime);STYRALLYL ACETATE(1-phenylethyl acetate);SUPER MUGUET((E)-6-ethyl-3-methyloct-6-en-1-ol);SYLKOLIDE((E)-2-((3,5-dimethylhex-3-en-2-yl)oxy)-2-methylpropyl cyclopropanecarboxylate);TERPINENE ALPHA(1-METHYL-4-PROPAN-2-YLCYCLOHEXA-1,3-DIENE);TERPINENE GAMMA(1-METHYL-4-PROPAN-2-YLCYCLOHEXA-1,4-DIENE);TERPINEOL(2-(4-METHYLCYCLOHEX-3-EN-1-YL)PROPAN-2-OL);TERPINEOL ALPHA(2-(4-METHYLCYCLOHEX-3-ENYL)PROPAN-2-OL);TERPINEOL PURE(2-(4-METHYLCYCLOHEX-3-ENYL)PROPAN-2-OL);TERPINOLENE(1-METHYL-4-(PROPAN-2-YLIDENE)CYCLOHEX-1-ENE);TERPINYL ACETATE(2-(4-METHYLCYCLOHEX-3-ENYL)PROPAN-2-YL ACETATE);TETRAHYDRO LINALOOL(3,7-dimethyloctan-3-ol);TETRAHYDRO MYRCENOL(2,6-dimethyloctan-2-ol);

[0098] THIBETOLIDE(OXACYCLOHEXADECAN-2-ONE);THYMOL(2-ISOPROPYL-5-METHYLPHENOL);TOSCANOL(1-(CYCLOPYLMETHYL)-4-METHOXYBENZENE);TRICYCLAL(2,4-DIMETHYLCYCLOHEX-3-ENECARBALDEHYDE);TRIDECENE-2-NITRILE((E)-TRIDECENENITRILE);TRIFERNAL(3-PHENYLBUTANAL);TROPIONAL(3-(BENZO[d][1,3]DIOXOL-5-YL)-2-METHYLPHENYL) TROPIONAL(3-(BENZO[d][1,3]DIOXOL-5-YL)-2-METHYLPROPANAL); UNDECATRIENE((3E,5Z)-UNDECA-1,3,5-TRIENE); UNDECAVERTOL((E)-4-METHYLDECA-3-ENE-5-OL); VANILLIN(4-HYDROXY-3-METHOXYBENZALDEHYDE); VELOUTONE(2,2,5-TRIMETHYL-5-PENTYLCYCLOPENTANONE); VELVIONE((Z)-CYCLOHEXADECA-5-ENONE); VIOLET NITRILE((2E,6Z)-NONA-2,6-DIENENITRILE);

[0099] YARA YARA (2-methoxynaphthalene); ZINARINE (2-(2,4-dimethylcyclohexyl)pyridine); BOIS CEDRE ESS CHINE (cedarwood oil); EUCALYPTUS GLOBULUS ESS CHINA (eucalyptus oil); GALBANUM ESS (galbanum oil); GIROFLE FEUILLES ESS RECT MADAGASCAR (clove oil); LAVANDIN GROSSO OIL FRANCE ORPUR (lavandin oil); MANDARIN OIL WASHED COSMOS (mandarin oil); ORANGE TERPENES (orange terpenes); PATCHOULI ESS INDONESIE (patchouli oil); and YLANG ECO ESSENCE (Iranian oil). These fragrance ingredients, thanks to their advantageous lipophilicity and olfactory performance, are particularly suitable for obtaining stable and performant microcapsules.

[0100] Comprehensive listings of fragrance ingredients which may also be encapsulated in accordance with the present invention may be found in perfumery literature, such as "Perfume & Flavor Chemicals", S. Arctander (Allured Publishing, 1994).

