Precision application device and composition

Abstract

A composition comprising a pesticide; gellan gum; and a carrier fluid is provided, wherein the gellan gum is present in an amount of 0.001 to 2% by weight, and wherein the carrier fluid comprises water and is present in an amount of 65 to 95% by weight.

Description

Technical Field

[0001] The present invention relates to a pesticide composition, a precision application device containing such a composition, and its use.

Background Art

[0002] Pesticides are biologically active materials such as herbicides, fungicides and insecticides used by farmers and growers to control weeds, insects and fungal pests on, onto or around crops. Typically, pesticides are supplied as concentrates that are diluted with water prior to application to form the final composition to be applied. Typically, the diluted pesticide composition is applied by spray application. Spray application enables a large area to be treated in a relatively short time. Sprays can be applied manually, with spray equipment mounted on a dedicated tractor, or even by aircraft, depending on the scale of application. Conventional pesticide sprays generally rely on supplying a diluted pesticide formulation under pressure to produce fine spray particles in a fan or conical shape from a nozzle. This enables a relatively uniform application of the diluted pesticide over a relatively wide area by the sweep of the sprayer.

[0003] In recent years, it has been recognized that in some applications, rather than treating the entire field area uniformly, it may be more advantageous to use a more targeted application of pesticides. For example, if individual weeds can be identified by an automatic identification system connected to an automatic application system, this system should be able to apply herbicides only to these weeds. Similarly, if individual plants parasitized by insects or fungi can be identified, it should be possible to treat only these parasitized plants with insecticides or fungicides. Alternatively, for crops grown in regular rows, it is possible to apply herbicides only to the gaps between the rows. For herbicides, the use of non-selective herbicides (those that kill substantially all plants) targeted at weeds in the crop plants being cultivated may become possible. For all types of pesticides, it may also be possible to use pesticides at lower average levels across the field, reducing the farmer's costs and the amount of pesticides in the environment. This targeted spray application is known as "precision application".

[0004] "Precision application" is defined as the application of pesticides to individual locations of the target site rather than over the entire area (broadcast application). Types of precision application include, but are not limited to, variable rate application using covered / banded application, prescription maps, and optical spot spraying. Precision application also includes this type of targeted application in the use of non-row crop species such as inter-row application or fruit tree spraying. For all types of precision application, the application equipment is likely to require dedicated nozzles to direct the pesticide product more accurately, and typically these will be, but are not limited to, narrow-angle hydraulic nozzles or jet-type nozzles. The most advanced precision application type is optical spot spraying, which includes, in addition to, or instead of, standard application equipment, an imaging system and an analysis system to determine the application location.

[0005] For precision application, different types of spray patterns are required than those of the prior art. By its nature, a precision spray is not intended to spread out and cover a large area. Instead, ideally, it should land precisely on the targeted location and nowhere else. This requires a spray pattern of fine jets of liquid or narrow-angle fan-shaped fine droplets, rather than the conventional wide-angle fan or cone shape.

[0006] It has been found that problems occur when applying liquid pesticides in water with high precision, rather than a wide spray. This problem is that a significant proportion of the spray tends to bounce off or break up as small droplets and land at some distance from the target. This causes the pesticide to spread, and not all of it lands precisely where intended, but also lands on nearby plants and soil. This undermines the whole concept of precision application. When a non-selective herbicide is used on target weeds, nearby crop plants may be damaged or die. For any pesticide, additional pesticides need to be applied to compensate for the material wasted by reaching unwanted locations.

[0007] The problem is further exacerbated because many pesticide compositions contain surfactants and emulsifiers. Some of these are included to improve the physical or chemical stability of the pesticide concentrate, or to improve and maintain the dispersion of the diluted pesticide in the spray tank. Others are included to enhance the biological effect of the pesticide by improving the spreading performance on the surface of the target plant or the penetration performance into the outer surface of the target plant, insect or fungus for the diluted composition. Due to these surfactant properties, such materials increase the formation of small droplets when the liquid lands on the surface, thus exacerbating the problem of movement outside the target. Therefore, it is highly desirable to reduce movement outside the target, and the inventors herein refer to this as reducing the fragmentation of the composition.

[0008] "Droplet breakup" is defined as the splitting of a primary droplet having a nominal diameter upon impact with a surface, which subsequently results in a greater number of smaller secondary droplets that fall outside the initial impact zone. "Reduction of breakup" is thus defined as the reduction rate of the total number of secondary droplets due to a change in composition or compared to a reference composition. Therefore, there is a need for low-breakup compositions suitable for precision application uses and devices. SUMMARY OF THE INVENTION MEANS FOR SOLVING THE PROBLEM

[0009] In a first aspect of the present invention, therefore, pesticides; gum diutan; and a composition comprising a carrier fluid is provided, wherein the gum diutan is present in an amount of 0.001 to 2% by weight, wherein the carrier fluid comprises water and is present in an amount of 65 to 95% by weight.

[0010] Surprisingly, the composition according to the present invention has been found to solve the above technical problem. BRIEF DESCRIPTION OF THE DRAWINGS

[0011]

Figure 1

[0012] Advantageously, the carrier fluid is present in an amount of 68 to 93% by weight, such as 69 to 92% by weight, 70 to 91% by weight, or 71 to 90% by weight.

[0013] Preferably, the carrier fluid comprises water in an amount of 80 to 100%, or 80 to 99.5% by weight, of the carrier fluid.

[0014] The gum diutan may be present in an amount of 0.01 to 0.20% by weight.

[0015] Advantageously, the agricultural chemical is used at the maximum use amount on the label of the active ingredient.

[0016] The agricultural chemical can be used in an amount of 0.0001 to 25% by weight, such as 0.001 to 20% by weight, 0.01 to 5% by weight, or 6 to 15% by weight.

[0017] One or more agricultural chemicals or salts of agricultural chemicals selected from those described below are suitable for the present invention.

[0018] Suitable herbicides or plant growth regulators include acetochlor, asiflufen (including asiflufen-sodium), acifluorfen, ametryn, aminocarbazone, aminopyralid, aminotriazole, atrazine, beflubutamid-M, bentriazone, bensulfuron (including bensulfuron-methyl), bentazone, bicyclopyrone, bilanafos, bipyrazone, bispyribac-sodium, bispyrazoxone, bromacil, bromoxynil, butachlor, butaphenacyl, carfentrazone (including carfentrazone-ethyl), chloransulam (including chloransulam-methyl), chlorimuron (including chlorimuron-ethyl), chlorotoluron, chlorosulfuron, cinmethylin, clathrifos, clethodim, clodinafop (including clodinafop-propargyl), chlormazone, clopyralid, cyclopyranil, cyclopyrimorate, cyclosulfamuron, cyhalofop (including cyhalofop-butyl), 2,4-D (including its choline salt and 2-ethylhexyl ester), 2,4-DB, desmedipham, dicamba (including aluminum, aminopropyl, bis-aminopropylmethyl, choline, dichloroprop, diglycolamine, dimethylamine, dimethylammonium, its potassium and sodium salts), diclosulam, diflufenican, diflufenopir, dimethachlor, dimethenamid-P, dioxopyrimetry, diquat dibromide, diuron, epiriflophenacyl, ethalfluralin, ethofumesate, fenoxaprop (including fenoxaprop-P-ethyl), fenoxysulfuron, fenpyrazone, fenquinotrione, fentrazamide, flazasulfuron, florasulam, flupyradifurone (including flupyradifurone-benzyl), fluazifop (including fluazifop-P-butyl), flucarbazone (including flucarbazone-sodium), flufenacet, flumetsulam, flumioxazin, flumetsuron, foramsulfuron, flupyrsulfuron (including flupyrsulfuron-methyl-sodium), fluroxypyr (including fluroxypyr-meptyl), foramsulfuron, halosulfuron, glufosinate (including L-glufosinate and both ammonium salts),Glyphosate (including its diammonium, isopropylammonium, and potassium salts), halauxifen (including halauxifen-methyl), haloxyfop (including haloxyfop-methyl), hexazinone, hydantocidin, imazamox (including R-imazamox), imazapic, imazapyr, imazethapyr, indaziflam, iodosulfuron (including iodosulfuron-methyl-sodium), iofensulfuron (including iofensulfuron-sodium), ioxtynil, isoproturon, isoxaflutole, rankotriol, MCPA, MCPB, mecoprop-P, mesosulfuron (including mesosulfuron-methyl), mesotrione, metazachlor, metazachlor, metiamiduron, methiozolin, metolachlor, metosulam, metribuzin, metsulfuron, napropamide, nicosulfuron, norflurazon, oxadiazon, oxasulfuron, oxyfluorfen, paraquat dichloride, pendimethalin, penoxsulam, fenmedipham, picloram, pinoxaden, pretilachlor, primisulfuron-methyl, prometryn, propanil, propaquizafop, propyrisulfuron, propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraflufen (including pyraflufen-ethyl), pyrazosulfuron, pyridate, pyriftalid, pyrimisulfan, pyroxasulfone, pyroxysulam, cinchonazine, cinchonine, quizalofop (including quizalofop-P-ethyl and quizalofop-P-tefuryl), rimsulfuron, sulfentrazone, sulfosulfuron, tebuthiuron, tefuryltrione, tembotrione, terbuthylazine, terbutryn, tetrafluoropyrimethan, thienacarbazone, thifensulfuron, thiafenacyl, topramezone, traloxydim, triafamone, triallate, triasulfuron, tribenuron (including tribenuron-methyl), triclopyr, trifloxysulfuron (including trifloxysulfuron-sodium), triflumizoxazin, trifluralin, triflusulfuron, tripyrasulfone,[(E)-[2-(Trifluoromethyl)phenyl]methyleneamino]2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoate, ethyl 3-(2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydropyrimidin-1(2H)-yl)phenyl)-5-methyl-4,5-dihydroisoxazole-5-carboxylate, 4-hydroxy-1-methoxy-5-methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one, 4-hydroxy-1,5-dimethyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one, 5-ethoxy-4-hydroxy-1-methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one, 4-hydroxy-1-methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one, 4-hydroxy-1,5-dimethyl-3-[1-methyl-5-(trifluoromethyl)pyrazol-3-yl]imidazolidin-2-one, (4R)1-(5-tert-butylisoxazol-3-yl)-4-ethoxy-5-hydroxy-3-methyl-imidazolidin-2-one, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylic acid (including its agrochemically acceptable esters such as methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate, prop-2-ynyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate and cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine-2-carboxylate), 3-ethylsulfanyl-N-(1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide, 3-(sulfanylmethyl)-N-(5-methyl-1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide,3-(Isopropylsulfonylmethyl)-N-(5-methyl-1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide, 3-(ethylsulfonylmethyl)-N-(5-methyl-1,3,4-oxadiazol-2-yl)-5-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]pyridine-8-carboxamide, ethyl 2-[[3-[[3-chloro-5-fluoro-6-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]-2-pyridyl]oxy]acetate, 6-chloro-4-(2,7-dimethyl-1-naphthyl)-5-hydroxy-2-methyl-pyridazin-3-one, tetrahydrofuran-2-ylmethyl (2R)-2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propanoate, (2R)-2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propanoic acid, tetrahydrofuran-2-ylmethyl 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propanoate, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridyl)oxy]propanoic acid, 2-fluoro-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-[(R)-propylsulfinyl]-4-(trifluoromethyl)benzamide, 2-fluoro-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-propylsulfinyl-4-(trifluoromethyl)benzamide, (2-fluorophenyl)methyl 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxy-phenyl)pyrimidine-4-carboxylate, 6-amino-5-chloro-2-(4-chloro-2-fluoro-3-methoxy-phenyl)pyrimidine-4-carboxylic acid, 3-(3-chlorophenyl)-6-(5-hydroxy-1,3-dimethyl-pyrazole-4-carbonyl)-1,5-dimethyl- quinazoline-2,4-dione and [4-[3-(3-chlorophenyl)-1,5-dimethyl-2,4-dioxo-quinazoline-6-carbonyl]-2,5-dimethyl-pyrazol-3-yl] N,N-diethylcarbamate,It may be selected from methyl 2-[(E)-[2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]phenyl]methyleneamino]oxypropanoate and methyl (2R)-2-[(E)-[2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)pyrimidin-1-yl]phenyl]methyleneamino]oxypropanoate.,

[0019] The above compound or mixture can also be used in combination with one or more herbicide safeners. Examples of such safeners include benoxacor, cloquintocet (including cloquintocet mexyl), cyprosulfamide, dichlormid, fenchlorazole (including fenchlorazole-ethyl), fenclorim, flurxypyrim, furilazole, isoxadifen (including isoxadifen-ethyl), mefenpyr (including mefenpyr-diethyl), metcamifene, and oxabetrinil.

