Method for controlling harmful arthropods using heterocyclic compounds
Heterocyclic compounds address the inadequacies of existing arthropod control methods by offering a comprehensive pest management solution for plants and soil using a variety of active ingredients.
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2025-12-09
- Publication Date
- 2026-03-17
AI Technical Summary
Existing methods for controlling harmful arthropods are inadequate.
A method using heterocyclic compounds represented by formula (I) and their derivatives, applied in compositions with various active ingredients, for controlling harmful arthropods on plants and soil, including arthropod-killing and nematode-killing agents, fungicides, plant growth regulators, and biological control materials.
Effectively controls harmful arthropods on plants and soil, providing comprehensive pest management.
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Abstract
Description
[Technical Field]
[0001] This invention relates to a method for controlling harmful arthropods using heterocyclic compounds. [Background technology]
[0002] Various compounds have been investigated to date for the purpose of controlling harmful arthropods. For example, Patent Document 1 describes that certain compounds have pest control effects. [Prior art documents] [Patent Documents]
[0003] [Patent Document 1] International Publication No. 2022 / 157188 [Overview of the Initiative] [Problems that the invention aims to solve]
[0004] The present invention aims to provide a method for controlling harmful arthropods. [Means for solving the problem]
[0005] The present invention is as follows: [1] Equation (I) TIFF2026048769000001.tif2851 [in the formula, R 1 This represents a C1-C3 chain hydrocarbon group, a cyclopropyl group, or a hydrogen atom, which may be substituted with one or more halogen atoms. R 2is a 5- or 6-membered aromatic heterocyclic group optionally substituted with one or more substituents selected from Group A, a phenyl group optionally substituted with one or more substituents selected from Group A, a 9-membered aromatic heterocyclic group {the 9-membered aromatic heterocyclic group is optionally substituted with one or more substituents selected from the group consisting of a C1-C6 linear hydrocarbon group optionally substituted with one or more halogen atoms, and a halogen atom}, a group represented by Formula A1, a group represented by Formula A2, a group represented by Formula A3, or a group represented by Formula A4 (# 1 represents a bonding site with Q), TIFF2026048769000002.tif36150R a11 , R a12 , R a33 , and R a34 are the same or different and each represents a C1-C6 linear hydrocarbon group optionally substituted with one or more halogen atoms, a cyclopropyl group, C(O)OR aa1 , C(O)NR aa2 R aa3 , a cyano group, a halogen atom, or a hydrogen atom, R a21 , R a23 , R a42 , and R a44 are the same or different and each represents a halogen atom or a hydrogen atom, R aa1 represents a C1-C6 linear hydrocarbon group optionally substituted with one or more substituents selected from the group consisting of a cyclopropyl group and a halogen atom, or a hydrogen atom, R aa2 represents a C1-C6 linear hydrocarbon group optionally substituted with one or more halogen atoms, a C3-C6 cycloalkyl group optionally substituted with one or more halogen atoms, or a hydrogen atom, R aa3 represents a C1-C6 linear hydrocarbon group optionally substituted with one or more halogen atoms, or a hydrogen atom, R a31 , R a32 , R a53 , or R a54This represents a phenyl group, a cyclopropyl group, or a halogen atom, which may be substituted with one or more substituents selected from group C, or a hydrogen atom, which may be the same or different in nature. R 3 This includes a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group B, a cyclopropyl group, a C1-C6 alkylsulfonyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkylsulfonyl group, OR 3a , C(O)R 3b , C(O)OR 3c , or represents a hydrogen atom, R 3a This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group, a phenyl group which may be substituted with one or more substituents selected from group C, and a halogen atom}, or a hydrogen atom. R 3b This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with a cyclopropyl group, a phenyl group which may be substituted with one or more substituents selected from group C, and a halogen atom which may be substituted with one or more substituents selected from group C}, a phenyl group which may be substituted with one or more substituents selected from group C, a cyclopropyl group, or a hydrogen atom, R 3c This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with a cyclopropyl group, a phenyl group which may be substituted with one or more substituents selected from group C, and one or more substituents selected from the group consisting of halogen atoms}, a phenyl group which may be substituted with one or more substituents selected from group C, or a cyclopropyl group. Q is a group represented by formula B1, a group represented by formula B2, or a group represented by formula B3 (# 2 is R 1 This represents the bonding site with the carbon atom that is bonded to it, # 3 is R 2 (represents the connection site with) TIFF2026048769000003.tif3894R b11 This includes a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, a halogen atom, and NR. ba1 C(O)R ba2 , NR ba3 C(O)OR ba4 , NR ba5 R ba6 , C(O)NR ba7 R ba8 , C(O)OR ba9 , S(O) q R ba10 , represents a cyano group or a hydrogen atom, R ba1 C(O)R is a C1-C4 chain hydrocarbon group which may be substituted with one or more halogen atoms. ba11 , or represents a hydrogen atom, R ba2 , R ba4 , R ba9 , R ba10 , and R ba11 This represents a C1-C4 chain hydrocarbon group that is the same or different in phase and may be substituted with one or more halogen atoms. R ba3 , R ba5 , R ba6 , R ba7 and R ba8 This represents a C1-C4 chain hydrocarbon group, which may be identical or different in phase and substituted with one or more halogen atoms, or a hydrogen atom. q represents 0, 1, or 2. R b21 , and R b22 This represents a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, a halogen atom, or a hydrogen atom, which may be the same or different in phase. R b31 This includes a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, and NR bb1 C(O)Rbb2 , NR bb3 C(O)OR bb4 , NR bb5 C(O)NR bb6 R bb7 , NR bb8 S(O)2R bb9 , NR bb10 R bb11 , represents a nitro group, a cyano group, a halogen atom, or a hydrogen atom, R bb1 , R bb3 , R bb5 , R bb6 , R bb8 , and R bb10 This represents a C1-C3 chain hydrocarbon group, which may be identical or different in phase and substituted with one or more halogen atoms, or a hydrogen atom. R bb2 This represents a C1-C3 chain hydrocarbon group, a cyclopropyl group, or a hydrogen atom, which may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group and halogen atoms. R bb4 This represents a C1-C3 chain hydrocarbon group