[0101] A second aspect of the present invention provides a method for obtaining an encapsulated composition, especially a composition as described herein above. The method involves the following steps: a) providing a core composition comprising an aminosilane; b) providing an aqueous phase comprising at least one polymeric surfactant containing fully or partially dissociated carboxylic acid groups; c) emulsifying the core composition provided in step a) in the aqueous phase provided in step b) to obtain an emulsion of core composition droplets dispersed in the aqueous phase; d) reacting the aminosilane and the polymeric surfactant to form a polymeric stabilizer that stabilizes the dispersed oil droplets; e) adding at least one multifunctional isocyanate; f) adding at least one multifunctional amine containing at least one amino group; and g) reacting a polyfunctional isocyanate and a polyfunctional amine to form a slurry of microcapsules to form a shell around the core composition droplets; Including, wherein the cationic polymer containing quaternary ammonium groups is added before, during or after step g), preferably before or during step g); and Here, the nominal molar ratio of the amino groups and quaternary ammonium groups to the carboxylic acid groups is 0.8 to 1.1, preferably 0.9 to 1.08, and more preferably 1.00 to 1.06.

[0102] Appropriate stirring speed and mixer geometry can be selected to obtain the desired average droplet size and droplet size distribution. It is a feature of the present invention that the polymeric stabilizer has particularly high surface active power and can promote the formation of dispersed oil droplets with the desired small droplet size and low polydispersity.

[0103] A feature of the process of the present invention is that in a 1 liter vessel equipped with a cross-beam agitator with a pitched beam and having an agitator diameter to reactor diameter of about 0.7, microcapsules having an average particle size D(50) of 30 microns or less, more specifically 20 microns or less, and a polydispersity span of less than 1.5, more specifically less than 1.3, even more specifically less than 1.2 can be formed using a cross-beam agitator with a pitched beam such as a turbine, Mig agitator or the like, at a stirring speed of less than 1000 rpm, more specifically about 100 to about 1000 rpm, even more specifically about 500 to about 700 rpm, for example on the order of 600 rpm. Preferably, a Mig stirrer operating at a speed of 600±50 rpm is used. However, one skilled in the art will readily appreciate that such stirring conditions may vary depending on the size of the reactor and the volume of the slurry, the exact geometry of the agitator, and the ratio of the agitator diameter to the reactor diameter. For example, for a Mig agitator with an agitator to reactor diameter ratio of 0.5-0.9 and a slurry volume of 0.5-8 tons, the preferred agitation speed in the context of the present invention is 150 rpm-50 rpm.

[0104] In the formation of the oil-in-water emulsion (steps a)-d)), the maleic anhydride copolymer is added to the aqueous external phase and the aminosilane is miscible in the oil phase. These separations are a process optimization consideration to control the rate of hydrolysis of the silane and ensure that the silane and maleic anhydride copolymer react in an optimal manner at the oil-water interface to form the polymeric stabilizer in situ. If silanes are allowed to hydrolyze too quickly, they are prone to self-condensation. Employing the silane in the oil phase promotes reaction with the polymeric surfactant at the oil-water interface rather than undergoing self-condensation.

[0105] To provide optimal reaction conditions for the coupling of aminosilanes with maleic anhydride, the pH of the mixture is raised to about 3.5-7, for example 4.5 or 6. This can be achieved by the addition of a suitable base. A dilute solution of ammonia (20%) is suitable for this purpose, but other bases such as dilute sodium hydroxide can also be employed. The entire process can be carried out for about 1 h to 3 h, more specifically 2±0.5 h, and at ambient temperature or at a slightly elevated temperature, for example 35±5°C. The polymeric stabilizer thus formed in-situ associates at the oil-water interface and forms at least a partial layer around the oil droplets, stabilizing them and preventing their coalescence.

[0106] Concerning step g), the formation of the shell around the droplets can be effectively carried out by heating. This can be achieved at a temperature of at least 50° C., preferably at least 60° C., more preferably in the range of 65° C. to 90° C., to ensure a sufficiently rapid reaction proceeds. It may be preferable to increase the temperature continuously or stepwise (for example by 5° C. in each case) until the reaction is essentially complete. The dispersion may then be cooled to room temperature.

