N-(cyclopropylmethyl)-5-(methylsulfonyl)-n-{1-[1-(pyrimidin-2-yl)-1h-1,2,4-triazol-5-yl]ethyl}benzamide derivatives and the corresponding pyridine-carboxamide derivatives as pesticides
Novel heteroaryl-triazole and heteroaryl-tetrazole compounds with specific structural variations provide improved pest control efficacy and resistance against arthropods and insects, overcoming limitations of existing pesticides and veterinary ectoparasiticides.
Patent Information
- Application Number
- JP2025040873
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Priority Date
- 2018-11-29
- Filing Date
- 2025-03-14
- Publication Date
- 2025-06-24
- Estimated Expiration
- 2039-04-10
AI Technical Summary
Existing pesticides and veterinary ectoparasiticides face challenges in efficacy, persistence, resistance, toxicity, formulation compatibility, and synthesis costs, necessitating the development of new compounds with improved properties.
The development of novel heteroaryl-triazole and heteroaryl-tetrazole compounds with specific structural variations, including various substituents, to expand the spectrum of pest control and improve efficacy against arthropods and insects.
The novel compounds offer enhanced efficacy, persistence, and resistance-breaking properties, addressing the limitations of existing formulations while reducing toxicity and synthesis costs.
Smart Images

Figure 2025094025000001 
Figure 2025094025000002 
Figure 2025094025000003
Abstract
Description
Technical Field
[0001] The present invention relates to novel heteroaryl - triazole compounds and heteroaryl - tetrazole compounds, formulations and compositions containing such compounds, and their use in the control of animal pests (which includes arthropods and insects) and their use for controlling external parasites of animals.
Background Art
[0002] Specific heteroaryl - triazole compounds and heteroaryl - tetrazole compounds represented by formula (I) (R 3b = hydrogen) have been disclosed in WO2017 / 192385 with respect to their use in the control of external parasites of animals.
[0003] Modern plant protection products and veterinary ectoparasiticides have to meet many requirements, for example, with regard to efficacy, persistence, spectrum and resistance breaking properties. Problems regarding toxicity, the possibility of combination with other active compounds or formulation aids, in addition to the cost required to synthesize the active compound, play a certain role. Furthermore, resistance can also occur. For all these reasons, the search for new crop protection compositions or veterinary ectoparasiticides cannot be considered complete, and new compounds with improved properties compared to known compounds, at least with respect to individual aspects, are constantly being sought.
Prior Art Documents
Patent Documents
[0004]
Patent Document 1
Summary of the Invention
Problems to be Solved by the Invention
[0005] An object of the present invention was to provide a compound that expands the spectrum of pesticides in various aspects.
Means for Solving the Problems
[0006] Accordingly, the present invention provides a compound of general formula (I)
Chemical Formula
[0007] [In the formula (Constitution 1-1): X is O or S; Q 1 and Q 2 are independently CR 5 or N, provided that at least 1 one of Q 2 and Q is N; Y is a direct bond or CH2; R 1 is hydrogen; C1-C6 alkyl [wherein the alkyl is substituted with one substituent selected from -CN, -CONH2, -COOH, -NO2 and -Si(CH3)3]; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl ; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl - [wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-, or benzyl [where the benzyl may be substituted with halogen or C1-C3 haloalkyl] Yes; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents, provided that at least one substituent is present on any carbon adjacent to the carbon bonded to the C═X group, and the substituent is halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, or C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C3 haloalkylthio, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1- C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, - N(C1-C4 alkyl)CO-C1-C4 alkyl, -NHCO-phenyl, -CO2 C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl )2, -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkyl)( C3-C6 cycloalkyl), -C(═NOC1-C4 alkyl)H, -C(═NOC1 -C4 alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [where the heteroaryl is optionally substituted with 1 to 3 substituents selected from halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, or C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C3 haloalkylthio, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1- C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, - N(C1-C4 alkyl)CO-C1-C4 alkyl, -NHCO-phenyl, -CO2 C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl ), -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkyl)( C3-C6 cycloalkyl), -C(═NOC1-C4 alkyl)H, -C(═NOC1 -C4 alkyl)-C1-C4 alkyl; and the heteroaryl is optionally fused to a benzene ring;]] X is O, S, or NR1, where R1 is hydrogen, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, wherein the phenyl or 5- or 6-membered heteroaryl is halogen, -CN, in each case optionally substituted C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alk oxy, each independently selected from the group consisting of 1 to 2 substituents by which it may be substituted; and is each independently selected from the group consisting of; or R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with a total of 1 to 3 substituents provided that the substituent is not present on any carbon adjacent to the carbon to which the C=X group is attached, and at least 1 and at most 3 substituents are C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3 -C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C 6 cycloalkylsulfonyl, C1-C3 haloalkylsulfinyl, C1-C3 halo alkylsulfonyl, in each case optionally substituted C3-C6 cycloalkyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1-C 4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N (C1-C4 alkyl)CO-C1-C4 alkyl -NHCO-phenyl, -CO2C 1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl )2, -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkyl)(C )2, -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkyl)(C 3-C6 cycloalkyl), -C(=NOC1-C4 alkyl)H, -C(=NOC1- (C4-alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [wherein , the phenyl or 5- to 6-membered heteroaryl is halogen, -CN, in each case optionally substituted C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy, each independently selected from the group consisting of 1 to 2 substituents with which it may be substituted], and is independently selected from the group A; the remaining 1 to 2 optional substituents are halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, in each case optionally substituted C1-C 6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl , C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1 -C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl , C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 halo alkylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl , -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1 -C4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl, -NHCO- phenyl, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON (C1-C4 alkyl)2, -CONH(C3-C6 cycloalkyl), -CON(C1 -C4 alkyl)(C3-C6 cycloalkyl), -C(=NOC1-C4 alkyl)H , -C(=NOC1-C4 alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered he teroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is halogen, -CN C1-C6 alkyl, C1-C3 haloalkyl, each of which may be substituted in any case and 1 to 2 substituents each independently selected from the group consisting of C1-C4 alkoxy which may be substituted; and are each independently selected from group B; or R 2 is naphthyl, where the naphthyl is halogen, hydroxy, -CN, - COOH, -CONH2, -NO2, -SF5, -NH2, C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl -C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1-C4 alkyl ), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1-C 4 alkyl)CO-C1-C4 alkyl, -NHCO-phenyl, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -C (=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [where the phenyl or 5- to 6-membered hetero aryl is halogen, -CN, C1-C6 alkyl which may be substituted in any case , -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -C(=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [where the phenyl or 5- to 6-membered heteroaryl is halogen, -CN, C1-C6 alkyl which may be substituted in any case 4 alkyl)CO-C1-C4 alkyl, -NHCO-phenyl, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -C alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 (=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [where the phenyl or 5- to 6-membered hetero aryl is halogen, -CN, C1-C6 alkyl which may be substituted in any case and are each independently selected from the group consisting of C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl Independently selected from the group consisting of Rukir, C1-C3 haloalkyl, and C1-C4 alkoxy, each may be substituted with 1 to 2 substituents selected independently from the group consisting of, and may be substituted with 1 to 3 substituents; ; Or, R 2 is a 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl, a heterocyclic ring selected from the group consisting of 9-membered heteroaryl and 10-membered heteroaryl, where these are each halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -NO2, -SF5, -NH2, in each case optionally substituted C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C 6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, phenyl sulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1- C4 alkyl)CO-C1-C4 alkyl, -NHCO-phenyl, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, - C(=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl)-C1-C4 a nd may be substituted with the following substituents: ; ; lkyl, Lukir; phenyl and 5- to 6-membered heteroaryl [wherein said phenyl or 5- to 6-membered he teroaryl is independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C4 alkoxy, each of which may be optionally substituted] and is optionally substituted with 1 to 3 substituents independently selected from the group consisting of: ; or, R 2 is C1-C6 alkyl, C3-C6 cycloalkyl, or C1-C6 haloalkyl, each of which may be optionally substituted; ; R 3a , R 3b are independently hydrogen; halogen; -CN; C1-C6 alkyl [wherein said alkyl is halogen, hydroxy, -CN, -COOH, -CONH2, -NO2 , -NH2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C4 alkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, -NH(C1-C4 alkyl), -N(C 1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1-C4 alkyl) CO-C1-C4 alkyl, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl ), and -CON(C1-C4 alkyl)2, each of which may be optionally substituted with 1 to 3 substituents independently selected from the group consisting of:]; optionally substituted C3-C6 cycloalkyl; optionally substituted C1-C6 haloalkyl; optionally substituted C2-C6 alkenyl; optionally substituted C2-C6 haloalkenyl; optionally substituted C2-C ; ; ; 6-alkynyl; benzyl [wherein the phenyl substituent is halogen, hydroxy, -CN , -COOH, -CONH2, -NO2, -NH2, -SF5, and in each case may be substituted by 1 to 5 substituents independently selected from the group consisting of C1-C6 alkyl, C1-C4 alkoxy, C1-C3 alkylthio , C1-C3 alkylsulfinyl and C1-C3 alkylsulfonyl]; heterocyclyl-C 1-C6 alkyl [wherein the heterocyclyl substituent is selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyls, 5-membered heteroaryls and 6-membered heteroaryls , and wherein these are each independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN , -COOH, -CONH2, -NO2, -NH2, and in each case may be substituted by 1 to 3 substituents independently selected from the group consisting of C1-C6 alkyl and C1-C4 alkoxy]; phenyl [wherein the phenyl is halogen, hydroxy , -CN, -COOH, -CONH2, -NO2, -NH2, -SF5, and in each case may be substituted by C1-C6 alkyl, C1-C4 alkoxy, C1-C 3 alkylthio, C1-C3 alkylsulfinyl and C1-C3 alkylsulfonyl, each independently selected from the group consisting of 1 to 5 substituents; or heterocyclyl [wherein the heterocyclyl substituent is selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyls, 5-membered heteroaryls and 6-membered heteroaryls , and wherein these are each independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN , -COOH, -CONH2, -NO2, -NH2, and in each case may be substituted by 1 to 3 substituents independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN , -COOH, -CONH2, -NO2, -NH2, and in each case may be substituted by 1 to 3 substituents independently selected from the group consisting of C1-C6 alkyl and C1-C4 alkoxy]; or , -COOH, -CONH2, -NO2, -NH2, and in each case may be substituted selected independently from the group consisting of C1-C6 alkyl and C1-C4 alkoxy, and may be substituted with 1 to 3 substituents; or R 3a , R 3b together with the carbon to which they are attached forms a C3-C6 carbocyclic ring system or a 3- to 6-membered heterocyclic ring system, where the ring system is halogen, -CN, optionally substituted C1-C6 alkyl, C1-C4 alkoxy and C1-C3 haloalkoxy, each independently selected from the group consisting of 1 to 2 substituents, and may be substituted; R 4 is pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl , where the pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl is halogen, hydroxy, -CN, -COOH, -CONH2, -CSNH2, -NO2, -NH2, optionally substituted C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy , C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1- C3 haloalkylsulfonyl, -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -NHCO-C3-C6 cycloalkyl, - NHCO-phenyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl, -N(C 1-C4 alkyl)CO-C3-C6 cycloalkyl, -N(C1-C4 alkyl)CO -phenyl, -N(SO2C1-C3 alkyl)2, -NH(SO2C1-C3 alkyl ), -N(C1-C4 alkyl)(SO2C1-C3 alkyl), -CO2C1-C4 al kyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -C (=NOC1-C4 alkyl)H and -C(=NOC1-C4 alkyl)-C1-C4 al kyl, and may be substituted with 1 to 3 substituents selected from the group consisting of; R 5 is hydrogen, halogen, -CN, or C1 -C3 alkyl, C3-C4 cycloalkyl, C1-C3 alkoxy, C1-C3 alco xyC(O)-, (C1-C3 alkoxy)2CH-, -CO2C1-C4 alkyl, - CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -NHCO-C 1-C4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl, -C(=N OC1-C4 alkyl)H or -C(=NOC1-C4 alkyl)-C1-C4 al kyl〕 To provide a compound represented by.
[0008] The present invention further provides a general formula (I) 〔Wherein (Configuration 1-2), X is O or S; Q 1 And Q 2 Are independently CR 5 Or N, provided that Q 1 And Q 2 At least One of them is N; Y is a direct bond or CH2 which may be substituted; R 1 Is hydrogen; C1-C6 alkyl [wherein the alkyl is -CN, -CONH2, substituted with one substituent selected from -COOH, -NO2, and -Si(CH3)3 ; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl ; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C4 cycloalkyl-C1-C2 alkyl- [wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-, or benzyl [wherein the benzyl may be substituted with halogen or C1-C3 haloalkyl] ; R is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents, provided that at least one substituent is present on any carbon adjacent to the carbon bonded to the C=X group, and the substituent is 2 halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, and in each case optionally substituted C1-C6 alkyl, C3-C6 cycloalkyl , C3-C6 cycloalkyl-C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy , C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl , C1-C6 alkylsulfonyl, C1-C6 haloalkylthio, C3-C6 cycloalkylsulfanyl , C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C6 haloalkylsulfinyl , C1-C6 haloalkylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, ; ; ; ; ; ; -NH(C1-C6 alkyl), -N(C1-C6 alkyl)2, -NHCO-C1-C 6 alkyl, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -NHCO-phen yl, -CO2C1-C6 alkyl, -CONH(C1-C6 alkyl), -CON(C 1-C6 alkyl)2, -CONH(C3-C6 cycloalkyl), -CON(C1-C 6 alkyl)(C3-C6 cycloalkyl), -C(=NOC1-C6 alkyl)H, - C(=NOC1-C6 alkyl)-C1-C6 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is each independently selected from the group consisting of halogen, -CN, C1-C6 alkyl optionally substituted in any case, C1-C6 haloalkyl, and C1-C6 alkoxy, and is optionally substituted with 1 to 2 substituents]; and, optionally substituted 4- to 6-membered saturated or partially unsaturated heterocyclic ring is each independently selected from the group consisting of; or, R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with a total of 1 to 3 substituents provided that the substituents are not present on any carbon adjacent to the carbon to which the C=X group is attached, and at least 1 and at most 3 substituents are optionally substituted C4-C6 alkyl; C1-C6 alkylthio [wherein the alkylthio is -NH2, -OH, -NO2, - CN, -SH, CO2C1-C4 alkyl, -CONH2, SF5, -SO2NH2, C 1-C4 alkyl, C3-C4 cycloalkyl, C2-C4 alkenyl, C5-C6 cyclo Lower alkenyl, C2-C4 alkynyl, -NH(C1-C6 alkyl), -N(C1-C 6 alkyl)2, N-C1-C4 alkanoyl amino, C1-C4 alkoxy, C1-C 4 haloalkoxy, C2-C4 alkenyloxy, C2-C4 alkynyloxy, C3- C4 cycloalkoxy, C5-C6 cycloalkenyloxy, C1-C4 alkoxycarbonyl , C2-C4 alkenyloxycarbonyl, C2-C4 alkynyloxycarbonyl , C6-aryloxycarbonyl, C 10 -aryloxycarbonyl, C 14 -a ryl oxycarbonyl, C1-C4 alkanoyl, C2-C4 alkenylcarbonyl, C2-C4 alkynylcarbonyl, C6-arylcarbonyl, C 10 -arylcarbonyl , C 14 -arylcarbonyl, C1-C4 alkylthio, C1-C4 haloalkyl thio, C3-C4 cycloalkylthio, C2-C4 alkenylthio, C5-C6 cyclo alkenylthio, C2-C4 alkynylthio, C1-C4 alkylsulfinyl, C1-C 4 haloalkylsulfinyl, C1-C4 alkylsulfonyl, C1-C4 haloalkyl sulfonyl, -SO2-NH(C1-C6 alkyl), -SO2-N(C1-C6 alkyl )2, C1-C4 alkylphosphinyl, C1-C4 alkylphosphonyl, N-C1- C4 alkylaminocarbonyl, N,N-di-C1-C4 alkylaminocarbonyl, N -C1-C4 alkanoylaminocarbonyl, N-C1-C4 alkanoyl-N-C1- C4 alkylaminocarbonyl, C6-aryl, C 10 -aryl, C 14 -aryl , C6-aryloxy, C10 - aryloxy, C 14 - aryloxy, benzyl , benzyloxy, benzylthio, C6 - arylthio, C 10 - arylthio, C 14 - arylthio, C6 - arylamino, C 10 - arylamino, C 14 - aryl a mino, benzylamino, heterocyclyl, heteroaryl and trialkylsilyl, double bond - linked substituents (e.g., C1 - C4 - alkylidene (e.g., methylidene or ethylidene), oxo group, imino group and substituted imino group) selected independently from the group consisting of 1 to 3 substituents; and, optionally substituted C4 - C6 haloalkylthio, C4 - C6 haloalk oxy, C4 - C6 alkoxy, C4 - C6 haloalkyl, C3 - C6 cycloalkyl , C1 - C6 alkylsulfinyl, C1 - C6 alkylsulfonyl, C3 - C6 cyclo alkylsulfanyl, C3 - C6 cycloalkylsulfinyl, C3 - C6 cycloalk ylsulfonyl, C1 - C6 haloalkylsulfinyl, C1 - C6 haloalkylsulfon yl, C2 - C6 alkenylsulfanyl, C2 - C6 alkenylsulfinyl, C2 - C6 alkenylsulfonyl, C2 - C6 alkynylsulfanyl, C2 - C6 alkynyl sulfinyl, C2 - C6 alkynylsulfonyl, phenylsulfanyl, phenylsulf inyl, phenylsulfonyl, heterocyclylsulfanyl, heterocyclylsulfi nyl, heterocyclylsulfonyl, heteroarylsulfanyl, heteroarylsulf inyl, heteroarylsulfonyl, S - C1 - C6 alkylsulfinimidoyl, S -C3-C6 cycloalkylsulfinimidoyl, S-C2-C6 alkenylsulfin imidoyl, S-C2-C6 alkynylsulfinimidoyl, S-phenylsulfin imidoyl, S-heterocyclylsulfinimidoyl, S-heteroarylsulfin imidoyl, S-C1-C6 alkylsulfonimidoyl, S-C3-C6 cycloal kylsulfonimidoyl, S-C2-C6 alkenylsulfonimidoyl, S-C2-C 6 alkynylsulfonimidoyl, S-phenylsulfonimidoyl, S-heterocycly lsulfonimidoyl, S-heteroarylsulfonimidoyl, -NH(C1-C6 al kyl), -N(C1-C6 alkyl)2, -NHCO-C1-C6 alkyl, -N(C 1-C6 alkyl)CO-C1-C6 alkyl, -N(C3-C6 cycloalkyl)CO -C1-C6 alkyl, -NHCO-phenyl, -N(C1-C6 alkyl)CO-phen yl, -N(C3-C6 cycloalkyl)CO-phenyl, -NHCO-C3-C6 cyclo alkyl, -N(C1-C6 alkyl)CO-(C3-C6 cycloalkyl), -N( C3-C6 cycloalkyl)CO-(C3-C6 cycloalkyl), -NHCO-hetero aryl, -N(C1-C6 alkyl)CO-heteroaryl, -N(C3-C6 cyclo alkyl)CO-heteroaryl, -NHCO-heterocyclyl, -N(C1-C6 al kyl)CO-heterocyclyl, -N(C3-C6 cycloalkyl)CO-heterocyclyl 、-CO2C1-C6 alkyl, -CONH(C1-C6 alkyl), -CON(C1- C6 alkyl)2, -CONH(C3-C6 cycloalkyl), -CON(C1-C6 al kyl)(C3-C6 cycloalkyl), -CON(C3-C6 cycloalkyl)2, - CONH-phenyl, -CON(C1-C6 alkyl)phenyl, -CON(C3-C6 cycloalkyl)phenyl, -CONH-heteroaryl, -CON(C1-C6 alkyl )heteroaryl, -CON(C3-C6 cycloalkyl)heteroaryl, -CON H-heterocyclyl, -CON(C1-C6 alkyl)heterocyclyl, -CON(C3 -C6 cycloalkyl)heterocyclyl, -C(=NOC1-C6 alkyl)H, -C( =NOC1-C6 alkyl)-C1-C6 alkyl, -NHSO2-C1-C6 alkyl 、-N(C1-C6 alkyl)SO2-C1-C6 alkyl, -N(C3-C6 cyclo alkyl)SO2-C1-C6 alkyl, -NHSO2-phenyl, -N(C1-C6 alkyl yl)SO2-phenyl, -N(C3-C6 cycloalkyl)SO2-phenyl, -NH SO2-C3-C6 cycloalkyl, -N(C1-C6 alkyl)SO2-(C3-C6 cycloalkyl), -N(C3-C6 cycloalkyl)SO2-(C3-C6 cycloalkyl yl), -NHSO2-heterocyclyl, -N(C1-C4 alkyl)SO2-heterocy ryl, -N(C3-C6 cycloalkyl)SO2-heterocyclyl, -NHSO2-he teroaryl, -N(C1-C6 alkyl)SO2-heteroaryl, -N(C3-C6 cycloalkyl)SO2-heteroaryl, -SO2NH(C1-C6 alkyl), -S O2N(C1-C6 alkyl)2, -SO2N(C1-C6 alkyl)(C3-C6 cycl oalkyl), -SO2NH(C3-C6 cycloalkyl), -SO2N(C3-C6 cyc loalkyl)2, -SO2NH(phenyl), -SO2N(C1-C6 alkyl)(ph -SO2N(C1-C4 cycloalkyl)(phenyl), -SO2N(C1-C4 cycloalkyl)(heteroaryl), -SO2NH(heteroaryl), -SO2N(C1-C6 alkyl)(heteroaryl), -SO2N(C3-C6 cycloalkyl)(heteroaryl), -SO2NH(heterocyclic), -SO2N(C1-C4 alkyl)(heterocyclic), -SO2N(C3-C6 cycloalkyl)(heterocyclic); and, phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is optionally substituted with 1 to 2 substituents independently selected from the group consisting of halogen, -CN, C1-C6 alkyl optionally substituted in any case, C1-C6 haloalkyl, C1-C6 alkoxy, and C1-C6 haloalkoxy]; and, optionally substituted 4- to 6-membered saturated or partially unsaturated heterocyclic ring; and, -SO2NH2; selected independently from the group A consisting of; and, the remaining 1 to 2 optional substituents are halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, and C1-C6 alkyl optionally substituted in any case, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylthio, C1-C6 haloalkylsulfinyl, C1-C6 haloalkylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1-C6 alkyl), - selected independently from the group consisting of; and, optionally substituted 4- to 6-membered saturated or partially unsaturated heterocyclic ring; and, -SO2NH2; selected independently from the group A consisting of; and, the remaining 1 to 2 optional substituents are halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -N O2, and C1-C6 alkyl optionally substituted in any case, C3-C6 cycloalkyl C3-C6 cycloalkyl-C1-C6 alkyl, C1-C6 haloalkyl, C1-C 6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkyl sulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylthio, C1- C6 haloalkylsulfinyl, C1-C6 haloalkylsulfonyl, phenylsulfanyl phenylsulfinyl, phenylsulfonyl, -NH(C1-C6 alkyl), - N(C1-C6 alkyl)2, -NHCO-C1-C6 alkyl, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -NHCO-phenyl, -CO2C1-C6 alkyl , -CONH(C1-C6 alkyl), -CON(C1-C6 alkyl)2, -CONH (C3-C6 cycloalkyl), -CON(C1-C6 alkyl)(C3-C6 cycloalkyl), -C(=NOC1-C6 alkyl)H, -C(=NOC1-C6 alkyl)- C1-C6 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein said phenyl or 5- to 6-membered heteroaryl is each independently selected from the group consisting of halogen, -CN, C1-C6 alkyl which may in each case be substituted, C1-C6 haloalkyl and C1-C6 alkoxy and is optionally substituted with 1 to 2 substituents selected therefrom]; each independently selected from group B; or, R is naphthyl, wherein said naphthyl is halogen, hydroxy, -CN, -COOH, -CONH2, -NO2, -SF5, -NH2, and, C1-C6 alkyl which may in each case be substituted, C3-C6 cycloalkyl, 2 C3-C6 cycloalkyl-C1-C6 alkyl, C1-C6 haloalkyl, C1-C 6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alkyl sulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C 6 haloalkylthio, C1-C6 haloalkylsulfinyl, C1-C6 haloalkylsulfonyl; from the group consisting of; and is optionally substituted with 1 to 2 substituents independently selected from the group consisting of halogen, -CN, C1-C6 alkyl which may in each case be substituted, C1-C6 haloalkyl and C1-C6 alkoxy; ; Killsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1-C6 alkyl), -N(C1-C6 alkyl)2, -NHCO-C1-C 6 alkyl, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -NHCO-phen yl, -CO2C1-C6 alkyl, -CONH(C1-C6 alkyl), -CON(C 1-C6 alkyl)2, -C(=NOC1-C6 alkyl)H, -C(=NOC1-C6 alkyl)-C1-C6 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is each independently selected from the group consisting of halogen, -CN, C1-C6 alkyl which may be substituted in any case, C1-C6 haloalkyl and C1-C6 alkoxy and is optionally substituted with 1 to 2 substituents each independently selected therefrom]; and is optionally substituted with 1 to 3 substituents each independently selected from the group consisting of: or, or, R 2 is a heterocyclic ring selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl, 9-membered heteroaryl and 10-membered heteroaryl, wherein these are each, halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -NO2 -SF5, -NH2, and, C1-C6 alkyl which may be substituted in any case, C3-C6 cycloalkyl C3-C6 cycloalkyl-C1-C6 alkyl, C1-C6 haloalkyl, C1-C 6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1-C6 alk ylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfonyl; Lu, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C 1-C6 haloalkylthio, C1-C6 haloalkylsulfinyl, C1-C6 haloalkyl sulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C1-C6 alkyl), -N(C1-C6 alkyl)2, -NHCO-C1-C 6 alkyl, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -NHCO-phenyl -CO2C1-C6 alkyl, -CONH(C1-C6 alkyl), -CON(C 1-C6 alkyl)2, -C(=NOC1-C6 alkyl)H, -C(=NOC1-C6 alkyl)-C1-C6 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein, the phenyl or 5- to 6-membered heteroaryl is optionally substituted with 1 to 2 substituents independently selected from the group consisting of halogen, -CN, C1-C6 alkyl which may be substituted in any case, C1-C6 haloalkyl and C1-C6 alkoxy]; optionally substituted with 1 to 3 substituents independently selected from the group consisting of: or, or, R 2 is C1-C6 alkyl, C3-C6 cycloalkyl or C1-C6 haloalkyl which may be substituted in any case; R R 3a R 3b are independently hydrogen; halogen; -CN; C1-C6 alkyl [wherein the alkyl is halogen, hydroxy, -CN, -COOH, -CONH2, -NO2 -NH2, C1-C6 alkyl which may be substituted in any case, C3-C6 cycloalkyl haloalkyl, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkylsulf Rufinyl, C1-C6 alkylsulfonyl, -NH(C1-C6 alkyl), -N(C 1-C6 alkyl)2, -NHCO-C1-C6 alkyl, -N(C1-C6 alkyl) CO-C1-C6 alkyl, -CO2C1-C6 alkyl, -CONH(C1-C6 al kyl) and -CON(C1-C6 alkyl)2, independently selected from the group consisting of 1 to 3 substituents; optionally substituted C3-C6 cycloalkyl; optionally substituted C1-C6 haloalkyl; optionally substituted C2-C6 alke nyl; optionally substituted C2-C6 haloalkenyl; optionally substituted C2-C 6 alkynyl; benzyl [wherein the phenyl substituent is halogen, hydroxy, -CN , -COOH, -CONH2, -NO2, -NH2, -SF5, in each case optionally substituted by 1 to 5 substituents independently selected from the group consisting of C1-C6 alkyl, C1-C6 alkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl]; heterocyclyl-C 1-C6 alkyl [wherein the heterocyclyl substituent is selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl and 6-membered heteroaryl, where these are each independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, in each case optionally substituted by 1 to 3 substituents independently selected from the group consisting of C1-C6 alkyl and C1-C6 alkoxy]; phenyl [wherein the phenyl is halogen, hy droxy, -CN, -COOH, -CONH2, -NO2, -NH2, -SF5, in any case optionally substituted by 1 to 3 substituents independently selected from the group consisting of C1-C6 alkyl and C1-C6 alkoxy]; drogen, -COOH, -CONH2, -NO2, -NH2, -SF5, any of which may be substituted C1-C6 alkyl, C1-C6 alkoxy, C1-C 6 alkylthio, C1-C6 alkylsulfinyl and C1-C6 alkylsulfonyl, each of which may be substituted with 1 to 5 substituents independently selected from the group consisting of; or It may be substituted with 1 to 5 substituents independently selected from the group consisting of; or heterocyclyl [wherein the heterocyclyl substituent is selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl and 6-membered heteroaryl, and wherein these are each independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN -COOH, -CONH2, -NO2, -NH2, C1-C6 alkyl and C1-C6 alkoxy, each of which may be substituted in any case, and may be substituted with 1 to 3 substituents]; selected from the group consisting of; or, R and R together with the carbon to which they are attached form a C3-C6 carbocyclic ring system or 3a a 3- to 6-membered heterocyclic ring system, where the ring system is halogen, -CN, C1-C6 alkyl, C1-C6 alkoxy and C1-C6 3b haloalkoxy, each of which may be substituted with 1 to 2 substituents independently selected from the group consisting of, and may be substituted; R is pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl, and wherein the pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl is halogen, hydroxy, -CN, -COOH, -CO2-C1-C6 alkyl, -SO2 NH2, -CONH2, -CSNH2, -NO2, -NH2, each of which may be substituted in any case, and R 4 is pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl, and wherein the pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl is halogen, hydroxy, -CN, -COOH, -CO2-C1-C6 alkyl, -SO2 NH2, -CONH2, -CSNH2, -NO2, -NH2, each of which may be substituted in any case, and R C1-C6 alkyl, C3-C6 cycloalkyl, C1-C6 haloalkyl, which may be present , C1-C6 alkoxy, C1-C6 haloalkoxy, C1-C6 alkylthio, C1- C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylthio , C1-C6 haloalkylsulfinyl, C1-C6 haloalkylsulfonyl, C3- C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C2-C4 alkenylsulfanyl, C2-C4 alkenyl sulfinyl, C2-C4 alkenylsulfonyl, C2-C4 alkynylsulfanyl, C2-C4 alkynylsulfinyl, C2-C4 alkynylsulfonyl, phenylsulf anyl, phenylsulfinyl, phenylsulfonyl, S-C1-C6 alkylsulfin imidoyl, S-C3-C6 cycloalkylsulfinimidoyl, S-C2-C6 a lkenylsulfinimidoyl, S-C2-C6 alkynylsulfinimidoyl, S- phenylsulfinimidoyl, S-C1-C6 alkylsulfonimidoyl, S-C3 -C6 cycloalkylsulfonimidoyl, S-C2-C6 alkenylsulfonimidoy l, S-C2-C6 alkynylsulfonimidoyl, S-phenylsulfonimidoyl, -NH(C1-C6 alkyl), -N(C1-C6 alkyl)2, -NHCO-C1-C 6 alkyl, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -N(C3-C6 cycloalkyl)CO-C1-C6 alkyl, -NHCO-C3-C6 cycloalkyl, -N(C1-C6 alkyl)CO-(C3-C6 cycloalkyl), -N(C3-C6 cy cloalkyl)CO-(C3-C6 cycloalkyl), -N(C1-C6 alkyl)CO -phenyl, -N(C3-C6 cycloalkyl)CO-phenyl, -NHCO-phenyl , -N(CO-C1-C6 alkyl)2, -N(CO-C3-C6 cycloalkyl)2, -N(CO-phenyl)2, -N(CO-C3-C6 cycloalkyl)(CO-C1-C 6 alkyl), -N(CO-C3-C6 cycloalkyl)(CO-phenyl), -N(C O-C1-C6 alkyl)(CO-phenyl), -CONH(C1-C6 alkyl), - CON(C1-C6 alkyl)2, -CONH(C3-C6 cycloalkyl), -CON (C1-C6 alkyl)(C3-C6 cycloalkyl), -CON(C3-C6 cyclo alkyl)2, -CONH-SO2-C1-C6 alkyl, -CONH-SO2-phenyl , -CONH-SO2-(C3-C6 cycloalkyl), -CON(C1-C6 alkyl )-SO2-C1-C6 alkyl, -CON(C1-C6 alkyl)-SO2-phenyl , -CON(C1-C6 alkyl)-SO2-(C3-C6 cycloalkyl), -CON H-phenyl, -CON(C1-C6 alkyl)phenyl, -CON(C3-C6 cyclo alkyl)phenyl, -N(SO2C1-C6 alkyl)2, -N(SO2C1-C6 halo alkyl)2, -N(SO2C3-C6 cycloalkyl)2, -N(SO2C1-C6 alkyl)SO2-phenyl, -N(SO2C3-C6 cycloalkyl)SO2-phenyl , -NHSO2-C1-C6 alkyl, -NHSO2-C1-C6 haloalkyl, -N (C1-C6 alkyl)SO2-C1-C6 alkyl, -N(C3-C6 cycloalkyl )SO2-C1-C6 alkyl, -NHSO2-phenyl, -N(C1-C6 alkyl) SO2-phenyl, -N(C3-C6 cycloalkyl)SO2-phenyl, -NHSO2 -C3-C6 cycloalkyl, -N(C1-C6 alkyl)SO2-(C3-C6 cyclo alkyl), -N(C3-C6 cycloalkyl)SO2-(C3-C6 cycloalkyl) , -SO2NH(C1-C6 alkyl), -SO2N(C1-C6 alkyl)2, -SO 2N(C1-C6 alkyl)(C3-C6 cycloalkyl), -SO2NH(C3-C6 cycloalkyl), -SO2N(C3-C6 cycloalkyl)2, -SO2NH(phenyl yl), -SO2N(C1-C6 alkyl)(phenyl), -SO2N(C1-C4 cyclo alkyl)(phenyl), -C(=NOC1-C6 alkyl)H and -C(=NOC1- C6 alkyl)-C1-C6 alkyl, and may be substituted with 1 to 3 substituents selected from the group consisting of; ; R 5 is hydrogen, halogen, -CN, or in each case optionally substituted C1 -C6 alkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 alkoxy C(O)-, (C1-C6 alkoxy)2CH-, -CO2C1-C6 alkyl, - CONH(C1-C6 alkyl), -CON(C1-C6 alkyl)2, -NHCO-C 1-C6 alkyl, -N(C1-C6 alkyl)CO-C1-C6 alkyl, -C(=N OC1-C6 alkyl)H or -C(=NOC1-C6 alkyl)-C1-C6 alkyl 〕 To provide a compound represented by.
[0009] The compound represented by formula (I) further includes all diastereomers or enantiomers and E / Z isomers present, and also salts and N-oxides of the compound represented by formula (I) omers. including Syd, and also including their use for controlling pests.
[0010] Regarding the preferred definitions of the radicals for the formulas specified above and below, are described below.
