Composite Panes

Abstract

The present invention relates to a composite pane having an IR-reflective coating and a low-emissivity coating, to a method for obtaining said pane, and to its uses.

Description

[Technical field]

[0001] The present invention relates to a composite pane having an IR reflective coating and a low emissivity coating, a method for providing said pane, and uses thereof. [Background technology]

[0002] Composite panes with sun shielding are well known in the art.

[0003] EP 1 060 876 A2 relates to a glazing comprising at least two pieces of glass joined by a thermoplastic layer and a solar shielding layer reflecting radiation outside the visible spectrum of solar radiation, in particular infrared radiation. A transparent low-emissivity layer reflecting thermal radiation is arranged towards the inside of the solar shielding layer. The thermal radiation reflecting layer is preferably a layer of a pyrolytically deposited doped metal oxide, in particular fluorine-doped tin oxide, with at least one sublayer and / or at least one top layer, and in particular a mechanically resistant protective layer. The solar shielding layer comprises a stack of layers, including at least one metal layer, in particular at least one silver-based layer, contained between two layers of metal oxide or nitride, for example AlN or Si3N4. The glazing can be used as a windshield, side window, rear window or roof of a motor vehicle.

[0004] WO 2016 / 184732 A1 relates to a pane for separating an interior from an external environment, comprising at least a substrate (1), a thermal radiation-reflective coating (2) on an interior surface (i) of the substrate (1), the coating having at least one functional layer (2a) comprising a transparent conductive oxide (TCO) and a top layer (2b), the top layer (2b) comprising silicon dioxide (SiO2), and a polymeric fixing or sealing element (3) on the thermal radiation-reflective coating (2).

[0005] WO 2019 / 110172 discloses a composite pane comprising an outer pane (1) having an outer surface (I) and an inner surface (II); an inner pane (2) having an outer surface (III) and an inner surface (IV); and a thermoplastic intermediate layer (3) joining the inner surface (II) of the outer pane (1) to the outer surface (III) of the inner pane (2), said composite pane comprising at least one solar shielding coating (4) between the outer pane (1) and the inner pane (2), said solar shielding coating reflecting or absorbing radiation mainly outside the visible spectrum of solar radiation, in particular infrared radiation, said composite pane comprising a thermal radiation reflecting coating (5) (low-E coating) on ​​the inner surface (IV) of the inner pane (2), said composite pane being characterized in that it has a transmittance index A of 0.02 to 0.08, said transmittance index A being calculated according to the formula (I): A=TL 複合ガラスペイン / (TL低E被覆ペイン*TE) (I), where TL is the light transmittance and TE is the energy transmittance measured in accordance with ISO 9050.

[0006] Glazing, such as that used in sunroofs and sliding roofs, requires 2-10% light transmission and specific solar blocking.

[0007] To obtain such low light transmission, an obscuring sheet must be present in the laminated glazing, which may be a tinted glass sheet or a tinted thermoplastic interlayer.

[0008] Typically, colored thermoplastic interlayers contain pigments and dyes that can deteriorate due to the effects of sunlight and heat. Deterioration of the content of the colored thermoplastic interlayer can also result in loss of adhesion and loss of cohesive strength within the colored thermoplastic interlayer. This is especially true when the colored thermoplastic interlayer is derived from recycled thermoplastic materials.

[0009] The recycled thermoplastic material can be obtained by reprocessing of used material and / or remaining parts of new thermoplastic material obtained, for example, after cutting and sizing. The disassembly and recovery of individual components of laminated glazing has been known since the early 1990s. The reuse of composite materials has not been given much consideration in the past, but the situation is now changing in view of the increasing interest in environmental issues related to industrial applications. The recycled thermoplastic material is typically obtained from a mixture of used interlayers and / or interlayer scrap from various sources.

[0010] Despite technological efforts in the field of recycling of thermoplastic materials, some recycled materials cannot show the exact same properties as the original materials, also called "virgin" or "new" materials. The main problem associated with such recycled materials is their insufficient chemical stability due to their different origin. Recycled materials with two or more compositions mean that there are different chemistries in terms of basic interlayer resins, type and amount of plasticizers, or adhesion modifier ions mixed in one product. Since classification is rarely or not performed at all, the exact chemical composition of the recycled materials may not be stable over time.

[0011] This has proven to be particularly problematic in the case of laminated coated glass, where the thermoplastic interlayer is heated by the sun's radiation, leading to a deterioration in the adhesive properties and breakage resistance. This problem has not arisen with "virgin" PVB with standard coatings developed up to now. This manufacturing hazard is unacceptable.

[0012] While a slight decrease in the quality of recycled materials may be acceptable, a slight decrease in safety may not be acceptable.

[0013] Coated glass substrates are well known in the field of laminated glazing. They can be coated to provide solar control, thermal control or other functions. Such coated glass substrates can be used in laminated form with thermoplastic materials. With the rise of recycled thermoplastic materials, in practice, some of these materials seem unable to show consistent quality in bonding with coated glass substrates.

[0014] Therefore, for long term use of vehicles, it is important that roofs and windows have a life span of at least more than 10 years, despite the existence of recycled thermoplastic materials. Summary of the Invention

[0015] It is therefore an object to provide a composite pane that meets current demands with regard to temperature management, light management, has a long shelf life and includes at least one thermoplastic interlayer that includes at least 10% recycled material.

[0016] Therefore, a composite pane aims to have the following characteristics: - Light transmission of 1-10% to ensure the best possible compromise between the view to the outside through the roof and thermal properties; - Light reflectance observed from the outside Rext<13%; - Light reflectance observed from the inside Rin<8%.

[0017] The composite pane is expected to have a shelf life of at least 10 years. This object is achieved according to the invention by a composite pane as claimed in claim 1. [Brief description of the drawings]

[0018] [Figure 1] FIG. 1 shows a cross section of one embodiment of a composite pane according to the present invention. [Diagram 2] FIG. 2 shows a cross-section of a second embodiment of a composite pane according to the present invention, which is compatible with another embodiment of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0019] Composite panes are intended in a window opening to separate an interior space, in particular to separate the interior of a vehicle from the external environment. A composite pane is a laminate, which in the context of the present invention is called "outer pane" and "inner pane", and which comprises a first pane and a second pane, which are joined to each other via a thermoplastic intermediate layer. In the context of the present invention, "inner pane" is the pane which faces the inside in the installed position. "Outer pane" means the pane which faces the outside environment in the installed position. "Inner surface (or inner or inner surface)" means in the context of the present invention the surface of the pane which faces the inside in the installed position. "Outer surface (outer or outer surface)" means in the context of the present invention the surface of the pane which faces the outside environment in the installed position.

[0020] The surfaces of the panes are typically referenced as follows: the exterior side of the outer pane is referred to as side 1. The interior side of the outer pane is referred to as side 2. The exterior side of the inner pane is referred to as side 3. The interior side of the inner pane is referred to as side 4. The interior surface of the outer pane and the exterior surface of the inner pane face each other and are joined to each other by a thermoplastic interlayer.

