Positive electrode active material for nonaqueous electrolyte secondary battery and production method thereof

Abstract

To provide a positive electrode active material for a nonaqueous electrolyte secondary battery, capable of constituting a nonaqueous electrolyte secondary battery having a high initial efficiency and durability.SOLUTION: A positive electrode active material for a nonaqueous electrolyte secondary battery includes a lithium-transition metal composite oxide that contains lithium, nickel, cobalt, and manganese and that has a layered structure. The lithium-transition metal composite oxide has a ratio D50 / DSEM of 1 or more and 4 or less, in which D50 is a 50% particle diameter in a cumulative particle size distribution on a volumetric basis and DSEM is an average particle diameter of primary particles based on electron microscope observation, and also has such a composition that a ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is 0.03 or more and less than 0.2, and a ratio of the number of moles of manganese to the total number of moles of the metals other than lithium is 0.01 or more and less than 0.2. The disorder of elemental nickel is 1.8% or less, and the lithium-transition metal composite oxide may have a deposit containing boron on its surface.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present disclosure relates to a positive electrode active material for a non-aqueous electrolyte secondary battery and a method for producing the same. [Background technology]

[0002] Electrode active materials for non-aqueous electrolyte secondary batteries containing lithium nickel-cobalt aluminum oxide with a high proportion of nickel are used in large power equipment such as electric vehicles, and there is a demand for improved output characteristics for these electrode active materials. In order to obtain high output characteristics, a positive electrode active material having a structure of secondary particles (hereinafter also referred to as aggregated particles) in which many primary particles are aggregated is considered effective. However, in a positive electrode active material containing aggregated particles, cracks may occur in the aggregated particles due to pressure treatment when forming an electrode, expansion and contraction of the electrode active material during charging and discharging, etc., making it impossible to obtain desired output characteristics. In relation to this, a method for producing a positive electrode active material containing lithium transition metal oxide particles (hereinafter collectively referred to as single particles) in which the number of primary particles constituting a single particle or one secondary particle is reduced has been proposed (see, for example, Patent Document 1).

[0003] Meanwhile, a technique has been proposed for producing a lithium transition metal composite oxide containing nickel, in which the lithium site occupancy rate of the 3a site is 96.0% or more as calculated by Rietveld analysis, by using a crystallization promoter containing an alkali metal other than lithium, and this is said to improve cycle characteristics while maintaining charge / discharge capacity (see, for example, Patent Document 2). [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2017-188444 A [Patent Document 2] JP 2016-115658 A Summary of the Invention [Problem to be solved by the invention]

[0005] An object of one aspect of the present disclosure is to provide a positive electrode active material for a nonaqueous electrolyte secondary battery that can constitute a nonaqueous electrolyte secondary battery having high initial efficiency and durability, and a method for producing the same. [Means for solving the problem]

[0006] A first aspect of the present disclosure is a positive electrode active material for a non-aqueous electrolyte secondary battery, which contains a lithium transition metal composite oxide that contains lithium, nickel, cobalt, and manganese and has a layered structure. The lithium transition metal composite oxide has an average particle size D SEM 50% particle size D of cumulative particle size distribution based on volume 50 Ratio of D 50 / D SEM is 1 or more and 4 or less, the ratio of the number of moles of nickel to the total number of moles of metals other than lithium is greater than 0.8 and less than 1, the ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is less than 0.2, the ratio of the number of moles of manganese to the total number of moles of metals other than lithium is less than 0.2, and the ratio of the number of moles of manganese to the sum of the number of moles of cobalt and the number of moles of manganese is less than 0.58.

[0007] A second aspect of the present disclosure is a method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery, comprising: preparing a composite containing nickel, cobalt, and manganese as metal components, the ratio of the number of moles of nickel to the total number of moles of the metal components being greater than 0.8 and less than 1; the ratio of the number of moles of cobalt to the total number of moles of the metal components being less than 0.2; the ratio of the number of moles of manganese to the total number of moles of the metal components being less than 0.2; and the ratio of the number of moles of manganese to the sum of the number of moles of cobalt and the number of moles of manganese being less than 0.58; mixing the composite with a lithium compound and an alkali metal compound having a melting point of 400° C. or less and containing an alkali metal other than lithium to obtain a lithium mixture; heat-treating the lithium mixture at a temperature of 650° C. or more and 800° C. or less to obtain a heat-treated product; dispersing the heat-treated product in a dry state to obtain a first dispersion; contacting the first dispersion with a liquid medium and then removing at least a part of the liquid medium to obtain a lithium transition metal composite oxide. The lithium transition metal composite oxide has an average particle size D based on observation with an electron microscope. SEM 50% particle size D of cumulative particle size distribution based on volume 50 Ratio of D 50 / D SEM is between 1 and 4 inclusive. Effect of the Invention

[0008] According to the present disclosure, it is possible to provide a positive electrode active material for a non-aqueous electrolyte secondary battery capable of forming a non-aqueous electrolyte secondary battery having high initial efficiency and durability, and a method for producing the same. [Brief description of the drawings]

[0009] [Figure 1] 2 is an example of a scanning electron microscope (SEM) image of the positive electrode active material according to Example 1. [Diagram 2] 4 is an example of an SEM image of the positive electrode active material according to Example 2. [Diagram 3] 1 is an example of an SEM image of a positive electrode active material according to Example 3. [Figure 4] 1 is an example of an SEM image of a positive electrode active material according to Example 4. [Diagram 5]1 is an example of an SEM image of a positive electrode active material according to Example 5. [Figure 6] 4 is an example of an SEM image of a positive electrode active material according to Comparative Example 1. [Figure 7] 1 is an example of an SEM image of a positive electrode active material according to Comparative Example 2. [Figure 8] 13 is an example of an SEM image of a positive electrode active material according to Comparative Example 3. [Figure 9] 13 is an example of an SEM image of a positive electrode active material according to Comparative Example 4. [Figure 10] 13 is an example of an SEM image of a positive electrode active material according to Comparative Example 5. [Figure 11] 13 is an example of an SEM image of a positive electrode active material according to Comparative Example 6. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] In this specification, the term "step" includes not only an independent step, but also a step that cannot be clearly distinguished from other steps, as long as the intended purpose of the step is achieved. In addition, the content of each component in the composition means the total amount of the multiple substances present in the composition when multiple substances corresponding to each component are present in the composition, unless otherwise specified. Hereinafter, the embodiments of the present invention will be described in detail. However, the embodiments shown below are examples of positive electrode active materials for non-aqueous electrolyte secondary batteries and methods for producing the same for embodying the technical idea of ​​the present invention, and the present invention is not limited to the positive electrode active materials for non-aqueous electrolyte secondary batteries and methods for producing the same shown below.

[0011] Cathode active material for non-aqueous electrolyte secondary batteries The positive electrode active material for non-aqueous electrolyte secondary batteries (hereinafter simply referred to as the positive electrode active material) has an average particle diameter D SEM 50% particle size D of cumulative particle size distribution based on volume 50 Ratio of D 50 / D SEMThe lithium transition metal composite oxide particles (hereinafter also simply referred to as composite oxide particles) have a layered structure and contain lithium, nickel, cobalt and manganese as a composition, with a molar ratio of 1 to 4. The lithium transition metal composite oxide (hereinafter also simply referred to as composite oxide) constituting the composite oxide particles may have a composition in which the ratio of the number of moles of nickel to the total number of moles of metals other than lithium is greater than 0.8 and less than 1, the ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is less than 0.2, the ratio of the number of moles of manganese to the total number of moles of metals other than lithium is less than 0.2, and the ratio of the number of moles of manganese to the sum of the number of moles of cobalt and the number of moles of manganese is less than 0.58.