Mode for Carrying Out the Invention
[0011] Preferred is (Configuration 2-1), Formula (I) [wherein, X is O or S; Q 1 and Q 2 are independently CR 5 or N, provided that at least 1 one of Q 2 and Q is N; Y is a direct bond or CH2; R 1 is hydrogen; C1-C6 alkyl [wherein the alkyl is substituted with one substituent selected from -CN, -CONH2, -COOH, -NO2 and -Si(CH3)3 and may be substituted]; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl ; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl- [wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or benzyl [where the benzyl may be substituted with halogen or C1-C3 haloalkyl] and is; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents and provided that at least one substituent is present on any carbon adjacent to the carbon to which the C=X group is attached, and the substituent is halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, C1-C6 alkyl, optionally substituted C3-C6 cycloalkyl; C3-C6 cycloalkyl-C1-C 6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy , C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl , C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; phenylsulfanyl , phenylsulfinyl, phenylsulfonyl [wherein in each case the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl]; -NH(C1-C4 alkyl), - N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1-C4 alkyl CO-C1-C4 alkyl; -NHCO-phenyl [wherein the phenyl is halo gen, CN, C1-C6 alkyl and C1-C3 haloalkyl selected from the group consisting of optionally substituted with 1 to 2 substituents selected]; -CO2C1-C4 alkyl, -CONH( C1-C4 alkyl), -CON(C1-C4 alkyl)2, -CONH(C3-C6 cyclo alkyl), -CON(C1-C4 alkyl)(C3-C6 cycloalkyl), -C (=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl)-C1-C4 alkyl ; provided that when the C=X group is a C=O group, the substituent is not -COOH or -CONH2; provided that when the C=X group is a C=S group, the substituent is not - SF5; provided that when the C=X group is a C=N-OR group, the substituent is not -C(=NOR)H or -C(=NOR)-R; provided that when the C=X group is a C=N-NR2 group, the substituent is not - NH2; provided that when the C=X group is a C=N-NHCOR group, the substituent is not -NH2; provided that when the C=X group is a C=N-NRCOR group, the substituent is not -NH2; provided that when the C=X group is a C=N- NHSO2R group, the substituent is not -NH2; provided that when the C=X group is a C=N-NHCONR2 group, the substituent is not -NH2; provided that when the C=X group is a C=N-NHSO2NR2 group, the substituent is not -NH2; provided that when the C=X group is a C=N- (=NOR)H, -C(=NOR)-R; provided that when the C=X group is a C=N-NR2 group, the substituent is not -NH2; provided that when the C=X group is a C=N-NHCOR group, the substituent is not -NH2; provided that when the C=X group is a C=N-NRCOR group, the substituent is not -NH2; provided that when the C=X group is a C=N- Kill; phenyl and 5- or 6-membered heteroaryl [wherein the phenyl or 5- or 6-membered heteroaryl is each independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C 1-C4 alkoxy, and may be substituted with 1 to 2 substituents selected independently therefrom]; and are each independently selected from the group consisting of: Or, R 2 Is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein The phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with a total of 1 to 3 substituents Provided that the substituents are not present on any carbon adjacent to the carbon to which the C═X group is attached, and at least one and up to three substituents are C1-C6 al Kylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3- C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 Cycloalkylsulfonyl, C1-C3 haloalkylsulfinyl, C1-C3 haloal Kylsulfonyl; phenylsulfanyl, phenylsulfinyl, phenylsulfonyl Wherein in each case the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C6 alkyl and C1-C3 haloalkyl; optionally substituted C3-C6 cycloalkyl; -NH(C1-C4 alkyl) -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1-C4 Alkyl)CO-C1-C4 alkyl; -NHCO-phenyl [wherein the phenyl is Selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl And may be substituted; optionally substituted C3-C6 cycloalkyl; -NH(C1-C4 alkyl) -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1-C4 Alkyl)CO-C1-C4 alkyl; -NHCO-phenyl [wherein the phenyl is Selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl may be substituted with 1 to 2 substituents selected therefrom]; -CO2C1-C4 alkyl, -CON H(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -CONH(C3-C 6 cycloalkyl), -CON(C1-C4 alkyl)(C3-C6 cycloalkyl), -C(=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy and C1-C4 haloalkoxy and may be substituted with 1 to 2 substituents selected therefrom]; independently selected from group A consisting of ; the remaining 1 to 2 optional substituents are halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, C1-C6 alkyl, optionally substituted C3 -C6 cycloalkyl; C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 halo alkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio o, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C3 halo alkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl l; phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein in each case, the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 halo alkyl]; -NH( C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alk yl, -N(C1-C4 alkyl)CO-C1-C4 alkyl; -NHCO-phenyl [where Here, the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl, and C1-C3 haloalkyl ;-CO2C1-C 4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkyl)(C3-C 6 cycloalkyl), -C(=NOC1-C4 alkyl)H, -C(=NOC1-C4 a lkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [here, the ph enyl or 5- to 6-membered heteroaryl is independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1 -C3 haloalkyl, and C1-C4 alkoxy and is optionally substituted with 1 to 2 substituents selected therefrom]; each independently selected from group B consisting of ; Or, R 2 is naphthyl, where the naphthyl is halogen, hydroxy, -CN, - COOH, -CONH2, -NO2, -SF5, -NH2, C1-C6 alkyl, optionally substituted C3-C6 cycloalkyl; C3-C6 cycloalkyl-C1-C6 al kyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C 1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C 3-C6 cycloalkylthio, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloal kylsulfinyl, C1-C3 haloalkylsulfonyl; phenylsulfanyl, phe nylsulfinyl, phenylsulfonyl [in each case, the phenyl is h selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl and may be substituted with 1 to 2 substituents; -NH(C1-C4 alkyl), -N(C 1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1-C4 alkyl) CO-C1-C4 alkyl; -NHCO-phenyl [wherein the phenyl is halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl and may be substituted with 1 to 2 substituents selected from the group consisting of]; -CO2C1-C4 alkyl, -CONH(C1- C4 alkyl), -CON(C1-C4 alkyl)2, -C(=NOC1-C4 alkyl )H, -C(=NOC1-C4 alkyl)-C1-C4 alkyl; phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is halogen, - CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy and may each be independently substituted with 1 to 2 substituents selected from the group consisting of]; and may be independently substituted with 1 to 3 substituents selected from the group consisting of; or, R 2 is a heterocyclic ring selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl, 9-membered heteroaryl and 10-membered heteroaryl, and wherein these are each halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -NO2, -SF5, -NH2, C1-C6 alkyl, substituted optionally C3-C6 cycloalkyl; C3-C6 cycloalkyl-C1-C6 a lkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, and C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl ; C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl , C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 halo alkylsulfinyl, C1-C3 haloalkylsulfonyl; phenylsulfanyl, ph enylsulfinyl, phenylsulfonyl [wherein in each case, the phenyl is selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl and may be substituted with 1 to 2 substituents]; -NH(C1-C4 alkyl), -N( C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N(C1-C4 alkyl )CO-C1-C4 alkyl; -NHCO-phenyl [wherein the phenyl is halogen , CN, C1-C6 alkyl and C1-C3 haloalkyl and may be selected from the group consisting of 1 to 2 substituents]; -CO2C1-C4 alkyl, -CONH(C1 -C4 alkyl), -CON(C1-C4 alkyl)2, -C(=NOC1-C4 alkyl )H, -C(=NOC1-C4 alkyl)-C1-C4 alkyl; phenyl and 5 to 6 membered heteroaryl [wherein the phenyl or 5 to 6 membered heteroaryl is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy and may be independently selected from the group consisting of 1 to 2 substituents]; and may be substituted with 1 to 3 substituents independently selected from the group consisting of ; or, or, R 2 is C1-C6 alkyl, wherein the alkyl is C1-C3 alkoxy- , C1-C3 haloalkoxy-, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; phenyl and 5- to 6-membered heteroaryl [wherein said phenyl or 5- to 6-membered heteroaryl is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy selected independently from the group consisting of 1 to 2 substituents which may be substituted]; C3-C6 cycloalkyl [wherein said cycloalkyl is halogen, -CN, -COOH, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C1-C6 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; phenyl and 5- to 6-membered heteroaryl [wherein said phenyl or 5- to 6-membered heteroaryl is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy selected independently from the group consisting of 1 to 2 substituents which may be substituted]; C3-C6 cycloalkyl [wherein said cycloalkyl is halogen, -CN, -COOH, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; phenyl and 5- to 6-membered heteroaryl [wherein said phenyl or 5- to 6-membered heteroaryl is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy selected independently from the group consisting of 1 to 2 substituents which may be substituted]; C3-C6 cycloalkyl [wherein said cycloalkyl is halogen, -CN, -COOH, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C1-C3 haloalkylsulfonyl; phenyl and 5- to 6-membered heteroaryl [wherein said phenyl or 5- to 6-membered heteroaryl is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy selected independently from the group consisting of 1 to 2 substituents which may be substituted]; C3-C6 cycloalkyl [wherein said cycloalkyl is halogen, -CN, -COOH, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy selected independently from the group consisting of 1 to 2 substituents which may be substituted]; C3-C6 cycloalkyl [wherein said cycloalkyl is halogen, -CN, -COOH, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C3-C6 cycloalkyl [wherein said cycloalkyl is halogen, -CN, -COOH, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C3-C6 cycloalkyl [wherein said cycloalkyl is halogen, -CN, -COOH, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH (C1-C4 alkyl) and -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; -CON (C1-C4 alkyl) 2 selected from the group consisting of 1 to 2 substituents which may be substituted]; substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; Substituted with 1 substituent selected from the group consisting of C1-C6 haloalkyl; ; R 3a R 3b are independently hydrogen; halogen; -CN; C1-C6 alkyl [wherein said alkyl is hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NH (C1-C4 alkyl), -N (C1-C4 alkyl) 2, -NHCO-C1-C4 alkyl, -N C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NH (C1-C4 alkyl), -N (C1-C4 alkyl) 2, -NHCO-C1-C4 alkyl, -N C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NH (C1-C4 alkyl), -N (C1-C4 alkyl) 2, -NHCO-C1-C4 alkyl, -N C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NH (C1-C4 alkyl), -N (C1-C4 alkyl) 2, -NHCO-C1-C4 alkyl, -N C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NH (C1-C4 alkyl), -N (C1-C4 alkyl) 2, -NHCO-C1-C4 alkyl, -N C1-C4 alkyl), -N (C1-C4 alkyl) 2, -NHCO-C1-C4 alkyl, -N (C1-C4 alkyl)CO-C1-C4 alkyl, -CO2C1-C4 alkyl, -C optionally substituted with 1 to 3 substituents independently selected from the group consisting of ONH(C1-C4 alkyl) and -CON(C1-C4 alkyl)2]; C3-C6 cycloalkyl [wherein the cycloalkyl is halogen, -CN, -COOH, -CONH2, C1- C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy , C1-C6 haloalkoxy, -CO2C1-C4 alkyl, -CONH(C1-C 4 alkyl) and -CON(C1-C4 alkyl)2, optionally substituted with 1 to 2 substituents selected from the group consisting of; C1-C6 haloalkyl [wherein the haloalkyl is , hydroxy, -CN, C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl) and -CON(C1-C4 alkyl)2, optionally substituted with 1 to 2 substituents selected from the group consisting of; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkynyl; benzyl [wherein the phenyl substituent is halogen, hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, -SF5, C1 -C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy , C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl, optionally substituted with 1 to 5 substituents each independently selected from the group consisting of; heterocyclyl-C1-C6 alkyl [wherein the he The terocyclic substituent is selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl, and 6-membered heteroaryl, where these are each optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C4 alkoxy]; phenyl [where the phenyl is optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, -SF5, C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, and C1-C3 haloalkylsulfonyl]; and heterocyclyl [where the heterocyclic substituent is selected from the group consisting of 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl, and 6-membered heteroaryl, where these are each optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C4 alkoxy]; selected from the group consisting of; or, R, R, together with the carbon to which they are attached, form a C3-C6 carbocyclic ring system or ; ; ; ; ; ; ; ; ; ; ; ; ; ; 3a ; 3b ; Form a 3- to 6-membered heterocyclic ring system, where the ring system is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy and C1-C3 haloalkoxy and may be substituted with 1 to 2 substituents each independently selected from the group consisting of; R 4 is pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl and where the pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl is halogen, hydroxy, -CN, -COOH, -CONH2, -CSNH2, -NO2, -NH2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C 6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C3 haloalkylthio , C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NH( C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl yl, -NHCO-C3-C6 cycloalkyl; -NHCO-phenyl [where the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl]; -N(C1-C4 alkyl)CO -C1-C4 alkyl, -N(C1-C4 alkyl)CO-C3-C6 cycloalkyl; -N(C1-C4 alkyl)CO-phenyl [where the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN , C1-C6 alkyl and C1-C3 haloalkyl]; -N(SO2C1-C3 alkyl)2, -NH(SO2 , C1-C6 alkyl and C1-C3 haloalkyl; -N(SO2C1-C3 alkyl)2, -NH(SO2 C1-C3 alkyl) and may be substituted with 1 to 2 substituents each independently selected from the group consisting of; (C1-C3 alkyl), -N(C1-C4 alkyl)(SO2C1-C3 alkyl), - CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -C(=NOC1-C4 alkyl)H and -C(=NOC1-C4 alkyl )-C1-C4 alkyl, and may be substituted with 1 to 3 substituents selected from the group consisting of: preferably; R 5 is hydrogen, halogen, -CN, C1-C3 alkyl, C1-C3 haloalkyl, C 3-C4 cycloalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C 3 alkoxyC(O)-, (C1-C3 alkoxy)2CH-, -CO2C1-C4 alkyl kil, -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -NH CO-C1-C4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl, - C(=NOC1-C4 alkyl)H or -C(=NOC1-C4 alkyl)-C1-C4 alkyl]; is a compound represented by.
[0012] Equally preferred is (Configuration 2-2), formula (I) [wherein, X is O or S; Q 1 and Q 2 are independently CR 5 or N, provided that at least 1 one of Q 2 and Q is N; Y is a direct bond or CH2; R 1 is hydrogen; C1-C6 alkyl [wherein the alkyl is substituted with 1 substituent selected from -CN, -CONH2, -COOH, -NO2 and -Si(CH3)3]; may also be]; C1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkynyl; C3-C4 cycloalkyl-C1-C2 alkyl-[wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or, benzyl [wherein the benzyl may be substituted with halogen or C1-C3 haloalkyl]; C3-C4 cycloalkyl-C1-C2 alkyl-[wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or, benzyl [wherein the benzyl may be substituted with halogen or C1-C3 haloalkyl]; C3-C4 cycloalkyl-C1-C2 alkyl-[wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or, benzyl [wherein the benzyl may be substituted with halogen or C1-C3 haloalkyl]; C3-C4 cycloalkyl-C1-C2 alkyl-[wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or, benzyl [wherein the benzyl may be substituted with halogen or C1-C3 haloalkyl]; C3-C4 cycloalkyl-C1-C2 alkyl-[wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or, benzyl [wherein the benzyl may be substituted with halogen or C1-C3 haloalkyl]; exists; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents, provided that at least one substituent is present on any carbon adjacent to the carbon bonded to the C=X group, and the substituent is the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents, provided that at least one substituent is present on any carbon adjacent to the carbon bonded to the C=X group, and the substituent is the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents, provided that at least one substituent is present on any carbon adjacent to the carbon bonded to the C=X group, and the substituent is halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -NO2, C1-C6 alkyl, optionally substituted C3-C6 cycloalkyl; optionally substituted C3-C6 cycloalkyl; C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein in each case, the phenyl is halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein in each case, the phenyl is halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl, optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C 4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl; -NHCO-phenyl, wherein the phenyl is selected from halogen, CN, C1-C6 alkyl and and C1-C3 haloalkyl, good]; -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C 4 alkyl), -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkoxy) -C(=NOC1-C4 alkyl)H, -C(= NOC1-C4 alkyl)-C1-C4 alkyl; and Phenyl and 5-6 membered heteroaryl [wherein the phenyl or 5-6 membered heteroaryl The alkyl groups are halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C 4 alkoxy, each of which is substituted with 1 to 2 substituents independently selected from the group consisting of [May be] each independently selected from the group consisting of: Or, R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine has a total of 1 to 3 substituents. provided that the substituent is not adjacent to the carbon bonded to the C=X group. not present on any carbon atom, and at least one and at most three substituents are C4-C6-alkyl, C1-C6 alkylthio, C1-C6 alkylsulfinyl, C 1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl, C3-C6 cyclo alkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1-C3 haloalkyl sulfinyl, C1-C3 haloalkylsulfonyl; phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein, in each case, the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl, and C1-C3 haloalkyl]; optionally substituted C3-C6 cycloalkyl; -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C 4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl, -NHCO-C3 -C4 cycloalkyl, -NHSO2-phenyl; -NHCO-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C6 alkyl, and C1-C3 haloalkyl]; -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C 4 alkyl)2, -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkyl)(C3-C6 cycloalkyl), -C(=NOC1-C4 alkyl)H, -C(= NOC1-C4 alkyl)-C1-C4 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl may each independently be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, and C1-C4 haloalkoxy] independently selected from the group A consisting of; and, Any of the remaining 1 to 2 substituents is halogen, hydroxy, -NH2, -CN, -SF5, -COOH, -CONH2, -N O2, C1-C6 alkyl, optionally substituted C3-C6 cycloalkyl; C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkyl sulfinyl, C1-C6 alkylsulfonyl, C1-C3 haloalkylthio, C1-C 3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein, in any case, the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl]; -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C 4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl; -NHCO-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl]; -NHCO-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl]; and may be]; -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C 4 alkyl)2, -CONH(C3-C6 cycloalkyl), -CON(C1-C4 alkyl )(C3-C6 cycloalkyl), -C(=NOC1-C4 alkyl)H, -C( =NOC1-C4 alkyl)-C1-C4 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl or 5- to 6-membered heteroaryl]] is substituted with 1 to 2 substituents each independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C 4 alkoxy; each independently selected from group B consisting of; or R 2 is naphthyl, where the naphthyl is halogen, hydroxy, -CN, -COOH, -CONH2, -NO2, -SF5, -N H2, C1-C6 alkyl, optionally substituted C3-C6 cycloalkyl; C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkyl sulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl 、C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1 -C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkyl sulfonyl; phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [where in each case, the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl, and C1-C3 haloalkyl]; -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C 4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl; -NHCO-phenyl [where the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl, and C1-C3 haloalkyl]; 4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl; -NHCO-phenyl [where the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl, and C1-C3 haloalkyl]; and C1-C3 haloalkyl; -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C 4 alkyl)2, -C(=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl )-C1-C4 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein, the phenyl or 5- to 6-membered heteroaryl is each independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C 4 alkoxy and may be substituted with 1 to 2 substituents] and may be substituted with 1 to 3 substituents independently selected from the group consisting of; or, R 2 is a 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heteroaryl, 9-membered heteroaryl and 10-membered heteroaryl selected from the group consisting of a heterocyclic ring, wherein, these are each, halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -NO2 , -SF5, -NH2, C1-C6 alkyl, optionally substituted C3-C6 cycloalkyl; C3-C6 cycloalkyl-C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C6 alkylthio, C1-C6 alkyl sulfinyl, C1-C6 alkylsulfonyl, C3-C6 cycloalkylsulfanyl , C3-C6 cycloalkylsulfinyl, C3-C6 cycloalkylsulfonyl, C1 -C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkyl sulfonyl; phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein, any of the In each case, the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl, and C1-C3 haloalkyl; ; -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C 4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl; -NHCO-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl, and C1-C3 haloalkyl]; ; -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl), -CON(C1-C 4 alkyl)2, -C(=NOC1-C4 alkyl)H, -C(=NOC1-C4 alkyl )-C1-C4 alkyl; and, phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl may each independently be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C 4 alkoxy]; ; may be independently substituted with 1 to 3 substituents selected from the group consisting of; or, R 2 is C1-C6 alkyl, wherein the alkyl is C1-C3 alkoxy-, C1-C3 haloalkoxy-, C1-C6 alkylthio, C1 -C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C3 haloalkyl thio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl may each independently be substituted with halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C 4 alkoxy; optionally substituted with 1 to 2 substituents each independently selected from the group consisting of 4 alkoxy; ; C3-C6 cycloalkyl [wherein the cycloalkyl is halogen, -CN, -COO H, -CONH2, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cyclo alkyl, C1-C6 alkoxy, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl) and -CON(C1-C4 alkyl)2, and may be substituted with 1 to 2 substituents selected from the group consisting of:]; and, ; and C1-C6 haloalkyl substituted with 1 substituent selected from the group consisting of:; R 3a and R 3b are each independently hydrogen; halogen; -CN; C1-C6 alkyl [wherein the alkyl is hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2 , C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C 4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkyl sulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1- C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NH(C1-C 4 alkyl), -N(C1-C4 alkyl)2, -NHCO-C1-C4 alkyl, -N (C1-C4 alkyl)CO-C1-C4 alkyl, -CO2C1-C4 alkyl, -C ONH(C1-C4 alkyl) and -CON(C1-C4 alkyl)2, and may be independently substituted with 1 to 3 substituents selected from the group consisting of:]; C3-C6 cycloalkyl [wherein the cycloalkyl is halogen, -CN, -COOH, -CONH2, C1- ; here, the cycloalkyl is halogen, -CN, -COOH, -CONH2, C1- C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C1-C6 alkoxy oxy, C1-C6 haloalkoxy, -CO2C1-C4 alkyl, -CONH(C1-C 1 to 2 selected from the group consisting of -CON(C1-C4 alkyl) and -CON(C1-C4 alkyl)2 may be substituted by a substituent; C1-C6 haloalkyl, wherein the haloalkyl is , hydroxy, -CN, C3-C6 cycloalkyl, C1-C6 alkoxy, C1-C6 Haloalkoxy, -CO2C1-C4 alkyl, -CONH(C1-C4 alkyl) and -CON(C1-C4 alkyl)2 C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkyl nyl; C2-C6 haloalkynyl; benzyl, wherein the phenyl substituents are halogen, Hydroxy, -CN, -COOH, -CONH2, -NO2, -NH2, -SF5, C1 -C6 alkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C4 haloal koxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkyl sulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl, Heterocyclyl-C1-C6 alkyl, optionally substituted by a substituent; The heterocyclyl substituents are 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered heterocyclyl, and 6-membered heteroaryl, each of which is selected from the group consisting of Halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH2, -N O2, -NH2, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy optionally substituted with 1 to 3 substituents independently selected from the group consisting of ]; phenyl yl [wherein the phenyl is halogen, hydroxy, -CN, -COOH, -CONH2 , -NO2, -NH2, -SF5, C1-C6 alkyl, C1-C3 haloalkyl, C1 -C4 alkoxy, C1-C4 haloalkoxy, C1-C3 alkylthio, C1-C3 a lkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C 1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl, and may be optionally substituted with 1 to 5 substituents independently selected from the group consisting of ]; and hetero cyclic [wherein the heterocyclic substituent is selected from the group consisting of 4- to 10-membered saturated and partially unsaturated he terocyclyl, 5-membered heteroaryl and 6-membered heteroaryl, and wherein these are each independently selected from the group consisting of halogen, =O (oxo), hydroxy, -CN, -COO H, -CONH2, -NO2, -NH2, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy, and may be optionally substituted with 1 to 3 substituents independently selected from the group consisting of ]; and is selected from the group consisting of; or, R and R form, together with the carbon to which they are attached, a C3-C6 carbocyclic ring system or a 3a 3- to 6-membered heterocyclic ring system, wherein the ring system may be optionally substituted with 1 to 2 substituents independently selected from the group consisting of halogen, -CN, C1-C6 3b alkyl, C1-C3 haloalkyl, C1-C4 alkoxy and C1-C3 haloalkoxy ; and R is pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl, and R 4 is pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl , herein, the pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl is halogen, hydroxy, -CN, -COOH, -CO2-C1-C6 alkyl, -CON H2, -CSNH2, -NO2, -NH2, C1-C6 alkyl, C3-C6 cycloalkyl , C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C 1-C6 alkylthio, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl , C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 halo alkylsulfonyl, -NH(C1-C4 alkyl), -N(C1-C4 alkyl)2 , -NHCO-C1-C4 alkyl [wherein the alkyl may be substituted with -CN, C1-C6 alkyl and C1-C4 alkoxy]; -NHCO-C1-C4 haloalkyl , -NHCO-C3-C6 cycloalkyl [wherein the cycloalkyl may be substituted with halogen , -CN, C1-C6 alkyl or C1-C4 alkoxy and is optionally substituted with 1 to 2 substituents selected from the group consisting of]; -NHCO-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C6 alkyl and C1-C3 haloalkyl ; -N(C1-C4 alkyl)CO- C1-C4 alkyl, -N(C1-C4 alkyl)CO-C3-C6 cycloalkyl; - N(C1-C4 alkyl)CO-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C 1-C6 alkyl and C1-C3 haloalkyl ; -N(SO2C1-C3 alkyl)2, -NH(SO2C1 -C3 alkyl), -N(C1-C4 alkyl)(SO2C1-C3 alkyl), -N( (SO2C1-C3 haloalkyl)2, -NH(SO2C1-C3 haloalkyl), -CO NH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -CONH-SO2 -C1-C3 alkyl, -CON(C1-C4 alkyl)(C3-C6 cycloalkyl) , -CONH(C1-C4 haloalkyl), -CONH(C3-C6 cycloalkyl), -CONH(C3-C6 cyanocycloalkyl), -C(=NOC1-C4 alkyl)H and -C(=NOC1-C4 alkyl)-C1-C4 alkyl; and, -CONH-phenyl wherein the phenyl is optionally substituted with 1 to 2 substituents each independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 halo alkyl and C1-C4 alkoxy] and is optionally substituted with 1 to 3 substituents selected from the group consisting of ; ; R 5 is hydrogen, halogen, -CN, C1-C3 alkyl, C1-C3 haloalkyl, C 3-C4 cycloalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, C1-C 3 alkoxyC(O)-, (C1-C3 alkoxy)2CH-, -CO2C1-C4 alkyl , -CONH(C1-C4 alkyl), -CON(C1-C4 alkyl)2, -NH CO-C1-C4 alkyl, -N(C1-C4 alkyl)CO-C1-C4 alkyl, - C(=NOC1-C4 alkyl)H or -C(=NOC1-C4 alkyl)-C1-C4 alkyl); and is a compound represented by
[0013] More preferred is (Constitution 3-1), formula (I) [wherein, X is O or S; Q 1 and Q2 is, independently, CR 5 or N, provided that Q 1 and Q 2 of which at least one is N; Y is a direct bond or CH2; R 1 is hydrogen; C1-C3 alkyl [wherein the alkyl is substituted with one substituent selected from -CN, -CONH2, -COOH, -NO2 and -Si(CH3)3]; C1-C3 haloalkyl; C2-C4 alkenyl; C2-C4 haloalkenyl ; C2-C4 alkynyl; C2-C4 haloalkynyl; C3-C4 cycloalkyl-C 1-C2 alkyl- [wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or benzyl [where in the benzyl may be substituted with halogen or C1-C3 haloalkyl]; and; ; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents provided that at least one substituent is present on any carbon adjacent to the carbon to which the C=X group is attached, and the substituent is halogen, -CN, -NO2 , C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C 4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkyl sulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl , C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C ; 1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloal phenyl and 5-6 membered heteroaryl, The 6-membered heteroaryl includes halogen, -CN, C1-C3 alkyl and C1-C3 haloaryl. and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl, alkyl, and alkyl. are each independently selected; Or, R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine has a total of 1 to 3 substituents. provided that the substituent is not adjacent to the carbon bonded to the C=X group. and at least one and at most two substituents are not present on any of the C3-C4 carbon atoms. Chloroalkyl, C1-C4 alkylthio, C1-C3 alkylsulfinyl, C1-C3 Alkyl sulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkyl sulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylsulf phenylsulfanyl, C1-C3 haloalkylsulfonyl; phenylsulfanyl [wherein the phenyl The alkyl group is selected from the group consisting of halogen, -CN, C1-C3 alkyl, or C1-C3 haloalkyl. phenylsulfinyl [wherein The phenyl is selected from halogen, -CN, C1-C3 alkyl, and C1-C3 haloalkyl. phenylsulfonyl, optionally substituted with 1 to 2 substituents selected from the group consisting of
[0023] wherein the phenyl is selected from halogen, -CN, C1-C3 alkyl or C1-C3 haloaryl. -NHCO -phenyl, wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C 3 haloalkyl]; - CONH(C3-C4 cycloalkyl), -CON(C1-C3 alkyl)(C3-C4 cycloalkyl), -C(=NOC1-C3 alkyl)-C1-C3 alkyl; phenyl and 5- to 6-membered heteroaryl, wherein the phenyl or 5- to 6-membered heteroaryl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl, C1-C3 haloalkyl and C1-C3 halo alkoxy]; are independently selected from the group A; The remaining 1 to 2 optional substituents are halogen, -CN, -NO2, C1-C6 alkyl, C 3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C 3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfi nyl, C1-C3 haloalkylsulfonyl; phenyl and 5- to 6-membered heteroaryl [where in, the phenyl and 5- to 6-membered heteroaryl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 al kyl and C1-C3 haloalkyl]; are independently selected from the group B respectively; Or, or R 2 is thiophene, furan, pyrazole, thiazole, isothiazole, oxazolo le or isoxazole, wherein each of these is halogen, hydroxy, -CN, -NO2, C1-C6 alkyl, C3-C4 cycloalkyl, C1-C3 halo Lukyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkyl sulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkyl sulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C 1-C3 haloalkylsulfonyl; phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is optionally substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl, and C1-C3 haloalkyl]; and is optionally substituted with 1 to 3 substituents independently selected from the group consisting of ; or, or, R 2 is C1-C6 alkyl, wherein the alkyl is C1-C3 alkoxy- , C1-C3 haloalkoxy-, C1-C3 alkylthio, C1-C3 alkylsulfi nyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkyl sulfinyl, C1-C3 haloalkylsulfonyl; phenyl [wherein the phenyl is optionally substituted with 1 to 2 substituents independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C4 alkoxy]; and is substituted with 1 substituent selected from the group consisting of ; R 3a , R 3b are independently hydrogen; C1-C6 alkyl [wherein the alkyl is C 1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 a lkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkyls Rufinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 optionally substituted with 1 to 3 substituents independently selected from the group consisting of haloalkylsulfinyl and C1-C3 haloalkylsulfonyl]; C3-C6 cycloalkyl; C 1-C6 haloalkyl; C2-C6 alkenyl; C2-C6 haloalkenyl; C2-C6 alkynyl; C2-C6 haloalkynyl; benzyl [wherein the phenyl substituent is halo gen, -CN, -NO2, C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 a lkoxy and C1-C4 haloalkoxy, optionally substituted with 1 to 3 substituents independently selected from the group consisting of]; or, heterocyclyl-C1-C6 alkyl [wherein the heterocyclyl substituent is selected from the group consisting of 4- to 10-membered heterocyclyl, 5-membered heteroaryl and 6-membered he teroaryl, wherein each of these is independently selected from the group consisting of halogen, -CN , -NO2, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy, optionally substituted with 1 to 3 substituents]; or, phe nyl [wherein the phenyl is optionally substituted with 1 substituent selected from the group consisting of halogen, -CN, -NO2, C1-C6 alkyl, C1 -C3 haloalkyl and C1-C4 alkoxy]; selected from the group consisting of; or, R 3a 、R 3b together with the carbon to which they are attached form a cyclopropane ring, cyclobut ane ring, oxetane ring or tetrahydropyran ring, wherein the ring is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy, consisting of may be substituted with 1 to 2 substituents each independently selected from the following groups; R 4 is pyridine, pyrimidine or thiazole, where (A) the pyridine or pyrimidine is substituted with 1 to 3 substituents selected from the group consisting of halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl and C1-C 3 haloalkylsulfonyl, and (B) the thiazole is substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1- C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1 -C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulf inyl and C1-C3 haloalkylsulfonyl; may be substituted; R 5 is hydrogen, halogen, -CN, C1-C3 alkyl, C1-C3 haloalkyl, C 3-C4 cycloalkyl or C1-C3 alkoxy); is a compound represented by
[0014] Equally more preferred is (Constitution 3-2), Formula (I) [wherein, X is O or S; Q 1 and Q 2 are independently CR 5 or N, provided that at least one of Q 1 and Q 2 is 1 is also N; Y is either a direct bond or CH2; R 1 is hydrogen; C1-C3 alkyl [wherein the alkyl is substituted with one substituent selected from -CN, -CONH2, -COOH, -NO2 and -Si(CH3)3]; C1-C3 haloalkyl; C2-C4 alkenyl; C2-C4 haloalkenyl ; C2-C4 alkynyl; C2-C4 haloalkynyl; C3-C4 cycloalkyl-C1-C2 alkyl-[wherein the C3-C4 cycloalkyl may be substituted with one or two halogen atoms]; oxetan-3-yl-CH2-; or benzyl [wherein the benzyl may be substituted with halogen or C1-C3 haloalkyl]; and R is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, wherein the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents, provided that at least one substituent is present on any carbon adjacent to the carbon bonded to the C=X group, and the substituent is halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1- 2 C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; and phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is substituted with 1 to 5 substituents selected from halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, and phenyl and 5- to 6-membered heteroaryl]; and the substituents are selected from halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1- C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; and phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl is substituted with 1 to 5 substituents selected from halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, and phenyl and 5- to 6-membered heteroaryl]; and the substituents are selected from halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; and phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl R is selected independently from the group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl, and may be substituted with 1 to 2 substituents selected from the group consisting of; or, R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where the phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with a total of 1 to 3 substituents provided that the substituents are not present on any carbon adjacent to the carbon to which the C═X group is attached, and that at least 1 and at most 2 of the substituents are C4-alkyl, C3-C4 cycloalkyl [wherein the C3-C4 cycloalkyl may be substituted with -CN or halogen], C1-C4 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; and phenylsulfanyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl]; phenylsulfinyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl]; phenylsulfonyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl]; phenylsulfinyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl]; phenylsulfonyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl]; -NHCO-phenyl, wherein the phenyl is substituted with 1 to 2 substituents selected from the group consisting of halogen, CN, C1-C6 alkyl and C1-C3 haloalkyl; ; -NHCO-C1-C3 alkyl, -NHCO-C3-C4 cycloalkyl, -NHSO 2-phenyl; -CONH(C3-C4 cycloalkyl), -CON(C1-C3 alkyl)(C3-C 4 cycloalkyl), -C(=NOC1-C3 alkyl)-C1-C3 alkyl; and phenyl and 5- to 6-membered heteroaryl, wherein the phenyl or 5- to 6-membered heteroaryl is substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl, C1-C3 haloalkyl and C1-C 3 haloalkoxy; is independently selected from group A; and the remaining 1 to 2 optional substituents are halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1- C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alk ylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C 3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulf onyl; and phenyl and 5- to 6-membered heteroaryl, wherein the phenyl and 5- to 6-membered heteroaryl are substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl are each independently selected from group B; or R 2 is thiophene, furan, pyrazole, thiazole, isothiazole, oxazole or isoxazole, where each of these is independently selected from the group consisting of halogen, hydroxy, -CN, -NO2, C1-C6 alkyl, C3-C4 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C 1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; and phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl may be substituted with 1 to 2 substituents independently selected from the group consisting of halogen, -CN, C1-C3 alkyl, and C1-C3 haloalkyl] and may be substituted with 1 to 3 substituents independently selected from the group consisting of; or, R is C1-C6 alkyl, where the alkyl is substituted with 1 substituent independently selected from the group consisting of C1-C3 alkoxy-, C1-C3 haloalkoxy-, C1-C3 alkylthio, C1 -C3 alkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkyl 2 thio, C1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl; and phenyl [wherein the phenyl may be substituted with 1 to 2 substituents independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C4 alkoxy] and is substituted with 1 substituent selected from the group consisting of; and is substituted with 1 substituent selected from the group consisting of; wherein each phenyl is independently selected from the group consisting of halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl, and C1-C4 alkoxy and may be substituted with 1 to 2 substituents] or R 2 is naphthyl, where the naphthyl is halogen, hydroxy, -CN, -NO2, C1-C6 alkyl, C3-C4 cycloalkyl kil, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C 1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl , C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 halo alkylsulfinyl, C1-C3 haloalkylsulfonyl; and phenyl and 5- to 6-membered heteroaryl [where the phenyl or 5- to 6-membered heteroaryl may be substituted with one or two substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl, and C1-C3 haloalkyl] and may be independently selected from the group consisting of one to three substituents] or or R 2 is 9- or 10-membered heteroaryl, where the heteroaryl is halogen, hydroxy, -CN, -NO2, C1-C6 alkyl, C3-C4 cycloalkyl kil, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C 1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkylsulfonyl , C3-C4 cycloalkylsulfanyl, C3-C4 cycloalkylsulfinyl, C3-C4 cycloalkylsulfonyl, C1-C3 haloalkylthio, C1-C3 halo alkylsulfinyl, C1-C3 haloalkylsulfonyl; and Phenyl and 5-6 membered heteroaryl [wherein the phenyl or 5-6 membered heteroaryl The group consisting of halogen, -CN, C1-C3 alkyl and C1-C3 haloalkyl. may be substituted with 1 to 2 substituents selected from may be substituted with 1 to 3 substituents independently selected from the group consisting of: R 3a , R 3b are independently hydrogen; C1-C6 alkyl, 1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 a alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkyls Rufinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C1-C3 Independently from the group consisting of haloalkylsulfinyl and C1-C3 haloalkylsulfonyl 1 to 3 substituents selected from the group consisting of C3-C6 cycloalkyl; 1-C6 haloalkyl;C2-C6 alkenyl;C2-C6 haloalkenyl;C2-C6 Alkynyl; C2-C6 haloalkynyl; benzyl, wherein the phenyl substituent is halo. Gen, -CN, -NO2, C1-C6 alkyl, C1-C3 haloalkyl, C1-C4 a 1 to 3 substituents independently selected from the group consisting of alkoxy and C1-C4 haloalkoxy or heterocyclyl-C1-C6 alkyl, Heterocyclyl substituents include 4- to 10-membered heterocyclyl, 5-membered heteroaryl and 6-membered aryl. and aryl, each of which is selected from the group consisting of halogen, -CN , -NO2, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy. or phenyl, each of which is optionally substituted with 1 to 3 substituents independently selected from the group consisting of: nil [wherein the phenyl is substituted with one substituent selected from the group consisting of halogen, -CN, -NO2, C1-C6 alkyl, C1 -C3 haloalkyl and C1-C4 alkoxy] and is selected from the group consisting of; optionally substituted]; or, R 3a and R 3b together with the carbon to which they are attached form a cyclopropane ring, cyclobut ane ring, oxetane ring or tetrahydropyran ring, wherein the ring is halogen, -CN, C1-C6 alkyl, C1-C3 haloalkyl and C1-C4 alkoxy are each independently selected from the group consisting of optionally substituted with 1 to 2 substituents; R 4 is pyridine, pyrimidine, pyrazine, pyridazine or thiazole, wherein , (A) the pyridine, pyrimidine, pyrazine or pyridazine is halogen, -CN, -N H2, -NO2, -COOH, -CONH2, -CSNH2, -CO2-C1-C3 alk yl, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1 -C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 a lkylsulfinyl, C1-C3 alkylsulfonyl, C1-C3 haloalkylthio, C 1-C3 haloalkylsulfinyl, C1-C3 haloalkylsulfonyl, -NHCO- C1-C3 alkyl, -NHCO-C1-C3 haloalkyl, -NHCO-C1-C3 cy cloalkyl, -NHCO-C3-C4 cycloalkyl [wherein the cycloalkyl is, fluorine, chlorine, -CN, C1-C6 alkyl or C1-C4 alkoxy selected from the group consisting of optionally substituted with 1 to 2 substituents]; -NHCO-phenyl [wherein the The phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl, C1-C3 haloalkyl, C1- C3 alkoxy and C1-C3 haloalkoxy]; -NHSO2-C1-C3 alkyl, -NHSO2-C1- C3 haloalkyl, -CONH(C1-C3 alkyl), -CON(C1-C3 alkyl )2, -CONH-SO2-C1-C3 alkyl, -CON(C1-C3 alkyl)(C 3-C6 cycloalkyl), -CONH(C1-C3 haloalkyl), -CONH(C3 -C6 cycloalkyl), -CONH(1-cyano-C3-C6 cycloalkyl), -C ONH-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, C1-C3 alkyl, C 1-C3 haloalkyl, C1-C3 alkoxy and C1-C3 haloalkoxy]; and is substituted with 1 to 3 substituents selected from the group consisting of: and, ; and (B) the thiazole may be substituted with 1 to 2 substituents selected from the group consisting of halogen, -CN, -NO2, C1-C6 alkyl, C3-C6 cycloalkyl, C1-C3 haloalkyl, C1-C4 alkoxy, C1-C3 haloalkoxy, C1-C3 alkylthio, C1-C3 alkylsulfinyl, C1-C3 alkyl sulfonyl, C1-C3 haloalkylthio, C1-C3 haloalkylsulfinyl and C1-C3 haloalkylsulfonyl; ; ; ; R 5 is hydrogen, halogen, -CN, C1-C3 alkyl, C1-C3 haloalkyl, C 3-C4 cycloalkyl or C1-C3 alkoxy). It is a compound represented by
[0015] Particularly preferred is (Constitution 4-1), formula (I) [wherein, X is O or S; Q 1 and Q 2 are independently CR 5 or N, provided that Q 1 and Q 2 at least one of is N; Y is a direct bond or CH2; R 1 is hydrogen; C1-C3 alkyl [wherein the alkyl may be substituted with -CN, -Si(CH3 )3, or may be substituted with 1 to 3 substituents selected from the group consisting of fluorine, chlorine or bromine]; C2-C4 alkenyl; C2-C4 al kynyl; C3-C4 cycloalkyl-C1-C2 alkyl- [wherein the C3-C4 cyclo alkyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine and bromine] ; ; R 2 is phenyl or pyridine, wherein the phenyl or pyridine is substituted with 1 to 3 substituents, provided that at least one substituent is present on any carbon adjacent to the carbon bonded to the C=X group, and the substituent is fluorine, chlorine, bromine, -CN, -NO2, methyl, cyclopropyl, difluoromethyl, trifluorometh yl, methoxy, trifluoromethoxy, difluoromethoxy, methylthio, methylsulf inyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethylsulfonyl, i sopropylthio, isopropylsulfinyl, isopropylsulfonyl, cyclopropyl thio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoromethylthio ; , difluoromethylsulfinyl, difluoromethylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl and phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl] are each independently selected; or, R is phenyl or pyridine, wherein the phenyl or pyridine is substituted with a total of 1 to 3 substituents, provided that the substituents are not present on any carbon adjacent to the carbon to which the C=X group is attached, and one of the substituents is cyclopropyl, methylthio, methylsulfinyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethylsulfonyl, isopropylthio, isopropylsulfinyl, isopropylsulfonyl, tert-butylthio, tert-butylsulfinyl, tert-butylsulfonyl, cyclopropylthio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoromethylsulfinyl, difluoromethylsulfonyl, trifluoromethylsulfinyl, trifluoromethylsulfonyl; phenylsulfonyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl]; -NHCO-phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, CN, methyl and trifluoromethyl]; (cyclopropylamino)carbonyl, 1-(methoxyimino)ethyl; phenyl and 5-membered heteroaryl [wherein the phenyl or respectively independently selected; or, R 2 is phenyl or pyridine, where the phenyl or pyridine is substituted with a total of 1 to 3 substituents, provided that the substituents are not present on any carbon adjacent to the carbon to which the C=X group is attached, and one of the substituents is cyclopropyl, methylthio, methylsulfinyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethyl sulfonyl, isopropylthio, isopropylsulfinyl, isopropylsulfonyl, tert-butylthio, tert-butylsulfinyl, tert-butylsulfonyl, cyclopropylthio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoro methylsulfinyl, difluoromethylsulfonyl, trifluoromethylsulfinyl, trifluoromethylsulfonyl; phenylsulfonyl [where the phenyl is selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl] may be substituted with 1 to 2 substituents; -NHCO-phenyl [where the phenyl is selected from the group consisting of fluorine, chlorine, CN, methyl and trifluoromethyl] may be substituted with 1 to 2 substituents; (cyclopropylamino)carbonyl, 1 -(methoxyimino)ethyl; phenyl and 5-membered heteroaryl [where the phenyl or wherein the phenyl is phenyl or pyridine, and the phenyl or pyridine is substituted with a total of 1 to 3 substituents, provided that the substituents are not present on any carbon adjacent to the carbon to which the C=X group is attached, and one of the substituents is cyclopropyl, methylthio, methylsulfinyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethyl sulfonyl, isopropylthio, isopropylsulfinyl, isopropylsulfonyl, tert-butylthio, tert-butylsulfinyl, tert-butylsulfonyl, cyclopropylthio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoromethylsulfinyl, difluoromethylsulfonyl, trifluoromethylsulfinyl, trifluoromethylsulfonyl; phenylsulfonyl [where the phenyl is selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl] may be substituted with 1 to 2 substituents; -NHCO-phenyl [where the phenyl is selected from the group consisting of fluorine, chlorine, CN, methyl and trifluoromethyl] may be substituted with 1 to 2 substituents; (cyclopropylamino)carbonyl, 1-(methoxyimino)ethyl; phenyl and 5-membered heteroaryl [where the phenyl or The 5-membered heteroaryl is selected independently from group A consisting of optionally substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl, trifluoro methyl and trifluoromethoxy; wherein the remaining 1 to 2 optional substituents are fluorine, chlorine, bromine, -CN, -NO2, methyl, cyclo propyl, difluoromethyl, trifluoromethyl, methoxy, trifluoromethoxy difluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl, difluoro romethylthio, difluoromethylsulfinyl, difluoromethylsulfonyl, triflu oromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl and phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl]; each independently selected from group B consisting of; or, or, R 2 is thiophene, furan, pyrazole, thiazole, oxazole or isoxa zole, wherein each of these is independently fluorine, chlorine, bromine, -CN, -NO2, methyl, cyclopropyl, difluoromethyl, trifluoromethyl, methoxy, triflu oromethoxy, difluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl difluoromethylthio, difluoromethylsulfinyl, difluoromethylsulfonyl trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl and phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoro romethyl and trifluoromethyl]; optionally substituted with 1 to 3 substituents independently selected from the group consisting of ; or R 2 is C1-C3 alkyl, where the alkyl is methoxy, trifluoro methoxy, difluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluoromethylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfono yl and phenyl [where the phenyl is substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluorometh yl and trifluoromethyl and may be substituted]; substituted with 1 substituent selected from the group consisting of R 3a and R 3b are independently hydrogen; C1-C3 alkyl [where the alkyl is me thyl, ethyl, iso-propyl, n-propyl, cyclopropyl, cyclobutyl, diflu oromethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, triflu oromethoxy, methylthio, methylsulfinyl, methylsulfonyl, trifluorometh ylthio, trifluoromethylsulfinyl and trifluoromethylsulfonyl and may be independently substituted with 1 to 3 substituents selected from the group consisting of]; cyclopropyl, di fluoromethyl, trifluoromethyl, difluoromethyl, trifluoromethyl, 2,2 -difluoroethyl, 2,2,2-trifluoroethyl, ethynyl, 2-propen-1- yl and 2-propyn-1-yl; benzyl [where the phenyl substituent is fluorine, chlorine independently selected from the group consisting of sulfur, bromine, -CN, NO2, methyl, trifluoromethyl and methoxy]; heterocyclyl-methyl wherein the heterocyclyl substituent is selected from the group consisting of 4- to 10-membered heterocyclyl, 5-membered heteroaryl and 6-membered heteroaryl, wherein these are each independently selected from the group consisting of fluorine chlorine, bromine, -CN, -NO2, methyl, trifluoromethyl and methoxy and may be substituted with 1 to 3 substituents; and phenyl [where the phenyl may be substituted with 1 substituent selected from the group consisting of fluorine, chlorine, bromine, -CN, -NO2, methyl, trifluoromethyl and methoxy]; selected from the group consisting of ; or, or R 3a and R 3b together with the carbon to which they are attached form a cyclopropane ring, cyclobutane ring, oxetane ring or tetrahydropyran ring; R 4 is pyridine, pyrimidine or thiazole, where (A) the pyridine or pyrimidine is selected from the group consisting of fluorine, chlorine, bromine, -CN, -NO2, methyl, ethyl, difluoromethyl trifluoromethyl, pentafluoroethyl, cyclopropyl, methoxy, difluoro methoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl difluoromethylthio, difluoromethylsulfinyl, difluoromethylsulfonyl trifluoromethylthio, trifluoromethylsulfinyl and trifluoromethyl sulfonyl and may be substituted with 1 to 3 substituents, and (B) the thiazole is selected from the group consisting of fluorine, chlorine, bromine, -CN, -NO2, methyl, ethyl, dif Ruo methyl, trifluoromethyl, pentafluoroethyl, cyclopropyl, methoxy , difluoromethoxy, trifluoromethoxy, methylthio, methylsulfinyl, meth ylsulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluorometh ylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl and triflu oromethylsulfonyl, and may be substituted with 1 to 2 substituents selected from the group consisting of ; R 5 is hydrogen, fluorine, chlorine, bromine, -CN, methyl, ethyl, iso-propyl, dif luoromethyl, trifluoromethyl, cyclopropyl, methoxy or ethoxy) is a compound represented by
[0016] Equally particularly preferred is (Constitution 4-2), formula (I) [wherein, X is O or S; Q 1 and Q 2 are independently CR 5 or N, provided that at least 1 one of Q 2 and Q is N; Y is a direct bond or CH2; R 1 is hydrogen; C1-C3 alkyl [wherein the alkyl may be substituted with -CN, -Si(CH3 )3, or may be substituted with 1 to 3 substituents selected from the group consisting of fluorine, chlorine or bromine]; C2-C4 alkenyl; C2-C4 al kynyl; C3-C4 cycloalkyl-C1-C2 alkyl- [wherein the C3-C4 cyclo alkyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine and bromine] ; ; R 2is phenyl or pyridine, where the phenyl or pyridine is substituted with 1 to 3 substituents, provided that at least 1 substituent is present on any carbon adjacent to the carbon bonded to the C=X group, and the substituent is fluorine, chlorine, bromine, -CN, -NO2, methyl, cyclopropyl, difluoromethyl, trifluoromethyl, methoxy, trifluoromethoxy, difluoromethoxy, methylthio methylsulfinyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethyl sulfonyl, isopropylthio, isopropylsulfinyl, isopropylsulfonyl, cyclopropylthio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoro methylthio, difluoromethylsulfinyl, difluoromethylsulfonyl, trifluoro luoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl, and phenyl [where the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl]; and are each independently selected from the group consisting of ; or R 2 is phenyl or pyridine, where the phenyl or pyridine is substituted with a total of 1 to 3 substituents, provided that the substituents are not present on any carbon adjacent to the carbon bonded to the C=X group, and 1 substituent is tert-butyl, cyclopropyl, 1-cyanocyclopropyl, methylthio, methyls ulfinyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethylsulfonyl, isopropylthio, isopropylsulfinyl, isopropylsulfonyl, tert-but Chlorothio, tert-butylsulfinyl, tert-butylsulfonyl, cyclopropyl thio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoromethyls ulfinyl, difluoromethylsulfonyl, trifluoromethylsulfinyl, triflu oromethylsulfonyl, trifluoroethylsulfinyl, trifluoroethylsulfoni l; Phenylsulfonyl [wherein the phenyl is substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoro methyl and trifluoromethyl]; -NHCO-phenyl [wherein the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, CN, methyl and trif luoromethyl]; (Cyclopropylamino)carbonyl, 1-(methoxyimino)ethyl, acetamide, (Cyclopropylcarbonyl)amino, (phenylsulfonyl)amino; and, (Phenylsulfonyl)amino; and, Phenyl and 5-membered heteroaryl [wherein the phenyl or 5-membered heteroaryl is optionally substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl, trifluoromethyl and trifluorometh oxy] selected independently from the group A consisting of; and, The remaining 1 to 2 optional substituents are fluorine, chlorine, bromine, -CN, -NO2, methyl, cyclopropyl, difluoromethyl, trifluoromethyl, methoxy, trifluoromethoxy, difluoromethoxy, methylth io, methylsulfinyl, methylsulfonyl, difluoromethylthio, difluoromethyl sulfinyl, difluoromethylsulfonyl, trifluoromethylthio, trifluorometh ylsulfinyl, trifluoromethylsulfonyl, trifluoroethylthio, trifluoroeth Thiylsulfinyl, trifluoromethylsulfonyl; and, phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl] each independently selected from group B consisting of; or, R 2 is thiophene, furan, pyrazole, thiazole, oxazole or isoxa zole, wherein these are each fluorine, chlorine, bromine, -CN, -NO2, methyl, cyclopropyl, difluoromethyl, trifluoromethyl, methoxy, trifluoromethoxy, difluoromethoxy, methylthio methylsulfinyl, methylsulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluoro methylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, trifluoro methylsulfinyl, trifluoromethylsulfonyl; and, phenyl [wherein the phenyl may be substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, difluoromethyl and trifluoromethyl] optionally substituted with 1 to 3 substituents independently selected from the group consisting of; or, R 2 is C1-C3 alkyl, wherein the alkyl is methoxy, trifluoromethoxy, difluoromethoxy, methylthio, methylsulfini yl, methylsulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluoro methylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, tri fluoromethylsulfonyl; and, phenyl [wherein the phenyl may be substituted with fluorine, chlorine, bromine, -CN, difluoromethyl and optionally substituted with 1 to 2 substituents selected from the group consisting of trifluoromethyl and substituted with 1 substituent selected from the group consisting of; or R 2 is naphthyl; or pyrazolo[1.5-a]pyridin-2-yl[wherein this is optionally substituted with trifluoromethyl or chlorine]; R 3a and R 3b are independently hydrogen; C1-C3 alkyl[wherein the alkyl is me thyl, ethyl, iso-propyl, n-propyl, cyclopropyl, cyclobutyl, diflu oromethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, triflu oromethoxy, methylthio, methylsulfinyl, methylsulfonyl, trifluorometh ylthio, trifluoromethylsulfinyl and trifluoromethylsulfonyl, independently selected from the group consisting of 1 to 3 substituents; cyclopropyl, di fluoromethyl, trifluoromethyl, difluoromethyl, trifluoromethyl, 2,2 -difluoroethyl, 2,2,2-trifluoroethyl, ethynyl, 2-propen-1- yl and 2-propyn-1-yl; benzyl[wherein the phenyl substituent is fluorine, chlorine ine, -CN, NO2, methyl, trifluoromethyl and methoxy, independently selected from the group consisting of 1 to 3 substituents; heterocyclyl-methyl wherein the heterocyclyl substituent is a 4- to 10-membered heterocyclyl, a 5-membered heteroaryl and a 6-membered heteroaryl, selected from the group consisting of, wherein these are each fluorine ine, chlorine, bromine, -CN, -NO2, methyl, trifluoromethyl and methoxy, independently selected from the group optionally substituted with 1 to 3 substituents independently selected from; and phenyl wherein the phenyl is optionally substituted with 1 substituent selected from the group consisting of fluorine, chlorine, bromine, -CN, -NO2, methyl, trifluoromethyl and methoxy]; selected from the group consisting of ; or R 3a and R 3b together with the carbon to which they are attached form a cyclopropane ring, cyclobutane ring, oxetane ring or tetrahydropyran ring; ; R 4 is pyridine, pyrimidine, pyrazine or thiazole, where (A) the pyridine, pyrimidine or pyrazine is fluorine, chlorine, bromine, -CN, -NH2, -NO2 , -COOH, -CONH2, -CSNH2, -CO2Me, methyl, ethyl, difluoromethyl, trifluoromethyl, pentafluoroethyl, cyclopropyl, methoxy, difluoromethoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluoromethylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl, -NHCO-methyl, -NHCO-trifluoromethyl, -NHCO- CH2CN, -NHCO-cyclopropyl, -NHCO-1-cyanocyclopropyl, - NHSO2-methyl, -NHSO2-trifluoromethyl, -NHCO-phenyl [where the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy]; -CONH-methyl, -CONH- ; ; ; ; ; where the phenyl is optionally substituted with 1 to 2 substituents selected from the group consisting of fluorine, chlorine, bromine, -CN, methyl, difluoromethyl, trifluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy]; -CONH-methyl, -CONH- ; ; SO2-methyl, -CON-(N-methyl)-N-cyclopropyl, -CONH-diflu oroethyl, -CONH-trifluoroethyl, -CONH-cyclopropyl, -CON H-1-cyanocyclopropyl, -CONH-phenyl [wherein the phenyl is fluorine , chlorine, bromine, -CN, methyl, difluoromethyl, trifluoromethyl, methoxy, di fluoromethoxy and trifluoromethoxy, and may be substituted with 1 to 2 substituents selected from the group consisting of and may be substituted with 1 to 3 substituents selected from the group consisting of]; and ; and (B) the thiazole is fluorine, chlorine, bromine, -CN, -NO2, methyl, ethyl, dif luoromethyl, trifluoromethyl, pentafluoroethyl, cyclopropyl, methoxy , difluoromethoxy, trifluoromethoxy, methylthio, methylsulfinyl, meth ylsulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluorometh ylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl and triflu oromethylsulfonyl, and may be substituted with 1 to 2 substituents selected from the group consisting of ; R 5 is hydrogen, fluorine, chlorine, bromine, -CN, methyl, ethyl, iso-propyl, dif luoromethyl, trifluoromethyl, cyclopropyl, methoxy or ethoxy) is a compound represented by.