[0021] The outer and inner panes may independently be glass sheets, or plastic sheets including or consisting of poly(methyl meth)acrylate (PMMA), polycarbonate, polyethylene terephthalate (PET), polyolefins, polyvinyl chloride (PVC), or mixtures thereof.

[0022] In most cases, at least one of the outer and inner panes will be a glass substrate, however, it is preferred that both the outer and inner panes are glass substrates.

[0023] The glass may be of any type, such as conventional float glass or flat glass, and may be of any composition having any optical property, such as any value of visible transmittance, ultraviolet transmittance, infrared transmittance, and / or total solar energy transmittance greater than 10%.

[0024] Thus, the glass may be of the soda-lime-silica, aluminosilicate, or borosilicate type, etc. The glass composition typically comprises the following components (Comp. A): In all glass compositions described herein, the amounts are expressed in weight percentages or ppm by weight, expressed based on the total weight of the glass.

[0025] The glass may be a regular clear, tinted, or ultra-clear (i.e., lower iron content and higher transmittance) glass substrate. Further examples of glass substrates include clear, green, bronze, or blue-green glass substrates.

[0026] The preferred glass substrates for the inner and outer panes can be selected from clear or ultra-clear soda-lime glass. They typically have a light transmission of at least 89% (for a glass sheet thickness of 4 mm). They can be considered colorless when viewed through their main surface. These clear glass types have the great advantage that they do not accumulate heat, thus reducing the heat absorption from the sun's rays, which in turn reduces the need for air conditioning inside the vehicle. In particular, when the outer glass sheet is such a high-transmittance glass sheet, the IR-reflective layer present in the composite pane can be sufficiently effective in reflecting the heat rays, so that the heat is not absorbed in the glass sheet and the temperature management is optimized.

[0027] A typical composition of soda-lime silicate type glasses (Comp. B) is as follows: TIFF2025509132000002.tif57170

[0028] In the art, "ultra-white" or "extra-clear" or "low iron" glasses have long been known in the solar or architectural fields due to their high luminous transmittance and / or energy transmittance (at least 90% for a glass sheet thickness of 4 mm). These glasses contain small amounts of iron, such as 0.002-0.06% by weight, preferably 0.002-0.04% by weight, more preferably 0.002-0.02% by weight of total iron (expressed as Fe2O3).

[0029] Examples of suitable transparent soda-lime glasses include types of glasses that have high transmittance at infrared wavelengths obtained by adding certain oxidizers, such as chromium oxide, cobalt oxide, selenium oxide, manganese oxide, and / or cerium oxide, to a base soda-lime composition. For example, a glass composition comprising, in contents expressed as percentages in the total weight of the glass: total iron (expressed as Fe2O3) in an amount of 0.002-0.06 wt.-%; and Cr2O3 in an amount of 0.0001-0.06 wt.-%, preferably 0.002-0.06 wt.-%; or a glass composition comprising, in contents expressed as percentages in the total weight of the glass: Cr2O3 in an amount of 0.0015-1 wt.-% and Co in an amount of 0.0001-1 wt.-%; or a glass composition comprising, in contents expressed as percentages in the total weight of the glass: total iron (expressed as Fe2O3) in an amount of 0.02-1 wt.-%, preferably 0.06-1 wt.-%, Cr2O3 in an amount of 0.002-0.5 wt.-%; and Co in an amount of 0.0001-0.5 wt.-%. Another solution to obtain low iron glass with very high transmission in the infrared is to use cerium oxide (0.001-1% by weight) and / or combinations of known oxidizers such as manganese (0.01-1% by weight MnO), antimony (0.01-1% by weight Sb2O3), arsenic (0.01-1% by weight As2O3), and / or copper (0.0002-0.1% by weight CuO). The composition is chosen so that the glass sheet is a transparent glass.

[0030] Further examples of suitable transparent soda-lime glasses include those formulated to be more easily chemically tunable and more conveniently ion-exchanged than conventional soda-lime-silica glass compositions, while remaining easy to manufacture, particularly on existing lines of conventional soda-lime-silica glass production. Such glass compositions may include compositions C to E of the following components. Preferably, these glasses contain a small amount of iron, for example 0.0001 to 0.06 wt. %, preferably 0.002 to 0.04 wt. %, more preferably 0.002 to 0.02 wt. % total iron (expressed as Fe2O3). TIFF2025509132000003.tif80170

[0031] Further examples of suitable transparent soda-lime glasses include those formulated to provide high luminous transmittance and colorless / achromatic edges. Such glass compositions may include, in terms of content expressed as a percentage of the total weight of the glass: 0.002-0.04 wt. % total iron (expressed in the form of Fe2O3) in a redox ratio ≦32%, 0.003-0.1 wt. % erbium (expressed in the form of Er2O3), where: 1.3*Fe2O3≦Er2O3-21.87*Cr2O3-53.12*Co≦2.6*Fe2O3.

[0032] Another example of a clear soda-lime glass composition can include the following components, expressed as percentages of the total weight of the glass: total iron (expressed as Fe2O3) in an amount of 20 to 750 ppm; selenium (expressed as Se) in an amount of 0.1 to <3 ppm; cobalt (expressed as Co) in an amount of 0.05 to 5 ppm; and a ratio of Er2O3 / Fe2O3 of 0.1 to 1.5.

[0033] The glass may be annealed, tempered, or heat strengthened glass.

[0034] The outer and inner panes may independently have a thickness in the range of 0.5 mm to 15 mm, alternatively 0.5 mm to 10 mm, alternatively 0.5 mm to 8 mm, alternatively 0.5 mm to 6 mm.

[0035] The outer and inner panes in the composite pane may have a thickness in the range of 0.5 to 4 mm.

[0036] Both panes can have the same thickness, for example 0.5 mm, or 0.8 mm, or 1.2 mm, or 1.6 mm, or 2.1 mm, or 3 mm. Such a symmetrical structure of the glass thickness facilitates the process and allows conventional sizing of the lamination process.

[0037] Both panes may have different thicknesses resulting in an asymmetric laminated glazing, for example pane 1=0.5 mm and pane 2=2.1 mm, or pane 1=0.8 mm and pane 2=2.1 mm, or pane 1=0.5 mm and pane 2=1.6 mm, pane 1=0.8 mm and pane 2=1.6 mm, or pane 1=1.6 mm and pane 2=2.1 mm. Such an asymmetric structure of the glass thickness allows freedom of curvature and / or weight management and / or freedom of light / solar modulation.

[0038] As used herein, the terms "polymer interlayer sheet", "interlayer" can generally refer to a monolayer sheet or a multilayer interlayer. A "monolayer sheet", as the name suggests, is a single or monolithic thermoplastic layer extruded as a layer, which is then used to laminate two panes. A multilayer interlayer, on the other hand, can include multiple layers, including separately extruded layers, coextruded layers, or any combination of separate layers of thermoplastic material and coextruded layers. Thus, a multilayer interlayer can include, for example: two or more monolayer sheets combined together ("multilayer sheet"); two or more layers coextruded together ("coextruded sheet"); two or more coextruded sheets combined together; a combination of at least one monolayer sheet and at least one coextruded sheet; a combination of at least one multilayer sheet and at least one coextruded sheet, or any other combination of sheets as desired.