[0012] The ratio of the mole number of nickel in the composition is equal to or greater than a predetermined value, the ratio of the mole number of manganese to cobalt and manganese is less than a predetermined value, and the ratio D 50 / D SEM A positive electrode active material containing a lithium transition metal composite oxide particle in a single particle form having a molar ratio of manganese within a predetermined range can achieve both excellent initial efficiency and durability at a high level in a nonaqueous electrolyte secondary battery containing the positive electrode active material. This is thought to be because the crystal structure is more stable than that of a lithium transition metal composite oxide particle in a single particle form that does not contain manganese in its composition, and therefore the initial efficiency and durability are improved. In addition, compared to a lithium transition metal composite oxide particle in a single particle form in which the molar ratio of manganese to cobalt and manganese is a predetermined value or more, the manganese is prevented from acting as a resistor, and therefore the initial efficiency and durability are improved.

[0013] The composite oxide particles constituting the positive electrode active material have a ratio of D 50 / D SEM may be 1 or more and 4 or less. 50 / D SEM When the ratio D is 1, it indicates that the particles are single particles, and the closer it is to 1, the fewer the number of primary particles that make up the composite oxide particles. 50 / D SEM From the viewpoint of durability, the ratio D is preferably less than 4. 50 / D SEMThe lower limit of the number of primary particles constituting the composite oxide particle may be, for example, 1.1 or more. The number of primary particles constituting the composite oxide particle may be, for example, 30 or less, preferably 14 or less, and more preferably 7 or less. The lower limit of the number of primary particles constituting the composite oxide particle is 1 or more.

[0014] For composite oxide particles, the average particle size D based on electron microscope observation SEM However, from the viewpoint of durability, the thickness may be, for example, 1 μm or more and 7 μm or less. SEM From the viewpoints of power density and electrode plate packing property, D is preferably 1.1 μm or more, more preferably 1.2 μm or more, and further preferably 1.3 μm or more. SEM is preferably 5 μm or less, more preferably 4 μm or less, even more preferably 3 μm or less, particularly preferably 2 μm or less, and most preferably 1.6 μm or less.

[0015] Average particle size D based on electron microscope observation SEM is obtained by observing using a scanning electron microscope (SEM) at a magnification range of 1000x to 10000x depending on the particle size, selecting 100 primary particles whose particle outlines can be confirmed, calculating the equivalent sphere diameter of the selected particles using image processing software, and taking the arithmetic mean of the obtained equivalent sphere diameters. Here, being able to confirm the particle outline means that the outline of the primary particle can be traced on the SEM image.

[0016] The 50% particle size D 50 may be, for example, 1 μm or more and 15 μm or less. 50 From the viewpoint of power density, the 50% particle diameter D is preferably 1.5 μm or more, more preferably 2.5 μm or more, even more preferably 3 μm or more, particularly preferably 3.2 μm or more, and most preferably 4 μm or more. 50 is preferably 8 μm or less, more preferably 6 μm or less, further preferably 5.6 μm or less, and particularly preferably 5.4 μm or less.

[0017] 50% particle size D 50is determined as the particle size corresponding to 50% cumulative volume from the small diameter side in the cumulative particle size distribution on a volume basis measured under wet conditions using a laser diffraction particle size distribution analyzer. 90 and 10% particle size D 10 are calculated as the particle diameters corresponding to 90% and 10% cumulative volumes from the small diameter side, respectively.

[0018] The composite oxide particles have a 90% particle size D 90 10% particle size D 10 The ratio of D to, for example, indicates the spread of the particle size distribution, and the smaller the ratio value, the more uniform the particle size. 90 / D 10 The ratio D may be, for example, 4.5 or less. 90 / D 10 From the viewpoint of power density, the ratio D is preferably 4 or less, and more preferably 3.9 or less. 90 / D 10 The lower limit can be, for example, 1.2 or more.

[0019] The lithium transition metal composite oxide (hereinafter also referred to as composite oxide) constituting the composite oxide particles has a layered structure containing lithium (Li), nickel (Ni), cobalt (Co) and manganese (Mn) in its composition. The composition of the composite oxide may have a ratio of the number of moles of nickel to the total number of moles of metals other than lithium that is, for example, greater than 0.8 and less than 1. The ratio of the number of moles of nickel to the total number of moles of metals other than lithium is preferably 0.82 or more, more preferably 0.85 or more, and particularly preferably 0.87 or more. The ratio of the number of moles of nickel to the total number of moles of metals other than lithium is preferably 0.92 or less, and more preferably 0.9 or less. The composition of the composite oxide may have a ratio of the number of moles of cobalt to the total number of moles of metals other than lithium that is, for example, less than 0.2. The ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is preferably less than 0.19, more preferably less than 0.18, even more preferably 0.16 or less, even more preferably 0.13 or less, and particularly preferably 0.09 or less. The ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is preferably 0.03 or more, more preferably 0.05 or more. The composition of the composite oxide may be, for example, a ratio of the number of moles of manganese to the total number of moles of metals other than lithium less than 0.2. The ratio of the number of moles of manganese to the total number of moles of metals other than lithium is preferably less than 0.19, more preferably less than 0.18, even more preferably 0.16 or less, even more preferably 0.1 or less, and particularly preferably 0.05 or less. The ratio of the number of moles of manganese to the total number of moles of metals other than lithium is preferably 0.01 or more, more preferably 0.03 or more. The composition of the composite oxide may be, for example, a ratio of the molar ratio of lithium to the total number of moles of metals other than lithium less than 1 and 1.15. The molar ratio of lithium to the total number of moles of metals other than lithium is preferably 1.01 or more, more preferably 1.03 or more. The molar ratio of lithium to the total number of moles of metals other than lithium is preferably 1.1 or less, more preferably 1.06 or less.

[0020] The composition of the composite oxide may be, for example, less than 0.58 in terms of discharge capacity, in which the ratio of the moles of manganese to the total moles of cobalt and manganese is 0.05 or more, more preferably 0.1 or more. The ratio of the moles of manganese to the total moles of cobalt and manganese is preferably 0.5 or less, more preferably 0.4 or less, particularly preferably 0.3 or less, and most preferably 0.25 or less.

[0021] The molar ratio of nickel, cobalt and manganese in the composite oxide may be, for example, nickel:cobalt:manganese=(0.8 to 0.98):(0.01 to 0.18):(0.01 to 0.18), and is preferably (0.85 to 0.95):(0.03 to 0.15):(0.01 to 0.06).

[0022] The composite oxide is made of metals other than lithium, nickel, cobalt and manganese. 1 The metal M may further comprise 1 Examples of the element include aluminum (Al), boron (B), sodium (Na), magnesium (Mg), silicon (Si), phosphorus (P), sulfur (S), potassium (K), calcium (Ca), titanium (Ti), vanadium (V), chromium (Cr), zinc (Zn), strontium (Sr), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), indium (In), tin (Sn), barium (Ba), lanthanum (La), cerium (Ce), neodymium (Nd), samarium (Sm), europium (Eu), and gadolinium (Gd). At least one element selected from the group consisting of these elements may be used.

[0023] The composite oxide is metal M 1 If lithium is included, the number of moles of metal M relative to the total number of moles of metals other than lithium is 1 The ratio of the number of moles of metal M to the total number of moles of metals other than lithium may be, for example, 0.1 or less. 1is preferably 0.05 or less, more preferably 0.04 or less, and is preferably 0.005 or more, more preferably 0.01 or more.