[0017] Highly particularly preferred is (Constitution 5-1), formula (I) [wherein, X is O; Q 1 is N; Q 2 is CR 5 ; Y is a direct bond; R 1 is hydrogen, cyclopropyl-CH2-, 3,3,3-trifluoropropyl, ethyl or 2,2-difluoroethyl; R 2 is 3-chloro-2-fluoro-5-(trifluoromethyl)phenyl, 3-chloro 5-(methylsulfonyl)phenyl, 5-(methylsulfonyl)pyridin-3-yl , 3-(methylsulfonyl)phenyl, 3-(trifluoromethylsulfonyl)phenyl , 5-[(trifluoromethyl)sulfonyl]pyridin-3-yl, 3-chloro-5- (cyclopropylamino)carbonyl]phenyl, 3-cyclopropyl-5-(trif luoromethyl)phenyl, 2,3,5-trichlorophenyl, 3-phenyl-5-(trif luoromethyl)phenyl, [3-chloro-5-(trifluoromethyl)phenyl]methyl , 3-(4-fluorophenyl)-5-(trifluoromethyl)phenyl, 2-chlorop henyl, 2,5-dichlorophenyl, 2,3,4-trichlorophenyl, 2,3-dichloro phenyl, 2,4-dichlorophenyl, 2,6-difluorophenyl, 3-chloro-5 -(trifluoromethylsulfonyl)phenyl, 5-chloro-3-thienyl, 3,4,5 -trichloro-2-thienyl, 2,5-dichloro-3-thienyl, 4,5-dichloro-2 -thienyl, 1-methyl-5-(trifluoromethyl)-1H-pyrazol-3-yl, 4-chloro-1-methyl-3-(trifluoromethyl)-1H-pyrazol-5-yl, 5-methyl-1,2-oxazol-3-yl, 5-cyclopropyl-1,2-oxazo le-3-yl, 3-chloro-1,2-oxazol-5-yl, 2-chloro-1,3- Thiazol-5-yl, 1-methyl-1H-pyrazol-4-yl, 5-chloro-1-me thyl-1H-pyrazol-4-yl, 3-chloro-5-cyclopropylsulfonylpheni l, 3-chloro-5-(4-fluorophenyl)sulfonylphenyl, 3-chloro-5- ethylsulfonylphenyl, 3-cyclopropyl-5-fluorophenyl, 3-chloro- 5-(isopropylthio)phenyl, 3-chloro-5-(1H-pyrazol-1-yl) phenyl, 3-chloro-5-(1H-1,2,4-triazol-1-yl)phenyl, 3-chloro-5-cyclopropylphenyl, 3-chloro-5-isopropylsulfonylf enyl, 1-(4-fluorophenyl)-3-(trifluoromethyl)-1H-pyrazo l-5-yl, 3-cyclopropyl-5-(trifluoromethoxy)phenyl, 4-(tr ifluoromethylsulfonyl)phenyl, 3-chloro-5-[1-(methoxyimino)e thyl]phenyl, 3-(tert-butylthio)-5-chlorophenyl, 1-(4-flu orophenyl)-5-(trifluoromethyl)-1H-pyrazol-3-yl, 5-[4 -(trifluoromethoxy)phenyl]pyridin-3-yl, 3-chloro-5-methyls ulfanyl phenyl, 3-chloro-5-methylsulfinylphenyl or 3-benzami do-5-chlorophenyl; R 3a is hydrogen, methyl or methoxymethyl; R 3b is, when R 3a is hydrogen, methyl or methoxymethyl; R 3b is, when R 3a is methyl or methoxymethyl, hydrogen; R 4is 2-pyridinyl, 2-pyrimidin-2-yl, 2-pyrimidin-4-yl, 5 -chloropyridin-2-yl, 4-chloropyridin-2-yl, 5-cyanopyridin-2 -yl, 4-cyano-2-pyridinyl, 5-(trifluoromethyl)-pyridin-2-yl 5-(difluoromethoxy)pyridin-2-yl, 5-(trifluoromethylthio) pyridin-2-yl, 3,5-difluoro-2-pyridinyl, 5-chloro-3-fluoro -2-pyridinyl, 5-fluoropyrimidin-2-yl, 5-chloropyrimidin-2-yl 2-pyrazin-2-yl or 1,3-thiazol-2-yl; R 5 is hydrogen or methyl〕 and is a compound represented by the formula:
[0018] Equally highly particularly preferred is (Constitution 5-2), formula (I) [wherein, X is O or S; Q 1 is N; Q 2 is CR 5 ; Y is a direct bond or CH2; R 1 is hydrogen, methyl, ethyl, 2-(trimethylsilyl)ethyl, 2,2-difluoro ethyl, 2,2,2-trifluoroethyl, 3,3,3-trifluoropropyl or cyclo propyl-CH2-; R 2 is 3-chloro-2-fluoro-5-(trifluoromethyl)phenyl, 3-chloro 5-(methylsulfonyl)phenyl, 3-methylsulfonyl-5-(trifluoromethyl phenyl, 5-(methylsulfonyl)pyridin-3-yl, 3-(methylsulfonyl phenyl, 3-(trifluoromethylsulfonyl)phenyl, 5-[(trifluoro (methyl)sulfonyl]pyridin-3-yl, 3-chloro-5-[(cyclopropylamino )carbonyl]phenyl, 3-cyclopropyl-5-(trifluoromethyl)phenyl, 2,3,5-trichlorophenyl, 3-phenyl-5-(trifluoromethyl)phenyl , [3-chloro-5-(trifluoromethyl)phenyl]methyl, 3-(4-fluorop enyl)-5-(trifluoromethyl)phenyl, 2-chlorophenyl, 2,5-dichloro rophenyl, 2,3,4-trichlorophenyl, 2,3-dichlorophenyl, 2,4-dichloro rophenyl, 2,6-difluorophenyl, 3-fluoro-5-(trifluoromethyl sulfonyl)phenyl, 3-chloro-5-(trifluoromethylsulfonyl)phenyl , 5-chloro-3-thienyl, 3,4,5-trichloro-2-thienyl, 2,5-dichloro ro-3-thienyl, 4,5-dichloro-2-thienyl, 1-methyl-5-(trifluoromethyl )-1H-pyrazol-3-yl, 4-chloro-1-methyl-3-(trifluoromethyl )-1H-pyrazol-5-yl, 5-methyl-1,2-oxazol-3-yl , 5-cyclopropyl-1,2-oxazol-3-yl, 3-chloro-1,2-oxa zol-5-yl, 2-chloro-1,3-thiazol-5-yl, 1-methyl-1H-py razol-4-yl, 5-chloro-1-methyl-1H-pyrazol-4-yl, 3-chloro ro-5-cyclopropylsulfonylphenyl, 3-chloro-5-(4-fluorophenyl )sulfonylphenyl, 3-chloro-5-ethylsulfonylphenyl, 3-cyclopropyl -5-fluorophenyl, 3-chloro-5-(isopropylthio)phenyl, 3-chloro ro-5-(1H-pyrazol-1-yl)phenyl, 3-chloro-5-(1H-1,2, (4 - Triazol - 1 - yl)phenyl, 3 - tert - butyl - 5 - chlorophenyl, 3 - tert - butyl - 5 - bromophenyl, 3 - fluoro - 5 - cyclopropylphenyl , 3 - chloro - 5 - cyclopropylphenyl, 3 - chloro - 5 - isopropylsulfonyl phenyl, 1 - (4 - fluorophenyl) - 3 - (trifluoromethyl) - 1H - pyra zol - 5 - yl, 3 - cyclopropyl - 5 - (trifluoromethoxy)phenyl, 4 - (trifluoromethylsulfonyl)phenyl, 3 - chloro - 5 - [1 - (methoxyimino )ethyl]phenyl, 3 - (tert - butylthio) - 5 - chlorophenyl, 1 - (4 - fluorophenyl) - 1H - pyrazol - 4 - yl, 1 - (4 - fluorophenyl) - 5 - (trifluoromethyl) - 1H - pyrazol - 3 - yl, 5 - [4 - (trifluorometh oxy)phenyl]pyridin - 3 - yl, 3 - chloro - 5 - methylsulfanyl phenyl , 3 - chloro - 5 - methylsulfinyl phenyl, 3 - benzamido - 5 - chlorophenyl , 3 - (tert - butylsulfonyl) - 5 - chlorophenyl, 5 - [4 - (triflu oromethyl)phenyl] - pyridin - 3 - yl, 5 - [4 - (trifluoromethoxy)f enyl] - pyridin - 3 - yl, 5 - (4 - chlorophenyl)pyridin - 3 - yl, 5 - (4 - fluorophenyl)pyridin - 3 - yl, 3 - chloro - 5 - [(phenylsulfonyl )amino]phenyl, 3 - acetamido - 5 - chlorophenyl, 3 - chloro - 5 - [(cyclopropylcarbonyl)amino]phenyl, 3 - chloro - 5 - [(2,2,2 - tri fluoroethyl)sulfinyl]phenyl, 3 - chloro - 5 - [(2,2,2 - triflu [[3-(ethylsulfonyl)phenyl]], 3-chloro-5-[3-(trifluoromethyl)- 1H-pyrazol-1-yl]phenyl, 3,5-bis(methylsulfonyl)phenyl, pyrazolo[1,5-a]pyridin-2-yl, 7-(trifluoromethyl)pyrazolo[1 ,5-a]pyridin-2-yl, 6-chloropyrazolo[1,5-a]pyridin-2-yl , naphthalen-2-yl, 3-[4'-(trifluoromethoxy)phenyl]-phenyl, 3 -(4'-fluorophenyl)-5-(trifluoromethyl)phenyl or 3-chloro- 5-(1-cyanocyclopropyl)phenyl; R 3a is hydrogen, methyl or methoxymethyl; R 3b is, when R 3a is hydrogen, methyl or methoxymethyl; R 3b is, when R 3a is methyl or methoxymethyl, hydrogen; R 3a and R 3b together with the carbon to which they are attached form a cyclopropane ring; R 4 is pyridin-2-yl, pyrimidin-2-yl, pyrimidin-4-yl, 5-f luoropyrimidin-2-yl, 5-chloropyrimidin-2-yl, 5-cyanopyrimidin -2-yl, 5-(trifluoromethyl)pyrimidin-2-yl, 5-methylpyrimidin -2-yl, 5-fluoropyridin-2-yl, 5-chloropyridin-2-yl, 2-c hloropyridin-4-yl, 5-cyanopyridin-2-yl, 4-cyano-pyridin-2- yl, 6-cyano-pyridin-2-yl, 5-methoxy-pyridin-2-yl, 5-(tr ifluoromethyl)-pyridin-2-yl, 5-(difluoromethoxy)pyridin-2- Il, 5-(trifluoromethylthio)pyridin-2-yl, 5-nitropyridin-2- Il, 5-aminopyridin-2-yl, 3,5-difluoropyridin-2-yl, 5-cl loro-3-fluoropyridin-2-yl, pyridin-2-yl-5-carboxylic acid, pyrid in-2-yl-5-methyl carboxylate, N-methyl-pyridin-2-yl-5-carbox amide, N-cyclopropyl-pyridin-2-yl-5-carboxamide, N-cyclop ropyl-N-methyl-pyridin-2-yl-5-carboxamide, N-(1-cyanocycl opropyl)-pyridin-2-yl-5-carboxamide, N-(2,2-difluoroeth yl)-pyridin-2-yl-5-carboxamide, N-(2,2,2-trifluoroeth yl)-pyridin-2-yl-5-carboxamide, N-methylsulfonyl-pyridin- 2-yl-5-carboxamide, N-(4-fluorophenyl)-pyridin-2-yl- 5-carboxamide, 5-acetamidopyridin-2-yl, 5-(trifluoroacet amide)-pyridin-2-yl, 5-(2-cyanoacetylamino)-pyridin-2-i l, 5-[(cyclopropylcarbonyl)amino]pyridin-2-yl, 5-[(1-cy anocyclopropylcarbonyl)amino]-pyridin-2-yl, 5-(methanesulfon amide)-pyridin-2-yl, 5-(trifluoromethylsulfonamide)-pyridin -2-yl, 5-[(4-fluorobenzoyl)amino]pyridin-2-yl pyrazine -2-yl, 2-cyano-pyrazin-5-yl or 1,3-thiazol-2-yl; ; R 5 is hydrogen, methyl or trifluoromethyl〕 is a compound represented by.
[0019] In a preferred further embodiment, the present invention relates to a compound of formula (I’)
Chemical formula
[0020] wherein, in the above formula, the structural elements Y, Q 1 , Q 2 , R 1 , R 2 , R 3a , R 3b , R 4 and R 5 have the meanings given in configuration (1-1) or configuration (2-1) or configuration (3-1) or configuration (4-1) or configuration (5-1).
[0021] In another preferred further embodiment, the present invention relates to a compound of formula (I’)
Chemical formula
[0022] wherein, in the above formula, the structural elements Y, Q 1 , Q 2 , R 1 , R 2 , R 3a , R 3b , R 4 and R 5 have the meanings given in configuration (1-2) or configuration (2-2) or configuration (3-2) or configuration (4-2) or configuration (5-2).
[0023] In a preferred further embodiment of the compound represented by formula (I’), Q 1 represents N or CR 5 and Q 2 represents N, and all further structural elements Y, R 1 , R 2 , R 3a , R 3b , R 4 and R 5 has the meaning described above in Configuration (1-1) or Configuration (2-1) or Configuration (3-1) or Configuration (4-1) or Configuration (5-1).
[0024] In a further preferred alternative embodiment of the compound represented by formula (I’), Q 1 is N or C R 5 represents, and Q 2 represents N, and all further structural elements Y, R 1 , R 2 , R 3a , R 3b , R 4 and R 5 has the meaning described above in Configuration (1-2) or Configuration (2-2) or Configuration (3- 2) or Configuration (4-2) or Configuration (5-2). .
[0025] In a further preferred alternative embodiment of the compound represented by formula (I’), Q 1 represents N , and Q 2 represents CR 5 represents, and all further structural elements Y, R 1 , R 2 , R 3 a , R 3b , R 4 and R 5 has the meaning described above in Configuration (1-1) or Configuration (2-1) or Configuration (3-1) or Configuration (4-1) or Configuration (5-1).
[0026] In a further preferred alternative embodiment of the compound represented by formula (I’), Q 1 represents N , and Q 2 represents CR 5and all further structural elements Y, R 1 , R 2 , R 3 a , R 3b , R 4 and R 5 is structure (1-2) or structure (2-2) or structure (3-2) or has the meaning described above in structure (4-2) or structure (5-2).
[0027] Among these, the following configurations are particularly preferred: [Table 1] TIFF2025094025000005.tif115133
[0028] In a further preferred embodiment, the present invention relates to a compound of formula (I″) [ka]
[0029] In the compound represented by the formula 3b is C1-C3 alkyl (particularly preferred The most important ones are Me) and R 3a is H, where the structuring elements Y, Q 1 , Q 2 , R 1 , R 2 , R 4 and R 5 is configuration (1-1) or configuration (2-1) or configuration (3-1) Or has the meaning given in structure (4-1) or structure (5-1).
[0030] In yet another preferred embodiment, the present invention relates to a compound of formula (I″): [ka]
[0031] relates to a compound represented by, wherein in the above formula, R 3b is C1-C3 alkyl (particularly preferably Me), and R 3a is H, wherein the structural elements Y, Q 1 , Q 2 , R 1 , R 2 , R 4 and R 5 have the meanings given in configuration (1-2) or configuration (2-2) or configuration (3-2) or configuration (4-2) or configuration (5-2).
[0032] In a further preferred embodiment, the present invention relates to a compound of formula (I''')
Chemical formula
[0033] relates to a compound represented by, wherein in the above formula, R 3b is C1-C3 alkyl (particularly preferably Me), and R 3a is H, wherein the structural elements Y, Q 1 , Q 2 , R 1 , R 2 , R 4 and R 5 have the meanings given in configuration (1-1) or configuration (2-1) or configuration (3-1) or configuration (4-1) or configuration (5-1).
[0034] In a further preferred alternative embodiment, the present invention relates to a compound of formula (I''')
Chemical formula
[0035] relates to a compound represented by, wherein in the above formula, R 3b is C1-C3 alkyl (particularly preferably What is significant is Me), and R 3a is H, where the structural elements Y, Q 1 Q 2 R 1 R 2 R 4 and R 5 have the meanings given in Configuration (1-2) or Configuration (2-2) or Configuration (3-2) or Configuration (4-2) or Configuration (5-2).
[0036] In a preferred further embodiment, the present invention relates to a compound represented by formula (I’p1)
Chemical formula
[0037] wherein, in the above formula, Y is a direct bond, and the structural element R 1 R 2 R 3a R 3b R 4 and R 5 have the meanings given in the following table as follows:
Table 2
[0038] In another preferred further embodiment, the present invention relates to a compound represented by formula (I’p1)
Chemical formula
[0039] wherein, in the above formula, Y is a direct bond, and the structural element R 1 R 2 R3a , R 3b , R 4 and R 5 have the meanings given in the following table as follows:
Table 3
[0040] TIFF2025094025000015.tif60167
[0041] According to a further aspect, the present invention includes intermediate compounds useful for preparing the compounds represented by the above general formula (I).
[0042] In particular, the present invention relates to a general formula (a * ):
Chemical formula
[0043] and includes intermediate compounds represented by, wherein in the above formula, the structural elements Y, R 1 , R 2 , R 3a and R 3b have the meanings given in configuration (1-1) or configuration (2-1) or configuration (3-1) or configuration (4-1 ) or configuration (5-1).
[0044] In particular, the present invention further includes intermediate compounds represented by the general formula (a * ):
Chemical formula
[0045] and also includes intermediate compounds represented by, wherein in the above formula, the structural elements Y, R 1 , R 2 , R 3a and R 3b has the meaning given in configuration (1-2) or configuration (2-2) or configuration (3-2) or configuration (4-2 ) or configuration (5-2).
[0046] In particular, the present invention relates to an intermediate compound represented by the general formula (b * ):
Chemical formula
[0047] and includes an intermediate compound represented by the formula: wherein in the above formula: E is hydrogen or C1-C6 alkyl; A is -CN, chlorine or fluorine; L is S, SO or SO2.
[0048] In particular, the present invention relates to an intermediate compound represented by the general formula (c * ):
Chemical formula
[0049] and includes an intermediate compound represented by the formula: wherein in the above formula: E is hydrogen or C1-C6 alkyl; A is bromine, chlorine, fluorine, -CN or trifluoromethyl, preferably chlorine .
[0050] In particular, the present invention relates to an intermediate compound represented by the general formula (d * ):
Chemical formula
[0051] and includes an intermediate compound represented by the formula: wherein in the above formula: E is hydrogen or C1-C6 alkyl; A is bromine, chlorine or fluorine, preferably chlorine; L is S, SO or SO2, preferably S or SO2, more preferably SO2; J is ethyl, iso-propyl, tert-butyl, cyclopropyl, 2,2,2-tri fluoroethyl or 4-fluorophenyl; and, here, the compound represented by formula (d * ) is not 3-(ethylsulfanyl)-5-fluoro benzoic acid, nor 3-(tert-butylsulfanyl)-5-fluorobenzoic acid .
[0052] The present invention further includes the compound 3-cyclopropyl-5-(trifluoromethoxy)benzoic acid and methyl 3-cyclopropyl-5-(trifluoromethoxy)benzoate.
[0053] Depending on the type of its substituents, the compound represented by formula (I) may exist in the form of stereoisomers, namely, geometric isomers and / or optical isomers or mixtures of isomers in various compositions. Even if generally only the compound represented by formula (I) is discussed herein, the present invention provides both pure stereoisomers and any desired mixtures of these isomers. That is, in the form of geometric isomers and / or optical isomers or mixtures of isomers in various compositions. However, according to the present invention, preferably, the optically active stereoisomers of the compound represented by formula (I) and their salts are used. Even if generally only the compound represented by formula (I) is discussed herein, the present invention provides both pure stereoisomers and any desired mixtures of these isomers. Accordingly, the present invention relates to both pure enantiomers and diastereomers and mixtures thereof for controlling pests (which include arthropods, particularly insects).
[0054] However, according to the present invention, preferably, the optically active stereoisomers of the compound represented by formula (I) and their salts are used. Stereoisomers and their salts are used.
[0055] Therefore, the present invention relates to both pure enantiomers and diastereomers and mixtures thereof for controlling pests (which include arthropods, particularly insects). It relates to both pure enantiomers and diastereomers and mixtures thereof for controlling pests (which include arthropods, particularly insects). Do.
[0056] When appropriate, the compound represented by formula (I) may exist in various polymorphic forms or may exist as a mixture of various polymorphic forms. Both pure polymorphs and polymorph mixtures are provided by the present invention and can be used in accordance with the present invention.
[0057] Definition Those skilled in the art know that when the expressions "a" or "an" are used in this application, even if not explicitly shown, depending on the situation, they may mean "1", "1 or more" or "at least 1 ".
[0058] For all structures described herein, such as ring systems and groups, adjacent atoms shall not be -O -O- or -O-S-.
[0059] Structures having possible carbon atoms (C atoms) of variables are, for the purpose of more specifically specifying in this application, C 炭素原子の下限 -C 炭素原子の上限 structures (C LL -C UL structures). For example, an alkyl group may be composed of 3 to 10 carbon atoms, in which case it corresponds to C3-C -alkyl. A ring structure composed of carbon atoms and heteroatoms may be described as an "LL~UL member" structure. One example of a 6-membered ring structure is toluene 10 (a 6-membered ring structure substituted with a methyl group). (a 6-membered ring structure substituted with a methyl group). (a 6-membered ring structure substituted with a methyl group).
[0060] Collective terms for substituents, for example, C LL -C UL -alkyl, when it is a complex substituent, for example, C LL -CUL -Cycloalkyl-C LL -C UL -When at the end of -alkyl, the first component of its complex substituent, e.g., C -C LL -C UL -Cycloalkyl may be the same or different and, independently, the latter substituent, e.g., C -C LL -C UL -Al kyl can be mono- or polysubstituted. All collective terms used in this application regarding chemical groups, ring systems, and cyclic groups can be specified more specifically by adding " -C LL -C UL " or "LL~UL members".
[0061] In the definitions of the symbols given in the above formula, the following collective terms are generally used to represent the substituents.
[0062] Halogens are elements of Group 7, preferably fluorine, chlorine, bromine, and iodine, more preferably fluorine, chlorine, and bromine, and even more preferably fluorine and chlorine.
[0063] Examples of heteroatoms are N, O, S, P, B, Si. Preferably, the term "heteroatom" relates to N, S, and O.
[0064] According to the present invention, "alkyl" alone or as part of a chemical group is preferably a straight-chain or branched hydrocarbon having 1 ~6 carbon atoms, e.g., methyl, ethyl, n- propyl, isopropyl, n-butyl, isobutyl, s-butyl, t-butyl, pentyl 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,2-dimethylpropyl 1,1-dimethylpropyl, 2,2-dimethylpropyl, 1-ethylpropyl, hexyl Ru, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl Ru, 1,2-dimethylpropyl, 1,3-dimethylbutyl, 1,4-dimethylbutyl, 2 ,3-dimethylbutyl, 1,1-dimethylbutyl, 2,2-dimethylbutyl, 3,3-di methylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1 -ethylbutyl and 2-ethylbutyl. Alkyl having 1 to 4 carbon atoms, for example especially, methyl, ethyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, s-butyl or t-butyl etc. are also preferable. The alkyl according to the present invention can be substituted with radicals which are the same or different and have 1 or more.
[0065] According to the present invention, "alkenyl", alone or as part of a chemical group, preferably is a straight-chain or branched hydrocarbon having 2 to 6 carbon atoms and at least one double bond , for example, vinyl, 2-propenyl, 2-butenyl, 3-butenyl, 1-methyl-2-pro penyl, 2-methyl-2-propenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl nil, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl nil, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl , 1,1-dimethyl-2-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl -2-propenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl , 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl nil, 4-methyl-2-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pen Ntenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4 -pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1 -dimethyl-3-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3- butenyl, 1,3-dimethyl-2-butenyl, 2,2-dimethyl-3-butenyl, 2,3 -dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 1-ethyl-2-buteny l, 1-ethyl-3-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl , 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl and 1-ethyl-2-methyl-2-propenyl. Alkenyl having 2 to 4 carbon atoms, for example, especially 2-propenyl, 2-butenyl or 1-methyl-2-propen yl, etc. are also preferred. The alkenyl according to the present invention can be substituted with one or more identical or different radicals.
[0066] According to the present invention, "alkynyl", alone or as part of a chemical group, preferably has 2 to 6 carbon atoms and at least one triple bond, a straight-chain or branched hydrocarbon, for example, 2-propynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl , 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-3-butynyl, 2- methyl-3-butynyl, 1-methyl-2-butynyl, 1,1-dimethyl-2-propynyl , 1-ethyl-2-propynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5 -hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl Chlor-4-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-3-butynyl , 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 1-ethyl-3 -butynyl, 2-ethyl-3-butynyl, 1-ethyl-1-methyl-2-propynyl and 2,5-hexadiynyl. Alkynyl having 2 to 4 carbon atoms, for example, optionally , ethynyl, 2-propynyl or 2-butynyl-2-propenyl, etc. are also preferred. The alkynyl according to the present invention may be substituted with one or more identical or different radicals .
[0067] According to the present invention, "cycloalkyl" is preferably a monocyclic, bicyclic or tricyclic hydrocarbon having 3 to 10 carbons, alone or as part of a chemical group, for example, cyclo propyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl, cycloo ctyl, bicyclo[2.2.1]heptyl, bicyclo[2.2.2]octyl or adam antyl. Cycloalkyl having 3, 4, 5, 6 or 7 carbon atoms, for example , especially, cyclopropyl or cyclobutyl, etc. are also preferred. The cycloalkyl according to the present invention may be substituted with one or more identical or different radicals.
[0068] According to the present invention, "alkylcycloalkyl" is preferably a monocyclic, bicyclic or tricyclic alkylcycloalkyl having 4 to 10 or 4 to 7 carbon atoms, for example, methyl cyclopropyl, ethylcyclopropyl, isopropylcyclobutyl, 3-methylcy clopentyl and 4-methylcyclohexyl. Having 4, 5 or 7 carbon atoms The alkylcycloalkyl to be used, for example, especially ethylcyclopropyl or 4-methyl such as cyclohexyl and the like are also preferred. The alkylcycloalkyl according to the present invention may be substituted with one or more identical or different radicals.
[0069] According to the present invention, "cycloalkylalkyl" preferably has 4 to 10 or 4 to 7 carbon atoms, and is a monocyclic, bicyclic or tricyclic cycloalkylalkyl, for example, cy clopropylmethyl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl and cyclopentylethyl. Cycloalkylalkyl having 4, 5 or 7 carbon atoms, for example, especially cyclopropylmethyl or cyclobutylmethyl and the like are also preferred. The cycloalkylalkyl according to the present invention may be substituted with one or more identical or different radicals.
[0070] According to the present invention, "hydroxyalkyl" preferably has 1 to 6 carbon atoms and is a straight-chain or branched-chain alcohol, for example, methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, s-butanol and t-butanol represent. A hydroxyalkyl group having 1 to 4 carbon atoms is also preferred. The hydroxyalkyl group according to the present invention may be substituted with one or more identical or different radicals.
[0071] According to the present invention, "alkoxy" preferably has 1 to 6 carbon atoms and is a straight-chain or branched-chain O-alkyl, for example, methoxy, ethoxy, n-propoxy, isopropoxy n-butoxy, isobutoxy, s-butoxy and t-butoxy. 1 to 4 carbon An alkoxy group having a sulfur atom is also preferable. The alkoxy group according to the present invention can be substituted with one or more identical or different radicals.
[0072] According to the present invention, "alkylthio" or "alkylsulfanyl" preferably represents a linear or branched S-alkyl having 1 to 6 carbon atoms, such as methylthio, ethylthio, n-propylthio, isopropylthio, n-butylthio, isobutylthio, s-butylthio, and t-butylthio. An alkylthio group having 1 to 4 carbon atoms is also preferable. The alkylthio group according to the present invention can be substituted with one or more identical or different radicals.
[0073] According to the present invention, "alkylsulfinyl" preferably represents a linear or branched alkylsulfinyl having 1 to 6 carbon atoms, such as methylsulfinyl, ethylsulfinyl, n-propylsulfinyl, isopropylsulfinyl, n-butylsulfinyl, isobutylsulfinyl, s-butylsulfinyl, and t-butylsulfinyl. An alkylsulfinyl group having 1 to 4 carbon atoms is also preferable. The alkylsulfinyl group according to the present invention can be substituted with one or more identical or different radicals and includes both enantiomers.
[0074] According to the present invention, "alkylsulfonyl" preferably represents a linear or branched alkylsulfonyl having 1 to 6 carbon atoms, such as methylsulfonyl, ethylsulfonyl, n-propylsulfonyl, isopropylsulfonyl, n-butylsulfonyl, isobutylsulfonyl, Represents sulfonyl, s-butylsulfonyl and t-butylsulfonyl. An alkylsulfonyl group having 1 to 4 carbon atoms is also preferred. The alkylsulfonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "cycloalkylthio" or "cycloalkylsulfanyl" preferably represents -S-cycloalkyl having 3 to 6 carbon atoms, for example, cyclopropylthio, cyclobutylthio, cyclopentylthio, cyclohexylthio. A cycloalkylthio group having 3 to 5 carbon atoms is also preferred. The cycloalkylthio group according to the present invention may be substituted with one or more identical or different radicals.
[0075] According to the present invention, "cycloalkylsulfinyl" preferably represents -S(O)-cycloalkyl having 3 to 6 carbon atoms, for example, cyclopropylsulfinyl, cyclobutylsulfinyl, cyclopentylsulfinyl, cyclohexylsulfinyl. A cycloalkylsulfinyl group having 3 to 5 carbon atoms is also preferred. The cycloalkylsulfinyl group according to the present invention can be substituted with one or more identical or different radicals and includes both enantiomers. According to the present invention, "cycloalkylsulfonyl" preferably represents -SO2-cycloalkyl having 3 to 6 carbon atoms, for example, cyclopropylsulfonyl, cyclobutylsulfonyl, cyclopentylsulfonyl, cyclohexylsulfonyl. A cycloalkylsulfonyl group having 3 to 5 carbon atoms is also preferred. The cycloalkylsulfonyl group according to the present invention can be substituted with one or more identical or different radicals.
[0076] According to the present invention, "cycloalkylsulfinyl" preferably represents -S(O)-cycloalkyl having 3 to 6 carbon atoms, for example, cyclopropylsulfinyl, cyclobutylsulfinyl, cyclopentylsulfinyl, cyclohexylsulfinyl. A cycloalkylsulfinyl group having 3 to 5 carbon atoms is also preferred. The cycloalkylsulfinyl group according to the present invention can be substituted with one or more identical or different radicals and includes both enantiomers. According to the present invention, "cycloalkylsulfonyl" preferably represents -SO2-cycloalkyl having 3 to 6 carbon atoms, for example, cyclopropylsulfonyl, cyclobutylsulfonyl, cyclopentylsulfonyl, cyclohexylsulfonyl. A cycloalkylsulfonyl group having 3 to 5 carbon atoms is also preferred. The cycloalkylsulfonyl group according to the present invention can be substituted with one or more identical or different radicals and includes both enantiomers.
[0077] According to the present invention, "cycloalkylsulfonyl" preferably represents -SO2-cycloalkyl having 3 to 6 carbon atoms, for example, cyclopropylsulfonyl, cyclobutylsulfonyl, cyclopentylsulfonyl, cyclohexylsulfonyl. A cycloalkylsulfonyl group having 3 to 5 carbon atoms is also preferred. The cycloalkylsulfonyl group according to the present invention can be substituted with one or more identical or different radicals. A cycloalkylsulfonyl group having 3 to 5 carbon atoms is also preferred. The cycloalkyl according to the present invention The sulfonyl group may be substituted with one or more identical or different radicals.