or a cyclopropyl group, which may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group and halogen atoms. R bb7 and R bb11 This represents a C1-C3 chain hydrocarbon group, a cyclopropyl group, or a hydrogen atom, which may be the same or different in phase and may be substituted with one or more halogen atoms. R bb9 This represents a C1-C3 chain hydrocarbon group or a cyclopropyl group which may be substituted with one or more halogen atoms. R b32 This includes a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, and C(O)NR bb12 R bb13 , C(O)OR bb14 S(O)2R bb15 , represents a cyano group, a nitro group, a halogen atom, or a hydrogen atom, R bb12represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a hydrogen atom, R bb13 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a cyclopropyl group, or a hydrogen atom, R bb14 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a hydrogen atom, R bb15 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a cyclopropyl group, Z 1 represents an oxygen atom, a sulfur atom, NR ZZ1 N-OR ZZ2 N-CN, N-NO2, C(CN)2, NS(O)2R ZZ3 or NC(O)OR ZZ4 represents, R ZZ1 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from Group C, or a hydrogen atom, R ZZ2 represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from a phenyl group which may be substituted with one or more substituents selected from Group C, and a halogen atom}, or a hydrogen atom, R ZZ3 represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from Group C. R ZZ4 represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from a phenyl group which may be substituted with one or more substituents selected from Group C, and a halogen atom}, a phenyl group which may be substituted with one or more substituents selected from Group C, or a cyclopropyl group, X is a group represented by formula C1-1, a group represented by formula C2-1, or a group represented by formula C3-1 (# 4 is Z 1 This represents the bonding site with the carbon atom that is bonded to it. TIFF2026048769000004.tif31111Z 2 This represents an oxygen atom or a sulfur atom. Z 3 is a nitrogen atom, or CR C14 This represents, Z 4 , Z 5 , Z 6 and Z 7 The combination is, Z 4 CR C21 And Z 5 CR C22 And Z 6 CR C23 And Z 7 CR C24 A combination that is; Z 4 This is a nitrogen atom, Z 5 CR C22 And Z 6 CR C23 And Z 7 CR C24 A combination that is; Z 4 CR C21 And Z 5 This is a nitrogen atom, Z 6 CR C23 And Z 7 CR C24 A combination that is; Or, Z 4 CR C21 And Z 5 CR C22 And Z 6 CR C23 And Z 7 This represents a combination where the atom is a nitrogen atom. R c21 , R c31 , R c14 , R c24 , and R c34This represents a C1-C6 chain hydrocarbon group, a halogen atom, or a hydrogen atom, which may be the same or different in phase and may be substituted with one or more halogen atoms. R c22 , R c32 , R c13 , R c23 , and R c35 These are the same or different C1-C6 chain hydrocarbon group, cyclopropyl group {the C1-C6 chain hydrocarbon group and the cyclopropyl group may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms}, NR cc1 C(O)R cc2 , C(O)NR cc3 R cc4 , C(O)OR cc5 , OR cc6 S(O)2R cc7 , represents a nitro group, a cyano group, a halogen atom, or a hydrogen atom, R c15 , R c25 , and R c33 These are the same or different C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a phenyl group, a cyclopropyl group, a cyano group, and a halogen atom, which may be substituted with one or more substituents selected from group C}, cyclopropyl group {the cyclopropyl group may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom}, C(O)NR cc8 R cc9 , C(O)R cc10 , or S(O)2R cc11 This represents, R cc1 This is a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, OR 1C , or represents a hydrogen atom, R 1C This represents a cyclopropyl group, a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a phenyl group which may be substituted with one or more substituents selected from group C, and halogen atoms}, and a hydrogen atom. R cc2 and Rcc4 This represents a C1-C6 chain hydrocarbon group, which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group, which may be substituted with one or more halogen atoms, or a hydrogen atom, which may be the same or different in phase. R cc3 This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R cc5 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. R cc6 C3-C6 cycloalkyl groups, C1-C6 chain hydrocarbon groups (the C1-C6 chain hydrocarbon groups may be substituted with one or more substituents selected from the group consisting of halogen atoms and cyano groups), C(O)R 61C , C(O)OR 62C , C(O)NR 63C R 64C S(O)2R 65C , or represents a hydrogen atom, R 61C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R 62C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms. R 63C This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R 64C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R 65C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R cc7 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R cc8 This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R cc9 This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a phenyl group which may be substituted with one or more substituents selected from group C, and halogen atoms}, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R cc10 and R cc11 This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group C, a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group C, a cyclopropyl group, and one or more substituents selected from the group consisting of halogen atoms}, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group C, a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group C, or a hydrogen atom, Group A: C1-C6 chain hydrocarbon group {The C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of C3-C6 cycloalkyl groups, cyano groups, and halogen atoms, which may be substituted with one or more halogen atoms}, cyclopropyl group {The cyclopropyl group may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms}, OR 1A SF5, NR 2A C(O)R 3A , NR 4A C(O)OR 5A , NR 6A C(O)NR 7A R 8A N=S(O)p R 9A R 10A , C(O)R 11A , C(O)OR 12A , C(O)NR 13A R 14A , S(O)2NR 15A R 16A , NR 17A S(O)2R 18A , S(O) m R 19A A group consisting of a cyano group and a halogen atom. R 1A This includes a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from the group consisting of halogen atoms and cyano groups, a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, and C(O)R 20A , C(O)OR 21A , C(O)NR 22A R 23A S(O)2R 24A , or represents a hydrogen atom, R 2A , R 4A , R 6A , R 7A , R 13A , R 15A , R 17A , and R 22A This represents a C1-C6 chain hydrocarbon group, which may be identical or different in phase and substituted with one or more halogen atoms, or a hydrogen atom. R 3A , R 8A , R 11A , R 14A , and R 16A This represents a C1-C6 chain hydrocarbon group, which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group, which may be substituted with one or more halogen atoms, or a hydrogen