Light-emitting device and display device including the same
Patent Information
- Application Number
- JP2024037425
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2023-08-23
- Filing Date
- 2024-03-11
- Publication Date
- 2025-03-07
AI Technical Summary
【0027】 本発明の実施形態によると、効率及びロールオフ特性が改善された発光素子及びそれを含む表示装置を提供することができる。
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Figure 2025031491000001_ABST
Abstract
Description
[Technical field]
[0001] The present invention relates to a light-emitting element and a display device including the same. [Background technology]
[0002] 2. Description of the Related Art With the development of information technology, the importance of display devices, which are a connecting medium between users and information, is becoming more and more apparent. [Prior art documents] [Patent documents]
[0003] [Patent Document 1] Korean Patent Application Publication No. 2010-0073785
[0004] The display device includes a plurality of light emitting elements that emit light when holes and electrons injected from an anode electrode and a cathode electrode are recombined in an emission layer to generate excitons, which are converted from an excited state to a ground state. Summary of the Invention [Problem to be solved by the invention]
[0005] It is an object of the present invention to provide a light emitting device having improved efficiency and roll-off characteristics and a display device including the same.
[0006] However, the object of the present invention is not limited to the above object, and can be variously expanded within the scope of the concept and scope of the present invention. [Means for solving the problem]
[0007] According to an embodiment, the light-emitting device includes an anode electrode, a cathode electrode facing the anode electrode, and a light-emitting structure disposed between the anode electrode and the cathode electrode, the light-emitting structure including a first light-emitting unit, a charge generation layer, and a second light-emitting unit. The second light-emitting unit may include a second hole transport unit disposed on the charge generation layer, a second light-emitting layer disposed on the second hole transport unit, an intermediate layer disposed on the second light-emitting layer, a third light-emitting layer disposed on the intermediate layer, and a second electron transport unit disposed between the third light-emitting layer and the cathode electrode.
[0008] The first light-emitting section may include a first hole transport section disposed on the anode electrode, a first electron transport section facing the first hole transport section and adjacent to the charge generation layer, and a first light-emitting layer disposed between the first hole transport section and the first electron transport section.
[0009] The second light-emitting layer, the intermediate layer, and the third light-emitting layer may have a total thickness of 30 to 50 nm.
[0010] The intermediate layer may have a thickness of 0.5 to 3 nm.
[0011] The LUMO energy level of the intermediate layer may be higher than the LUMO energy level of the third light-emitting layer.
[0012] The LUMO energy level of the intermediate layer may be less than 1.5 eV.
[0013] The intermediate layer may include a compound having at least one of a carbazole group and a triphenylamine group.
[0014] The first light emitting layer can emit blue light, the second light emitting layer can emit red light, and the third light emitting layer can emit green light.
[0015] The first light-emitting layer may include a blue fluorescent host and a blue fluorescent dopant.
[0016] The second emitting layer may include a red hole-transporting host, a red electron-transporting host, and a red phosphorescent dopant, and the third emitting layer may include a green hole-transporting host, a green electron-transporting host, and a green phosphorescent dopant.
[0017] The charge generation layer may include an n-type charge generation layer adjacent to the first light emitting portion and a p-type charge generation layer adjacent to the second light emitting portion.
[0018] The device may further include a capping layer disposed on the cathode electrode.
[0019] According to an embodiment, the light emitting device includes an anode electrode, a cathode electrode facing the anode electrode, and a light emitting structure disposed between the anode electrode and the cathode electrode, the light emitting structure including a first light emitting unit, a charge generation layer, and a second light emitting unit, the second light emitting unit including a second hole transport unit disposed on the charge generation layer, a second electron transport unit facing the second hole transport unit and adjacent to the cathode electrode, and a second light emitting layer and a third light emitting layer disposed between the second hole transport unit and the second electron transport unit, and the second light emitting layer may include a red bipolar host and a red phosphorescent dopant.
[0020] The second light-emitting layer may be disposed between the second hole transporting portion and the third light-emitting layer, and the third light-emitting layer may be disposed between the second light-emitting layer and the second electron transporting portion.
[0021] The third light-emitting layer may include a green hole-transporting host, a green electron-transporting host, and a green phosphorescent dopant.
[0022] The LUMO energy level of the red bipolar host can be higher than the LUMO energy level of the green electron transporting host.
[0023] The LUMO energy level of the red bipolar host may be less than 1.9 eV.
[0024] The first light-emitting section may include a first hole transport section disposed on the anode electrode, a first electron transport section facing the first hole transport section and adjacent to the charge generation layer, and a first light-emitting layer disposed between the first hole transport section and the first electron transport section.
[0025] A display device according to an embodiment may include the light emitting device.
[0026] The display device may include any one of a flat panel display, a curved display, a flexible display, a rollable display, a foldable display, a stretchable display, a head-up display, a head-mounted display, a wearable display, a microdisplay, a 3D display, a virtual reality display, an augmented reality display, and a mixed reality display. Effect of the Invention
[0027] According to an embodiment of the present invention, a light emitting device having improved efficiency and roll-off characteristics and a display device including the same can be provided.
[0028] However, the effects of the present invention are not limited to the above-mentioned effects, and can be variously expanded within the scope of the concept and scope of the present invention. [Brief description of the drawings]
[0029] [Figure 1] FIG. 1 illustrates a display device according to an embodiment. [Diagram 2] FIG. 2 illustrates a sub-pixel according to one embodiment. [Diagram 3] FIG. 2 illustrates a display panel according to one embodiment. [Figure 4] FIG. 4 is an exploded perspective view showing a part of the display panel of FIG. [Diagram 5] FIG. 5 illustrates an embodiment of one of the pixels of FIG. [Figure 6] FIG. 5 illustrates an embodiment of one of the pixels of FIG. [Figure 7] FIG. 5 is a plan view illustrating one embodiment of the pixels of FIG. [Figure 8] 6 is a cross-sectional view taken along line II' in FIG. 5. [Figure 9] FIG. 2 illustrates a light emitting device according to an embodiment. [Figure 10] 10 is a diagram illustrating the light emission principle of the light emitting element of FIG. [Figure 11] 10 is a diagram illustrating the distribution of excitons according to the position of the light emitting element in FIG. 9 by gray scale. [Figure 12] FIG. 2 illustrates a light emitting device according to an embodiment. [Figure 13] 13 is a diagram illustrating the light emission principle of the light emitting element of FIG. 12. [Figure 14] 13 is a diagram showing the distribution of excitons by gray scale depending on the position of the light emitting element in FIG. 12. [Figure 15] FIG. 13 is a graph showing red light efficiency according to current density for each light emitting element. [Figure 16] FIG. 11 is a graph showing current density as a function of driving voltage for each light-emitting element. [Figure 17] FIG. 2 illustrates a light emitting device according to an embodiment. [Figure 18] 18 is a diagram illustrating the light emission principle of the light emitting element of FIG. 17. [Figure 19] 18 is a diagram showing the distribution of excitons by gray scale depending on the position of the light emitting element in FIG. 17. [Figure 20] FIG. 13 is a graph showing red light efficiency according to current density for each light emitting element. [Figure 21] FIG. 11 is a graph showing current density as a function of driving voltage for each light-emitting element. [Figure 22] FIG. 1 illustrates a display system according to one embodiment. [Figure 23] FIG. 23 is a diagram showing an application example of the display system of FIG. 22. [Figure 24] FIG. 24 is a diagram showing a head-mounted display device worn by the user of FIG. 23. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0030] Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings. Please note that in the following description, only parts necessary for understanding the operation of the present invention will be described, and descriptions of other parts will be omitted so as not to make the gist of the present invention unclear. In addition, the present invention is not limited to the embodiments described herein, and may be embodied in other forms. However, the embodiments described herein are provided in detail to the extent that those skilled in the art to which the present invention pertains can easily implement the technical ideas of the present invention.
[0031] Throughout the specification, when a part is said to be "connected" to another part, this includes not only the case where the part is "directly connected" to the other part, but also the case where the part is "indirectly connected" to the other part through another element therebetween. The terms used herein are for describing a particular embodiment, and are not intended to limit the present invention. Throughout the specification, when a part "includes" a certain component, this means that the part may further include the other component, not excluding the other component, unless otherwise specified. "At least one of X, Y, and Z" and "at least one selected from the group consisting of X, Y, and Z" can be interpreted as one X, one Y, one Z, or any combination of two or more of X, Y, and Z (e.g., XYZ, XYY, YZ, ZZ). Here, "and / or" includes all combinations of one or more of the relevant components.
[0032] Here, terms such as first, second, etc. may be used to describe various components, but these components are not limited to these terms. These terms are used to distinguish one component from another. Thus, a first component can refer to a second component without departing from the scope of the disclosure herein.
[0033] Spatially relative terms such as "below," "above," and the like may be used for purposes of description and describe the relationship of one element or feature to another element or feature as depicted in the drawings. Spatially relative terms include the orientation depicted in the drawings as well as different orientations during use, operation, and / or manufacture. For example, if a device depicted in the drawings is flipped over, an element depicted as being "below" another element or feature would be in an orientation "above" the other element or feature. Thus, the term "below" in one embodiment can include both an orientation of above and below. Additionally, a device may be otherwise oriented (e.g., rotated 90 degrees or at other orientations) and the spatially relative terms used herein should be interpreted accordingly.
[0034] Various embodiments are described with reference to drawings that illustrate idealized embodiments. As such, the shapes may vary depending on, for example, tolerances and / or manufacturing techniques. Thus, the embodiments disclosed herein should not be construed as limited to the particular shapes shown, but should be construed to include, for example, variations in shapes that occur as a result of manufacturing. As such, the shapes shown in the drawings may not depict the actual shapes of regions of a device, and the embodiments are not limited thereto.
[0035] Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.
[0036] FIG. 1 is a diagram showing a display device according to an embodiment.
[0037] Referring to FIG. 1, a display device 100 may include a display panel 110, a gate driver 120, a data driver 130, a voltage generator 140, and a controller 150.
[0038] The display panel 110 includes sub-pixels SP. The sub-pixels SP may be connected to a gate driver 120 via a first gate line GL1 to an m-th gate line GLm. The sub-pixels SP may be connected to a data driver 130 via a first data line DL1 to an n-th data line DLn, where m and n are natural numbers.
[0039] Each of the sub-pixels SP may include at least one light-emitting element configured to generate light. Thus, each of the sub-pixels SP may generate light of a particular color, such as red, green, blue, cyan, magenta, or yellow. Two or more of the sub-pixels SP may constitute one pixel PXL. For example, three sub-pixels may constitute one pixel PXL as shown in FIG. 1.
[0040] The gate driver 120 is connected to the sub-pixels SP arranged in the row direction via the first gate line GL1 to the m-th gate line GLm. The gate driver 120 can output gate signals to the first gate line GL1 to the m-th gate line GLm in response to a gate control signal GCS. In the embodiment, the gate control signal GCS may include a start signal indicating the start of each frame, a horizontal synchronization signal for outputting a gate signal in synchronization with the timing at which a data signal is applied, and the like.
[0041] In the embodiment, the first light emission control line EL1 to the m-th light emission control line ELm connected to the row-direction sub-pixels SP may be further provided. In this case, the gate driver 120 may include a light emission control driver configured to control the first light emission control line EL1 to the m-th light emission control line ELm, and the light emission control driver may operate according to the control of the controller 150.