[0078] According to the present invention, "phenylthio" or "phenylsulfanyl" represents -S-phenyl , for example, phenylthio. The phenylthio group according to the present invention may be substituted with one or more identical or different radicals.
[0079] According to the present invention, "phenylsulfinyl" represents -S(O)-phenyl, for example, phe nylsulfinyl. The phenylsulfinyl group according to the present invention can be substituted with one or more identical or different radicals, and includes both enantiomers.
[0080] According to the present invention, "phenylsulfonyl" represents -SO2-phenyl, for example, phenyl sulfonyl. The phenylsulfonyl group according to the present invention may be substituted with one or more identical or different radicals.
[0081] According to the present invention, "alkylcarbonyl" represents methylcarbonyl, ethylcarbonyl, n-propylcarbonyl, isopropylcarbonyl, s-butylcarbonyl and t-butyl lucarbonyl, etc., preferably a linear or branched alkyl having 2 to 7 carbon atoms -C(=O). Alkylcarbonyl having 1 to 4 carbon atoms is also preferred. The alkylcarbonyl according to the present invention may be substituted with one or more identical or different radicals.
[0082] According to the present invention, "alkoxycarbonyl", alone or as a constituent of a chemical group, is The alkoxy moiety preferably has 1 to 6 carbon atoms or has 1 to 4 carbon atoms and is a linear or branched alkoxycarbonyl, for example, methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl, and t-butoxycarbonyl. The alkoxycarbonyl group according to the present invention may be substituted with one or more identical or different radicals. The alkoxy moiety preferably has 1 to 6 carbon atoms or has 1 to 4 carbon atoms and is a linear or branched alkoxycarbonyl, for example, methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl, and t-butoxycarbonyl. The alkoxycarbonyl group according to the present invention may be substituted with one or more identical or different radicals. The alkoxy moiety preferably has 1 to 6 carbon atoms or has 1 to 4 carbon atoms and is a linear or branched alkoxycarbonyl, for example, methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl, and t-butoxycarbonyl. The alkoxycarbonyl group according to the present invention may be substituted with one or more identical or different radicals. The alkoxy moiety preferably has 1 to 6 carbon atoms or has 1 to 4 carbon atoms and is a linear or branched alkoxycarbonyl, for example, methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl, and t-butoxycarbonyl. The alkoxycarbonyl group according to the present invention may be substituted with one or more identical or different radicals. The alkoxy moiety preferably has 1 to 6 carbon atoms or has 1 to 4 carbon atoms and is a linear or branched alkoxycarbonyl, for example, methoxycarbonyl, ethoxycarbonyl, n-propoxycarbonyl, isopropoxycarbonyl, s-butoxycarbonyl, and t-butoxycarbonyl. The alkoxycarbonyl group according to the present invention may be substituted with one or more identical or different radicals.
[0083] According to the present invention, "alkylaminocarbonyl" is a linear or branched alkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, methylaminocarbonyl, ethylaminocarbonyl, n-propylaminocarbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl, and t-butylaminocarbonyl. The alkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "alkylaminocarbonyl" is a linear or branched alkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, methylaminocarbonyl, ethylaminocarbonyl, n-propylaminocarbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl, and t-butylaminocarbonyl. The alkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "alkylaminocarbonyl" is a linear or branched alkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, methylaminocarbonyl, ethylaminocarbonyl, n-propylaminocarbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl, and t-butylaminocarbonyl. The alkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "alkylaminocarbonyl" is a linear or branched alkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, methylaminocarbonyl, ethylaminocarbonyl, n-propylaminocarbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl, and t-butylaminocarbonyl. The alkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "alkylaminocarbonyl" is a linear or branched alkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, methylaminocarbonyl, ethylaminocarbonyl, n-propylaminocarbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl, and t-butylaminocarbonyl. The alkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "alkylaminocarbonyl" is a linear or branched alkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, methylaminocarbonyl, ethylaminocarbonyl, n-propylaminocarbonyl, isopropylaminocarbonyl, s-butylaminocarbonyl, and t-butylaminocarbonyl. The alkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals.
[0084] According to the present invention, "N,N-dialkylaminocarbonyl" is a linear or branched N,N-dialkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, N,N-dimethylaminocarbonyl, N,N-diethylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(isopropylamino)carbonyl, and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "N,N-dialkylaminocarbonyl" is a linear or branched N,N-dialkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, N,N-dimethylaminocarbonyl, N,N-diethylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(isopropylamino)carbonyl, and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "N,N-dialkylaminocarbonyl" is a linear or branched N,N-dialkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, N,N-dimethylaminocarbonyl, N,N-diethylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(isopropylamino)carbonyl, and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "N,N-dialkylaminocarbonyl" is a linear or branched N,N-dialkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, N,N-dimethylaminocarbonyl, N,N-diethylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(isopropylamino)carbonyl, and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "N,N-dialkylaminocarbonyl" is a linear or branched N,N-dialkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, N,N-dimethylaminocarbonyl, N,N-diethylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(isopropylamino)carbonyl, and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "N,N-dialkylaminocarbonyl" is a linear or branched N,N-dialkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, N,N-dimethylaminocarbonyl, N,N-diethylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(isopropylamino)carbonyl, and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals. According to the present invention, "N,N-dialkylaminocarbonyl" is a linear or branched N,N-dialkylaminocarbonyl having preferably 1 to 6 carbon atoms or 1 to 4 carbon atoms in the alkyl moiety, for example, N,N-dimethylaminocarbonyl, N,N-diethylaminocarbonyl, N,N-di(n-propylamino)carbonyl, N,N-di(isopropylamino)carbonyl, and N,N-di-(s-butylamino)carbonyl. The N,N-dialkylaminocarbonyl group according to the present invention may be substituted with one or more identical or different radicals.
[0085] According to the present invention, "aryl" preferably has 6 to 14, particularly 6 to 10 ring carbon atoms, and represents a monocyclic, bicyclic or polycyclic aromatic system, such as phenyl, naphthyl, anthryl, phenanthrenyl, and preferably represents phenyl. Further, aryl also represents a polycyclic system in which the bonding site is on the aromatic system, such as tetrahydronaphthyl, indenyl, indanyl, fluorenyl, biphenyl, etc. The aryl group according to the present invention may be substituted with one or more identical or different radicals. Examples of substituted aryls are arylalkyls, which may be similarly substituted with one or more identical or different radicals in the C1-C4-alkyl moiety and / or the C6-C aryl moiety. Examples of such arylalkyls include benzyl and phenyl-1-ethyl. According to the present invention, "heterocycle", "heterocyclic ring" or "heterocyclic ring system" represents a carbocyclic ring system having at least one ring (where the ring may or may not be substituted and the bonding site is on the ring atom) in which at least one carbon atom is replaced by a heteroatom (preferably a heteroatom selected from the group consisting of N, O, S, P, B, Si, Se) and is saturated, unsaturated or heteroaromatic. Unless otherwise defined, the heterocyclic ring preferably has 3 to 9 ring atoms (particularly 3 to 6 ring atoms) and one or more (preferably 1 to 4, particularly 1, 2 or 3) heteroatoms (preferably heteroatoms selected from the group consisting of N, O and S) in the heterocyclic ring.
[0086] 14
[0087] It contains (an atom), but the two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains no more than 4 nitrogen atoms and / or no more than 2 oxygen atoms and / or no more than 2 sulfur atoms. When the heterosilyl radical or the heterocyclic ring may be substituted, the heterosilyl radical or the heterocyclic ring may be fused to another carbocyclic ring or heterocyclic ring. In the case of a heterosilyl that may be substituted, the present invention includes polycyclic systems, for example, 8-azabicyclo[3.2.1]octanyl or 1-azabicyclo[2.2.1]heptyl, etc. In the case of a heterosilyl that may be substituted, the present invention also includes spirocyclic systems, for example, 1-oxa-5-azaspiro[2.3]hexyl, etc. The heterosilyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxepanyl, etc. Particularly important is heteroaryl, that is, a heteroaromatic system. According to the present invention, the term "heteroaryl" refers to a heteroaromatic compound, that is, included in the above definition of a heterocyclic ring. Although it contains (an atom), the two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains no more than 4 nitrogen atoms and / or no more than 2 oxygen atoms and / or no more than 2 sulfur atoms. When the heterosilyl radical or the heterocyclic ring may be substituted, the heterosilyl radical or the heterocyclic ring may be fused to another carbocyclic ring or heterocyclic ring. In the case of a heterosilyl that may be substituted, the present invention includes polycyclic systems, for example, 8-azabicyclo[3.2.1]octanyl or 1-azabicyclo[2.2.1]heptyl, etc. In the case of a heterosilyl that may be substituted, the present invention also includes spirocyclic systems, for example, 1-oxa-5-azaspiro[2.3]hexyl, etc. The heterosilyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxepanyl, etc. Particularly important is heteroaryl, that is, a heteroaromatic system. According to the present invention, the term "heteroaryl" refers to a heteroaromatic compound, that is, included in the above definition of a heterocyclic ring. Although it contains (an atom), the two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains no more than 4 nitrogen atoms and / or no more than 2 oxygen atoms and / or no more than 2 sulfur atoms. When the heterosilyl radical or the heterocyclic ring may be substituted, the heterosilyl radical or the heterocyclic ring may be fused to another carbocyclic ring or heterocyclic ring. In the case of a heterosilyl that may be substituted, the present invention includes polycyclic systems, for example, 8-azabicyclo[3.2.1]octanyl or 1-azabicyclo[2.2.1]heptyl, etc. In the case of a heterosilyl that may be substituted, the present invention also includes spirocyclic systems, for example, 1-oxa-5-azaspiro[2.3]hexyl, etc. The heterosilyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxepanyl, etc.
[0088] Although it contains (an atom), the two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains no more than 4 nitrogen atoms and / or no more than 2 oxygen atoms and / or no more than 2 sulfur atoms. When the heterosilyl radical or the heterocyclic ring may be substituted, the heterosilyl radical or the heterocyclic ring may be fused to another carbocyclic ring or heterocyclic ring. In the case of a heterosilyl that may be substituted, the present invention includes polycyclic systems, for example, 8-azabicyclo[3.2.1]octanyl or 1-azabicyclo[2.2.1]heptyl, etc. In the case of a heterosilyl that may be substituted, the present invention also includes spirocyclic systems, for example, 1-oxa-5-azaspiro[2.3]hexyl, etc. The heterosilyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxepanyl, etc. Particularly important is heteroaryl, that is, a heteroaromatic system. According to the present invention, the term "heteroaryl" refers to a heteroaromatic compound, that is, included in the above definition of a heterocyclic ring. Although it contains (an atom), the two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains no more than 4 nitrogen atoms and / or no more than 2 oxygen atoms and / or no more than 2 sulfur atoms. When the heterosilyl radical or the heterocyclic ring may be substituted, the heterosilyl radical or the heterocyclic ring may be fused to another carbocyclic ring or heterocyclic ring. In the case of a heterosilyl that may be substituted, the present invention includes polycyclic systems, for example, 8-azabicyclo[3.2.1]octanyl or 1-azabicyclo[2.2.1]heptyl, etc. In the case of a heterosilyl that may be substituted, the present invention also includes spirocyclic systems, for example, 1-oxa-5-azaspiro[2.3]hexyl, etc. The heterosilyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxepanyl, etc. Particularly important is heteroaryl, that is, a heteroaromatic system. According to the present invention, the term "heteroaryl" refers to a heteroaromatic compound, that is, included in the above definition of a heterocyclic ring. Although it contains (an atom), the two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains no more than 4 nitrogen atoms and / or no more than 2 oxygen atoms and / or no more than 2 sulfur atoms. When the heterosilyl radical or the heterocyclic ring may be substituted, the heterosilyl radical or the heterocyclic ring may be fused to another carbocyclic ring or heterocyclic ring. In the case of a heterosilyl that may be substituted, the present invention includes polycyclic systems, for example, 8-azabicyclo[3.2.1]octanyl or 1-azabicyclo[2.2.1]heptyl, etc. In the case of a heterosilyl that may be substituted, the present invention also includes spirocyclic systems, for example, 1-oxa-5-azaspiro[2.3]hexyl, etc. The heterosilyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxepanyl, etc.
[0089] Although it contains (an atom), the two oxygen atoms must not be directly adjacent. The heterocyclic ring usually contains no more than 4 nitrogen atoms and / or no more than 2 oxygen atoms and / or no more than 2 sulfur atoms. When the heterosilyl radical or the heterocyclic ring may be substituted, the heterosilyl radical or the heterocyclic ring may be fused to another carbocyclic ring or heterocyclic ring. In the case of a heterosilyl that may be substituted, the present invention includes polycyclic systems, for example, 8-azabicyclo[3.2.1]octanyl or 1-azabicyclo[2.2.1]heptyl, etc. In the case of a heterosilyl that may be substituted, the present invention also includes spirocyclic systems, for example, 1-oxa-5-azaspiro[2.3]hexyl, etc. The heterosilyl group according to the present invention is, for example, piperidinyl, piperazinyl, morpholinyl, thiomorpholinyl, dihydropyranyl, tetrahydropyranyl, dioxanyl, pyrrolyl, pyrrolidinyl, imidazolinyl, imidazolidinyl, thiazolidinyl, oxazolidinyl, dioxolanyl, dioxolyl, pyrazolidinyl, tetrahydrofuranyl, dihydrofuranyl, oxetanyl, oxiranyl, azetidinyl, aziridinyl, oxazetidinyl, oxaziridinyl, oxazepanyl, oxazinanyl, azepanyl, oxopyrrolidinyl, dioxopyrrolidinyl, oxomorpholinyl, oxopiperazinyl and oxepanyl, etc. Represents a completely unsaturated aromatic heterocyclic compound. Preferably, 1 ~3 (preferably 1 or 2) identical or different heteroatoms are present in a 5- to 7-membered ring. The heteroaryl according to the present invention is, for example, furyl, thienyl, pyrazolyl, imidazolyl, 1,2,3-triazolyl and 1,2,4-triazolyl, isoxazolyl, thiazolyl, isothiazolyl, 1,2,3-oxadiazolyl, 1,3 ,4-oxadiazolyl, 1,2,4-oxadiazolyl and 1,2,5-oxadiazol yl, azepinyl, pyrrolyl, pyridyl, pyridazinyl, pyrimidinyl, pyrazinyl, 1 ,3,5-triazinyl, 1,2,4-triazinyl and 1,2,3-triazinyl, 1 ,2,4-oxazinyl, 1,3,2-oxazinyl, 1,3,6-oxazinyl and 1 ,2,6-oxazinyl, oxepinyl, thiepinyl, 1,2,4-triazolonyl, and also 1,2,4-diazepinyl. The heteroaryl group according to the present invention may be substituted with one or more identical or different radicals.
[0090] The term "optionally substituted in any case" means that a group / substituent, for example, alkyl, alkenyl, alkynyl, alkoxy, alkylthio, alkylsulfinyl, alkyl sulfonyl, cycloalkyl, aryl, phenyl, benzyl, heterocyclyl and hetero aryl radicals, etc. are substituted, which means, for example, a substituted radical derived from an unsubstituted basic structure, where the substituent (for example, one substituent, or a plurality of substituents, preferably 1, 2, 3, 4, 5, 6 or 7 substituents ) is, for example, amino, hydroxyl, halogen, nitro, cyano, isocyano, mercapto, isothiocyanato, C1-C4-carboxyl, carboxamide, SF5, amino sulfonyl, C1-C4-alkyl, C1-C4-haloalkyl, C3-C4-cycloalkyl, C2-C4-alkenyl, C5-C6-cycloalkenyl, C2-C4-alkynyl, N-mono-C1-C4-alkylamino, N,N-di-C1-C4-alkylamino, N-C1-C4-alkanoylamino, C1-C4-alkoxy, C1-C4-haloalkoxy, C2-C4-alkenyloxy, C2-C4-alkynyloxy, C3-C4-cycloalkoxy, C5-C6-cycloalkenyloxy, C1-C4-alkoxycarbonyl, C2-C4-alkenyloxycarbonyl, C2-C4-alkynyloxycarbonyl, C6-aryloxycarbonyl, C 10 -aryloxycarbonyl, C 14 -aryloxycarbonyl, C1-C4-alkanoyl, C2-C4-alkenyl carbonyl, C2-C4-alkynylcarbonyl, C6-arylcarbonyl, C 10 - arylcarbonyl, C 14 -arylcarbonyl, C1-C4-alkylthio, C1- C4-haloalkylthio, C3-C4-cycloalkylthio, C2-C4-alkenylthio, C5-C6-cycloalkenylthio, C2-C4-alkynylthio, C1-C4-alkylsulfinyl (wherein both enantiomers of the C1-C4-alkylsulfinyl group are included), C1-C4-haloalkylsulfinyl (wherein both enantiomers of the C1-C4-haloalkylsulfinyl group are included), C1-C4-alkyl sulfinyl (wherein both enantiomers of the C1-C4-alkylsulfinyl group are included), C1-C4-haloalkylsulfinyl (wherein both enantiomers of the C1-C4-haloalkylsulfinyl group are included), C1-C4-alkyl sulfinyl (wherein both enantiomers of the C1-C4-alkylsulfinyl group are included), C1-C4-haloalkylsulfinyl (wherein both enantiomers of the C1-C4-haloalkylsulfinyl group are included), C1-C4-alkyl Rusulfonyl, C1-C4-haloalkylsulfonyl, N-mono-C1-C4-alkyl aminosulfonyl, N,N-di-C1-C4-alkylaminosulfonyl, C1-C4- alkylphosphinyl, C1-C4-alkylphosphonyl (wherein both enantiomers of C1-C4-alkyl phosphinyl and C1-C4-alkylphosphonyl are included), N-C1-C4-alkylaminocarbonyl, N,N-di-C1-C4- alkylaminocarbonyl, N-C1-C4-alkanoylaminocarbonyl, N-C1-C4- alkanoyl-N-C1-C4-alkylaminocarbonyl, C6-aryl, C - 10 - -aryl, C 14 -aryloxy, C6-aryloxy, C 10 -aryloxy, C 14 -aryloxy, benzyl, benzyloxy, benzylthio, C6-arylthio, C 10 -arylthio, C 14 -arylthio, C6-arylamino, C 10 -arylamino, benzylamino, heterocyclyl and trialkylsilyl, substituents bonded via a double bond (e.g., C1-C4-alkylidene (e.g., methylene or ethylidene), oxo group, imino group and substituted imino group) selected from the group consisting of 14 -arylamino, benzylamino, heterocyclyl and trialkylsilyl, substituents bonded via a double bond (e.g., C1-C4-alkylidene (e.g., methylene or ethylidene), oxo group, imino group and substituted imino group) selected from the group consisting of methylene or ethylidene), oxo group, imino group and substituted imino group) are selected from the group consisting of oxo group, imino group and substituted imino group) are selected from the group consisting of , carbocyclic, heterocyclic, saturated, partially saturated, unsaturated (including, for example, aromatic rings) and may be further substituted. The substituents (the "first substituent level") listed above as examples, when they contain a hydrocarbonaceous component, they which may further have one or more of substituents (the "second substituent level") within it, for example, halogen, hydroxyl, amino, nitro, cyano, isocyano, azide, acylamino, oxo group and imino group, or each independently selected from one or more of the substituents. The term "substituted (which may be substituted)" group preferably includes only one or two substituent levels.
[0091] A chemical group substituted with halogen or a halogenated group (e.g., alkyl or alkoxy) according to the present invention is mono-substituted with halogen or polysubstituted with halogen up to the maximum possible number of substituents. Such a group is also referred to as a halo group (e.g., haloalkyl). When polysubstituted with halogen, the halogen atoms may be the same or different, and all may be bonded to one carbon atom or may be bonded to a plurality of carbon atoms. Halogen is particularly fluorine, chlorine, bromine or iodine, preferably fluorine, chlorine or bromine, and more preferably fluorine. More specifically, a group substituted with halogen is a monohalocycloalkyl, for example, 1-fluorocyclo propyl, 2-fluorocyclopropyl or 1-fluorocyclobutyl, monohaloalkyl, for example, 2-chloroethyl, 2-fluoroethyl, 1-chloroethyl, 1-fluoro ethyl, chloromethyl or fluoromethyl, perhaloalkyl, for example, trichlorometh yl or trifluoromethyl or CF2CF3, polyhaloalkyl, for example, difluoro methyl, 2-fluoro-2-chloroethyl, dichloromethyl, 1,1,2,2-tetrafluoro ethyl or 2,2,2-trifluoroethyl. Further examples of haloalkyl are , trichloromethyl, chlorodifluoromethyl, dichlorofluoromethyl, chloromethyl , bromomethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl , 2,2,2-trifluoroethyl, 2,2,2-trichloroethyl, 2-chloro-2, 2-difluoroethyl, pentafluoroethyl, 3,3,3-trifluoropropyl and pentafluoro-t-butyl. Preferably, it is a haloalkyl having 1 to 4 carbon atoms and 1 to 9 (preferably 1 to 5) identical or different halogen atoms selected from fluorine, chlorine and bromine. Particularly preferred is a haloalkyl having 1 or 2 carbon atoms and 1 to 5 identical or different halogen atoms selected from fluorine and chlorine (for example, especially, difluoromethyl, trifluoromethyl or 2,2-difluoroethyl). Further examples of the compound substituted with halogen are haloalkoxy, for example, OCF3, OCHF2, OCH2F, OCF2CF3, O CH2CF3, OCH2CHF2 and OCH2CH2Cl, haloalkylsulfanyl, for example, difluoromethylthio, trifluoromethylthio, trichloromethylthio, chloro difluoromethylthio, 1-fluoroethylthio, 2-fluoroethylthio, 2,2- difluoroethylthio, 1,1,2,2-tetrafluoroethylthio, 2,2,2-tri fluoroethylthio or 2-chloro-1,1,2-trifluoroethylthio, haloalkyl sulfinyl, for example, difluoromethylsulfinyl, trifluoromethylsulfinyl , trichloromethylsulfinyl, chlorodifluoromethylsulfinyl, 1-fluoro ethylsulfinyl, 2-fluoroethylsulfinyl, 2,2-difluoroethylsulfinyl and 2-chloro-1,1,2-trifluoroethylsulfinyl Sulfinyl, 1,1,2,2 - tetrafluoroethylsulfinyl, 2,2,2 - tri fluoroethylsulfinyl and 2 - chloro - 1,1,2 - trifluoroethylsulfi nyl, haloalkylsulfinyl, for example, difluoromethylsulfinyl, trifluo romethylsulfinyl, trichloromethylsulfinyl, chlorodifluoromethylsulf inyl, 1 - fluoroethylsulfinyl, 2 - fluoroethylsulfinyl, 2,2 - difluoroethylsulfinyl, 1,1,2,2 - tetrafluoroethylsulfinyl, 2,2,2 - trifluoroethylsulfinyl and 2 - chloro - 1,1,2 - trifluo roethylsulfinyl, haloalkylsulfonyl group, for example, difluoromethylsulfoni lum, trifluoromethylsulfonyl, trichloromethylsulfonyl, chlorodifluorometh ylsulfonyl, 1 - fluoroethylsulfonyl, 2 - fluoroethylsulfonyl, 2, 2 - difluoroethylsulfonyl, 1,1,2,2 - tetrafluoroethylsulfonyl, 2,2,2 - trifluoroethylsulfonyl and 2 - chloro - 1,1,2 - trifluoro ethylsulfonyl.
[0092] In the case of a radical having a carbon atom, preferably those having 1 to 4 carbon atoms (especially 1 or preferably 2 carbon atoms). Generally, halogen (for example, fluorine and chlorine) , (C1 - C4) alkyl (preferably methyl or ethyl), (C1 - C4) haloalk yl (preferably trifluoromethyl), (C1 - C4) alkoxy (preferably meth oxy or ethoxy), (C1 - C4) haloalkoxy, nitro and cyano are selected from the group The substituents to be used are preferred. Here, particularly preferred are the substituents methyl, methoxy, and fluorine. and chlorine.
[0093] The substituted amino (e.g., mono-substituted amino or di-substituted amino) means a radical selected from the group consisting of, for example, alkyl, hydroxy, amino, alkoxy, acyl, and aryl, and is N-substituted with one or two identical or different radicals selected from the group of substituted amino radicals; preferably, N-monoalkylamino and N,N- dialkylamino (e.g., methylamino, ethylamino, N,N-dimethylamino, N,N-diethylamino, N,N-di-n-propylamino, N,N-diisopropylamino or N,N-dibutylamino), N-monoalkoxyalkylamino or N,N-di alkoxyalkylamino groups (e.g., N-methoxymethylamino, N-methoxyethyl amino, N,N-di(methoxymethyl)amino or N,N-di(methoxyethyl)amino ), N-monoarylamino and N,N-diarylamino, for example, aniline which may be substituted, acylamino, N,N-diacylamino, N-alkyl-N-arylamino, N-alkyl-N-acylamino, and further means a saturated N-heterocycle; here, preferably, an alkyl radical having 1 to 4 carbon atoms; here, aryl is preferably phenyl or substituted phenyl; for acyl, the definitions given further below apply, and preferably, (C1-C4)-alkanoyl yl. The same applies to the substituted hydroxylamino or hydrazino.
[0094] The replaced amino acid further includes a quaternary ammonium compound (salt) having four organic substituents on the nitrogen atom. It also includes.
[0095] Optionally substituted phenyl is preferably unsubstituted phenyl or or one or more substituents (preferably up to 3 substituents) selected from the group consisting of halogen, (C1-C4)-alkyl, (C1-C4)-alkoxy, (C1-C 4)-alkoxy-(C1-C4)-alkoxy, (C1-C4)-alkoxy-(C1 -C4)-alkyl, (C1-C4)-haloalkyl, (C1-C4)-haloalkoxy , (C1-C4)-alkylthio, (C1-C4)-haloalkylthio, (C1-C4) -alkylsulfinyl, (C1-C4)-haloalkylsulfinyl, (C1-C4) -alkylsulfonyl, (C1-C4)-haloalkylsulfonyl, cyano, isocyano and nitro, which are the same or different, such as o-tolyl, m-tolyl and p-tolyl, dimethylphenyl, 2-chlorophenyl, 3-chlorophenyl and 4-chlorophenyl, 2-fluorophenyl, 3-fluorophenyl and 4- fluorophenyl, 2-trifluoromethylphenyl, 3-trifluoromethylphenyl and 4-trifluoromethylphenyl, and 4-trichloromethylphenyl, 2,4- dichlorophenyl, 3,5-dichlorophenyl, 2,5-dichlorophenyl and 2,3- dichlorophenyl, o-methoxyphenyl, m-methoxyphenyl and p-methoxyphenyl and 4-heptafluorophenyl. Optionally substituted cycloalkyl is preferably unsubstituted cycloalkyl is.
[0096] It is. is a cycloalkyl which is the same as or different from each other and is monosubstituted or polysubstituted (preferably up to trisubstituted) by radicals selected from the group consisting of halogen, cyano, (C1-C4)-alkyl, (C1-C4)- alkoxy, (C1-C4)-alkoxy-(C1-C4)-alkoxy, (C1-C4) -alkoxy-(C1-C4)-alkyl, (C1-C4)-haloalkyl and (C1- C4)-haloalkoxy, especially cycloalkyl substituted by one or two (C1-C4)-alkyl radicals is.
[0097] The compounds of the present invention may exist in preferred embodiments. The individual embodiments described herein can be combined with each other. Combinations that are contrary to the laws of nature and would therefore be excluded by a person skilled in the art based on their expertise are not included. For example, a ring structure having three or more adjacent oxygen atoms is excluded.
[0098] Isomer The compounds represented by formula (I) can exist in the form of geometric isomers, and / or in the form of optically active isomers, or in the form of corresponding isomer mixtures in various compositions, depending on the type of their substituents. These stereoisomers are, for example, enantiomers, diastereomers, atropisomers or geometric isomers. Accordingly, the present invention encompasses both pure stereoisomers and any mixtures of these isomers.
[0099] Methods and uses The present invention also relates to a method for controlling pests, wherein in the method, the formula (I) is represented The resulting compound is made to act on pests and / or their habitats. The control of pests is preferably carried out in agriculture and forestry, as well as in the protection of materials. Preferably, methods of surgical or therapeutic treatment of the human or animal body and diagnostic methods performed on the human or animal body are excluded from the above methods.
[0100] The present invention further relates to the use of a compound of formula (I) as a pesticidal agent, in particular as a crop protection agent.
[0101] In connection with the present application, the term "pesticide" always includes, in any case, the term "crop protection agent".
[0102] A compound of formula (I) which shows good tolerance in plants, has a desirable degree of toxicity to warm-blooded animals, and shows good environmental compatibility is suitable for protecting plants and plant organs against biotic and abiotic stress factors, is suitable for increasing the yield, is suitable for improving the quality of the harvested product, and is also suitable for controlling pests encountered in agriculture, horticulture, animal husbandry, hydroponics, in forests, in gardens and leisure facilities, in the protection of stored products and materials, and in the field of hygiene, in particular insects, arachnids, worms, in particular nematodes, and molluscs.
[0103] In connection with the present patent application, the term "hygiene" means any and all means, methods and practices aimed at preventing diseases (in particular infectious diseases), and useful for protecting the health of humans and animals and / or protecting the environment and / or maintaining cleanliness. It is understood to mean any and all means, methods and implementations. means for cleaning, disinfecting and sterilizing, e.g. For example, textile or hard surfaces (especially glass, wood, concrete, porcelain, ceramic Hand tools for cleaning surfaces (e.g., plastic surfaces, or even metal surfaces) means for disinfecting and sterilizing the same, and means for preventing sanitary pests and / or Means for ensuring that the device remains free of waste material are included. In this connection, preferably, surgical or therapeutic procedures that can be performed on the human or animal body are also included. Devices and diagnostic methods performed on the human or animal body are within the scope of protection according to the invention. are excluded from the scope.
[0104] The term "in the field of hygiene" therefore includes those areas in which such hygienic means, methods and practices are important. All areas, technical and industrial applications, e.g. kitchens, bakeries, airports, bathrooms, Regarding hygiene in swimming pools, department stores, hotels, hospitals, livestock sheds, livestock farms, etc. The scope of the present application covers all areas, technical fields and industrial applications.
[0105] Therefore, the term "sanitary pest" refers to insects whose presence is problematic in the field of hygiene, especially those is understood to mean one or more types of pests that are problematic for health reasons. The main objective is to avoid or minimize the presence of sanitary pests in the field of hygiene. and / or avoid or minimize contact with sanitary pests. This is particularly important to prevent outbreaks and to tackle existing outbreaks. This can be achieved by applying insecticides that can be used for both There is also the possibility of using preparations that avoid or reduce contact with pests. Sanitary Pests include, for example, the organisms described below.
[0106] Thus, the term "hygienic protection" encompasses all acts of maintaining and / or improving such hygienic means, methods, and practices.