[0020] Suitable insecticides include abamectin, acetamiprid, acetoprole, acrinathrin, asinapyr, afidopyropen, afoxolaner, alanicarb, allethrin, α-cypermethrin, α-methrin, amidoflumet, aminocarb, azocyclotin, bensultap, benzoximate, benzpyrimoxan, β-cyfluthrin, β-cypermethrin, bifenazate, bifenthrin, binapacryl, bioallethrin, S-bioallethrin, bioresmethrin, bistrifluron, broflanilide, brofluthrinate, bromophos-ethyl, buprofezin, butocarboxim, kazusaphos, carbaryl, carbosulfan, cartap, CAS No.: 1632218-00-8, CAS No.: 1808115-49-2, CAS No.: 2032403-97-5, CAS No.: 2044701-44-0, CAS No.: 2128706-05-6, CAS No.: 2095470-94-1, CAS No.: 2377084-09-6, CAS No.: 1445683-71-5, CAS No.: 2408220-94-8, CAS No.: 2408220-91-5, CAS No.: 1365070-72-9, CAS No.: 2171099-09-3, CAS No.: 2396747-83-2, CAS No.: 2133042-31-4, CAS No.: 2133042-44-9, CAS No.: 1445684-82-1, CAS No.: 1922957-45-6, CAS No.: 1922957-46-7, CAS No.: 1922957-47-8, CAS No.: 1922957-48-9, CAS No.: 2415706-16-8, CAS No.: 1594624-87-9, CAS No.: 1594637-65-6, CAS No.: 1594626-19-3, CAS No.: 1990457-52-7, CAS No.: 1990457-55-0, CAS No.: 1990457-57-2, CAS No.: 1990457-77-6, CAS No.: 1990457-66-3, CAS No.: 1990457-85-6, CAS No.: 2220132-55-6, CAS No.: 1255091-74-7, CAS No.: RNA (Colorado potato beetle (Leptinotarsa decemLineata)-specific recombinant double-stranded interference GS2), CAS No.: 2719848-60-7,CAS No.: 1956329-03-5, Chlorantraniliprole, Chlordane, Chlorfenapyr, Chlorpropetrin, Chromafenozide, Clethodim, Cloethocarb, Clothianidin, 2-Chlorophenyl N-methylcarbamate (CPMC), Cyanofenphos, Cyantraniliprole, Cyclaniliprole, Cyclobutrifluram, Cycloprothrin, Cycloxaprid, Cyenopyrafen, Cyetpyrafen (or Ethiprole), Ciflumetofen, Cifluthrin, Cyhalodiamide, Cyhalothrin, Cypermethrin, Cyphenothrin, Cyproflanilide, Cyromazine, Deltamethrin, Diafenthiuron, Diazinon, Dibrom, Dichloromethothiaz, Diflubenzuron, Dimpropylate, Dinactin, Dinocap, Dinotefuran, Dioxabenzofos, Emamectin (or Emamectin Benzoate), Empenthrin, ε-Monofluorothrin, ε-Methofluthrin, Esfenvalerate, Ethion, Ethiprole, Etofenprox, Ethoxazole, Fanfan, Phenazak, Fenfluthrin, Fenitrothion, Fenmezodithiaz, Phenothiocarb, Phenoxycarb, Fenpropathrin, Fenpyroximate, Fensulphothion, Fenthion, Fentin Acetate, Fenvalerate, Fipronil, Flometoquin, Flonicamid, Fluacrypyrim, Fluazaindolizine, Fluazuron, Flubendiamide, Flubendimine, Flucycloxuron, Flucythrinate, Flucycloxuron, Fluensulfone, Flufenoxuron, Flufenprox, Flufiprole, Flufenhexathion, Flumethrin, Fluopyram, Flupentiofenox, Flupyradifurone, Flupyrimin, Fluralaner, Flubavinate, Fluxametamide, Phosphazetate, γ-Cyhalothrin, Guazatine, Halofenozide, Halfenprox, Heptafluthrin, Hexythiazox, Hydramethylnon, Imicyafos, Imidacloprid, Imiprothrin, Indazapyrroxamet, Indoxacarb, Iodomethane, Iprodione, Isocycloseram, Isothioate, Ivermectin, κ-Bifenthrin, κ-Tefluthrin, Lambda-Cyhalothrin, Lepimectin, Lotilaner, Lufenuron,Metflumizone, metaaldehyde, metam, methomyl, methoxyfenozide, metofluthrin, methiocarb, mexacarbate, milbemectin, monofluoro triin, niclosamide, niflumuron, nitenpyram, nithiazine, omethoate, oxamyl, oxazosulfyl, parathion-ethyl, permethrin, phenothrin, phosphocarb, piperonyl butoxide, pyrimicarb, pyrimiphos-ethyl, pyrimiphos-methyl, polyhedrosis virus, prallethrin, profenofos, profluthrin, propargite, propetamphos, propoxur, prothiofos, protriofenbut, piflubumide, pymetrozine, pyraclofos, pyrafluprole, pyridaben, pyridalyl, pyrifluquinazon, pyrimidifen, pyriminostrobin, pyriprole, pyriproxyfen, resmethrin, silafluofen, spinetoram, spinosad, spirodiclofen, spirotetramat, spidoxamat, sulfoxaflor, tebufenozide, tebufenpyrad, tebupirimfos, tefluthrin, temephos, tetrachlorantraniliprole, tetradifon, tetramethrin, tetramethylfluthrin, tetranactin, tetraniliprole, theta-cypermethrin, thiacloprid, thiamethoxam, thiosyclam, thiodicarb, thiofanox, thiomethon, thiosultap, thigolaner, thiorantraniliprole, thioxazafen, tolfenpyrad, toxaphene, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, trichloronate, trichlorfon, trifluenflonate, triflumizopyrim, chlorpyrifluazuron, zeta-cypermethrin, seaweed extract and fermentation products derived from molasses, seaweed extract and fermentation products derived from molasses containing urea, amino acids, potassium and molybdenum and EDTA-chelated manganese, seaweed extract and fermented plant products, seaweed extract and fermented plant products containing plant hormones, vitamins, EDTA-chelated copper, zinc, and iron, azadirachtin, Bacillus aizawaiBacillus chitinosporus AQ746 (NRRL accession number B-21618), Bacillus firmus, Bacillus kurstaki, Bacillus mycoides AQ726 (NRRL accession number B-21664), Bacillus pumilus (NRRL accession number B-30087), Bacillus pumilus AQ717 (NRRL accession number B-21662), Bacillus sp. AQ178 (ATCC accession number 53522), Bacillus sp. AQ175 (ATCC accession number 55608), Bacillus sp. AQ177 (ATCC accession number 55609), Bacillus subtilis unspecified, Bacillus subtilis AQ153 (ATCC accession number 55614), Bacillus subtilis AQ30002 (NRRL accession number B-50421), Bacillus subtilis AQ30004 (NRRL accession number B-50455), Bacillus subtilis AQ713 (NRRL accession number B-21661), Bacillus subtilis AQ743 (NRRL accession number B-21665), Bacillus thuringiensis AQ52 (NRRL accession number B-21619), Bacillus thuringiensis BD#32 (NRRL accession number B-21530), Bacillus thuringiensis subspecies kurstaki BMP123, Beauveria bassiana, D-limonene, granulovirus, harpin, Helicoverpa armigera nuclear polyhedrosis virus, Helicoverpa zea nuclear polyhedrosis virus,The false armyworm (Heliothis virescens) nuclear polyhedrosis virus, the native budworm (Heliothis punctigera) nuclear polyhedrosis virus, species of Metarhizium spp., Muscodor albus 620 (NRRL accession number 30547), Muscodor roseus A3-5 (NRRL accession number 30548), neem tree-based products, Paecilomyces fumosoroseus, Paecilomyces lilacinus, Pasteuria nishizawae, Pasteuria penetrans, Pasteuria ramosa, Pasteuria thornei, Pasteuria usgae, p-cymene, the diamondback moth (Plutella xylostella) granulosis virus, the diamondback moth (Plutella xylostella) nuclear polyhedrosis virus, polyhedrosis virus, chrysanthemum, QRD420 (terpenoid blend), QRD452 (terpenoid blend), QRD460 (terpenoid blend), Quillaja saponaria, Rhodococcus globerulus AQ719 (NRRL accession number B-21663), the fall armyworm (Spodoptera frugiperda) nuclear polyhedrosis virus, Streptomyces galbus (NRRL accession number 30232), species of Streptomyces sp. (NRRL accession number B-30145), terpenoid blends, and species of Verticillium spp.;, An algicide selected from the group of substances consisting of vetoxazine, copper neodecanoate (170), copper sulfate (172), sibuthrin, dichloron (1052), dichlorophene (232), endothal (295), fentin (347), slaked lime, nabam (566), quinoclamine (714), quinone amide (1379), simazine (730), triphenyltin acetate (347), and triphenyltin hydroxide (347); An anthelmintic selected from the group of substances consisting of abamectin (1), curdphos (1011), doramectin, emamectin (291), emamectin benzoate (291), epirinomectin, ivermectin, milbemycin oxime, moxidectin, piperazine, selamectin, spinosad (737), and thiophanate (1435); A bird repellent selected from the group of substances consisting of chloralose (127), endrin (1122), fenthion (346), pyridin-4-amine (23), and strychnine (745); A bactericide selected from the group of substances consisting of 1-hydroxy-1H-pyridine-2-thione (1222), 4-(quinoxalin-2-ylamino)benzenesulfonamide (748), 8-hydroxyquinoline sulfate (446), bronopol (97), copper neodecanoate (170), copper hydroxide (169), cresol, dichlorophene (232), dipyrithione (1105), dodine (1112), fenaminosulf (1144), formaldehyde (404), hydralgafene, kasugamycin (483), kasugamycin hydrochloride hydrate (483), nickel bis(dimethyldithiocarbamate) (1308), nitrapyrin (580), octhilinone (590), oxolinic acid (606), oxytetracycline (611), potassium hydroxyquinoline sulfate (446), probenazole (658), streptomycin (744), streptomycin sesquisulfate (744), tecnazene (766), and thimerosal; Adoxophyes orana GV(12), Agrobacterium radiobacter(13), Amblyseius spp.(19), Anagrapha falcifera NPV(28), Anagrus atomus(29), Aphelinus abdominalis(33), Aphidius colemani(34), Aphidoletes aphidimyza(35), Autographa californica NPV(38), Bacillus firmus(48), Bacillus sphaericus Neide (scientific name)(49), Bacillus thuringiensis Berliner (scientific name)(51), Bacillus thuringiensis subsp. aizawai (scientific name)(51), Bacillus thuringiensis subsp. israelensis (scientific name)(51), Bacillus thuringiensis subsp. japonensis (scientific name)(51), Bacillus thuringiensis subsp. kurstaki (scientific name)(51), Bacillus thuringiensis subsp. tenebrionis(Bacillus thuringiensis subsp.Tenebrionis) (scientific name) (51), Beauveria bassiana (53), Beauveria brongniartii (54), Chrysoperla carnea (151), Cryptolaemus montrouzieri (178), Cydia pomonella GV (191), Dacnusa sibirica (212), Diglyphus isaea (254), Encarsia formosa (scientific name) (293), Eretmocerus eremicus (300), Helicoverpa zea NPV (431), Heterorhabditis bacteriophora and H. megidis (433), Hippodamia convergens (442), Leptomastix dactylopii (488), Macrolophus caliginosus (491), Mamestra brassicae NPV (494), Metaphycus helvolus (522), Metarhizium anisopliae var. acridum (scientific name) (523), Metarhizium anisopliae var. anisopliae (scientific name) (523), Neodiprion sertifer NPV and N. lecontei NPV (575), Orius spp. of the genus Orius)(596), Paecilomyces fumosoroseus (613), Phytoseiulus persimilis (644), Spodoptera exigua multiple capsid nuclear polyhedrosis virus (scientific name) (741), Steinernema bibionis (742), Steinernema carpocapsae (742), Steinernema feltiae (742), Steinernema glaseri (742), Steinernema riobrave (742), Steinernema riobravis (742), Steinernema scapterisci (742), Steinernema spp. (742), Trichogramma spp. (826), Typhlodromus occidentalis (844), and Verticillium lecanii (848); a biological agent selected from the group consisting of substances;. A soil sterilizing agent selected from the group consisting of methyl iodide (542) and methyl bromide (537); An infertility agent selected from the group consisting of aldicarb, bisazir, busulfan, diflubenzuron (250), dimatif, hemer, hempa, metepa, methiotepa, methyl aldicarb, moludid, penfluron, tepa, thiohempa, thiotepa, tretamine, and uredepa; (E)-Dec-5-en-1-yl acetate + (E)-dec-5-en-1-ol(222), (E)-tridec-4-en-1-yl acetate(829), (E)-6-methylhepta-2-en-4-ol(541), (E,Z)-tetradeca-4,10-dien-1-yl acetate(779), (Z)-dodec-7-en-1-yl acetate(285), (Z)-hexadeca-11-enal(436), (Z)-hexadeca-11-en-1-yl acetate(437), (Z)-hexadeca-13-en-11-in-1-yl acetate(438), (Z)-icos-13-en-10-one(448), (Z)-tetradec-7-en-1-al(782), (Z)-tetradec-9-en-1-ol(783), (Z)-tetradec-9-en-1-yl acetate(784), (7E,9Z)-dodeca-7,9-dien-1-yl acetate(283), (9Z,11E)-tetradeca-9,11-dien-1-yl acetate(780), (9Z,12E)-tetradeca-9,12-dien-1-yl acetate(781), 14-methyloctadec-1-ene(545), 4-methylnonan-5-ol + 4-methylnonan-5-one(544), α-multistriatin, brevicomin, codlelure, codlemone(167), querelure(179), disparlure(277), dodec-8-en-1-yl acetate(286), dodec-9-en-1-yl acetate(287), dodeca-8,10-dien-1-yl acetate(284), dominicalure, ethyl 4-methyloctanoate(317), eugenol, frontalin, Gossyplure (registered trademark) (alternative name;(Z,E) and (Z,Z) isomers of hexadeca-7,11-dien-1-yl acetate (1:1 mixture) (420), grandlure (421), grandlure I (421), grandlure II (421), grandlure III (421), grandlure IV (421), hexalure, ipsdienol, ipsenol, japonilure (481), linaethin, litlure, looplure, medlure, megatomonic acid, methyleugenol (540), muscalure (563), octadeca-2,13-dien-1-yl acetate (588), octadeca-3,13-dien-1-yl acetate (589), orfralure, orictalure (317), ostramone, siglure, soldi-dine (736), sulcatol, tetradeca-11-en-1-yl acetate (785), trimedlure (839), trimedlure A (839), trimedlure B1 (839), trimedlure B2 (839), trimedlure C (839) and an insect pheromone selected from the group consisting of trunc-call; An insect repellent selected from the group consisting of 2-(octylthio)ethanol (591), butapironexyl (933), butoxy(polypropylene glycol) (936), dibutyl adipate (1046), dibutyl phthalate (1047), dibutyl succinate (1048), diethyltoluamide, dimethylcarbamate, dimethyl phthalate, ethylhexanediol (1137), hexamide, methoquine-butyl (1276), methyl neodecanamide, oxamate and picaridin; A molluscicide selected from the group of substances consisting of bis(tributyltin)oxide (913), bromoacetamide, calcium arsenate, chloethocarb (999), copper acetoarsenite, copper sulfate (172), fentin (347), ferric phosphate (352), metaaldehyde (518), methiocarb (530), niclosamide (576), niclosamide - olamine (576), pentachlorophenol (623), sodium pentachlorophenoxide (623), thionazin (1412), thiodicarb (799), tributyltin oxide (913), triphenyltin hydroxide (347), triphenyltin acetate (347), and pyriprole [394730 - 71 - 3]; AKD-3088 (Compound Code), 1,2-dibromo-3-chloropropane (1045), 1,2-dichloropropane (IUPAC / Chemical Abstracts name) (1062), 1,2-dichloropropane + 1,3-dichloropropene (1063), 1,3-dichloropropene (233), 3,4-dichlorotetrahydrothiophene 1,1-dioxide (1065), 3-(4-chlorophenyl)-5-methylrhodanine (980), 5-methyl-6-thioxo-1,3,A nematicide selected from the group consisting of 5-thiazadiinan-3-ylacetic acid (1286), 6-isopentenylaminopurine (210), abamectin (1), acetoprole, alanicarb (15), aldicarb (16), aldoxycarb (863), AZ60541 (compound code), benclothiaz, benomyl (62), butylpyridaben, kazusaphos (109), carbofuran (118), carbon disulfide (945), carbosulfan (119), chloropicrin (141), chlorpyrifos (145), chloetocarb (999), cytokinin (210), dazomet (216), DBCP (1045), DCIP (218), diamidafos (1044), dichloropenthion (1051), dichlorvos, dimethoate (262), doramectin, emamectin (291), emamectin benzoate (291), eprinomectin, ethoprophos (312), ethylene dibromide (316), fenamiphos (326), fenpyrazamine, fensulfothion (1158), fostiazate (408), fosthietan (1196), lufenuron, GY-81 (development code) (423), heterophos, iodomethane (542), isamidophos (1230), isazophos (1231), ivermectin, kinetin (210), mecarbam (1258), metam (519), metam-potassium (519), metam-sodium (519), methyl bromide (537), methyl isothiocyanate (543), milbemycin oxime, moxidectin, Myrothecium verrucaria composition (565), NC-184 (compound code), oxamyl (602), phorate (636), phosphamidon (639), phosphocarb, sebufos, selamectin, spinosad (737), terbam, terbufos (773), tetrachlorothiophene (IUPAC / Chemical Abstracts name) (1422), thiafenox, thionazin (1434), triazophos (820), triazolone, xylenol orange, YI-5302 (compound code), and zeatin (210), fluensulfone [318290-98-1], fluopyram; A nitrification inhibitor selected from the group of substances consisting of potassium ethylxanthate and nitrapyrin (580); A plant activator selected from the group of substances consisting of acibenzolar (6), acibenzolar-S-methyl (6), probenazole (658) and an extract of Reynoutria sachalinensis (720); A rodenticide selected from the group of substances consisting of 2-isovalerylindane-1,3-dione (1246), 4-(quinoxalin-2-ylamino)benzenesulfonamide (748), α-chlorohydrin, aluminum phosphide (640), ants (880), arsenic trioxide (882), barium carbonate (891), bistiosemi (912), brodifacoum (89), brodifacoum (or α-brodifacoum), bromethalin (92), calcium cyanide (444), chloralose (127), chlorophacinone (140), colecalciferol (850), coumachlor (1004), coumafury (1005), coumatetralyl (175), crimidine (1009), diphenacoum (246), diphacinone (249), difenacoum (273), ergocalciferol (301), flocoumafen (357), fluoroacetamide (379), flupropazin (1183), flupropazin hydrochloride (1183), γ-HCH (430), HCH (430), hydrogen cyanide (444), iodomethane (542), lindane (430), magnesium phosphide (640), methyl bromide (537), norbormide (1318), phosphoacetim (1336), phosphine (640), phosphorus, pindone (1341), potassium arsenite, pirinuron (1371), silymarin (1390), sodium arsenite, sodium cyanide (444), sodium fluoroacetate (735), strychnine (745), thallium sulfate, warfarin (851) and zinc phosphide (640); A synergist selected from the group of substances consisting of 2-(2-butoxyethoxy)ethyl piperonylate (934), 5-(1,3-benzodioxol-5-yl)-3-hexylcyclohex-2-enone (903), farnesol + nerolidol (324), MB-599 (development code) (498), MGK 264 (development code) (296), piperonyl butoxide (649), piprotal (1343), propyl isomer (1358), S421 (development code) (724), sesamux (1393), sesasmolin (1394) and sulfoxide (1406); An animal repellent selected from the group of substances consisting of anthraquinone (32), chloralose (127), copper naphthenate, copper oxychloride (171), diazinon (227), dicyclopentadiene (scientific name) (1069), guazatine (422), guazatine acetate (422), methiocarb (530), pyridin-4-amine (23), thiram (804), trimethacarb (840), zinc naphthenate and dithiram (856); An antiviral agent selected from the group of substances consisting of imanin and ribavirin; A wound protectant selected from the group of substances consisting of mercury(II) oxide (512), octilinone (590) and thiophanate-methyl (802); 1,1-Bis(4-chlorophenyl)-2-ethoxyethanol, 2,4-dichlorophenylbenzenesulfonate, 2-fluoro-N-methyl-N-1-cinnamaldehyde, 4-chlorophenylphenylsulfone, aceprol, aldoxycarb, amidithion, amidithioate, amiton, hydrogen oxalate amiton, amitraz, aramite, arsenic trioxide, azobenzene, azothoate, benomyl, benoxaphos, benzyl benzoate, bixafen, brofenvalerate, bromocyclene, bromophos, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, butylpyridaben, calcium polysulfide, camphocol, carbaryl, carbophenothion, cymiazole, chinomethionat, chlorbenside, chlordimeform, chlordimeform hydrochloride, chlorphenethol, chlorphensone, chlorphensulfide, chlorobenzilate, chloromethiuron, chloropropylate, chlorothiophos, cinerin I, cinerin II, cinerin s, chrysanthemum, coumaphos, chlorotamitone, crotoxyphos, kufraeb, cyanothoate, DCPM, DDT, demephion, demephion-O, demephion-S, demeton-methyl, demeton-O, demeton-O-methyl, demeton-S, demeton-S-methyl, demeton-S-methyl sulfone, dichlofluanid, dichlorvos, dicriphos, dienochlor, dimefox, dinex, dinex dicrexine, dinocap-4, dinocap-6, dinoceton, dinopenton, dinosulfon, dinoterbon, dioxathion, diphenylsulfone, disulfiram, DNOC, dofenapyn, doramectin, endothion, eprinomectin, ethothiomethyle, ethirimol, fenazaflor, fenbutatin oxide, phenothiocarb, fenpyrazamine, fenpyroximate, fenpyrazamine, fenson, fentrifanil, flubenzimine, flucycloxuron, fluenethil, flubenzide, FMC1137, formetanate, formetanate hydrochloride, formparanate, γ-HCH, gliotoxin, halfenprox, hexadecyl cyclopropanecarboxylate, isocarbophos, jasmonine I, jasmonine II, iodofenphos, lindane, malonoben,Mecarbam, Methidathion, Mesulfen, Methacrifos, Methyl bromide, Methiocarb, Mexacarbate, Milbemycin oxime, Mipafox, Monocrotophos, Morphothion, Moxidectin, Naled, 4-Chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3-pyridyl)methoxy]pyridazin-3-one, Nifluridide, Nikkomycin, Nitrilacarb, Nitrilacarb 1:1 zinc chloride complex, Omethoate, Oxydemeton-methyl, Oxydisulfoton, pp’-DDT, Parathion, Permethrin, Fenchlorphos, Phosalone, Phosphorothioate, Phosphamidon, Polychloroterpene, Polyactin, Proclonol, Promacyl, Propoxur, Prothidathion, Prothoate, Pyrethrin I, Pyrethrin II, Pyrethrins, Pyridafenthion, Pyrimidate, Quinalphos, Quincholphos, R-1492, Phosphoglycine, Rotenone, Schradan, Sevofos, Selamectin, Sofamide, SSI-121, Sulfiram, Sulfuryl fluoride, Sulfotepp, Sulfur, Diflubenzuron, τ-Fluvalinate, TEPP, Terbumethrin, Tetradifon, Tetrasul, Thiafenthox, Thiocarbamate, Thiofanox, Thimet, Thioquinox, Tsingyensin, Triamiphos, Triarathene, Triazophos, Triazolone, Triphenyl phosphate, Trinactin, Vamidothion, Vaniliprole, Vetoxazine, Copper neodecanoate, Copper sulfate, Sibuthrin, Dicloran, Dichlorophen, Endothal, Fentin, Hydrated lime, Nervonic acid, Quinoclamine, Quinone amide, Simazine, Triphenyltin acetate, Triphenyltin hydroxide, Crufomate, Piperazine, Thiophanate, Chloralose, Fenthion, Pyridin-4-amine, Strychnine, 1-Hydroxy-1H-pyridine-2-thione, 4-(Quinoxalin-2-ylamino)benzenesulfonamide, 8-Hydroxyquinoline sulfate, Bronopol, Copper hydroxide, Cresol, Dipyrithione, Dodine, Phenaminosulf, Formaldehyde, Hydrargaphen, Kasugamycin, Kasugamycin hydrochloride hydrate, Nickel bis(dimethyldithiocarbamate), Nitrapyrin, Octhilinone, Oxolinic acid, Oxytetracycline, Potassium hydroxyquinoline sulfate, Probenazole, Streptomycin,Streptomycin sesquisulfate, tecnophthalum, thimerosal, Adoxophyes orana GV, Agrobacterium radiobacter, Amblyseius spp., Anagrapha falcifera NPV, Anagrus atomus, Aphelinus abdominalis, Aphidius colemani, Aphidoletes aphidimyza, Autographa californica NPV, Bacillus sphaericus Neide, Beauveria brongniartii, Chrysoperla carnea, Cryptolaemus montrouzieri, Cydia pomonella GV, Dacnusa sibirica, Diglyphus isaea, Encarsia formosa, Eretmocerus eremicus, Heterorhabditis bacteriophora and H. megidis, Hippodamia convergens, Leptomastix dactylopii, Macrolophus caliginosus, Mamestra brassicae NPV, Metaphycus helvolus, Metarhizium anisopliae var. acridum, Metarhizium anisopliae var. anisopliae,Neodiprion sertifer NPV and N. lecontei NPV, Orius spp. Paecilomyces fumosoroseus, Phytoseiulus persimilis, Steinernema bibionis, Steinernema carpocapsae, Steinernema feltiae, Steinernema glaseri, Steinernema riobrave, Steinernema riobravis, Steinernema scapterisci, Steinernema spp., Trichogramma spp., Typhlodromus occidentalis, Verticillium lecanii, apholate, bisazir, busulfan, dimatiph, hemer, hempa, metepa, methiotepa, methyl apholate, moldid, penfluron, tepa, thiohempa, thiotepa, tretamine, uredepa, (E)-deca-5-en-1-yl acetate + (E)-deca-5-en-1-ol, (E)-trideca-4-en-1-yl acetate, (E)-6-methylhepta-2-en-4-ol, (E,Z)-tetradeca-4,10-dien-1-yl acetate, (Z)-dodeca-7-en-1-yl