[0042] The gate driver 120 may be disposed on one side of the display panel 110, but the embodiment is not limited thereto. For example, the gate driver 120 may be divided into two or more physically and / or logically divided drivers, and the drivers may be disposed on one side of the display panel 110 and on another side of the display panel 110 opposite the one side. In this manner, the gate driver 120 may be disposed around the display panel 110 in various forms depending on the embodiment.
[0043] The data driver 130 is connected to the sub-pixels SP arranged in a column direction via the first data line DL1 to the n-th data line DLn. The data driver 130 receives video data DATA and a data control signal DCS from the controller 150. The data driver 130 operates in response to the data control signal DCS. In an embodiment, the data control signal DCS may include a source start pulse, a source shift clock, a source output enable signal, etc.
[0044] The data driver 130 can apply a data signal having a gray scale voltage corresponding to the image data DATA to the first data line DL1 to the n-th data line DLn using a voltage from the voltage generator 140. When a gate signal is applied to each of the first gate line GL1 to the m-th gate line GLm, a data signal corresponding to the image data DATA can be applied to the data lines DL1 to DLm. This allows the corresponding sub-pixel SP to emit light corresponding to the data signal. This allows an image to be displayed on the display panel 110.
[0045] In an embodiment, the gate driver 120 and the data driver 130 may include complementary metal-oxide semiconductor (CMOS) circuit elements.
[0046] The voltage generator 140 can operate in response to a voltage control signal VCS from the controller 150. The voltage generator 140 is configured to generate a plurality of voltages and provide the generated voltages to the components of the display device 100. For example, the voltage generator 140 may be configured to receive an input voltage from outside the display device 100, adjust the received voltage, and generate a plurality of voltages by regulating the regulated voltage.
[0047] The voltage generator 140 may generate a first power supply voltage VDD and a second power supply voltage VSS, and the generated first and second power supply voltages VDD and VSS may be provided to the sub-pixels SP. The first power supply voltage VDD may have a relatively high voltage level, and the second power supply voltage VSS may have a voltage level lower than the first power supply voltage VDD. In other embodiments, the first power supply voltage VDD or the second power supply voltage VSS may be provided by an external device of the display device 100.
[0048] In addition, the voltage generator 140 may generate various voltages. For example, the voltage generator 140 may generate an initialization voltage to be applied to the sub-pixel SP. For example, during a sensing operation for sensing electrical characteristics of the transistors and / or light emitting elements of the sub-pixel SP, a predetermined reference voltage may be applied to the first data line DL1 to the n-th data line DLn, and the voltage generator 140 may generate such a reference voltage.
[0049] The controller 150 controls various operations of the display device 100. The controller 150 receives input image data IMG from the outside and a control signal CTRL for controlling the display of the input image data IMG. The controller 150 can provide a gate control signal GCS, a data control signal DCS, and a voltage control signal VCS in response to the control signal CTRL.
[0050] The controller 150 may convert the input image data IMG to be compatible with the display device 100 or the display panel 110, and output the image data DATA. In an embodiment, the controller 150 may align the input image data IMG to be compatible with the sub-pixels SP arranged in rows, and output the image data DATA.
[0051] Two or more of the data driver 130, the voltage generator 140, and the controller 150 may be implemented in one integrated circuit. As shown in FIG. 1, the data driver 130, the voltage generator 140, and the controller 150 may be included in a driver integrated circuit DIC. In this case, the data driver 130, the voltage generator 140, and the controller 150 may be functionally separate components within a single driver integrated circuit DIC. In other embodiments, at least one of the data driver 130, the voltage generator 140, and the controller 150 may be provided as a separate component from the driver integrated circuit DIC.
[0052] The display device 100 may include at least one temperature sensor 160. The temperature sensor 160 is configured to sense a temperature in its surroundings and generate temperature data TEP indicative of the sensed temperature. In an embodiment, the temperature sensor 160 may be disposed adjacent to the display panel 110 and / or the driver integrated circuit DIC.
[0053] The controller 150 may control various operations of the display device 100 in response to the temperature data TEP. In an embodiment, the controller 150 may adjust the brightness of an image output from the display panel 110 in response to the temperature data TEP. For example, the controller 150 may adjust the data signals and the first and second power supply voltages VDD and VSS by controlling components such as the data driver 130 and / or the voltage generator 140.
[0054] In one embodiment, the display device 100 may include any one of a flat panel display, a curved display, a flexible display, a rollable display, a foldable display, a stretchable display, a head-up display, a head-mounted display, a wearable display, a micro display, a 3D display, a virtual reality display, an augmented reality display, and a mixed reality display.
[0055] 2 is a diagram illustrating a sub-pixel according to an embodiment, in which a sub-pixel SPij arranged in the i-th row (i is an integer greater than or equal to 1 and less than or equal to m) and j-th column (j is an integer greater than or equal to 1 and less than or equal to n) of the sub-pixel SP in FIG.
[0056] Referring to FIG. 2, the sub-pixel SPij may include a sub-pixel circuit SPC and a light-emitting element LD.
[0057] The light emitting element LD is connected between a first power supply voltage node VDDN and a second power supply voltage node VSSN. At this time, the first power supply voltage node VDDN is a node that transmits the first power supply voltage VDD in FIG. 1, and the second power supply voltage node VSSN is a node that transmits the second power supply voltage VSS in FIG. 1.
[0058] The anode electrode AE of the light emitting element LD may be connected to the first power supply voltage node VDDN via the sub-pixel circuit SPC, and the cathode electrode CE of the light emitting element LD may be connected to the second power supply voltage node VSSN. For example, the anode electrode AE of the light emitting element LD may be connected to the first power supply voltage node VDDN via one or more transistors included in the sub-pixel circuit SPC.
[0059] The sub-pixel circuit SPC may be connected to the ith gate line GLi among the first gate line GL1 to the mth gate line GLm in Fig. 1, the ith light-emitting control line ELi among the first light-emitting control line EL1 to the mth light-emitting control line ELm in Fig. 1, and the jth data line DLj among the first data line DL1 to the nth data line DLn in Fig. 1. The sub-pixel circuit SPC is configured to control the light-emitting element LD in response to signals received via such signal lines.
[0060] The sub-pixel circuit SPC can operate in response to a gate signal received via an ith gate line GLi. The ith gate line GLi may include one or more sub-gate lines. In an embodiment, as shown in FIG. 2, the ith gate line GLi may include a first sub-gate line SGL1 and a second sub-gate line SGL2. The sub-pixel circuit SPC can operate in response to a gate signal received via the first sub-gate line SGL1 and the second sub-gate line SGL2. In this way, when the ith gate line GLi includes two or more sub-gate lines, the sub-pixel circuit SPC can operate in response to a gate signal received via the corresponding sub-gate line.
[0061] The sub-pixel circuit SPC can operate in response to a light emission control signal received via an i-th light emission control line ELi. In an embodiment, the i-th light emission control line ELi may include one or more sub-light emission control lines. When the i-th light emission control line ELi includes two or more sub-light emission control lines, the sub-pixel circuit SPC can operate in response to a light emission control signal received via the corresponding sub-light emission control line.
[0062] The sub-pixel circuit SPC may receive a data signal via the j-th data line DLj. The sub-pixel circuit SPC may store a voltage corresponding to the data signal in response to at least one of the gate signals received via the first sub-gate line SGL1 and the second sub-gate line SGL2. The sub-pixel circuit SPC may adjust a current flowing from the first power supply voltage node VDDN to the second power supply voltage node VSSN via the light emitting element LD in response to the stored voltage in response to the light emitting control signal received via the ith light emitting control line ELi. This allows the light emitting element LD to generate light with a brightness corresponding to the data signal.
[0063] FIG. 3 is a diagram showing a display panel according to an embodiment.
[0064] 3, an embodiment of the display panel 110 of FIG. 1 may include a display area DA and a non-display area NDA. The display panel DP displays an image through the display area DA. The non-display area NDA is disposed around the display area DA.
[0065] The display panel DP may include a substrate SUB, sub-pixels SP, and pads PD.
[0066] When the display panel DP is used as a display screen for a head mounted display device (HMD), a virtual reality (VR) device, a mixed reality (MR) device, an augmented reality (AR) device, or the like, the display panel DP may be located very close to a user's eyes. In this case, sub-pixels SP with a relatively high degree of integration are required. In order to increase the integration degree of the sub-pixels SP, the substrate SUB may be provided as a silicon substrate. The sub-pixels SP and / or the display panel DP may be formed on the substrate SUB, which is a silicon substrate. A display device 100 (see FIG. 1) including a display panel DP formed on the substrate SUB, which is a silicon substrate, may be referred to as an OLEDoS (OLED on Silicon) display device.
[0067] The sub-pixels SP are disposed in a display area DA on a substrate SUB. The sub-pixels SP may be arranged in a matrix shape along a first direction DR1 and a second direction DR2 intersecting the first direction DR1. However, the embodiment is not limited thereto. For example, the sub-pixels SP may be arranged in a zigzag shape along the first direction DR1 and the second direction DR2. For example, the sub-pixels SP may be arranged in a pentile (PENTILE) shape. TM The first direction DR1 may be the row direction, and the second direction DR2 may be the column direction.
[0068] Two or more of the sub-pixels SP can form one pixel PXL.
[0069] Components for controlling the sub-pixels SP may be arranged in the non-display area NDA on the substrate SUB. For example, wirings connected to the sub-pixels SP, such as the first gate line GL1 to the m-th gate line GLm and the first data line DL1 to the n-th data line DLn in FIG. 1, may be arranged in the non-display area NDA.
[0070] At least one of the gate driver 120, the data driver 130, the voltage generator 140, the controller 150, and the temperature sensor 160 in Fig. 1 may be integrated in the non-display area NDA of the display panel DP. In an embodiment, the gate driver 120 in Fig. 1 is implemented in the display panel DP, but may be disposed in the non-display area NDA. In another embodiment, the gate driver 120 may be embodied as an integrated circuit separate from the display panel DP. In an embodiment, the temperature sensor 160 may be disposed in the non-display area NDA to detect the temperature of the display panel DP.
[0071] The pads PD are arranged in the non-display area NDA on the substrate SUB. The pads PD may be electrically connected to the sub-pixels SP via wiring. For example, the pads PD may be connected to the sub-pixels SP via the first data line DL1 to the n-th data line DLn.
[0072] The pad PD may interface the display panel DP with other components of the display device 100 (see FIG. 1). In an embodiment, voltages and signals required for the operation of the components included in the display panel DP may be provided from the driver integrated circuit DIC of FIG. 1 via the pad PD. For example, the first data line DL1 to the n-th data line DLn may be connected to the driver integrated circuit DIC via the pad PD. For example, the first and second power supply voltages VDD and VSS may be received from the driver integrated circuit DIC via the pad PD. For example, when the gate driver 120 is implemented in the display panel DP, the gate control signal GCS may be transmitted from the driver integrated circuit DIC to the gate driver 120 via the pad PD.
[0073] In an embodiment, the circuit board may be electrically connected to the pads PD using a conductive adhesive member such as an anisotropic conductive film. In this case, the circuit board may be a flexible circuit board (FPCB) or a flexible film having a flexible material. The driver integrated circuit DIC may be mounted on the circuit board and electrically connected to the pads PD.
[0074] In the embodiment, the display area DA can have various shapes. The display area DA can be a closed loop with straight and / or curved sides. For example, the display area DA can have a polygonal, circular, semicircular, elliptical, etc.
[0075] In an embodiment, the display panel DP may have a flat display surface. In another embodiment, the display panel DP may have an at least partially round display surface. In an embodiment, the display panel DP may be bendable, foldable or rollable. In this case, the display panel DP and / or the substrate SUB may comprise a material having flexible properties.