[0107] The compounds represented by formula (I) can preferably be used as pesticidal agents. They are effective against normal susceptible and resistant species and are active against all developmental stages or some developmental stages. Examples of the above pests include the following: : Pests of the phylum Arthropoda, especially those of the class Arachnida, such as species of the genus Acarus ( Acarus spp.), such as Acarus siro, Aceria kuko, Aceria sheldoni, species of the genus Aculops, species of the genus Aculus ( Aculus spp.), such as Aculus fockeui, Aculus schlechtendali, species of the genus Amblyomma, Amphitetranychus viennensis, species of the genus Argas, species of the genus Boophilus, species of the genus Brevipalpus ( Brevipalpus spp.), such as Brevipalpus phoenicis, Bryobia graminum (Brevipalpus phoenicis), Bryobia graminum Bia graminum), Bryobia praet iosa), Centruroides spp., Choriopt es spp., Dermanyssus gallinae, Derma tophagoides pteronyssinus, Derma tophagoides farinae, Dermacentor spp., Eotetranychus spp., e.g., Eotetranychu s hicoriae, Epitrimerus pyri Eutetranychus spp., e.g., Eutetrany chus banksi, Eriophyes spp., e.g., Eriophy es pyri, Glycyphagus domesticus Halotydeus destructor, Hemitarsonemus spp., e.g., Hemitarsonemus latus (= Poly phagotarsonemus latus) Hyalomma spp., Ixodes spp., e.g., Hemitarsonemus latus, Polyphagotarsonemus latus ), Hyalomma spp., Ixodes spp., e.g., spp.), Latrodectus spp., Loxosceles spp., Neutrombicula autumnalis, Nuphersa spp., Oligonychus spp., for example, Oligonychus coffeae, Oligonychus coniferarum, Oligonychus ilicis, Oligonychus indicus, Oligonychus mangiferus, Oligonychus pratensis, Oligonychus punicae, Oligonychus yothersi), Ornithodorus spp., Ornithonyssus spp., Panonychus spp., for example, Panonychus citri (= Metatetranychus citri), Panonychus ulmi (= Metatetranychus ulmi), Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonem spp., Neutrombicula autumnalis (Neutrombicula autumnalis), Nuphersa spp., Oligonychus spp., for example, Oli gonychus coffeae, Oligonychus co niferarum, Oligonychus i licis, Oligonychus indicus (Oligonychus indicus), Oligonychus mangiferus (Oligonychus mangiferus), Oligonychus pratensis (Oligonychus pratensis), Oligonychus punicae (Oligonychus punicae), Oligonychus yothersi ), Ornithodorus spp., Ornithonyssus spp (Ornithonyssus spp.), Panonychus spp., for example, Panonychus citri(= Me (= Metatetranychus citri), Panonych us ulmi(= Metatetranychus ulmi(Met atetranychus ulmi)), Phyllocoptruta oleivora (Phyllocoptruta oleivora), Platytetranychus multidigituli (Platytetranychus multidigituli), Polyphagotarsonem Polyphagotarsonemus latus, Psoroptes genus species (Psoroptes spp.), Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsonemus spp., Steneotarsonemus spin ki, Tarsonemus spp., for example, Tarsonemus confusus, Tarsonemus pallidus, Tetranych us spp., for example, Tetranychus c anadensis, Tetranychus ci nnabarinus, Tetranychus tu rkestani, Tetranychus urtic ae, Trombicula alfredduge si, Vaejovis spp., Vasates lycopersici ; For Chilopoda, for example, Geophilus spp., Scutigera spp.; For Collembola or Collembola class, for example, Oniscus al ; For example, Geophilus spp., Scutigera spp.; For Collembola or Collembola class, for example, Oniscus al Onychiurus armatus; Sminthurus viridis nthurus viridis from the class Diplopoda, for example, Blani ulus guttulatus from the class Insecta, for example, from the order Blattodea, for example , Blatta orientalis, Blattella a sahinai, Blattella germanica, Leucophae a maderae, Loboptera decipi ens, Neostylopyga rhombi folia, Panchlora spp., Parcoblatta spp. (Parcoblatta spp.), Periplaneta spp. (Periplaneta spp.), for example, Periplaneta ameri cana, Periplaneta austral asiae, Pycnoscelus suri namensis, Supella longipalpa ; from the order Coleoptera, for example, Acal ymma vittatum, Acanthosc elides obtectus, Adoretus spp. Aethina tumida, Agelastica alni, Agrilus spp., for example, Agrilus planipennis, Agrilus coxalis, Agrilus bilineatus, Agrilus anxius, Agriotes spp., for example, Agriotes linneatus, Agriotes mancus, Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., for example, Anoplophora glabripennis, Anthonomus spp., for example, Anthonomus grandis, Anthrenus spp., Apion spp., Apogonia spp., Atomaria spp., for example, Atomaria linearis, Attagenus spp., Baris caerulescens, Bruchidius obtectus astica alni), Agrilus spp., for example, Agr ilus planipennis), Agrilus coxalis), Agrilus bilineatus ), Agrilus anx ius), Agriotes spp., for example, Agriotes linneatus), Agriotes mancus ), Alphitobius diaperinus ), Amphimallon solstitialis ), Anobium punctatum ), Anoplophora spp., for example ), Anoplophora glabripenn is), Anthonomus spp., for example, Anthonomus · grandis), Anthrenus spp., ), Apion spp., Apogonia spp., ), Atomaria spp., for example ), Atomaria linearis), Attagenus spp., ), Baris caerule scens), Bruchidius obtectus ), Bruchus spp., such as Bruchus pisorum, Bruchus rufimanus, Cassida spp., Ceutorhynchus trifurcata, Ceutorrhynchus spp., such as Ceutorrhynchus assimilis, Ceutorrhynchus quadridens, Ceutorrhynchus rapae, Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus chus pisorum), Bruchus rufimanus, Cassida spp., Ceutorrhynchus trifurcata, Ceutorrhynchus spp., such as Ceutorrhynchus assimilis, Ceutorrhynchus quadridens, Ceutorrhynchus rapae, Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus nus), Cassida spp., Ceutorrhynchus trifurcata, Ceutorrhynchus spp., such as Ceutorrhynchus assimilis, Ceutorrhynchus quadridens, Ceutorrhynchus rapae, Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus rotoma trifurcata), Ceutorrhynchus spp., such as Ceutorrhynchus assimilis, Ceutorrhynchus quadridens, Ceutorrhynchus rapae, Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus hus spp.), such as Ceutorrhynchus assimilis, Ceutorrhynchus quadridens, Ceutorrhynchus rapae, Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus us assimilis), Ceutorrhynchus quadridens, Ceutorrhynchus rapae, Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus chus quadridens), Ceutorrhynchus rapae, Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus hus rapae), Chaetocnema spp., such as Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus ba, Chaetocnema confinis, Chaetocnema denticulata, Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus トクネマ·デンチクラタ(Chaetocnema denticulata), Chaetocnema ectypa, Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus クネマ·エクチパ(Chaetocnema ectypa), Cleonus mendicus, Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus (Cleonus mendicus), Conoderus spp., Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus .), Cosmopolites spp., such as Cosmopolites sordidus, Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus リテス·ソルジズス(Cosmopolites sordidus), Costelytra zealandica, Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus ゼアランジカ(Costelytra zealandica), Ctenicera spp., Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus enicera spp.), Curculio spp., such as Curculio caryae, Curculio caryatrypes, Curculio obtusus 、クルクリオ·カリアエ(Curculio caryae), Curculio caryatrypes, Curculio obtusus ペス(Curculio caryatrypes), Curculio obtusus culio obtusus), Curculio sayi, Cryptolestes ferrugineu s), Cryptolestes pusillus, Cryptorhynchus lapathi, Crypt torhynchus mangiferae , Cylindrocopturus spp., Cylin drocopturus adspers us), Cylindrocopturus fur nissi), Dendroctonus spp., for ex ample, Dendroctonus ponderosae ), Dermestes spp., Diabrotica spp. ), for example, Diabrotica balteata ), Diabrotica barber i), Diabrotica und ecimpunctata howardi), Diabrotica undecimpunctata undecimpunctata ), Diabrotica virgifera virgifera ), Diabrotica virgifera zeae), Diatraea spp. Species (Dichocrocis spp.), Dichocrocis armigera spa armigera), Diloboderus spp. , Epicaerus spp., Epilachna spp. hna spp.), for example, Epilachna borealis alis), Epilachna varivestis , Epitrix spp., for example, Epitrix cucumeris (Epitrix cucumeris), Epitrix fuscula fuscula), Epitrix hirtipennis nis), Epitrix subcrinita, Ep itrix tuberis, Faustinus spp. ustinus spp.), Gibbium psylloides ides), Gnathocerus cornutus , Hellula undalis, Heteronychus arator (Heteronychus arator), Heteronyx spp. spp.), Hylamorpha elegans, Hy lotrupes bajulus, Hypera postica (Hypera postica), Hypomeces squamosus squamosus), Hypothenemus spp., for example For example, Hypothenemus hampei, Hypothenemus obscurus, Hypothenemus pubescens, Lachnosterna con sanguinea, Lasioderma serricorne, Latheticus oryzae (Latheticus oryzae), Lathridius spp., Lema spp., Leptinotarsa decemlineata (Leptinotarsa decemlineata), Leucoptera spp., for example, Leucoptera coffeella (Leucoptera coffeella), Limonius ectypus, Lissorhoptrus oryzophilus (Lissorhoptrus oryzophilus), Listronotus spp. (= Hyperodes spp.) (= Hyperodes spp.), Lixus spp., Luperodes spp., Luperomorpha xanthodera (Luperomorpha xanthodera), Lyctus spp., Megacyllene spp., for example, Megacyllene robiniae (Megacyllene robiniae), Megascelis spp., Melanotus spp., for example, Melanotus longulus oregonensis (Melanotus longulus oregonensis), etc. (etc.), etc. (etc.), etc. (etc.), etc. (etc.), etc. (etc.), etc. (etc.), etc. (etc.), etc. (Melanotus longulus oregonensis), etc. Onensis), Meligethes aeneus, Species of the genus Melolontha, such as Melolontha melolontha (Melolontha melolontha), Species of the genus Migdolus spp.), Species of the genus Monochamus, Nauphactus xanthographus (Naupactus xanthographus), Species of the genus Necrobia (Necrobia spp.), Species of the genus Neogalerucella spp.), Niptus hololeucus, Oryctes rhinoceros (Oryctes rhinoceros), Oryzaephilus surinamensis (Oryzaephilus surinamensis), Oryzaphagus oryzae (Oryzaphagus oryzae), Species of the genus Otiorhynchus spp.), such as Otiorhynchus cribricollis (Otiorhynchus cribricollis), Otiorhynchus ligustici (Otiorhynchus ligustici), Otiorhynchus ovatus (Otiorhynchus ovatus), Otiorhynchus rugosostriarus (Otiorhynchus rugosostriarus), Otiorhynchus sulcatus (Otiorhynchus sulcatus), Species of the genus Oulema such as Oulema melanopus, Oulema oryzae (Oulema oryzae), Oxycetonia jucunda a jucunda), Phaedon cochlearia riae), Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., e.g., Phyllotreta armoraciae, Phyllotreta pusilla , Phyllotreta ramosa, Phyllotreta striolata, Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., e.g., Psylliodes affinis, Psylliodes chrysocephala, Psylliodes punctulata, Ptinus spp., Rhizobius ventr alis, Rhizopertha dominica , Rhynchophorus spp., Rhynchophorus ferrugineus, Rhynchophorus palmarum, Scobius spp., e ntralis, Rhizopertha dominica ), Rhynchophorus spp., Rhynchophorus ferrugineus , Rhynchophorus palmarum, Scobius spp., Scobius spp., olyptus spp.), for example, Scolytu s multistriatus), Sinoxylon perforans , Sitophilus spp.), for example , Sitophilus granarius, Sitophilus linearis, Sitophilus oryzae , Sitophilus zeamais, Sphenophorus spp.), Stegobium paniceum, Sternechus spp.), for example, Sternechus paludatus , Symphylletes spp.), Tanymecus spp.), for example, Tanymecus dilaticollis, Tanymecus indicus, Tanymecus palliatus, Tenebrio molitor, Tenebrioides mauretanicus , Tribolium spp.), for example , Tribolium audax, Tribolium castaneum, Tribolium confusum, Trogoderma spp.) , for example, Tribolium audax, Tribolium castaneum, Tribolium confusum, Trogoderma spp.) spp.), Tychius spp., Xyl otrechus spp., Zabrus spp., for example, Zabrus tenebrioides; of the order Dermaptera, for example, Anisolabis maritime, Forficula auricularia, Labidura ripar ia; of the order Diptera, for example, Aedes spp., for example, Aedes aegypti, Aedes albopictus (Aedes albopictus), Aedes sti cticus, Aedes vexans, Agromyza spp., for example, (Agromyza frontella), Agromyza parvi cornis, Anastrepha spp., Anopheles spp., for example, Anopheles quadrimaculatus (Anopheles quadrimaculatus), Anopheles gambiae (Anopheles gambiae), Asphondyli a spp., Bactrocera spp., for example, Bactrocera cucurbitae, Bactrocera cucurbitae, Bactrocera Bactrocera dorsalis, Bactrocera oleae (Bactrocera oleae), Bibio hort ulanus), Calliphora erythro cephala), Calliphora vicina, Cerat itis capitata), species of the genus Chironomus (Chir onomus spp.), species of the genus Chrysomya (Chrysomya spp.), Chry sops spp.), Chrysops pluvialis (Chrysoz ona pluvialis), species of the genus Cochliomya (Cochliomya spp.) , species of the genus Contarinia (Contarinia spp.), for example, Contarinia john soni (Contarinia johnsoni), Contarinia nasturtii (C ontarinia nasturtii), Contarinia pyrivora (Contari nia pyrivora), Contarinia sch ulzi (Contarinia schulzi), Contarinia sorghicola (Contarinia sorghicola ), Contarinia tritici, Cordylobia anthropophaga (Cordylobia anthropophaga), Cricot opus sylvestris (Cricotopus sylvestris), species of the genus Culex (Culex spp.) , for example, Culex pipiens (Culex pipien s), Culex quinquefasciatus (Culex quinquefasciat us), species of the genus Culicoides (Culicoides spp.), species of the genus Culiseta (Cul species of Oestrus, Cuterebra spp., Dacus oleae, Dasineura spp. , for example, Dasineura brassicae, Delia spp. , for example, Delia antiqua, Delia coarctata, Delia flo rilega, Delia platura, Delia radicum, Dermatobia hominis (Dermatobia hominis), Drosophila spp. (Drosophila spp.), for example, Drosophila melanogaster, Drosophila suzukii (Drosophila melanogaster), Drosophila suzukii (Drosophila suzukii), Echinocnemus spp., Euleia heraclei (Euleia heraclei), Fannia spp. (Fannia spp.), Gasterophilus spp., Glossina spp. (Glossina spp.), Haematopota spp. (Haematopota spp.), Hydrellia spp. (Hydrellia spp.), Hydrellia griseola, Hylemya spp. (Hylemya spp.), Hippobosca spp., Hypoderma spp. (Hypoderma spp.), Liriomyza spp. (Liriomyza spp.), for example, Liriomyza Liriomyza brassicae, Liriomyza huidobrensis Liriomyza huidobrensis, Liriomyza sativae Lucilia spp., for example, Lucilia cuprina, Lutzomyia spp., Mansonia spp., Musca spp., for example, Musca domestica, Musca domestica vicina, Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomya or Pegomyia spp., for example, Pegomya betae, Pegomya hyoscyami, Pegomya rubivora, Phlebotomus spp., Phorbia spp., Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., Psila rosae, Rhagoletis spp., for example, Rhagoletis · Rhagoletis cingulata, Rhagoletis completa (Rhagoletis completa), Rhagoletis fausta etis fausta), Rhagoletis indifferens ndifferens), Rhagoletis mendax x), Rhagoletis pomonella, Sarcophaga spp. Sarcophaga spp., Simulium spp. pp.), for example, Simulium meridionale le), Stomoxys spp., Tabanus spp. s spp.), Tetanops spp., Tipula spp. pula spp.), for example, Tipula paludosa ), Tipula simplex, Toxotrypana curvicauda uda); Hemiptera, for example, Acizzia acaciaebaileyanae (Acizzia acaciaebaileyanae), Acizzia dodonaeae Acizzia dodonaeae), Acizzia uncatoides uncatoides), Acrida turrita, Acyrthosipon spp. pp.), for example, Acyrthosiphon pisum m), Acrogonia spp., Aeneolamia spp., Agonosena a spp.), Aeneolamia spp., Agonosena Species of Agonoscena, Aleurocants spp., Aleyrodes prolet ella, Aleurolobus barodensis, Aleurothrixus flocco sus, Allocaridara malayensis, Amrasca spp., e.g., Amrasca bigutulla Amrasca devastans, Anuraphis cardui, Aonidiella spp., e.g., Aonidiella aurantii Aonidiella citrina, Aonidiella inornata, Aphanostigma piri Aphis spp., e.g., Aphis citricola, Aphis craccivora Aphis fabae, Aphis forbesi, Aphis glycines Aphis gossypii, Aphis hederae, Aphis illinoensis Aphis middletoni, Aphis Aphis Aphis Aphis Aphis Aphis Aphis Aphis Aphis Aphis Aphis Aphis nasturtii, Aphis nerii erii, Aphis pomi, Aphis spiraecola his spiraecola, Aphis vibur niphila, Arboridia apicalis (), Arytainilla spp., Aspidiella spp. pidiella spp., Aspidiotus spp. (), for example, Aspidiotus nerii, Atanus spp., Aulacorthum solani , Bemisia tabaci, Blastopsylla occidentalis Boreioglycaspis melaleuca e, Brachycaudus helichrysi (), Brachycolus spp., Brevicoryne brassicae e, Cacopsylla spp. (), for example, Cacopsylla pyricola cola, Calligypona marginata , Capulinia spp., Carneocephala fulgida C arneocephala fulgida, Cerato woolly aphid), Cercopidae, Ceroplastes spp., Kaetosiphon fragaefolii (C hionaspis tegalensis), Chlorita onukii, Chondracris rosea (Chromaphis juglandicola) , Chrysomphalus aonidum, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., e.g., Coccus hesperidum, Coccus longulus (Coccus pseudomagnoliarum), Coccus vir idis, Cryptomyzus ribis, Cryptoneossa spp., Ctenarytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes citri, Diaphorina citri, Diaspis spp., Diur Diuraphis spp., Doralis sp p., Drosicha spp., Dysaph is spp., for example, Dysaphis apiif olia, Dysaphis plantaginea ), Dysaphis tulipae, Dysmicoccus spp (Dysmicoccus spp.), Empoasca spp .), for example, Empoasca abrupta, Em poasca fabae, Empoasca maligna(Em poasca maligna), Empoasca sola na, Empoasca stevensi, Eriosoma spp.), for example, Eriosoma americanum(Erio soma americanum), Eriosoma lanigerum(Eriosoma la nigerum), Eriosoma pyricola, E rythroneura spp., Eucalyptolyma spp(E ucalyptolyma spp.), Euphyllura s pp.), Euscelis bilobatus, Ferri sia spp., Fiorinia sp p.), Furcaspis oceanica, Geoco Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., e.g., Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M ycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., e.g., Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M bana, Heteropsylla spinulosa, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., e.g., Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M a, Homalodisca coagulata, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., e.g., Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M a, Hyalopterus arundinis, Hyalopterus pruni, Icerya spp., e.g., Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M a, Hyalopterus pruni, Icerya spp., e.g., Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M a spp., e.g., Icerya purchasi, Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M a spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M opus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M triatellus, Lecanium spp., e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M triatellus, e.g., Lecanium corni (= Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M Parthenolecanium corni), Lepidosaphes spp., e.g., Lepidosaphes ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M es ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M es ulmi, Lipaphis erysimi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M es ulmi, Lopholeucaspis japonica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M ica, Lycorma delicatula, Macrosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M crosiphum spp., e.g., Macrosiphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M siphum euphorbiae, Macrosiphum lilii, Macrosiphum rosae, M m lilii, Macrosiphum rosae, M Macrosteles facifrons, Maha Mahanarva spp., Melanaphis sacchari Metcalfiella spp., Metcalfa pruinosa, Metopolophium dirhodum Monellia costalis, Monelliopsis pecanis, Myzus spp., for example, Myzus ascalonicus, Myzus cerasi, Myzus ligustri , Myzus ornatus, Myzus persicae, Myzus nicotianae , Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., for example, Nephotettix cincticeps, Nephotettix nigropictus , Nettigoniella spectra, Nilaparvata lugens, Oncometopia spp., Orthezia spp. Orthezia praelonga, Oxya chinensis, Pachypsylla spp., Parabemisia myricae, Paratrioza spp., e.g., Paratrioza cockerelli, Parlatoria spp., Pemphigus spp., e.g., Pemphigus bursarius, Pemphigus populivenae, Peregrinus maidis, Perkinsiella spp., Phenacoccus spp., e.g., Phenacoccus madeirensis, Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., e.g., Phylloxera devastatrix, Phylloxera notabilis, Pinnaspis aspidistrae, Planococcus spp., e.g., Planococcus citri, Prosopidopsylla Prosopidopsylla flava, Protopulvinaria pyriformis Protopulvinaria pyriformis, Pseudaulacaspis Pseudaulacaspis pentagona, Pseudococcus spp., e.g., Pseudococcus calceolariae, Pseudococcus calceolariae, Pseudococcus comstocki, Pseudococcus comstocki, Pseudococcus longispinus, Pseudococcus longispinus, Pseudococcus maritimus, Pseudococcus maritimus, Pseudococcus viburni, Psyllopsis spp., Psylla spp., e.g., Psylla buxi, Psylla mali Psylla spp., e.g., Psylla buxi, Psylla mali Psylla pyri, Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspidiotus spp., e.g., Quadraspidiotus juglansregiae, Quadraspidiotus ostreaeformis, Quadraspidiotus perniciosus, Quesada gigas, Lastrococcus Quadraspidiotus spp., e.g., Quadraspidiotus juglansregiae, Quadraspidiotus ostreaeformis, Quadraspidiotus perniciosus, Quesada gigas, Lastrococcus Quadraspidiotus juglansregiae, Quadraspidiotus ostreaeformis Quadraspidiotus ostreaeformis, Quadraspidiotus perniciosus Quadraspidiotus perniciosus, Quesada gigas, Lastrococcus ciosus, Quesada gigas, Lastrococcus Species of Rastrococcus, Rhopalosiphum spp., for example, Rhopalosiphum maidis, Rhopalosiphum oxyacanthae, Rhopalosiphum padi , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. Species of Rastrococcus, Rhopalosiphum spp., for example, Rhopalosiphum maidis, Rhopalosiphum oxyacanthae, Rhopalosiphum padi , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. , Rhopalosiphum rufiabdominale, Saissetia spp., for example, Saissetia coffeae, Saissetia miranda, Saissetia neglecta, Saissetia oleae, Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Siphona flava, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninus phillyreae, Tenalaphara malayensis, Tetragonoscelifera spp. Tragonocephela spp.), Tinochalis caryaefoliae, Tomaspis sp p.), Toxoptera spp., for example, Toxoptera aurantii, Toxoptera citricidus, Trialeurodes vaporariorum (Toxoptera aurantii), Toxoptera citricidus (Toxoptera citricidus), Trialeurodes vaporariorum Trialeurodes vaporariorum), Trioza spp .), for example, Trioza diospyri, Typhlocyba spp .), Unaspis spp., Viteus vitifolii, Zygina spp (Zygina spp.); (Zygina spp.); For Heteroptera, for example, Aelia spp .), Anasa tristis, Antestiopsis spp .), Boisea spp .), Blissus spp., Calocoris spp .), Campylomma livida, Cavelerius spp .), Cimex spp .), for example, Cimex adjunctus, Cimex hemipterus, Cimex lectularius, Cimex pilos ellus, Cimex pilosellus ellus), Collaria spp., Creontiades dilutus s), Dasynus piperis s), Dichelops furcatus s), Diconocoris hewetti, Dysdercus spp. s), Euschistus spp., for example, Euschistus hero s), Euschistus servus, Euschistus tristigmus s), Euschistus variolarius, Eurydema spp. s), Eurygaster spp., Halyomorpha halys, Heliopeltis spp. s), Horcias nobilellus, Leptocorisa spp. s), Leptocorisa varicornis, Leptoglossus occidentalis s), Leptoglossus phyllopus, Lygocoris spp. s), for example, Lygocoris pabulinus, Lygus spp. s), for example, Lygus elisus, Lygus hesperus s), Leptocorisa varicornis is), Leptoglossus occidentalis is), Leptoglossus phyllopus s), for example, Lygocoris pabulinus s), Lygus spp. s), for example, Lygus elisus, Lygus hesperus gus hesperus), Lygus lineolari s), Macropes excavatus, Megaco pta cribraria, Miridae dae), Monalonion atratum, Neza ra spp., e.g., Nezara vir idula), Nysius spp., Oebalus spp. ), Pentomidae, Piezma quadrata (P iesma quadrata), Piezodorus spp. ), e.g., Piezodorus guildinii ), Psallus spp., Pseudacysta persea ), Rhodnius spp., S ahlbergella singularis, S captocoris castanea, Scotinopho ra spp., Stephanitis nashi ), Tibraca spp., Triatoma spp. ; Of the order Hymenoptera, e.g., Acromyrmex spp. ), Athalia spp., e.g., Athalia rosae, Atta spp., Camponotus Camponotus spp., Dolicho vespula spp., Diprion spp., for example, Diprion similis, Hoplocampa spp., for example, Hoplocampa cookei, Hoplocampa testud inea, Lasius spp., Linepithema (Iridiomyrmex) humile , Monomorium pharaonis, Paratrechina spp., Paravespula spp., Plagiolepis spp., Sirex spp., for example, Sirex noctilio, Solenopsis invict a, Tapinoma spp., Technomyrmex albipes, Urocerus s pp., Vespa spp., for example, Vespa crabro, Wasmannia auro punctata, Xeris spp.; Isopoda, for example, Armadillidium vulgare, Oniscus as ellus ellius), Porcellio scaber; from the order Isoptera, such as species of the genus Coptotermes spp.), such as Coptotermes formosanus, Cornitermes cumulans, species of the genus Cryptotermes, Incisitermes spp., Kalotermes spp., Microtermes besi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp.), such as Reticulitermes flavipes, Reticulitermes hesperus; from the order Lepidoptera, such as Acroia grisella, Acronicta major, species of the genus Adoxophyes, such as Adoxophyes orana, Aedia leucomelas, species of the genus Agrotis, such as Agrotis segetum, Agrotis ipsilon from the order Lepidoptera, such as Acroia grisella, Acronicta major, species of the genus Adoxophyes, such as Adoxophyes orana, Aedia leucomelas, species of the genus Agrotis, such as Agrotis segetum, Agrotis ipsilon from the order Lepidoptera, such as Acroia grisella, Acronicta major, species of the genus Adoxophyes, such as Adoxophyes orana, Aedia leucomelas, species of the genus Agrotis, such as Agrotis segetum, Agrotis ipsilon (Agrotis ipsilon), Alabama spp., for example, Alabama argillacea, Amyelois transitella, Anarsia spp., Anticarsia spp., for example, Anticarsia gemmatalis, Argyroploce spp., Autographa spp., Barathra brassicae, Blastodacna atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., for example, Chilo plejadellus, Chilo suppressalis, Choreutis pariana, Choristoneura spp., ... ... ... ... ... ... ... spp.), Chrysodeixis chalcites ), Clysia ambiguella, Cnaphalo cerus spp., Cnaphalocrocis medinalis ), Cnephasia spp., Conopomorpha spp. ), Conotrachelus spp., Copitarsia spp. ), Cydia spp., for example, Cydia nigricana, Cydia pomonella ), Dalaca noctuides ), Diaphania spp., Dipalopsis spp. ), Diatraea saccharalis ), Dioryctria spp., for example, Dioryctria zimmermani, Earias spp. ), Ecdytoctophaga aurantium ), Elasmopalpus lignosellus ), Eldana saccharina ), Ephestia spp., for example, Ephestia elutella, Ephestia kuehniella ), The flour moth (Ephestia kuehniella), Epinotia species (Epinotia spp.), the light brown apple moth (Epiphyas postvittan a), Erannis species (Erannis spp.), Elasmobiela musculana (E rschoviella musculana), Etiella species (Etiella sp p.), Eudocima species (Eudocima spp.), Eulia species (Eulia spp.), Eupoecilia ambiguella (Eupoecilia ambiguel la), Euproctis species (Euproctis spp.), for example, Euprocti s chrysorrhoea (Euproctis chrysorrhoea), Euxoa species (Euxoa spp.), Feltia species (Feltia spp.), the greater wax moth (Galleria mellonella), Gracillaria species (Gracil laria spp.), Grapholitha species (Grapholitha spp.), for example Grapholita molesta (Grapholita molesta), Grapholita prunivora (Grapholita pr univora), Hedylepta species (Hedyl epta spp.), Helicoverpa species (Helicoverpa spp.), for example Helicoverpa armigera (Helicoverpa armigera), Helicover pa zea (Helicoverpa zea), Heliothis species (Heliothi s spp.), for example, Heliothis virescens (Heliothis viresc ens), Hofmannophila pseudospretella (Hofmannophila ps eudospretella), Homoeosoma species (Homoeosoma spp.) , Homona spp., Hyponomeuta padella ta padella), Kakivoria flavofasciata vofasciata), Lampides spp., Laphygma spp., Laspeyresia molesta ia molesta), Leucinodes orbonalis onalis), Leucoptera spp., for example, Leucoptera coffeella coffeella), Lithocolletis spp., for example, Lithocolletis blancardella blancardella), Lithophane antennata antenna), Lobesia spp., for example, Lobesia botrana pp.), for example, Lobesia botrana), Loxagrotis albicosta pp.), for example, Lobesia botrana), Loxagrotis albicosta), Lymantria spp., for example, Lymantria dispar Loxagrotis albicosta), Lymantria spp., for example, Lymantria dispar ria dispar), Lyonetia spp., for example, Lyonetia clerkella ria dispar), Lyonetia spp., for example, Lyonetia clerkella), Malacosoma neustria clerkella), Malacosoma neustria), Maruca testulalis ca testulalis), Mamestra brassicae sicae), Melanitis leda), Moses spp., for example, Mo sicae), Melanitis leda), Moses spp., for example, Mo cis spp.), Monopis obviella, M Mythimna separata, Nemapogon cloacellus (Nemapogon cloacellus), Nymphula spp pp.), Oiketicus spp., Omphisa spp pp.), Operophtera spp., O ria spp., Orthaga spp., Ostrinia spp pp.), for example, Ostrinia nubilalis (Os trinia nubilalis), Panolis flammea (Panolis fla mmea), Parnara spp., Pectinophora spp pp.), for example, Pectinophora gossypiella (Pectino phora gossypiella), Perileucoptera spp pp.), Phthorimaea spp., for example Phthorimaea operculella , Phyllocnistis citrella, Phyllonorycter spp pp.), for example, Phyllonorycter blancardella (Phyllonory cter blancardella) , Phyllonorycter crataegella pp.), Pieris spp., for example, Pieris rapae (Pi eris rapae), Platynota stultana na), Plodia interpunctella ), Plusia spp., Plutella xylostella (= Plutella maculipennis) , Podesia spp., e.g., Podesia syringae , Prays spp., Prodenia spp., Protoparce spp .), Pseudaletia spp .), e.g., Pseudaletia unipuncta , Pseudoplusia includens , Pyrausta nubilalis, Rachiplusia nu , Schoenobius spp., e.g., Schoenobius bipunctifer , Scirpophaga spp., e.g., Scirpophaga innotata , Scotia segetum, Sesamia spp .), e.g., Sesamia inferens , Sparganothis spp., Spodoptera spp .), e.g., Spodoptera eridania , Spodoptera spp., e.g., Spodoptera exigua , Spodoptera spp., e.g., Spodoptera frugiperda , Spodoptera spp., e.g., Spodoptera litura Spodoptera eradiana), Spodoptera exigua, Spodoptera frugi perda), Spodoptera praefica ), Stathmopoda spp., Stenoma spp., Stomopteryx subsecivella ), Synanthedon spp., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix sp .), Trichophaga tapetzella ), Trichoplusia spp., for example, Trichoplusia ni, Tryporyza incertulas, Tuta absoluta ), Virachola spp.; Orthoptera or Saltatoria, for example, Acheta domesticus, Dichroplus spp., Gryllotalpa spp ), ), ), p ), ), ), ), ; ), for example, Acheta domesticus, Dichroplus spp., Gryllotalpa spp ), ), For example, Gryllotalpa gryllotalpa a), Hieroglyphus spp., Locusta spp. such as Locusta migratoria , Melanoplus spp., such as Mel anoplus devastator , Paratlanticus ussuriensis , Schistocerca gregaria; Of the order Phthiraptera, for example, Damalinia spp. , Haematopinus spp., Linognathus spp. , Pediculus spp., Phylloxera vastatrix , Phthirus pubis, Trichodectes spp. ; Of the order Psocoptera, for example, Lepinotus spp. , Liposcelis spp.; Of the order Siphonaptera, for example, Ceratophyllus spp. , Ctenocephalides spp. such as Ctenocephalides canis , Ctenocephalides felis ; felis), Pulex irritans, Tunga penetrans, Xenopsylla cheopis); Tunga penetrans, Xenopsylla cheopis); ylla cheopis); Thysanoptera, for example, Anaphothrips obscurus Anaphothrips obscurus, Baliothrips biformis Baliothrips biformis, Caetanaphothrips leeuweni Caetanaphothrips leeuweni, Drepanothrips reuteri Drepanothrips reuteri, Enneothrips flavens Enneothrips flavens, Frankliniella spp.) Frankliniella spp.), for example, Frankliniella fusca Frankliniella fusca, Frankliniella occidentalis Frankliniella occidentalis, Frankliniella schultzei Frankliniella schultzei, Frankliniella tritici Frankliniella tritici, Frankliniella vaccinii Frankliniella vaccinii, Frankliniella williamsi Frankliniella williamsi, Haplothrips spp.) Haplothrips spp.), Heliothrips spp.) Heliothrips femoralis, Hercinothrips femoralis Hercinothrips femoralis, Kakothrips spp.) othrips cruentatus), Scirtothrips spp., Taeniothrips cardamomi, Thrips spp., for example, Thrips palmi (Thrips palmi), Thrips tabaci; (Thrips palmi), Thrips tabaci; Insects of the order Zygentoma (= Thysanura), for example, Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; Lepismodes inquilinus, Thermobia domestica; ca); Pests of the class Symphyla, for example, Scutigerella spp., for example, Scutigerella immaculata; Pests of the class Symphyla, for example, Scutigerella spp., for example, Scutigerella immaculata; immaculata); Pests of the phylum Mollusca, for example, pests of the class Bivalvia, for example, Dreissena spp.; and, furthermore, Pests of the class Gastropoda, for example, Arion spp., for example, Arion ater rufus, Biomphalaria spp., Bulinus spp., Deroceras spp., for example, Deroceras laeve, Galba spp., Pests of the class Gastropoda, for example, Arion spp., for example, Arion ater rufus, Biomphalaria spp., Bulinus spp., Deroceras spp., for example, Deroceras laeve, Galba spp., .), for example, Arion ater rufus, Biomphalaria spp., Bulinus spp., Deroceras spp., for example, Deroceras laeve, Galba spp., Biomphalaria spp., Bulinus spp., Deroceras spp., for example, Deroceras laeve, Galba spp., Deroceras spp., for example, Deroceras laeve, Galba spp., Deroceras laeve, Galba spp., )), Lymnaea spp., Oncomelania spp., Lania spp., Pomacea spp., Succinea spp.; (Succinea spp.); Plant pests of the phylum Nematoda (i.e., plant parasitic nematodes), in particular, Aglenchus spp., such as Aglenchus agricola, Anguina spp., (e.g., Anguina tritici), Aphelenchoides spp., such as Aphelenchoides arachidis, Aphelenchoides fragariae, Belonolaimus spp., (e.g., Belonolaimus gracilis, Belonolaimus longicaudatus, Belonolaimus nortoni), Bursaphelenchus spp., (e.g., Bursaphelenchus cocophilus, Bursaphelenchus eremus, Bursaphelenchus xylophilus), Cacopaurus spp., (e.g., Cacopaurus pestis), Criconemella spp., (e.g., Belonolaimus gracilis), Belonolaimus longicaudatus, Belonolaimus nortoni, Bursaphelenchus spp., (e.g., Bursaphelenchus cocophilus), Bursaphelenchus eremus, Bursaphelenchus xylophilus, Cacopaurus spp., (e.g., Cacopaurus pestis), Criconemella spp., (e.g., Belonolaimus nortoni), Bursaphelenchus spp., (e.g., Bursaphelenchus cocophilus), Bursaphelenchus eremus, Bursaphelenchus xylophilus, Cacopaurus spp., (e.g., Bursaphelenchus cocophilus), Bursaphelenchus eremus, Bursaphelenchus xylophilus, Cacopaurus spp., (e.g., Bursaphelenchus eremus), Bursaphelenchus xylophilus, Cacopaurus spp., (e.g., Bursaphelenchus xylophilus), Cacopaurus spp., (e.g., Cacopaurus pestis), Criconemella spp., (Criconemella spp.) ) For example, Criconemella curvata, Criconemella onoensis, Cric onemella ornata, Criconemella rusium , Criconemella xenoplax ( = Mesocriconema xenoplax) , Criconemoides spp., for example, Criconemoides ferniae , Criconemoides onoense, Criconemoides ornatum, Ditylenchus spp. , for example, Ditylenchus dipsaci, Dolichodorus spp., Globodera spp. , for example, Globodera pallida , Globodera rostochiensis , Helicotylenchus spp., for example, Helicotylenchus dihystera , Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp. , for example, Heterodera avenae , , eterodera spp., for example, Heterodera avenae a avenae), Heterodera glycine s), Heterodera schachtii, Hirsch maniella spp.), Hoplolaimus spp .), Longidorus spp .), for example, Longidorus africanu s), Meloidogyne spp.), for example, Meloidogyne · chitwoodi, Meloidogyne fallax ), Meloidogyne hapla ), Meloidogyne incognita ), Meloinema spp.), Nacobbus spp ), Neotylenchus spp ), Paralongidorus spp.), Para phelenchus spp.), Paratrichodorus spp .), for example, Paratrichodorus minor (Paratrichodorus minor), Paratylenchus spp ), Pratylenchus spp .), for example, Pratylenchus penet rans), Pseudohalenchus spp.), Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index. Species of Psilenchus, Punctodera spp., Quinisulcius spp., Radopholus spp., for example, Radopholus citrophilus, Radopholus similis, Rotylenchu lus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., for example, Trichodorus obtusus, Trichodorus primitivus, Tylenchorhynchus spp., for example, Tylenchorhynchus annulatus, Tylenchulus spp., for example, Tylenchulus semipenetrans, Xiphinema spp., for example, Xiphinema index.
[0108] The compound represented by formula (I) may optionally be used as a herbicide, a phytotoxicity reducing agent, a growth regulator, or an agent for improving plant characteristics at a specific concentration or specific application rate, or as a microbicide or a gametocide The compound represented by formula (I) may optionally be used as a herbicide, a phytotoxicity reducing agent, a growth regulator, or an agent for improving plant characteristics at a specific concentration or specific application rate, e) for example, as a fungicide, an antimycoti c), a bactericide or a virucide (which also includes agents acting on viroids) and can also be used as, or as an agent acting on MLO (mycoplasma-like organisms) and RLO (rickettsia -like organisms). Where appropriate, they can also be used as intermediates or precursors for synthesizing another active compound .
[0109] Formulation The present invention further relates to a formulation as a pesticidal agent containing at least one compound represented by formula (I) and a form of use prepared from the formulation [for example, an irrigation solution, a dropping solution and a spraying solution]. Optionally, the form of use further contains a further pesticidal agent and / or , an adjuvant for improving the effect, for example, a penetrant, for example, a vegetable oil (for example, rapeseed oil , sunflower oil), a mineral oil (for example, paraffin oil), a vegetable fatty acid alkyl ester (for example rapeseed oil methyl ester or soybean oil methyl ester), or an alkanol alkoxy xylates, and / or a spreading agent, for example, alkyl siloxanes and / or salts, for example organic or inorganic ammonium salts or phosphonium salts (for example, ammonium sulfate or diammonium hydrogen phosphate), and / or a retention promoter (for example, dioctyl sulfosuccinate or hydroxypropyl guar polymer ), and / or a wetting agent (for example, glycerol), and / or a fertilizer (for example, ammonium -containing fertilizer, potassium-containing fertilizer or phosphorus-containing fertilizer). ) .
[0110] Conventional formulations are, for example, the following: water-soluble liquid formulations (SL), emulsions (EC), Water-in-oil emulsion agents (EW), suspension formulations (SC, SE, FS, OD), granule wettable powders ( WG), granules (GR), and capsule formulations (capsule concentrat es) (CS); these formulation types and other possible formulation types are described, for example, in the following: Crop Life International and in Pe sticide Specifications, Manual on develo pment and use of FAO and WHO specificati ons for pesticides, FAO Plant Production and Protection Papers -173 (source: the FAO / WHO Joint Meeting on Pesticide Specifica tions, 2004, ISBN:9251048576). The formulation contains, in addition to one or more compounds represented by formula (I), optionally, further pesticidal active compounds 。 。 。
[0111] These are preferably formulations or use forms containing adjuvants [e.g., extenders, solvents, spontaneity promoters, carriers, emulsifiers, dispersants, frost protectants, biocides, thickeners and / or other adjuvants (e.g., adjuvants neity promoter), carriers, emulsifiers, dispersants, frost p rotectant), biocides, thickeners and / or other adjuvants (e.g., adjuvants ) etc.]. In this regard, an adjuvant is a component that enhances the biological effect of the formulation, and the component itself does not have a biological effect 。 。Examples of adjuvants are substances that promote retention, spreading, adhesion to the leaf surface or substances that promote penetration.
[0112] These formulations are prepared in a known manner, for example, by mixing a compound of formula (I) with adjuvants (for example, extenders, solvents and / or solid carriers, and / or other adjuvants, for example, surfactants ). Such formulations are prepared using suitable equipment or prepared before or during application.
[0113] The adjuvants used may be substances suitable for imparting special properties, for example, specific physical, technical and / or biological properties, to the formulations of the compounds of formula (I) or to the use forms prepared therefrom (for example, ready-to-use pesticides, for example spray liquors or seed dressing products).
[0114] Suitable extenders are, for example, water and polar and nonpolar organic chemical liquids, for example those selected from the following classes: aromatic and non-aromatic hydrocarbons (for example, paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may be substituted, etherified and / or esterified, where appropriate), ketones (for example, acetone, cyclohexanone), esters (which include fats and oils) and (poly)ethers, unsubstituted and substituted amines, amides, lactams (for example, N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (for example, dimethyl sulfoxide), carbonates and nitriles. (for example, N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (for example, dimethyl sulfoxide), carbonates and nitriles.
[0115] When the extender used is water, an organic solvent can also be used as a co-solvent, for example That is. Essentially, suitable liquid solvents are as follows: aromatic compounds such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic compounds or chlorinated aliphatic hydrocarbons, for example, chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, for example, cyclohexane or paraffins such as mineral oil fractions, mineral oil and vegetable oil, alcohols such as butanol or glycols and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide or dimethyl sulfoxide, carbonates such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles such as acetonitrile or propanenitrile. and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, such as mineral oil fractions, mineral oil and vegetable oil, alcohols, such as butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles, such as acetonitrile or propanenitrile. hydrocarbons, such as cyclohexane or paraffins, such as mineral oil fractions, mineral oil and vegetable oil, alcohols, such as butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles, such as acetonitrile or propanenitrile. hydrocarbons, such as mineral oil fractions, mineral oil and vegetable oil, alcohols, such as butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles, such as acetonitrile or propanenitrile. alcohols, such as butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles, such as acetonitrile or propanenitrile. ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethylformamide or dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles, such as acetonitrile or propanenitrile. polar solvents, such as dimethylformamide or dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles, such as acetonitrile or propanenitrile. carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, or nitriles, such as acetonitrile or propanenitrile. or nitriles, such as acetonitrile or propanenitrile.
[0116] In principle, it is possible to use all suitable solvents. Examples of suitable solvents are aromatic hydrocarbons such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic hydrocarbons or chlorinated aliphatic hydrocarbons, such as chlorobenzene, chloroethylene or methylene chloride, aliphatic hydrocarbons, such as cyclohexane, paraffins, petroleum fractions, mineral oil and vegetable oil, alcohols, such as methanol, ethanol, isopropanol, butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. hydrocarbons such as xylene, toluene or alkylnaphthalenes, chlorinated aromatic hydrocarbons or chlorinated aliphatic hydrocarbons, such as chlorobenzene, chloroethylene or methylene chloride, aliphatic hydrocarbons, such as cyclohexane, paraffins, petroleum fractions, mineral oil and vegetable oil, alcohols, such as methanol, ethanol, isopropanol, butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. hydrogen or chlorinated aliphatic hydrocarbons, such as chlorobenzene, chloroethylene or methylene chloride, aliphatic hydrocarbons, such as cyclohexane, paraffins, petroleum fractions, mineral oil and vegetable oil, alcohols, such as methanol, ethanol, isopropanol, butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. hydrocarbons, such as cyclohexane, paraffins, petroleum fractions, mineral oil and vegetable oil, alcohols, such as methanol, ethanol, isopropanol, butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. alcohols, such as methanol, ethanol, isopropanol, butanol or glycols and their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents, such as dimethyl sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. sulfoxide, carbonates, such as propylene carbonate, butylene carbonate, diethyl carbonate or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. ethyl or dibutyl carbonate, nitriles, such as acetonitrile or propanenitrile. Trillium, and furthermore, water.
[0117] In principle, it is possible to use all suitable carriers. Useful carriers include, in particular, the following: for example, ammonium salts, and ground natural minerals, such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic materials, such as finely ground silica, alumina, and natural or synthetic silicates, resins, waxes, and / or solid fertilizers. Mixtures of such carriers can likewise be used. Useful carriers for granules include the following: for example, ground and sorted natural rocks, such as calcite, marble, pumice, sepiolite, dolomite, and synthetic granules consisting of inorganic and organic coarse powders, and furthermore, granules consisting of organic materials (such as sawdust, paper, coconut shells, corn cobs and tobacco stalks, etc.). It is also possible to use a liquefied gas extender or solvent. Particularly suitable extenders or carriers are extenders or carriers that are gases under ambient temperature and atmospheric pressure, such as aerosol propellant gases, such as halohydrocarbons, and furthermore, butane, propane, nitrogen and carbon dioxide, etc. Examples of emulsifiers and / or foam formers, dispersants or wetting agents having ionic or non-ionic properties, or mixtures of these surfactants are as follows: salts of polyacrylic acid, salts of lignosulfonic acid, salts of phenolsulfonic acid or naphthalenesulfonic acid, polycondensates of ethylene oxide and fatty alcohols or ethylene oxide and fatty acids, etc.
[0118] It is also possible to use a liquefied gas extender or solvent. Particularly suitable extenders or carriers are extenders or carriers that are gases under ambient temperature and atmospheric pressure, such as aerosol propellant gases, such as halohydrocarbons, and furthermore, butane, propane, nitrogen and carbon dioxide, etc. Examples of emulsifiers and / or foam formers, dispersants or wetting agents having ionic or non-ionic properties, or mixtures of these surfactants are as follows: salts of polyacrylic acid, salts of lignosulfonic acid, salts of phenolsulfonic acid or naphthalenesulfonic
[0119] acids, polycondensates of ethylene oxide and fatty alcohols or ethylene oxide and fatty acids, etc. salts of polyacrylic acid, salts of lignosulfonic acid, salts of phenolsulfonic acid or naphthalenesulfonic acid, polycondensates of ethylene oxide and fatty alcohols or ethylene oxide and fatty Polycondensates of acids or polycondensates of ethylene oxide and fatty amines, ethylene oxide and substituted phenols (preferably alkylphenols or arylphenols), polycondensates of sulfosuccinic acid esters, taurine derivatives (preferably alkyltaurates), isethionate derivatives, phosphate esters of polyethoxylated alcohols or phosphate esters of polyethoxylated phenols, fatty esters of polyols, and derivatives of such compounds containing sulfate anions, sulfonate anions and phosphate anions, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates, protein hydrolysates, lignosulfite waste liquors, and methylcellulose. If one or more of the compounds represented by formula (I) and / or one or more of the inert carriers are water-insoluble and the application is carried out with water, it is advantageous to have a surfactant present.
[0120] As further adjuvants in the formulation and the use forms derived therefrom, colorants, for example inorganic pigments such as iron oxide, titanium oxide and Prussian blue, and organic dyes such as alizarin dyes, azo dyes and metal phthalocyanine cyanine dyes, and nutrients and micronutrients such as iron salts, manganese salts, boron salts, copper salts, cobalt salts, molybdenum salts and zinc salts etc. can be used.
[0121] Further components can be stabilizers (e.g. low temperature stabilizers), preservatives, antioxidants, light stabilizers, or other agents that can improve chemical and / or physical stability. Further, foam A forming agent or defoaming agent can also be present.
[0122] Among the formulations and the forms of use derived therefrom, as additional auxiliaries, adhesives, for example, carboxymethyl cellulose, and natural and synthetic polymers in the form of powders or granules or latexes, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, or natural phospholipids, such as cephalin and lecithin, and, synthetic phospholipids and the like can also be present. Further possible auxiliaries are mineral oil and vegetable oil.
[0123] Optionally, further auxiliaries can also be present in the formulations and the forms of use derived therefrom. Examples of such additives include fragrances, protective colloids, binders, adhesives, thickeners, thixotropic agents, penetrants, retention promoters, stabilizers, sequestering agents, complexing agents, wetting agents, spreading agents, etc. Generally, the compounds represented by formula (I) can be combined with any solid or liquid additives commonly used for formulation purposes.
[0124] Useful retention promoters include all substances that reduce dynamic surface tension (e.g., dioctyl sulfosuccinate) or all substances that increase viscoelasticity (e.g., hydroxypropyl guar polymer).
[0125] Suitable penetrants in the context of the present invention are all substances generally used to improve the penetration of pesticidal active compounds into plants. In this regard, penetrants are those that, from (generally aqueous) application solutions and / or from films applied by spraying, penetrate into the cuticle of plants. permeability, by which the mobility of the active compound within the cuticle can be enhanced is defined by. To confirm this property, the method described in the literature (Baur et al., 19 97, Pesticide Science 51, 131 - 152) can be used. Examples thereof include alcohol alkoxylates, such as coconut fatty ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters, such as rapeseed oil methyl ester or soybean oil methyl ester, fatty amine alkoxylates such as tallow amine ethoxylate (15), or ammonium salts and / or phosphonium salts, such as ammonium sulfate or diammonium hydrogen phosphate, etc. can be mentioned . The formulation preferably contains, based on the weight of the formulation, 0.00000001 wt% to 9 8 wt% of the compound represented by formula (I), or particularly preferably 0.01 wt
[0126] % to 95 wt% of the compound represented by formula (I), and more preferably 0.5 wt% to 90 wt% of the compound represented by formula (I).
[0127] The content of the compound represented by formula (I) in the use form prepared from the formulation (especially the pesticidal agent) can vary within a wide range. The concentration of the compound represented by formula (I) in the use form is generally 0.00000001 wt% to 95 wt% of the compound represented by formula (I), preferably 0.00001 wt% to 1 wt % of the compound represented by formula (I), based on the weight of the use form. The compound is prepared by conventional methods suitable for its use form Use.
[0128] Mixture The compounds of formula (I) may be used, for example, with a prolonged action in order to extend the spectrum of action. To increase the duration, speed of action, and repulsion To prevent the development of resistance to one or more suitable fungicides, Bactericides, acaricides, molluscicides, nematicides, insecticides, microbial agents ogicals), beneficial species, herbicides, fertilizers, bird repellents, plant enhancers (phytotoni c) In mixtures with sterilants, safeners, semiochemicals and / or plant growth regulators Moreover, such active compound combinations can be used to improve plant growth. and / or resistance to abiotic factors (e.g. high or low temperatures); Improving tolerance to drought or increased moisture content or soil salinity It is also possible to improve flowering and fruiting performance, and germination ability. It is also possible to optimize the strength and root development, and to facilitate harvesting, yielding It is possible to improve yield, influence maturity, and improve the quality of harvested It is also possible to improve the quality and / or nutritional value of the harvested produce. It may also increase the shelf life and / or improve the processability of the harvested produce. It is also possible to do so.