atom, which may be the same or different in phase. R 5A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms. NR 2AC(O)R 3A If R 2A and R 3A R 2A The nitrogen atom to which it is bonded, and R 3A Together with the carbon atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. NR 4A C(O)OR 5A If R 4A and R 5A R 4A The nitrogen atom to which it is bonded, and R 5A Together with the oxygen atom to which it is bonded, it may form a 5 or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. NR 6A C(O)NR 7A R 8A If R 6A and R 7A R 6A The nitrogen atom to which it is bonded, and R 7A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. NR 6A C(O)NR 7A R 8A If R 7A and R 8A R 7A and R 8A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. C(O)NR 13A R 14A If R 13A and R 14A R 13Aand R 14A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. p represents 0 or 1, R 9A and R 10A This represents a C1-C6 alkyl group that is the same or different in phase and may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group that may be substituted with one or more halogen atoms. R 12A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. R 18A and R 19A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group C, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, m represents 0, 1, or 2. R 20A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a cyclopropyl group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. R 21A , R 23A , and R 24A This represents a C1-C6 chain hydrocarbon group, a cyclopropyl group, or a phenyl group, which may be substituted with one or more substituents selected from group C, and which are the same or different in phase. Group B: Cyclopropyl group, phenyl group which may be substituted with one or more substituents selected from Group C, OR 3B A group consisting of a cyano group and a halogen atom. R 3B This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms. Group C: C1-C6 chain hydrocarbon groups {the C1-C6 chain hydrocarbon groups may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms}, C3-C6 cycloalkyl groups {the C3-C6 cycloalkyl groups may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms}, and a group consisting of C1-C6 alkoxy groups, cyano groups, and halogen atoms, which may be substituted with one or more halogen atoms. A compound represented by formula (I), its N oxide, or a salt thereof (hereinafter, the compound represented by formula (I), its N oxide, or a salt thereof will be referred to as "this compound"). [2] A method for controlling harmful arthropods as described in [1], wherein the plant growing carrier is soil. [3] A composition containing a compound represented by formula (I) described in [1], its N oxide, or a salt thereof, and one or more components selected from the groups (a), (b), (c), (d), (e), (f), (g), (h), (i), and (j): Group (a): A group consisting of arthropod-killing and nematode-killing active ingredients; Group (b): Fungicidally active ingredients; Group (c): Plant growth regulating components; Group (d): Ingredients that reduce drug-induced harm; Group (e): Synergistic agent; Group (f): Repellent component; Group (g): Molluscicide components; Group (h): Insect pheromones; Group (i): herbicidal active ingredients; Group (j): Biological control materials. [4] A method for controlling harmful arthropods, comprising the step of applying an effective amount of the composition described in [3] to harmful arthropods, habitats of harmful arthropods, plants, or plant cultivation carriers. [5] A method for controlling harmful arthropods as described in [4], wherein the plant growing carrier is soil. [6] Seeds or vegetative reproductive organs containing an effective amount of the compound represented by formula (I) described in [1], its N oxide, or a salt thereof, or the composition described in [3]. [Effects of the Invention]
[0006] This invention makes it possible to control harmful arthropods. [Modes for carrying out the invention]
[0007] The substituents in this invention will now be described. Halogen atoms refer to fluorine atoms, chlorine atoms, bromine atoms, or iodine atoms. If a substituent has two or more halogen atoms or substituents, those halogen atoms or substituents may be the same or different. In this specification, the notation "CX-CY" means that the number of carbon atoms is X through Y. For example, the notation "C1-C6" means that the number of carbon atoms is 1 through 6. A chain-like hydrocarbon group refers to an alkyl group, an alkenyl group, or an alkynyl group. Examples of alkyl groups include methyl, ethyl, propyl, isopropyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-ethylpropyl, butyl, sec-butyl, tert-butyl, pentyl, and hexyl groups. Examples of alkenyl groups include vinyl, 1-propenyl, 2-propenyl, 1-methyl-1-propenyl, 1-methyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1-ethyl-2-propenyl, 3-butenyl, 4-pentenyl, and 5-hexenyl groups. Examples of alkynyl groups include ethynyl group, 1-propynyl group, 2-propynyl group, 1-methyl-2-propynyl group, 1,1-dimethyl-2-propynyl group, 1-ethyl-2-propynyl group, 2-butynyl group, 4-pentynyl group, and 5-hexynyl group. Examples of alkoxy groups include methoxy, ethoxy, propoxy, isopropoxy, butoxy, tert-butoxy, pentyloxy, and hexyloxy groups. Examples of cycloalkyl groups include cyclopropyl, cyclobutyl, cyclopentyl, and cyclohexyl groups. Examples of alkylsulfonyl groups include methylsulfonyl groups, ethylsulfonyl groups, propylsulfonyl groups, and isopropylsulfonyl groups. Examples of cycloalkylsulfonyl groups include cyclopropylsulfonyl, cyclobutylsulfonyl, cyclopentylsulfonyl, and cyclohexylsulfonyl groups. Examples of nine-membered aromatic heterocyclic groups include benzoxazolyl, benzoisoxazolyl, benzothiazolyl, benzoisothiazolyl, triazolopyridyl, triazolopyrimidinyl, and imidazolopyrimidinyl groups. Examples of 5- or 6-membered aromatic heterocyclic groups include 5-membered aromatic heterocyclic groups selected from pyrazolyl, imidazolyl, thiazolyl, isothiazolyl, oxazolyl, isoxazolyl, 1,2,4-oxadiazolyl, 1,3,4-oxadiazolyl, 1,2,4-thiadiazolyl, 1,3,4-thiadiazolyl, 1,2,3-triazolyl, 1,2,4-triazolyl, and tetrazolyl groups; and 6-membered aromatic heterocyclic groups selected from pyridyl, pyrimidinyl, pyridadinyl, and pyrazinyl groups. A (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms represents a group in which (C3-C6 cycloalkyl) and / or (C1-C3 alkyl) may have one or more halogen atoms, and examples include the cyclopropylmethyl group, the cyclopropylethyl group, the (2,2-difluorocyclopropyl)methyl group, the 2-cyclopropyl-1,1,2,2-tetrafluoroethyl group, and the 2-(2,2-difluorocyclopropyl)-1,1,2,2-tetrafluoroethyl group. Examples of C1-C6 chain hydrocarbon groups that may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group and a halogen atom include a methyl group, an ethyl group, a propyl group, a 1,1-difluoroethyl group, a 1-cyclopropylethyl group, and a propagyl group.