acetate, (Z)-hexadeca-11-enal, (Z)-hexadeca-11-en-1-yl acetate, (Z)-hexadeca-13-en-11-in-1-yl acetate, (Z)-icos-13-en-10-one, (Z)-tetradeca-7-en-1-al, (Z)-tetradeca-9-en-1-ol, (Z)-tetradeca-9-en-1-yl acetate, (7E,9Z)-dodeca-7,9-dien-1-yl acetate, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate, (9Z,12E)-tetradeca-9,12-dien-1-yl acetate, 14-methyloctadeca-1-ene,4-Methylnonan-5-ol + 4-Methylnonan-5-one, α-Multistriatin, Brevicomin, Codlelure, Codlemone, Querelure, Disparlure, Dodeca-8-en-1-yl acetate, Dodeca-9-en-1-yl acetate, Dodeca-8,10-dien-1-yl acetate, Dominicalure, Ethyl 4-methyloctanoate, Eugenol, Frontalin, Grandlure, Grandlure I, Grandlure II, Grandlure III, Grandlure IV, Hexalure, Ipsdienol, Ipsenol, Japonilure, Linalool, Litlure, Rupelure, Medlure, Megatomoic acid, Methyleugenol, Muscalure, Octadeca-2,13-dien-1-yl acetate, Octadeca-3,13-dien-1-yl acetate, Orfluralure, Oricolure, Ostramone, Siglure, Soldiure, Sulcatol, Tetradeca-11-en-1-yl acetate, Trimedlure, Trimedlure A, Trimedlure B1, Trimedlure B2, Trimedlure C, Trunc-call, 2-(Octylthio)ethanol, Butapironexyl, Butoxy(polypropylene glycol), Dibutyl adipate, Dibutyl phthalate, Dibutyl succinate, Diethyltoluamide, Dimethyl carbonate, Dimethyl phthalate, Ethylhexanediol, Hexamide, Methokin-butyl, Methyl neodecanamide, Oxamate, Picaridin, 1-Dichloro-1-nitroethane, 1,1-Dichloro-2,2-bis(4-ethylphenyl)ethane, 1,2-Dichloropropane + 1,3-Dichloropropene, 1-Bromo-2-chloroethane, 2,2,2-Trichloro-1-(3,4-dichlorophenyl)ethyl acetate, 2,2-Dichlorovinyl 2-ethylsulfinylethyl methyl phosphate, 2-(1,3-Dithiolan-2-yl)phenyl dimethylcarbamate, 2-(2-Butoxyethoxy)ethyl thiocyanate, 2-(4,5-Dimethyl-1,3-dioxolan-2-yl)phenyl methylcarbamate, 2-(4-Chloro-3,5-xylyloxy)ethanol, 2-Chlorovinyl diethyl phosphate, 2-Imidazolidone, 2-Isovalerylindane-1,3-dione, 2-Methyl(prop-2-ynyl)aminophenyl methylcarbamate, 2-Thiocyanatoethyl laurate,3-Bromo-1-chloroprop-1-ene, 3-methyl-1-phenylpyrazol-5-yl dimethylcarbamate, 4-methyl(prop-2-ynyl)amino-3,5-xylyl methylcarbamate, 5,5-dimethyl-3-oxocyclohex-1-enyl dimethylcarbamate, acetion, acrylonitrile, aldrin, alloxydim, alicarb, α-ecdysone, aluminium phosphide, aminocarb, anabasine, atidathion, azamethiphos, Bacillus thuringiensis δ-endotoxin, barium hexafluorosilicate, barium polysulphide, barthrin, Bayer 22 / 190, Bayer 22408, β-cyfluthrin, β-cyphenothrin, bioethanomethrin, biopermethrin, bis(2-chloroethyl)ether, sodium borate, bromfenvinfos, bromo-DDT, bufencarb, butacarb, butathiophos, butonate, calcium arsenate, calcium cyanide, carbon disulphide, carbon tetrachloride, cartap hydrochloride, sevin, chlorbicyclen, chlordane, chlordecone, chloroform, chloropicrin, chloroxime, chlorprozophos, cis-resmethrin, cis-methrin, chlorthrin, copper acetoarsenite, copper arsenite, copper oleate, cumithoate, cryolite, CS708, cyanofenphos, cyanophos, cycloprothrin, cythioate, d-tetramethrin, DAEP, dazomet, decarbofuran, diamidafos, dicapton, dichlorophenthion, dicresyl, diclornil, dieldrin, diethyl 5-methylpyrazol-3-yl phosphate, dicrotophos, dimefluthrin, dimethan, dimethrin, dimethylvinphos, dimethilan, dinopropr, dinosam, dinoseb, diofenolan, dioxabenzofos, dichlorvos, DSP, ecdysterone, EI 1642, EMPC, EPBP, ethion, ethiofencarb, ethyl formate, ethylene dibromide, dichloroethane, ethylene oxide, EXD, fenchlorphos, fenethacarb, fenitrothion, phenoxycarb, fenpyrethrin, fenthion-ethyl, flucofuron, formothion, fosmethilan, fosthiazate, fluthiacarb, flumethrin, guazatine, guazatine acetate,Sodium tetrathiocarboxylate, halfenprox, HCH, HEOD, heptachlor, heterophos, HHDN, hydrogen cyanide, hikarcarb, IPSP, isazophos, isobenzan, isodrin, isofenphos, isolan, isoprothiolane, isoxathion, juvenile hormone I, juvenile hormone II, juvenile hormone III, kerevan, kinoprene, lead arsenate, leptophos, liliumphos, lithidathion, m-cumenyl methylcarbamate, magnesium phosphide, madex, mecarbam, menazon, mercurous chloride, mesulfenphos, metam, metam-potassium, metam-sodium, methanesulfonyl fluoride, methocrotophos, methoprene, methothrin, methoxychlor, methyl isothiocyanate, methyl chloroform, methylene chloride, methoxadiazone, mirex, naphthalophos, naphthalene, NC-170, nicotine, nicotine sulfate, nithiazine, nor-nicotine, O-5-dichloro-4-iodophenyl O-ethyl ethylphosphonothioate, O,O-diethyl O-4-methyl-2-oxo-2H-chromen-7-yl phosphorothionate, O,O-diethyl O-6-methyl-2-propylpyrimidin-4-yl phosphorothionate, O,O,O’,O’-tetrapropyl dithiopyrophosphate, oleic acid, para-dichlorobenzene, parathion-methyl, pentachlorophenol, pentachlorophenyl laurate, PH60-38, fencaptone, phosphonitrol, phosphine, hokxim-methyl, pirimiphos, polychlorodicyclopentadiene isomers, Potassium arsenite, potassium thiocyanate, precocene I, precocene II, precocene III, pyrimidophos, profenofos, promecarb, prothiofos, pyrazophos, pyresmethrin, cassia, quinalphos-methyl, quinothione, rafoxanide, resmethrin, rotenone, cadethrin, ryania, ryanodine, sabadilla, shradan, sebufos, SI-0009, thiapronyl, sodium arsenite, sodium cyanide, sodium fluoride, sodium hexafluorosilicate, sodium pentachlorophenoxide salt, sodium selenate, sodium thiocyanate, sulcofuron, sulcofuron-sodium, sulfuryl fluoride, sulprofos, tar oil, thionazin, TDE, tebupirimfos, temephos, terallethrin, tetrachloroethane, trichlorphon, thiosultap, thiosultap-sodium, tralomethrin, transpermethrin, triazamate, trichlorometaphos-3, trichloronate, trimethacarb, tolprocarb, triclopyricarb, triprene, veratridine, veratrin, XMC, zeta-methrin, zinc phosphide, zolaprofos, meperfluthrin, tetramethylfluthrin, bis(tributyltin) oxide, bromoacetamide, ferric diphosphate, niclosamide-olamine, tributyltin oxide, pyrimorph, trifenmorph, 1,2-dibromo-3-chloropropane, 1,3-dichloropropene, 3,4-dichlorotetrahydrothiophene 1,1-dioxide, 3-(4-chlorophenyl)-5-methylrhodanine, 5-methyl-6-thioxo-1,3,5-thiadiazinan-3-ylacetic acid, 6-isopentenylaminopurine, anilofop-ethyl, benclothiaz, cytokinin, DCIP, lufural, isamidophos, kinetin, Myrothecium verrucaria composition, tetrachlorothiophene, xylenol orange, zeatin, potassium ethylxanthate, acibenzolar, acibenzolar-S-methyl, Reynoutria sachalinensis extract, α-chlorohydrin, ants, barium carbonate, bistiosemi, brodifacoum, bromadiolone, bromethalin, chlorophacinone, cholecalciferol,Coumachlor, Cumafuril, Cumatetril, Crimidine, Difenacoum, Difethialone, Difacinone, Ergocalciferol, Flocoumafen, Fluoroacetamide, Flupropazin, Flupropazin Hydrochloride, Norbormide, Phosacetim, Phosphorus, Pindone, Pyrinuron, Silicoside, Sodium Fluoroacetate, Potassium Sulfate, Warfarin, 2-(2-Butoxyethoxy)ethyl Piperonate, 5-(1,3-Benzodioxol-5-yl)-3-hexylcyclohex-2-enone, Farnesol + Nerolidol, Berberine, MGK 264, Piperonyl Butoxide, Piperonal, Propyl Isomer, S421, Sesamex, Sesasmolin, Sulfoxide, Anthraquinone, Copper Naphthenate, Copper Oxychloride, Dicyclopentadiene, Thiram, Zinc Naphthenate, Dithiram, Imanine, Ribavirin, Chloroinconazide, Mercury(II) Oxide, Thiophanate-Methyl, Azaconazole, Bitertanol, Bromoconazole, Cyproconazole, Difenoconazole, Diniconazole, Epoxiconazole, Fenbuconazole, Fluquinconazole, Flusilazole, Flutriafol, Flametopyril, Hexaconazole, Imazalil, Imibenconazole, Ipconazole, Metconazole, Microbutanyl, Paclobutrazol, Pefurazoate, Penconazole, Prothioconazole, Pyriofenox, Prochloraz, Propiconazole, Pyrisoxazole, Simeconazole, Tebuconazole, Tetraconazole, Triadimefon, Triadimenol, Triflumizole, Triticonazole, Ancymidol, Fenarimol, Nuarimol, Buptyramate, Dimethirimol, Ethirimol, Dodemorph, Fenpropimorph, Spiroxamine, Tridemorph, Cyprodinil, Mepanipyrim, Pyrimethanil, Fenpiclonil, Fluazinam, Benalaxyl, Furalaxyl, Metalaxyl, R-Metalaxyl, Ofurace, Oxadixyl, Carbendazim, Decabarb, Fuberidazole, thiabendazole, Chlorozolinate, Diclorozoline, Micronazole, Procymidone, Vinclozolin, Boscalid, Carboxin, Fenfluram, Flutolanil, Mepronil, Oxacarboxin, Penthiopyrad, Tifluzamide, Dodine,Iminoctadine, azoxystrobin, dimoxystrobin, enestroburin, fenaminstrobin, fluopicoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, trifloxystrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyra-metostrobin, pyraoxystrobin, ferbam, mancozeb, manneb, metam, propineb, zineb, captan, captophos, fluazinam, folpet, trifulanide, Bordeaux mixture, copper oxide, mancopper, copper oxine, nitrothal-isopropyl, edifenphos, iprobenfos, fosdiphen, tolclofos-methyl, anilazine, benalaxyl, blasticidin-S, chloroneb, chlorothalonil, cyflufenamid, cymoxanil, cyclobutriflan, diclocymet, diclomezine, dichloran, diethofencarb, dimethomorph, flumorph, dithianon, ethaboxam, etridiazole, famoxadone, fenamidone, phenoxanil, ferimzone, fluazinam, flumetylsulforim, fluopicolide, fluoxythioconazole, flusulfamide, fluopyram, fenhexamid, fosetyl-aluminum, hymexazol, iprovalicarb, cyazofamid, methiocarb, metrafenone, penthiopyrad, phthalide, polyoxin, propamocarb, pyriminobac, proquinazid, pyroquilon, pyrifluquinazon, quinoxyfen, quintozene, thiazinyl, triazoxide, tricyclazole, triforine, validamycin, valifenalate, zoxamide, mandipropamid, flubenthram, isopyrazam, sedaxane, benzovindiflupyr, pidiflumetofen, 3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxylic acid (3’,4’,5’-trifluoro-biphenyl-2-yl)-amide, isoflupyrimid, isothianil, diphenamid, 6-ethyl-5,7-dioxo-pyrrolo[4,5][1,4]dithieno[1,2-c]isothiazole-3-carbonitrile, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide,4-(2,6-Difluorophenyl)-6-methyl-5-phenyl-pyridazine-3-carbonitrile, (R)-3-(difluoromethyl)-1-methyl-N-[1,1,3-trimethylinden-4-yl]pyrazole-4-carboxamide, 4-(2-bromo-4-fluoro-phenyl)-N-(2-chloro-6-fluoro-phenyl)-2,5-dimethyl-pyrazol-3-amine, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, fluindapil, kresoxim-methyl (diaxianshuangjunzhi), rubenmixianan Diclobenziazox, Mandestrobin, 3-(4,4-Difluoro-3,4-dihydro-3,3-dimethylisoquinolin-1-yl)quinolone, 2-[2-Fluoro-6-[(8-fluoro-2-methyl-3-quinolyl)oxy]phenyl]propan-2-ol, Oxathiapiprolin, tert-Butyl N-[6-[[[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate, Pyraziflumid, Impflufoxam, Turoprocarb, Mefentrifluconazole, Ipflentrifluconazole, 2-(Difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, N'-(2,5-Dimethyl-4-phenoxyphenyl)-N-ethyl-N-methyl-formamidine, N'-[4-(4,5-Dichlorothiazol-2-yl)oxy-2,5-dimethylphenyl]-N-ethyl-N-methyl-formamidine, [2-[3-[2-[1-[2-[3,5-Bis(difluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]thiazol-4-yl]-4,5-dihydroisoxazol-5-yl]-3-chloro-phenyl]methanesulfonic acid, But-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate, Methyl N-[[5-[4-(2,4-dimethylphenyl)triazol-2-yl]-2-methyl-phenyl]methyl]carbamate, 3-Chloro-6-methyl-5-phenyl-4-(2,4,6-trifluorophenyl)pyridazine, Pyridachloromethy, 3-(Difluoromethyl)-1-methyl-N-[1,1,3-trimethylindan-4-yl]pyrazole-4-carboxamide, 1-[2-[[1-(4-chlorophenyl)pyrazol-3-yl]oxymethyl]-3-methylphenyl]-4-methyl-tetrazol-5-one, 1-Methyl-4-[3-methyl-2-[[2-methyl-4-(3,4,5-trimethylpyrazol-1-yl)phenoxy]methyl]phenyl]tetrazol-5-one, Aminopyrifen, Ametoctradin, Amisulbrom, Penflufen, (Z,2E)-5-[1-(4-Chlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-penta-3-enamide, florylpicoxamid, fenpicoxamid, metrilpicoxamid, tebufloquin, ipuphenoxine, chinomethrin, isofenphamide, ethyl 1-[[4-[[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy]phenyl]methyl]pyrazole-3-carboxylate (which can be prepared by the method described in International Publication No. 2020 / 056090), ethyl 1-[[4-[(Z)-2-ethoxy-3,3,3-trifluoro-prop-1-enoxy]phenyl]methyl]pyrazole-3-carboxylate (which can be prepared by the method described in International Publication No. 2020 / 056090), methyl N-[[4-[1-(4-cyclopropyl-2,6-difluoro-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamate (which can be prepared by the method described in International Publication No. 2020 / 097012), methyl N-[[4-[1-(2,6-difluoro-4-isopropyl-phenyl)pyrazol-4-yl]-2-methyl-phenyl]methyl]carbamate (which can be prepared by the method described in International Publication No. 2020 / 097012), 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoro-ethyl]-5-methyl-pyridazine-4-carboxamide (which can be prepared by the method described in International Publication No. 2020 / 109391), 6-chloro-N-[2-(2-chloro-4-methyl-phenyl)-2,2-difluoro-ethyl]-3-(3-cyclopropyl-2-fluoro-phenoxy)-5-methyl-pyridazine-4-carboxamide (which can be prepared by the method described in International Publication No. 2020 / 109391), 6-chloro-3-(3-cyclopropyl-2-fluoro-phenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoro-ethyl]-5-methyl-pyridazine-4-carboxamide (which can be prepared by the method described in International Publication No. 2020 / 109391), N-[2-[2,4-dichloro-phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4-carboxamide, N-[2-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl]-3-(difluoromethyl)-1-methyl-pyrazole-4-carboxamide, benzothiostrobin, fenamacril, 5-amino-1,3,4-thiadiazole-2-thiol zinc salt (2:1), fluopyram, fluphenoxadiazam, fluthianil, fluopyrimid, pyrapropoyne, picarbutrazox, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-((3R)-1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, methyltetraprole, 2-(difluoromethyl)-N-((3R)-1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, α-(1,1-dimethylethyl)-α-[4’-(trifluoromethoxy)[1,1'-Biphenyl]-4-yl]-5-pyrimidinemethanol, fluoxapiprolin, enoxastrobin, methyl (Z)-3-methoxy-2-[2-methyl-5-[4-(trifluoromethyl)triazol-2-yl]phenoxy]prop-2-enoate, methyl (Z)-3-methoxy-2-[2-methyl-5-(4-propyltriazol-2-yl)phenoxy]prop-2-enoate, methyl (Z)-2-[5-(3-isopropylpyrazol-1-yl)-2-methyl-phenoxy]-3-methoxy-prop-2-enoate, methyl (Z)-3-methoxy-2-[2-methyl-5-(3-propylpyrazol-1-yl)phenoxy]prop-2-enoate, methyl (Z)-3-methoxy-2-[2-methyl-5-[3-(trifluoromethyl)pyrazol-1-yl]phenoxy]prop-2-enoate (these compounds can be prepared by the method described in International Publication No. 2020 / 079111), methyl (Z)-2-(5-cyclohexyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoate, methyl (Z)-2-(5-cyclopentyl-2-methyl-phenoxy)-3-methoxy-prop-2-enoate (these compounds can be prepared by the method described in International Publication No. 2020 / 193387), 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-thioxo-4H-1,2,4-(1,2,4-Triazol-1-yl)propyl]-3-pyridyloxy]benzonitrile, trinexapac, kresoxim-methyl, zhongshengmycin, copper thiodiazole, zinc thiazole, abamectin, iprodione, cymoxanil, N’-[5-bromo-2-methyl-6-[(1S)-1-methyl-2-propoxy-ethoxy]-3-pyridyl]-N-ethyl-N-methyl-formamidine, N’-[5-bromo-2-methyl-6-[(1R)-1-methyl-2-propoxy-ethoxy]-3-pyridyl]-N-ethyl-N-methyl-formamidine, N’-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine, N’-[5-chloro-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine, N’-[5-bromo-2-methyl-6-(1-methyl-2-propoxy-ethoxy)-3-pyridyl]-N-isopropyl-N-methyl-formamidine (these compounds can be prepared by the method described in International Publication No. 2015 / 155075);, N’-[5-Bromo-2-methyl-6-(2-propoxypropoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine (this compound can be prepared by the method described in IPCOM000249876D); N-isopropyl-N’-[5-methoxy-2-methyl-4-(2,2,2-trifluoro-1-hydroxy-1-phenyl-ethyl)phenyl]-N-methyl-formamidine, N’-[4-(1-cyclopropyl-2,2,2-trifluoro-1-hydroxy-ethyl)-5-methoxy-2-methyl-phenyl]-N-isopropyl-N-methyl-formamidine (these compounds can be prepared by the method described in International Publication No. 2018 / 228896); N-ethyl-N’-[5-methoxy-2-methyl-4-[(2-trifluoromethyl)oxetan-2-yl]phenyl]-N-methyl-formamidine, N-ethyl-N’-[5-methoxy-2-methyl-4-[(2-trifluoromethyl)tetrahydrofuran-2-yl]phenyl]-N-methyl-formamidine (these compounds can be prepared by the method described in International Publication No. 2019 / 110427);N-[(1R)-1-Benzyl-3-chloro-1-methyl-but-3-enyl]-8-fluoro-quinoline-3-carboxamide, N-[(1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl]-8-fluoro-quinoline-3-carboxamide, N-[(1R)-1-benzyl-3,3,3-trifluoro-1-methyl-propyl]-8-fluoro-quinoline-3-carboxamide, N-[(1S)-1-benzyl-3,3,3-trifluoro-1-methyl-propyl]-8-fluoro-quinoline-3-carboxamide, N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide, N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-7,8-difluoro-quinoline-3-carboxamide, 8-fluoro-N-[(1R)-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide, 8-fluoro-N-[(1S)-1-[(3-fluorophenyl)methyl]-1,3-dimethyl-butyl]quinoline-3-carboxamide, N-[(1R)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide, N-[(1S)-1-benzyl-1,3-dimethyl-butyl]-8-fluoro-quinoline-3-carboxamide, N-((1R)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline-3-carboxamide, N-((1S)-1-benzyl-3-chloro-1-methyl-but-3-enyl)-8-fluoro-quinoline-3-carboxamide (these compounds can be prepared by the method described in International Publication No. WO 2017 / 153380);1-(6,7-Dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4,6-trifluoro-3,3-dimethyl-isoquinoline, 4,4-difluoro-3,3-dimethyl-1-(6-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline, 4,4-difluoro-3,3-dimethyl-1-(7-methylpyrazolo[1,5-a]pyridin-3-yl)isoquinoline, 1-(6-chloro-7-methyl-pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-isoquinoline (these compounds can be prepared by the methods described in International Publication No. WO 2017 / 025510); 1-(4,5-dimethylbenzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-isoquinoline, 1-(4,5-dimethylbenzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-isoquinoline, 6-chloro-4,4-difluoro-3,3-dimethyl-1-(4-methylbenzimidazol-1-yl)isoquinoline, 4,4-difluoro-1-(5-fluoro-4-methyl-benzimidazol-1-yl)-3,3-dimethyl-isoquinoline, 3-(4,4-difluoro-3,3-dimethyl-1-isoquinolyl)-7,8-dihydro-6H-cyclopenta[e]benzimidazole (these compounds can be prepared by the methods described in International Publication No. WO 2016 / 156085);N-Methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide, N,2-dimethoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, N-ethyl-2-methyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, 1,3-dimethoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, 3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propanamide, 4,4-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, 5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, ethyl 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrazole-4-carboxylate, N,N-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-1,2,4-triazol-3-amine (these compounds can be prepared by the methods described in International Publication No. WO 2017 / 055473, International Publication No. WO 2017 / 055469, International Publication No. WO 2017 / 093348, and International Publication No. WO 2017 / 118689); 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound can be prepared by the method described in International Publication No. WO 2017 / 029179);2-[6-(4-Bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol (this compound can be prepared by the method described in International Publication No. WO 2017 / 029179); 3-[2-(1-Chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound can be prepared by the method described in International Publication No. WO 2016 / 156290); 3-[2-(1-Chlorocyclopropyl)-3-(3-chloro-2-fluoro-phenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile (this compound can be prepared by the method described in International Publication No. WO 2016 / 156290); (4-Phenoxyphenyl)methyl 2-amino-6-methyl-pyridine-3-carboxylate (this compound can be prepared by the method described in International Publication No. WO 2014 / 006945); 2,6-Dimethyl-1H,5H-[1,4]dithieno[2,3-c:5,6-c’]dipyrrole-1,3,5,7(2H,6H)-tetrone (this compound can be prepared by the method described in International Publication No. WO 2011 / 138281) N-Methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzenecarbothioamide; N-Methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide; (Z,2E)-5-[1-(2,4-Dichlorophenyl)pyrazol-3-yl]oxy-2-methoxyimino-N,3-dimethyl-penta-3-enamide (this compound can be prepared by the method described in International Publication No. WO 2018 / 153707); N’-(2-Chloro-5-methyl-4-phenoxy-phenyl)-N-ethyl-N-methyl-formamidine; N’-[2-Chloro-4-(2-fluorophenoxy)-5-methyl-phenyl]-N-ethyl-N-methyl-formamidine (this compound can be prepared by the method described in International Publication No. WO 2016 / 202742); 2-(Difluoromethyl)-N-[(3S)-3-ethyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide (this compound can be prepared by the method described in International Publication No. WO 2014 / 095675);(5-Methyl-2-pyridyl)-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone, (3-methylisoxazol-5-yl)-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methanone (these compounds can be prepared by the method described in International Publication No. WO 2017 / 220485); 2-oxo-N-propyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide (this compound can be prepared by the method described in International Publication No. WO 2018 / 065414); ethyl 1-[[5-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]-2-thienyl]methyl]pyrazole-4-carboxylate (this compound can be prepared by the method described in International Publication No. WO 2018 / 158365); 2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]acetamide, N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, N-[N-methoxy-C-methyl-carboximidoyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide (these compounds can be prepared by the method described in International Publication No. WO 2018 / 202428); a biologically active substance selected from these; Microorganisms including the following: Acinetobacter lwoffii, Acremonium alternatum, Acremonium cephalosporium, Acremonium diospyri, Acremonium obclavatum, Adoxophyes orana granulovirus (AdoxGV) (Capex (registered trademark)), Agrobacterium radiobacter strain