[0129] Additionally, the compounds of formula (I) may be used in combination with other active compounds or semiochemicals, e.g. attractants, and / or bird repellents, and / or plant activators, and / or growth regulators, It can also be present in a mixture with ( / or a fertilizer). Similarly, the compound represented by formula (I) can also be used to improve the characteristics of plants (such as growth, yield, and quality of the harvested product).
[0130] In a specific embodiment according to the present invention, the compound represented by formula (I) is present in a formulation or in a form of use prepared from such a formulation in a state mixed with a further compound (preferably a compound described below). If one of the compounds described below can exist in various tautomeric forms, those forms are also included in any case, even if not explicitly mentioned. Further, all co-formulants named can, if possible by their functional groups, also form salts with appropriate bases or acids in some cases.
[0131]
[0132] Insecticide / acaricide / nematicide The active compounds identified by their "common names" in this specification are known and, as such, are described, for example, in the Pesticide Handbook ("The Pesticide Manual" 16th Ed., British Crop Protection Council 2012) or can be found on the Internet (for example, "http: / / www.alanwood.net / pesticides"). Their classification is based on the latest "IRAC Mode of Action Classification Scheme" at the time of filing of this patent application.
[0133] (1) Acetylcholinesterase (AChE) inhibitors, preferably, carbamates, which are aldicarb, aldicarb sulfoxide, benfuracarb, benomyl, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, fosthiazate, isoprocarb, methiocarb, methomyl, methomyl oxime, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC, and xylylcarb; or, organophosphates, which are acephate, azamethiphos,azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos / DDVP, dichlorvos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, etoprophos, famphur, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl O-(methoxyaminothiophosphoryl) salicylate, isoxathion, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, parathion-methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos-methyl, profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos; selected from; or, selected from; Selected from binphos, thiometon, triazophos, trichlorfon and bamidothion .
[0134] (2) GABA-regulated chloride channel blockers, preferably cyclodiene-organochlorines, which are selected from chlordane and endosulfan ; or phenylpyrazole (fiprole), e.g., ethiprole and fipronil.
[0135] (3) Sodium channel modulators, preferably pyrethroids, which are selected from acrinathrin, allethrin, d-cis-trans allethr in, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin s- cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta -cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cyp ermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin , zeta-cypermethrin, fenothrin [(1R)-trans-isomer], delta methrin, empenthrin [(EZ)-(1R)-isomer], esfenvalerate, e tofenprox, fenpropathrin, fenvalerate, flucythrinate, flu methrin, tau-fluvalinate, halfenprox, imiprothrin, kadethrin , monofluorothrin, permethrin, fenothrin [(1R)-trans-isomer], prallethrin, pyrethrins (pyrethrum), resmethrin, silaflu ofen, tefluthrin, tetramethrin, tetramethrin [(1R)-isomer], t ralomethrin and transfluthrin; or DDT; or, methoxychlor.
[0136] (4) Nicotinic acetylcholine receptor (nAChR) competitive modulators, preferably, or, neonicotinoids, which are selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam; or , nicotine; or, sulfoxaflor, or, flupyradifurone.
[0137] (5) Nicotinic acetylcholine receptor (nAChR) allosteric modulators, preferably, or, spinosyns, which are selected from spinetoram and spinosad.
[0138] (6) Glutamate-gated chloride channel (GluCl) allosteric modulators, preferably, or, avermectin / milbemycin series, which are selected from abamectin, emamectin benzoate, lepimectin and milbemycin.
[0139] (7) Juvenile hormone mimics, preferably, juvenile hormone analogs, which are selected from hydroprene, kinoprene and methoprene; or, or, fenoxycarb; or, pyriproxyfen.
[0140] (8) Various unspecified (multi-site) inhibitors, preferably, alkyl halides, which are selected from methyl bromide and another alkyl halide; or, or, chloropicrin; or, sulfuryl fluoride; or, borax; or, tartar emetic; or, Methyl isocyanate product substances, which are selected from dazomet and metam. Selected from.
[0141] (9) Chordotonal organ TRPV channel modulators, which are selected from pimetrozine and pyrifluquinazon. Selected from.
[0142] (10) Mite growth inhibitors, which are selected from clofentezine, hexythiazox, diflovidazin and etoxazole. Selected from.
[0143] (11) Insect midgut microbial disruptors, which are selected from Bacillus thuringiensis subsp. israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bt plant proteins (which are selected from Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb and Cry34Ab1 / 35Ab1). Subspecies israelensis ecies israelensis), Bacillus sphaericus (Bacillus sphaericus), Bacillus thuringiensis subspecies aizawai (Baci llus thuringiensis subspecies aizawai), B acillus thuringiensis subspecies kurstaki (Bacillus thuringie nsis subspecies kurstaki), Bacillus thuringiensis Subspecies tenebrionis (Bacillus thuringiensis subspe cies tenebrionis) and Bt plant proteins (which are Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCr y3A, Cry3Ab, Cry3Bb and Cry34Ab1 / 35Ab1 selected from ) selected from.
[0144] (12) Inhibitors of mitochondrial ATP synthase, preferably An ATP disruptor, which is selected from diafenthiuron; or, An organotin compound, which is selected from azocyclotin, cyhexatin, and fenbutatin oxide ; or, Propargite; or, tetradifon.
[0145] (13) An uncoupler of oxidative phosphorylation by disrupting the proton gradient, which is selected from chlorfenapyr, DNOC, and sulfiram.
[0146] (14) A nicotinic acetylcholine receptor channel blocker, which is selected from bensultap, cartap hydrochloride, thiocylam, and thiosultap-sodium.
[0147] (15) An inhibitor of chitin biosynthesis (type 0), which is selected from bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, and triflumuron.
[0148] (16) An inhibitor of chitin biosynthesis (type 1), which is selected from buprofezin.
[0149] (17) An ecdysis disruptor (especially for Diptera, i.e., for dipterans), which is selected from silafluofen.
[0150] (18) An ecdysone receptor agonist, which is selected from chromafenozide, halofenozide, methoxyphenozide, and tebufenozide.
[0151] (19) An octopamine receptor agonist, which is selected from amitraz.
[0152] (20) A mitochondrial complex III electron transport inhibitor, which is selected from hydramethylnon, acequinocyl, and fluacrypyrim.
[0153] (21) A mitochondrial complex I electron transport inhibitor, preferably, a METI acaricide, which is selected from phenothrin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, and tolfenpyrad; or, rotenone (Derris).
[0154] (22) A voltage-dependent sodium channel blocker, which is selected from indoxacarb and me tifulmizon.
[0155] (23) An inhibitor of acetyl-CoA carboxylase, preferably, tetronic acid derivatives and tetramic acid derivatives, which are selected from spirodiclofen, spirome fen, and spirotetramat.
[0156] (24) A mitochondrial complex IV electron transport inhibitor, preferably, a phosphine-based one, which is selected from aluminum phosphide, calcium phosphide, phosphine, and zinc phosphide; or, cyanides, which are selected from calcium cyanide, potassium cyanide, and sodium cyanide ; and, selected from.
[0157] (25) A mitochondrial complex II electron transport inhibitor, preferably, β-ketonitrile derivatives, which are selected from cyenopyrafen and cyflumetofen ; and, Carboxyanilide-based, which is selected from piflubumide.
[0158] (28) Ryanodine receptor modulator, preferably, Diamide-based, which is selected from chlorantraniliprole, cyantraniliprole and flubendiamide.
[0159] (29) Chordotonal organ modulator (target site not defined), which is selected from flonicamid.
[0160] (30) Further active ingredients selected from the following: acinonapil, aphidipropen, afoxolaner, azadirachtin, benclothiaz, benzoximate, benzpyrimoxan, bifenazate, broflanilide, bromopropylate, chinomethionat, chloroprallethrin, cryolite, cyclaniliprole, cycloxaprid, cyhalodiamide, dichloromethothiaz, dichlorvos, ε-methofluthrin, ε-momfluthrin, flometokine, fluaazindrilin, fluensulfone, flufenoxuron, flufenoxystrobin, flufiprole, flufexahone, fluopyram, flupyrimin, fluralaner, fluxametamide, flufenoxido, guazipyr, heptafluthrin, imidaclothiz, iprodione, κ-bifenthrin, κ-tefluthrin, lotilaner, meperfluthrin, oxathiazinyl, paichongding, pyridalyl, pyrifluquinazon, pyriofenostrobin, spirobudiclofen, spiro Pidion, tetramethylfluthrin, tetraniliprole, tetrachlorantraniliprole, tigolaner, thioxazafen, thiofluoximate, triflumethoprim, and iodomethane; further, preparations based on Bacillus firmus (I-1582, BioNeem, Votivo), and further, the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO2006 / 043635) (CAS 885026-50-6), {1'-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 637360-23-7), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006 / 003494) (CAS 872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]deca-3-en-2-one (known from WO2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]deca-3-en-4-yl ethyl carbonate (known from EP2647626) -role, thiofluoximate, triflumethoprim, and iodomethane; and further, preparations based on Bacillus firmus (I-1582, BioNeem, Votivo), and further, the following compounds: 1-{2 -fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO2006 / 043635) (CAS 885026-50-6), {1' -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro -[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 6373 -fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO2006 / 043635) (CAS 885026-50-6), {1' -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro (indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 6373 -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro -[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 6373 -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro -[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 6373 -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro -[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 6373 -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro -[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 6373 -[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro -[indole-3,4'-piperidine]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 6373 -[4.5]deca-3-en-4-yl ethyl carbonate (known from EP2647626) known (CAS 1440516-42-6), 4-(but-2-yn-1-yloxy) -6-(3,5-dimethylpiperidin-1-yl)-5-fluoropyrimidine (known from WO20 04 / 099160) (CAS 792914-58-0), PF1364 (J known from P2010 / 018586) (CAS 1204776-60-2), (3E) -3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1, 1,1-trifluoro-propan-2-one (known from WO2013 / 144213) (CA S 1461743-15-6), N-[3-(benzylcarbamoyl)-4-chlorop henyl]-1-methyl-3-(pentafluoroethyl)-4-(trifluoromethyl)- 1H-pyrazole-5-carboxamide (known from WO2010 / 051926) (CA S 1226889-14-0), 5-bromo-4-chloro-N-[4-chloro-2-me thyl-6-(methylcarbamoyl)phenyl]-2-(3-chloro-2-pyridyl)pyr azole-3-carboxamide (known from CN103232431) (CAS 14492 20-44-3), 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5- (trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-ox ido-3-thietanyl)benzamide, 4-[5-(3,5-dichlorophenyl)-4, 5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N -(trans-1-oxide-3-thietanyl)benzamide and 4-[(5S)-5- (3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3- Isooxazolyl]-2-methyl-N-(cis-1-oxide-3-thietanyl)benz amide (known from WO2013 / 050317A1) (CAS 1332628-83- 7), N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N -ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propanamide , (+)-N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl] -N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]propan- amide and (-)-N-[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4- yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]pro- panamide (known from WO2013 / 162715A2, WO2013 / 162716A2, US 2014 / 0213448A1) (CAS 1477923-37-7), 5- [[(2E)-3-chloro-2-propen-1-yl]amino]-1-[2,6-dichloro ro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfini yl]-1H-pyrazole-3-carbonitrile (known from CN101337937A) ( CAS 1105672-77-2), 3-bromo-N-[4-chloro-2-methyl-6 -[(methylamino)thioxomethyl]phenyl]-1-(3-chloro-2-pyridinyl -1H-pyrazole-5-carboxamide, (Liudaibenjiaxuanan known from CN103109816A) (CAS 1232543-85-9); N- 4-chloro-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylf enyl]-1-(3-chloro-2-pyridinyl)-3-(fluoromethoxy)-1H-pi Lazorole-5-carboxamide (known from WO2012 / 034403A1) (CAS 1268277-22-0), N-[2-(5-amino-1,3,4-thiadiazol- 2-yl)-4-chloro-6-methylphenyl]-3-bromo-1-(3-chloro-2- pyridinyl)-1H-pyrazole-5-carboxamide (known from WO2011 / 085575A 1) (CAS 1233882-22-8), 4-[3-[2,6-dichloro- 4-[(3,3-dichloro-2-propen-1-yl)oxy]phenoxy]propoxy -2-methoxy-6-(trifluoromethyl)pyrimidine (known from CN101337940A )(CAS 1108184-52-6); (2E)- and 2(Z)-2-[2 -(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene] -N-[4-(difluoromethoxy)phenyl]hydrazinecarboxamide (known from CN101 715774A) (CAS 1232543-85-9); 3-(2,2-dic hloroethenyl)-2,2-dimethyl-4-(1H-benzimidazol-2-yl)phen yl-cyclopropanecarboxylic acid ester (known from CN103524422A) (CA S 1542271-46-4); (4aS)-7-chloro-2,5-dihydro-2- [(methoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl]amino]ca rbonyl]indeno[1,2-e][1,3,4]oxadiazin-4a(3H)-car boxylic acid methyl ester (known from CN102391261A) (CAS 1370358 -69-2); 6-deoxy-3-O-ethyl-2,4-di-O-methyl-,1-[N- [4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]-1H -1,2,4-triazol-3-yl]phenyl]carbamate]-α-L-mannopy ranose (known from US2014 / 0275503A1) (CAS 1181213-1 4-8); 8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy) -3-(6-trifluoromethyl-pyridazin-3-yl)-3-aza-bicyclo[3. 2.1]octane (CAS 1253850-56-4), (8-anti)-8-(2- cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-triflu oromethyl-pyridazin-3-yl)-3-aza-bicyclo[3.2.1]octane (C AS 933798-27-7), (8-syn)-8-(2-cyclopropylmethoxy- 4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl-pyridazin- 3-yl)-3-aza-bicyclo[3.2.1]octane (WO2007040280A 1, WO2007040282A1 known) (CAS 934001-66-8), N -[3-chloro-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl -3-[(3,3,3-trifluoropropyl)thio]-propanamide (WO2015 / 058021A1, WO2015 / 058028A1 known) (CAS 14779 19-27-9), and, N-[4-(aminothioxomethyl)-2-methyl-6-[( methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridini yl)-1H-pyrazole-5-carboxamide (known from CN103265527A) ( CAS 1452877-50-7), 5-(1,3-dioxan-2-yl)-4- [4-(Trifluoromethyl)phenyl]methoxy]-pyrimidine (known from WO2013 / 11 5391A1) (CAS 1449021-97-9), 3-(4-chloro-2 ,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[4.5 decane-2,4-dione (known from WO2014 / 187846A1) (CAS 16 38765-58-8), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy -1-methyl-2-oxo-1,8-diazaspiro[4.5]deca-3-en-4-yl -carboxylic acid ethyl ester (known from WO2010 / 066780A1, WO2011151 146A1) (CAS 1229023-00-0), 4-[(5S)-5-( 3,5-dichloro-4-fluorophenyl)-4,5-dihydro-5-(trifluorometh yl)-3-isoxazolyl]-N-[(4R)-2-ethyl-3-oxo-4-is oxazolidinyl]-2-methyl-benzamide (known from WO2011 / 067272, WO2 013 / 050302) (CAS 1309959-62-3).
[0161] Fungicide The active ingredients specified by the "common name" in this specification are known and are described, for example, in "The Pesticide Manual (16th Ed.Bri tish Crop Protection Council)" or can be searched on the Internet (e.g., "www.alanwood. net / pesticides").
[0162] All fungicidal mixing partners listed by name in classes (1)-(15) are their Depending on the functional group, it may also be possible to form salts with suitable bases or acids, if appropriate. All of the co-formers named in classes (1) to (15) may, where appropriate, include tautomeric forms.
[0163] (1) Inhibitors of ergosterol biosynthesis, for example, (1.001) cyproconazole , (1.002) difenoconazole, (1.003) epoxiconazole, (1.00 4) fenhexamid, (1.005) fenpropimorph, (1.006) fenpropidin morph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1. 009) flutriafol, (1.010) imazalil, (1.011) imazalil sulfate , (1.012) ipconazole, (1.013) metconazole, (1.014) myclo butanyl, (1.015) paclobutrazol, (1.016) procraz, (1. 017) propiconazole, (1.018) prothioconazole, (1.019) pyrithio xazole, (1.020) spiroxamine, (1.021) tebuconazole, (1.0 22) tetraconazole, (1.023) triadimenol, (1.024) tridemorph , (1.025) triticonazole, (1.026) (1R,2S,5S)-5-(4 -chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-tri azol-1-ylmethyl)cyclopentanol, (1.027) (1S,2R,5R )-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1 ,2,4-triazol-1-ylmethyl)cyclopentanol, (1.028) (2R )-2-(1-Chlorocyclopropyl)-4-[(1R)-2,2-dichlorocycloprop yl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1 .029)(2R)-2-(1-Chlorocyclopropyl)-4-[(1S)-2,2-di chlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan- 2-ol, (1.030)(2R)-2-[4-(4-Chlorophenoxy)-2-(tr ifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)pro pan-2-ol, (1.031)(2S)-2-(1-Chlorocyclopropyl)-4 -[(1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triaz ol-1-yl)butan-2-ol, (1.032)(2S)-2-(1-Chlorocyclopr opyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1, 2,4-triazol-1-yl)butan-2-ol, (1.033)(2S)-2- [4-(4-Chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H -1,2,4-triazol-1-yl)propan-2-ol, (1.034)(R) -[3-(4-Chloro-2-fluorophenyl)-5-(2,4-difluorophenyl) -1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.035 )(S)-[3-(4-Chloro-2-fluorophenyl)-5-(2,4-difluorop enyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1 .036)[3-(4-Chloro-2-fluorophenyl)-5-(2,4-difluorop enyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1 .037) 1 - ({(2R,4S)-2 - [2 - chloro - 4 - (4 - chlorophenoxy) phenyl] - 4 - methyl - 1,3 - dioxolan - 2 - yl}methyl) - 1H - 1,2, 4 - triazole, (1.038) 1 - ({(2S,4S)-2 - [2 - chloro - 4 - ( 4 - chlorophenoxy)phenyl] - 4 - methyl - 1,3 - dioxolan - 2 - yl}me thyl) - 1H - 1,2,4 - triazole, (1.039) 1 - {[3 - (2 - chloroph enyl) - 2 - (2,4 - difluorophenyl)oxolan - 2 - yl]methyl} - 1H - 1,2,4 - triazole - 5 - yl thiocyanate, (1.040) 1 - {[rel (2R,3R) - 3 - (2 - chlorophenyl) - 2 - (2,4 - difluorophenyl) o xylan - 2 - yl]methyl} - 1H - 1,2,4 - triazole - 5 - yl thiocyan ate, (1.041) 1 - {[rel(2R,3S) - 3 - (2 - chlorophenyl) - 2 - (2,4 - difluorophenyl)oxolan - 2 - yl]methyl} - 1H - 1,2,4 - triazole - 5 - yl thiocyanate, (1.042) 2 - [(2R,4R,5R) - 1 - (2,4 - dichlorophenyl) - 5 - hydroxy - 2,6,6 - trimethylhep tan - 4 - yl] - 2,4 - dihydro - 3H - 1,2,4 - triazole - 3 - thione, ([[]] 1.043) 2 - [(2R,4R,5S) - 1 - (2,4 - dichlorophenyl) - 5 - h droxy - 2,6,6 - trimethylheptane - 4 - yl] - 2,4 - dihydro - 3H - 1 ,2,4 - triazole - 3 - thione, (1.044) 2 - [(2R,4S,5R) - 1 - (2,4 - dichlorophenyl) - 5 - hydroxy - 2,6,6 - trimethylheptane - 4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1. 045)2-[(2R,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy -2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2 ,4-triazole-3-thione, (1.046)2-[(2S,4R,5R)-1-( 2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4- yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.04 7)2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy -2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4 -triazole-3-thione, (1.048)2-[(2S,4S,5R)-1-(2, 4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl -2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049) 2-[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2 ,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-1,2,4-tri azole-3-thione, (1.050)2-[1-(2,4-dichlorophenyl)-5 -hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H -1,2,4-triazole-3-thione, (1.051)2-[2-chloro-4-(2 ,4-dichlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1- yl)propan-2-ol, (1.052)2-[2-chloro-4-(4-chlorophen oxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2- All, (1.053) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl) phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.054) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl) phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol , (1.055) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)p henyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.056) 2-{[3-(2-chlorophenyl)-2-(2,4-difluorophen yl)oxirane-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triaz ole-3-thione, (1.057) 2-{[rel(2R,3R)-3-(2-chlorop henyl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-2, 4-dihydro-3H-1,2,4-triazole-3-thione, (1.058) 2-{ rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophen yl)oxirane-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triaz ole-3-thione, (1.059) 5-(4-chlorobenzyl)-2-(chloromethyl) -2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopenta nol, (1.060) 5-(allylsulfanyl)-1-{[3-(2-chlorophen yl)-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1 ,2,4-triazole, (1.061) 5-(allylsulfanyl)-1-{[rel ,2,4-triazole (2R,3R)-3-(2-Chlorophenyl)-2-(2,4-difluorophenyl)oxiranyl methyl}-1H-1,2,4-triazole, (1.062) 5- (allylsulfanyl)-1-{[rel(2R,3S)-3-(2-chlorophenyl) -2-(2,4-difluorophenyl)oxiranyl-2-yl]methyl}-1H-1,2 ,4-triazole, (1.063) N'-(2,5-dimethyl-4-{[3-(1,1 ,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl -N-methylformimidamide, (1.064) N'-(2,5-dimethyl-4-{ 3-(2,2,2-trifluoroethoxy)phenyl]sulfanyl}phenyl)-N- ethyl-N-methylformimidamide, (1.065) N'-(2,5-dimethyl-4 -{[3-(2,2,3,3-tetrafluoropropoxy)phenyl]sulfanyl}ph enyl)-N-ethyl-N-methylformimidamide, (1.066) N'-(2,5 -dimethyl-4-{[3-(pentafluoroethoxy)phenyl]sulfanyl}pheni l)-N-ethyl-N-methylformimidamide, (1.067) N'-(2,5-di methyl-4-{3-[(1,1,2,2-tetrafluoroethyl)sulfanyl]pheno xy}phenyl)-N-ethyl-N-methylformimidamide, (1.068) N'- (2,5-dimethyl-4-{3-[(2,2,2-trifluoroethyl)sulfanyl] phenoxy}phenyl)-N-ethyl-N-methylformimidamide, (1.069) N'-(2,5-dimethyl-4-{3-[(2,2,3,3-tetrafluoropropyl) sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylformimidamide, (1.070) N'-(2,5-Dimethyl-4-{3-[(pentafluoroethyl)sulf anyl]phenoxy}phenyl)-N-ethyl-N-methylimidohydroxamic acid, (1 .071) N'-(2,5-Dimethyl-4-phenoxyphenyl)-N-ethyl-N-meth ylimidohydroxamic acid, (1.072) N'-(4-{[3-(difluoromethoxy) phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N-methylimi dohydroxamic acid, (1.073) N'-(4-{3-[(difluoromethyl)sulfani l]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidohydrox amic acid, (1.074) N'-[5-Bromo-6-(2,3-dihydro-1H-inden -2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylimi dohydroxamic acid, (1.075) N'-{4-[(4,5-Dichloro-1,3-thiazol -2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylimidoh olumic acid, (1.076) N'-{5-Bromo-6-[(1R)-1-(3,5-dif luorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-meth ylimidohydroxamic acid, (1.077) N'-{5-Bromo-6-[(1S)-1-(3 ,5-Difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl -N-methylimidohydroxamic acid, (1.078) N'-{5-Bromo-6-[(cis- 4-Isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-e thyl-N-methylimidohydroxamic acid, (1.079) N'-{5-Bromo-6-[(t {[1-(3,5-Diisopropylcyclohexyl)oxy]-2-methylpyridin-3-yl} -N-ethyl-N-methylimidohydroxamic acid, (1.080) N’-{5-bromo-6 - [1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}- N-ethyl-N-methylimidohydroxamic acid, (1.081) mefentrifluconazole (mefentrifluconazole), (1.082) ipfentrifluconazole .
[0164] (2) Inhibitors of the respiratory chain in Complex I or Complex II, for example, (2.001) benzo[b]difluopyr, (2.002) bixafen, (2.003) boscalid, (2. 004) carboxin, (2.005) fluopyram, (2.006) flutolanil, ([[]] 2.007) fluxapyroxad, (2.008) flutriafol, (2.009) isofetamid, (2.010) isopyrazam (anti-epimeric enantiomer 1R,4 S,9S), (2.011) isopyrazam (anti-epimeric enantiomer 1S, 4R,9R), (2.012) isopyrazam (anti-epimeric racemate 1RS ,4SR,9SR), (2.013) isopyrazam (syn-epimeric racemate (1 RS,4SR,9RS) and anti-epimeric racemate (1RS,4SR,9SR) mixture), (2.014) isopyrazam (syn-epimeric enantiomer 1R,4 S,9R), (2.015) isopyrazam (syn-epimeric enantiomer 1S,4 R,9S), (2.016) isopyrazam (syn-epimeric racemate 1RS,4 R,9RS), (2.017) isopyrazam (syn-epimeric racemate 1RS,4 R,9SR) and anti-epimeric racemate (1RS,4SR,9SR) (SR,9RS), (2.017) penflufen, (2.018) penthiopyrad, (2 .019) pydiflumetofen, (2.020) pyracloforumide, (2.021) sedaxane , (2.022) 1,3 - dimethyl - N - (1,1,3 - trimethyl - 2,3 - dihydro - 1H - inden - 4 - yl) - 1H - pyrazole - 4 - carboxamide, (2.0 23) 1,3 - dimethyl - N - [(3R) - 1,1,3 - trimethyl - 2,3 - dihydro - 1H - inden - 4 - yl] - 1H - pyrazole - 4 - carboxamide, (2.024 ) 1,3 - dimethyl - N - [(3S) - 1,1,3 - trimethyl - 2,3 - dihydro - 1 H - inden - 4 - yl] - 1H - pyrazole - 4 - carboxamide, (2.025) 1 - methyl - 3 - (trifluoromethyl) - N - [2’ - (trifluoromethyl)biphenyl yl - 2 - yl] - 1H - pyrazole - 4 - carboxamide, (2.026) 2 - fluoro - 6 - (trifluoromethyl) - N - (1,1,3 - trimethyl - 2,3 - dihydro - 1 H - inden - 4 - yl)benzamide, (2.027) 3 - (difluoromethyl) - 1 - methyl - N - (1,1,3 - trimethyl - 2,3 - dihydro - 1H - inden - 4 - yl yl) - 1H - pyrazole - 4 - carboxamide, (2.028) 3 - (difluoromethyl ) - 1 - methyl - N - [(3R) - 1,1,3 - trimethyl - 2,3 - dihydro - 1H - inden - 4 - yl] - 1H - pyrazole - 4 - carboxamide, (2.029) 3 - ( difluoromethyl) - 1 - methyl - N - [(3S) - 1,1,3 - trimethyl - 2,3 - dihydro - 1H - inden - 4 - yl] - 1H - pyrazole - 4 - carboxamide, (2 .030) 3 - (difluoromethyl) - N - (7 - fluoro - 1,1,3 - trimethyl - (2,3-Dihydro-1H-inden-4-yl)-1-methyl-1H-pyrazole-4- carboxamide, (2.031) 3-(Difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1- methyl-1H-pyrazole-4-carboxamide, (2.032) 3-(Difluoromethyl)-N-[(3S)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1- H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.033) 5,8-Difluoro-N-[2-(2-fluoro-4-{[4-(trifluoro methyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amine, (2.034) N-(2-Cyclopentyl-5-fluorobenzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-ca rboxamide, (2.035) N-(2-tert-Butyl-5-methylbenzyl)-N- cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.036) N-(2-tert-Butylbenzyl)- N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyra zole-4-carboxamide, (2.037) N-(5-Chloro-2-ethylbenzyl )-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H- pyrazole-4-carboxamide, (2.038) N-(5-Chloro-2-isopropyl benzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H- pyrazole-4-carboxamide, (2.039) N-(5-Chloro-2-isopropyl benzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H- pyrazole-4-carboxamide, (2.040) N-(5-Chloro-2-isopropyl benzyl)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H- pyrazole-4-carboxamide, (2.041) N-(5-Chloro-2-isopropyl Chir-1H-pyrazole-4-carboxamide, (2.039) N-[(1R,4S)- 9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalene -5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carbo xamide, (2.040) N-[(1S,4R)-9-(dichloromethylene)-1,2, 3,4-tetrahydro-1,4-methanonaphthalene-5-yl]-3-(difluorometh yl)-1-methyl-1H-pyrazole-4-carboxamide, (2.041) N-[1- (2,4-dichlorophenyl)-1-methoxypropan-2-yl]-3-(difluoro methyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.042) N- 2-chloro-6-(trifluoromethyl)benzyl]-N-cyclopropyl-3-(dif luoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.043) N-[3-chloro-2-fluoro-6-(trifluoromethyl)benzyl -N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H -pyrazole-4-carboxamide, (2.044) N-[5-chloro-2-(trif luoromethyl)benzyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro ro-1-methyl-1H-pyrazole-4-carboxamide, (2.045) N-cyclop ropyl-3-(difluoromethyl)-5-fluoro-1-methyl-N-[5-methyl-2 -(trifluoromethyl)benzyl]-1H-pyrazole-4-carboxamide, (2. 046) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-f luoro-6-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxa Mid, (2.047) N - Cyclopropyl - 3 - (difluoromethyl) - 5 - fluoro - N - (2 - Isopropyl - 5 - methylbenzyl) - 1 - methyl - 1H - pyrazole - 4 - carboxamide, (2.048) N - Cyclopropyl - 3 - (difluoromethyl) - 5 - fluoro - N - (2 - isopropylbenzyl) - 1 - methyl - 1H - pyrazole - 4 - ca rbothioamide, (2.049) N - Cyclopropyl - 3 - (difluoromethyl) - 5 - fluoro - N - (2 - isopropylbenzyl) - 1 - methyl - 1H - pyrazole - 4 - ca rboxamide, (2.050) N - Cyclopropyl - 3 - (difluoromethyl) - 5 - f luoro - N - (5 - fluoro - 2 - isopropylbenzyl) - 1 - methyl - 1H - pyraz ole - 4 - carboxamide, (2.051) N - Cyclopropyl - 3 - (difluorometh yl) - N - (2 - ethyl - 4,5 - dimethylbenzyl) - 5 - fluoro - 1 - methyl - 1 H - pyrazole - 4 - carboxamide, (2.052) N - Cyclopropyl - 3 - (dif luoromethyl) - N - (2 - ethyl - 5 - fluorobenzyl) - 5 - fluoro - 1 - meth yl - 1H - pyrazole - 4 - carboxamide, (2.053) N - Cyclopropyl - 3 - (difluoromethyl) - N - (2 - ethyl - 5 - methylbenzyl) - 5 - fluoro - 1 - methyl - 1H - pyrazole - 4 - carboxamide, (2.054) N - Cyclopropyl - N - (2 - cyclopropyl - 5 - fluorobenzyl) - 3 - (difluoromethyl) - 5 - fluoro - 1 - methyl - 1H - pyrazole - 4 - carboxamide, (2.055) N - s cyclopropyl - N - (2 - cyclopropyl - 5 - methylbenzyl) - 3 - (difluorometh (2.0) N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide (56) N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl )-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide.
[0165] (3) Inhibitors of the respiratory chain in Complex III, for example, (3.001) ametoctradin , (3.002) amisulbrom, (3.003) azoxystrobin, (3.00 4) coumethoxystrobin, (3.005) kresoxim-methyl , (3.006) cymoxanil, (3.007) dimoxystrobin , (3.008) enoxastrobin, (3.009) famoxadone, (3.010) fenamidone, (3.011) flufenoxystrobin , (3.012) fluoxastrobin, (3.013) kresoxim-methyl , (3.014) metominostrobin, (3.015) orysastrobin, (3.01 6) picoxystrobin, (3.017) pyraclostrobin, (3.018) pyrametostrobin , (3.019) pyraoxystrobin, (3.020) trifloxystrobin , (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)- 1-fluoro-2-phenylvinyl]oxy}phenyl)ethylidene]amino}oxy) methyl]phenyl}-2-(methoxyimino)-N-methylacetamide, (3.022 )(2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3 .023)(2R)-2-{2-[(2,5-Dimethylphenoxy)methyl]phenyl} -2-methoxy-N-methylacetamide, (3.024)(2S)-2-{2-[(2 ,5-Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetam ide, (3.025)(3S,6S,7R,8R)-8-Benzyl-3-[({3-[(I sobutyryloxy)methoxy]-4-methoxypyridin-2-yl}carbonyl)amino -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl 2-methylpro panoate, (3.026)2-{2-[(2,5-Dimethylphenoxy)methyl]phe nyl}-2-methoxy-N-methylacetamide, (3.027)N-(3-Ethyl-3 ,5,5-Trimethylcyclohexyl)-3-formamido-2-hydroxybenzam ide, (3.028)(2E,3Z)-5-{[1-(4-Chloro-2-fluorophenyl )-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethyl lpent-3-enamide, (3.029){5-[3-(2,4-Dimethylphenyl) -1H-pyrazol-1-yl]-2-methylbenzyl}carbamic acid methyl.
[0166] (4) Inhibitors of mitosis and cell division, for example, (4.001) Carbendazim, ( 4.002) Diethofencarb, (4.003) Etaboxam, (4.004) Flu picolide, (4.005) Pencycuron, (4.006) Thiabendazole, (4.00 7) Thiram, (4.008) Zoxamide, (4.009) 3-Chloro- 4-(2,6-Difluorophenyl)-6-methyl-5-phenylpyridazine, (4.0 10) 3-Chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl) -6-methylpyridazine, (4.011) 3-chloro-5-(6-chloropyridin-3- yl)-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.0 12) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl )-1,3-dimethyl-1H-pyrazole-5-amine, (4.013) 4-(2-bro mo-4-fluorophenyl)-N-(2-bromo-6-fluorophenyl)-1,3-di methyl-1H-pyrazole-5-amine, (4.014) 4-(2-bromo-4-flu rophenyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazole-5 -amine, (4.015) 4-(2-bromo-4-fluorophenyl)-N-(2-chlo ro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4 .016) 4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)- 1,3-dimethyl-1H-pyrazole-5-amine, (4.017) 4-(2-bromo- 4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-py razole-5-amine, (4.018) 4-(2-chloro-4-fluorophenyl)-N -(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine , (4.019) 4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6- fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, (4.020 ) 4-(2-chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3- dimethyl-1H-pyrazole-5-amine, (4.021) 4-(2-chloro-4-flu Orophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazole -5-amine, (4.022) 4-(4-chlorophenyl)-5-(2,6-difluoro phenyl)-3,6-dimethylpyridazine, (4.023) N-(2-bromo-6-flu orophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H -pyrazole-5-amine, (4.024) N-(2-bromophenyl)-4-(2-ch loro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine, ([[]] (4.025) N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4 -fluorophenyl)-1,3-dimethyl-1H-pyrazole-5-amine.
[0167] (5) Compounds that can act on multiple sites, for example, (5.001) Bordeaux mixture, (5. 002) Captan, (5.003) Captan, (5.004) Chlorothalonil, ( 5.005) Copper hydroxide, (5.006) Copper naphthenate, (5.007) Copper oxide, (5.0 08) Basic copper chloride, (5.009) Copper sulfate (2+), (5.010) Dithianon, (5 .011) Dodine, (5.012) Folpet, (5.013) Mancozeb, (5.014 ) Maneb, (5.015) Metiram, (5.016) Metiram zinc (metiram zinc), (5.017) Copper oxine, (5.018) Propineb, (5.019) Sulf ur and sulfur agents, for example, calcium polysulfide, (5.020) Thiuram, (5.021) Di neb, (5.022) Dithiram, (5.023) 6-Ethyl-5,7-dioxo-6,7- dihydro-5H-pyrrolo[3’,4’:5,6][1,4]dithieno[2,3-c][1 ,2]Thiazole-3-carbonitrile.
[0168] (6) Compounds capable of inducing the host's defense, for example, (6.001) acibenzolar-S -methyl, (6.002) isothianyl, (6.003) probenazole, (6.004 ) thiazinyl.
[0169] (7) Inhibitors of the biosynthesis of amino acids and / or proteins, for example, (7.001) cy prodinyl, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate substance, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.00 6) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin -1-yl) quinoline.
[0170] (8) Inhibitors of ATP production, for example, (8.001) silthiopham.
[0171] (9) Inhibitors of cell wall synthesis, for example, (9.001) benalaxyl-M, (9.0 02) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, ([ 9.005) mandipropamid, (9.006) pyrimorph, ([ 9.007) valifenalate, (9.008) (2E)-3-(4-tert-butyl phenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl) p rop-2-en-1-one, (9.009) (2Z)-3-(4-tert-butylphen yl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl) propa -2-en-1-one.
[0172] (10) Inhibitors of lipid and membrane synthesis, for example, (10.001) propamocarb, ( 10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl.
[0173] (11) Inhibitors of melanin biosynthesis, for example, (11.001) tricyclazole, ( 11.002) 2,2,2-trifluoroethyl {3-methyl-1-[(4-methylbenz oyl)amino]butan-2-yl} carbamate.
[0174] (12) Inhibitors of nucleic acid synthesis, for example, (12.001) benalaxyl, (12.00 2) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.00 4) metalaxyl-M (mefenoxam).
[0175] (13) Inhibitors of signal transduction, for example, (13.001) fluazinam, (1 3.002) iprodione, (13.003) procymidone, (13.004) procina zide, (13.005) quinoxyfen, (13.006) vinclozolin.
[0176] (14) Compounds that can act as uncouplers, for example, (14.001) fluazinam , (14.002) meptyldinocap.
[0177] (15) Further compounds, for example, (15.001) abscisic acid, (15.002 ) benzothiazole, (15.003) benzoxazine, (15.004) capsimycin ( capsimycin), (15.005) carvone, (15.006) quinomethionate , (15.007) kresoxim-methyl, (15.008) cyflufenamid, (15.009 ) cymoxanil, (15.010) cyprosulfamide, (15.011) flutianil , (15.012) fosetyl-aluminum, (15.013) fosetyl-calcium, (15.014) fosetyl-sodium, (15.015) methyl isothiocyanate, ( 15.016) metrafenone, (15.017) milbemycin, (15.018 ) natamycin, (15.019) nickel dimethyldithiocarbamate, (15.02 0) nitrothal-isopropyl, (15.021) oxamocarb (oxamocarb ), (15.022) oxathiapiprolin, (15.023) oxyfenthiin (o xyfenthiin), (15.024) pentachlorophenol and salts, (15.0 25) phosphorous acid and its salts, (15.026) propamocarb-fosetylate (prop amocarb-fosetylate), (15.027) pyriofenone (chlazafenone enone)), (15.028) tebufloquin, (15.02 9) tecnazene, (15.030) tolfenpyrad, (15.031) 1-(4-{ 4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxa zole-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2 -[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone , (15.032) 1-(4-{4-[(5S)-5-(2,6-difluorophenyl) -4,5-dihydro-1,2-oxazole-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2 -[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.033) 2-(6-benzylpyridin-2-yl -2-yl)ethanone, (15.034) 2-(6-benzylpyridin-2-yl (15.034) 2,6 - dimethyl - 1H,5H - [1,4]dithiino[2,3 - c:5,6 - c']dipyrrole - 1,3,5,7(2H,6H) - tetrone 、(15.035) 2 - [3,5 - bis(difluoromethyl) - 1H - pyrazol - 1 - yl] - 1 - [4 - (4 - {5 - [2 - (prop - 2 - yn - 1 - yloxy)phenyl -4,5 - dihydro - 1,2 - oxazol - 3 - yl}-1,3 - thiazol - 2 - yl)piperidin - 1 - yl]ethanone 、(15.036) 2 - [3,5 - bis(difluoromethyl) - 1H - pyrazol - 1 - yl] - 1 - [4 - (4 - {5 - [2 - chloro - 6 - (prop - 2 - yn - 1 - yloxy)phenyl]-4,5 - dihydro - 1,2 - oxazol - 3 - yl}-1,3 - thiazol - 2 - yl)piperidin - 1 - yl]ethanone 、(15.037) 2 - [3,5 - bis(difluoromethyl) - 1H - pyrazol - 1 - yl] - 1 - [4 - (4 - {5 - [2 - fluoro - 6 - (prop - 2 - yn - 1 - yloxy)phenyl]-4,5 - dihydro - 1,2 - oxazol - 3 - yl}-1,3 - thiazol - 2 - yl)piperidin - 1 - yl]ethanone 、(15.038) 2 - [6 - (3 - fluoro - 4 - methoxyphenyl) - 5 - methylpyridin - 2 - yl]quinazoline 、(15.039) 2 - {(5R) - 3 - [2 - (1 - {[3,5 - bis(difluoromethyl) - 1H - pyrazol - 1 - yl]acetyl}piperidin - 4 - yl)-1,3 - thiazol - 4 - yl]-4,5 - dihydro - 1,2 - oxazol - 5 - yl}-3 - chlorophenyl methanesulfonate 、(15.040) 2 - {(5S) - 3 - [2 - ([1 - {[3,5 - bis(difluoromethyl) - 1H - pyrazol - 1 - yl]acetyl} (piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2 -oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.04 1) 2-{2-[(7,8-difluoro-2-methylquinolin-3-yl)oxy]-6 -fluorophenyl}propan-2-ol, (15.04 2) 2-{2-fluoro-6 -[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propan-2 -ol, (15.04 3) 2-{3-[2-(1-{[3,5-bis(difluoromethyl l)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thia zol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chloro phenyl methanesulfonate, (15.04 4) 2-{3-[2-(1-{[3,5 -bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4 -yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazole -5-yl}phenyl methanesulfonate, (15.04 5) 2-phenylphenol and salts, (15.04 6) 3-(4,4,5-trifluoro-3,3-dimethyl-3,4 -dihydroisoquinolin-1-yl)quinoline, (15.04 7) 3-(4,4-diflu oro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15 .04 8) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-am ino-5-fluoropyrimidin-2(1H)-one), (15.04 9) 4-oxo-4- [(2-phenylethyl)amino]butanoic acid, (15.05 0) 5-amino-1,3,4 -Thiadiazole-2-thiol, (15.051) 5-chloro-N'-phenyl-N' -(prop-2-yn-1-yl)thiophene 2-sulfonohydrazide, (15.05 2) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.053) 5-fluoro-2-[(4-methylbenzyl)oxy]pyrimidin-4 -amine, (15.054) 9-fluoro-2,2-dimethyl-5-(quinolin-3-yl yl)-2,3-dihydro-1,4-benzoxazepine, (15.055) but-3-yn-1 -yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)( phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, ( (15.056) (2Z)-3-amino-2-cyano-3-phenylacrylic acid ethyl ester, ( (15.057) phenazine-1-carboxylic acid, (15.058) 3,4,5-trihydro xybenzoic acid propyl, (15.059) quinolin-8-ol, (15.060) quin olin-8-ol sulfate (2:1), (15.061) {6-[({[(1-methyl -1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl] pyridin-2-yl}carbamic acid tert-butyl, (15.062) 5-fluoro- 4-imino-3-methyl-1-[(4-methylphenyl)sulfonyl]-3,4-dihydro ropyrimidin-2(1H)-one.