[0039] Thus, the thermoplastic interlayer may be formed by one or more thermoplastic films, where at least one film contains at least 10% recycled material.

[0040] Thermoplastic film layers containing at least 10% recycled material can be obtained by methods known in the art, which are not the subject of the present invention. In the recycling method of thermoplastic materials, typically chopping, grinding and washing with solvents and / or water are performed to separate the glass and thermoplastic material, followed by separation of the other chemicals present (stabilizers, plasticizers, dyes, etc.) from said materials, followed by extraction and / or filtration. The thermoplastic material obtained can then be used again, for example using an alcohol process. There are various methods that result in materials with similar or equivalent chemical and physical properties to standard (new / virgin) materials. This means that when used, different properties appear, with altered behavior towards heat and solar radiation, or a change in appearance can be observed, depending on the composition of the thermoplastic film material, such as pigments and dyes and additives.

[0041] Recycled materials within the scope of the present invention require materials obtained from different interlayer products or manufacturers and collected after at least one first use, including materials recovered from lamination process remains, waste rolls, or excess materials. That is, thermoplastic film layers that have been processed during the lamination step and are separated from the final laminate can be collected, mixed, and reprocessed to provide recycled materials. Such recycled materials are typically obtained from a mixture of initial materials from different sources, so that the chemical composition is more variable than that of "new" or "virgin" thermoplastic film layers. In fact, "new" or "virgin" thermoplastic materials typically have a reproducible and calibrated composition, which is consistently constant over time as a result of the specific chemical composition, and therefore the presence of specific ions is defined by their origin and source. The thermoplastic materials typically contain metal salts, or preferably alkali metal salts, or even more preferably alkaline earth metal salts, which are typically used as adhesion modifiers to maintain sufficient adhesion between the glass and the "new" thermoplastic film, thereby ensuring the adhesion of the material to the glass pane.

[0042] For example, a "new" thermoplastic material (PVB) from one PVB sheet manufacturer may be characterized by the presence of Mg and Na ions, or the presence of Mg and K ions, while a "new" thermoplastic material (PVB) from another PVB sheet manufacturer may be characterized by the presence of K and S ions in addition to Mg and Na ions.

[0043] Recycled materials, on the other hand, typically contain waste materials of various initial virgin thermoplastic materials of different commercial sources and therefore different compositions, so that their combination after recycling contains a wider variety of ions than the original virgin thermoplastic materials, since it varies in composition from batch to batch and is obtained from a mixture of different sources.

[0044] Recycled materials useful in the present invention can be characterized by compositions that include a wide variety of ions, typically including at least the ions Mg, Na, K, S, P, Li, Rb, Cs, Ca, Sr, and Ba. These ions are thus remnants of the mixture of metal salts that are recovered from the original "new" or "virgin" thermoplastic film layers after the recycling procedure.

[0045] Although thermoplastic film layers containing at least 10% recycled material are intended to have similar properties as standard / virgin materials, experience has shown that thermoplastic film layers containing at least 10% recycled material may vary in ionic concentration from batch to batch. Without wishing to be bound by theory, it is believed that such varying chemical composition may be a major factor in varying adhesion performance to panes and varying stability to pigments and / or colorants. Poor compatibility with materials may ultimately result in safety issues such as reduced adhesion over time and / or color degradation and / or reduced aesthetics over time. Variations in composition may also result in variations in appearance.

[0046] Within the scope of the present invention, the thermoplastic interlayer is formed from at least one thermoplastic film layer that contains at least 10% recycled material, alternatively at least 20% recycled material, alternatively at least 60% recycled material, alternatively 100% recycled material. Typically, the remainder of the thermoplastic interlayer may be formed from film layers of virgin material that may be of the same type or different from the at least one thermoplastic film layer that contains at least 10% recycled material.

[0047] In some cases, the thermoplastic intermediate layer is formed entirely from thermoplastic film layers that contain at least 10% recycled material, which can have the same or different composition.

[0048] In other cases, the thermoplastic interlayer is a thermoplastic film layer that contains at least 10% recycled material, alternatively at least 20% recycled material, alternatively at least 60% recycled material, or alternatively 100% recycled material. .

[0049] Exemplary materials for the thermoplastic interlayer include, but are not limited to, polyvinyl acetal, polyvinyl butyral, polyurethane, poly(ethylene-co-vinyl acetate), polyvinyl chloride, poly(vinyl chloride-co-methacrylate), polyethylene, polyolefins, ethylene acrylate ester copolymers, poly(ethylene-co-butyl acrylate), silicone elastomers, epoxy resins, and acid copolymers.

[0050] The thermoplastic film preferably comprises polyvinyl butyral (PVB), ethylene vinyl acetate (EVA), polyurethane (PU), and / or mixtures and / or copolymers thereof, particularly preferably polyvinyl butyral.

[0051] The films are preferably based on the materials described, but may contain other components, such as plasticizers, photophores, thermal insulating particles, infrared absorbing particles, polymer dispersed liquid crystals, suspended particles, pigments, colorants, or UV absorbers, preferably at a content of less than 50%.

[0052] At least one thermoplastic film layer containing at least 10% recycled material has a light transmittance of 1-20%, preferably 1-15%, more preferably 1-10%, most preferably 1-8%, measured with a 2° observer by Illuminant A. As is well known in the art, the light transmittance of a thermoplastic film layer can be calculated from the light transmittance value of a laminated form of said thermoplastic film layer of 0.76 mm between two sheets of 2.1 mm clear glass, according to the standard EN410 (2011). The change in thickness of the glass sheets can typically affect the light transmittance of the thermoplastic film layer by up to 0.01%.

[0053] The lower the light transmission of the thermoplastic film layer, the better the protection of the comfort of the interior compartment, while still allowing some visibility through the composite pane.

[0054] By using a thermoplastic polymer film containing at least 10% recycled material with such a light transmission, the final composite pane can reach a light transmission (measured using Illuminant A, 2°) of 1-10%, preferably 1%-7%.

[0055] The individual thermoplastic film layers preferably have a thickness of from about 0.2 mm to 1 mm, for example 0.38 mm or 0.76 mm.

[0056] Examples of polyvinyl butyral thermoplastic film layers containing at least 10% recycled material include Trosifol® from Kuraray Corp., Butacite® G from Dupont, Butvar or Saflex® from Eastman, or products from Sekisui Corp.

[0057] At least one of the infrared reflective coating and the low emissivity coating of the present invention is each independently provided as a thin film coating having a thickness in the range of 10 to 1000 nm.

[0058] When discussing the infrared reflective and low emissivity coatings of the present invention, it is understood that the layers are typically numbered in order starting from the substrate surface. That is, the first layer is understood to be the first one attached to the substrate, the second one is the second layer attached to the substrate over the first layer, etc. The sequential order of positions is considered to be relative to the substrate going up to the top layer.

[0059] Within the scope of the present invention, the terms "lower", "bottom" and "lower" refer to the relative position of a layer facing the next layer in the layer sequence starting from the substrate. Within the scope of the present invention, the terms "upper" and "upper" refer to the relative position of a layer facing the next layer in the layer sequence starting from the substrate.