[0107] For shell formation around the droplets, the pH of the aqueous phase may be adjusted to a range of 4 to 8, preferably 5 to 7, for example about 6. The pH may be adjusted using an inorganic base, for example sodium hydroxide solution, or a carbonate buffer salt.

[0108] The reaction time typically depends on the nature of the reactive wall-forming material, the amount of said material employed, and the temperature used. The reaction period can be from a few minutes to a few hours. In most cases, microcapsule formation is effectively carried out between about 60 minutes and up to 6 or 8 hours at the temperatures defined above.

[0109] According to the process described herein, it is possible to obtain microcapsules that show good retention of core contents, but are rather fragile.In this way, the microcapsules are sufficiently robust to show low levels of leakage during storage, even in extraction medium, but can break relatively easily to release core contents at a significant rate when applied.This is particularly advantageous in encapsulated perfume applications, and more specifically in encapsulated perfume for laundry applications.

[0110] Applicants believe, without intending to be bound by any particular theory, that by operating within the process parameters described herein, including selection of reagents and control of the rate and / or duration of heating of the specifically described methods, it is possible to control the reaction of the shell-forming monomers to produce a relatively thin and homogenous resinous shell that is resistant to leakage, yet capable of breaking down in response to only light or moderate shear forces.

[0111] After the formation of microcapsules, the encapsulation composition can be cooled to room temperature.Preferably, the cooling time is at least 1 hour, more particularly at least 2 hours, for example 2.5 hours ± 0.5 hours.By slow cooling in this manner, the resin can be further arranged by annealing, which is also believed to affect the homogeneity of the resin shell and thus contribute to the properties of the microcapsules when applied.

[0112] Before, during or after cooling, the encapsulated composition may be further processed. Further processing may include treating the composition with one or more antimicrobial preservatives, which are well known in the art. Further processing may also include adding a suspension aid, such as a hydrocolloid suspension aid, to aid in the stable physical dispersion of the microcapsules and prevent any creaming or coalescence. Any additional adjuvants that may be desired or are conventional in the art may also be added at this point.

[0113] The resulting encapsulation composition is presented in the form of a slurry of microcapsules suspended in an aqueous suspension medium and may be incorporated directly into a consumer product base. However, if desired, the slurry may be dehydrated to present the encapsulation composition in the form of a dry powder. The dehydration of the microcapsule slurry is conventional and may be carried out according to techniques known in the art, such as spray drying, evaporation or freeze drying. Typically, as is conventional in the art, the dry microcapsules will be dispersed or suspended in a suitable powder, such as powdered silica or the like, which may act as a bulking agent, flow aid or the like. Such a suitable powder may be added to the encapsulation composition before, during or after the drying step.

[0114] A third aspect of the present invention provides the use of an encapsulation composition as described herein to obtain a consumer product that is free of agglomerates of microcapsules. Such consumer products may comprise at least one cationic surfactant in a consumer product base.The consumer product is preferably a fabric care conditioner or a hair care conditioner.

[0115] The at least one cationic surfactant can be a quaternized triethanolamine ester selected from the group consisting of quaternized triethanolamine monoesters, quaternized triethanolamine diesters, and quaternized triethanolamine triesters.

[0116] In a specific embodiment, the consumer product contains at least one cationic surfactant in an amount of 0.5 to 15 wt.%, preferably 1.0 wt.% to 10 wt.%, more preferably 1.5 to 8.0 wt.%, and even more preferably 2.0 to 4.0 wt.%, based on the total weight of the consumer product.

[0117] In a specific embodiment, the level of the encapsulated composition in the consumer product is from 0.01 to 5 wt %, preferably from 0.05 to 2.5 wt %, more preferably from 0.1 to 2.0 wt %, and even more preferably from 0.1 to 1.5 wt %, based on the total weight of the consumer product.