[0076] Figure 4 is an exploded perspective view showing a portion of the display panel of Figure 3. For clarity and conciseness of explanation, Figure 4 shows only a schematic representation of the portion of the display panel DP corresponding to two pixels PXL1, PXL2 of the pixels PXL of Figure 3. The portions of the display panel DP corresponding to the remaining pixels can be similarly configured.
[0077] 3 and 4, each of the first and second pixels PXL1 and PXL2 may include a first sub-pixel SP1 to a third sub-pixel SP3. However, the embodiment is not limited thereto. For example, each of the first and second pixels PXL1 and PXL2 may include four sub-pixels or two sub-pixels.
[0078] 4, the first to third sub-pixels SP1 to SP3 are shown to have a rectangular shape when viewed in the first direction DR1 and the third direction DR3 intersecting the second direction DR2, and to have the same size. However, the embodiment is not limited thereto. The first to third sub-pixels SP1 to SP3 may be modified to have various shapes.
[0079] The display panel DP may include a substrate SUB, a pixel circuit layer PCL, a light emitting element layer LDL, a sealing layer TFE, an optical functional layer OFL, an overcoat layer OC, and a cover window CW.
[0080] In an embodiment, the substrate SUB may comprise a silicon wafer substrate formed using a semiconductor process. The substrate SUB may comprise a semiconductor material suitable for forming circuit elements. For example, the semiconductor material may comprise silicon, germanium, and / or silicon-germanium. The substrate SUB may be provided from a bulk wafer, an epitaxial layer, a silicon on insulator (SOI) layer, a semiconductor on insulator (SeOI) layer, or the like. In another embodiment, the substrate SUB may comprise a glass substrate. In yet another embodiment, the substrate SUB may comprise a polyimide (PI) substrate.
[0081] A pixel circuit layer PCL is disposed on a substrate SUB. The substrate SUB and / or the pixel circuit layer PCL may include an insulating layer and a conductive pattern disposed between the insulating layer. The conductive pattern of the pixel circuit layer PCL may function as at least a part of a circuit element, a wiring, etc. The conductive pattern may include copper, although the embodiment is not limited thereto.
[0082] The circuit element may include subpixel circuits SPC (see FIG. 2) of the first to third subpixels SP1 to SP3. The subpixel circuits SPC may include a transistor and one or more capacitors. Each transistor may include a semiconductor portion including a source region, a drain region, and a channel region, and a gate electrode superimposed on the semiconductor portion. In the embodiment, when a silicon substrate is provided as the substrate SUB, the semiconductor portion may be included in the substrate SUB, and the gate electrode may be included in the pixel circuit layer PCL as a conductive pattern of the pixel circuit layer PCL. In the embodiment, when a glass substrate or a PI substrate is provided as the substrate SUB, the semiconductor portion and the gate electrode may be included in the pixel circuit layer PCL. Each capacitor may include electrodes spaced apart from each other. For example, each capacitor may include electrodes spaced apart from each other on a plane defined by the first direction DR1 and the second direction DR2. For example, each capacitor may include electrodes spaced apart from each other in the third direction DR3 with an insulating layer sandwiched therebetween.
[0083] The wiring of the pixel circuit layer PCL may include signal lines, such as gate lines, emission control lines, and data lines, connected to each of the first to third sub-pixels SP1 to SP3. The wiring may further include a wiring connected to the first power supply voltage node VDDN in Fig. 2. The wiring may further include a wiring connected to the second power supply voltage node VSSN in Fig. 2.
[0084] The light emitting element layer LDL may include an anode electrode AE, a pixel defining layer PDL, a light emitting structure EMS, and a cathode electrode CE.
[0085] The anode electrode AE may be disposed on the pixel circuit layer PCL. The anode electrode AE may be in contact with a circuit element of the pixel circuit layer PCL. The anode electrode AE may include an opaque conductive material that can reflect light, but the embodiment is not limited thereto.
[0086] A pixel defining film PDL is disposed on the anode electrodes AE. The pixel defining film PDL may include openings OP exposing parts of the anode electrodes AE. The openings OP of the pixel defining film PDL may be understood as light emitting regions corresponding to the first to third sub-pixels SP1 to SP3, respectively.
[0087] In an embodiment, the pixel defining film PDL may include an inorganic material. In this case, the pixel defining film PDL may include a plurality of stacked inorganic layers. For example, the pixel defining film PDL may include silicon oxide (SiOx) and silicon nitride (SiNx). In another embodiment, the pixel defining film PDL may include an organic material. However, the material of the pixel defining film PDL is not limited thereto.
[0088] The light emitting structure EMS may be disposed on the anode electrode AE exposed by the opening OP of the pixel defining film PDL. The light emitting structure EMS may include a light emitting layer configured to emit light, an electron transport layer configured to transport electrons, and a hole transport layer configured to transport holes.
[0089] In the embodiment, the light emitting structure EMS fills the opening OP of the pixel defining film PDL, but may be entirely disposed on the upper part of the pixel defining film PDL. That is, the light emitting structure EMS may extend across the first sub-pixel SP1 to the third sub-pixel SP3. In this case, at least a part of a layer in the light emitting structure EMS may be cut or bent at the boundary between the first sub-pixel SP1 to the third sub-pixel SP3. However, the embodiment is not limited thereto. For example, the portions of the light emitting structure EMS corresponding to the first sub-pixel SP1 to the third sub-pixel SP3 may be separated from each other, and each of them may be disposed in the opening OP of the pixel defining film PDL.
[0090] The cathode electrode CE may be disposed on the light emitting structure EMS. The cathode electrode CE may extend across the first sub-pixel SP1 to the third sub-pixel SP3. In this manner, the cathode electrode CE may be provided as a common electrode for the first sub-pixel SP1 to the third sub-pixel SP3.
[0091] The cathode electrode CE may be a thin metal layer having a sufficient thickness to transmit light emitted from the light emitting structure EMS. The cathode electrode CE may be formed of a metal material or a transparent conductive material so as to have a relatively thin thickness. In an embodiment, the cathode electrode CE may include at least one of a variety of transparent conductive materials, including indium tin oxide, indium zinc oxide, indium tin zinc oxide, aluminum zinc oxide, gallium zinc oxide, zinc tin oxide, or gallium tin oxide. In another embodiment, the cathode electrode CE may include at least one of silver (Ag), magnesium (Mg), and mixtures thereof. However, the material of the cathode electrode CE is not limited thereto.
[0092] Any one of the anode electrodes AE, a portion of the light emitting structure EMS overlapping therewith, and a portion of the cathode electrode CE overlapping therewith may be understood as constituting one light emitting element LD (see FIG. 2). That is, each of the light emitting elements of the first subpixel SP1 to the third subpixel SP3 may include one anode electrode, a portion of the light emitting structure EMS overlapping therewith, and a portion of the cathode electrode CE overlapping therewith. In each of the first subpixel SP1 to the third subpixel SP3, holes injected from the anode electrode AE and electrons injected from the cathode electrode CE are transported into the light emitting layer of the light emitting structure EMS to form excitons, and when the excitons transition from the excited state to the ground state, light may be generated. The luminance of the light may be determined according to the amount of current flowing through the light emitting layer. The wavelength range of the generated light may be determined according to the configuration of the light emitting layer.
[0093] An encapsulation layer TFE is disposed on the cathode electrode CE. The encapsulation layer TFE may cover the light emitting element layer LDL and / or the pixel circuit layer PCL. The encapsulation layer TFE may be configured to prevent oxygen and / or moisture from penetrating into the light emitting element layer LDL. In an embodiment, the encapsulation layer TFE may include a structure in which one or more inorganic films and one or more organic films are alternately laminated. For example, the inorganic film may include silicon nitride, silicon oxide, silicon oxynitride (SiOxNy), or the like. For example, the organic film may include an organic insulating material such as an acrylic resin, an epoxy resin, a phenolic resin, a polyamide resin, a polyimides resin, an unsaturated polyesters resin, a polyphenylenes resin, a polyphenylenesulfides resin, or benzocyclobutene (BCB). However, the materials of the organic film and the inorganic film of the sealing layer TFE are not limited thereto.
[0094] In order to improve the sealing efficiency of the encapsulation layer TFE, the encapsulation layer TFE may further include a thin film containing aluminum oxide (AlOx). The thin film containing aluminum oxide may be located on an upper surface of the encapsulation layer TFE facing the optical function layer OFL and / or a lower surface of the encapsulation layer TFE facing the light emitting element layer LDL.
[0095] The thin film including aluminum oxide may be formed by an atomic layer deposition (ALD) method. However, the embodiment is not limited thereto. The encapsulation layer TFE may further include a thin film formed of at least one of various materials suitable for improving encapsulation efficiency.
[0096] The optical functional layer OFL is disposed on the encapsulation layer TFE. The optical functional layer OFL may include a color filter layer CFL and a lens array LA.
[0097] The color filter layer CFL is disposed between the sealing layer TFE and the lens array LA. The color filter layer CFL is configured to filter the light emitted from the light emitting structure EMS to selectively output light of a wavelength range or color corresponding to each sub-pixel. The color filter layer CFL includes color filters CF corresponding to the first to third sub-pixels SP1 to SP3, respectively, and each of the color filters CF can pass light of a wavelength range corresponding to the corresponding sub-pixel. For example, the color filter corresponding to the first sub-pixel SP1 can pass red light, the color filter corresponding to the second sub-pixel SP2 can pass green light, and the color filter corresponding to the third sub-pixel SP3 can pass blue light. At least a part of the color filters CF may be omitted depending on the light emitted from the light emitting structure EMS of each sub-pixel.
[0098] The lens array LA is disposed on the color filter layer CFL. The lens array LA may include lenses LS corresponding to the first to third sub-pixels SP1 to SP3, respectively. Each of the lenses LS may improve light emission efficiency by outputting light emitted from the light emitting structure EMS to an intended path. The lens array LA may have a relatively high refractive index. For example, the lens array LA may have a higher refractive index than the overcoat layer OC. In an embodiment, the lens LS may include an organic material. In an embodiment, the lens LS may include an acrylate material. However, the material of the lens LS is not limited thereto.
[0099] In the embodiment, at least a part of the color filters CF of the color filter layer CFL and at least a part of the lenses LS of the lens array LA may be shifted in a direction parallel to a plane defined by the first direction DR1 and the second direction DR2, compared with the apertures OP of the pixel definition film PDL. Specifically, in the central region of the display area DA, the centers of the color filters and the lenses may coincide with or overlap the centers of the apertures OP of the corresponding pixel definition film PDL when viewed from the third direction DR3. For example, in the central region of the display area DA, the apertures OP of the pixel definition film PDL may completely overlap the corresponding color filters of the color filter layer CFL and the corresponding lenses of the lens array LA. In a region of the display area DA adjacent to the non-display area NDA, the centers of the color filters and the lenses may be shifted in a planar direction from the centers of the apertures OP of the corresponding pixel definition film PDL when viewed from the third direction DR3. For example, in a region of the display area DA adjacent to the non-display area NDA, the apertures OP of the pixel definition film PDL may partially overlap the corresponding color filters of the color filter layer CFL and the corresponding lenses of the lens array LA. As a result, the light emitted from the light emitting structure EMS at the center of the display area DA can be efficiently output in the normal direction of the display surface, and the light emitted from the light emitting structure EMS at the periphery of the display area DA can be efficiently output in a direction inclined at a predetermined angle with respect to the normal direction of the display surface.