[0178] Biological pest control agent as a mixing component The compound represented by formula (I) can be combined with a biological pest control agent.
[0179] Biological pest control agents include, in particular, bacteria, fungi, yeasts, plant extracts and those produced by microorganisms The product formed thereby (e.g., protein and secondary metabolite) is included.
[0180] Biological pest control agents include bacteria, such as spore-forming bacteria, bacteria that form colonies on roots, and bacteria that act as biological insecticides, fungicides or nematicides.
[0181] Examples of the above-mentioned bacteria that are used or can be used as biological pest control agents are as follows: Bacillus amyloliquefaciens strain FZB42 (DSM 231179), or Bacillus cereus, in particular, Bacillus cereus strain CNCM I-1562, or Bacillus firmus strain I-1582 (deposit number CNCM I-1582), or Bacillus pumilus, in particular, strain GB34 (deposit number ATCC 7008 14) and strain QST2808 (deposit number NRRL B-30087), or Bacillus subtilis, in particular, strain GB03 (deposit number ATCC SD-1397), or Bacillus subtilis strain QST713 (deposit number NRRL B-21661), or Bacillus subtilis strain OST 30002 (deposit number NRRL B-50421), Bacillus thuringiensis, in particular, Bacillus thuringiensis subsp. israelensis B. thuringiensis subspecies israelensi (s) (serotype H-14) strain AM65-52 (deposit number ATCC 1276), or Bacillus thuringiensis subsp. aizawai (B. thuringiensis subsp. aizawai), particularly strain ABTS-1857 (SD-1372), or Bacillus thuringiensis subsp. kurstaki (B. thuringiensi s subsp. kurstaki) strain HD-1, or Bacillus thuringiensis subsp. tenebrionis (B. thuringiensis subsp. tene brionis) strain NB 176 (SD-5428), Pasteuria penetrans (P asteuria penetrans), Pasteuria spp. (Pasteuria s pp.) (Rotylenchulus reniformis nematode)-PR3 (deposit number ATCC SD-5834), Streptomyces · microflavus strain AQ612 1 (= QRD 31.013, NRRL B-50550), Streptomyces gal bus strain AQ 6047 (deposit number NRR L 30232).
[0182] Examples of fungi and yeasts that are used or can be used as biological pesticides against pests are as follows: Beauveria bassiana, particularly strain ATCC 74040, Coniothyrium minitans (Coniothyrium minita ns), in particular, strain CON / M / 91-8 (deposit number DSM-9660), Lecanicillium spp. , in particular, strain HRO LEC 12, Lecanicillium lecanii (formerly known as Verticillium lecanii), in particular, strain KV01, Metarhizium anisopliae , in particular, strain F52 (DSM3884 / ATCC 90448) , Metschnikowia fructicola , in particular, strain NRRL Y-30752, Paecilomyces fumosoroseus (currently: Isaria fumosorosea) , in particular, strain IFPC 200613 or strain Apopka 97 (deposit number ATCC 20874), Paecilomyces lilacinus , in particular, Paecilomyces lilacinus strain 251 (AGAL 89 / 030550), Talaromyces flavus , in particular, strain V117b, Trichoderma atroviride , in particular, strain SC1 (deposit number CBS 122089), Trichoderma harzianum , in particular, Trichoderma harzianum rifai T39 (deposit number CNCM I-952).
[0183] Viruses that are being used or can be used as biological pesticides Examples are as follows: Apple tortrix (Adoxophyes orana) granulosis virus (GV) , Codling moth (Cydia pomonella) granulosis virus (GV), Tobacco budworm (Helicoverpa armigera) nuclear polyhedrosis virus (NPV), Beet armyworm (Spodoptera exigua) mNPV, Fall armyworm (Spodoptera frugiperda) mNPV, Egyptian cotton leafworm (Spodoptera littoral is) NPV.
[0184] Bacteria and fungi that are added as "inoculum sources" to plants or plant parts or plant organs and enhance plant growth and plant health by their specific characteristics are also included. Examples that can be cited are as follows: Agrobacterium spp., Azorhizobium caulinodans, Azospirillum spp., Azotobacter spp., Bradyrhizobium spp .), Burkholderia spp., in particular, Burkholderia cepacia (formerly known as Pseudomonas cepacia), Gigaspora spp. or Gigaspora monosporum (Gi Gaspora monosporum), Glomus spp., Laccaria spp., Lactobacillus buchneri Paraglomus spp., Pisolithus tinctorus Pseudomonas spp., Rhizobium spp., especially Rhizobium trifolii, Rhizopogon spp., Scleroderma spp., Suillus spp., Streptomyces spp.
[0185] Plant extracts and products formed by microorganisms that are used or can be used as biological pesticides (which include proteins and secondary metabolites) Examples are as follows: Garlic (Allium sativum), Wormwood (Artemisia absinthium), Azadirachtin, Biokeeper WP, Cassia nigricans, Celastrus angulatus, Chenopodium anthelminticum, Chitin, Armour-Zen, Dryopteris filix-mas, Equisetum arvense, Fortune Aza, Fungastop, Hea ds Up (Chenopodium quinoa saponin extract), insect repellent Pyrethrum / Pyrethrins, Quassia amara, Quercus, Quillaja, Rega lia, (「Requiem Insecticide」), rotenone, Ryania / TM ryanodine, Symphytum officinale, Tanacetum vulgare , thymol, Triact 70, TriCon (Tropaeolum majus), Urtica dioica, Veratrin, Viscum album ), Brassicaceae extract, especially, rapeseed powder or mustard powder . The compound represented by formula (I) is a phytotoxicity reducing agent, for example, benoxacol, crocintoce t (-methyl), thiomethrinyl, cyprosulfamide, dichloramide, fenchlorazole (-ethyl), fenchlorim, flurazole, flutriafol, furilazole
[0186] (-ethyl), mefenpyr (-diethyl), naphthalic anhydride, o...
Claims
1. Formula (I) 【Chemistry 1】 [During the ceremony, X is O or S; Q 1 and Q. 2 is independently 5 or N, where Q 1 and Q 2 At least one of 1 is N; Y is a direct bond or an optionally substituted CH 2 and R 1 is hydrogen; 1 -C 6 Alkyl [wherein the alkyl is -CN, -CONH 2 , -COOH, -NO 2 and -Si(CH 3 ) 3 is substituted with one substituent selected from may be]; C 1 -C 6 Haloalkyl; C 2 -C 6 Alkenyl; C 2 -C 6 Haloarkeni Ru;C 2 -C 6 Alkynyl; C 2 -C 6 Haloalkynyl; 3 -C 4 Cycloalkyl-C 1 -C 2 alkyl-[wherein the C 3 -C 4 Cycloalkyl is a group containing one or two halogen atoms. oxetan-3-yl-CH 2 - or benzyl [ Here, the benzyl is a halogen or C 1 -C 3 may be substituted with haloalkyl; can be; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents. provided that at least one substituent is adjacent to the carbon bonded to the C=X group. and the substituent is present on any carbon atom of Halogen, hydroxy, -NH 2 , -CN, -SF 5 , -COOH, -CONH 2 , -N O 2 , and In either case, optionally substituted C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl , C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 6 Haloalkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alki Rusulfinyl, C 1 -C 6 Alkylsulfonyl, C 1 -C 6 Haloalkylthio, C 3 - C 6 Cycloalkylsulfanyl, C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloalkylsulfonyl, C 1 -C 6 Haloalkylsulfinyl, C 1 -C 6 Haloal phenylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C 1 -C 6 Alkyl), -N(C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Alkyl)CO-C 1 -C 6 Alkyl, -NHCO-phenyl Nil, -CO 2 C 1 -C 6 Alkyl, -CONH(C 1 -C 6 alkyl), -CON(C 1 -C 6 Alkyl) 2 , -CONH(C 3 -C 6 cycloalkyl), -CON(C 1 -C 6 Alkyl) (C 3 -C 6 Cycloalkyl), -C(=NOC 1 -C 6 Alkyl) H, - C (=NOC 1 -C 6 Alkyl)-C 1 -C 6 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is a halogen, —CN, or a C 1 -C 6 Alkyl , C 1 -C 6 Haloalkyl and C 1 -C 6 each independently selected from the group consisting of alkoxy; and Optionally substituted 4- to 6-membered saturated or partially unsaturated heterocyclic ring are each independently selected from the group consisting of: Or, R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine has a total of 1 to 3 substituents. provided that the substituent is not adjacent to the carbon bonded to the C=X group. is not present on any carbon atom, and at least one and at most three substituents are Optionally substituted C 4 -C 6 Alkyl; C 1 -C 6 Alkylthio [wherein the alkylthio is -NH 2 , -OH, -NO 2 , - CN, -SH, CO 2 C 1 -C 4 Alkyl, -CONH 2 , S.F. 5 , -SO 2 N.H. 2 , C 1 -C 4 Alkyl, C 3 -C 4 Cycloalkyl, C 2 -C 4 Alkenyl, C 5 -C 6 Sik alkenyl, C 2 -C 4 Alkynyl, -NH(C 1 -C 6 Alkyl), -N(C 1 -C 6 Alkyl) 2 , N.C. 1 -C 4 Alkanoylamino, C 1 -C 4 Alkoxy, C 1 -C 4 Haloalkoxy, C 2 -C 4 Alkenyloxy, C 2 -C 4 Alkynyloxy, C 3 - C 4 Cycloalkoxy, C 5 -C 6 Cycloalkenyloxy, C 1 -C 4 Alkoxycarb Bonil, C. 2 -C 4 Alkenyloxycarbonyl, C 2 -C 4 Alkynyloxycarbonyl Lu, C 6 -aryloxycarbonyl, C 10 -aryloxycarbonyl, C 14 -a Aryloxycarbonyl, C 1 -C 4 Alkanoyl, C 2 -C 4 Alkenyl carbonyl, C 2 -C 4 Alkynylcarbonyl, C 6 -arylcarbonyl, C 10 -Aryl carbo Nill, C. 14 -arylcarbonyl, C 1 -C 4 Alkylthio, C 1 -C 4 Haloalkyl Chio, C. 3 -C 4 Cycloalkylthio, C 2 -C 4 Alkenylthio, C 5 -C 6 Cycloa Rukenylthio, C 2 -C 4 Alkynylthio, C 1 -C 4 Alkylsulfinyl, C 1 -C 4 Haloalkylsulfinyl, C 1 -C 4 Alkylsulfonyl, C 1 -C 4 Haloalkyl Sulfonyl, -SO 2 -NH(C 1 -C 6 Alkyl), -SO 2 -N(C 1 -C 6 Alki L) 2 , C 1 -C 4 Alkylphosphinyl, C 1 -C 4 Alkylphosphonyl, N-C 1 - C 4 Alkylaminocarbonyl, N,N-di-C 1 -C 4 Alkylaminocarbonyl, N -C 1 -C 4 Alkanoylaminocarbonyl, N-C 1 -C 4 Alkanoyl-N-C 1 - C 4 Alkylaminocarbonyl, C 6 -Aryl, C 10 -Aryl, C 14 -Aryl , C 6 -aryloxy, C 10 -aryloxy, C 14 -aryloxy, benzyl , benzyloxy, benzylthio, C 6 -arylthio, C 10 -arylthio, C 14 -arylthio, C 6 -arylamino, C 10 -arylamino, C 14 -Arria amino, benzylamino, heterocyclyl, heteroaryl and trialkylsilyl, Substituents attached via bonds (e.g., C 1 -C 4 -Alkylidene (e.g., methyl phenylene or ethylidene), oxo group, imino group and substituted imino group and optionally substituted with 1 to 3 substituents independently selected from And, In either case, optionally substituted C 4 -C 6 Haloalkylthio, C 4 -C 6 HelloA Lukoxi, C 4 -C 6 Alkoxy, C 4 -C 6 Haloalkyl, C 3 -C 6 Cycloalkyl , C 1 -C 6 Alkylsulfinyl, C 1 -C 6 Alkylsulfonyl, C 3 -C 6 Cyclo Alkylsulfanyl, C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloal Kyrsulfonyl, C 1 -C 6 Haloalkylsulfinyl, C 1 -C 6 Haloalkylsulfonate Nill, C. 2 -C 6 Alkenylsulfanyl, C 2 -C 6 Alkenylsulfinyl, C 2 - C 6 Alkenylsulfonyl, C 2 -C 6 Alkynylsulfanyl, C 2 -C 6 Alkynyl Sulfinyl, C 2 -C 6 Alkynylsulfonyl, phenylsulfanyl, phenylsulf phenylsulfonyl, heterocyclylsulfanyl, heterocyclylsulfi Heterocyclylsulfonyl, heteroarylsulfanyl, heteroarylsulf S-C 1 -C 6 Alkyl sulfinimidoyl, S -C 3 -C 6 Cycloalkylsulfinimidoyl, S-C 2 -C 6 Alkenyl sulfide Nimidyl, S-C 2 -C 6 Alkynylsulfinimidoyl, S-phenylsulfi S-heterocyclylsulfinimidoyl, S-heteroarylsulfinimidoyl Nimidyl, S-C 1 -C 6 Alkyl sulfonimidoyl, S-C 3 -C 6 Cycloal Chilsulfonimidoyl, S-C 2 -C 6 Alkenylsulfonimidoyl, S-C 2 -C 6 Alkynylsulfonimidoyl, S-phenylsulfonimidoyl, S-heterocyclyl S-heteroarylsulfonimidoyl, S-heteroarylsulfonimidoyl, -NH(C 1 -C 6 a Rukill), -N(C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Alkyl)CO-C 1 -C 6 Alkyl, -N(C 3 -C 6 Cycloalkyl)CO -C 1 -C 6 Alkyl, -NHCO-phenyl, -N(C 1 -C 6 Alkyl)CO-phenyl Nyl, -N(C 3 -C 6 cycloalkyl)CO-phenyl, -NHCO-C 3 -C 6 Sik alkyl, -N(C 1 -C 6 alkyl)CO-(C 3 -C 6 Cycloalkyl), -N( C 3 -C 6 Cycloalkyl)CO-(C 3 -C 6 Cycloalkyl), -NHCO-hetero Aryl, -N(C 1 -C 6 alkyl)CO-heteroaryl, -N(C 3 -C 6 Cyclo alkyl)CO-heteroaryl, -NHCO-heterocyclyl, -N(C 1 -C 6 Al -CO-heterocyclyl, -N(C 3 -C 6 Cycloalkyl)CO-heterocyclyl , -CO 2 C 1 -C 6 Alkyl, -CONH(C 1 -C 6 alkyl), -CON(C 1 - C 6 Alkyl) 2 , -CONH(C 3 -C 6 cycloalkyl), -CON(C 1 -C 6 a Rukill) (C 3 -C 6 cycloalkyl), -CON(C 3 -C 6 Cycloalkyl) 2 , - CONH-phenyl, -CON(C 1 -C 6 alkyl)phenyl, -CON(C 3 -C 6 cycloalkyl)phenyl, -CONH-heteroaryl, -CON(C 1 -C 6 Alki heteroaryl, -CON(C 3 -C 6 cycloalkyl)heteroaryl, -CON H-heterocyclyl, -CON(C 1 -C 6 alkyl)heterocyclyl, -CON(C 3 -C 6 cycloalkyl)heterocyclyl, -C(=NOC 1 -C 6 Alkyl)H, -C( = NOC 1 -C 6 Alkyl)-C 1 -C 6 Alkyl, -NHSO 2 -C 1 -C 6 Alkyl , -N(C 1 -C 6 Alkyl)SO 2 -C 1 -C 6 Alkyl, -N(C 3 -C 6 Cycloa Rukyil) SO 2 -C 1 -C 6 Alkyl, -NHSO 2 -phenyl, -N(C 1 -C 6 Al Kill) SO 2 -phenyl, -N(C 3 -C 6 Cycloalkyl)SO 2 -phenyl, -NH SO 2 -C 3 -C 6 Cycloalkyl, -N(C 1 -C 6 Alkyl)SO 2 - (C 3 -C 6 cycloalkyl), -N(C 3 -C 6 Cycloalkyl)SO 2 - (C 3 -C 6 Cycloal Kill), -NHSO 2 -heterocyclyl, -N(C 1 -C 4 Alkyl)SO 2 - Heterosi Kryl, -N(C 3 -C 6 Cycloalkyl)SO 2 -heterocyclyl, -NHSO 2 - He Heteraryl, -N(C 1 -C 6 Alkyl)SO 2 -heteroaryl, -N(C 3 -C 6 Cycloalkyl)SO 2 -heteroaryl, -SO 2 NH (C 1 -C 6 Alkyl), -S O 2 N (C 1 -C 6 Alkyl) 2 , -SO 2 N (C 1 -C 6 Alkyl) (C 3 -C 6 Sik -Oalkyl), -SO 2 NH (C 3 -C 6 Cycloalkyl), -SO 2 N (C 3 -C 6 S Chloroalkyl) 2 , -SO 2 NH (phenyl), -SO 2 N (C 1 -C 6 Alkyl) (F phenyl), -SO 2 N (C 1 -C 4 Cycloalkyl)(phenyl), -SO 2 NH (Hee -aryl), -SO 2 N (C 1 -C 6 alkyl) (heteroaryl), -SO 2 N (C 3 -C 6 cycloalkyl)(heteroaryl), -SO 2 NH (heterocyclyl), -S O 2 N (C 1 -C 4 alkyl)(heterocyclyl), -SO 2 N (C 3 -C 6 Cycloal (heterocyclyl); and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is a halogen, —CN, or a C 1 -C 6 Alkyl , C 1 -C 6 Haloalkyl, C 1 -C 6 Alkoxy and C 1 -C 6 From Haloalkoxy each of which is optionally substituted with 1 to 2 substituents independently selected from the group consisting of And, an optionally substituted 4- to 6-membered saturated or partially unsaturated heterocyclic ring; And, -SO 2 NH 2 ; Independently selected from Group A consisting of: And, The remaining 1 to 2 optional substituents are Halogen, hydroxy, -NH 2 , -CN, -SF 5 , -COOH, -CONH 2 , -N O 2 , and In either case, optionally substituted C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl , C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 6 Haloalkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alki Rusulfinyl, C 1 -C 6 Alkylsulfonyl, C 1 -C 6 Haloalkylthio, C 1 - C 6 Haloalkylsulfinyl, C 1 -C 6 Haloalkylsulfonyl, Phenylsulfa nyl, phenylsulfinyl, phenylsulfonyl, -NH(C 1 -C 6 Alkyl), - N (C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Al Kill) CO-C 1 -C 6 Alkyl, -NHCO-phenyl, -CO 2 C 1 -C 6 Alkyl , -CONH(C 1 -C 6 alkyl), -CON(C 1 -C 6 Alkyl) 2 , -CONH (C 3 -C 6 cycloalkyl), -CON(C 1 -C 6 Alkyl) (C 3 -C 6 Cycloa Rukill), -C (=NOC 1 -C 6 Alkyl)H, -C(=NOC 1 -C 6 Alkyl)- C 1 -C 6 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is a halogen, —CN, or a C 1 -C 6 Alkyl , C 1 -C 6 Haloalkyl and C 1 -C 6 each independently selected from the group consisting of alkoxy; may be substituted with one or two substituents selected from the group consisting of each independently selected from Group B consisting of: Or, R 2 is naphthyl, wherein the naphthyl is Halogen, hydroxy, -CN, -COOH, -CONH 2 , -NO 2 , -SF 5 , -N H 2 , and In either case, optionally substituted C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl , C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 6 Haloalkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alki Rusulfinyl, C 1 -C 6 Alkylsulfonyl, C 3 -C 6 Cycloalkylsulfani Lu, C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloalkylsulfonyl, C 1 -C 6 Haloalkylthio, C 1 -C 6 Haloalkylsulfinyl, C 1 -C 6 Haloal phenylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C 1 -C 6 alkyl), -N(C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Alkyl)CO-C 1 -C 6 Alkyl, -NHCO-phenyl Nil, -CO 2 C 1 -C 6 Alkyl, -CONH(C 1 -C 6 alkyl), -CON(C 1 -C 6 Alkyl) 2 , -C(=NOC 1 -C 6 Alkyl)H, -C(=NOC 1 -C 6 Alkyl)-C 1 -C 6 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is a halogen, —CN, or a C 1 -C 6 Alkyl , C 1 -C 6 Haloalkyl and C 1 -C 6 each independently selected from the group consisting of alkoxy; may be substituted with one or two substituents selected from the group consisting of and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, R 2 is 4-10 membered saturated and partially unsaturated heterocyclyl, 5 membered heteroaryl, A heterocyclic ring selected from the group consisting of 9-membered heteroaryl and 10-membered heteroaryl. where these are, respectively, Halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH 2 , -NO 2 , -SF 5 , -NH 2 , and In either case, optionally substituted C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl , C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 6 Haloalkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alki Rusulfinyl, C 1 -C 6 Alkylsulfonyl, C 3 -C 6 Cycloalkylsulfani Lu, C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloalkylsulfonyl, C 1 -C 6 Haloalkylthio, C 1 -C 6 Haloalkylsulfinyl, C 1 -C 6 Haloal phenylsulfonyl, phenylsulfanyl, phenylsulfinyl, phenylsulfonyl, -NH(C 1 -C 6 alkyl), -N(C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Alkyl)CO-C 1 -C 6 Alkyl, -NHCO-phenyl Nil, -CO 2 C 1 -C 6 Alkyl, -CONH(C 1 -C 6 alkyl), -CON(C 1 -C 6 Alkyl) 2 , -C(=NOC 1 -C 6 Alkyl)H, -C(=NOC 1 -C 6 Alkyl)-C 1 -C 6 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is a halogen, —CN, or a C 1 -C 6 Alkyl , C 1 -C 6 Haloalkyl and C 1 -C 6 each independently selected from the group consisting of alkoxy; may be substituted with one or two substituents selected from the group consisting of and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, R 2 is optionally substituted C 1 -C 6 Alkyl, C 3 -C 6 Sik aryl alkyl or C 1 -C 6 haloalkyl; R 3a , R 3b are independently hydrogen; halogen; -CN; 1 -C 6 Alkyl [where The alkyl is halogen, hydroxy, —CN, —COOH, —CONH 2 , -NO 2 , -NH 2 , optionally substituted C in either case 1 -C 6 Alkyl, C 3 -C 6 S Chloroalkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkyls Rufinyl, C 1 -C 6 Alkylsulfonyl, -NH(C 1 -C 6 alkyl), -N(C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Alkyl) CO-C 1 -C 6 Alkyl, -CO 2 C 1 -C 6 Alkyl, -CONH(C 1 -C 6 Al KILL) and -CON(C 1 -C 6 Alkyl) 2 1 to 3 independently selected from the group consisting of Optionally substituted with a substituent of the formula: 3 -C 6 Cycloalkyl; Optionally substituted C 1 -C 6 Haloalkyl; optionally substituted C 2 -C 6 Arke Nyl; optionally substituted C 2 -C 6 Haloalkenyl; optionally substituted C 2 -C 6 alkynyl; benzyl, wherein the phenyl substituents are halogen, hydroxy, -CN , -COOH, -CONH 2 , -NO 2 , -NH 2 , -SF 5 In either case, C may be 1 -C 6 Alkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkylsulfinyl and C 1 -C 6 It is selected from the group consisting of alkylsulfonyl. each of which is optionally substituted with 1 to 5 independently selected substituents; heterocyclyl-C 1 -C 6 Alkyl, wherein the heterocyclyl substituent is 4-10 membered saturated and partially unsaturated Selected from the group consisting of saturated heterocyclyl, 5-membered heteroaryl, and 6-membered heteroaryl where these are, respectively, halogen, ═O (oxo), hydroxy, —CN, -COOH, -CONH 2 , -NO 2 , -NH 2 In either case, it may be substituted. I C 1 -C 6 Alkyl and C 1 -C 6 1 to 3 independently selected from the group consisting of alkoxy phenyl, wherein the phenyl is optionally substituted by halogen, aryl, Droxy, -CN, -COOH, -CONH 2 , -NO 2 , -NH 2 , -SF 5 , either C which may also be substituted 1 -C 6 Alkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkylsulfinyl and C 1 -C 6 Alkyl sulfonyl and each of the groups consisting of 1 to 5 substituents independently selected from the group consisting of: heterocyclyl, wherein the heterocyclyl substituent is a 4- to 10-membered saturated and partially Selected from the group consisting of unsaturated heterocyclyl, 5-membered heteroaryl, and 6-membered heteroaryl. where these are selected from halogen, ═O (oxo), hydroxy, —CN , -COOH, -CONH 2 , -NO 2 , -NH 2 , even if replaced in either case Good C 1 -C 6 Alkyl and C 1 -C 6 1 independently selected from the group consisting of alkoxy and optionally substituted with 1 to 3 substituents; Or, R 3a , R 3b are C together with the carbon to which they are attached. 3 -C 6 - a carbocyclic ring system or forming a 3- to 6-membered heterocyclic ring system, wherein the ring system is substituted with halogen, -CN, C which may also be substituted 1 -C 6 Alkyl, C 1 -C 6 Alkoxy and C 1 -C 6 substituted with 1 to 2 substituents each independently selected from the group consisting of haloalkoxy; It is okay to have; R 4 is pyridine, pyrimidine, pyrazine, pyridazine or a 5-membered heteroaryl; wherein the pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl is Halogen, hydroxy, -CN, -COOH, -CO 2 -C 1 -C 6 Alkyl, -SO 2 N.H. 2 , -CONH 2 , -CSNH 2 , -NO 2 , -NH 2 , which is replaced in both cases C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 -C 6 Haloalkyl , C 1 -C 6 Alkoxy, C 1 -C 6 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 - C 6 Alkylsulfinyl, C 1 -C 6 Alkylsulfonyl, C 1 -C 6 Haloalkyl O, C 1 -C 6 Haloalkylsulfinyl, C 1 -C 6 Haloalkylsulfonyl, C 3 - C 6 Cycloalkylsulfanyl, C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloalkylsulfonyl, C 2 -C 4 Alkenylsulfanyl, C 2 -C 4 Alkenyl Sulfinyl, C 2 -C 4 Alkenylsulfonyl, C 2 -C 4 Alkynylsulfanyl, C 2 -C 4 Alkynylsulfinyl, C 2 -C 4 Alkynylsulfonyl, Phenylsulf Anyl, phenylsulfinyl, phenylsulfonyl, S-C 1 -C 6 Alkyl Sulfide Nimidyl, S-C 3 -C 6 Cycloalkylsulfinimidoyl, S-C 2 -C 6 a Alkenylsulfinimidoyl, S-C 2 -C 6 Alkynylsulfinimidoyl, S- Phenylsulfinimidoyl, S-C 1 -C 6 Alkyl sulfonimidoyl, S-C 3 -C 6 Cycloalkylsulfonimidoyl, S-C 2 -C 6 Alkenyl sulfonimide Lu, S.C. 2 -C 6 Alkynylsulfonimidoyl, S-phenylsulfonimidoyl, -NH(C 1 -C 6 Alkyl), -N(C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Alkyl)CO-C 1 -C 6 Alkyl, -N(C 3 -C 6 Cycloalkyl)CO-C 1 -C 6 Alkyl, -NHCO-C 3 -C 6 Cycloalkyl, -N(C 1 -C 6 alkyl)CO-(C 3 -C 6 cycloalkyl), -N(C 3 -C 6 S chloroalkyl)CO-(C 3 -C 6 cycloalkyl), -N(C 1 -C 6 Alkyl)CO -phenyl, -N(C 3 -C 6 cycloalkyl)CO-phenyl, -NHCO-phenyl , -N(CO-C 1 -C 6 Alkyl) 2 , -N(CO-C 3 -C 6 Cycloalkyl) 2 , -N(CO-phenyl) 2 , -N(CO-C 3 -C 6 Cycloalkyl) (CO-C 1 -C 6 alkyl), -N(CO-C 3 -C 6 cycloalkyl)(CO-phenyl), -N(C O-C 1 -C 6 alkyl)(CO-phenyl), -CONH(C 1 -C 6 Alkyl), - CON (C 1 -C 6 Alkyl) 2 , -CONH(C 3 -C 6 Cycloalkyl), -CON (C 1 -C 6 Alkyl) (C 3 -C 6 cycloalkyl), -CON(C 3 -C 6 Cycloa Rukill) 2 , -CONH-SO 2 -C 1 -C 6 Alkyl, -CONH-SO 2 -Phenyl , -CONH-SO 2 - (C 3 -C 6 cycloalkyl), -CON(C 1 -C 6 Alkyl ) -SO 2 -C 1 -C 6 Alkyl, -CON(C 1 -C 6 (alkyl)-SO 2 -Phenyl , -CON(C 1 -C 6 (alkyl)-SO 2 - (C 3 -C 6 Cycloalkyl), -CON H-phenyl, -CON(C 1 -C 6 alkyl)phenyl, -CON(C 3 -C 6 Cyclo alkyl)phenyl, -N(SO 2 C 1 -C 6 Alkyl) 2 , -N(SO 2 C 1 -C 6 Ha (alkyl) 2 , -N(SO 2 C 3 -C 6 Cycloalkyl) 2 , -N(SO 2 C 1 -C 6 Alkyl)SO 2 -phenyl, -N(SO 2 C 3 -C 6 Cycloalkyl)SO 2 -Feni Ru, -NHSO 2 -C 1 -C 6 Alkyl, -NHSO 2 -C 1 -C 6 Haloalkyl, -N (C 1 -C 6 Alkyl)SO 2 -C 1 -C 6 Alkyl, -N(C 3 -C 6 Cycloalkyl ) S.O. 2 -C 1 -C 6 Alkyl, -NHSO 2 -phenyl, -N(C 1 -C 6 Alkyl) SO 2 -phenyl, -N(C 3 -C 6 Cycloalkyl)SO 2 -phenyl, -NHSO 2 -C 3 -C 6 Cycloalkyl, -N(C 1 -C 6 Alkyl)SO 2 - (C 3 -C 6 Cyclo Alkyl), -N(C 3 -C 6 Cycloalkyl)SO 2 - (C 3 -C 6 Cycloalkyl) , -SO 2 NH (C 1 -C 6 Alkyl), -SO 2 N (C 1 -C 6 Alkyl) 2 , -SO 2 N (C 1 -C 6 Alkyl) (C 3 -C 6 Cycloalkyl), -SO 2 NH (C 3 -C 6 Cycloalkyl), -SO 2 N (C 3 -C 6 Cycloalkyl) 2 , -SO 2 NH (Feni -SO 2 N (C 1 -C 6 alkyl) (phenyl), -SO 2 N (C 1 -C 4 Cyclo alkyl) (phenyl), -C(=NOC 1 -C 6 Alkyl)H and -C(=NOC 1 - C 6 Alkyl)-C 1 -C 6 substituted with 1 to 3 substituents selected from the group consisting of alkyl may be R 5 is hydrogen, halogen, -CN or optionally substituted C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Arco oxyC(O)-, (C 1 -C 6 Alkoxy) 2 CH-, -CO 2 C 1 -C 6 Alkyl, - CONH (C 1 -C 6 alkyl), -CON(C 1 -C 6 Alkyl) 2 , -NHCO-C 1 -C 6 Alkyl, -N(C 1 -C 6 Alkyl)CO-C 1 -C 6 Alkyl, -C(=N O.C. 1 -C 6 Alkyl)H or -C(=NOC 1 -C 6 Alkyl)-C 1 -C 6 Al It is a kill. A compound represented by the formula:
2. X is O or S; Q 1 and Q. 2 is independently 5 or N, where Q 1 and Q 2 At least one of the other is N; Y is a direct bond or CH 2 and R 1 is hydrogen; 1 -C 6 Alkyl [wherein the alkyl is -CN, -CONH 2 , -COOH, -NO 2 and -Si(CH 3 ) 3 is substituted with one substituent selected from may be]; C 1 -C 6 Haloalkyl; C 2 -C 6 Alkenyl; C 2 -C 6 Haloarkeni Ru;C 2 -C 6 Alkynyl; C 2 -C 6 Haloalkynyl; 3 -C 4 Cycloalkyl-C 1 -C 2 alkyl-[wherein the C 3 -C 4 Cycloalkyl is a group containing one or two halogen atoms. oxetan-3-yl-CH 2 -; or benzyl [ Here, the benzyl is a halogen or C 1 -C 3 may be substituted with haloalkyl; can be; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents. provided that at least one substituent is adjacent to the carbon bonded to the C=X group. and the substituent is present on any carbon atom of Halogen, hydroxy, -NH 2 , -CN, -SF 5 , -COOH, -CONH 2 , -N O 2 , C 1 -C 6 Alkyl, Optionally substituted C 3 -C 6 Cycloalkyl; C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkyl Sulfinyl, C 1 -C 6 Alkylsulfonyl, C 3 -C 6 Cycloalkylsulfanyl , C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloalkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Hello Aruki sulfonyl; Phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein any In some cases, the phenyl may be selected from halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 Haloal and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; -NH(C 1 -C 4 alkyl), -N(C 1 -C 4 Alkyl) 2 , -NHCO-C 1 -C 4 Alkyl, -N(C 1 -C 4 Alkyl)CO-C 1 -C 4 Alkyl; -NHCO-phenyl, wherein the phenyl is selected from halogen, CN, C 1 -C 6 Alkyl and Bi C 1 -C 3 and optionally substituted with 1 to 2 substituents selected from the group consisting of haloalkyl. good]; -CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl), -CON(C 1 -C 4 Alkyl) 2 , -CONH(C 3 -C 6 cycloalkyl), -CON(C 1 -C 4 Al Kill) (C 3 -C 6 Cycloalkyl), -C(=NOC 1 -C 4 Alkyl)H, -C(= NOC 1 -C 4 Alkyl)-C 1 -C 4 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 alkoxy is substituted with 1 to 2 substituents each independently selected from the group consisting of It is okay. are each independently selected from the group consisting of: Or, R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine has a total of 1 to 3 substituents. provided that the substituent is not adjacent to the carbon bonded to the C=X group. is not present on any carbon atom, and at least one and at most three substituents are C 4 -C 6 -Alkyl, C 1 -C 6 Alkylthio, C 1 -C 6 Alkylsulfinyl, C 1 -C 6 Alkylsulfonyl, C 3 -C 6 Cycloalkylsulfanyl, C 3 -C 6 Sik C alkylsulfinyl 3 -C 6 Cycloalkylsulfonyl, C 1 -C 3 Hello Aruki Rusulfinyl, C 1 -C 3 Haloalkylsulfonyl; Phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein any In some cases, the phenyl may be selected from halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 Haloal and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; Optionally substituted C 3 -C 6 Cycloalkyl; -NH(C 1 -C 4 alkyl), -N(C 1 -C 4 Alkyl) 2 , -NHCO-C 1 -C 4 Alkyl, -N(C 1 -C 4 Alkyl)CO-C 1 -C 4 Alkyl, -NHCO-C 3 -C 4 Cycloalkyl, -NHSO 2 -phenyl; -NHCO-phenyl, wherein the phenyl is selected from the group consisting of halogen, -CN, C 1 -C 6 Alkyl and C 1 -C 3 substituted with 1 to 2 substituents selected from the group consisting of haloalkyl; may also be]; -CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl), -CON(C 1 -C 4 Alkyl) 2 , -CONH(C 3 -C 6 cycloalkyl), -CON(C 1 -C 4 Al Kill) (C 3 -C 6 Cycloalkyl), -C(=NOC 1 -C 4 Alkyl)H, -C(= NOC 1 -C 4 Alkyl)-C 1 -C 4 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy and C 1 -C 4 haloalkoxy may be substituted with up to 2 substituents. Independently selected from Group A consisting of: The remaining 1 to 2 optional substituents are Halogen, hydroxy, -NH 2 , -CN, -SF 5 , -COOH, -CONH 2 , -N O 2 , C 1 -C 6 Alkyl, Optionally substituted C 3 -C 6 Cycloalkyl; C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkyl Sulfinyl, C 1 -C 6 Alkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Haloalkylsulfonyl; Phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein any In some cases, the phenyl may be selected from halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 Haloal and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; -NH(C 1 -C 4 Alkyl), -N(C 1 -C 4 Alkyl) 2 , -NHCO-C 1 -C 4 Alkyl, -N(C 1 -C 4 Alkyl)CO-C 1 -C 4 Alkyl; -NHCO-phenyl phenyl, wherein the phenyl is selected from halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 Halo and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; -CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl), -CON(C 1 -C 4 Alkyl) 2 , -CONH(C 3 -C 6 cycloalkyl), -CON(C 1 -C 4 Al Kill) (C 3 -C 6 Cycloalkyl), -C(=NOC 1 -C 4 Alkyl)H, -C(= NOC 1 -C 4 Alkyl)-C 1 -C 4 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 alkoxy is substituted with 1 to 2 substituents each independently selected from the group consisting of It is okay. each independently selected from Group B consisting of: Or, R 2 is naphthyl, wherein the naphthyl is Halogen, hydroxy, -CN, -COOH, -CONH 2 , -NO 2 , -SF 5 , -N H 2 , C 1 -C 6 Alkyl, Optionally substituted C 3 -C 6 Cycloalkyl; C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkyl Sulfinyl, C 1 -C 6 Alkylsulfonyl, C 3 -C 6 Cycloalkylsulfanyl , C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloalkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Hello Aruki sulfonyl; Phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein any In some cases, the phenyl may be selected from halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 Haloal and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; -NH(C 1 -C 4 Alkyl), -N(C 1 -C 4 Alkyl) 2 , -NHCO-C 1 -C 4 Alkyl, -N(C 1 -C 4 Alkyl)CO-C 1 -C 4 Alkyl; -NHCO-phenyl, wherein the phenyl is halogen, CN, C 1 -C 6 Alkyl and Bi C 1 -C 3 and optionally substituted with 1 to 2 substituents selected from the group consisting of haloalkyl. good]; -CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl), -CON(C 1 -C 4 Alkyl) 2 , -C(=NOC 1 -C 4 Alkyl)H, -C(=NOC 1 -C 4 Alki R)-C 1 -C 4 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 alkoxy is substituted with 1 to 2 substituents each independently selected from the group consisting of It is okay. and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, R 2 is 4-10 membered saturated and partially unsaturated heterocyclyl, 5 membered heteroaryl, A heterocyclic ring selected from the group consisting of 9-membered heteroaryl and 10-membered heteroaryl. where these are, respectively, Halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH 2 , -NO 2 , -SF 5 , -NH 2 , C 1 -C 6 Alkyl, Optionally substituted C 3 -C 6 Cycloalkyl; C 3 -C 6 Cycloalkyl-C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkyl Sulfinyl, C 1 -C 6 Alkylsulfonyl, C 3 -C 6 Cycloalkylsulfanyl , C 3 -C 6 Cycloalkylsulfinyl, C 3 -C 6 Cycloalkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Hello Aruki sulfonyl; Phenylsulfanyl, phenylsulfinyl, phenylsulfonyl [wherein any In some cases, the phenyl may be selected from halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 Haloal and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; -NH(C 1 -C 4 alkyl), -N(C 1 -C 4 Alkyl) 2 , -NHCO-C 1 -C 4 Alkyl, -N(C 1 -C 4 Alkyl)CO-C 1 -C 4 Alkyl; -NHCO-phenyl phenyl, wherein the phenyl is selected from halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 Halo and optionally substituted with 1 to 2 substituents selected from the group consisting of alkyl; -CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl), -CON(C 1 -C 4 Alkyl) 2 , -C(=NOC 1 -C 4 Alkyl)H, -C(=NOC 1 -C 4 Alki R)-C 1 -C 4 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 alkoxy is substituted with 1 to 2 substituents each independently selected from the group consisting of It is okay. and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, R 2 is C 1 -C 6 alkyl, where the alkyl is C 1 -C 3 Alkoxy-, C 1 -C 3 Haloalkoxy-, C 1 -C 6 Alkylthio, C 1 -C 6 Alkylsulfinyl, C 1 -C 6 Alkylsulfonyl, C 1 -C 3 Haloalkyl Chio, C. 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Haloalkylsulfonyl; Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 alkoxy is substituted with 1 to 2 substituents each independently selected from the group consisting of may be]; C 3 -C 6 Cycloalkyl [wherein the cycloalkyl is a halogen, —CN, —COO H, -CONH 2 , C 1 -C 6 Alkyl, C 1 -C 6 Haloalkyl, C 3 -C 6 Cycloa Rukill, C 1 -C 6 Alkoxy, -CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl) and -CON(C 1 -C 4 Alkyl) 2 One or two substituents selected from the group consisting of which may be substituted with a substituent; And, C 1 -C 6 Haloalkyl and is substituted with one substituent selected from the group consisting of: R 3a , R 3b are independently hydrogen; halogen; -CN; 1 -C 6 Alkyl [where The alkyl is hydroxy, —CN, —COOH, —CONH 2 , -NO 2 , -NH 2 , C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 Alkylthio, C 1 -C 3 Alki Rusulfinyl, C 1 -C 3 Alkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 - C 3 Haloalkylsulfinyl, C 1 -C 3 Haloalkylsulfonyl, -NH(C 1 -C 4 Alkyl), -N(C 1 -C 4 Alkyl) 2 , -NHCO-C 1 -C 4 Alkyl, -N (C 1 -C 4 Alkyl)CO-C 1 -C 4 Alkyl, -CO 2 C 1 -C 4 Alkyl, -C ONH (C 1 -C 4 alkyl) and -CON(C 1 -C 4 Alkyl) 2 From the group consisting of and optionally substituted with 1 to 3 substituents selected from 3 -C 6 Cycloalkyl [wherein the cycloalkyl is halogen, —CN, —COOH, —CONH 2 , C 1 - C 6 Alkyl, C 1 -C 6 Haloalkyl, C 3 -C 6 Cycloalkyl, C 1 -C 6 Arco Kishi, C 1 -C 6 Haloalkoxy, —CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl) and -CON(C 1 -C 4 Alkyl) 2 One to two selected from the group consisting of which may be substituted by a substituent; 1 -C 6 haloalkyl, wherein the haloalkyl is , Hydroxy, -CN, C 3 -C 6 Cycloalkyl, C 1 -C 6 Alkoxy, C 1 -C 6 Haloalkoxy, —CO 2 C 1 -C 4 Alkyl, -CONH(C 1 -C 4 alkyl) and -CON (C 1 -C 4 Alkyl) 2 is substituted with 1 to 2 substituents selected from the group consisting of may be]; C 2 -C 6 Alkenyl; C 2 -C 6 Haloalkenyl; C 2 -C 6 Alki Nil;C 2 -C 6 haloalkynyl; benzyl, wherein the phenyl substituents are halogen, Hydroxy, -CN, -COOH, -CONH 2 , -NO 2 , -NH 2 , -SF 5 , C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 4 Haloal Koki, C. 1 -C 3 Alkylthio, C 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alki sulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl and C 1 -C 3 haloalkylsulfonyl, Heterocyclyl-C 1 -C 6 Alkyl [wherein Heterocyclyl substituents include 4- to 10-membered saturated and partially unsaturated heterocyclyl, 5-membered hetercyclyl, and 6-membered heteroaryl, each of which is selected from the group consisting of Halogen, =O (oxo), hydroxy, -CN, -COOH, -CONH 2 , -N O 2 , -NH 2 , C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 Alcoki phenyl, optionally substituted with 1 to 3 substituents independently selected from the group consisting of wherein the phenyl is selected from the group consisting of halogen, hydroxy, —CN, —COOH, —CONH 2 , -NO 2 , -NH 2 , -SF 5 , C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 4 Haloalkoxy, C 1 -C 3 Alkylthio, C 1 -C 3 a alkylsulfinyl, C 1 -C 3 Alkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl and C 1 -C 3 from the group consisting of haloalkylsulfonyl each of which is optionally substituted with 1 to 5 substituents independently selected from And hetero cyclyl, wherein the heterocyclyl substituent is a 4- to 10-membered saturated and partially unsaturated heterocyclyl; is selected from the group consisting of tetracyclyl, 5-membered heteroaryl, and 6-membered heteroaryl; Here, these are halogen, ═O (oxo), hydroxy, —CN, and —COO, respectively. H, -CONH 2 , -NO 2 , -NH 2 , C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 substituted with 1 to 3 substituents independently selected from the group consisting of alkoxy; and optionally selected from the group consisting of Or, R 3a , R 3b are C together with the carbon to which they are attached. 3 -C 6 - a carbocyclic ring system or Forming a 3-6 membered heterocyclic ring system, wherein the ring system is free of halogen, -CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy and C 1 -C 3 Haloalkoki each of which is optionally substituted with 1 to 2 substituents independently selected from the group consisting of R 4 is pyridine, pyrimidine, pyrazine, pyridazine or a 5-membered heteroaryl; wherein the pyridine, pyrimidine, pyrazine, pyridazine or 5-membered heteroaryl is Halogen, hydroxy, -CN, -COOH, -CO 2 -C 1 -C 6 Alkyl, -CON H 2 , -CSNH 2 , -NO 2 , -NH 2 , C 1 -C 6 Alkyl, C 3 -C 6 Cycloal Kill, C. 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 6 Alkylthio, C 1 -C 6 Alkylsulfinyl, C 1 -C 6 Alkyl sulfonyl Lu, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Ha alkylsulfonyl, -NH(C 1 -C 4 alkyl), -N(C 1 -C 4 Alkyl) 2 , -NHCO-C 1 -C 4 Alkyl [wherein the alkyl is -CN, C 1 -C 6 Alki Ru and C 1 -C 4 -NHCO-C 1 -C 4 HelloA Rukyr, -NHCO-C 3 -C 6 Cycloalkyl [wherein the cycloalkyl is a halogen atom] N, -CN, C 1 -C 6 Alkyl or C 1 -C 4 1 selected from the group consisting of alkoxy -NHCO-phenyl, wherein the phenyl is , halogen, -CN, C 1 -C 6 Alkyl and C 1 -C 3 haloalkyl may be substituted with 1 to 2 substituents selected from the group consisting of -N(C 1 -C 4 alkyl)CO- C 1 -C 4 Alkyl, -N(C 1 -C 4 Alkyl)CO-C 3 -C 6 Cycloalkyl; - N (C 1 -C 4 alkyl)CO-phenyl [wherein the phenyl is halogen, CN, C 1 -C 6 Alkyl and C 1 -C 3 1 to 2 substituents selected from the group consisting of haloalkyl may be substituted with]; 2 C 1 -C 3 Alkyl) 2 , -NH(SO 2 C 1 -C 3 Alkyl), -N(C 1 -C 4 Alkyl) (SO 2 C 1 -C 3 Alkyl), -N( SO 2 C 1 -C 3 haloalkyl) 2 , -NH(SO 2 C 1 -C 3 haloalkyl), -CO NH (C 1 -C 4 alkyl), -CON(C 1 -C 4 Alkyl) 2 , -CONH-SO 2 -C 1 -C 3 Alkyl, -CON(C 1 -C 4 Alkyl) (C 3 -C 6 Cycloalkyl) , -CONH(C 1 -C 4 haloalkyl), -CONH(C 3 -C 6 Cycloalkyl), -CONH(C 3 -C 6 cyanocycloalkyl), -C(=NOC 1 -C 4 Alkyl)H and -C (= NOC 1 -C 4 Alkyl)-C 1 -C 4 Alkyl; and -CONH-phenyl phenyl, wherein the phenyl is selected from the group consisting of halogen, —CN, 1 -C 6 Alkyl, C 1 -C 3 Halo Alkyl and C 1 -C 4 1 to 2 independently selected from the group consisting of alkoxy and each of the substituted or unsubstituted groups is substituted with one to three substituents selected from the group consisting of It is okay to have; R 5 is hydrogen, halogen, -CN, C 1 -C 3 Alkyl, C 1 -C 3 Haloalkyl, C 3 -C 4 Cycloalkyl, C 1 -C 3 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 AlkoxyC(O)-, (C 1 -C 3 Alkoxy) 2 CH-, -CO 2 C 1 -C 4 Al Kill, -CONH(C 1 -C 4 alkyl), -CON(C 1 -C 4 Alkyl) 2 , -NH CO-C 1 -C 4 Alkyl, -N(C 1 -C 4 Alkyl)CO-C 1 -C 4 Alkyl, - C (=NOC 1 -C 4 Alkyl)H or -C(=NOC 1 -C 4 Alkyl)-C 1 -C 4 is alkyl; The compound of claim 1.