[0118] The encapsulated composition of the present invention can be employed as a delivery system to deliver active ingredients such as fragrances for use in any type of consumer product. The term "consumer product" specifically refers to home care products, textile care products or personal care products, such as body care products and hair care products.

[0119] The encapsulated compositions according to the present invention are particularly usefully employed as perfume delivery vehicles in consumer products which require the microcapsules to adhere well to the substrate to which they are applied in order to provide optimal perfume benefit, including fabric treatment products such as hair shampoos and conditioners, and laundry detergents and conditioners. A series of examples will now be presented to further illustrate the invention.

[0120] Examples 1.1-1.9: Preparation and characterization of microcapsules Polyurea microcapsules were prepared by carrying out the following steps (see Table 1 for details): 1) preparing a core composition containing 3-aminopropyltriethoxysilane by combining a known amount of 3-aminopropyltriethoxysilane with 31 g of a fragrance composition; 2) emulsifying the core composition obtained in step 1) in 54.8 g of water containing a known amount of ZeMac E400 using a mechanical stirrer at 900 rpm at a temperature of 35±2° C.; 3) adjusting the pH to 6.0 by adding a 10% by weight solution of NaOH in water and maintaining the system at a temperature of 35±2° C. for 1 hour while stirring as in step 2); 4) adding a known amount of a water-dispersible isocyanate based on hexamethylene diisocyanate (Bayhydur XP2547, Covestro) and a known amount of diisocyanate 4,4-dicyclohexylmethanediyl (Desmodur W1, Covestro) to the emulsion and maintaining the system at a temperature of 35±2° C. for 30 minutes, while stirring, as in steps 2) and 3); 5) adding a known amount of polyethyleneimine solution (Lupasol G100, BASF) in one step and gradually heating the reaction mixture to 70° C. over a period of 2 hours; 6) adding a known amount of cationic polymer solution in water (see Table 1 for details) and further heating the reaction mixture to 85° C. for 2 hours; 7) Adding 1 g of ammonia solution and 0.2 g of hydroxyethyl cellulose (Natrosol 250HX, Ashland) and cooling the mixture to room temperature. 8) Adjust the final pH of the suspension to 4.0 ± 0.2 with the citric acid solution.

[0121] The volume-average capsule size distribution obtained by light scattering measurements using a Malvern 2000S instrument: the volume-median diameter D(50) and D(90) values ​​are reported in Table 1. Colloidal stability was assessed visually by assessing the absence of microcapsule aggregates in the samples, the formation of which is characterized by the appearance of white flocs visible to the human eye.

[0122] [Table 1]

[0123] (1) Merquat 281 is polyquaternium 22 (poly(acrylic acid-co-dimethyldiallylammonium chloride) copolymer) available from Merck. (2) Merquat 100 is polyquaternium 6 (poly(diallyldimethylammonium chloride) homopolymer) available from Merck. (3) Merquat 740 is polyquaternium 7 (poly(acrylamide-co-diallyldimethylammonium chloride) copolymer) available from Merck. (4) Merquat 2001 is polyquaternium 47 (poly(acrylic acid-co-methacrylamidopropyltrimethylammonium chloride-co-methylacrylate) copolymer) available from Merck.

[0124] These results show that microcapsules with a nominal molar ratio of amino and quaternary ammonium groups to carboxylic acid groups of 1.03 and 1.05, respectively (samples 1.2 and 1.8), are colloidally stable in both cationic softeners and liquid detergents. Among these samples, the one using the amphoteric copolymer Merquat 281 is particularly preferred because the microcapsules obtained using this copolymer have a lower polydispersity than those using Merquat 740. It is expected that the average molecular weight of Merquat 740 will be beyond the range where the desired particle size and particle polydispersity are obtained.