[0024] The composite oxide may have a composition represented by the following formula (1), for example. Li p Ni x Co y Mn z M 1 w O2(1) In formula (1), 1≦p≦1.15, 0.8 <x<1、0<y<0.2、0<z<0.2、0≦w≦0.1、x+y+z+w≦1、0<z / (y+z)<0.58である。M 1 is at least one selected from the group consisting of Al, B, Na, Mg, Si, P, S, K, Ca, Ti, V, Cr, Zn, Sr, Y, Zr, Nb, Mo, In, Sn, Ba, La, Ce, Nd, Sm, Eu, and Gd. Preferably, 1.01≦p≦1.1, 0.82≦x≦0.92, 0.03≦y<0.18, 0.01≦z<0.18, 0≦w≦0.1, x+y+z+w≦1, 0.05≦z / (y+z)≦0.5, and more preferably, 1.01≦p≦1.1, 0.82≦x≦0.92, 0.03≦y<0.18, 0.01≦z<0.18, 0.005≦w≦0.05, x+y+z+w≦1, 0.05≦z / (y+z)≦0.5.

[0025] From the viewpoint of the initial efficiency of the non-aqueous electrolyte secondary battery, the complex oxide may have a disorder of nickel element determined by X-ray diffraction method of, for example, 3% or less. The disorder of nickel element is preferably 2% or less, more preferably 1.8% or less, even more preferably 1.2% or less, particularly preferably 0.8% or less, and most preferably 0.4% or less. The lower limit of the disorder of nickel element can be, for example, 0.05% or more. Here, the disorder of nickel element means a chemical disorder of the transition metal ion (nickel ion) that should occupy the original site. In the complex oxide with a layered structure, the representative example is the replacement of the lithium ion that should occupy the site represented by 3b (3b site, the same below) and the transition metal ion that should occupy the 3a site when expressed by the Wyckoff symbol. The smaller the disorder of nickel element, the more the initial efficiency tends to improve.

[0026] The disorder of nickel element in the composite oxide can be obtained as follows. X-ray diffraction spectrum of the composite oxide is measured by CuKα radiation. The composition model is Li 1-d Ni d MeO2 (Me is a transition metal other than nickel in the composite oxide) is used, and structural optimization is performed by Rietveld analysis based on the obtained X-ray diffraction spectrum. The percentage of d calculated as a result of structural optimization is the disorder value of the nickel element.

[0027] The lithium transition metal composite oxide constituting the positive electrode active material may have a boron-containing deposit in at least a part of the surface. The boron-containing deposit may further contain oxygen, lithium, etc. in addition to boron. Specific examples of the boron-containing deposit include lithium metaborate (LiBO2) and boric acid (H3BO3). The boron-containing deposit may be physically attached to the lithium transition metal composite oxide, and at least a part of the deposit may chemically form a compound with the lithium transition metal composite oxide. The content of the boron-containing deposit in the positive electrode active material may be, for example, 0.1 mol% or more and 3 mol% or less as a ratio of the number of moles of boron to the total number of moles of metals other than lithium in the lithium transition metal composite oxide. The content of the boron-containing deposit in the positive electrode active material is preferably 0.2 mol% or more, more preferably 0.3 mol% or more, and particularly preferably 0.5 mol% or more as a ratio of the number of moles of boron to the total number of moles of metals other than lithium in the lithium transition metal composite oxide. The content of the boron-containing deposit is preferably 1.5 mol% or less, more preferably 1 mol% or less, and particularly preferably 0.6 mol% or less. The content of the boron-containing deposit in the positive electrode active material can be measured, for example, by an inductively coupled plasma optical emission spectrometer.

[0028] Method for producing positive electrode active material for non-aqueous electrolyte secondary battery The method for producing a positive electrode active material for a non-aqueous electrolyte secondary battery includes the steps of: preparing a composite containing nickel, cobalt, and manganese as metal components, the ratio of the number of moles of nickel to the total number of moles of the metal components being greater than 0.8 and less than 1; the ratio of the number of moles of cobalt to the total number of moles of the metal components being less than 0.2; the ratio of the number of moles of manganese to the total number of moles of the metal components being less than 0.2; and the ratio of the number of moles of manganese to the sum of the number of moles of cobalt and the number of moles of manganese being less than 0.58; mixing the prepared composite with a lithium compound and an alkali metal compound having a melting point of 400° C. or less and containing an alkali metal other than lithium to obtain a lithium mixture; synthesizing the lithium mixture at a temperature of 650° C. or more and 800° C. or less to obtain a heat-treated product; dispersing the heat-treated product in a dry dispersion process to obtain a first dispersion; and contacting the first dispersion with a liquid medium and then removing at least a part of the liquid medium. The lithium transition metal composite oxide obtained after the washing step has an average particle size D based on observation with an electron microscope. SEM 50% particle size D of cumulative particle size distribution based on volume 50 Ratio of D 50 / D SEM may be 1 or more and 4 or less.

[0029] The alkali metal compound containing an alkali metal other than lithium having a melting point of 400°C or less promotes sintering, and therefore, at a relatively low heat treatment temperature, the ratio of the mole number of nickel in the composition is a predetermined value or more, the ratio of the mole number of manganese to cobalt and manganese is less than a predetermined value, and the ratio D 50 / D SEM The lithium transition metal composite oxide particles obtained by this production method have a single particle form and have a specific range of . As a result, the lithium transition metal composite oxide particles obtained by this production method are prevented from generating impurity phases that become resistance components during charging and discharging due to thermal reduction during heat treatment. Therefore, it is believed that a nonaqueous electrolyte secondary battery containing the lithium transition metal composite oxide particles can achieve excellent initial efficiency and durability.

[0030] Preparation process In the preparation step, a composite having a desired composition is prepared. The composite may include metal components including at least nickel, cobalt, and manganese, and oxygen atoms. The composite may include oxides, hydroxides, carbonates, acetates, etc. of the metal components, and may include at least oxides.

[0031] The composition of the composite may have a ratio of the number of moles of nickel to the total number of moles of the metal components greater than 0.8 and less than 1, for example. The ratio of the number of moles of nickel to the total number of moles of the metal components is preferably 0.82 or more, more preferably 0.85 or more, and even more preferably 0.87 or more. The ratio of the number of moles of nickel to the total number of moles of the metal components is preferably 0.92 or less, and more preferably 0.90 or less. The composition of the composite may have a ratio of the number of moles of cobalt to the total number of moles of metals other than lithium less than 0.2, for example. The ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is preferably less than 0.19, more preferably 0.16 or less, even more preferably 0.13 or less, and particularly preferably 0.09 or less. The ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is preferably 0.03 or more, and more preferably 0.05 or more. The composition of the composite may have a ratio of the number of moles of manganese to the total number of moles of metals other than lithium less than 0.2, for example. The ratio of the number of moles of manganese to the total number of moles of metals other than lithium is preferably less than 0.19, more preferably 0.16 or less, even more preferably 0.1 or less, and particularly preferably 0.05 or less. The ratio of the number of moles of manganese to the total number of moles of metals other than lithium is preferably 0.01 or more, more preferably 0.03 or more.

[0032] The composition of the composite may be, for example, less than 0.58 in terms of discharge capacity, in which the ratio of the number of moles of manganese to the total number of moles of cobalt and manganese is preferably 0.05 or more, more preferably 0.1 or more. The ratio of the number of moles of manganese to the total number of moles of cobalt and manganese is preferably 0.5 or less, more preferably 0.4 or less, even more preferably 0.3 or less, and particularly preferably 0.25 or less.