[0008] NR 2A C(O)R 3A If R 2A and R 3A R 2A The nitrogen atom to which it is bonded, and R 3A Together with the carbon atom to which it is bonded, it may form a 5 or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}, for example, the following ring structure: TIFF2026048769000005.tif4021(# 1 (This represents the connection site with Q.) It can form. NR 4A C(O)OR 5A If R 4A and R 5A R 4A The nitrogen atom to which it is bonded, and R 5A Together with the oxygen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}, for example, the following ring structure: TIFF2026048769000006.tif4020(# 1 (This represents the connection site with Q.) It can form. NR 6A C(O)NR 7A R 8A If R 6A and R 7A R 6A The nitrogen atom to which it is bonded, and R 7ATogether with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}, for example, the following ring structure: TIFF2026048769000007.tif4224(# 1 (This represents the connection site with Q.) It can form. NR 6A C(O)NR 7A R 8A If R 7A and R 8A R 7A and R 8A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}, for example, the following ring structure: TIFF2026048769000008.tif5120(# 1 (This represents the connection site with Q.) It can form. C(O)NR 13A R 14A If R 13A and R 14A R 13A and R 14A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}, for example, the following ring structure: TIFF2026048769000009.tif4026(# 1 (This represents the connection site with Q.) It can form.
[0009] This compound may have one or more stereoisomers. Examples of stereoisomers include enantiomers, diastereomers, and geometric isomers. This compound may contain each stereoisomer and mixtures of stereoisomers in any proportion.
[0010] The compound represented by formula (I) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids such as hydrogen halides (e.g., hydrogen chloride, hydrogen bromide, hydrogen iodide), phosphoric acid, and sulfuric acid; and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, p-toluenesulfonic acid, trifluoromethanesulfonic acid, and methanesulfonic acid. The acid addition salt can be obtained, for example, by mixing the compound represented by formula (I) with an acid.
[0011] Next, the method for producing this compound will be described.
[0012] Manufacturing method 1 The compound represented by formula (I-3) (hereinafter referred to as compound (I-3)) can be produced by reacting the compound represented by formula (I-1) (hereinafter referred to as compound (I-1)) and the compound represented by formula (I-2) (hereinafter referred to as compound (I-2)) in the presence of a carbonylating agent. TIFF2026048769000010.tif38128 [in the formula, R x31 This may be a C1-C6 chain hydrocarbon group, a cyclopropyl group, a hydrogen atom, or OR which may be substituted with one or more substituents selected from group B. 3a This represents [the symbol], and the other symbols have the same meaning as above. The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include ethers such as tetrahydrofuran (hereinafter referred to as THF), 1,4-dioxane, 1,2-dimethoxyethane, methyl tert-butyl ether, and diethyl ether (hereinafter referred to as ethers); halogenated hydrocarbons such as dichloromethane and chloroform (hereinafter referred to as halogenated hydrocarbons); nitriles such as acetonitrile (hereinafter referred to as nitriles); aromatic hydrocarbons such as toluene and xylene (hereinafter referred to as aromatic hydrocarbons); aprotic polar solvents such as N-methylpyrrolidone (hereinafter referred to as NMP), N,N-dimethylformamide (hereinafter referred to as DMF), and dimethyl sulfoxide (hereinafter referred to as aprotic polar solvents); water; and mixtures of two or more of these. Examples of carbonylating agents used in the reaction include di(N-succinimidyl) carbonate, triphosgene, phosgene, thiophosgene, phenyl chloroformate, isobutyl chloroformate, ethyl chloroformate, methyl chloroformate, 1,1'-carbonyldiimidazole, ditert-butyl dicarbonate, diphenyl carbonate, S,S'-dimethyl dithiocarbonate, 4-nitrophenyl chloroformate, 4-nitrobenzyl chloroformate, 2,4,6-trichlorobenzoyl chloride, bis(pentafluorophenyl) carbonate, and bis(4-nitrophenyl) carbonate. The reaction may use a base as needed. Examples of bases that can be used in the reaction include organic bases such as triethylamine, N,N-diisopropylethylamine, pyridine, and 4-(dimethylamino)pyridine (hereinafter referred to as organic bases); and alkali metal carbonates such as sodium carbonate, potassium carbonate, and cesium carbonate (hereinafter referred to as alkali metal carbonates). In the reaction, compound (I-2) is typically used in a ratio of 1 to 10 moles per mole of compound (I-1), and a carbonylating agent is also typically used in a ratio of 1 to 10 moles per mole of compound (I-1). If a base is used in the reaction, the base is typically used in a ratio of 0.1 to 5 moles per mole of compound (I-1). The reaction temperature is typically in the range of 0°C to 200°C. The reaction time is typically in the range of 0.1 to 48 hours. After the reaction is complete, compound (I-3) can be obtained by adding water to the reaction mixture, extracting it with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer. Compound (I-2) may form an acid addition salt. Examples of acids that form an acid addition salt include inorganic acids such as hydrochloric acid and sulfuric acid (hereinafter referred to as inorganic acids); and organic acids such as acetic acid, trifluoroacetic acid, benzoic acid, trifluoromethanesulfonic acid, and p-toluenesulfonic acid (hereinafter referred to as organic acids). Compound (I-1) can be prepared using known methods.