[0100] The overcoat layer OC may be disposed on the lens array LA. The overcoat layer OC may cover the optical function layer OFL, the encapsulation layer TFE, the light emitting structure EMS, and / or the pixel circuit layer PCL. The overcoat layer OC may include various materials suitable for protecting its underlying layers from foreign substances such as dust and moisture. For example, the overcoat layer OC may include at least one of an inorganic insulating film and an organic insulating film. For example, the overcoat layer OC may include epoxy, but the embodiment is not limited thereto. The overcoat layer OC may have a lower refractive index than the lens array LA.
[0101] A cover window CW may be disposed on the overcoat layer OC. The cover window CW is configured to protect the layers underneath. The cover window CW may have a higher refractive index than the overcoat layer OC. The cover window CW may include glass, but the embodiment is not limited thereto. For example, the cover window CW may be an encapsulation glass configured to protect the components disposed underneath. In other embodiments, the cover window CW may be omitted.
[0102] Figure 5 is a diagram illustrating one embodiment of the pixel of Figure 4. For clarity and conciseness, Figure 5 only illustrates a first pixel PXL1 of the first pixel PXL1 and the second pixel PXL2 of Figure 4. The remaining pixels may be configured similarly to the first pixel PXL1.
[0103] 4 and 5, the first pixel PXL1 may include a first sub-pixel SP1 to a third sub-pixel SP3 arranged in a first direction DR1.
[0104] The first sub-pixel SP1 may include a first light-emitting region EMA1 and a non-light-emitting region NEA around the first light-emitting region EMA1. The second sub-pixel SP2 may include a second light-emitting region EMA2 and a non-light-emitting region NEA around the second light-emitting region EMA2. The third sub-pixel SP3 may include a third light-emitting region EMA3 and a non-light-emitting region NEA around the third light-emitting region EMA3.
[0105] The first light-emitting region EMA1 may be a region where light is emitted from a portion of the light-emitting structure EMS (see FIG. 4) corresponding to the first sub-pixel SP1. The second light-emitting region EMA2 may be a region where light is emitted from a portion of the light-emitting structure EMS corresponding to the second sub-pixel SP2. The third light-emitting region EMA3 may be a region where light is emitted from a portion of the light-emitting structure EMS corresponding to the third sub-pixel SP3. As described with reference to FIG. 4, each light-emitting region can be understood as an opening OP of the pixel defining layer PDL corresponding to each of the first to third sub-pixels SP1 to SP3.
[0106] FIG. 6 illustrates an embodiment of any one of the pixels of FIG.
[0107] Referring to FIG. 6, the first pixel PXL1' may include a first sub-pixel SP1' to a third sub-pixel SP3'.
[0108] The first sub-pixel SP1' may include a first light-emitting region EMA1' and a non-light-emitting region NEA' around the first light-emitting region EMA1'. The second sub-pixel SP2' may include a second light-emitting region EMA2' and a non-light-emitting region NEA' around the second light-emitting region EMA2'. The third sub-pixel SP3' may include a third light-emitting region EMA3' and a non-light-emitting region NEA' around the third light-emitting region EMA3'.
[0109] The first sub-pixel SP1' and the second sub-pixel SP2' may be arranged in the second direction DR2. The third sub-pixel SP3' may be disposed in the first direction DR1 relative to each of the first sub-pixel SP1' and the second sub-pixel SP2'.
[0110] The second sub-pixel SP2' may have a larger area than the first sub-pixel SP1', and the third sub-pixel SP3' may have a larger area than the second sub-pixel SP2'. Thus, the second light-emitting region EMA2' may have a larger area than the first light-emitting region EMA1', and the third light-emitting region EMA3' may have a larger area than the second light-emitting region EMA2'. However, the embodiment is not limited thereto. For example, the first sub-pixel SP1' and the second sub-pixel SP2' may have substantially the same area, and the third sub-pixel SP3' may have a larger area than the first sub-pixel SP1' and the second sub-pixel SP2'. In this way, the areas of the first sub-pixel SP1' to the third sub-pixel SP3' may be variously modified according to the embodiment.
[0111] FIG. 7 is a plan view illustrating one embodiment of any one of the pixels of FIG.
[0112] Referring to FIG. 7, the first pixel PXL1'' may include a first sub-pixel SP1'' to a third sub-pixel SP3''.
[0113] The first subpixel SP1'' may include a first light-emitting region EMA1'' and a non-light-emitting region NEA'' around the first light-emitting region EMA1''. The second subpixel SP2'' may include a second light-emitting region EMA2'' and a non-light-emitting region NEA'' around the second light-emitting region EMA2''. The third subpixel SP3'' may include a third light-emitting region EMA3'' and a non-light-emitting region NEA'' around the third light-emitting region EMA3''.
[0114] The first to third subpixels SP1'' to SP3'' may have a polygonal shape when viewed from the third direction DR3. For example, the first to third subpixels SP1'' to SP3'' may have a hexagonal shape as shown in FIG.
[0115] The first light-emitting region EMA1'' to the third light-emitting region EMA3'' may have a circular shape when viewed from the third direction DR3. However, the embodiment is not limited thereto. For example, each of the first light-emitting region EMA1'' to the third light-emitting region EMA3'' may have a polygonal shape.
[0116] The first sub-pixel SP1″ and the third sub-pixel SP3″ may be arranged in the first direction DR1. The second sub-pixel SP2″ may be arranged in a direction inclined at an acute angle (or diagonally) with respect to the second direction DR2 with respect to the first sub-pixel SP1″.
[0117] The arrangements of the sub-pixels shown in Figures 5 to 7 are illustrative and are not intended to limit the scope of the present invention, and each pixel may include two or more sub-pixels, and the sub-pixels may be arranged in various ways, and each sub-pixel may have a different shape, and each of the light-emitting regions may have a different shape.
[0118] FIG. 8 is a cross-sectional view taken along line II' in FIG.
[0119] Referring to FIG. 8, a substrate SUB and a pixel circuit layer PCL disposed on the substrate SUB are provided.
[0120] The substrate SUB may include a silicon wafer substrate formed using a semiconductor process. For example, the substrate SUB may include silicon, germanium, and / or silicon-germanium.
[0121] A pixel circuit layer PCL is disposed on a substrate SUB. The substrate SUB and the pixel circuit layer PCL may include circuit elements of the first to third subpixels SP1 to SP3. For example, the substrate SUB and the pixel circuit layer PCL may include a transistor T_SP1 of the first subpixel SP1, a transistor T_SP2 of the second subpixel SP2, and a transistor T_SP3 of the third subpixel SP3. The transistor T_SP1 of the first subpixel SP1 may be any one of the transistors included in the subpixel circuit SPC of the first subpixel SP1 (see FIG. 2), the transistor T_SP2 of the second subpixel SP2 may be any one of the transistors included in the subpixel circuit SPC of the second subpixel SP2, and the transistor T_SP3 of the third subpixel SP3 may be any one of the transistors included in the subpixel circuit SPC of the third subpixel SP3. In FIG. 8, for clarity and conciseness, one of the transistors of each subpixel is shown, and the remaining circuit elements are omitted.
[0122] The transistor T_SP1 of the first sub-pixel SP1 may include a source region SRA, a drain region DRA, and a gate electrode GE.
[0123] The source region SRA and the drain region DRA may be disposed in a substrate SUB. A well WL formed through an ion implantation process may be disposed in the substrate SUB, and the source region SRA and the drain region DRA may be disposed apart from each other in the well WL. A region between the source region SRA and the drain region DRA in the well WL may be defined as a channel region.
[0124] The gate electrode GE may overlap the channel region between the source region SRA and the drain region DRA and may be disposed in the pixel circuit layer PCL. The gate electrode GE may be separated from the well WL or the channel region by an insulating material such as a gate insulating layer GI. The gate electrode GE may include a conductive material.
[0125] The layers included in the pixel circuit layer PCL include conductive patterns disposed between insulating layers, and the conductive patterns may include a first conductive pattern CP1 and a second conductive pattern CP2. The first conductive pattern CP1 may be electrically connected to the drain region DRA via a drain connection portion DRC that penetrates one or more insulating layers. The second conductive pattern CP2 may be electrically connected to the source region SRA via a source connection portion SRC that penetrates one or more insulating layers.
[0126] The gate electrode GE, the first conductive pattern CP1, and the second conductive pattern CP2 are connected to other circuit elements and / or wiring, so that the transistor T_SP1 of the first sub-pixel SP1 can be provided as any one of the transistors of the first sub-pixel SP1.
[0127] The transistor T_SP2 of the second sub-pixel SP2 and the transistor T_SP3 of the third sub-pixel SP3 may each be configured similarly to the transistor T_SP1 of the first sub-pixel SP1.
[0128] In this manner, the substrate SUB and the pixel circuit layer PCL may include circuit elements of each of the first to third sub-pixels SP1 to SP3.
[0129] A via layer VIAL is disposed on the pixel circuit layer PCL. The via layer VIAL covers the pixel circuit layer PCL and may have an overall flat surface. The via layer VIAL is configured to flatten steps on the pixel circuit layer PCL. The via layer VIAL may include at least one of silicon oxide (SiOx), silicon nitride (SiNx), and silicon carbon nitride (SiCN), but the embodiment is not limited thereto.
[0130] The light emitting element layer LDL is disposed on the via layer VIAL. The light emitting element layer LDL may include a first reflective electrode RE1 to a third reflective electrode RE3, a planarization layer PLNL, a first anode electrode AE1 to a third anode electrode AE3, a pixel defining layer PDL, a light emitting structure EMS, and a cathode electrode CE.
[0131] A first reflective electrode RE1 to a third reflective electrode RE3 are disposed on the via layer VIAL for the first sub-pixel SP1 to the third sub-pixel SP3, respectively. Each of the first reflective electrode RE1 to the third reflective electrode RE3 can be in contact with a circuit element disposed in the pixel circuit layer PCL through a via penetrating the via layer VIAL.
[0132] The first to third reflective electrodes RE1 to RE3 may function as full mirrors that reflect light emitted from the light emitting structure EMS toward the display surface (or the cover window CW). The first to third reflective electrodes RE1 to RE3 may include a metal material suitable for reflecting light. The first to third reflective electrodes RE1 to RE3 may include at least one of aluminum (Al), silver (Ag), magnesium (Mg), platinum (Pt), palladium (Pd), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr), titanium (Ti), and an alloy of two or more materials selected therefrom, but the embodiment is not limited thereto.
[0133] In an embodiment, a connection electrode may be disposed under each of the first to third reflective electrodes RE1 to RE3. The connection electrode may improve electrical connection characteristics between the corresponding reflective electrode and a circuit element of the pixel circuit layer PCL. The connection electrode may have a multi-layer structure. The multi-layer structure may include titanium (Ti), titanium nitride (TiN), tantalum nitride (TaN), etc., but the embodiment is not limited thereto. In an embodiment, the corresponding reflective electrode may be located between multiple layers of the connection electrodes.
[0134] A buffer pattern BFP may be disposed under at least one of the first reflective electrode RE1 to the third reflective electrode RE3. The buffer pattern BFP may include an inorganic material such as silicon carbon nitride, but the embodiment is not limited thereto. By disposing the buffer pattern BFP, the height of the corresponding reflective electrode in the third direction DR3 may be adjusted. For example, the buffer pattern BFP may be disposed between the first reflective electrode RE1 and the via layer VIAL to adjust the height of the first reflective electrode RE1.