[0060] Within the scope of the present invention, the relative positions of layers in a stack do not necessarily indicate direct contact between the layers. That is, there may be some intermediate layer between the first and second layers. For example, a first layer "deposited on" a substrate does not exclude the presence of one or more other coating layers of the same or different composition located between the film of the first layer and the substrate, unless the object of the present invention is compromised.

[0061] In some cases, a layer may actually be made up of several individual layers.

[0062] Unless otherwise stated, all layer thicknesses herein are geometric layer thicknesses.

[0063] In accordance with the present invention, a low-emissivity coating is applied on the interior side (side 4) of the inner pane. Such a low-emissivity coating reflects thermal radiation, i.e., particularly IR radiation with longer wavelengths than the IR component of solar radiation. At low exterior temperatures, the low-emissivity coating reflects heat back to the interior, reducing interior cooling. At high exterior temperatures in the summer, the low-emissivity coating on the interior side of the inner pane reduces radiation of heat to the exterior environment in the winter while reducing radiation of thermal radiation from the pane to the interior.

[0064] The low-emissivity coating comprises at least one functional layer comprising a transparent conductive oxide (TCO) selected from indium tin oxide, antimony-doped or fluorine-doped tin oxide, zinc oxide doped with gallium and / or aluminum, mixed indium zinc oxide, vanadium oxide, vanadium oxide doped with tungsten and / or magnesium, titanium oxide doped with niobium, cadmium stannate, and / or zinc stannate.

[0065] Preferred transparent conductive oxides (TCOs) may be selected from indium tin oxide, antimony-doped or fluorine-doped tin oxide, and / or aluminum-doped zinc oxide (ZnO:Al), and / or gallium-doped zinc oxide (ZnO:Ga), with indium tin oxide or fluorine-doped tin oxide being most preferred.

[0066] The refractive index of the material of the TCO functional layer is preferably between 1.7 and 2.5.

[0067] The emissivity of the pane according to the invention can be influenced by the thickness of the functional layer of the low-emissivity coating. The thickness of at least one functional layer can be in the range of 75 nm to 210 nm, preferably 90 nm to 175 nm, most preferably 105 nm to 170 nm. This range allows an optimal compromise between the low-emissivity of the pane and resistance to heat treatment. Within the scope of the invention, the low-emissivity coating can be characterized by an emissivity <0.2 (in accordance with standard EN 12898).

[0068] Suitable first low-emissivity coatings include coatings that include, in order: a first low refractive index layer, such as silicon oxide, and a transparent conductive oxide layer.

[0069] This first suitable low-emissivity coating makes it possible to reach a light reflectance Rin on the inside of the vehicle of <10% or even <8%.

[0070] In a second suitable low-emissivity coating, at least one TCO functional layer can be surrounded by dielectric layers that can have alternating low and high refractive indices. In particular, the first dielectric layer, i.e., the layer below the TCO functional layer, can include a first sublayer of a high refractive index material, followed by a second sublayer of a low refractive index material. The second dielectric layer, i.e., the layer above the TCO functional layer, can include a third sublayer of a high refractive index material, followed by a fourth sublayer of a low refractive index material.

[0071] Examples of high refractive index dielectric layers with refractive index >1.7 or >1.8 include zirconium doped titanium dioxide, silicon doped titanium dioxide, mixed oxides of zinc and tin, and mixed oxides of titanium and silicon.

[0072] Examples of low refractive index dielectric layers with a refractive index ≦1.6, or ≦1.55 include silicon oxide, zirconium doped silicon oxide, mixed oxides of silicon and aluminum, and magnesium fluoride.

[0073] Optimal low-emissivity coatings include coatings that include, in order: a first high refractive index layer, a first low refractive index layer, a transparent conductive oxide layer, an optional barrier layer, a second low refractive index layer, and an optional topcoat layer having a low refractive index.

[0074] The first high refractive index layer may have a thickness in the range of 7 to 23 nm, alternatively 8 to 20 nm, alternatively 9 to 19 nm.

[0075] The first low refractive index layer may have a thickness in the range of 18 to 55 nm, alternatively 20 to 50 nm, alternatively 25 to 45 nm.

[0076] The transparent conductive oxide layer may have a thickness in the range of 75 to 210 nm, alternatively 90 to 175 nm, alternatively 105 to 170 nm.

[0077] The optional barrier layer may have a thickness in the range of 0 to 15 nm, alternatively 1 to 15 nm, alternatively 1 to 12 nm.

[0078] The second low refractive index layer may have a thickness in the range of 40 to 110 nm, alternatively 45 to 105 nm, alternatively 50 to 95 nm.

[0079] The optional topcoat may have a thickness in the range of 2 to 40 nm, alternatively 5 to 35 nm, alternatively 6 to 30 nm.

[0080] The optional topcoat may be a layer of silicon oxide containing zirconium in an amount of 5-40 mole %. Such a top layer allows for example to adjust the neutral color rendering of the low-emissivity coating with good resistance to scratches. Indeed, since the low-emissivity coating is placed towards the passenger compartment, it may be subject to wear and scratches due to cleaning or passenger occupancy. Such passenger occupancy may affect the integrity of the coating, such as friction or objects (umbrellas, balls, clothing, etc.). This top layer may also provide compatibility and adhesion to the fastening elements that are later used to fasten the composite pane in the frame of the vehicle.

[0081] An optimal low-emissivity coating may therefore include a coating comprising, in order: a first high refractive index layer having a thickness in the range of 7-23 nm, a first low refractive index layer having a thickness in the range of 18-55 nm, a transparent conductive oxide layer having a thickness in the range of 75-210 nm, an optional barrier layer having a thickness in the range of 0-15 nm, a second low refractive index layer having a thickness in the range of 40-110 nm, and an optional topcoat layer having a low refractive index and a thickness in the range of 2-40 nm.

[0082] Typically, a pane of clear float glass (soda-lime glass) provided with such an optimized low-emissivity coating can have a light transmission of 85-94%.

[0083] With this optimal low-emissivity coating it is possible to reach very low light reflectance values ​​of Rin<4%, or Rin<3%, or even Rin<2% inside the vehicle.

[0084] This optimal low-emissivity coating can be characterized by an emissivity of <0.15 (in accordance with standard EN 12898).

[0085] Yet another example of a suitable low-emissivity coating may be a low-emissivity coating comprising at least two layers of transparent conductive oxide, each having a thickness in the range of 20-80 nm, separated by at least one layer of dielectric material. Thus, such a low-emissivity coating may comprise n' TCO layers and n'+1 dielectric layers, where n'≧1, and each IR layer is surrounded by two dielectric layers. Examples of the dielectric layers of such suitable low-emissivity coatings include silicon oxide, silicon nitride, zinc oxide, tin oxide, or alloys or mixtures thereof.

[0086] In accordance with the present invention, an IR reflective coating is present between the outer and inner panes. The primary role of such an IR reflective coating is to reflect the infrared portion of solar radiation, thereby reducing heat transfer towards the interior of the vehicle.