[0013] Manufacturing method 2 The compound represented by formula (I-5) (hereinafter referred to as compound (I-5)) can be produced by reacting the compound represented by formula (I-4) (hereinafter referred to as compound (I-4)) and compound (I-2) in the presence of an azide. TIFF2026048769000011.tif38133 [In this formula, the symbols have the same meaning as above.] The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include ethers; halogenated hydrocarbons; nitriles; aromatic hydrocarbons; and mixtures of two or more of these. Examples of azides used in the reaction include sodium azide and diphenylphosphonic acid azide. The reaction may use a base as needed. Examples of bases that can be used in the reaction include organic bases. In the reaction, compound (I-2) is typically used in a ratio of 1 to 10 moles and azide in a ratio of 1 mole of compound (I-4). When a base is used in the reaction, the base is typically used in a ratio of 0.1 to 5 moles in a ratio of 1 mole of compound (I-4). The reaction temperature is typically in the range of 0°C to 200°C. The reaction time is typically in the range of 0.1 to 48 hours. After the reaction is complete, compound (I-5) can be obtained by adding water to the reaction mixture, extracting it with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer. Compound (I-4) can be prepared using known methods.
[0014] Manufacturing method 3 The compound represented by formula (I-7) (hereinafter referred to as compound (I-7)) can be produced by reacting compound (I-5) with the compound represented by formula (I-6) (hereinafter referred to as compound (I-6)). TIFF2026048769000012.tif37131 [In the formula, R x32This includes a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group B, a cyclopropyl group, a C1-C6 alkylsulfonyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkylsulfonyl group, and C(O)R 3b , or C(O)OR 3c Represents M x1 The symbols represent leaving groups such as chlorine, bromine, and iodine atoms, while the other symbols have the same meaning as above. The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include ethers; halogenated hydrocarbons; nitriles; aromatic hydrocarbons; aprotic polar solvents; and mixtures of two or more of these. The reaction may use a base as needed. Examples of bases that can be used in the reaction include organic bases and alkali metal carbonates. In the reaction, compound (I-6) is typically used in a ratio of 1 to 10 moles per mole of compound (I-5). When a base is used in the reaction, it is typically used in a ratio of 0.1 to 5 moles per mole of compound (I-5). The reaction temperature is typically in the range of -78°C to 100°C. The reaction time is typically in the range of 0.1 to 48 hours. After the reaction is complete, compound (I-7) can be obtained by adding water to the reaction mixture, extracting it with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer. Compound (I-6) is either a commercially available compound or can be produced using known methods.
[0015] Manufacturing method 4 The compound represented by formula (I-10) (hereinafter referred to as compound (I-10)) can be produced by reacting the compound represented by formula (I-8) (hereinafter referred to as compound (I-8)) and the compound represented by formula (I-9) (hereinafter referred to as compound (I-9)) in the presence of a metal catalyst. TIFF2026048769000013.tif38150 [In the formula, M X2 represents a chlorine atom, a bromine atom, or an iodine atom, M AThe symbol represents a 9-borabicyclo[3.3.1]nonane-9-yl group, a borono group, a 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl group, or a tributylstannyl group, and the other symbols have the same meaning as above. The reaction is usually carried out in a solvent. Examples of solvents used in the reaction include ethers; aromatic hydrocarbons; aprotic polar solvents; water; and mixtures of two or more of these. Examples of metal catalysts used in the reaction include palladium catalysts such as tetrakis(triphenylphosphine)palladium(O), 1,1'-bis(diphenylphosphine)ferrocenepalladium(II) dichloride, tris(dibenzylideneacetone)dipalladium(O), and palladium(II) acetate; nickel catalysts such as bis(cyclooctadiene)nickel(O) and nickel(II) chloride; iron catalysts such as iron(III) chloride and iron(III) acetylacetone; copper catalysts such as copper(I) iodide and copper(I) chloride; and combinations of two or more of these. Ligands, bases, and / or inorganic halides may be used in the reaction as needed. Ligands used in the reaction include triphenylphosphine, xanthophos, 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 1,1'-bis(diphenylphosphino)ferrocene, 2-dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl, 2-dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 1,2-bis(diphenylphosphino)ethane, 2,2'-bipyridine, 2-aminoethanol, 8-hydroxyquinoline, and 1,10-phenanthroline. Examples of bases used in the reaction include organic bases and alkali metal carbonates. Examples of inorganic halides used in the reaction include alkali metal fluorides such as potassium fluoride and sodium fluoride, and alkali metal chlorides such as lithium chloride and sodium chloride. In the reaction, compound (I-9) is typically used in a ratio of 1 to 10 moles per mole of compound (I-8), and a metal catalyst is typically used in a ratio of 0.01 to 0.5 moles. When a ligand is used in the reaction, the ligand is typically used in a ratio of 0.01 to 1 mole per mole of compound (I-8). When a base is used in the reaction, the base is typically used in a ratio of 0.1 to 5 moles per mole of compound (I-8). When an inorganic halide is used in the reaction, the inorganic halide is typically used in a ratio of 0.1 to 5 moles per mole of compound (I-8). The reaction temperature is typically in the range of -20°C to 200°C. The reaction time is typically in the range of 0.1 to 72 hours. After the reaction is complete, compound (I-10) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer. Compound (I-9) is either a commercially available compound or can be produced using known methods. The reaction can also be carried out, for example, in accordance with the method described in Example H2 of International Publication No. 2020 / 070049.
[0016] Reference manufacturing method 1 The compound represented by formula (M-2) (hereinafter referred to as compound (M-2)) can be produced by reacting the compound represented by formula (M-1) (hereinafter referred to as compound (M-1)) and compound (I-2) in the presence of a carbonylating agent. TIFF2026048769000014.tif43145 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with Manufacturing Method 1, using compound (M) instead of compound (I-1). Compound (M-1) can be produced using known methods.
[0017] Reference manufacturing method 2 The compound represented by formula (M-4) (hereinafter referred to as compound (M-4)) can be produced by reacting the compound represented by formula (M-3) (hereinafter referred to as compound (M-3)) with compound (I-2). TIFF2026048769000015.tif39150 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with Manufacturing Method 2, using compound (M-3) instead of compound (I-4). Compound (M-3) can be produced using known methods.