[0135] The first reflective electrode RE1 to the third reflective electrode RE3 may function as full mirrors, and the cathode electrode CE may function as a half mirror. Light emitted from the light emitting layer of the light emitting structure EMS may be amplified by at least partially traveling back and forth between the corresponding reflective electrodes and the cathode electrode CE, and the amplified light may be output through the cathode electrode CE. In this manner, the distance between each reflective electrode and the cathode electrode CE may be understood as a resonance distance for the light emitted from the light emitting layer of the light emitting structure EMS.
[0136] The first sub-pixel SP1 may have a shorter resonance distance than the other sub-pixels due to the buffer pattern BFP. The adjusted resonance distance may effectively and efficiently amplify light in a specific wavelength range (e.g., red). As a result, the first sub-pixel SP1 may effectively and efficiently output light in the corresponding wavelength range.
[0137] 8, the buffer pattern BFP is provided in the first sub-pixel SP1, and not provided in the second sub-pixel SP2 and the third sub-pixel SP3, but the embodiment is not limited thereto. At least one of the second sub-pixel SP2 and the third sub-pixel SP3 may also be provided with a buffer pattern to adjust the resonance distance of at least one of the second sub-pixel SP2 and the third sub-pixel SP3. For example, the first sub-pixel SP1 to the third sub-pixel SP3 may correspond to red, green, and blue, respectively, and the distance between the first reflective electrode RE1 and the cathode electrode CE may be shorter than the distance between the second reflective electrode RE2 and the cathode electrode CE, and the distance between the second reflective electrode RE2 and the cathode electrode CE may be shorter than the distance between the third reflective electrode RE3 and the cathode electrode CE.
[0138] In order to flatten the steps between the first reflective electrode RE1 to the third reflective electrode RE3, a flattening layer PLNL may be disposed on the via layer VIAL and the first reflective electrode RE1 to the third reflective electrode RE3. The flattening layer PLNL entirely covers the first reflective electrode RE1 to the third reflective electrode RE3 and the via layer VIAL, but may have a flat surface. In the embodiment, the flattening layer PLNL may be omitted.
[0139] On the planarization layer PLNL, the first anode electrode AE1 to the third anode electrode AE3 are disposed so as to overlap the first reflective electrode RE1 to the third reflective electrode RE3, respectively. The first anode electrode AE1 to the third anode electrode AE3 may have shapes similar to the first light emitting region EMA1 to the third light emitting region EMA3 of FIG. 5 when viewed from the third direction DR3. The first anode electrode AE1 to the third anode electrode AE3 are connected to the first reflective electrode RE1 to the third reflective electrode RE3, respectively. The first anode electrode AE1 may be connected to the first reflective electrode RE1 through a first via VIA1 penetrating the planarization layer PLNL. The second anode electrode AE2 may be connected to the second reflective electrode RE2 through a second via VIA2 penetrating the planarization layer PLNL. The third anode electrode AE3 may be connected to the third reflective electrode RE3 through a third via VIA3 penetrating the planarization layer PLNL.
[0140] In the embodiment, the first anode electrode AE1 to the third anode electrode AE3 may include at least one of transparent conductive materials such as indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnOx), indium gallium zinc oxide (IGZO), and indium tin zinc oxide (ITZO). However, the material of the first anode electrode AE1 to the third anode electrode AE3 is not limited thereto. For example, the first anode electrode AE1 to the third anode electrode AE3 may include titanium nitride.
[0141] In the embodiment, an insulating layer for adjusting the height of one or more of the first anode electrode AE1 to the third anode electrode AE3 may be further provided. The insulating layer may be disposed between one or more of the first anode electrode AE1 to the third anode electrode AE3 and the corresponding reflective electrode. In this case, the planarizing layer PLNL and / or the buffer pattern BFP may be omitted. For example, the first sub-pixel SP1 to the third sub-pixel SP3 correspond to red, green, and blue, respectively, and the distance between the first anode electrode AE1 and the cathode electrode CE may be shorter than the distance between the second anode electrode AE2 and the cathode electrode CE, and the distance between the second anode electrode AE2 and the cathode electrode CE may be shorter than the distance between the third anode electrode AE3 and the cathode electrode CE.
[0142] A pixel defining film PDL is disposed on parts of the first anode electrode AE1 to the third anode electrode AE3 and the planarizing layer PLNL. The pixel defining film PDL may include openings OP exposing parts of each of the first anode electrode AE1 to the third anode electrode AE3. The openings OP of the pixel defining film PDL can define the light emitting regions of the first sub-pixel SP1 to the third sub-pixel SP3. In this manner, the pixel defining film PDL is disposed in the non-light emitting region NEA in FIG. 5 and can define the first light emitting region EMA1 to the third light emitting region EMA3 in FIG. 5.
[0143] In the embodiment, the pixel defining film PDL may include a plurality of inorganic insulating layers. Each of the plurality of inorganic insulating layers may include at least one of silicon oxide (SiOx) and silicon nitride (SiNx). For example, the pixel defining film PDL may include first to third inorganic insulating layers stacked in order, and the first to third inorganic insulating layers may include silicon nitride, silicon oxide, and silicon nitride, respectively. However, the embodiment is not limited thereto. The first to third inorganic insulating layers may have a stepped cross section in a region adjacent to the opening OP.
[0144] A separator SPR may be provided in the boundary region BDA between adjacent sub-pixels, that is, a separator SPR may be provided in each of the boundary regions between the sub-pixels SP in FIG.
[0145] The separator SPR may cause a discontinuity to be formed in the light emitting structure EMS at the boundary region BDA, for example, the separator SPR may cause the light emitting structure EMS to break or bend at the boundary region BDA.
[0146] The separator SPR may be provided in or on the pixel definition film PDL. The pixel definition film PDL may include one or more trenches TRCH1, TRCH2 as the separator SPR in the boundary region BDA. In an embodiment, as shown in FIG. 8, the one or more trenches TRCH1, TRCH2 may penetrate the pixel definition film PDL and partially penetrate the planarization layer PLNL. In another embodiment, the one or more trenches TRCH1, TRCH2 may penetrate the pixel definition film PDL and the planarization layer PLNL and partially penetrate the via layer VIAL. In another embodiment, the one or more trenches TRCH1, TRCH2 may at least partially penetrate the planarization layer PLNL and / or the via layer VIAL, and a part of the pixel definition film PDL may be disposed in the one or more trenches TRCH1, TRCH2.
[0147] 8 shows two trenches TRCH1 and TRCH2 provided in the boundary region BDA. However, the embodiment is not limited thereto. For example, the pixel definition film PDL may include one trench in the boundary region BDA. Or, the pixel definition film PDL may include three or more trenches in the boundary region BDA.
[0148] The first trench TRCH1 and the second trench TRCH2 may form discontinuous portions, such as a first void VD1 and a second void VD2, in the light emitting structure EMS in the boundary region BDA. Some of the layers stacked in the light emitting structure EMS may be cut or bent by the first void VD1 and the second void VD2. For example, at least one charge generation layer included in the light emitting structure EMS may be cut by the first void VD1 and the second void VD2. In this manner, the first trench TRCH1 and the second trench TRCH2 may at least partially separate the portions of the light emitting structure EMS included in the first to third sub-pixels SP1 to SP3.
[0149] 8 shows that the first void VD1 and the second void VD2 are formed in the light emitting structure EMS in the boundary area BDA, but this is merely an example and the embodiment is not limited thereto. For example, a concave valley may be formed in the light emitting structure EMS in the boundary area BDA. The discontinuous portions formed in the light emitting structure EMS may be variously changed according to the shapes of the first trench TRCH1 and the second trench TRCH2.
[0150] In the embodiment, the light emitting structure EMS may be formed by a process such as vacuum deposition, inkjet printing, etc. In this case, the same material as the light emitting structure EMS may be located on the bottom surfaces of the first trench TRCH1 and the second trench TRCH2 adjacent to the via layer VIAL.
[0151] The separator SPR may be provided in various modified forms so that the light emitting structure EMS may have a discontinuous portion in the boundary region BDA. In an embodiment, an inorganic insulating pattern may be additionally stacked on the pixel defining layer PDL in the boundary region BDA without the first trench TRCH1 and the second trench TRCH2. The width of the uppermost inorganic insulating pattern among the additionally stacked inorganic insulating patterns may be larger than the width of the inorganic insulating pattern disposed immediately below it. For example, in the boundary region BDA, the first to third inorganic insulating patterns are sequentially stacked on the pixel defining layer PDL, and the uppermost third inorganic insulating pattern may have a width larger than that of the second inorganic insulating pattern. For example, the pixel defining layer PDL may have a "T"-shaped or "I"-shaped cross section in the boundary region BDA. Depending on the shape of the pixel defining layer PDL, a plurality of layers included in the light emitting structure EMS may be at least partially cut or bent in the boundary region BDA.
[0152] The light emitting structure EMS may be disposed on the anode electrode AE exposed by the opening OP of the pixel defining layer PDL. The light emitting structure EMS may be disposed over the entire first to third sub-pixels SP1 to SP3, filling the opening OP of the pixel defining layer PDL. As described above, the light emitting structure EMS may be at least partially cut or bent in the boundary region BDA by the separator SPR. As a result, the current flowing from each of the first to third sub-pixels SP1 to SP3 to the adjacent sub-pixels through the layers included in the light emitting layer EML during operation of the display panel DP may be reduced. Therefore, the first to third light emitting elements LDa to LDc may operate with relatively high reliability.
[0153] The cathode electrode CE may be disposed on the light emitting structure EMS. The cathode electrode CE may be provided in common to the first to third sub-pixels SP1 to SP3. The cathode electrode CE may function as a half mirror that partially transmits and partially reflects light emitted from the light emitting structure EMS.
[0154] The first anode electrode AE1, a portion of the light emitting structure EMS overlapping the first anode electrode AE1, and a portion of the cathode electrode CE overlapping the first anode electrode AE1 may form a first light emitting element LDa. The second anode electrode AE2, a portion of the light emitting structure EMS overlapping the second anode electrode AE2, and a portion of the cathode electrode CE overlapping the second anode electrode AE2 may form a second light emitting element LDb. The third anode electrode AE3, a portion of the light emitting structure EMS overlapping the third anode electrode AE3, and a portion of the cathode electrode CE overlapping the third anode electrode AE3 may form a third light emitting element LDc.
[0155] A sealing layer TFE is disposed on the cathode electrode CE. The sealing layer TFE can prevent oxygen and / or moisture from penetrating into the light emitting element layer LDL.
[0156] The optical functional layer OFL is disposed on the encapsulation layer TFE. In an embodiment, the optical functional layer OFL may be attached to the encapsulation layer TFE via an adhesive layer APL. For example, the optical functional layer OFL may be manufactured separately and attached to the encapsulation layer TFE via an adhesive layer APL. The adhesive layer APL may further function to protect the lower layers including the encapsulation layer TFE.
[0157] The optical function layer OFL may include a color filter layer CFL and a lens array LA. The color filter layer CFL may include a first color filter CF1 to a third color filter CF3 corresponding to the first sub-pixel SP1 to the third sub-pixel SP3, respectively. The first color filter CF1 to the third color filter CF3 can transmit light of different wavelength ranges. For example, the first color filter CF1 to the third color filter CF3 can transmit red, green, and blue light, respectively.
[0158] In the embodiment, the first to third color filters CF1 to CF3 may partially overlap each other in the border area BDA. In another embodiment, the first to third color filters CF1 to CF3 may be spaced apart from each other, and a black matrix may be provided between the first to third color filters CF1 to CF3.