[0033] The molar ratio of nickel, cobalt and manganese in the composite may be, for example, nickel:cobalt:manganese=(0.8 to 0.98):(0.01 to 0.18):(0.01 to 0.18), preferably (0.85 to 0.95):(0.03 to 0.15):(0.01 to 0.06).

[0034] The compound contains metals other than lithium, nickel, cobalt and manganese. 1 The metal M may further comprise 1 Examples of the element include aluminum (Al), boron (B), sodium (Na), magnesium (Mg), silicon (Si), phosphorus (P), sulfur (S), potassium (K), calcium (Ca), titanium (Ti), vanadium (V), chromium (Cr), zinc (Zn), strontium (Sr), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), indium (In), tin (Sn), barium (Ba), lanthanum (La), cerium (Ce), neodymium (Nd), samarium (Sm), europium (Eu), and gadolinium (Gd). At least one element selected from the group consisting of these elements may be used.

[0035] The compound is metal M 1 If lithium is included, the number of moles of metal M relative to the total number of moles of metals other than lithium is 1 The ratio of the number of moles of metal M to the total number of moles of metals other than lithium may be, for example, 0.1 or less. 1is preferably 0.05 or less, more preferably 0.04 or less, and is preferably 0.005 or more, more preferably 0.01 or more.

[0036] The composite may be prepared by appropriately selecting from commercially available products, or by preparing a composite having a desired composition by a conventional method. Examples of a method for obtaining a composite having a desired composition include a method in which raw material compounds (hydroxides, carbonates, etc.) are mixed according to the target composition and decomposed into a composite by heat treatment, and a coprecipitation method in which a raw material compound soluble in a solvent is dissolved in a solvent, and a precursor precipitate having the target composition is obtained by adjusting the temperature, adjusting the pH, adding a complexing agent, etc., and the precursor precipitate is heat-treated to obtain a composite. An example of a method for producing a composite is described below.

[0037] The method for obtaining a composite by coprecipitation may include a seed generation step of adjusting the pH of a mixed solution containing metal ions in a desired composition ratio to obtain a seed crystal, a crystallization step of growing the generated seed crystal to obtain a precursor precipitate having desired properties, and a step of heat-treating the obtained precursor precipitate to obtain a composite. For details of the method for obtaining such a composite, for example, JP 2003-292322 A, JP 2011-116580 A (US Patent Publication 2012-270107 A), etc. may be referred to.

[0038] In the seed generation step, the pH of a mixed solution containing nickel ions, cobalt ions, and manganese ions in a desired composition ratio is adjusted to, for example, 11 to 13 to prepare a liquid medium containing seed crystals. The seed crystals may contain, for example, a composite hydroxide containing nickel, cobalt, and manganese in a desired ratio. The mixed solution can be prepared by dissolving nickel salt, cobalt salt, and manganese salt in water in a desired ratio. Examples of nickel salt, cobalt salt, and manganese salt include sulfate salt, nitrate salt, and hydrochloride salt. In addition to nickel salt, cobalt salt, and manganese salt, the mixed solution may contain other metal salts (for example, metal M) as needed. 1The temperature in the seed generating step may be, for example, 40° C. to 80° C. The atmosphere in the seed generating step may be a low oxidizing atmosphere, and the oxygen concentration may be maintained at, for example, 10% by volume or less.

[0039] In the crystallization step, the generated seed crystals are grown to obtain a precursor precipitate containing nickel, cobalt, and manganese having desired properties. The precursor precipitate may, for example, contain a composite hydroxide containing nickel, cobalt, and manganese in a desired ratio. The seed crystals can be grown, for example, by adding a mixed solution containing nickel ions, cobalt ions, and manganese ions, and other metal ions as necessary, to a liquid medium containing the seed crystals while maintaining the pH at, for example, 7 to 12.5, preferably 7.5 to 12. The addition time of the mixed solution may be, for example, 1 hour to 24 hours, preferably 3 hours to 18 hours. The temperature in the crystallization step may be, for example, 40°C to 80°C. The atmosphere in the crystallization step is the same as that in the seed generation step. The pH in the seed generation step and the crystallization step can be adjusted using an acidic aqueous solution such as an aqueous sulfuric acid solution or an aqueous nitric acid solution, an alkaline aqueous solution such as an aqueous sodium hydroxide solution, or an aqueous ammonia solution.

[0040] In the step of obtaining a composite, the precursor precipitate obtained in the crystallization step is heat-treated to obtain a composite. The heat treatment may be performed by heating the precursor precipitate at a temperature of, for example, 500°C or less, preferably 350°C or less. The temperature of the heat treatment may be, for example, 100°C or more, preferably 200°C or more. The time of the heat treatment may be, for example, 0.5 hours to 48 hours, preferably 5 hours to 24 hours. The atmosphere of the heat treatment may be air or an atmosphere containing oxygen. The heat treatment may be performed using, for example, a box furnace, a rotary kiln furnace, a pusher furnace, a roller hearth kiln furnace, or the like.

[0041] The average particle size of the composite may be, for example, 2 μm or more and 30 μm or less. The average particle size of the composite is preferably 3 μm or more and 25 μm or less. The average particle size of the composite is a volume average particle size, and is a value at which the volume integrated value from the small particle size side in the volume-based particle size distribution obtained by a laser scattering method is 50%.

[0042] Mixing process In the mixing step, the composite, the lithium compound, and an alkali metal compound having a melting point of 400° C. or less and containing an alkali metal other than lithium are mixed to obtain a lithium mixture. Examples of the lithium compound include lithium hydroxide, lithium carbonate, and lithium oxide. The lithium compound used for mixing may be either a solid or a solution. The particle size of the solid lithium compound may be, for example, 0.1 μm or more and 100 μm or less, as a volume average particle size, and preferably 2 μm or more and 20 μm or less. The mixing ratio of the composite and the lithium compound may be, for example, a mixing ratio in which the ratio of the number of moles of lithium contained in the lithium compound to the total number of moles of metal elements contained in the composite is 0.95 or more and 1.2 or less, and preferably 1 or more and 1.1 or less.

[0043] Examples of the alkali metal other than lithium contained in the alkali metal compound include sodium, potassium, rubidium, cesium, etc., and may be at least one selected from the group consisting of these, and may include at least one of sodium and potassium. The alkali metal compound may be, for example, a hydroxide, an oxide, a carbonate, an acetate, etc., and may be at least one selected from the group consisting of these. The melting point of the alkali metal compound may be, for example, 400°C or less or 365°C or less, and may be 200°C or more or 280°C or more. Specific examples of the alkali metal compound include potassium hydroxide (melting point 360°C), sodium hydroxide (melting point 318°C), potassium acetate (melting point 292°C), etc.

[0044] The alkali metal compound used for mixing may be either a solid or a solution. The particle size of the solid alkali metal compound may be, for example, 0.1 μm to 100 μm, preferably 2 μm to 20 μm, as the volume average particle size. The concentration of the alkali metal compound in the solution may be, for example, 10 mass% to 60 mass%, preferably 40 mass% to 55 mass%. The mixing ratio of the complex and the alkali metal compound may be such that the ratio of the number of moles of the alkali metal contained in the alkali metal compound to the total number of moles of the metal elements contained in the complex is, for example, 0.03 to 0.15. The mixing ratio of the complex and the alkali metal compound is such that the ratio of the number of moles of the alkali metal to the total number of moles of the metal elements in the complex is, preferably, 0.055 to 0.1.

[0045] In the mixing step, the composite, the lithium compound, and the alkali metal compound may be mixed simultaneously, the composite and the lithium compound may be mixed and then the alkali metal compound may be mixed, or the composite and the alkali metal compound may be mixed and then the lithium compound may be mixed. The mixing may be performed using, for example, a high-speed shear mixer.