K84 (Galltrol-A (registered trademark)), Alternaria alternate, Alternaria cassia, Alternaria destruens (Smolder (registered trademark)), Ampelomyces quisqualis (AQ10 (registered trademark)), Aspergillus flavus AF36 (AF36 (registered trademark)), Aspergillus flavus NRRL21882 (Aflaguard (registered trademark)), a species of Aspergillus spp.) Aureobasidium pullulans, Azospirillum, (MicroAZ (registered trademark), TAZO B (registered trademark)), Azotobacter, Azotobacter chroocuccum (Azotomeal (registered trademark)), Azotobacter cysts (Bionatural Blooming Blossoms (registered trademark)), Bacillus amyloliquefaciens, Bacillus cereus, Bacillus chitinosporus strain CM-1, Bacillus chitinosporus strain AQ746, Bacillus licheniformis strain HB-2 (Biostart (trademark) Rhizoboost (registered trademark)), Bacillus licheniformis strain 3086 (EcoGuard (registered trademark), Green Releaf (registered trademark)), Bacillus circulans, Bacillus firmus (BioSafe (registered trademark), BioNem-WP (registered trademark), VOTiVO (registered trademark)), Bacillus firmus strain I-1582, Bacillus macerans, Bacillus marismortui, Bacillus megaterium, Bacillus mycoides strain AQ726, Bacillus papillae (Milky Spore Powder (registered trademark)), Bacillus pumilus spp.) Bacillus pumilus strain GB34 (Yield Shield®), Bacillus pumilus strain AQ717, Bacillus pumilus strain QST2808 (Sonata®, Ballad Plus®), Bacillus sphaericus (VectoLex®), Bacillus spp., Bacillus spp. strain AQ175, Bacillus spp. strain AQ177, Bacillus spp. strain AQ178, Bacillus subtilis strain QST713 (CEASE®, Serenade®, Rhapsody®), Bacillus subtilis strain QST714 (JAZZ®), Bacillus subtilis strain AQ153, Bacillus subtilis strain AQ743, Bacillus subtilis strain QST3002, Bacillus subtilis strain QST3004, Bacillus subtilis var. amyloliquefaciensStrain FZB24 of Bacillus amyloliquefaciens (Taegro (registered trademark), Rhizopro (registered trademark)), Bacillus thuringiensis Cry 2Ae, Bacillus thuringiensis Cry1Ab, Bacillus thuringiensis aizawai GC 91 (Agree (registered trademark)), Bacillus thuringiensis israelensis (BMP123 (registered trademark), Aquabac (registered trademark), VectoBac (registered trademark)), Bacillus thuringiensis kurstaki (Javelin (registered trademark), Deliver (registered trademark), CryMax (registered trademark), Bonide (registered trademark), Scutella WP (registered trademark), Turilav WP (registered trademark), Astuto (registered trademark), Dipel WP (registered trademark), Biobit (registered trademark), Foray (registered trademark)), Bacillus thuringiensis kurstaki BMP 123 (Baritone (registered trademark)), Bacillus thuringiensis kurstaki HD-1 (Bioprotec-CAF / 3P (registered trademark)), Bacillus thuringiensis strain BD#32, Bacillus thuringiensis strain AQ52, Bacillus thuringiensis var. aizawai (XenTari (registered trademark), DiPel (registered trademark)). Species of the genus Bacteria (bacteria spp.) (GROWMEND®, GROWSWEET®, Shootup®), bacteriophage of Clavipacter michiganensis (AgriPhage®), Bakflor®, Beauveria bassiana (Beaugenic®, Brocaril WP®), Beauveria bassiana GHA (Mycotrol ES®, Mycotrol O®, BotaniGuard®), Beauveria brongniartii (Engerlingspilz®, Schweizer Beauveria®, Melocont®), Species of the genus Beauveria (Beauveria spp.), Botrytis cinerea, Bradyrhizobium japonicum (TerraMax®), Brevibacillus brevis, Bacillus thuringiensis tenebrionis (Novodor®), BtBooster, Burkholderia cepacia (Deny®, Intercept®, Blue Circle®), Burkholderia gladii, Burkholderia gladioli, Species of the genus Burkholderia (Burkholderia spp.) Canadian thistle fungus (CBH Canadian Bioherbicide®), Candida butyri, Candida famata, Candida fructus, Candida glabrata, Candida guilliermondii, Candida melibiosica, Candida oleophila strain O, Candida parapsilosis, Candida pelliculosa, Candida pulcherrima, Candida reukaufii, Candida saitoana (Bio-Coat®, Biocure®), Candida sake, Candida spp., Candida tenius, Cedecea dravisae, Cellulomonas flavigena, Chaetomium cochliodes (Nova-Cide®), Chaetomium globosum (Nova-Cide®), Chromobacterium subtsugae strain PRAA4-1T (Grandevo®), Cladosporium cladosporioides, Cladosporium oxysporum, Cladosporium chlorocephalum, Cladosporium spp.) Cladosporium tenuissimum, Clonostachys rosea (EndoFine (registered trademark)), Colletotrichum acutatum, Coniothyrium minitans (Cotans WG (registered trademark)), species of Coniothyrium spp.) Cryptococcus albidus (YIELDPLUS (registered trademark)), Cryptococcus Humicola, Cryptococcus infirmo-miniatus, Cryptococcus laurentii, Cryptophlebia leucotreta granulovirus (Cryptex (registered trademark)), Cupriavidus campinensis, Cydia pomonella granulovirus (CYD-X (registered trademark)), Cydia pomonella granulovirus (Madex (registered trademark), Madex Plus (registered trademark), Madex Max / Carpovirusine (registered trademark)), Cylindrobasidium laeve (Stumpout (registered trademark)), Cylindrocladium genus, Debaryomyces hansenii, Drechslera hawaiinensis, Enterobacter cloacae, Enterobacteriaceae, Entomophtora virulenta (Vektor (registered trademark)), Epicoccum nigrum, Epicoccum purpurascens, Epicoccum spp.)、Filobasidium floriforme, Fusarium acuminatum, Fusarium chlamydosporum, Fusarium oxysporum (Fusaclean® / Biofox C®), Fusarium proliferatum, Fusarium spp.,. Galactomyces geotrichum, Gliocladium catenulatum (Primastop®, Prestop®), Gliocladium roseum, Gliocladium spp. (SoilGard®), Gliocladium virens (Soilgard®), Granupom®, Halobacillus halophilus, Halobacillus litoralis, Halobacillus trueperi, Halomonas spp., Halomonas subglaciescola, Halovibrio variabilis, Hanseniaspora uvarum, Helicoverpa armigera nuclear polyhedrosis virus (Helicovex®), Helicoverpa zea nuclear polyhedrosis virus (Gemstar®), Isoflavone - Hormonenectin (Myconate®), Kloeckera apiculata, Kloeckera spp.) Lagenidium giganteum (Laginex®), Lecanicillium longisporum (Vertiblast®), Lecanicillium muscarium (Vertikil®), Lymantria Dispar nucleopolyhedrosis virus (Disparvirus®), Marinococcus halophilus, Meira geulakonigii, Metarhizium anisopliae (Met52®), Metarhizium anisopliae (Destruxin WP®), Metschnikowia fruticola (Shemer®), Metschnikowia pulcherrima, Microdochium dimerum (Antibot®), Micromonospora coerulea, Microsphaeropsis ochracea, Muscodor albus 620 (Muscudor®), Muscodor roseus strain A3-5, Mycorrhizae spp.)(AMykor (registered trademark), Root Maximizer (registered trademark)), Myrothecium verrucaria strain AARC-0255 (DiTera (registered trademark)), BROS PLUS (registered trademark), Ophiostoma piliferum strain D97 (Sylvanex (registered trademark)), Paecilomyces farinosus, Paecilomyces fumosoroseus (PFR-97 (registered trademark), PreFeRal (registered trademark)), Paecilomyces linacinus (Biostat WP (registered trademark)), Paecilomyces lilacinus strain 251 (MeloCon WG (registered trademark)), Paenibacillus polymyxa, Pantoea agglomerans (BlightBan C9-1 (registered trademark)), Pantoea spp., Pasteuria spp. (Econem (registered trademark)), Pasteuria nishizawae, Penicillium aurantiogriseum, Penicillium billai (Jumpstart (registered trademark), TagTeam (registered trademark)), Penicillium brevicompactum, Penicillium frequentans, Penicillium griseofulvum, Penicillium purpurogenum, Penicillium spp.) Penicillium viridicatum, Phlebiopsis gigantean (Rotstop®), Phosphomeal® (phosphate-solubilizing bacteria), Phytophthora cryptogea, Phytophthora palmivora (Devine®), Pichia anomala, Pichia guilermondii, Pichia membranaefaciens, Pichia onychis, Pichia stipites, Pseudomonas aeruginosa, Pseudomonas aureofasciens (Spot-Less Biofungicide®), Pseudomonas cepacia, Pseudomonas chlororaphis (AtEze®), Pseudomonas corrugate, Pseudomonas fluorescens strain A506 (BlightBan A506®), Pseudomonas putida, Pseudomonas reactans, Pseudomonas spp.) Pseudomonas syringae (Bio-Save (registered trademark)), Pseudomonas viridiflava, Pseudomons fluorescens (Zequanox (registered trademark)), Pseudozyma flocculosa strain PF-A22 UL (Sporodex L (registered trademark)), Puccinia canaliculata, Puccinia thlaspeos (Wood Warrior (registered trademark)), Pythium paroecandrum, Pythium oligandrum (Polygandron (registered trademark), Polyversum (registered trademark)), Pythium periplocum, Rhanella aquatilis, Rhanella spp.,. Rhizobium (Dormal (registered trademark), Vault (registered trademark)), Rhizoctonia, Rhodococcus globerulus strain AQ719, Rhodosporidium diobovatum, Rhodosporidium toruloides, Rhodotorula spp., Rhodotorula glutinis, Rhodotorula graminis, Rhodotorula mucilagnosa, Rhodotorula rubra, Saccharomyces cerevisiae, Salinococcus roseus, Sclerotinia minor, Sclerotinia minor (SARRITOR (registered trademark)), Scytalidium spp., Scytalidium uredinicola, Spodoptera exigua nuclear polyhedrosis virus (Spod-X (registered trademark), Spexit (registered trademark)), Serratia marcescens, Serratia plymuthica, Serratia spp.) Sordaria fimicola, Spodoptera littoralis nucleopolyhedrovirus (Littovir (registered trademark)), Sporobolomyces roseus, Stenotrophomonas maltophilia, Streptomyces ahygroscopicus, Streptomyces albaduncus, Streptomyces exfoliates, Streptomyces galbus, Streptomyces griseoplanus, Streptomyces griseoviridis (Mycostop (registered trademark)), Streptomyces lydicus (Actinovate (registered trademark)), Streptomyces lydicus WYEC-108 (ActinoGrow (registered trademark)), Streptomyces violaceus, Tilletiopsis minor, Tilletiopsis spp.) Trichoderma asperellum (T34 Biocontrol®), Trichoderma gamsii (Tenet®), Trichoderma atroviride (Plantmate®), Trichoderma hamatum TH382, Trichoderma harzianum rifai (Mycostar®), Trichoderma harzianum T-22 (Trianum-P®, PlantShield HC®, RootShield®, Trianum-G®), Trichoderma harzianum T-39 (Trichodex®), Trichoderma inhamatum, Trichoderma koningii, Trichoderma spp. LC 52 (Sentinel®), Trichoderma lignorum, Trichoderma longibrachiatum, Trichoderma polysporum (Binab T®), Trichoderma taxi, Trichoderma virens, Trichoderma virens (formerly Gliocladium virens GL-21) (SoilGuard®), Trichoderma viride, Trichoderma viride strain ICC 080 (Remedier®), Trichosporon pullulans, Trichosporon spp.) species of the genus Trichothecium, Trichothecium roseum, Typhula phacorrhiza strain 94670, Typhula phacorrhiza strain 94671, Ulocladium atrum, Ulocladium oudemansii (Botry-Zen (registered trademark)), Ustilago maydis, various bacteria and auxiliary trace elements (Natural II (registered trademark)), various fungi (Millennium Microbes (registered trademark)), Verticillium chlamydosporium, Verticillium lecanii (Mycotal (registered trademark), Vertalec (registered trademark)), Vip3Aa20 (VIPtera (registered trademark)), Virgibaclillus marismortui, Xanthomonas campestris pv. Poae (Camperico (registered trademark)), Xenorhabdus bovienii, Xenorhabdus nematophilus;. A plant extract containing the following: pine oil (Retenol (registered trademark)), azadirachtin (Plasma Neem Oil (registered trademark), AzaGuard (registered trademark), MeemAzal (registered trademark), Molt-X (registered trademark), Botanical IGR (Neemazad (registered trademark), Neemix (registered trademark)), canola oil (Lilly Miller Vegol (registered trademark)), Chenopodium ambrosioides near ambrosioides (Requiem (registered trademark)), chrysanthemum extract (Crisant (registered trademark)), neem oil extract (Trilogy (registered trademark)), essential oil of Labiatae (Botania (registered trademark)), extract of clove, rosemary, peppermint and thyme oil (Garden insect killer (registered trademark)), glycine betaine (Greenstim (registered trademark)), garlic, lemongrass oil (GreenMatch (registered trademark)), neem oil, Nepeta cataria (catnip oil), Nepeta catarina, nicotine, oregano oil (MossBuster (registered trademark)), oil of Pedaliaceae (Nematon (registered trademark)), Chou chou, Quillaja saponaria (NemaQ (registered trademark)), Reynoutria sachalinensis (Regalia (registered trademark), Sakalia (registered trademark)), rotenone (Eco Roten (registered trademark)), extract of Rutaceae (Soleo (registered trademark)), soybean oil (Ortho ecosense (registered trademark)), tea tree oil (Timorex Gold (registered trademark)), thyme oil, AGNIQUE (registered trademark) MMF, BugOil (registered trademark), mixture of rosemary, cumin, peppermint, thyme and cinnamon extract (EF 300 (registered trademark)), mixture of clove, rosemary and peppermint extract (EF 400 (registered trademark)), mixture of clove, peppermint, garlic oil and mint SoilShot (registered trademark), kaolin (Screen (registered trademark)), laminarin (registered trademark) of brown algae; Pheromones including the following: blackheaded fireworm pheromone (3M Sprayable Blackheaded Fireworm Pheromone (registered trademark)), codling moth pheromone (Paramount dispenser-(CM) / Isomate C-Plus (registered trademark)), grape berry moth pheromone (3M MEC-GBM Sprayable Pheromone (registered trademark)), leafroller pheromone (3M MEC-LR Sprayable Pheromone (registered trademark)), Muscamone (Snip7 Fly Bait (registered trademark), Starbar Premium Fly Bait (registered trademark)), oriental fruit moth pheromone (3M oriental fruit moth sprayable pheromone (registered trademark)), peachtree borer pheromone (Isomate-P (registered trademark)), tomato pinworm pheromone (3M Sprayable pheromone (registered trademark)), Entostat powder (extract from palm tree) (Exosex CM (registered trademark)), (E,Z,Z)-3,8,11-tetradecatrienyl acetate, (Z,Z,E)-7,11,13-hexadecatrienal, (E,Z)-7,9-dodecadien-1-yl acetate, 2-methyl-1-butanol, calcium acetate, Scenturion (registered trademark), Biolure (registered trademark), Check-Mate (registered trademark), lavandulyl senecioate; Organisms including the following: Aphelinus abdominalis, Aphidius ervi (Aphelinus-System (registered trademark)), Acerophagus papaya, Adalia bipunctata (Adalia-System (registered trademark)), Adalia bipunctata (Adaline (registered trademark)), Adalia bipunctata (Aphidalia (registered trademark)), Ageniaspis citricola, Ageniaspis fuscicollis, Amblyseius andersoni (Anderline (registered trademark), Andersoni-System (registered trademark)), Amblyseius californicus (Amblyline (registered trademark), Spical (registered trademark)), Amblyseius cucumeris (Thripex (registered trademark), Bugline cucumeris (registered trademark)), Amblyseius fallacis (Fallacis (registered trademark)), Amblyseius swirskii (Bugline swirskii (registered trademark), Swirskii-Mite (registered trademark)), Amblyseius womersleyi (WomerMite (registered trademark)), Amitus hesperidum, Anagrus atomus, Anagyrus fusciventris, Anagyrus kamali, Anagyrus loecki, Anagyrus pseudococci (Citripar (registered trademark)), Anicetus benefices, AnisopteromalusCalandrae), Anthocoris nemoralis (Anthocoris-System (registered trademark)), Aphelinus abdominalis (Apheline (registered trademark), Aphiline (registered trademark)), Aphelinus asychis, Aphidius colemani (Aphipar (registered trademark)), Aphidius ervi (Ervipar (registered trademark)), Aphidius gifuensis, Aphidius matricariae (Aphipar-M (registered trademark)), Aphidoletes aphidimyza (Aphidend (registered trademark)), Aphidoletes aphidimyza (Aphidoline (registered trademark)), Aphytis lingnanensis, Aphytis melinus, Aprostocetus hagenowii, Atheta coriaria (Staphyline (registered trademark)), species of the genus Bombus (Bombus spp.), Bombus terrestris (Natupol Beehive (registered trademark)), Bombus terrestris (Beeline (registered trademark), Tripol (registered trademark)), Cephalonomia stephanoderis, Chilocorus nigritus, Chrysoperla carnea (Chrysoline (registered trademark)), Chrysoperla carnea (Chrysopa (registered trademark)), Chrysoperla rufilabris, Cirrospilus ingenuus, Cirrospilus quadristriatus (Cirrospilusquadristriatus), Citrostichus phyllocnistoides, Closterocerus chamaeleon, Closterocerus spp., Coccidoxenoides perminutus (Planopar®), Coccophagus cowperi, Coccophagus lycimnia, Cotesia flavipes, Cotesia plutellae, Cryptolaemus montrouzieri (Cryptobug®, Cryptoline®), Cybocephalus nipponicus, Dacnusa sibirica, Dacnusa sibirica (Minusa®), Diglyphus isaea (Diminex®), Delphastus catalinae (Delphastus®), Delphastus pusillus, Diachasmimorpha krausii, Diachasmimorpha longicaudata, Diaparsis jucunda, Diaphorencyrtus aligarhensis, Diglyphus isaea, Diglyphus isaea (Miglyphus®, Digline®), Dacnusa sibirica (DacDigline®, Minex®), Diversinervus spp., Encarsia citrinacitrina), Encarsia formosa (Encarsia max (registered trademark), Encarline (registered trademark), En-Strip (registered trademark)), Eretmocerus eremicus (Enermix (registered trademark)), Encarsia guadeloupae, Encarsia haitiensis, Episyrphus balteatus (Syrphidend (registered trademark)), Eretmoceris siphonini, Eretmocerus californicus, Eretmocerus eremicus (Ercal (registered trademark), Eretline e (registered trademark)), Eretmocerus eremicus (Bemimix (registered trademark)), Eretmocerus hayati, Eretmocerus mundus (Bemipar (registered trademark), Eretline m (registered trademark)), Eretmocerus siphonini, Exochomus quadripustulatus, Feltiella acarisuga (Spidend (registered trademark)), Feltiella acarisuga (Feltiline (registered trademark)), Fopius arisanus, Fopius ceratitivorus, Hormone (Wirless Beehome (registered trademark)), Franklinothrips vespiformis (Vespop (registered trademark)), Galendromus occidentalis, Goniozus legneri, Habrobracon hebetor, Harmonia axyridis (HarmoBeetle®), Heterorhabditis spp. (Lawn Patrol®), Heterorhabditis bacteriophora (NemaShield HB®, Nemaseek®, Terranem-Nam®, Terranem®, Larvanem®, B-Green®, NemAttack®, Nematop®), Heterorhabditis megidis (Nemasys H®, BioNem H®, Exhibitline hm®, Larvanem-M®), Hippodamia convergens, Hypoaspis aculeifer (Aculeifer-System®, Entomite-A®), Hypoaspis miles (Hypoline m®, Entomite-M®), Lbalia leucospoides, Lecanoideus floccissimus, Lemophagus errabundus, Leptomastidea abnormis, Leptomastix dactylopii (Leptopar®), Leptomastix epona, Lindorus lophanthae, Lipolexis oregmae, LuciliaCaesar)(Natufly (registered trademark)), Lysiphlebus testaceipes, Macrolophus caliginosus (Mirical-N (registered trademark), Macroline c (registered trademark), Mirical (registered trademark)), Mesoseiulus longipes, Metaphycus flavus, Metaphycus lounsburyi, Micromus angulatus (Milacewing (registered trademark)), Microterys flavus, Muscidifurax raptorellus, and Spalangia cameroni (Biopar (registered trademark)), Neodryinus typhlocybae, Neoseiulus californicus, Neoseiulus cucumeris (THRYPEX (registered trademark)), Neoseiulus fallacis, Nesideocoris tenuis (NesidioBug (registered trademark), Nesibug (registered trademark)), Ophyra aenescens (Biofly (registered trademark)), Orius insidiosus (Thripor-I (registered trademark), Oriline i (registered trademark)), Orius laevigatus (Thripor-L (registered trademark), Oriline l (registered trademark)), Orius majusculus (Oriline m (registered trademark)), Orius strigicollis (Thripor-S (registered trademark)), Pauesia juniperorum, Pediobius foveolatusfoveolatus), Phasmarhabditis hermaphrodita (Nemaslug®), Phymastichus coffea, Phytoseiulus macropilus, Phytoseiulus persimilis (Spidex®, Phytoline p®), Podisus maculiventris (Podisus®), Pseudacteon curvatus, Pseudacteon obtusus, Pseudacteon tricuspis, Pseudaphycus maculipennis, Pseudleptomastix mexicana, Psyllaephagus pilosus, Psyttalia concolor (complex), Quadrastichus spp., Rhyzobius lophanthae, Rodolia cardinalis, Rumina decollate, Semielacher petiolatus, Sitobion avenae (Ervibank®), Steinernema carpocapsae (Nematac C®, Millenium®, BioNem C®, NemAttack®, Nemastar®, Capsanem®), Steinernema feltiae (NemaShield®, Nemasys F®, BioNemF (Registered Trademark), Steinernema-System (Registered Trademark), NemAttack (Registered Trademark), Nemaplus (Registered Trademark), Exhibitline sf (Registered Trademark), Scia-rid (Registered Trademark), Entonem (Registered Trademark)), Steinernema kraussei (Nemasys L (Registered Trademark), BioNem L (Registered Trademark), Exhibitline srb (Registered Trademark)), Steinernema riobrave (BioVector (Registered Trademark), BioVektor (Registered Trademark)), Steinernema scapterisci (Nematac S (Registered Trademark)), Steinernema spp., Steinernematid spp. (Guardian Nematodes (Registered Trademark)), Stethorus punctillum (Stethorus (Registered Trademark)), Tamarixia radiate, Tetrastichus setifer, Thripobius semiluteus, Torymus sinensis, Trichogramma brassicae (Tricholine b (Registered Trademark)), Trichogramma brassicae (Tricho-Strip (Registered Trademark)), Trichogramma evanescens, Trichogramma minutum, Trichogramma ostriniae, Trichogramma platneri, Trichogramma pretiosum, Xanthopimpla stemmator; Other biological agents including: abscisic acid, bioSea®, Chondrostereum purpureum (Chontrol Paste®), Colletotrichum gloeosporioides (Collego®), copper octanoate (Cueva®), Delta traps (Trapline d®), Erwinia amylovora (Harpin) (ProAct®, Ni-HIBIT Gold CST®), fatty acids derived from natural by-products of extra-virgin olive oil (FLIPPER®), ferric phosphate (Ferramol®), Funnel trap (Trapline y®), Gallex®, Grower’s Secret®, Homo-brassonolide, iron phosphate (Lilly Miller Worry Free Ferramol Slug&Snail Bait®), MCP hail trap (Trapline f®), Microctonus hyperodae, Mycoleptodiscus terrestris (Des-X®), BioGain®, Aminomite®, Zenox®, Pheromone trap (Thripline ams®), potassium bicarbonate (MilStop®), potassium salts of fatty acids (Sanova®), potassium silicate solution (Sil-Matrix®), potassium iodide + potassium thiocyanate (Enzicur®), SuffOil-X®, spider venom, Nosema locustae (Semaspore Organic Grasshopper Control®), sticky traps (Trapline YF®, Rebell Amarillo®) and traps (Takitrapliney + b (Registered Trademark)); Toxicity reducing agents such as benoxacol, clocynthiuron (including clocynthiuron methyl), cyprosulfamide, dichloramide, fenchlorazole (including fenchlorazole-ethyl), fenclorim, fluchloxypyr, furilazole, isoxadifen (including isoxadifen-ethyl), mefenpyr (including mefenpyr-diethyl), metcamifene, and oxabetrinil may be selected from.