[0125] Comparative Example 1.1 (WO 2019 / 121736 A1, Example 4) has a low nominal molar ratio of amino groups and quaternary ammonium groups to carboxylic acid groups. The corresponding capsules are colloidally unstable in products containing cationic surfactants.

[0126] Comparative Example 1.3 has a nominal molar ratio of amino and quaternary ammonium groups to carboxylic acid groups slightly above the limit of 1.1. The corresponding capsules are colloidally unstable in products with both anionic surfactants and a moderately alkaline pH, such as pouch liquid detergents (pH approx. 8).

[0127] Comparative Examples 1.4 and 1.7 were obtained using cationic homopolymers, the corresponding microcapsules forming agglomerates in the slurry, demonstrating that homopolymers are less preferred for the present invention than copolymers consisting of non-cationic comonomers.

[0128] Comparative Examples 1.6 and 1.9 show that Merquat 2001 increases the slurry viscosity and is therefore not suitable for the purposes of the present invention. Furthermore, the molar fraction of cationic moieties in this polymer (31%) is lower than that of carboxyl moieties (69%). As a result, a nominal molar ratio of amino and / or quaternary ammonium groups to carboxylic acid groups greater than 0.7 is not feasible with this polymer.

Claims

1. An encapsulated composition comprising at least one core-shell microcapsule, the at least one core-shell microcapsule comprising a core containing at least one perfume ingredient and a shell surrounding the core, the shell comprising a thermosetting resin formed by the reaction of a polyfunctional amine containing at least one amino group with at least one polyfunctional isocyanate; the shell further comprises a cationic polymer comprising quaternary ammonium groups; the shell further comprises a polymeric stabilizer comprising fully or partially dissociated carboxylic acid groups; The encapsulated composition as described above, characterized in that the nominal molar ratio of amino groups and quaternary ammonium groups to carboxylic acid groups is 0.9 to 1.1, preferably 0.95 to 1.08, and more preferably 1.00 to 1.

06.

2. 2. The encapsulated composition of claim 1, wherein the at least one polyfunctional isocyanate comprises, or preferably consists of, an anionic modified polyisocyanate (A) selected from anionic modified hexamethylene diisocyanate, anionic modified isophorone diisocyanate, anionic modified dicyclohexylmethane-4,-4'-diisocyanate, anionic modified isocyanurates of hexamethylene diisocyanate, and mixtures thereof, and a nonionic polyisocyanate (B) selected from hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, isocyanurates of hexamethylene diisocyanate, and mixtures thereof.

3. The encapsulated composition according to claim 2, wherein the weight ratio of the anionic modified polyisocyanate (A) to the nonionic polyisocyanate (B) is in the range of 0.05 to 0.5, preferably 0.07 to 0.

25.

4. 10. The encapsulated composition of claim 1, wherein the polyfunctional amine comprises, preferably consists of, at least one polyethyleneimine.

5. The encapsulated composition of claim 1, wherein the weight ratio of polyfunctional amine to polyfunctional isocyanate is from 0.05 to 1, preferably from 0.1 to 0.5, and even more preferably from 0.15 to 0.

25.

6. 10. The encapsulated composition of claim 1, wherein the polymeric stabilizer is formed by a combination of a polymeric surfactant containing carboxylic acid groups and at least one aminosilane, preferably 3-aminopropyltriethoxysilane and at least one of poly(ethylene-co-maleic anhydride) and poly(styrene-co-maleic anhydride).

7. The encapsulated composition of claim 1, wherein the weight ratio of polymeric stabilizer to thermosetting resin is 0.4 to 0.9, preferably 0.45 to 0.

75.

8. The encapsulated composition of claim 1 , wherein the cationic polymer is a block copolymer comprising a quaternary ammonium group and at least one comonomer that is not cationic.