[0159] The lens array LA is disposed on the color filter layer CFL. The lens array LA may include a first lens LS1 to a third lens LS3 corresponding to the first sub-pixel SP1 to the third sub-pixel SP3, respectively. The first lens LS1 to the third lens LS3 output the light emitted from the first light-emitting element LDa to the third light-emitting element LDc to an intended path, thereby improving the light emission efficiency.
[0160] FIG. 9 is a diagram showing a light emitting device according to an embodiment.
[0161] 9, the light emitting device LD may have a tandem structure in which a first light emitting unit EU1 and a second light emitting unit EU2 are stacked. In this case, each of the first light emitting device LDa to the third light emitting device LDc in FIG. 8 may be formed as a light emitting device LD. The light emitting device LD may include an anode electrode AE, a light emitting structure EMS, and a cathode electrode CE. Depending on the embodiment, the light emitting device LD may further include a capping layer.
[0162] The light emitting structure EMS may be disposed between the anode electrode AE and the cathode electrode CE. The light emitting structure EMS may include a first light emitting unit EU1, a charge generation layer CGL, and a second light emitting unit EU2. Each of the first light emitting unit EU1 and the second light emitting unit EU2 may emit light in response to an applied current. The charge generation layer CGL may provide electrons or holes.
[0163] In the embodiment, the first light emitting unit EU1 and the second light emitting unit EU2 may emit light of different colors. Thus, the light emitted from the first light emitting unit EU1 and the second light emitting unit EU2 may be mixed and viewed as white light. For example, the first light emitting unit EU1 may emit blue light, and the second light emitting unit EU2 may emit yellow light.
[0164] The first light emitting unit EU1 may be disposed between the anode electrode AE and the charge generation layer CGL. The first light emitting unit EU1 may include a first hole transport unit HTU1, a first light emitting layer EML1, and a first electron transport unit ETU1. The first light emitting unit EU1 may emit light based on holes from the anode electrode AE and electrons from the charge generation layer CGL.
[0165] The first hole transport unit HTU1 may be disposed between the anode electrode AE and the first light emitting layer EML1. The first hole transport unit HTU1 may include at least one of a hole injection layer and a hole transport layer, and may further include a hole buffer layer, an electron blocking layer, etc., as necessary. The first hole transport unit HTU1 may transport holes from the anode electrode AE to the first light emitting layer EML1.
[0166] The first emission layer EML1 may be disposed between the first hole transport unit HTU1 and the first electron transport unit ETU1. In the embodiment, the first emission layer EML1 may emit blue light. In the embodiment, the first emission layer EML1 may include, but is not limited to, a blue fluorescent host and a blue fluorescent dopant. For example, the first emission layer EML1 may include a blue phosphorescent host and a blue phosphorescent dopant.
[0167] The first electron transport unit ETU1 may be disposed between the charge generation layer CGL and the first light-emitting layer EML1. The first electron transport unit ETU1 may include at least one of an electron injection layer and an electron transport layer, and may further include an electron buffer layer, a hole blocking layer, etc., as necessary. The first electron transport unit ETU1 may transport electrons from the charge generation layer CGL to the first light-emitting layer EML1.
[0168] The charge generation layer CGL may be disposed between the first light emitting unit EU1 and the second light emitting unit EU2. The charge generation layer CGL may include an organic layer. In an embodiment, the charge generation layer CGL may include a p-type charge generation layer p-CGL and an n-type charge generation layer n-CGL. The p-type charge generation layer p-CGL may be adjacent to the second light emitting unit EU2 (or the second hole transport unit HTU2). The p-type charge generation layer p-CGL may provide holes to the second light emitting unit EU2. For example, the p-type charge generation layer p-CGL may include, but is not limited to, a p-type dopant such as HAT-CN, TCNQ, NDP-9, etc. The n-type charge generation layer n-CGL may be adjacent to the first light emitting unit EU1 (or the first electron transport unit ETU1). The n-type charge generation layer n-CGL may provide electrons to the first light emitting unit EU1. For example, the n-type charge generation layer, n-CGL, can include, but is not limited to, an alkali metal, an alkaline earth metal, a lanthanide metal, or a combination thereof.
[0169] The second light emitting unit EU2 may be disposed between the cathode electrode CE and the charge generation layer CGL. The second light emitting unit EU2 may include a second hole transport unit HTU2, a second light emitting layer EML2, a third light emitting layer EML3, and a second electron transport unit ETU2. The second light emitting unit EU2 may emit light based on electrons from the cathode electrode CE and holes from the charge generation layer CGL.
[0170] The second hole transport unit HTU2 may be disposed between the charge generation layer CGL (or the p-type charge generation layer p-CGL) and the second light emitting layer EML2. The second hole transport unit HTU2 may include at least one of a hole injection layer and a hole transport layer, and may further include a hole buffer layer, an electron blocking layer, etc., as necessary. The second hole transport unit HTU2 may transport holes from the p-type charge generation layer p-CGL to the second light emitting layer EML2 and the third light emitting layer EML3.
[0171] The second emitting layer EML2 may be disposed between the second hole transporting unit HTU2 and the third emitting layer EML3. In an embodiment, the second emitting layer EML1 may emit red light. In an embodiment, the second emitting layer EML2 may include a red hole transporting host, a red electron transporting host, and a red phosphorescent dopant. The red hole transporting host is a compound having strong hole properties and may include a moiety (or hole transporting moiety) that readily accepts holes. For example, the hole transporting moiety may include, but is not limited to, an amine group, a carbazole group, a dibenzofuran group, a dibenzothiophene group, a fluorene group, and the like. The red electron transporting host is a compound having strong electronic properties and may include a moiety (or electron transporting moiety) that readily accepts electrons. For example, the electron transporting moiety may include -F, a cyano group, a C substituted with -F or a cyano group, 1 -C 60 C substituted with alkyl, -F or cyano group 6 -C 60 The red hole transporting host may include, but is not limited to, an aryl group, a π-electron deficient nitrogen-containing cyclic group, etc. The red hole transporting host and the red electron transporting host may be mixed in a weight ratio that balances hole transport and electron transport.
[0172] The third emitting layer EML3 may be disposed between the second emitting layer EML2 and the second electron transporting unit ETU2. In an embodiment, the third emitting layer EML3 may emit green light. In an embodiment, the third emitting layer EML3 may include a green hole transporting host, a green electron transporting host, and a green phosphorescent dopant. The green hole transporting host is a compound having strong hole properties and may include a hole transporting moiety. The green hole transporting host may be made of the same or different compound as the red hole transporting host. The green electron transporting host is a compound having strong electronic properties and may include an electron transporting moiety. The green electron transporting host may be made of the same or different compound as the red electron transporting host. The mixing ratio of the green hole transporting host and the green electron transporting host is not particularly limited, and they may be mixed at a weight ratio that balances hole transport and electron transport.
[0173] Since the second light emitting unit EU2 includes the second light emitting layer EML2 and the third light emitting layer EML3, the red light emitted from the second light emitting layer EML2 and the green light emitted from the third light emitting layer EML3 are mixed to provide yellow light.
[0174] The second electron transport unit ETU2 may be disposed between the third light-emitting layer EML3 and the cathode electrode CE. The second electron transport unit ETU2 may include at least one of an electron injection layer and an electron transport layer, and may further include an electron buffer layer, a hole blocking layer, etc., as necessary. The second electron transport unit ETU2 may transport electrons from the cathode electrode CE to the second light-emitting layer EML2 and the third light-emitting layer EML3.
[0175] The capping layer CPL may be disposed in a direction in which light is emitted. For example, the capping layer CPL may be disposed on the cathode electrode CE. The capping layer CPL may improve external light emission efficiency by the principle of constructive interference. The capping layer CPL may include an organic material, an inorganic material, or a composite material including an organic material and an inorganic material.
[0176] Fig. 10 is a diagram illustrating the light emission principle of the light emitting device of Fig. 9. Fig. 10 illustrates the configuration related to the light emission of the second light emitting layer EML2 and the third light emitting layer EML3, and the remaining configuration is omitted. Fig. 11 is a diagram illustrating the distribution of excitons according to the position of the light emitting device of Fig. 9 by gray scale.
[0177] 9 and 10, when a voltage is applied to the light emitting element LD, holes move along the highest occupied molecular orbital (HOMO) energy level. For example, holes from the p-type charge generation layer p-CGL reach the second light emitting layer EML2 and the third light emitting layer EML3 through the second hole transport unit HTU2. Electrons move along the lowest unoccupied molecular orbital (LUMO) energy level. For example, electrons from the cathode electrode CE reach the second light emitting layer EML2 and the third light emitting layer EML3 through the second electron transport unit ETU2. As a result, excitons in which holes and electrons are combined are formed in the second light emitting layer EML2 and the third light emitting layer EML3, respectively, and the second light emitting layer EML2 emits red light and the third light emitting layer EML3 emits green light.
[0178] At this time, since the LUMO energy level of the second emission layer EML2 is lower (or deeper) than the LUMO energy level of the third emission layer EML3, electrons are easily and quickly injected from the third emission layer EML3 to the second emission layer EML2. In particular, at low gradations, an excessive amount of electrons are injected into the second emission layer EML2, causing the red light efficiency to become excessively high. As a result, a roll-off phenomenon may occur in which the efficiency of red light decreases rapidly at high gradations due to saturation and deterioration of the characteristics of the second emission layer EML2.
[0179] Referring to FIG. 11, in the low gradation, since the electron injection from the third emission layer EML3 to the second emission layer EML2 is easy and fast, the excitons are formed in excess near the second emission layer EML2 adjacent to the second hole transport unit HTU2, and the red light efficiency becomes excessively high. In the high gradation, the excitons are mainly formed near the third emission layer EML3 adjacent to the second emission layer EML2. That is, as the gradation changes from low to high, the distribution of the excitons moves from the second emission layer EML2 to the third emission layer EML3. At this time, the exciton quenching, which reduces the light efficiency due to the mutual influence between the excitons of the second emission layer EML2 and the excitons of the third emission layer EML3, may occur. In this case, the difference in the red light efficiency between the low gradation and the high gradation is large, and the roll-off phenomenon may become serious.
[0180] Fig. 12 is a diagram showing a light emitting device according to an embodiment, in which the description of the same content as in Fig. 9 will be omitted or simplified.
[0181] 12, the light emitting element LD' may further include an intermediate layer IL. The intermediate layer IL may be included in the second light emitting unit EU2. The intermediate layer IL may be disposed on the second light emitting layer EML2. More specifically, the intermediate layer IL may be disposed between the second light emitting layer EML2 and the third light emitting layer EML3. The intermediate layer IL may increase hole injection from the second light emitting layer EML2 to the third light emitting layer EML3 and block (or reduce) electron injection from the third light emitting layer EML3 to the second light emitting layer EML2.
[0182] In the embodiment, the total thickness of the second emitting layer EML2, the intermediate layer IL, and the third emitting layer EML3 may be 30 to 50 nm, for example, about 41 to 43 nm.
[0183] In the embodiment, the thickness of the intermediate layer IL may be 0.5 to 3 nm. The thickness of the intermediate layer IL is preferably about 1 nm. Within the above range, it is possible to prevent the red light efficiency from increasing sharply at low gradations, thereby reducing the roll-off phenomenon of red light. In addition, it is possible to ensure sufficient red light efficiency without increasing the driving voltage.