[0018] Reference manufacturing method 3 The compound represented by formula (M-7) (hereinafter referred to as compound (M-7)) can be produced by reacting the compound represented by formula (M-5) (hereinafter referred to as compound (M-5)) with the compound represented by formula (M-6) (hereinafter referred to as compound (M-6)). TIFF2026048769000016.tif38130 [In the formula, M x3 The symbols represent a chlorine atom, a bromine atom, an iodine atom, a methanesulfonyloxy group, a trifluoromethanesulfonyloxy group, or a 4-methoxybenzenesulfonyloxy group, and the other symbols have the same meaning as above. The reaction may use a solvent as needed. Examples of solvents include ethers; halogenated hydrocarbons; nitriles; aromatic hydrocarbons; aprotic polar solvents; and mixtures of two or more of these. In the reaction, compound (M-6) is typically used in a ratio of 1 to 30 moles per mole of compound (M-5). The reaction temperature is typically in the range of 0°C to 200°C. The reaction time is typically in the range of 0.1 to 48 hours. After the reaction is complete, compound (M-7) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer. Compound (M-7) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids and organic acids. Compounds (M-5) and (M-6) are commercially available compounds or can be produced using known methods.
[0019] Reference manufacturing method 4 The compound represented by formula (M-9) (hereinafter referred to as compound (M-9)) can be produced by reacting the compound represented by formula (M-8) (hereinafter referred to as compound (M-8)) with compound (M-6). TIFF2026048769000017.tif35130 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out using compound (M-8) instead of compound (M-5), in accordance with Reference Manufacturing Method 3. Compound (M-9) may form an acid addition salt. Examples of acids that form acid addition salts include inorganic acids and organic acids. Compound (M-8) is either a commercially available compound or can be manufactured using known methods.
[0020] Reference manufacturing method 5 The compound represented by formula (M-11) (hereinafter referred to as compound (M-11)) can be produced by reacting the compound represented by formula (M-10) (hereinafter referred to as compound (M-10)) with compound (M-6). TIFF2026048769000018.tif37130 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with Reference Manufacturing Method 3, using compound (M-10) instead of compound (M-5). Compound (M-11) may form acid addition salts. Examples of acids that can form acid addition salts include inorganic acids and organic acids. Compound (M-10) is either a commercially available compound or can be manufactured using known methods.
[0021] Reference manufacturing method 6 The compound represented by formula (M-13) (hereinafter referred to as compound (M-13)) can be produced by reacting the compound represented by formula (M-12) (hereinafter referred to as compound (M-12)) with compound (M-6). TIFF2026048769000019.tif38130 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with Reference Manufacturing Method 3, using compound (M-12) instead of compound (M-5). Compound (M-13) may form acid addition salts. Examples of acids that can form acid addition salts include inorganic acids and organic acids. Compound (M-12) is either a commercially available compound or can be manufactured using known methods.
[0022] Reference manufacturing method 7 The compound represented by formula (M-16) (hereinafter referred to as compound (M-16)) can be produced by reacting the compound represented by formula (M-14) (hereinafter referred to as compound (M-14)) with the compound represented by formula (M-15) (hereinafter referred to as compound (M-15)). TIFF2026048769000020.tif38123 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with Reference Manufacturing Method 3, using compound (M-14) instead of compound (M-5) and compound (M-15) instead of compound (M-6). Compound (M-16) may form acid addition salts. Examples of acids that can form acid addition salts include inorganic acids and organic acids. Compounds (M-14) and (M-15) are commercially available compounds or can be manufactured using known methods.
[0023] Reference manufacturing method 8 The compound represented by formula (M-19) (hereinafter referred to as compound (M-19)) can be produced by reacting the compound represented by formula (M-17) (hereinafter referred to as compound (M-17)) with the compound represented by formula (M-18) (hereinafter referred to as compound (M-18)). TIFF2026048769000021.tif31116 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with Reference Manufacturing Method 3, using compound (M-17) instead of compound (M-5) and compound (M-18) instead of compound (M-6). Compound (M-19) may form acid addition salts. Examples of acids that can form acid addition salts include inorganic acids and organic acids. Compounds (M-17) and (M-18) are commercially available compounds or can be manufactured using known methods.
[0024] Reference manufacturing method 9 The compound represented by formula (M-21) (hereinafter referred to as compound (M-21)) can be produced by reacting the compound represented by formula (M-20) (hereinafter referred to as compound (M-20)) with compound (M-18). TIFF2026048769000022.tif34119 [In this formula, the symbols have the same meaning as above.] The reaction can be carried out in accordance with Reference Manufacturing Method 3, using compound (M-20) instead of compound (M-5) and compound (M-18) instead of compound (M-6). Compound (M-21) may form acid addition salts. Examples of acids that can form acid addition salts include inorganic acids and organic acids. Compound (M-20) is either a commercially available compound or can be manufactured using known methods.
[0025] Reference manufacturing method 10 The compound represented by formula (M-23) (hereinafter referred to as compound (M-23)) can be produced by reacting the compound represented by formula (M-22) (hereinafter referred to as compound (M-22)) with a reducing agent. TIFF2026048769000023.tif36102 [In this formula, the symbols have the same meaning as above.] The reaction is usually carried out in a solvent. Examples of solvents include alcohols such as butanol, ethanol, methanol, 2-propanol, and 2,2,2-trifluoroethanol (hereinafter referred to as alcohols); halogenated hydrocarbons; ethers; water; and mixtures of two or more of these. Reducing agents used in the reaction include sodium cyanoborohydride, sodium triacetoxyborohydride, sodium borohydride, and 2-picolineborane. The reaction may use an acid as needed. Examples of acids include organic acids and inorganic acids. In the reaction, the reducing agent used is typically used in a ratio of 1 to 10 moles per mole of compound (M-22). When an acid is used in the reaction, the acid is typically used in a ratio of 0.1 to 10 moles per mole of compound (M-22). The reaction temperature is typically in the range of 0°C to 100°C. The reaction time is typically in the range of 0.1 to 48 hours. After the reaction is complete, the reaction mixture can be mixed with water, extracted with an organic solvent, and the organic layer can be dried and concentrated to obtain compound (M-23).