[0021] Suitable bactericides and fungicides include etridiazole, fluazinam, benalaxyl, benalaxyl-M (kiralaxyl), fluralaxyl, metalaxyl, metalaxyl-M (mefenoxam), dodine, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylformamidine, N'-[4-(4,5-dichloro-thiazol-2-yloxy)-2,5-dimethylphenyl]-N-ethyl-N-methylformamidine, N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2,5-dimethylphenyl]-N-ethyl-N-methylformamidine, etirimol, 3'-chloro-2-methoxy-N-[(3RS)-tetrahydro-2-oxofuran-3-yl]acetamide-2',6'-xylidine (clozylacon), cyprodinil, mepanipyrim, pyrimethanil, dithianon, aureofungin, blasticidin-S, biphenyl, chloroneb, dicloran, benzovindiflupyr, pidiflumetofen, hexachlorobenzene, quintozene, tecnazene, (TCNB), tricophos-methyl, metrafenone, 2,6-dichloro-N-(4-trifluoromethylbenzyl)-benzamide, fluopicolide (fluopicolide), thioxamide, flusulfamide, benomyl, carbendazim, carbendazim chlorohydrate, chlorphenazole, fuberidazole, thiabendazole, thiophanate-methyl, benztiabencarb, chlobenthiazole, probenazole, acibenzolar, bethoxazin, pyriofenone (IKF-309), acibenzolar-S-methyl, pyribencarb (KIF-7767), butylamine, 3-iodo-2-propynyl n-butylcarbamate (IPBC), iodocarb (isopropyl butylcarbamate), isopropyl butylcarbamate (iodocarb), picarbutrazox, polycarbamate, propamocarb, tolcofos-methyl, 3-(difluoromethyl)-N-(7-fluoro-1,1,3,3-Tetramethyl-indan-4-yl)-1-methyl-pyrazole-4-carboxamide diclosimet, N-[(5-chloro-2-isopropyl-phenyl)methyl]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-pyrazole-4-carboxamide N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-[(2-isopropylphenyl)methyl]-1-methyl-pyrazole-4-carboxamide carpropamid, chlorothalonil, fluomorph, copper oxinate, simoxanil, fenamacril, cyazofamid, flutianil, thiazofan, chlorozolinate, iprodione, procymidone, vinclozolin, bupirimate, dinocap, dinopentate, dinobuton, dinocup, meptyldinocup, diphenylamine, fosdiphen, 2,6-dimethyl-[1,4]dithino[2,3-c:5,6-c’]dipyrrole-1,3,5,7(2H,6H)-tetraone, azitiram, etem, ferbam, mancozeb, manneb, metam, metham (polyram), metham-zinc, nabam, propineb, thiram, vapam (metam sodium), dinneb, dithiram, dithioether, isoprothiolane, ethaboxam, fosetyl, fosetyl-Al (fosetyl-aluminum), methyl bromide, methyl iodide, methyl isothiocyanate, cyclafuramid, fenfluram, validamycin, streptomycin, (2RS)-2-bromo-2-(bromomethyl)glutaronitrile (bromothalonil), dodine, doguadine, guazatine, iminoctadine, iminoctadine triacetate, 2,4-D, 2,4-DB, kasugamycin, dimethirimol, fenhexamid, hymexazol, hydroxyisoxazole imazalil, imazalil sulfate, oxpoconazole, pefurazoate, procymidone, triflumizole, fenamidone, Bordeaux mixture, calcium polysulfide, copper acetate, copper carbonate, copper hydroxide, copper naphthenate, copper oleate, copper oxychloride, copper 8-hydroxyquinolate, copper silicate, copper sulfate, copper tallate, cuprous oxide, sulfur, carbaryl, phthalide (fusaride), diniconazole (Jun Si Qi), oxathiapiprolin, fluoroimide, mandipropamid, KSF-1002, benzamorph, dimethomorph, fenpropimorph, tridemorph, dodemorph, diethofencarb, fenbutatin acetate, fenbutatin hydroxide, carboxin, oxycarboxin, drazoxolon, famoxadone, m-phenylphenol, p-phenylphenol, tribromophenol (TBP), 2-[2-[(7,8-difluoro-2-methyl-3-quinolyl)oxy]-6-fluorophenyl]propan-2-ol, 2-[2-fluoro-6-[(8-fluoro-2-methyl-3-quinolyl)oxy]phenyl]propan-2-ol, cyflufenamid, ofurace, oxadixyl, flutolanil, mepronil, isopfetamid, fenpiclonil, fludioxonil, penthiopyrad, edifenphos, iprobenfos, pyrazophos, phosphoric acid, tecnazene, captan, captan, ditrimfos, triafamone, fenpropidin, piperalin, osthol, 1-methylcyclopropene, 4-CPA, chlormequat, chlorfenprop-methyl, dichlorprop, dimethipin, endothal, ethephon, flumetralin, chlorfluazuron, brassinolide, gibberellin A2, hymexazol, maleic hydrazide, mepiquat chloride, naphthaleneacetamide, paclobutrazol, prohexadione, prohexadione-calcium, thidiazuron, tribufos (tributyl phosphorotrithioate), trinexapac, uniconazole, α-naphthaleneacetic acid, polyoxin D (polyoxylin), BLAD, chitosan, phenoxanil, folpet, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[1-methyl-2-(2,4,6-(Trichlorophenyl)ethyl]pyrazole-4-carboxamide, bixafen, fluxapyroxad, flutriafol, isopyrazam, penthiopyrad, sedaxane, fenpyrazamine, diclomezine, pyrifenox, boscalid, fluopyram, diflumetorim, fenarimol, 5-fluoro-2-(p-tolylmethoxy)pyrimidin-4-amine ferimzone, dimethachlon (dimethachlon), pyroquilon, proquinazid, ethoxyquin, quinoxyfen, 4,4,5-trifluoro-3,3-dimethyl-1-(3-quinolyl)isoquinoline, 4,4-difluoro-3,3-dimethyl-1-(3-quinolyl)isoquinoline 5-fluoro-3,3,4,4-tetramethyl-1-(3-quinolyl)isoquinoline 9-fluoro-2,2-dimethyl-5-(3-quinolyl)-3H-1,4-benzoxazepine, tebufloquin, oxolinic acid, quinomethionate (oxythioquinox, quinoxymethylthionate), spiroxamine, (E)-N-methyl-2-[2-(2,5-dimethylphenoxymethyl)phenyl]-2-methoxy-iminoacetamide, (mandestrobin), azoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, enoxastrobin, fenamidstrobin, fluopicoxystrobin, fluoxastrobin, kresoxim-methyl, mandestrobin, metaminostrobin, metoxystrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, triclopyricarb, trifloxystrobin, amisulbrom, dichlofluanid, tolylfluanid, but-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate, dazomet, isothianil, thiazinyl, tiadinil, zoxamide, anilazine, tricyclazole, (.+-.)-cis-1-(4-chlorophenyl)-2-(1H-1,2,4-triazol-1-yl)-cycloheptanol (fungunzuo), 1-(5-bromo-2-pyridyl)-2-(2,4-difluorophenyl)-1,1-difluoro-3-(1,2,2-(1-tert-butyl)-1-(2-chlorophenyl)-3-(1,2,4-triazol-1-yl)propan-2-ol (TCDP), azaconazole, bitertanol (bixolazole), bromoconazole, climbazole, cyproconazole, difenoconazole, diniconazole, diniconazole-M, epoxyconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ipconazole, ipfentrifluconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole,simeconazole, tebuconazole, tetraconazole, triadimefon, triadimenol, triazoxide, triticonazole, mefentrifluconazole, 2-[[(1R,5S)-5-[(4-fluorophenyl)methyl]-1-hydroxy-2,2-dimethyl-cyclopentyl]methyl]-4H-1,2,4-triazole-3-thione, 2-[[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl]-4H-1,2,4-triazole-3-thione, amisulbrom (imidium), iprovalicarb, valifenalate, 2-benzyl-4-chlorophenol (chlorophen), allyl alcohol, azaphenidene, benzalkonium chloride, chloropicrin, cresol, daracide, dichlorophen, diphenzoate, dipyrithione, N-(2-p-chlorobenzoylethyl)-hexaminium chloride, NNF-0721, octhilinone, oxasulfuron, propamidine and propionic acid may be selected from.,