[0184] In the embodiment, the LUMO energy level of the intermediate layer IL may be higher (or shallower) than the LUMO energy level of the third emission layer EML3. In this case, it becomes difficult to inject electrons from the third emission layer EML3 to the second emission layer EML2. In particular, by preventing excessive electron injection into the second emission layer EML2 at low gradations, a rapid increase in red light efficiency can be prevented.
[0185] In an embodiment, the LUMO energy level of the intermediate layer IL may be less than 1.5 eV. If the LUMO energy level of the intermediate layer IL is 1.5 eV or more, the electron injection from the third emission layer EML3 to the second emission layer EML2 may be excessively reduced, and the red light efficiency may be excessively low. That is, within the above range, an excessive increase or decrease in the red light efficiency at low gradations may be prevented, and sufficient red light efficiency may be ensured.
[0186] In an embodiment, the intermediate layer IL may include a compound having at least one of a carbazole group and a triphenylamine group. In this case, electron injection from the third emitting layer EML3 to the second emitting layer EML2 is prevented (or reduced), and hole injection from the second emitting layer EML2 to the third emitting layer EML3 can be smoothly performed. For example, the intermediate layer IL may include at least one compound among the compounds represented by the following chemical formulas 1 to 4. Chemical formula 1 is N-([1,1'-biphenyl]-4-yl)-N-phenyl-3'-(3-phenyl-9H-carbazol-9-yl)-[1,1'-biphenyl]-4-amine, chemical formula 2 is N,N-di([1,1'-biphenyl]-4-yl)-4'-(9H-carbazol-9-yl)-[1,1'-biphenyl]-4-amine, chemical formula 3 is N,N-di([1,1'-biphenyl]-4-yl)-3'-(9H-carbazol-9-yl)-[1,1'-biphenyl]-4-amine, and chemical formula 4 is N-([1,1'-biphenyl]-4-yl)-3'-(9H-carbazol-9-yl)-N-phenyl-[1,1'-biphenyl]-4-amine.
[0187] [ka] ...chemical formula 1
[0188] [ka] ...Chemical formula 2
[0189] [ka] ...chemical formula 3
[0190] [ka] ...chemical formula 4
[0191] Fig. 13 is a diagram showing the light emission principle of the light emitting device of Fig. 12. Fig. 13 shows the configuration related to the light emission of the second light emitting layer EML2 and the third light emitting layer EML3, and the remaining configuration is omitted. Fig. 14 is a diagram showing the distribution of excitons according to the position of the light emitting device of Fig. 12 by gray scale.
[0192] 12 and 13, since the LUMO energy level of the intermediate layer IL is higher (or shallower) than the LUMO energy level of the third emission layer EML3, electron injection from the third emission layer EML3 to the intermediate layer IL is reduced, resulting in reduced electron injection into the second emission layer EML2. In particular, since excessive electron injection into the second emission layer EML2 is prevented at low gradations, an excessive increase in red light efficiency can be prevented. As a result, the degree to which red light efficiency decreases at high gradations is reduced, improving the roll-off phenomenon.
[0193] Referring to FIG. 14, in low gradations, electron injection from the third emitting layer EML3 to the second emitting layer EML2 is prevented (or reduced), so excitons are mainly formed near the second emitting layer EML2 adjacent to the intermediate layer IL. Also, the amount of excitons formed in the second emitting layer EML2 decreases, so red light efficiency decreases. In high gradations, excitons are mainly formed near the third emitting layer EML3 adjacent to the intermediate layer IL. That is, as the gradation changes from low to high, the distribution of excitons moves from the second emitting layer EML2 to the third emitting layer EML3, but the degree of reduction in red light efficiency due to exciton quenching by the intermediate layer IL is reduced. Therefore, the difference in red light efficiency between low and high gradations is reduced, and the red light roll-off phenomenon can be improved.
[0194] Fig. 15 is a graph showing red light efficiency as a function of current density for each light emitting element, and Fig. 16 is a graph showing current density as a function of driving voltage for each light emitting element.
[0195] 15, in the light emitting device LD of FIG. 9, electrons are excessively injected into the second emission layer EML2 (see FIG. 10) at low gradations where the current density is low, so that the red light efficiency increases rapidly. As a result, a roll-off phenomenon occurs in which the degree of decrease in red light efficiency increases as the current density increases. On the other hand, in the light emitting device LD' of FIG. 13, electron injection into the second emission layer EML2 (see FIG. 13) is prevented (or reduced) at low gradations where the current density is low, so that the red light efficiency does not increase rapidly. Therefore, even at high gradations where the current density is high, the degree of decrease in red light efficiency is small, so that the roll-off phenomenon can be improved.
[0196] 16, the current density depending on the driving voltage of the light emitting device LD of FIG 9 is at a similar level to that of the light emitting device LD' of FIG 13. That is, when the light emitting device LD' including the intermediate layer IL (see FIG 13) is used, the above-mentioned roll-off phenomenon can be improved and sufficient current density can be ensured without increasing the driving voltage.
[0197] Fig. 17 is a diagram showing a light emitting device according to an embodiment, in which the description of the same content as in Fig. 9 will be omitted or simplified.
[0198] 17, the light emitting device LD'' does not include an intermediate layer IL, unlike the light emitting device LD' in FIG. 12, and includes a second light emitting layer EML2, which is different from the light emitting device LD in FIG.
[0199] In an embodiment, the second emissive layer EML2 may include a red bipolar host and a red phosphorescent dopant. The red bipolar host may include at least one hole transporting moiety and at least one electron transporting moiety. That is, the red bipolar host may be a bipolar host having both hole and electronic properties. For example, the hole transporting moiety may include an amine group, a carbazole group, a dibenzofuran group, a dibenzothiophene group, a fluorene group, etc., and the electron transporting moiety may include -F, a cyano group, a C substituted with -F or a cyano group. 1 -C 60 C substituted with alkyl, -F or cyano group 6 -C 60 The second emitting layer EML2 may include, but is not limited to, an aryl group, a π-electron-deficient nitrogen-containing cyclic group, etc. In this case, the electron-accepting ability of the second emitting layer EML2 is reduced compared to when the second emitting layer EML2 includes a red electron-transporting host (see FIG. 9), and therefore the amount of electron injection into the second emitting layer EML2 can be reduced.
[0200] In the embodiment, the LUMO energy level of the red bipolar host may be higher (or shallower) than the LUMO energy level of the green electron-transporting host included in the third emitting layer EML3. In this case, the LUMO energy level of the second emitting layer EML2 becomes higher than the LUMO energy level of the third emitting layer EML3, making it difficult to inject electrons from the third emitting layer EML3 to the second emitting layer EML2. In particular, by preventing excessive electron injection into the second emitting layer EML2 at low gradations, a rapid increase in red light efficiency can be prevented.
[0201] In an embodiment, the LUMO energy level of the red bipolar host may be less than 1.9 eV. If the LUMO energy level of the red bipolar host is 1.9 eV or more, the LUMO energy level of the second emission layer EML2 may be excessively high, and the electron injection from the third emission layer EML3 to the second emission layer EML2 may be excessively reduced, resulting in excessively low red light efficiency. That is, within the above range, excessive increase and decrease in red light efficiency at low gradations may be prevented, ensuring sufficient red light efficiency.
[0202] Fig. 18 is a diagram showing the light emission principle of the light emitting device of Fig. 17. Fig. 18 shows the configuration related to the light emission of the second light emitting layer EML2 and the third light emitting layer EML3, and the remaining configuration is omitted. Fig. 19 is a diagram showing the distribution of excitons according to the position of the light emitting device of Fig. 17 by gray scale.
[0203] 17 and 18, since the LUMO energy level of the second emission layer EML2 is higher (or shallower) than the LUMO energy level of the third emission layer EML3, electron injection from the third emission layer EML3 to the second emission layer EML2 is reduced. In particular, since excessive electron injection into the second emission layer EML2 is prevented at low gradations, an excessive increase in red light efficiency can be prevented. As a result, the degree to which red light efficiency decreases at high gradations is reduced, improving the roll-off phenomenon.
[0204] Referring to FIG. 19, since the injection of electrons from the third emission layer EML3 to the second emission layer EML2 is prevented (or reduced) at low gradations, excitons are mainly formed near the second emission layer EML2 adjacent to the third emission layer EML3. Also, the amount of excitons formed in the second emission layer EML2 decreases, resulting in a low red light efficiency. At high gradations, excitons are mainly formed near the third emission layer EML3 adjacent to the second emission layer EML2. That is, as the gradation changes from low to high, the distribution of excitons moves from the second emission layer EML2 to the third emission layer EML3, causing exciton quenching and reducing the red light efficiency. In this case, since the red light efficiency at low gradations is low, the difference in red light efficiency between low and high gradations is reduced, and the red light roll-off phenomenon can be improved.
[0205] Fig. 20 is a graph showing red light efficiency as a function of current density for each light emitting element, and Fig. 21 is a graph showing current density as a function of driving voltage for each light emitting element.
[0206] 20, in the light emitting device LD of FIG. 9, electrons are excessively injected into the second emission layer EML2 (see FIG. 10) at low gray scales with low current density, so that the red light efficiency increases rapidly. As a result, a roll-off phenomenon occurs in which the degree of decrease in red light efficiency increases as the current density increases and the gray scale increases. On the other hand, in the light emitting device LD″ of FIG. 17, electron injection into the second emission layer EML2 (see FIG. 18) is prevented (or reduced) at low gray scales with low current density, so that the red light efficiency does not increase rapidly. Therefore, even at high gray scales with high current density, the degree of decrease in red light efficiency is small, so that the roll-off phenomenon can be improved.
[0207] 21, the current densities depending on the driving voltage of the light emitting device LD of FIG. 9 and the light emitting device LD″ of FIG. 17 are at similar levels. That is, when the light emitting device LD′ including the second light emitting layer EML2 (see FIG. 17) including a red bipolar host is used, the above-mentioned roll-off phenomenon can be improved and sufficient current density can be ensured without increasing the driving voltage.
[0208] FIG. 22 is a diagram illustrating a display system according to one embodiment.
[0209] Referring to FIG. 22, a display system 1000 may include a processor 1100 and one or more display devices 1210, 1220.
[0210] The processor 1100 can perform various tasks and calculations. In an embodiment, the processor 1100 may include an application processor, a graphic processor, a microprocessor, a central processing unit (CPU), etc. The processor 1100 can be connected to other components of the display system 1000 via a bus system to control them.
[0211] 22, the display system 1000 is shown to include first and second display devices 1210, 1220. The processor 1100 may be connected to the first display device 1210 via a first channel CH1 and to the second display device 1220 via a second channel CH2.
[0212] Through the first channel CH1, the processor 1100 may transmit the first image data IMG1 and the first control signal CTRL1 to the first display device 1210. The first display device 1210 may display an image based on the first image data IMG1 and the first control signal CTRL1. The first display device 1210 may be configured similarly to the display device 100 described with reference to FIG. 1. In this case, the first image data IMG1 and the first control signal CTRL1 may be provided as the input image data IMG and the control signal CTRL of FIG. 1, respectively.
[0213] Through the second channel CH2, the processor 1100 may transmit the second image data IMG2 and the second control signal CTRL2 to the second display device 1220. The second display device 1220 may display an image based on the second image data IMG2 and the second control signal CTRL2. The second display device 1220 may be configured similarly to the display device 100 described with reference to FIG. 1. In this case, the second image data IMG2 and the second control signal CTRL2 may be provided as the input image data IMG and the control signal CTRL of FIG. 1, respectively.