[0026] Reference manufacturing method 11 Compound (M-22) can be produced by reacting the compound represented by formula (M-24) (hereinafter referred to as compound (M-24)) with the compound represented by formula (M-25) (hereinafter referred to as compound (M-25)). TIFF2026048769000024.tif34125 [In this formula, the symbols have the same meaning as above.] The reaction is usually carried out in a solvent. Examples of solvents include ethers; halogenated hydrocarbons; nitriles; aromatic hydrocarbons; aprotic polar solvents; alcohols; esters such as ethyl acetate, butyl acetate, isobutyl acetate, and isopropyl acetate (hereinafter referred to as esters); water; and mixtures of two or more of these. The reaction may use an acid as needed. Examples of acids that can be used in the reaction include organic acids and inorganic acids. In the reaction, compound (M-25) is typically used in a ratio of 1 to 10 moles per mole of compound (M-24). If an acid is used in the reaction, the acid is typically used in a ratio of 0.1 to 10 moles per mole of compound (M-24). The reaction temperature is typically in the range of 0°C to 100°C. The reaction time is typically in the range of 0.1 to 48 hours. After the reaction is complete, the compound (M-22) can be obtained by adding water to the reaction mixture, extracting with an organic solvent, and performing post-treatment operations such as drying and concentrating the organic layer. Compounds (M-24) and (M-25) are commercially available compounds or can be manufactured using known methods.
[0027] Reference manufacturing method 12 Compound (M-23) can be produced by reacting compound (M-24) and compound (M-25) in the presence of a reducing agent. TIFF2026048769000025.tif36127 [In this formula, the symbols have the same meaning as above.] The reaction is usually carried out in a solvent. Examples of solvents include alcohols; halogenated hydrocarbons; ethers; water; and mixtures of two or more of these. Reducing agents used in the reaction include sodium cyanoborohydride, sodium triacetoxyborohydride, sodium borohydride, and 2-picolineborane. The reaction may use an acid as needed. Examples of acids that can be used in the reaction include organic acids and inorganic acids. In the reaction, compound (M-25) is typically used in a ratio of 1 to 10 moles per mole of compound (M-24), and a reducing agent is also typically used in a ratio of 1 to 10 moles per mole of compound (M-24). If an acid is used in the reaction, the acid is typically used in a ratio of 0.1 to 10 moles per mole of compound (M-24). The reaction temperature is typically in the range of 0°C to 100°C. The reaction time is typically in the range of 0.1 to 48 hours. After the reaction is complete, the reaction mixture can be mixed with water, extracted with an organic solvent, and the organic layer can be dried and concentrated to obtain compound (M-23).
[0028] This compound can be mixed with or used in combination with one or more components selected from the groups (a), (b), (c), (d), (e), (f), (g), (h), (i), and (j) listed below (hereinafter referred to as "this component"). The aforementioned mixing or combined use means using the compound and the component simultaneously, separately, or at intervals of time. When this compound and this component are used simultaneously, they may be contained in separate formulations or in a single formulation. One aspect of the present invention is one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i), and group (j) (i.e., the component), and a composition containing the compound (hereinafter referred to as Composition A).
[0029] Group (a) includes acetylcholinesterase inhibitors (e.g., carbamate insecticides, organophosphate insecticides), GABAergic chloride ion channel blockers (e.g., phenylpyrazole insecticides), sodium channel modulators (e.g., pyrethroid insecticides), nicotinic acetylcholine receptor competitive modulators (e.g., neonicotinoid insecticides), nicotinic acetylcholine receptor allosteric modulators, glutamate-gated chloride ion channel allosteric modulators (e.g., macrolide insecticides), juvenile hormone receptor modulators, multisite inhibitors, string organ TRPV channel modulators, mite growth inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncoupling agents, nicotinic acetylcholine receptor channel blockers (e.g., nereistoxin insecticides), chitin biosynthesis inhibitors, molting inhibitors, ecdysone receptor agonists, octopamine receptor agonists, mitochondrial electron transport chain complexes I and II, This group consists of inhibitors of III and IV, voltage-gated sodium channel blockers, acetyl-CoA carboxylase inhibitors, ryanodine receptor modulators (e.g., diamide insecticides), chondrocyte nicotinamidase inhibitors, GABAergic chloride ion channel allosteric modulators, calcium-activated potassium channel modulators, RNA interference-mediated target repressors, vesicular acetylcholine transporter inhibitors, and other arthropod and nematode-killing active ingredients. These are described in the IRAC classification based on mechanism of action.
[0030] Group (b) consists of nucleic acid synthesis inhibitors (e.g., phenylamide fungicides, acyl amino acid fungicides), cell division and cytoskeleton inhibitors (e.g., MBC fungicides), respiratory inhibitors (e.g., QoI fungicides, QiI fungicides), amino acid and protein synthesis inhibitors (e.g., anilinopyrimidine fungicides), signaling inhibitors, lipid and membrane synthesis inhibitors, sterol biosynthesis inhibitors (e.g., triazole-based DMI fungicides), cell wall biosynthesis inhibitors, melanin synthesis inhibitors, plant defense inducers, multi-point contact active fungicides, microbial fungicides, and other fungicidal active ingredients. These are described in the FRAC classification based on mechanism of action.
[0031] Group (c) is a group of plant growth regulating components.
[0032] Group (d) is the group of ingredients that reduce drug-induced harm.
[0033] Group (e) is the group of synergists.
[0034] Group (f) is a group of repellent components consisting of bird repellent components, insect repellent components, and animal repellent components.
[0035] Group (g) is the group of mollusk components.
[0036] Group (h) is a group of signaling molecules consisting of pheromones and allelochemicals used by insects.