[0087] Within certain embodiments of the present invention, one further role of the IR reflective coating may be to form a light shield for the thermoplastic interlayer to protect the pigments / ingredients of the interlayer from the sun's rays while ensuring the thermal performance of the composite pane.

[0088] Thus, a preferred arrangement includes at least one IR-reflective coating embedded within (i.e., inside) the thermoplastic interlayer or at least one IR-reflective coating applied directly onto the interior surface of the outer pane, which provides improved protection of the at least one thermoplastic film layer containing at least 10% recycled material from external rays, thereby preventing its (pigment, etc.) degradation, thereby maintaining the quality of the composite pane over time.

[0089] In some alternative embodiments, the composite pane can include an IR-reflective coating embedded in the intermediate layer and an IR-reflective coating attached to the interior surface of the outer pane.

[0090] When the IR reflective coating is embedded in a thermoplastic interlayer, the IR reflective coating is attached to a carrier film that is disposed between two thermoplastic films, the carrier film preferably comprising polyethylene terephthalate (PET) and having a thickness of 0.012 to 0.2 mm.

[0091] Where an IR reflective coating is applied on the surface of the pane facing the thermoplastic interlayer, this is typically applied by a physical vapour deposition process.

[0092] An IR-reflective coating can include n infrared-reflective (IR) layers and n+1 dielectric layers, where n≧1, and each IR layer is surrounded by two dielectric layers.

[0093] The IR-reflective coating preferably comprises n infrared-reflective (IR) layers and n+1 dielectric layers, where n>1, and each IR layer is surrounded by two dielectric layers. Such an IR-reflective coating provides an optimal compromise between solar shielding efficiency and cost.

[0094] The IR reflective layer may be made of silver, gold, palladium, platinum, or alloys thereof.

[0095] The IR reflective or functional layer can have a thickness of 2 to 30 nm, alternatively 5 to 20 nm, alternatively 7 to 18 nm. These thickness ranges can provide the desired solar control function and / or conductivity (if required).

[0096] The dielectric layer may typically comprise an oxide, nitride, oxynitride, or oxycarbide of Zn, Sn, Ti, Zr, Si, In, Al, Bi, Ta, Hf, Mg, Nb, Y, Ga, Sb, Mg, Cu, Ni, Cr, Fe, V, B, or mixtures thereof.

[0097] In some embodiments of the present invention, the dielectric layer may comprise an oxide, nitride, oxynitride, or oxycarbide of Zn, Sn, Ti, Zr, Si, In, Al, Nb, Sb, Ni, Cr, V, Mb, Mg, or mixtures thereof, or the dielectric layer may comprise an oxide, nitride, or oxynitride of Zn, Sn, Ti, Zr, Si, In, Al, Nb, Sb, Ni, Cr, or mixtures thereof.

[0098] These materials can be optionally doped, with example dopants including aluminum, zirconium, or mixtures thereof. The dopant or mixture of dopants can be present in an amount up to 15% by weight.

[0099] Representative examples of dielectric materials include, but are not limited to, silicon-based oxides, silicon-based nitrides, zinc oxide, aluminum-doped zinc oxide, zinc-based oxides, tin oxide, mixed zinc-tin oxides, silicon nitride, silicon oxynitride, titanium oxide, aluminum oxide, zirconium oxide, niobium oxide, aluminum nitride, bismuth oxide, mixed silicon-zirconium nitrides, and mixtures of at least two thereof, such as titanium-zirconium oxide, titanium-niobium oxide, zinc-titanium oxide, zinc-gallium oxide, zinc-indium-gallium oxide (IGZO), zinc-titanium-aluminum oxide (ZTAO), zinc-tin-titanium oxide, zinc-aluminum-vanadium oxide, zinc-aluminum-molybdenum oxide, zinc-aluminum-magnesium oxide, zinc-aluminum-chromium oxide, zinc-aluminum-copper oxide, zinc-titanium-zirconium oxide, and the like.

[0100] The dielectric layer may be comprised of multiple individual layers consisting essentially of the above materials.

[0101] The dielectric layers may each have a thickness in the range of 0.1 to 200 nm, alternatively 0.1 to 150 nm, alternatively 1 to 120 nm, alternatively 1 to 80 nm. The different dielectric layers may have different thicknesses, i.e. a first dielectric layer may have a thickness that is the same or different, greater or less than the thickness of a second or third or any other dielectric layer.

[0102] A preferred IR-reflective coating may typically include at least one infrared-reflective layer embedded between a dielectric layer including a plurality of layers, in particular layers of varying composition in zinc oxide, i.e. layers of zinc oxide, zinc oxide doped with aluminum, or layers of mixed oxides of zinc and tin with a ratio Sn / Zn in the range of 0.5-2 by weight, or layers of mixed oxides of zinc, titanium, and aluminum with a ratio Sn / Zn in the range of 0.02-0.5 by weight; layers of silicon nitride; layers of titanium oxide; layers of silicon nitride; layers of mixed oxides of zinc, titanium, and aluminum. In some cases, the IR layer may be provided independently with a metallic barrier layer, such as Ti, Ni, NiCr, NiCrW, Zr, etc.

[0103] Preferred IR reflective coatings may include a topcoat that provides mechanical and chemical durability, typically selected from titanium oxide, zirconium oxide, silicon nitride, silicon oxide, mixed oxides of titanium and zirconium, mixed oxides of silicon and zirconium, or mixed nitrides of silicon and zirconium, and mixtures or alloys thereof.

[0104] Such preferred IR reflective coatings have demonstrated effectiveness in protecting thermoplastic interlayers from solar radiation while exhibiting particularly good compatibility with thermoplastic interlayers that contain at least 10% recycled material.

[0105] Examples of suitable IR-reflective coatings include coatings that include a dielectric layer; a first barrier layer (seed layer); an infrared (IR)-reflective layer that includes silver; a second barrier layer and another dielectric layer, where the dielectric layer can be selected from zinc oxide, silicon nitride, or mixtures thereof. The barrier can be selected from Ni, Cr, W, Ti, or any mixture or alloy thereof. Such coatings can also include more than one IR-reflective layer.