[0022] The pesticide may be in mesomeric form, and stereoisomers or enantiomers, and, where applicable, various polymorphic modification forms.,

[0023] More preferably, suitable herbicides include pinoxaden, bicyclopyrone, mesotrione, homosafen, tralkoxydim, napropamide, amitraz, propanil, pyrimethanil, dichloran, tecnazene, toclofos-methyl, flamprop-M, 2,4-D, MCPA, mecoprop, clodinafop-propargyl, cyhalofop-butyl, dichlofop-methyl, haloxyfop, quizalofop-P, indole-3-ylacetic acid, 1-naphthylacetic acid, isoxaben, tebutam, chlorthal-dimethyl, benomyl, benfuresate, dicamba, diclobenil, benazolin, triazoxide, fluazuron, teflubenzuron, fenmedifam, acetochlor, alachlor, metolachlor, pretilachlor, thenylchlor, alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tepraloxydim, pendimethalin, dinoterb, biphenox, oxyfluorfen, acifluorfen, flumiclorac-pentyl, picloram, amidosulfuron, chlorosulfuron,nicosulfuron, rimsulfuron, triasulfuron, triarat, pebulate, prosulfocarb, molinate, atrazine, simazine, cyanazine, ametryn, prometryn, terbuthylazine, terbutryn, sulcotrione, isoproturon, linuron, fenuron, chlorotoluron, metoxuron, iodosulfuron, mesosulfuron, diflufenican, flufenacet, fluroxypyr, aminopyralid, pyroxasulfone, XDE-848 Rinskor, and haloxyfop-methyl.