[0046] The lithium mixture contains other metals than nickel, cobalt, manganese, lithium and alkali metals (e.g., metal M 1 The lithium mixture may further contain other metals (metals excluding alkali metals). As the other metals, preferably, Al, Zr, Ti, Mg, Ta, Nb, Mo, W, etc. are mentioned, and at least one selected from the group consisting of these is more preferable. When the lithium mixture contains other metals, the lithium mixture can be obtained by mixing the simple substance or metal compound of the other metal with the composite, the lithium compound, and the alkali metal compound. As the metal compound containing the other metal, oxides, hydroxides, chlorides, nitrides, carbonates, sulfates, nitrates, acetates, oxalates, etc. can be mentioned.

[0047] When the lithium mixture contains other metals, the ratio of the total number of moles of the other metals to the total number of moles of the metal components constituting the composite may be, for example, 0.005 or more and 0.1 or less. The ratio of the total number of moles of the other metals to the total number of moles of the metal components constituting the composite is preferably 0.01 or more and 0.05 or less.

[0048] Synthesis process In the synthesis step, the lithium mixture is heat-treated at a temperature of 650°C or more and 800°C or less to obtain a heat-treated product. The heat-treated product may contain, for example, a lithium transition metal composite oxide. The heat treatment may be performed at a single temperature or at multiple temperatures. When heat-treating at multiple temperatures, for example, after heating to a first temperature, the first temperature may be held for a predetermined time, and then the temperature may be further raised to a second temperature and held for a predetermined time at the second temperature. The first temperature may be, for example, 200°C or more and 600°C or less, and preferably 400°C or more and 500°C or less. The second temperature may be, for example, 650°C or more and 800°C or less, and preferably 700°C or more and 780°C or less. The heat treatment time may be, for example, 0.5 hours to 48 hours, and when heat treatment is performed at multiple temperatures, each may be 0.2 hours to less than 48 hours.

[0049] The heat treatment may be performed in an atmosphere containing oxygen or in the air, and may be performed using, for example, a box furnace, a rotary kiln furnace, a pusher furnace, a roller hearth kiln furnace, or the like.

[0050] Dispersion process In the dispersion step, the heat-treated material is subjected to a dry dispersion treatment to obtain a first dispersion. By performing a dry dispersion treatment instead of a crushing treatment involving strong shearing force, impact, etc., the desired ratio D 50 / D SEM A first dispersion containing a lithium transition metal composite oxide having a particle size distribution or the like can be obtained. In the method for producing a positive electrode active material, the heat-treated material may be subjected to a crushing treatment prior to the dispersion treatment, or a classification treatment may be performed after the dispersion treatment. The dry dispersion treatment can be performed using, for example, a ball mill, a jet mill, or the like, using, for example, air as a dispersion medium.

[0051] For example, when the dispersion treatment is performed using a ball mill, a resin media can be used. Examples of the material of the resin media include urethane resin and nylon resin. By using the resin media, the sintered primary particles are dissociated without the particles being crushed. The size of the resin media may be, for example, φ5 mm or more and 30 mm or less. For the body (shell), for example, a urethane resin or a nylon resin can be used. The time for the dispersion treatment may be, for example, 3 minutes or more and 60 minutes or less, and preferably 10 minutes or more and 30 minutes or less. The conditions for the dispersion treatment using a ball mill include a desired ratio D 50 / D SEM In order to achieve the ratio D 90 / D 10 Depending on the above, the amount of media, rotation or oscillation speed, dispersion time, media specific gravity, etc. may be adjusted.

[0052] For example, when dispersion is performed using a jet mill, the primary particles are not pulverized and the desired ratio D 50 / D SEM The ratio of the raw material compounds D 90 / D 10 The supply pressure, pulverization pressure, supply speed, etc. may be adjusted according to the above. The supply pressure may be, for example, 0.1 MPa or more and 0.5 MPa or less. The pulverization pressure may be, for example, 0.1 MPa or more and 0.6 MPa or less.

[0053] Cleaning process In the washing step, the first dispersion containing the lithium transition metal composite oxide particles is contacted with a liquid medium, and then at least a part of the liquid medium is removed to obtain a second dispersion. The second dispersion may be subjected to a deliquoring process, a drying process, or the like, as necessary. The washing step may be, for example, a step of removing at least a part of the unreacted raw material alkaline component (e.g., lithium compound) present in the first dispersion.

[0054] The liquid medium used in the washing step may contain at least water, and may contain liquid components other than water, metal salts, etc. as necessary. Examples of liquid components other than water include water-soluble organic solvents such as alcohol. Examples of metal salts include alkali metal salts such as lithium and sodium. By containing a metal salt in the liquid medium, the alkali components of the unreacted raw materials can be removed more efficiently. Examples of metal salts include sulfates and hydroxides. When the liquid medium contains a metal salt, the content of the metal salt may be, for example, 0.01 mol / L or more and 2.0 mol / L or less in terms of the molar concentration of the metal ion. The content of the metal salt is preferably 0.015 mol / L or more and 1.0 mol / L or less, more preferably 0.015 mol / L or more and 0.2 mol / L or less, and even more preferably 0.015 mol / L or more and 0.15 mol / L or less.

[0055] The contact temperature between the first dispersion and the liquid medium may be, for example, 5° C. to 60° C., and preferably 10° C. to 40° C. The contact time may be, for example, 1 minute to 2 hours, and preferably 5 minutes to 30 minutes. The amount of the liquid medium used for the contact may be, for example, 0.5 to 10 times, and preferably 1 to 4 times, the mass of the first dispersion.

[0056] The contact between the first dispersion and the liquid medium may be carried out by preparing a slurry by putting the first dispersion into the liquid medium. When the contact is carried out as a slurry, the solid content concentration of the first dispersion in the slurry may be, for example, 10% by mass or more and 70% by mass or less, and preferably 20% by mass or more and 50% by mass or less. In the contact between the first dispersion and the liquid medium, the mixture of the first dispersion and the liquid medium may be stirred as necessary. The stirring may be carried out using, for example, a high-speed stirring mixer, a double cone, a kneader, or the like. The contact between the first dispersion and the liquid medium may also be carried out by passing the liquid medium through the first dispersion held on a filter.

[0057] The second dispersion obtained in the washing step may be dried. The drying process may be performed by heating, air drying, or vacuum drying, as long as at least a part of the liquid medium attached to the second dispersion can be removed. The drying temperature in the case of heating and drying may be any temperature at which the liquid medium contained in the second dispersion is sufficiently removed. The drying temperature may be, for example, 80°C or higher and 300°C or lower, and preferably 150°C or higher and 280°C or lower. When the drying temperature is within the above range, the dissolution of lithium into the attached liquid medium can be sufficiently suppressed. In addition, the collapse of the crystal structure on the particle surface can be suppressed, and the charge / discharge capacity can be sufficiently suppressed from decreasing. The drying time may be appropriately selected depending on the amount of water contained in the second dispersion. The drying time is, for example, 1 hour or higher and 12 hours or lower. The amount of water contained in the second dispersion after the drying process may be, for example, 0.2 mass% or less, and preferably 0.1 mass% or less.

[0058] The lithium transition metal composite oxide contained in the second dispersion obtained by the above-mentioned production method has a ratio D 50 / D SEM may be 1 or more and 4 or less. The composition may contain lithium, nickel, cobalt, and manganese, and the ratio of the number of moles of nickel to the total number of moles of metal components other than lithium may be greater than 0.8 and less than 1, the ratio of the number of moles of cobalt may be less than 0.2, the ratio of the number of moles of manganese to the total number of moles of cobalt and manganese may be less than 0.58. The lithium transition metal composite oxide may have a composition represented by the above formula (1), for example.