[0106] Further suitable examples of IR reflective coatings include: a base dielectric layer comprising at least a base dielectric lower layer and a base dielectric upper layer of a composition different from that of the base dielectric lower layer, the base dielectric upper layer comprising one of zinc oxide or a mixed oxide of Zn and at least one additional material X, where the ratio X / Zn in the base dielectric upper layer is 0.02-0.5 by weight, and X is one or more materials selected from the group comprising Sn, Al, Ga, In, Zr, Sb, Bi, Mg, Nb, Ta, and Ti; a first infrared-reflective layer, such as silver, gold, platinum, or mixtures thereof; A first barrier layer, a central dielectric layer comprising at least a central dielectric lower layer and a central dielectric upper layer of a composition different from that of the central dielectric lower layer, the central dielectric lower layer being in direct contact with the first barrier layer and the central dielectric upper layer; the central dielectric upper layer comprising one of zinc oxide or a mixed oxide of Zn and at least one additional material Y, where the ratio Y / Zn in the central dielectric upper layer is between 0.02 and 0.5 by weight, and Y is one or more of the materials selected from the group comprising Sn, Al, Ga, In, Zr, Sb, Bi, Mg, Nb, Ta, and Ti; A second infrared-reflective layer, such as silver, gold, platinum, or mixtures thereof; A second barrier layer, Top dielectric layer, Examples of solar control coatings include:

[0107] Further examples of suitable IR reflective coatings include: a base dielectric layer comprising at least a base dielectric lower layer and a base dielectric upper layer of a composition different from that of the base dielectric lower layer, the base dielectric upper layer comprising one of zinc oxide or a mixed oxide of Zn and at least one additional material X, where the ratio X / Zn in the base dielectric upper layer is 0.02-0.5 by weight, and X is one or more materials selected from the group comprising Sn, Al, Ga, In, Zr, Sb, Bi, Mg, Nb, Ta, and Ti; a first infrared-reflective layer, such as silver, gold, platinum, or mixtures thereof; A first barrier layer, a second dielectric layer comprising at least a second dielectric underlayer and a second dielectric overlayer of a composition different from that of the second dielectric underlayer, the second dielectric underlayer being in direct contact with the first barrier layer and the second dielectric overlayer; the second dielectric overlayer comprising one of zinc oxide or a mixed oxide of Zn and at least one additional material Y, where the ratio Y / Zn in the second dielectric overlayer is between 0.02 and 0.5 by weight, and Y is one or more of the materials selected from the group comprising Sn, Al, Ga, In, Zr, Sb, Bi, Mg, Nb, Ta, and Ti; A second infrared-reflective layer, such as silver, gold, platinum, or mixtures thereof; A second barrier layer, a third dielectric layer comprising at least a third dielectric lower layer and a third dielectric upper layer of a composition different from that of the third dielectric lower layer, the third dielectric lower layer being in direct contact with the second barrier layer and the third dielectric upper layer; the third dielectric upper layer comprising one of zinc oxide or a mixed oxide of Zn and at least one additional material Y, where the ratio Y / Zn in the third dielectric upper layer is between 0.02 and 0.5 by weight, and Y is one or more of the materials selected from the group comprising Sn, Al, Ga, In, Zr, Sb, Bi, Mg, Nb, Ta, and Ti; A third infrared-reflective layer, such as silver, gold, platinum, or mixtures thereof; A third barrier layer, Top dielectric layer, Examples of solar control coatings include:

[0108] In such an example of an IR-reflective coating, the base dielectric overlayer may be in direct contact with the first infrared-reflective layer. The central dielectric overlayer may be in direct contact with the second infrared-reflective layer. Both the base dielectric layer and the central, first and second dielectric overlayers may independently have a geometric thickness in the range of about 3 to 20 nm. One or both of the additional materials X and Y may be Sn and / or Al. The proportion of Zn in the mixed oxide forming the base dielectric overlayer and / or forming the central dielectric overlayer may be such that the ratio X / Zn and / or the ratio Y / Zn is about 0.03 to 0.3 by weight. The first and / or second and / or third barrier layers may be layers comprising Ti and / or comprising an oxide of Ti, each of which may independently have a geometric thickness of 0.5 to 7 nm. The base dielectric overlayer, and / or the middle and / or second and / or third dielectric overlayers can independently have a geometric thickness of <20 nm, alternatively <15 nm, alternatively <13 nm, alternatively <11 nm, and >3 nm, alternatively >5 nm, alternatively >10 nm. The infrared-reflective layers can each independently have a thickness of 2-22 nm, alternatively 5-20 nm, alternatively 8-18 nm. The top dielectric layer can include at least one layer comprising a mixed oxide of Zn and at least one additional material W, in which the ratio W / Zn in the layer is 0.02-2.0 by weight, W being one or more of the materials selected from the group including Sn, Al, Ga, In, Zr, Sb, Bi, Mg, Nb, Ta, and Ti. There may be a topcoat selected from titanium oxide, zirconium oxide, silicon nitride, silicon oxide, mixed oxides of titanium and zirconium, mixed oxides of silicon and zirconium, or mixed nitrides of silicon and zirconium, and mixtures or alloys thereof.

[0109] Typically, a pane of clear float glass (soda-lime glass) provided with such an IR-reflective coating can have a light transmittance of 70-80%.

[0110] The IR reflective coating may be a conductive coating, such as a conductive heated window coating, or a single film or multi-film coating that can function as an antenna.

[0111] The present invention relates to a method for obtaining a composite pane, comprising the steps of: 1) providing an outer pane having an exterior surface and an interior surface; 2) providing an inner pane having an exterior surface and an interior surface, the inner pane having a low-emissivity coating on the interior surface of the inner pane; 3) providing a thermoplastic interlayer formed from at least one thermoplastic film layer containing at least 10% recycled material, the at least one thermoplastic film layer having a light transmission of 1-20%; 4) providing at least one infrared reflective coating either on the interior surface of the outer pane or in the thermoplastic interlayer; 5) combining the inner surface of the outer pane with the outer surface of the inner pane by means of the thermoplastic interlayer to obtain a laminated glazing; Also provided is a method comprising:

[0112] The step of providing the inner pane with a low-emissivity coating, and the step of providing the outer pane when the outer pane includes at least one infrared-reflective coating, include a deposition step using a method selected from CVD, PECVD, PVD, magnetron sputtering, and the like.

[0113] The different layers of each coating can be deposited using different techniques.

[0114] When indium tin oxide is used, it is preferably deposited by magnetron-assisted cathodic sputtering using an indium tin oxide target. The target preferably contains 75% to 95% by weight of indium oxide and 5% to 25% by weight of tin oxide, as well as mixtures related to production. The deposition of indium tin oxide or tin-doped indium oxide is preferably carried out under a non-reactive gas atmosphere, for example under argon. For example, a small amount of oxygen can be added to the non-reactive gas to improve the uniformity of the functional layer.

[0115] Alternatively, the target may preferably contain at least 75% to 95% by weight of indium and 5% to 25% by weight of tin. The deposition of indium tin oxide is preferably carried out with the addition of oxygen as reactive gas during cathodic sputtering.

[0116] At least one infrared-reflective coating can be disposed on a carrier film embedded in an interlayer such as those described above.

[0117] The glass panes provided with each coating may be subsequently heat treated to strengthen the glass pane and optimize the performance of the coating.

[0118] The heat treatment involves heating the glazing in air to a temperature of at least 560°C, for example between 560°C and 700°C, in particular between about 630°C and 670°C, for about 3, 4, 6, 8, 10, 12 or even 15 minutes, depending on the type of heat treatment and the thickness of the glazing. This treatment can involve a quenching step after the heating step in order to introduce a stress difference between the surface and the center of the glass, so that in the event of an impact, this so-called tempered glass sheet breaks safely into small fragments. If the cooling step is not too intense, then the glass is simply thermally tempered, which in any case results in a better mechanical resistance.