[0024] Suitable fungicides include isopyrazam, mandipropamid, azoxystrobin, trifloxystrobin, kresoxim-methyl, mefenoxam, famoxadone, metominostrobin, picoxystrobin, cyprodanil, carbendazim, thiabendazole, dimethomorph, vinclozolin, iprodione, dithiocarbamate, imazalil, prochloraz, fluquinconazole, epoxiconazole, flutriafol, azaconazole, bitertanol, bromoconazole, cyproconazole, difenoconazole, hexaconazole, paclobutrazol, propiconazole, tebuconazole, triadimefon, triticonazole, fenpropimorph, tridemorph, fenpropidin, mancozeb, metiram, chlorothalonil, thiram, dithiram, captan, captophos, folpet, fluazinam, flutolanil, carboxin, metalaxyl, bupirimate, ethirimol, dimoxystrobin, fluoxastrobin, orysastrobin, metominostrobin, prothioconazole, adepidyn, bixafen, fluxapyroxad, prothioconazole, pyraclostrobin, revysol, solatenol, and zemicum.

[0025] Suitable insecticides include thiamethoxam, imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, fipronil, abamectin, emamectin, tefluthrin, emamectin benzoate, benfuracarb, carbaryl, phenoxycarb, isoprocarb, pyrimicarb, propoxur, xylylcarb, asulam, chlorpropham, endosulfan, heptachlor, tebufenozide, bensultap, diefenacarb, pirimiphos-methyl, aldicarb, methomyl, cypermethrin, bioallethrin, deltamethrin, lambda-cyhalothrin, cyhalothrin, cyfluthrin, fenvalerate, imiprothrin, permethrin, halfenprox, oxamyl, flupyradifurone, sedaxane, inscalis, lynxacypyr, cyantraniliprole, sulfoxaflor, and spinetoram.

[0026] Suitable plant growth regulators include paclobutrazol, trinexapac-ethyl, and 1-methylcyclopropene.

[0027] Suitable phytotoxicity reducers include benoxacor, cloquintocet-methyl, thiomethrinyl, dichlormid, fenchlorazole-ethyl, fenclorim, flurazole, fluxofenim, mefenpyr-diethyl, MG-191, naphthalic anhydride, and oxabetrinil.

[0028] Preferably, the pesticide is bicyclopyrone, mesotrione, pinoxaden, homosafen, tralkoxydim, napropamide, amitraz, propanil, pyrimethanil, dichloran, tecnazene, toclofos-methyl, flamprop-M, 2,4-D, MCPA, mecoprop, clodinafop-propargyl, cyhalofop-butyl, dichlorprop-methyl, haloxyfop, quizalofop-P, indole-3-ylacetic acid, 1-naphthylacetic acid, isoxaben, tebutam, chlorothaldimethyl, benomyl, benfuracarb, dicamba, diclobenil, benazolin, triazoxide, fluazuron, teflubenzuron, fenmedifam, acetochlor, alachlor, metolachlor, pretilachlor, thenylchlor, alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tepraloxydim, pendimethalin, dinoterb, biphenox, oxyfluorfen, acifluorfen, fluoroglycofen-ethyl, bromoxynil, ioxynil, imazamethabenz-methyl, imazapyr, imazakine, imazetapyr, imazapic, imazamox, flumioxazin, flumiclorac-pentyl, picloram, amidosulfuron, chlorosulfuron, nicosulfuron, rimsulfuron, triasulfuron, triazamate, pebulate, prosulfocarb, molinate, atrazine, simazine, cyanazine, ametryn, prometryn, terbuthylazine, terbutryn, sulcotrione, isoproturon, linuron, fenuron, chlorotoluron, metoxuron, isopyrazam, mandipropamid, azoxystrobin, trifloxystrobin, kresoxim-methyl, famoxadone, metominostrobin and picoxystrobin, cyprodanil, carbendazim, thiabendazole, dimethomorph, vinclozolin, iprodione, dithiocarbamate, imazalil, prochloraz, fluquinconazole, epoxiconazole, flutriafol, azaconazole, bitertanol, bromoconazole, cyproconazole, difenoconazole, hexaconazole, paclobutrazol, propiconazole, tebuconazole, triadimefon, triticonazole, fenpropimorph, tridemorph, fenpropidin, mancozeb, metiram,Selected from chlorothalonil, thiram, ziram, captan, captfol, folpet, fluazinam, flutolanil, carboxin, metalaxyl, bupirimate, etirimol, dimoxystrobin, fluoxastrobin, orysastrobin, metominostrobin, prothioconazole, thiamethoxam, imidacloprid, acetamiprid, clothianidin, dinotefuran, nitenpyram, fipronil, abamectin, emamectin, benfuracarb, carbaryl, phenoxycarb, isoprocarb, pyrimicarb, propoxur, xylylcarb, asulam, chlorpropham, endosulfan, heptachlor, tebufenozide, bensultap, diethofencarb, pirimiphos-methyl, aldicarb, methomyl, cyprmethrin, bioallethrin, deltamethrin, lambda-cyhalothrin, cyhalothrin, cyfluthrin, fenvalerate, imiprothrin, permethrin, halfenprox, paclobutrazol, 1-methylcyclopropene, benoxacor, cloquintocet-methyl, thiomethrinyl, dichloromid, fenchlorazole-ethyl, fenclorim, flurazole, flurioxypyr, mefenpyr-diethyl, MG-191, naphthalic anhydride and oxabetrinyl.,

[0029] Preferred pesticidal active ingredients are selected from homomethafen (preferably as the sodium salt), mesotrione, nicosulfuron, pinoxaden, isopyrazam, epoxiconazole, solatenol and cyantraniliprole.

[0030] Advantageously, the composition comprises one or more surfactants and / or oils (such as mineral oils and / or vegetable oils).

[0031] The surfactant is employed as a formulation component and as an adjuvant and may be present in an amount of 0.00001 to 8% by weight, such as 0.0001 to 5% by weight, 0.001 to 4% by weight, 0.01 to 3% by weight, or even 0.1 to 2% by weight.