[0214] The display system 1000 may include a computing system providing a video display function, such as a portable computer, a mobile phone, a smart phone, a tablet personal computer (PC), a smart watch, a watch phone, a portable multimedia player (PMP), a navigation system, an ultra mobile personal computer (UMPC), etc. The display system 1000 may also include at least one of a head mounted display device (HMD), a virtual reality (VR) device, a mixed reality (MR) device, and an augmented reality (AR) device.
[0215] FIG. 23 is a diagram showing an application example of the display system of FIG.
[0216] 23, the display system 1000 of FIG. 22 may be applied to a head-mounted display device 2000. The head-mounted display device 2000 may be a wearable electronic device that can be mounted on a user's head.
[0217] The head mounted display device 2000 may include a head mounted band 2100 and a display device housing case 2200. The head mounted band 2100 may be connected to the display device housing case 2200. The head mounted band 2100 may include a horizontal band and / or a vertical band for fixing the head mounted display device 2000 to the user's head. The horizontal band may be configured to surround the side of the user's head, and the vertical band may be configured to surround the top of the user's head. However, the embodiment is not limited thereto. For example, the head mounted band 2100 may be embodied in the shape of a glasses frame, a helmet, or the like.
[0218] The display device housing case 2200 can house the first and second display devices 1210 and 1220 of Fig. 22. The display device housing case 2200 can further house the processor 1100 of Fig. 22.
[0219] FIG. 24 is a diagram showing a head-mounted display device worn by the user of FIG.
[0220] 24, a first display panel DP1 of the first display device 1210 and a second display panel DP2 of the second display device 1220 are arranged in a head mounted display device 2000. The head mounted display device 2000 may further include one or more lenses LLNS, RLNS.
[0221] In the display device storage case 2200, the right eye lens RLNS can be disposed between the first display panel DP1 and the right eye of the user. In the display device storage case 2200, the left eye lens LLNS can be disposed between the second display panel DP2 and the left eye of the user.
[0222] The image output from the first display panel DP1 can be viewed by the user's right eye through the right-eye lens RLNS. The right-eye lens RLNS can refract light from the first display panel DP1 so that it faces the user's right eye. The right-eye lens RLNS can perform an optical function for adjusting the viewing distance between the first display panel DP1 and the user's right eye.
[0223] The image output from the second display panel DP2 can be viewed by the left eye of the user through the left eye lens LLNS. The left eye lens LLNS can refract light from the second display panel DP2 so that it faces the left eye of the user. The left eye lens LLNS can perform an optical function to adjust the viewing distance between the second display panel DP2 and the left eye of the user.
[0224] In an embodiment, each of the right-eye lens RLNS and the left-eye lens LLNS may include an optical lens having a pancake-shaped cross section. In an embodiment, each of the right-eye lens RLNS and the left-eye lens LLNS may include a multi-channel lens including sub-regions having different optical characteristics. In this case, each display panel outputs an image corresponding to each sub-region of the multi-channel lens, and the output image can pass through each corresponding sub-region and be viewed by a user.
[0225] [Example] Comparative Example 1 The light-emitting element LD1 of Comparative Example 1 does not include an intermediate layer IL. The second emitting layer EML2 includes a red hole-transporting host, a red electron-transporting host, and a red phosphorescent dopant, and the thickness of the second emitting layer EML2 is 5 nm. The third emitting layer EML3 includes a green hole-transporting host, a green electron-transporting host, and a green phosphorescent dopant, and the thickness of the third emitting layer EML3 is 35 nm.
[0226] Comparative Example 2 The light-emitting device LD2 of Comparative Example 2 is the same as the light-emitting device LD1 of Comparative Example 1, except that the second light-emitting layer EML2 contains a red fluorescent dopant and the third light-emitting layer EML3 contains a green fluorescent dopant.
[0227] Example 1 The light-emitting device LD1' of Example 1 is the same as the light-emitting device LD1 of Comparative Example 1, except that it includes an intermediate layer IL, which includes the compound F1 represented by Chemical Formula 1 above, and the thickness of the intermediate layer IL is 3 nm.
[0228] Example 2 The light-emitting device LD2' of Example 2 is the same as the light-emitting device LD1' of Example 1, except that the intermediate layer IL contains the compound F2 represented by Chemical Formula 2 above.
[0229] Example 3 The light-emitting device LD3' of Example 3 is the same as the light-emitting device LD1' of Example 1, except that the intermediate layer IL contains the compound F3 represented by Chemical Formula 3 above.
[0230] Example 4 The light-emitting element LD4' of Example 4 is the same as the light-emitting element LD3' of Example 3, except that the thickness of the intermediate layer IL is 2 nm.
[0231] Example 5 The light-emitting element LD5' of Example 5 is the same as the light-emitting element LD3' of Example 3, except that the thickness of the intermediate layer IL is 1 nm.
[0232] Example 6 The light-emitting device LD6' of Example 6 is the same as the light-emitting device LD5' of Example 5, except that the second light-emitting layer EML2 has a thickness of 8 nm and the third light-emitting layer EML3 has a thickness of 32 nm.
[0233] Example 7 The light-emitting device LD7' of Example 7 is the same as the light-emitting device LD5' of Example 5, except that the second light-emitting layer EML2 has a thickness of 10 nm and the third light-emitting layer EML3 has a thickness of 30 nm.
[0234] Example 8 The light-emitting element LD″ of Example 8 is the same as the light-emitting element LD1 of Comparative Example 1, except that the second emitting layer EML2 contains a red bipolar host, the second emitting layer EML2 has a thickness of 7 nm, and the third emitting layer EML3 has a thickness of 33 nm.
[0235] Evaluation example The following Table 1 shows the driving voltage, efficiency, and roll-off of the light-emitting elements of Comparative Examples 1 and 2 and Examples 1 to 8 at low gradations.
[0236] [Table 1]
[0237] Referring to Table 1, it can be seen that the light emitting device of Comparative Example 2 has improved red light roll-off compared to the light emitting device of Comparative Example 1, but has a problem in that the driving voltage is very high and the red light efficiency is very low. It can be seen that the light emitting devices of Examples 1 to 8 have improved red light roll-off compared to the light emitting device of Comparative Example 1, with no significant change in red light efficiency relative to the driving voltage. In particular, it can be seen that the light emitting device of Example 5 has improved red light roll-off while simultaneously maintaining the same red light efficiency and high green light efficiency compared to the light emitting device of Comparative Example 1 at the same driving voltage.
[0238] Although the present invention has been specifically described with reference to the above examples, it should be noted that the above examples are for the purpose of explaining the present invention and are not intended to limit the scope of the present invention. It will be understood by those skilled in the art that various modifications are possible within the scope of the technical concept of the present invention.
[0239] The scope of the present invention is not limited to the contents described in the detailed description of the specification, but should be determined by the claims. Furthermore, all modifications and variations derived from the meaning and scope of the claims and their equivalent concepts should be interpreted as being included in the scope of the present invention. [Explanation of symbols]
[0240] LD light emitting element AE anode electrode CE cathode electrode EMS Light-emitting Structure EU1, EU2 light emitting part CGL charge generation layer HTU1, HTU2 hole transporter ETU1, ETU2 Electronic Transport Department EML1, EML2, EML3 Emitting layers IL middle layer CPL Capping Layer
Claims
1. An anode electrode; a cathode electrode facing the anode electrode; a light emitting structure disposed between the anode electrode and the cathode electrode, the light emitting structure including a first light emitting unit, a charge generating layer, and a second light emitting unit; The second light emitting unit is a second hole transport part disposed on the charge generation layer; A second light-emitting layer disposed on the second hole transport part; an intermediate layer disposed on the second light-emitting layer; a third light-emitting layer disposed on the intermediate layer; a second electron transporting part disposed between the third light-emitting layer and the cathode electrode.
2. The first light emitting unit is A first hole transport part disposed on the anode electrode; a first electron transport section facing the first hole transport section and adjacent to the charge generation layer; The light emitting device according to claim 1 , further comprising: a first light emitting layer disposed between the first hole transporting part and the first electron transporting part.
3. 2. The light emitting device according to claim 1, wherein the second light emitting layer, the intermediate layer and the third light emitting layer have a total thickness of 30 to 50 nm.
4. 2. The light-emitting device according to claim 1, wherein the intermediate layer has a thickness of 0.5 to 3 nm.
5. The light-emitting device according to claim 1 , wherein the LUMO energy level of the intermediate layer is higher than the LUMO energy level of the third light-emitting layer.
6. The light-emitting device of claim 5 , wherein the LUMO energy level of the intermediate layer is less than 1.5 eV.
7. The light-emitting device according to claim 1 , wherein the intermediate layer includes a compound having at least one of a carbazole group and a triphenylamine group.
8. the first light-emitting layer emits blue light; the second light-emitting layer emits red light; The light-emitting device according to claim 2 , wherein the third light-emitting layer emits green light.
9. The light emitting device of claim 8 , wherein the first light emitting layer comprises a blue fluorescent host and a blue fluorescent dopant.
10. the second light-emitting layer comprises a red hole-transporting host, a red electron-transporting host, and a red phosphorescent dopant; The light-emitting device of claim 8 , wherein the third light-emitting layer comprises a green hole-transporting host, a green electron-transporting host, and a green phosphorescent dopant.
11. The charge generating layer comprises: an n-type charge generation layer adjacent to the first light emitting portion; The light emitting device of claim 1 , further comprising: a p-type charge generation layer adjacent to the second light emitting portion.
12. The light-emitting device of claim 1 , further comprising a capping layer disposed on the cathode electrode.
13. An anode electrode; a cathode electrode facing the anode electrode; a light emitting structure disposed between the anode electrode and the cathode electrode, the light emitting structure including a first light emitting unit, a charge generating layer, and a second light emitting unit; The second light emitting unit is a second hole transport part disposed on the charge generation layer; a second electron transport section facing the second hole transport section and adjacent to the cathode electrode; a second light-emitting layer and a third light-emitting layer disposed between the second hole transporting part and the second electron transporting part, the second light-emitting layer comprises a red bipolar host and a red phosphorescent dopant.
14. The light-emitting device according to claim 13 , wherein the second light-emitting layer is disposed between the second hole transporting part and the third light-emitting layer, and the third light-emitting layer is disposed between the second light-emitting layer and the second electron transporting part.
15. 14. The light-emitting device of claim 13, wherein the third light-emitting layer comprises a green hole-transporting host, a green electron-transporting host, and a green phosphorescent dopant.
16. 16. The light-emitting device of claim 15, wherein the LUMO energy level of the red bipolar host is higher than the LUMO energy level of the green electron-transporting host.
17. 17. The light-emitting device of claim 16, wherein the LUMO energy level of the red bipolar host is less than 1.9 eV.
18. The first light emitting unit is A first hole transport part disposed on the anode electrode; a first electron transport section facing the first hole transport section and adjacent to the charge generation layer; The light-emitting device according to claim 13 , further comprising: a first light-emitting layer disposed between the first hole transporting part and the first electron transporting part.
19. A display device comprising the light-emitting element according to any one of claims 1 to 18.
20. 20. The display device of claim 19, wherein the display device comprises any one of a flat panel display, a curved display, a flexible display, a rollable display, a foldable display, a stretchable display, a head-up display, a head-mounted display, a wearable display, a microdisplay, a 3D display, a virtual reality display, an augmented reality display, and a mixed reality display.
Citation Information
Patent Citations
KR2010-0073785