[0119] The step of combining two sheets of glass with at least one interlayer may be a lamination step for flat glass or a bending step for curved laminated glass, which bending step comprises first bending a sheet of glass and subsequently laminating said bent sheets of glass.

[0120] The composite pane can then be prepared for enamel deposition or for assembly into a frame.

[0121] For example, this composite pane can feature a light transmission of 1-10%, ensuring the best possible compromise between the view to the outside through the roof and good thermal properties. This light transmission can be achieved by choosing a suitable thermoplastic film layer that contains at least 10% recycled material and has a light transmission of 1-20% (III.A, 2°).

[0122] The combination of an IR-reflective coating inserted between the outer and inner panes and a selected thermoplastic film layer containing at least 10% recycled material allows reaching a light reflectance Rext observed from the outside of <13%.

[0123] A low-emissivity coating with good durability, placed on the inside side of the inner pane facing the vehicle compartment, can reach a light reflectance Rin observed from the inside of <8%, or Rin<4%, or Rin<3%, or even Rin<2%, depending on the type of low-emissivity coating selected.

[0124] The invention also relates to the use of a composite pane according to the invention as a window pane for a vehicle.

[0125] The composite panes according to the invention meet the high safety demands in the vehicle sector, which are typically verified by standardized crush, impact and abrasion tests, such as the ECE R43 ball drop test, well known to those skilled in the art.

[0126] The composite pane may be used particularly as a roof for a vehicle.

[0127] Vehicles include vehicles useful for movement on roads, in the air, underwater, and on water, especially cars, buses, trams, trains, ships, aircraft, spacecraft, space stations, and other self-propelled vehicles.

[0128] Window panes include rear windows, side windows, sunroofs, panoramic roofs, or any other window useful in a car, or any other glazing for a mobile device, where light transmission >70% is not a required feature.

[0129] The window pane is preferably a roof panel of a vehicle, particularly a passenger car, since this can best provide solar control over a larger surface area than a side window.

[0130] The panes may also be useful in architectural applications, including displays, windows, doors, partitions, shower panels, etc.

[0131] In some cases, the composite pane can function as a heatable vehicle glazing.

[0132] In the following, the present invention will be described in detail with reference to the drawings and representative embodiments. The drawings are schematic and not to scale. The drawings are not intended to limit the present invention in any way.

[0133] 1 shows a cross-section of one embodiment of a composite pane according to the present invention. The composite pane includes an outer pane 10 and an inner pane 20 joined together by a thermoplastic intermediate layer 30. The composite pane has a length of approximately 1 m. 2and is intended for use as a roof panel for a passenger vehicle, with the outer pane 10 intended to face the exterior environment and the inner pane 20 intended to face the interior of the vehicle. The outer pane 10 has an outer surface 11 and an inner surface 12. The inner pane 20 has an outer surface 21 and an inner surface 22. The outer surfaces 11 and 21 face the exterior environment in the installed position; the inner surfaces 12 and 22 face the interior of the vehicle in the installed position. The inner surface 12 of the outer pane 10 and the outer surface 21 of the inner pane 20 face each other. The outer pane 10 and the inner pane 20 comprise clear soda-lime glass. They may each have a thickness of 2.1 mm, or one pane may have a thickness of 1.6 mm and the other pane may have a thickness of 2.1 mm.

[0134] The thermoplastic interlayer 30 is formed from at least one thermoplastic film layer containing at least 10% recycled material, said at least one thermoplastic film layer having a light transmission of 1-20%. In a preferred embodiment, the at least one thermoplastic film layer contains at least 60% recycled material and is made of polyvinyl butyral (PVB). In a most preferred embodiment, the thermoplastic interlayer 30 is formed from one thermoplastic film layer containing 100% recycled material and has a light transmission of 1-20%.

[0135] The thermoplastic intermediate layer 30 typically has a thickness of 0.76 mm.

[0136] In FIG. 1, an IR-reflective coating 41 is arranged on the inner surface 12 of the outer pane 10. The IR-reflective coating 41 can extend over the entire surface 12 or over the entire surface except for a peripheral frame-type coating-free area of ​​width 1-10 mm. The coating-free area is sealed by bonding the thermoplastic intermediate layer 30. The IR-reflective coating 41 is therefore advantageously protected against damage and corrosion. The IR-reflective coating 41 comprises at least two functional layers, for example comprising or made of at least silver, with a layer thickness of 10 nm to 20 nm, each functional layer being arranged between two dielectric layers made of the materials mentioned above in connection with the IR-reflective coating.

[0137] Disposed on the interior surface 22 of the inner pane 20 is a low-emissivity coating 51. The coating 51 may be any suitable low-emissivity coating as previously described.

[0138] An enamel coating or dark printing 61 and 62 can be provided as an obscuring band typically present on vehicle glazing that is intended to be mounted on the vehicle frame. Typical fastening methods can be used to fasten the composite pane to the vehicle.

[0139] The IR reflective coating 41 reduces heating and therefore infrared degradation or degradation of the thermoplastic film layer containing at least 10% recycled material. The low-emissivity coating 51, on the other hand, reduces thermal radiation towards the passenger compartment in warmer climate conditions or reduces thermal radiation out of said passenger compartment in colder climate conditions. The aforementioned optimal low-emissivity coatings can further achieve low reflectance with values ​​of Rin<4%, or Rin<3%, or even Rin<2% on the inside of the vehicle together with high mechanical and chemical durability.

[0140] Selected combinations of various factors allow the use of recycled materials in high performance vehicle glazing, mitigating cost constraints while ensuring safety and thermal performance. Further cost constraints can be alleviated by the use of clear or ultra clear float glass in conjunction, further improving temperature management by avoiding heat absorption within the outer and / or inner panes.

[0141] Figure 2 shows a cross section of a second embodiment of a composite pane according to the invention, which fits another embodiment of the invention. In figure 2, the main elements are the same as in figure 1, except that an IR-reflective coating 41 is arranged on a PET carrier film inserted in a thermoplastic interlayer 30. In this embodiment, the thermoplastic interlayer 30 is formed from at least one thermoplastic film layer 32 containing at least 10% recycled material and having a light transmission of 1-20% and at least one thermoplastic film layer 31, which is preferably transparent and has a light transmission of >80%. The at least one thermoplastic film layer 32 containing at least 10% recycled material is preferably arranged between the IR-reflective coating on the carrier film and the inner pane, which is thereby protected from IR rays.

[0142] The thickness of the thermoplastic intermediate layer 30 may be in the range of 0.70 to 1.80 mm, because an IR reflective film disposed on a carrier film having a thickness of 0.01 to 0.20 mm is present within said thermoplastic intermediate layer. EXAMPLES

[0143] A variety of composite panes were made containing the following elements and having the properties outlined in Table 2.

[0144] component The outer and inner glass sheets were selected from 2.1 mm or 1.6 mm clear float glass.

[0145] IR reflective coating a.IRa: IR reflective coating with two silver layers embedded in a dielectric containing zinc oxide sublayers of various compositions, transmittance=72-75% on 2.1mm clear glass; b. IRb and IRb': IR reflective coatings with two silver layers embedded in a dielectric layer on a PET carrier layer; Selected from.