[0032] Suitable ionic surfactants are aromatic sulfonic acids such as lignosulfonic acid, phenolsulfonic acid, naphthalenesulfonic acid, dibutylnaphthalenesulfonic acid or fatty acid alkali, alkaline earth and ammonium salts, alkyl- and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and aliphatic alcohol sulfates, and salts of sulfated hexa-, hepta- and octadecanols, and salts of aliphatic alcohol glycol ethers, condensates of sulfonated naphthalenes and their derivatives with formaldehyde, condensates of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polycarboxylates or phosphate esters of alkoxylated alcohols.

[0033] Suitable nonionic surfactants are polyoxyethylene octylphenol ether, alkoxylated alcohols such as ethoxylated isooctyl-, octyl- or nonyl-phenol, alkylphenyl polyglycol ether, tributylphenyl polyglycol ether, alkylaryl polyether alcohol, isotridecyl alcohol, aliphatic alcohol / ethylene oxide condensates, ethoxylated castor oil, alkyl polyglycoside, polyoxyethylene alkyl ether or polyoxypropylene alkyl ether, lauryl alcohol polyglycol ether acetate, sorbitol esters, lignin-sulfite waste liquor and proteins, denatured proteins, hydrophobically modified starch, polyvinyl alcohol (e.g. Mowiol®), polyalkoxylate, polyvinylamine, polyethyleneimine, polyvinylpyrrolidone and its copolymers or block polymers.

[0034] Organic liquids (oils) can be employed as components of formulations as solvents or adjuvants. They can also be added to spray tank dilutions as adjuvants for various functions such as improving uptake, spreading properties, rainfastness, drift reduction, reduction of volatility, etc., although not limited to these.

[0035] Suitable oils can be vegetable, mineral and animal oils, and alkyl esters of these oils such as vegetable oils and vegetable oil esters and diesters (including esters with glycerin and propylene glycol). Some preferred oils are methyl, ethyl, isopropyl, isobutyl, butyl, hexyl and ethylhexyl esters. Others are methyl oleate, ethyl oleate, methyl palmitate, rapeseed oil methyl ester, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, ethylhexyl oleate, a mixture of ethylhexyl myristate / laurate, ethylhexyl laurate, a mixture of ethylhexyl caprylate / caprate, diisopropyl adipate, coconut oil propylene glycol diester, sunflower oil, rapeseed oil, corn oil, soybean oil and its alkyl esters, rice bran oil and its alkyl esters, olive oil, caprylic and capric triglycerides mixed with peanut oil, and vegetable oils and esters selected from the group consisting of mixed decanoyl and octanoyl glycerides. Also suitable are mineral oils such as Exxsol D100, Solvesso 200ND and white oil, and alkyl esters of phosphoric and phosphonic acids such as tris-alkyl-phosphate esters. Preferably, it is tris(2-ethylhexyl) phosphate.

[0036] Preferably, one or more surfactants and / or oils are selected from nonionic and ionic surfactants, castor oil ethoxylate, sulfosuccinate esters, alkyl polyglycosides, polypropylene glycol-polyethylene glycol copolymers, and / or ethoxylated trisiloxanes.

[0037] The composition may contain additional polymers, preferably the selected polymers are polysaccharides. Advantageously, the additional polymers are selected from one or more of unmodified and modified guar gum, xanthan gum, natural and / or modified cellulose-based.

[0038] The compositions described herein are advantageously suitable for use in precision application devices. The use of the compositions described herein in precision application devices is also provided.

[0039] In a second aspect of the invention, there is provided a precision application device, and a pesticide; a polymer; and a carrier fluid wherein the polymer is selected from one or more polysaccharides.

[0040] The device comprises a nozzle, preferably a jet nozzle or a narrow angle flat fan nozzle. In such a device, advantageously, the application is made at an application rate of 20 - 3000 L / Ha, preferably 200 - 500 L / Ha.

[0041] Advantageously, the composition comprises one or more surfactants and / or oils (such as mineral oil and / or vegetable oil).

[0042] The polymer is preferably selected from one or more of diutan gum, unmodified and modified guar gum, xanthan gum, natural and / or modified cellulose-based. Advantageously, the polymer can be present in an amount of 0.001 - 2 wt%, preferably 0.01 - 0.20 wt%, and preferably the carrier fluid contains water, such as 80 - 100% or 80 - 99.5 wt% of the carrier fluid.

[0043] Advantageously, the pesticide is used at the maximum label use rate of the active ingredient. The pesticide can be used in an amount of 0.0001 - 25 wt%, such as 0.001 - 20 wt%, 0.01 - 5 wt%, or 6 - 15 wt%. The pesticide is preferably selected from the above list.

[0044] The surfactant is employed as a formulation component and as an adjuvant, and can be present in an amount of 0.00001 - 8 wt%, such as 0.0001 - 5 wt%, 0.001 - 4 wt%, 0.01 - 3 wt%, or even 0.1 - 2 wt%.

[0045] Suitable ionic surfactants are aromatic sulfonic acids such as lignosulfonic acid, phenolsulfonic acid, naphthalenesulfonic acid, dibutylnaphthalenesulfonic acid or fatty acid alkali, alkaline earth and ammonium salts, alkyl- and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and aliphatic alcohol sulfates, and salts of sulfated hexa-, hepta- and octadecanols, and salts of aliphatic alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, polycarboxylate or phosphate esters of alkoxylated alcohols.

[0046] Suitable nonionic surfactants are polyoxyethylene octylphenol ether, alkoxylated alcohols such as ethoxylated isooctyl-, octyl- or nonyl-phenol, alkylphenyl polyglycol ether, tributylphenyl polyglycol ether, alkylaryl polyether alcohol, isotridecyl alcohol, aliphatic alcohol / ethylene oxide condensates, ethoxylated castor oil, alkyl polyglycoside, polyoxyethylene alkyl ether or polyoxypropylene alkyl ether, lauryl alcohol polyglycol ether acetate, sorbitol ester, lignin-sulfite waste liquor and proteins, denatured proteins, hydrophobically modified starch, polyvinyl alcohol (e.g., Mowiol®), polyalkoxylate, polyvinylamine, polyethyleneimine, polyvinylpyrrolidone and its copolymers or block polymers.

[0047] Organic liquids (oils) can be employed as components of formulations as solvents or adjuvants. They can also be added to spray tank dilutions as adjuvants for various functions such as improving uptake, spreading, rainfastness, drift reduction, reducing volatility, etc., without limitation.

[0048] Suitable oils can be plant, mineral and animal oils, and alkyl esters of these oils such as vegetable oils and vegetable oil esters and diesters (including esters with glycerin and propylene glycol). Some preferred oils are methyl, ethyl, isopropyl, isobutyl, butyl, hexyl and ethylhexyl esters. Others are methyl oleate, ethyl oleate, methyl palmitate, rapeseed oil methyl ester, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, ethylhexyl oleate, a mixture of ethylhexyl myristate / laurate, ethylhexyl laurate, a mixture of ethylhexyl caprylate / caprate, diisopropyl adipate, coconut oil propylene glycol diester, sunflower oil, rapeseed oil, corn oil, soybean oil and its alkyl esters, rice bran oil and its alkyl esters, olive oil, caprylic and capric triglycerides mixed with peanut oil, and vegetable oils and esters selected from the group consisting of mixed decanoyl and octanoyl glycerides. Also suitable are mineral oils such as Exxsol D100, Solvesso 200ND and white oil, and alkyl esters of phosphoric and phosphonic acids such as tris-alkyl-phosphate esters. Preferably, tris(2-ethylhexyl) phosphate.

[0049] Preferably, one or more surfactants and / or oils are selected from nonionic and ionic surfactants, castor oil ethoxylate, sulfosuccinate esters, alkyl polyglycosides, polypropylene glycol-polyethylene glycol copolymers, and / or ethoxylated trisiloxanes.

[0050] In a third aspect of the invention, there is provided the use of a polymer for reducing the breakup of a pesticide composition, preferably a herbicide composition, wherein the polymer is selected from one or more polysaccharides such as diutan gum, unmodified and modified guar gum, xanthan gum, one or more of natural and / or modified cellulose-based.

[0051] Preferably, the crushing is reduced by at least 50%, such as at least 60%, 70%, 75%, preferably at least 85%, or even at least 90%.

[0052] Unless otherwise specified, the amounts of components in percentages are described as percentages relative to the total weight, and all embodiments and preferred features can be combined in any combination.

[0053] The present invention is defined by the following non-limiting examples.

Example

[0054] Apparatus: Jet nozzle: Burkert 6712 Whisper Valve, 0.4 mm opening, using EPDM seal. Burkert Manifold (694895). 1 / 4 inch 21G Needle Tip. Flat fan: Pulsajet AAB10000AUH-03. Lechler 652.301 (PVDF)

[0055]

Table 1

[0056]

Table 2

[0057] Methodology Formulation preparation: All polysaccharides were prepared as 1% gels in deionized water by high-shear mixing before use.

[0058] The spray solution was prepared by completely mixing the required amounts of components defined in the following table. In all cases, the remaining amount up to 100% by weight was water as the carrier fluid.

[0059] Sulfacid Blue 5J was introduced into the spray solution at a final concentration of 0.5% w / w.

[0060] Spray evaluation To evaluate the effectiveness of the polysaccharide in reducing the fragmentation of the composition, a special spray evaluation method was developed. A custom electrostatic spray rig equipped with a jet-type nozzle operating at 3.0 ± 0.1 bar was constructed. The target surface was placed 10 cm below the nozzle tip, which was a circular synthetic fabric substrate (D = 20 mm) on a cylindrical support (20 mm × 80 mm) unless otherwise specified. This surface had a contact angle of 133 ± 2° with deionized water and was used to reproduce water-repellent foliage.

[0061] The formulation was charged into the spray rig and the operating parameters were adjusted so that a spray solution dosage of 14 ± 1 mg was reliably applied to the target. Below the supported target surface, A4 paper was placed to capture stray spray and visualization was assisted with a blue dye. For each spray condition, a total of 10 sprays were carried out and collected (e.g., 10 repetitions for 10 sheets of paper).

[0062] Compositions 1 - 27 were sprayed with a jet-type nozzle and compositions 28 - 30 were sprayed with a flat fan nozzle.

[0063] The fragmentation performance was evaluated as follows. Ten sheets of A4 capture paper were digitized using a Brother DS-720D scanner operating at 600 dpi. The digitized data was then analyzed using a custom ImageJ macro to collect information on the number of droplets, their arrangement, and area. The performance was evaluated by analysis of the total number of droplets, where reduction in fragmentation was characterized by the rate of decrease in the total number of droplets.

[0064] The results are shown in Tables 2 - 7.

[0065] Figure 1 shows the digitized droplet position data for formulation entries 16, 17, 18, and 21, demonstrating a significant improvement in the performance of the compositions according to the present invention.

[0066] Table 2. Summary of data for the diutan gum + spray solution containing 0.38% of H-1 at a constant concentration. The spray solution also contained 0.25% w / w ammonium sulfate. Empicol ESC 70 was constant at 0.25%. Nozzle type = jet nozzle

[0067]

Table 3

[0068] Table 3. Summary of data for diutan gum + various surfactant chemical substances. The diutan gum filling amount was constant at 0.10% w / w, and the surfactant filling amount was constant at 0.25% w / w. Nozzle type = jet nozzle

[0069]

Table 4

[0070] Table 4. Summary of data for single and mixed polysaccharides + Touchdown Quattro (TDQ). The total polysaccharide concentration was constant at a total of 0.10% w / w, where for the binary mixture it was a 1:1 mass ratio. TDQ was constant at 0.72% w / w. Nozzle type = jet nozzle

[0071]

Table 5

[0072] Table 5. Summary of data for the diutan gum spray solution used with the EC formulation (Katoun Gold, AI = pelargonic acid). The polysaccharide concentration was constant at 0.10% w / w, and pelargonic acid was constant at 10% w / w. Nozzle type = jet nozzle

[0073]

Table 6

[0074] Table 6. Summary of data for the diutan gum spray solution used with the SC (Quadris, AI = azoxystrobin) formulation. The polysaccharide concentration is constant at 0.10% w / w. Quadris is constant at 0.83% w / w. Nozzle type = jet nozzle

[0075]

Table 7

[0076] Table 7. Summary of data for the diutan gum spray solution used with Touchdown Quattro. Here, the polysaccharide concentration is constant at 0.10% w / w and Touchdown Quattro is constant at 0.72% w / w. Nozzle type = flat fan. In this case, the target substrate was an ellipse (D = 40 × 80 mm) placed on an elliptical cylindrical support (40 × 80 mm × 80 mm).

[0077]

Table 8

[0078] It can be seen that the composition according to the present invention shows a remarkable improvement in reducing fragmentation.

[0079] The present invention is defined by the claims.

Claims

1. a. A pesticide; b. Guar gum; and c. A carrier fluid A composition comprising: The guar gum is present in an amount of 0.001 to 2% by weight, The carrier fluid contains water and is present in an amount of 65 to 95% by weight.

2. The composition according to claim 1, wherein the pesticide is present in an amount of 0.0001 to 25% by weight.

3. The composition according to claim 1 or 2, wherein the guar gum is present in an amount of 0.01 to 0.20% by weight.

4. The composition according to any one of claims 1 to 3, comprising one or more surfactants and / or oils.

5. The composition according to claim 4, wherein the nonionic and ionic surfactants are preferably castor oil ethoxylate, sulfosuccinate ester, alkyl polyglycoside, polypropylene glycol - polyethylene glycol copolymer and / or ethoxylated trisiloxane.

6. The composition according to any one of claims 1 to 5, comprising an additional polymer, wherein the polymer is selected from polysaccharides.

7. The composition according to claim 6, wherein the additional polymer is selected from one or more of unmodified and modified guar gum, xanthan gum, natural and / or modified cellulose-based materials.

8. The composition according to any one of claims 1 to 7, which is suitable for use in a precision application device.

9. Use of the composition according to any one of claims 1 to 8 in a precision application device.

10. A precision application device and a. A pesticide; b. A polymer; and c. A carrier fluid A composition comprising: The polymer is selected from one or more polysaccharides, a precision application device and a composition.

11. The device according to claim 10, comprising a nozzle, preferably a jet nozzle or a narrow-angle flat fan nozzle.

12. The application is carried out at an application rate of 20 to 3000 L / Ha, preferably 200 to 500 L / Ha, the device according to claim 10 or 11.

13. The polymer is selected from guar gum, unmodified and modified guar gum, xanthan gum, natural and / or modified cellulose-based materials, the device according to any one of claims 10 to 13.

14. The carrier fluid contains water, the device according to any one of claims 10 to 13.

15. Use of a polymer for reducing the fragmentation of a pesticide composition, wherein the polymer is selected from one or more polysaccharides.

16. The use according to claim 15, wherein said crushing is reduced by at least 50%, preferably at least 85%.

17. The use according to claim 15 or 16, wherein said pesticide composition is a herbicide composition.

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