9. Cationic polymers include polyquaternium-2 (poly(bis[2-chloroethyl]ether-alt-1,3-bis[3-(dimethylamino)propyl]urea) copolymer), polyquaternium-4 (hydroxyethyl cellulose dimethyldiallylammonium chloride copolymer), polyquaternium-5 (poly(acrylamide-b-methacrylyloxyethyltrimethylammonium methosulfate) copolymer), polyquaternium-6 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-7 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-8 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-9 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-10 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-11 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-12 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-13 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-14 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-15 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-16 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-17 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-18 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-19 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-20 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-21 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-22 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-23 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-24 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-25 (poly(diallyldimethylammonium chloride) homopolymer), polyquaternium-26 (poly(diallyldimethylammonium chloride Polyquaternium-7 (poly(acrylamide-co-diallyldimethyl-ammonium chloride) copolymer), Polyquaternium-9 (poly(methacryloyloxyethyltrimethylammonium bromide) homopolymer), Polyquaternium-10 (hydroxyethyl cellulose-2-hydroxyethyltrimethylammonium chloride copolymer), Polyquaternium-11 (poly(vinylpyrrolidone-co-dimethylaminoethyl methacrylate) copolymer), Polyquaternium-12 (poly(ethyl methacrylate-co-abietyl methacrylate) acrylate-co-methacrylyloxyethyltrimethylammonium dimethyl sulfate) terpolymer), Polyquaternium-13 (poly(ethyl methacrylate-co-oleyl methacrylate-co-methacrylyloxyethyltrimethylammonium dimethyl sulfate) terpolymer), Polyquaternium-14 (poly(methacryloyloxy)-ethyl-N,N,N-trimethylammonium methosulfate) homopolymer), Polyquaternium-15 (poly(acrylamide-co-methacrylyloxyethyl Polyquaternium-16 (poly(vinylpyrrolidone-co-vinylimidazanium chloride) terpolymer), Polyquaternium-17 (adipic acid, dimethylaminopropylamine, and dichloroethylether terpolymer), Polyquaternium-18 (azelaic acid, dimethylaminopropylamine, and dichloroethylether terpolymer), Polyquaternium-19 (quaternized copolymer of poly(vinyl alcohol) and 2,3-epoxy-propylamine copolymer),Polyquaternium-22 (poly(acrylic acid-co-dimethyldiallylammonium chloride) copolymer), Polyquaternium-28 (poly(vinylpyrrolidone-co-methacylamidopropyltrimethylammonium chloride) copolymer), Polyquaternium-29 (chitosan modified with 2,3-dihydroxypropyl-2-hydroxy-3-(trimethylammonio)propyl ether, chloride), Polyquaternium-32 (poly(acrylamide-co-methacryloyloxyethyltrimethylammonium chloride) copolymer), Polymer), Polyquaternium-33 (Poly(acrylamide-co-acryloyloxyethyltrimethylammonium chloride) copolymer), Polyquaternium-34 (1,3-dibromopropane and N,N-diethyl-N',N'-dimethyl-1,3-propanediamine copolymer), Polyquaternium-35 (Poly(methacryloyloxyethyltrimethylammonium-co-methacryloyloxyethyldimethylacetylammonium methosulfate) copolymer), Polyquaternium-36 (Poly(butyl methacrylate) Polyquaternium-37 (poly(methacryloyloxyethyltrimethylammonium chloride) homopolymer), Polyquaternium-39 (poly(acrylic acid-co-acrylamide-co-diallyl-dimethylammonium chloride) terpolymer), Polyquaternium-42 (poly[oxyethylene(dimethylimino)ethylene(dimethylimino)ethylene dichloride] copolymer), Polyquaternium-43 (poly(acrylamide-co-acrylamidopropyltrimethylammonium chloride-co-2-amidopropylacrylamidosulfonate-co-dimethylaminopropylamine) copolymer), Polyquaternium-44 (poly(vinylpyrrolidone-co-imidazolinium) copolymer), Polyquaternium-45 (poly([N-methyl-N-ethoxyglycine]-methacrylate-co-methacryloyloxyethyl-trimethylammonium dimethyl sulfate) copolymer),The encapsulated composition of claim 1, wherein the encapsulating agent is selected from the group consisting of Polyquaternium-46 (poly(vinylcaprolactam-co-vinylpyrrolidone-co-vinylimidazolium methosulfate) terpolymer) and Polyquaternium-47 (poly(acrylic acid-co-methacrylamidopropyltrimethylammonium chloride-co-methylacrylate) terpolymer; preferably Polyquaternium-22 (poly(acrylic acid-co-dimethyldiallylammonium chloride) copolymer) and Polyquaternium-39 (poly(acrylic acid-co-acrylamide-co-diallyl-dimethylammonium chloride) terpolymer).