[0146] The intermediate layers are characterized by a composition based on 100% recycled materials and in each case a light transmission of less than 20%, or even 15%, with thicknesses given in mm. The intermediate layers have different grey colours depending on the desired light transmission.

[0147] Low emissivity coatings (low e) a. Low ea: See Table 1; b. Low eb: standard fluorine doped tin oxide on silicon oxide dielectric layer; Both low emissivity coatings have an optical index of refraction on 2.1 mm clear glass = 89-92%. TIFF2025509132000004.tif28170

[0148] result Performance evaluation was performed in accordance with the automotive standard ISO 9050. The values ​​of light transmittance-TL (%), energy transmittance-TE (%), reflectance from the glass side-Rout (%), and reflectance from the coating side-Rin (%) were determined in accordance with ISO 9050 under Illuminant A with a 2° observer.

[0149] Composite panes were also tested according to ECE R43 - "Ball Drop Test".

[0150] In the first test (BDT1), a steel ball weighing 227g was dropped from a height of 8.5m onto the outer pane. This test simulates the impact of a stone on the outside of the laminated glass. The test was considered passed if the ball was stopped by the laminated glass, did not penetrate it, and the amount of fragments on the side opposite the impact was less than a certain amount (which depends on the thickness).

[0151] In the second test (BDT2), a steel ball weighing 2260 g was dropped from a height of 100 m onto the inner pane. This test simulates the impact of a vehicle occupant's head on laminated glass. The test was considered passed if the ball was stopped by the laminated glass and did not penetrate within 5 seconds of fracture. TIFF2025509132000005.tif121170

[0152] The composite pane reaches the expected light energy performance, a.Light transmittance of 1-10%; b. An externally observed light reflectance of less than 13%; c. An internally observed light reflectance of less than 8%; It can be seen from Table 2 that

[0153] The energy transmittance TE also indicates the high solar shielding and high insulation properties of the composite pane, so that the inside environment is not affected by the heat rays from the outside.

[0154] If optimal low-emissivity coatings are used (low ea), the light reflectance observed from the inside can reach values ​​even below 4% and even below 2%, allowing the vehicle occupants to enjoy high comfort inside without affecting their visual comfort.

[0155] In all of the composite panes of Examples 1 to 8, the transmittance index A in accordance with WO 2019 / 110172 is less than 0.02.

[0156] All composite panes of Examples 1-8 passed both "ball drop tests", indicating that the composite panes are suitable as vehicle window panes and meet the adhesive safety requirements of the thermoplastic film layer containing at least 10% recycled material.

Claims

1. a. an outer pane having an exterior surface and an interior surface; b. an inner pane having an exterior surface and an interior surface; c. a thermoplastic intermediate layer joining the interior surface of the outer pane to the exterior surface of the inner pane; A composite pane comprising: the composite pane having at least one infrared-reflective coating between the outer pane and the inner pane; the composite pane having a low-emissivity coating on the interior surface of the inner pane; the thermoplastic intermediate layer is formed from at least one thermoplastic film layer containing at least 10% recycled material; A composite pane, wherein said at least one thermoplastic film layer has a light transmission (III.A, 2°) of 1 to 20%.

2. 10. The composite pane of claim 1, wherein the at least one thermoplastic film layer comprising at least 10% recycled material comprises polyvinyl butyral (PVB), vinyl ethylene vinyl acetate copolymer (EVA), polyurethane (PU), polyvinyl chloride (PVC), and / or mixtures thereof, and / or copolymers thereof.

3. 3. A composite pane according to claim 1 or 2, wherein the thermoplastic interlayer is formed by one or more thermoplastic films, at least one of the films comprising at least 10% recycled material.

4. 10. The composite pane of claim 1, wherein the low-emissivity coating comprises a functional layer comprising a transparent conductive oxide (TCO) selected from indium tin oxide, antimony-doped or fluorine-doped tin oxide, zinc oxide doped with gallium and / or aluminum, mixed indium zinc oxide, vanadium oxide, vanadium oxide doped with tungsten and / or magnesium, titanium oxide doped with niobium, cadmium stannate and / or zinc stannate.

5. 2. A composite pane according to claim 1, wherein the low-emissivity coating comprises a functional layer comprising a transparent conductive oxide (TCO) selected from indium tin oxide, antimony-doped or fluorine-doped tin oxide and / or aluminum-doped zinc oxide (ZnO:Al) and / or gallium-doped zinc oxide (ZnO:Ga).

6. 6. A composite pane according to claim 4 or 5, wherein the low-emissivity coating comprises, in order: a first high refractive index layer, a first low refractive index layer, a transparent conductive oxide layer, an optional barrier layer, a second low refractive index layer, and an optional topcoat layer having a low refractive index.

7. 10. The composite pane of claim 1, wherein the at least one IR-reflective coating is disposed on a carrier film that is attached directly to the interior surface of the exterior pane or embedded in the intermediate layer.

8. 10. The composite pane of claim 1 or 7, wherein the IR reflective coating comprises n infrared reflective (IR) layers and n+1 dielectric layers, where n≧1, and each IR layer is surrounded by two dielectric layers.

9. 9. The composite pane of claim 8, wherein the IR-reflective coating comprises n infrared-reflective (IR) layers and n+1 dielectric layers, where n>2, and each IR layer is surrounded by two dielectric layers.

10. 10. A composite pane according to claim 9, wherein the IR-reflective coating comprises at least one infrared-reflective layer embedded between dielectric layers comprising multiple layers of varying composition in zinc oxide, i.e. layers of zinc oxide, zinc oxide doped with aluminium, or layers of mixed oxide of zinc and tin having a ratio Sn / Zn in the range of 0.5 to 2 by weight, or having a ratio Sn / Zn in the range of 0.02 to 0.5 by weight; layers of silicon nitride; layers of titanium oxide; layers of silicon nitride; layers of mixed oxide of zinc, titanium and aluminium.

11. 10. The composite pane of claim 1, wherein the IR reflective coating comprises a topcoat selected from titanium oxide, zirconium oxide, silicon nitride, silicon oxide, mixed oxides of titanium and zirconium, mixed oxides of silicon and zirconium, or mixed nitrides of silicon and zirconium, and mixtures or alloys thereof.

12. 10. The composite pane of claim 1, wherein the inner and outer panes are selected from clear or ultra-clear soda-lime glass.

13. 1. A method for obtaining a composite pane, comprising: 1) providing an outer pane having an exterior surface and an interior surface; 2) providing an inner pane having an exterior surface and an interior surface, the inner pane having a low-emissivity coating on the interior surface of the inner pane; 3) providing a thermoplastic interlayer formed from at least one thermoplastic film layer containing at least 10% recycled material, said at least one thermoplastic film layer having a light transmission of 1-20%; 4) providing at least one infrared reflective coating either on the interior surface of the outer pane or in the thermoplastic interlayer; 5) combining the inner surface of the outer pane with the outer surface of the inner pane by means of the thermoplastic interlayer to obtain a laminated glazing; A method comprising:

14. 10. Use of the composite pane of claim 1 as a window pane in a vehicle.

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