[0059] The method for producing a positive electrode active material may include, as necessary, an attachment step of disposing a boron-containing deposit on the surface of the lithium transition metal composite oxide obtained in the washing step. By constructing a battery using a positive electrode active material including a lithium transition metal composite oxide having a boron-containing deposit on its surface, the discharge capacity of the battery can be further improved. The attachment step may include, for example, a boron mixing step of mixing the lithium transition metal composite oxide with a boron source compound that is a raw material for the boron-containing deposit to obtain a boron mixture, and a boron heat treatment step of heat-treating the boron mixture.

[0060] In the boron mixing step, the lithium transition metal composite oxide and the boron source compound are mixed to obtain a boron mixture. The lithium transition metal composite oxide and the boron source compound may be mixed in a dry manner or in a wet manner. The mixing may be performed using, for example, a super mixer.

[0061] The boron source compound may be at least one selected from the group consisting of boron oxide, boron oxoacids, and boron oxoacid salts. More specific examples of the boron source compound include lithium tetraborate (Li2B4O7), ammonium pentaborate (NH4B5O8), orthoboric acid (H3BO3; so-called ordinary boric acid), lithium metaborate (LiBO2), boron oxide (B2O3), etc., and may be at least one selected from the group consisting of these, and may be orthoboric acid from the viewpoint of cost.

[0062] The boron source compound may be mixed with the lithium transition metal composite oxide in a solid state, or may be mixed with the lithium transition metal composite oxide as a solution of the boron source compound. When a solid state boron source compound is used, the volume average particle size of the boron source compound may be, for example, 1 μm or more and 60 μm or less, and preferably 10 μm or more and 30 μm or less.

[0063] The content of the boron source compound in the boron mixture, expressed as the ratio of the number of moles of elemental boron to the total number of moles of metals other than lithium in the lithium transition metal composite oxide, may be 0.1 mol% or more and 3 mol% or less, preferably 0.2 mol% or more, more preferably 0.3 mol% or more, particularly preferably 0.5 mol% or more, preferably 1.5 mol% or less, more preferably 1 mol% or less, and particularly preferably 0.6 mol% or less.

[0064] The boron mixture may further contain a lithium compound as necessary. Examples of the lithium compound include lithium hydroxide, lithium oxide, lithium carbonate, lithium nitrate, etc., and may be at least one selected from the group consisting of these.

[0065] The lithium compound may be mixed with the lithium transition metal composite oxide and the boron source compound in a solid state, or may be mixed with the lithium transition metal composite oxide and the boron source compound as a solution of the lithium compound. When a solid lithium compound is used, the volume average particle size of the lithium compound may be, for example, 1 μm or more and 60 μm or less, and preferably 10 μm or more and 30 μm or less.

[0066] The content of the lithium compound in the boron mixture may be, for example, 0.05 mol% or more and 1 mol% or less, preferably 0.05 mol% or more and 0.5 mol% or less, and more preferably 0.1 mol% or more and 0.3 mol% or less, as a ratio of the number of moles of lithium to the total number of moles of metals other than lithium in the lithium transition metal composite oxide.

[0067] In the boron heat treatment step, the boron mixture is heat treated to obtain a positive electrode active material containing a lithium transition metal composite oxide having a boron-containing deposit on the surface. The temperature of this heat treatment may be, for example, 100°C or more and 450°C or less, preferably 150°C or more and 400°C or less, more preferably 200°C or more and 400°C or less, more preferably 220°C or more and 350°C or less, and even more preferably 250°C or more and 350°C or less. The atmosphere of this heat treatment may be an oxygen-containing atmosphere or may be air. The time of this heat treatment may be, for example, 1 hour or more and 20 hours or less, preferably 5 hours or more and 15 hours or less. The heat-treated product obtained in the boron heat treatment step may be subjected to a crushing treatment, a classification treatment, or the like, as necessary.

[0068] Electrodes for non-aqueous electrolyte secondary batteries The electrode for a non-aqueous electrolyte secondary battery includes a current collector and a positive electrode active material layer disposed on the current collector and containing the positive electrode active material for a non-aqueous electrolyte secondary battery produced by the above-mentioned production method. A non-aqueous electrolyte secondary battery including such an electrode can achieve high initial efficiency and high durability.

[0069] Examples of the material of the current collector include aluminum, nickel, stainless steel, etc. The positive electrode active material layer can be formed by applying a positive electrode mixture obtained by mixing the above-mentioned positive electrode active material, conductive material, binder, etc. with a solvent onto the current collector, and then performing a drying process, a pressure process, etc. Examples of the conductive material include natural graphite, artificial graphite, acetylene black, etc. Examples of the binder include polyvinylidene fluoride, polytetrafluoroethylene, polyamide acrylic resin, etc.

[0070] Nonaqueous electrolyte secondary battery The nonaqueous electrolyte secondary battery includes the above-mentioned electrode for nonaqueous electrolyte secondary battery. The nonaqueous electrolyte secondary battery includes, in addition to the electrode for nonaqueous electrolyte secondary battery, a negative electrode for nonaqueous electrolyte secondary battery, a nonaqueous electrolyte, a separator, etc. In the nonaqueous electrolyte secondary battery, the negative electrode, nonaqueous electrolyte, separator, etc., for example, those for nonaqueous electrolyte secondary batteries described in JP 2002-075367 A, JP 2011-146390 A, JP 2006-12433 A (the entire disclosures of which are incorporated herein by reference) can be appropriately used. EXAMPLES

[0071] The present invention will be described in more detail below with reference to examples, but the present invention is not limited to these examples.

[0072] Example 1 Seed generation process 10 kg of water was put into the reaction tank, and while stirring, an aqueous ammonia solution was added to adjust the ammonium ion concentration to 1.8% by mass. The temperature inside the tank was set to 25°C, nitrogen gas was circulated, and the oxygen concentration in the space inside the reaction tank was maintained at 10% or less. A 25% by mass aqueous sodium hydroxide solution was added to the water in the reaction tank, and the pH value of the solution in the tank was adjusted to 13.5 or more. Next, a nickel sulfate solution, a cobalt sulfate solution, and a manganese sulfate solution were mixed in a molar ratio of 88:9:3 to prepare a mixed solution (1.7 mol / L). The mixed solution was added to the tank until the solute amounted to 4 mol, and seeds were generated while controlling the pH value of the reaction solution to 12.0 or more with a sodium hydroxide solution.

[0073] Crystallization process After the seed generation process, the temperature in the tank was maintained at 25°C or higher until the end of the crystallization process. A mixed solution of 1200 moles of solute was prepared and added simultaneously with the aqueous ammonia solution over a period of 5 hours or more to prevent new seed generation in the reaction tank while maintaining the ammonium ion concentration in the solution at 2000 ppm or higher. During the reaction, the pH value in the reaction solution was controlled to be maintained at 10.5 to 12.0 with a sodium hydroxide solution. Sampling was carried out sequentially during the reaction, and the D of the composite hydroxide particles was measured. 50 The addition was stopped when the particle size reached about 4.4 μm. The product was then washed with water, filtered, and dried to obtain composite hydroxide particles as a precursor precipitate.