10. 2. The encapsulated composition of claim 1, wherein the level of shell material in the at least one core-shell microcapsule is from 2% to 25% by weight, preferably from 5% to 20% by weight, more preferably from 10% to 15% by weight, based on the total weight of the at least one core-shell microcapsule.

11. 2. The encapsulated composition of claim 1, comprising a plurality of core-shell microcapsules, wherein the microcapsules have a median diameter by volume Dv(50) of 1 to 50 μm, preferably 5 to 35 μm, and even more preferably 8 to 20 μm.

12. 10. The encapsulated composition of claim 1 in the form of a slurry, wherein the core-shell microcapsules are dispersed or suspended in an aqueous phase.

13. The encapsulated composition of claim 12, wherein the slurry has a solids content of 20% to 60% by weight, preferably 35% to 45% by weight.

14. A method for obtaining an encapsulated composition, in particular a composition according to any one of claims 1 to 13, comprising the following steps: a) providing a core composition comprising an aminosilane; b) providing an aqueous phase comprising at least one polymeric surfactant containing fully or partially dissociated carboxylic acid groups; c) emulsifying the core composition provided in step a) in the aqueous phase provided in step b) to obtain an emulsion of core composition droplets dispersed in the aqueous phase; d) reacting the aminosilane and polymeric surfactant to form a polymeric stabilizer that stabilizes the dispersed oil droplets; e) adding at least one polyfunctional isocyanate; f) adding at least one polyfunctional amine containing at least one amino group; and g) reacting a polyfunctional isocyanate and a polyfunctional amine to form a slurry of core-shell microcapsules, forming a shell around the core composition droplets; Including, wherein the cationic polymer containing quaternary ammonium groups is added before, during or after step g), preferably before or during step g); and Here, the nominal molar ratio of amino groups and quaternary ammonium groups to carboxylic acid groups is 0.8 to 1.1, preferably 0.9 to 1.08, and more preferably 1.00 to 1.

06. The method.

15. Use of an encapsulation composition according to any one of claims 1 to 13 to obtain a consumer product free of agglomerates of microcapsules.

16. 14. A consumer product comprising the encapsulated composition of any one of claims 1 to 13, wherein the consumer product comprises at least one cationic surfactant in a consumer product base, and wherein the consumer product is preferably a fabric care conditioner or a hair care conditioner.

17. 17. The consumer product of claim 16, wherein the at least one cationic surfactant is a quaternized triethanolamine ester selected from the group consisting of quaternized triethanolamine monoesters, quaternized triethanolamine diesters, and quaternized triethanolamine triesters.

18. 17. The consumer product according to claim 16, wherein the amount of the at least one cationic surfactant is 0.5 to 15 wt.-%, preferably 1.0 wt.-% to 10 wt.-%, more preferably 1.5 to 8.0 wt.-%, even more preferably 2.0 to 4.0 wt.-%, based on the total weight of the consumer product.

19. A consumer product as described in claim 17, wherein the level of the encapsulated composition is 0.01 to 5 wt%, preferably 0.05 to 2.5 wt%, more preferably 0.1 to 2.0 wt%, and even more preferably 0.1 to 1.5 wt%, based on the total weight of the consumer product.