3. X is O or S; Q 1 and Q. 2 is independently 5 or N, where Q 1 and Q 2 At least one of 1 is N; Y is a direct bond or CH 2 and R 1 is hydrogen; 1 -C 3 Alkyl [wherein the alkyl is -CN, -CONH 2 , -COOH, -NO 2 and -Si(CH 3 ) 3 is substituted with one substituent selected from may be]; C 1 -C 3 Haloalkyl; C 2 -C 4 Alkenyl; C 2 -C 4 Haloarkeni Ru;C 2 -C 4 Alkynyl; C 2 -C 4 Haloalkynyl; 3 -C 4 Cycloalkyl-C 1 -C 2 alkyl-[wherein the C 3 -C 4 Cycloalkyl is a group containing one or two halogen atoms. oxetan-3-yl-CH 2 -; or benzyl [ Here, the benzyl is a halogen or C 1 -C 3 may be substituted with haloalkyl; can be; R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine is substituted with 1 to 5 substituents. provided that at least one substituent is adjacent to the carbon bonded to the C=X group. and the substituent is present on any carbon atom of Halogen, -CN, -NO 2 , C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 - C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 Al Kirchio, C. 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alkylsulfonyl, C 3 -C 4 Cycloalkylsulfanyl, C 3 -C 4 Cycloalkylsulfinyl, C 3 -C 4 S Chloroalkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfur Finil, C 1 -C 3 haloalkylsulfonyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 3 Alkyl and C 1 -C 3 The group consisting of haloalkyl may be substituted with 1 to 2 substituents selected from are each independently selected from the group consisting of: Or, R 2 is phenyl, pyridine, pyrimidine, pyrazine or pyridazine, where The phenyl, pyridine, pyrimidine, pyrazine or pyridazine has a total of 1 to 3 substituents. provided that the substituent is not adjacent to the carbon bonded to the C=X group. is not present on any carbon atom, and at least one and at most two substituents are C 4 -Alkyl, C 3 -C 4 Cycloalkyl [wherein the C 3 -C 4 Cycloalkyl is may be substituted with —CN or halogen; 1 -C 4 Alkylthio, C 1 -C 3 a alkylsulfinyl, C 1 -C 3 Alkylsulfonyl, C 3 -C 4 Cycloalkylsulf Anil, C. 3 -C 4 Cycloalkylsulfinyl, C 3 -C 4 Cycloalkylsulfonyl , C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Haloalkylsulfonyl; And, Phenylsulfanyl [wherein the phenyl is selected from the group consisting of halogen, —CN, C 1 -C 3 Alkyl and C 1 -C 3 substituted with 1 to 2 substituents selected from the group consisting of haloalkyl; may also be]; Phenylsulfinyl [wherein the phenyl is selected from the group consisting of halogen, —CN, C 1 -C 3 Alkyl and C 1 -C 3 substituted with 1 to 2 substituents selected from the group consisting of haloalkyl; may also be]; Phenylsulfonyl [wherein the phenyl is selected from the group consisting of halogen, —CN, C 1 -C 3 Alkyl and Bi C 1 -C 3 and optionally substituted with 1 to 2 substituents selected from the group consisting of haloalkyl. good]; -NHCO-phenyl, wherein the phenyl is halogen, CN, C 1 -C 6 Alkyl and Bi C 1 -C 3 and optionally substituted with 1 to 2 substituents selected from the group consisting of haloalkyl. good]; -NHCO-C 1 -C 3 Alkyl, -NHCO-C 3 -C 4 Cycloalkyl, -NHSO 2 -phenyl; -CONH(C 3 -C 4 cycloalkyl), -CON(C 1 -C 3 Alkyl) (C 3 -C 4 Cycloalkyl), -C(=NOC 1 -C 3 Alkyl)-C 1 -C 3 Alkyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 3 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 3 and optionally substituted with 1 to 2 substituents selected from the group consisting of haloalkoxy. Independently selected from Group A consisting of: The remaining 1 to 2 optional substituents are Halogen, -CN, -NO 2 , C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 - C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 Al Kirchio, C. 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Haloalkyls sulfonyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl and the 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 3 Alkyl and C 1 -C 3 The group consisting of haloalkyl may be substituted with 1 to 2 substituents selected from each independently selected from Group B consisting of: Or, R 2 are thiophene, furan, pyrazole, thiazole, isothiazole, and oxazo or isoxazole, Halogen, hydroxy, -CN, -NO 2 , C 1 -C 6 Alkyl, C 3 -C 4 Cycloal Kill, C. 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 Alkylthio, C 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alkyl sulfonyl Lu, C 3 -C 4 Cycloalkylsulfanyl, C 3 -C 4 cycloalkylsulfinyl, C 3 -C 4 Cycloalkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 HelloA alkylsulfinyl, C 1 -C 3 haloalkylsulfonyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 3 Alkyl and C 1 -C 3 The group consisting of haloalkyl may be substituted with 1 to 2 substituents selected from and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, R 2 is C 1 -C 6 alkyl, where the alkyl is C 1 -C 3 Alkoxy-, C 1 -C 3 Haloalkoxy-, C 1 -C 3 Alkylthio, C 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alkylsulfonyl, C 1 -C 3 Haloalkyl Chio, C. 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Haloalkylsulfonyl; and 、 Phenyl [wherein the phenyl is selected from the group consisting of halogen, —CN, C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 alkoxy, 2, which may be substituted with the substituent of and is substituted with one substituent selected from the group consisting of: Or, R 2 is naphthyl, wherein the naphthyl is Halogen, hydroxy, -CN, -NO 2 , C 1 -C 6 Alkyl, C 3 -C 4 Cycloal Kill, C. 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 Alkylthio, C 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alkyl sulfonyl Lu, C 3 -C 4 Cycloalkylsulfanyl, C 3 -C 4 cycloalkylsulfinyl, C 3 -C 4 Cycloalkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 HelloA alkylsulfinyl, C 1 -C 3 haloalkylsulfonyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 3 Alkyl and C 1 -C 3 The group consisting of haloalkyl may be substituted with 1 to 2 substituents selected from and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, R 2 is a 9- or 10-membered heteroaryl, wherein the heteroaryl is Halogen, hydroxy, -CN, -NO 2 , C 1 -C 6 Alkyl, C 3 -C 4 Cycloal Kill, C. 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 Alkylthio, C 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alkyl sulfonyl Lu, C 3 -C 4 Cycloalkylsulfanyl, C 3 -C 4 cycloalkylsulfinyl, C 3 -C 4 Cycloalkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 HelloA alkylsulfinyl, C 1 -C 3 haloalkylsulfonyl; and Phenyl and 5- to 6-membered heteroaryl [wherein the phenyl or 5- to 6-membered heteroaryl The group is halogen, -CN, C 1 -C 3 Alkyl and C 1 -C 3 The group consisting of haloalkyl may be substituted with 1 to 2 substituents selected from and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: R 3a , R 3b are independently hydrogen; C 1 -C 6 Alkyl, wherein the alkyl is C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 a Lukoxi, C 1 -C 3 Haloalkoxy, C 1 -C 3 Alkylthio, C 1 -C 3 Alkyls Rufinyl, C 1 -C 3 Alkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl and C 1 -C 3 Independently from the group consisting of haloalkylsulfonyl and optionally substituted with 1 to 3 substituents selected from the following: 3 -C 6 Cycloalkyl; C 1 -C 6 Haloalkyl; C 2 -C 6 Alkenyl; C 2 -C 6 Haloalkenyl; C 2 -C 6 Alkynyl; C 2 -C 6 haloalkynyl; benzyl, wherein the phenyl substituent is Gen, -CN, -NO 2 , C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 a Leukoxy and C 1 -C 4 1 to 3 substitutions independently selected from the group consisting of haloalkoxy or heterocyclyl-C 1 -C 6 Alkyl [wherein Heterocyclyl substituents include 4- to 10-membered heterocyclyl, 5-membered heteroaryl and 6-membered aryl. and aryl, each of which is selected from the group consisting of halogen, —CN. , -NO 2 , C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 Alkoxy? and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, Fe Nyl [wherein the phenyl is selected from the group consisting of halogen, —CN, —NO 2 , C 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 alkoxy; and optionally substituted; Or, R 3a , R 3b Together with the carbon to which they are attached, they form a cyclopropane ring, a cyclobutene ring, forming a tetrahydropyran ring, an oxetane ring or a tetrahydropyran ring, wherein the ring is not further substituted with a halogen, -C.N., C. 1 -C 6 Alkyl, C 1 -C 3 Haloalkyl and C 1 -C 4 From alkoxy each of which is optionally substituted with 1 to 2 substituents independently selected from the group consisting of: R 4 is pyridine, pyrimidine, pyrazine, pyridazine or thiazole, (A) the pyridine, pyrimidine, pyrazine or pyridazine is not halogen, —CN, —N H 2 , -NO 2 , -COOH, -CONH 2 , -CSNH 2 , -CO 2 -C 1 -C 3 Al Kill, C. 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloalkoxy, C 1 -C 3 Alkylthio, C 1 -C 3 a alkylsulfinyl, C 1 -C 3 Alkylsulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl, C 1 -C 3 Haloalkylsulfonyl, -NHCO- C 1 -C 3 Alkyl, -NHCO-C 1 -C 3 Haloalkyl, -NHCO-C 1 -C 3 S Anoalkyl, -NHCO-C 3 -C 4 Cycloalkyl, wherein the cycloalkyl is Fluorine, chlorine, -CN, C 1 -C 6 Alkyl or C 1 -C 4 Selected from the group consisting of alkoxy -NHCO-phenyl [wherein the Phenyl is halogen, -CN, C 1 -C 3 Alkyl, C 1 -C 3 Haloalkyl, C 1 - C 3 Alkoxy and C 1 -C 3 1 to 2 substituents selected from the group consisting of haloalkoxy -NHSO 2 -C 1 -C 3 Alkyl, -NHSO 2 -C 1 - C 3 Haloalkyl, -CONH(C 1 -C 3 alkyl), -CON(C 1 -C 3 Alkyl ) 2 , -CONH-SO 2 -C 1 -C 3 Alkyl, -CON(C 1 -C 3 Alkyl) (C 3 -C 6 cycloalkyl), -CONH(C 1 -C 3 haloalkyl), -CONH(C 3 -C 6 cycloalkyl), -CONH(1-cyano-C 3 -C 6 Cycloalkyl), -C ONH-phenyl, wherein the phenyl is selected from the group consisting of halogen, —CN, C 1 -C 3 Alkyl, C 1 -C 3 Haloalkyl, C 1 -C 3 Alkoxy and C 1 -C 3 The group consisting of haloalkoxy may be substituted with 1 to 2 substituents selected from the group consisting of 3 substituents; and (B) The thiazole is a halogen, —CN, —NO 2 , C 1 -C 6 Alkyl, C 3 -C 6 Cycloalkyl, C 1 -C 3 Haloalkyl, C 1 -C 4 Alkoxy, C 1 -C 3 Haloal Koki, C. 1 -C 3 Alkylthio, C 1 -C 3 Alkylsulfinyl, C 1 -C 3 Alki sulfonyl, C 1 -C 3 Haloalkylthio, C 1 -C 3 Haloalkylsulfinyl and C 1 -C 3 substituted with 1 to 2 substituents selected from the group consisting of haloalkylsulfonyl; It may be; R 5 is hydrogen, halogen, -CN, C 1 -C 3 Alkyl, C 1 -C 3 Haloalkyl, C 3 -C 4 Cycloalkyl or C 1 -C 3 is alkoxy; 3. A compound according to claim 1 or 2.
4. X is O or S; Q 1 and Q. 2 is independently 5 or N, where Q 1 and Q 2 At least one of 1 is N; Y is a direct bond or CH 2 and R 1 is hydrogen; 1 -C 3 Alkyl [wherein the alkyl is -CN, -Si(CH 3 ) 3 or selected from the group consisting of fluorine, chlorine or bromine. and optionally substituted with 1 to 3 substituents selected from the group consisting of aryl, aryl, aryl and aryl; 2 -C 4 Alkenyl; C 2 -C 4 Al Quinyl; C 3 -C 4 Cycloalkyl-C 1 -C 2 alkyl-[wherein the C 3 -C 4 Sik The alkyl group is substituted with one or two substituents selected from the group consisting of fluorine, chlorine and bromine. and R 2 is phenyl or pyridine, wherein the phenyl or pyridine is one to three substituted with substituents, provided that at least one of the substituents is not bonded to the carbon atom bonded to the C=X group; and the substituent is present on any carbon adjacent to Fluorine, chlorine, bromine, -CN, -NO 2 , methyl, cyclopropyl, difluoromethyl, Trifluoromethyl, methoxy, trifluoromethoxy, difluoromethoxy, methylthio O, methylsulfinyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethyl Sulfonyl, isopropylthio, isopropylsulfinyl, isopropylsulfonyl, Cyclopropylthio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoro difluoromethylthio, difluoromethylsulfinyl, difluoromethylsulfonyl, trifluoromethylthio Fluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl, And, Phenyl, wherein the phenyl is selected from the group consisting of fluorine, chlorine, bromine, —CN, difluoromethyl and trifluoromethyl] are each independently selected from the group consisting of: Or, R 2 is phenyl or pyridine, where the phenyl or pyridine is a total of 1 substituted with up to 3 substituents, provided that the substituents are adjacent to the carbon bonded to the C=X group; and one substituent is not present on any carbon atom that is tert-Butyl, cyclopropyl, 1-cyanocyclopropyl, methylthio, methyls sulfinyl, methylsulfonyl, ethylthio, ethylsulfinyl, ethylsulfonyl, Isopropylthio, isopropylsulfinyl, isopropylsulfonyl, tert-butyl tert-butylsulfinyl, tert-butylsulfonyl, cyclopropyl Ruthio, cyclopropylsulfinyl, cyclopropylsulfonyl, difluoromethylsulfonyl sulfinyl, difluoromethylsulfonyl, trifluoromethylsulfinyl, trifluoro trifluoromethylsulfonyl, trifluoroethylsulfinyl, trifluoroethylsulfonyl Ru; Phenylsulfonyl [wherein the phenyl is fluorine, chlorine, bromine, —CN, difluoro Substituted with 1 to 2 substituents selected from the group consisting of methyl and trifluoromethyl. may be]; -NHCO-phenyl, wherein the phenyl is selected from fluorine, chlorine, CN, methyl and trifluor. and optionally substituted with 1 to 2 substituents selected from the group consisting of fluoromethyl; (cyclopropylamino)carbonyl, 1-(methoxyimino)ethyl, acetamide, (cyclopropylcarbonyl)amino, (phenylsulfonyl)amino; and Phenyl and 5-membered heteroaryl, wherein the phenyl or 5-membered heteroaryl is fluorine. Chlorine, bromine, -CN, difluoromethyl, trifluoromethyl and trifluorometh and optionally substituted with 1 to 2 substituents selected from the group consisting of aryl, aryloxy ... Independently selected from Group A consisting of: The remaining 1 to 2 optional substituents are Fluorine, chlorine, bromine, -CN, -NO 2 , methyl, cyclopropyl, difluoromethyl, Trifluoromethyl, methoxy, trifluoromethoxy, difluoromethoxy, methylthio O, methylsulfinyl, methylsulfonyl, difluoromethylthio, difluoromethyl Sulfinyl, difluoromethylsulfonyl, trifluoromethylthio, trifluoromethyl methylsulfinyl, trifluoromethylsulfonyl; and Phenyl, wherein the phenyl is selected from the group consisting of fluorine, chlorine, bromine, —CN, difluoromethyl and trifluoromethyl] each independently selected from Group B consisting of: Or, R 2 is thiophene, furan, pyrazole, thiazole, oxazole or isoxa sol, where each of these is Fluorine, chlorine, bromine, -CN, -NO 2 , methyl, cyclopropyl, difluoromethyl, Trifluoromethyl, methoxy, trifluoromethoxy, difluoromethoxy, methylthio O, methylsulfinyl, methylsulfonyl, difluoromethylthio, difluoromethyl Sulfinyl, difluoromethylsulfonyl, trifluoromethylthio, trifluoromethyl methylsulfinyl, trifluoromethylsulfonyl; and Phenyl, wherein the phenyl is selected from the group consisting of fluorine, chlorine, bromine, —CN, difluoromethyl and trifluoromethyl] and optionally substituted with 1 to 3 substituents independently selected from the group consisting of: Or, R 2 is C 1 -C 3 alkyl, where the alkyl is Methoxy, trifluoromethoxy, difluoromethoxy, methylthio, methylsulfini methylsulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluoro trifluoromethylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl; and Phenyl, wherein the phenyl is selected from the group consisting of fluorine, chlorine, bromine, —CN, difluoromethyl and trifluoromethyl] and is substituted with one substituent selected from the group consisting of: Or, R 2 is naphthyl; or pyrazolo[1.5-a]pyridin-2-yl [wherein may be substituted with trifluoromethyl or chlorine; R 3a , R 3b are independently hydrogen; C 1 -C 3 Alkyl, wherein the alkyl is methyl ethyl, ethyl, isopropyl, n-propyl, cyclopropyl, cyclobutyl, difluoro Oromethyl, trifluoromethyl, methoxy, ethoxy, difluoromethoxy, trifluoro oromethoxy, methylthio, methylsulfinyl, methylsulfonyl, trifluoromethyl The group consisting of ruthio, trifluoromethylsulfinyl and trifluoromethylsulfonyl cyclopropyl, diphenyl ether, Fluoromethyl, trifluoromethyl, difluoromethyl, trifluoromethyl, 2,2 -difluoroethyl, 2,2,2-trifluoroethyl, ethynyl, 2-propene-1- benzyl, wherein the phenyl substituents are fluorine, chlorine, Br, -CN, NO 2 methyl, trifluoromethyl and methoxy. heterocyclyl-methyl [ wherein the heterocyclyl substituent is a 4- to 10-membered heterocyclyl, a 5-membered heteroaryl and 6-membered heteroaryl, each of which is selected from the group consisting of fluorine. , chlorine, bromine, -CN, -NO 2 The group consisting of methyl, trifluoromethyl and methoxy. and phenyl [which may be substituted with 1 to 3 substituents independently selected from Here, the phenyl is fluorine, chlorine, bromine, -CN, -NO 2 , methyl, trifluoro and optionally substituted with one substituent selected from the group consisting of ethyl and methoxy. Selected from the group consisting of: Or, R 3a , R 3b Together with the carbon to which they are attached, they form a cyclopropane ring, a cyclobutene ring, Forms a tanane ring, an oxetane ring, or a tetrahydropyran ring; R 4 is pyridine, pyrimidine, pyrazine or thiazole, wherein (A) the pyridine is Lysine, pyrimidine, or pyrazine may be selected from the group consisting of fluorine, chlorine, bromine, —CN, and —NH. 2 , -NO 2 , -COOH, -CONH 2 , -CSNH 2 , -CO 2 Me, methyl, ethyl, difluoro Fluoromethyl, trifluoromethyl, pentafluoroethyl, cyclopropyl, methoxy, difluoromethyl Fluoromethoxy, trifluoromethoxy, methylthio, methylsulfinyl, methylsulfinyl sulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluoromethylsulfonyl sulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethyl Trisulfonyl, -NHCO-methyl, -NHCO-trifluoromethyl, -NHCO- CH 2 CN, -NHCO-cyclopropyl, -NHCO-1-cyanocyclopropyl, - N.H.S.O. 2 -Methyl, -NHSO 2 -trifluoromethyl, -NHCO-phenyl [herein and the phenyl is fluorine, chlorine, bromine, -CN, methyl, difluoromethyl, trifluoromethyl, Selected from the group consisting of fluoromethyl, methoxy, difluoromethoxy and trifluoromethoxy. -CONH-methyl, -CONH- SO 2 -methyl, -CON-(N-methyl)-N-cyclopropyl, -CONH-difluoro -O-fluoroethyl, -CONH-trifluoroethyl, -CONH-cyclopropyl, -CONH H-1-cyanocyclopropyl, -CONH-phenyl, wherein the phenyl is fluorine , chlorine, bromine, -CN, methyl, difluoromethyl, trifluoromethyl, methoxy, di 1 to 2 substituents selected from the group consisting of fluoromethoxy and trifluoromethoxy; and optionally substituted with 1 to 3 substituents selected from the group consisting of and (B) The thiazole is a fluorine, chlorine, bromine, —CN, —NO 2 , methyl, ethyl, diphenyl Fluoromethyl, trifluoromethyl, pentafluoroethyl, cyclopropyl, methoxy , difluoromethoxy, trifluoromethoxy, methylthio, methylsulfinyl, methyl sulfonyl, difluoromethylthio, difluoromethylsulfinyl, difluoromethyl trifluorosulfonyl, trifluoromethylthio, trifluoromethylsulfinyl and trifluoro and optionally substituted with 1 to 2 substituents selected from the group consisting of fluoromethylsulfonyl. ; R 5 is hydrogen, fluorine, chlorine, bromine, -CN, methyl, ethyl, isopropyl, diphenyl fluoromethyl, trifluoromethyl, cyclopropyl, methoxy or ethoxy; The compound according to any one of claims 1 to 3.
5. X is O or S; Q 1 is N; Q 2 is CR 5 and Y is a direct bond or CH 2 and R 1 is hydrogen, methyl, ethyl, 2-(trimethylsilyl)ethyl, 2,2-difluoro 2,2,2-trifluoroethyl, 3,3,3-trifluoropropyl or cyclopropyl Chloropropyl-CH 2 - and R 2 is 3-chloro-2-fluoro-5-(trifluoromethyl)phenyl, 3-methylsulfonyl-5-(trifluoromethyl)phenyl 5-(methylsulfonyl)pyridin-3-yl, 3-(methylsulfonyl)phenyl phenyl, 3-(trifluoromethylsulfonyl)phenyl, 5-[(trifluoro methyl)sulfonyl]pyridin-3-yl, 3-chloro-5-[(cyclopropylamino ) carbonyl]phenyl, 3-cyclopropyl-5-(trifluoromethyl)phenyl, 2,3,5-trichlorophenyl, 3-phenyl-5-(trifluoromethyl)phenyl , [3-chloro-5-(trifluoromethyl)phenyl]methyl, 3-(4-fluorophenyl phenyl)-5-(trifluoromethyl)phenyl, 2-chlorophenyl, 2,5-dichloro 2,3,4-trichlorophenyl, 2,3-dichlorophenyl, 2,4-dichlorophenyl Chlorophenyl, 2,6-difluorophenyl, 3-fluoro-5-(trifluoromethyl 3-chloro-5-(trifluoromethylsulfonyl)phenyl, 3-chloro-5-(trifluoromethylsulfonyl)phenyl , 5-chloro-3-thienyl, 3,4,5-trichloro-2-thienyl, 2,5-dichloro 4,5-dichloro-2-thienyl, 1-methyl-5-(trifluoro methyl)-1H-pyrazol-3-yl, 4-chloro-1-methyl-3-(trifluoro methyl)-1H-pyrazol-5-yl, 5-methyl-1,2-oxazol-3-yl , 5-cyclopropyl-1,2-oxazol-3-yl, 3-chloro-1,2-oxazol-3-yl 2-chloro-1,3-thiazol-5-yl, 1-methyl-1H-pi pyrazol-4-yl, 5-chloro-1-methyl-1H-pyrazol-4-yl, 3-chloro 3-chloro-5-(4-fluorophenyl ) sulfonylphenyl, 3-chloro-5-ethylsulfonylphenyl, 3-cyclopropyl 3-chloro-5-(isopropylthio)phenyl, 3-chloro-5-fluorophenyl, 5-(1H-pyrazol-1-yl)phenyl, 3-chloro-5-(1H-1,2, 4-triazol-1-yl)phenyl, 3-tert-butyl-5-chlorophenyl, 3-tert-butyl-5-bromophenyl, 3-fluoro-5-cyclopropylphenyl 3-chloro-5-cyclopropylphenyl, 3-chloro-5-isopropylsulfonyl 1-(4-fluorophenyl)-3-(trifluoromethyl)-1H-pyraphenyl, 3-cyclopropyl-5-(trifluoromethoxy)phenyl, 4- (trifluoromethylsulfonyl)phenyl, 3-chloro-5-[1-(methoxyimino )ethyl]phenyl, 3-(tert-butylthio)-5-chlorophenyl, 1-(4- 1-(4-fluorophenyl)-5H-pyrazol-4-yl -(trifluoromethyl)-1H-pyrazol-3-yl, 5-[4-(trifluoromethyl) 3-chloro-5-methylsulfanylphenyl , 3-chloro-5-methylsulfinylphenyl, 3-benzamido-5-chlorophenyl 3-(tert-butylsulfonyl)-5-chlorophenyl, 5-[4-(trifluorophenyl) -pyridin-3-yl, 5-[4-(trifluoromethoxy)phenyl]- phenyl]-pyridin-3-yl, 5-(4-chlorophenyl)pyridin-3-yl, 5- (4-fluorophenyl)pyridin-3-yl, 3-chloro-5-[(phenylsulfonyl 3-acetamido-5-chlorophenyl, 3-chloro-5-[( cyclopropylcarbonyl)amino]phenyl, 3-chloro-5-[(2,2,2-tri fluoroethyl)sulfinyl]phenyl, 3-chloro-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl (3-chloro-5-[3-(trifluoromethyl)- 1H-pyrazol-1-yl]phenyl, 3,5-bis(methylsulfonyl)phenyl, Pyrazolo[1,5-a]pyridin-2-yl, 7-(trifluoromethyl)pyrazolo[1 ,5-a]pyridin-2-yl, 6-chloropyrazolo[1,5-a]pyridin-2-yl , naphth-2-yl, 3-[4'-(trifluoromethoxy)phenyl]-phenyl, 3 -(4'-fluorophenyl)-5-(trifluoromethyl)phenyl or 3-chloro- 5-(1-cyanocyclopropyl)phenyl; R 3a is hydrogen, methyl or methoxymethyl; R 3b is R 3a when is hydrogen, is methyl or methoxymethyl; R 3b is R 3a is hydrogen when is methyl or methoxymethyl; R 3a and R 3b together with the carbons to which they are attached form a cyclopropane ring; R 4 pyridin-2-yl, pyrimidin-2-yl, pyrimidin-4-yl, 5-fluoro 5-chloropyrimidin-2-yl, 5-cyanopyrimidine -2-yl, 5-(trifluoromethyl)pyrimidin-2-yl, 5-methylpyrimidine 5-fluoropyridin-2-yl, 5-chloropyridin-2-yl, 2-chloropyridin-2-yl Loropyridine-4-yl, 5-cyanopyridin-2-yl, 4-cyano-pyridin-2-yl yl, 6-cyano-pyridin-2-yl, 5-methoxy-pyridin-2-yl, 5-(trimethylsilyl) 5-(difluoromethoxy)pyridine-2-yl, 5-(difluoromethoxy)pyridine-2-yl yl, 5-(trifluoromethylthio)pyridin-2-yl, 5-nitropyridin-2-yl yl, 5-aminopyridin-2-yl, 3,5-difluoropyridin-2-yl, 5-chloropyridin-2-yl 3-fluoropyridin-2-yl, pyridin-2-yl-5-carboxylic acid, pyridinyl Methyl N-pyridin-2-yl-5-carboxylate, Methyl N-pyridin-2-yl-5-carboxylate N-cyclopropyl-pyridin-2-yl-5-carboxamide, N-cyclopropyl propyl-N-methyl-pyridin-2-yl-5-carboxamide, N-(1-cyanocyclohexyl) N-(2,2-difluoropropyl)-pyridin-2-yl-5-carboxamide N-(2,2,2-trifluoroethyl)-pyridin-2-yl-5-carboxamide N-methylsulfonyl-pyridine- 2-yl-5-carboxamide, N-(4-fluorophenyl)-pyridin-2-yl- 5-Carboxamide, 5-acetamidopyridin-2-yl, 5-(trifluoroacetate Amido)-pyridin-2-yl, 5-(2-cyanoacetylamino)-pyridin-2-yl 5-[(cyclopropylcarbonyl)amino]pyridin-2-yl, 5-[(1-cyclopropylcarbonyl)amino]pyridin-2-yl 5-(methanesulfonyl)amino)-pyridin-2-yl amide)-pyridin-2-yl, 5-(trifluoromethylsulfonamido)-pyridine -2-yl, 5-[(4-fluorobenzoyl)amino]pyridin-2-yl pyrazine -2-yl, 2-cyano-pyrazin-5-yl or 1,3-thiazol-2-yl ; R 5 is hydrogen, methyl or trifluoromethyl; The compound according to any one of claims 1 to 4.
6. Formula (I') 【Chemistry 2】 [Wherein, structural elements Y, Q 1 , Q 2 , R 1 , R 2 , R 3a , R 3b , R 4 and R 5 is a claim In the sense given in claim 1 or in the sense given in claim 2 or in claim 3 or in the sense given in claim 4 or in the sense given in claim 5. have the meaning given to them in The compound according to any one of claims 1 to 5, characterized in that it has a structure represented by:
7. Q 1 is N or CR 5 and Q 2 represents N, as well as all further structures Elements Y and R 1 , R 2 , R 3a , R 3b , R 4 and R 5 is given in claim 1 or the meaning given in claim 2 or the meaning given in claim 3 or the meaning given in claim 4 or the meaning given in claim 5 The compound according to any one of claims 1 to 6, comprising:
8. Q 1 represents N, and Q 2 is CR 5 and all further structural elements Y , R 1 , R 2 , R 3a , R 3b , R 4 and R 5 has the meaning given in claim 1 or in the sense given in claim 2 or in the sense given in claim 3 or having the meaning given in claim 4 or the meaning given in claim 5 The compound according to any one of claims 1 to 6.
9. Formula (a * ) 【Chemistry 3】 [In the formula, structural elements Y, R 1 , R 2 , R 3a and R 3b is given in claim 1 or the meaning given in claim 2 or the meaning given in claim 3 or the meaning given in claim 4 or the meaning given in claim 5 have A compound represented by the formula:
10. Formula (b * ) 【Chemistry 4】 [During the ceremony, E is hydrogen or C 1 -C 6 is alkyl; A is -CN, chlorine or fluorine; L is S, SO or SO 2 is A compound represented by the formula:
11. Formula (c * ) 【Chemistry 5】 [During the ceremony, E is hydrogen or C 1 -C 6 is alkyl; A is bromine, chlorine, fluorine, -CN or trifluoromethyl, preferably chlorine. is A compound represented by the formula:
12. Formula (d * ) 【Chemistry 6】 [During the ceremony, E is hydrogen or C 1 -C 6 is alkyl; A is bromine, chlorine or fluorine, preferably chlorine; L is S, SO or SO 2 and preferably S or SO 2 and more preferably , SO 2 and J is ethyl, isopropyl, tert-butyl, cyclopropyl, 2,2,2-trimethylsilyl; trifluoroethyl or 4-fluorophenyl. A compound represented by the formula: Here, the formula (d * The compound represented by the formula (I) is 3-(ethylsulfanyl)-5-fluorobenzoate. Neither benzoic acid nor 3-(tert-butylsulfanyl)-5-fluorobenzoic acid stomach.
13. 3-Cyclopropyl-5-(trifluoromethoxy)benzoic acid and 3-cyclopropyl -5-(trifluoromethoxy)benzoic acid methyl ester.
14. Formulations, in particular agrochemical formulations, comprising the compound of formula (I) according to any one of claims 1 to 8 The formulation comprises at least one compound.
15. In addition, the composition may contain at least one bulking agent and / or at least one surfactant. The formulation of claim 14.
16. The compound of formula (I) is mixed with at least one further active compound 16. The formulation according to claim 14 or 15, characterized in that
17. A method for controlling pests, particularly insects, comprising the step of: The compound represented by formula (I) or the formulation according to any one of claims 14 to 16 is used to treat said pests and and / or their habitat.
18. The pest is a pest and includes insects, arachnids, or nematodes. or wherein the pest is an insect, an arachnid or a nematode; 20. The method of claim 17.
19. A compound of formula (I) according to any one of claims 1 to 8 for controlling insect pests. Use of a formulation according to any one of claims 14 to 16.
20. The pests include insects, arachnids or nematodes, or the pests include insects, 20. The use according to claim 19, characterized in that the animal is an arachnid or a nematode.
21. 21. Use according to claim 19 or 20 in crop protection.
22. 21. Use according to claim 19 or 20 in the field of animal health.
23. A method for protecting seeds or germinating plants from pests, particularly insects, comprising: A compound represented by formula (I) according to any one of claims 1 to 8 or any one of claims 14 to 16. The method comprises the step of contacting the subject with any one of the formulations described above.
24. Seeds obtained by the method according to claim 23.
Citation Information
Patent Citations
5-trifluoroacylamino-2-aryl oxazole
JP1993506244A
Therapeutic agent for neuroretinal degenerative disease
JP2001172258A
Acylated Aminoacetonitriles as Cysteine Protease Inhibitors
JP2002537285A
Heteropolycyclic compounds and their use as metabotropic glutamate receptor antagonists
JP2003507378A
Heteropolycyclic compounds and their use as metabotropic glutamate receptor antagonists
JP2004536037A