[0074] The composite hydroxide particles thus obtained were subjected to a heat treatment at 300°C for 20 hours in an air atmosphere to obtain a composite hydroxide having a molar ratio of Ni / Co / Mn=0.88 / 0.09 / 0.03, D 10 = 3.4 μm, D 50 = 4.3 μm, D 90 = 5.5 μm, D 90 / D 10 The transition metal oxides were obtained as composites with a .DELTA.=1.6.

[0075] Synthesis process The obtained composite was mixed with an aqueous potassium hydroxide solution (concentration 50%) to give a molar ratio of K / (Ni+Co+Mn)=0.05, and then lithium hydroxide monohydrate was added and mixed to give a molar ratio of Li / (Ni+Co+Mn)=1.08 and aluminum hydroxide to give a molar ratio of Al / (Ni+Co+Mn)=0.01 to obtain a lithium mixture. The obtained lithium mixture was heat-treated in air at 450°C for 3 hours, and then continuously heat-treated at 750°C for 8 hours to obtain a heat-treated product. The obtained heat-treated product was crushed and dispersed in a resin ball mill for 15 minutes to obtain a powdered material.

[0076] The obtained powder was added to pure water to prepare a slurry with a solid content concentration of 30% by mass. The solid content concentration was calculated by the mass of the powder / (mass of the powder + mass of the cleaning solution). After stirring the slurry for 30 minutes, it was dehydrated in a funnel and separated as a cake. The separated cake was dried at 250°C for 10 hours to obtain a dried product. The obtained dried product was crushed and sieved to obtain a positive electrode active material containing a lithium transition metal composite oxide. An SEM image of the obtained positive electrode active material was obtained using a scanning electron microscope (SEM; accelerating voltage 20 kV). The SEM image of the obtained positive electrode active material is shown in Figure 1, and the physical properties are shown in Table 1.

[0077] Example 2 A lithium transition metal oxide was obtained in the same manner as in Example 1, except that in the seed generating step, the nickel sulfate solution, the cobalt sulfate solution, and the manganese sulfate solution were mixed in a molar ratio of 90:9:1 to prepare a mixed solution.

[0078] Attachment process The obtained lithium transition metal oxide was mixed with orthoboric acid in an amount of 0.3 mol% as boron element and lithium hydroxide monohydrate in an amount of 0.15 mol% as lithium element based on the total number of moles of metals other than lithium in the lithium transition metal composite oxide, and stirred to obtain a mixture containing boron and lithium. The obtained mixture was heat-treated at 300°C for 10 hours in air to obtain a positive electrode active material containing a lithium transition metal composite oxide having a boron-containing deposit on its surface. An SEM image of the obtained positive electrode active material is shown in Figure 2, and its physical properties are shown in Table 1.

[0079] Example 3 A positive electrode active material containing a lithium transition metal oxide having a boron-containing deposit on its surface was obtained in the same manner as in Example 2, except that in the seed generation step, a nickel sulfate solution, a cobalt sulfate solution, and a manganese sulfate solution were mixed in a molar ratio of 88:9:3 to prepare a mixed solution. An SEM image of the obtained positive electrode active material is shown in FIG. 3, and physical properties are shown in Table 1.

[0080] Example 4 A positive electrode active material containing a lithium transition metal oxide having a boron-containing deposit on its surface was obtained in the same manner as in Example 3, except that in the synthesis process, a sodium hydroxide aqueous solution (concentration 50%) was used instead of the potassium hydroxide aqueous solution, and Na / (Ni+Co+Mn)=0.08 was obtained. An SEM image of the obtained positive electrode active material is shown in FIG. 4, and its physical properties are shown in Table 1.

[0081] Example 5 A positive electrode active material containing a lithium transition metal oxide having a boron-containing deposit on its surface was obtained in the same manner as in Example 4, except that in the seed generation step, a nickel sulfate solution, a cobalt sulfate solution, and a manganese sulfate solution were mixed in a molar ratio of 92:5:3 to prepare a mixed solution, and in the synthesis step, aluminum hydroxide was added so that Al / (Ni+Co+Mn)=0.02. An SEM image of the obtained positive electrode active material is shown in FIG. 5, and physical properties are shown in Table 1.

[0082] Comparative Example 1 A positive electrode active material containing a lithium transition metal oxide was obtained in the same manner as in Example 1, except that in the seed generation step, a mixed solution was prepared by mixing a nickel sulfate solution and a cobalt sulfate solution in a molar ratio of 95:5 without using a manganese sulfate solution, that in the synthesis step, aluminum hydroxide was added so that Al / (Ni+Co+Mn)=0.02, and that the heat treatment temperature was changed from 750° C. to 725° C. A SEM image of the obtained positive electrode active material is shown in FIG. 6, and its physical properties are shown in Table 1.

[0083] Comparative Example 2 The lithium transition metal oxide obtained in Comparative Example 1 was subjected to an adhesion step in the same manner as in Example 2 to obtain a positive electrode active material containing a lithium transition metal oxide having a boron-containing adhesion on its surface. The SEM image of the obtained positive electrode active material is shown in FIG. 7, and the physical properties are shown in Table 1.

[0084] Comparative Example 3 A positive electrode active material containing a lithium transition metal oxide was obtained in the same manner as in Example 4, except that in the seed generation step, a nickel sulfate solution, a cobalt sulfate solution, and a manganese sulfate solution were mixed in a molar ratio of 88:5:7 to prepare a mixed solution, in the synthesis step, aluminum hydroxide was added in an amount of Al / (Ni+Co+Mn)=0.01, and the heat treatment temperature was changed from 750° C. to 810° C. An SEM image of the obtained positive electrode active material is shown in FIG. 8, and its physical properties are shown in Table 1.

[0085] Comparative Example 4 A positive electrode active material containing a lithium transition metal oxide having a boron-containing deposit on its surface was obtained in the same manner as in Example 3, except that the potassium hydroxide aqueous solution (concentration: 50%) was not used in the synthesis step. An SEM image of the obtained positive electrode active material is shown in FIG. 9, and physical properties are shown in Table 1.

[0086] Comparative Example 5 A positive electrode active material containing a lithium transition metal oxide having a boron-containing deposit on its surface was obtained in the same manner as in Comparative Example 2, except that in the synthesis step, a potassium hydroxide aqueous solution (concentration: 50%) was not used and the heat treatment temperature was changed from 725° C. to 710° C. The SEM image of the obtained positive electrode active material is shown in FIG. 10, and the physical properties are shown in Table 1.

[0087] Comparative Example 6 Except for not using the potassium hydroxide aqueous solution (concentration 50%) in the synthesis step, a positive electrode active material containing a lithium transition metal oxide was obtained in the same manner as in Example 1. The SEM image of the obtained positive electrode active material is shown in FIG. 11, and the physical properties are shown in Table 1.

[0088] Particle size evaluation The physical properties of the positive electrode active material obtained above were measured as follows. 50 The cumulative particle size distribution on a volume basis was measured using a laser diffraction particle size distribution analyzer (SALD-3100, manufactured by Shimadzu Corporation), and the particle size was calculated as the particle size corresponding to the cumulative 50% from the small diameter side. The average particle size D SEM For the measurement, 100 particles whose particle outlines could be confirmed were selected from images observed at 1,000 to 10,000 magnifications using a scanning electron microscope (SEM), and the spherical equivalent diameter of the selected particles was calculated using image processing software (ImageJ), and the arithmetic mean of the obtained spherical equivalent diameters was obtained.

[0089] Nickel Disorder (Ni Disorder) The positive electrode active material obtained above was subjected to X-ray diffraction spectrum measurement using CuKα radiation (tube current 200 mA, tube voltage 45 kV). Based on the obtained X-ray diffraction spectrum, a composition model was created (Li 1-d Ni d )(Ni x Co y Mn z Al w)O2(x+y+z+w=1), and the structure of the lithium transition metal composite oxide was optimized by Rietveld analysis using Rietan2000 software. The percentage of d calculated as a result of the structure optimization was taken as Ni disorder.

[0090] [Table 1]

[0091] Preparation of evaluation battery Using the positive electrode active material obtained above, a battery for evaluation was produced in the following manner.

[0092] Preparation of the positive electrode A positive electrode mixture was prepared by dispersing 92 parts by mass of the positive electrode active material, 3 parts by mass of acetylene black, and 5 parts by mass of polyvinylidene fluoride (PVDF) in N-methyl-2-pyrrolidone (NMP). The obtained positive electrode mixture was applied to an aluminum foil as a current collector, dried, compressed and molded with a roll press, and then cut to a predetermined size to prepare a positive electrode.

[0093] Preparation of the negative electrode A negative electrode slurry was prepared by dispersing and dissolving 97.5 parts by weight of artificial graphite, 1.5 parts by weight of carboxymethyl cellulose (CMC), and 1.0 parts by weight of SBR (styrene butadiene rubber) in pure water. The obtained negative electrode slurry was applied to a current collector made of copper foil, dried, compressed and molded with a roll press, and cut to a specified size to prepare a negative electrode.

[0094] Preparation of evaluation battery After attaching lead electrodes to the current collectors of the positive and negative electrodes, a separator was placed between the positive and negative electrodes, and they were stored in a bag-shaped laminate pack. Next, this was vacuum dried at 65°C to remove moisture adsorbed on each component. After that, an electrolyte was injected into the laminate pack under an argon atmosphere and sealed to prepare an evaluation battery. As the electrolyte, ethylene carbonate (EC) and methyl ethyl carbonate (MEC) were mixed in a volume ratio of 3:7, and lithium hexafluorophosphate (LiPF6) was dissolved in the mixture to a concentration of 1 mol / L. The evaluation battery thus obtained was placed in a thermostatic chamber at 25°C, aged with a weak current, and then evaluated as follows. The results are shown in Table 2.

[0095] Initial efficiency measurement The obtained evaluation battery was charged at a constant voltage and constant current with a charging voltage of 4.25 V and a charging current of 0.1 C, and the charge capacity was measured. After the measurement, constant current discharge was performed with a discharging voltage of 2.5 V and a discharging current of 0.1 C, and the discharge capacity was measured.

[0096] Capacity retention rate measurement The obtained evaluation battery was aged by performing a single charge / discharge cycle consisting of a constant-voltage / constant-current charge at a charge voltage of 4.25 V (counter electrode Li) and a charge current of 0.2 C (1 C ≡ a current at which discharging is completed in 1 hour) and a constant-current discharge at a discharge voltage of 2.75 V (counter electrode Li) and a discharge current of 0.2 C.

[0097] After aging, one cycle consisted of a constant-voltage constant-current charge at a charge voltage of 4.25 V (counter electrode Li) and a charge current of 0.3 C, and a constant-current discharge at a discharge voltage of 2.75 V (counter electrode Li) and a discharge current of 0.3 C. The discharge capacity after each cycle was measured at a constant temperature of 45°C. The ratio of the discharge capacity Ed(n) after n cycles to the discharge capacity Ed(1) after 1 cycle (≡Ed(n) / Ed(1)) was defined as the capacity retention rate Rs(n) after n cycles. Note that the number of cycles n was 30.

[0098] [Table 2]

[0099] As shown in Table 2, the ratio D 50 / D SEM It was confirmed that a battery including a positive electrode active material in which the ratio of the number of moles of manganese to the total number of moles of cobalt and manganese was less than 0.58 had high initial efficiency and capacity retention rate (durability) compared to Comparative Examples 1 to 3. It was also confirmed that in Examples 2 to 5, the discharge capacity was higher than in Example 1 due to the presence of a deposit containing boron on the surface.

[0100] In Comparative Example 4 (agglomerated particles) containing manganese, the discharge capacity is lower than that of Comparative Example 5 (agglomerated particles). On the other hand, in Example 3 (single particle) containing manganese, the discharge capacity is improved compared to Comparative Example 2 (single particle). From these results, it can be seen that the effect of including manganese in the composition is the ratio D 50 / D SEM It was confirmed that this is an effect specific to single-particle lithium transition metal oxides, in which the

[0101] [Table 3]

[0102] [Table 4]

[0103] [Table 5]

[0104] Tables 3 to 5 show the improvement in discharge capacity of the lithium transition metal composite oxide having a boron-containing deposit compared to the lithium transition metal composite oxide not having a boron-containing deposit, and it was confirmed that the effect of the boron-containing deposit in the examples in Table 3 was the greatest compared to the effect of the boron-containing deposit in the agglomerated particles in Table 5 and the effect of the boron-containing deposit in the single particles in Table 4 whose composition does not include manganese.

[0105] The disclosure of Japanese Patent Application No. 2019-217181 (filing date: November 29, 2019) is incorporated herein by reference in its entirety. All documents, patent applications, and technical standards described herein are incorporated herein by reference to the same extent as if each individual document, patent application, and technical standard was specifically and individually indicated to be incorporated by reference.

Claims

1. A lithium transition metal composite oxide containing lithium, nickel, cobalt and manganese and having a layered structure, The lithium transition metal composite oxide has an average primary particle diameter D based on observation with an electron microscope. ＳＥＭ 50% particle size D of cumulative particle size distribution based on volume ５０ Ratio of D ５０ / D ＳＥＭ is between 1 and 4, The ratio of the number of moles of cobalt to the total number of moles of metals other than lithium is 0.03 or more and less than 0.2; A composition in which the ratio of the number of moles of manganese to the total number of moles of metals other than lithium is 0.01 or more and less than 0.2, The nickel element disorder is 1.8% or less, The lithium transition metal composite oxide is a positive electrode active material for a non-aqueous electrolyte secondary battery, the positive electrode active material having a boron-containing deposit on the surface thereof.

2. 2. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1, wherein the lithium transition metal composite oxide has a nickel disorder of 1.2% or less.

3. 3. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1, wherein the lithium transition metal composite oxide has a composition in which the ratio of the number of moles of manganese to the total number of moles of cobalt and manganese is less than 0.

58.

4. 4. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1, wherein the content of the deposit is 0.1 mol % or more and 3 mol % or less, expressed as a boron content relative to the total number of moles of metals other than lithium in the lithium transition metal composite oxide.

5. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the deposit further contains lithium.

6. The lithium transition metal composite oxide has an average particle size D ＳＥＭ 6. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1, wherein the average particle size is 1 μm or more and 7 μm or less.

7. The lithium transition metal composite oxide has a 90% particle size D ９０ 10% particle size D １０ Ratio to D ９０ / D １０ 7. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1, wherein the σ is 4.5 or less.

8. 8. The positive electrode active material for a non-aqueous electrolyte secondary battery according to claim 1, wherein the lithium transition metal composite oxide has a composition represented by the following formula: Li ｐ Ni ｘ Co ｙ Mn ｚ M １ ｗ O ２ (1≦p≦1.15, 0.8<x<1, 0.03≦y<0.2, 0.01≦<z<0.2, 0≦w≦0.1, x+y+z+w≦1, M １ is at least one selected from the group consisting of Al, B, Na, Mg, Si, P, S, K, Ca, Ti, V, Cr, Zn, Sr, Y, Zr, Nb, Mo, In, Sn, Ba, La, Ce, Nd, Sm, Eu, and Gd.

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