[0037] Group (i) consists of acetyl-CoA carboxylase (ACCase) inhibitors, acetolactate synthase (ALS) inhibitors, photosynthesis (photosystem II) inhibitors, photosystem I electron converters, protoporphyrinogen oxidase (PPO) inhibitors, phytoene desaturation system (PDS) inhibitors, 4-hydroxyphenylpyruvate dioxygenase (4-HPPD) inhibitors, carotenoid biosynthesis inhibitors, EPSP synthase inhibitors, glutamine synthase inhibitors, dihydropteroic acid (DHP) synthase inhibitors, microtubule polymerization inhibitors, mitosis / microtubule formation inhibitors, very long-chain fatty acid (VLCFA) inhibitors, cellulose synthesis inhibitors, uncoupling agents, lipid synthesis inhibitors, indoleacetic acid-like activators, auxin transfer inhibitors, and other herbicidal active ingredients. These are described in the classification based on the mechanism of action of HRAC.
[0038] Group (j) is a group of biological control materials consisting of bacteria, fungi, yeasts, protists, viruses, natural products, insects, mites, and mollusks that have control effects against harmful organisms (e.g., insecticidal activity, acaricidal activity, nematicidal activity, fungicidal activity, etc.), herbicidal activity, or plant growth regulating effects such as rhizobia and mycorrhizal fungi. Specifically, Group (j) is divided into subgroups: subgroup (j-1): bacteria, subgroup (j-2): fungi and yeasts, subgroup (j-3): protists, subgroup (j-4): viruses, subgroup (j-5): nematodes, subgroup (j-6): natural products, subgroup (j-7): insects, subgroup (j-8): mites, and subgroup (j-9): mollusks.
[0039] Examples of combinations of this component and this compound are listed below. For example, alanycarb + SX means the combination of alanycarb and SX. The abbreviation SX refers to any one of the compounds selected from the compound group SX1 to SX216. Furthermore, all of the components described below are known components and can be obtained from commercially available formulations or manufactured by known methods. If the component is a microorganism, it can also be obtained from a microbial depositary. The numbers in parentheses represent CAS RN(registered trademark).
[0040] Combinations of the component in group (a) above and the compound in question: Abamectin + SX, Acephate + SX, Acequinocyl + SX, Acetamiprid + SX, Acetic acid + SX, Acetoprole + SX, Acrinathrin + SX, Acynonapyr + SX, Afidopyropen + SX, Afoxolaner + SX, Alanicarb + SX, Aldicarb + SX, Allethrin + SX, Alpha-cypermethrin + SX, Alpha-endosulfan + SX, Aluminum phosphide + SX, Amitraz + SX, Azamethiphos + SX, Azinphos-ethyl + SX, Azinphos-methyl + SX, Azocyclotin + SX, Bendiocarb + SX, Benfluthrin + SX, Benfuracarb + SX, Bensultap + SX, Bentioflumin + SX, Benzoic acid + SX, Benzoximate + SX, Benzpyrimoxan + SX, Beta-cyfluthrin + SX, Beta-cypermethrin + SX, Bifenazate + SX, Bifenthrin + SX, Bilobalide + SX, Bioallethrin + SX, Bioresmethrin + SXBistrifluron + SX, Bisulflufen + SX, Borax + SX, Boric acid + SX, Broflanilide + SX, Bromopropylate + SX, Buprofezin + SX, Butyric acid + SX, Butocarboxim + SX, Butoxycarboxim + SX, Cadusafos + SX, Calcium phosphide + SX, Carbaryl + SX, Carbofuran + SX, Carbosulfan + SX, Cartap hydrochloride + SX, Cartap + SX, chinomethionate + SX, chlorantraniliprole + SX, chlordane + SX, chlorethoxyfos + SX, chlorfenapyr + SX, chlorfenvinphos + SX, chlorfluazuron + SX, chlormephos + SX, chloropicrin + SX, chlorpyrifos + SX, chlorpyrifos-methyl + SX, chromafenozide + SX, citric acid + SX, clofentezine + SX, Clothianidin + SX, Coumaphos + SX, Cryolite + SX, Cyanoflanilide + SX,Cyanophos + SX, Cyantraniliprole + SX, Cybenzoxasulfyl + SX, Cyclaniliprole + SX, Cyclobutrifluram + SX, Cycloprothrin + SX, Cycloxaprid + SX, Cyenopyrafen + SX, Cyetpyrafen + SX, Cyflumetofen + SX, Cyfluthrin + SX, Cyhalodiamide + SX, Cyhalothrin + SX, Cyhexatin + SX, Cypermethrin + SX, Cyphenothrin + SX, Cyproflanilide + SX, Cyromazine + SX, Dazomet + SX, Deltamethrin + SX, Demeton-S-methyl + SX, Diafenthiuron + SX, Diatomaceous earth + SX, Diazinon + SX, Dichlorvos + SX, Dichloromezotiaz + SX, Dicofol + SX, Diclotophos + SX, Diflovidazin + SX, Diflubenzuron + SX, Dimefluthrin + SX, Dimethoate + SX, Dimethylvinphos + SX, Dimpropyridaz + SX, Dinotefuran + SX,Disodium octaborate + SX, Disulfoton + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, Doramectin + SX, Emamectin-benzoate + SX, Empenthrin + SX, Endosulfan + SX, EPN (O-ethyl O-(4-nitrophenyl) phenylphosphonothioate) + SX, Epsilon-metofluthrin + SX, Epsilon-momfluorothrin + SX, Esfenvalerate + SX, Ethiofencarb + SX, Ethion + SX, Ethiprole + SX, etoprophos + SX, etofenprox + SX, etoxazole + SX, famphur + SX, fenamiphos + SX, fenargimine + SX, fenazaquin + SX, fenbutatin oxide + SX, fenitrothion + SX, fenmezoditiaz + SX, fenobucarb + SX, fenoxycarb + SX, fenpropathrin + SX, fenpyroximate + SX, fenthion + SX, Fentiazoluron + SX, fenvalerate + SX, fipronil + SX, flometoquin + SX,Flonicamide + SX, Fluacrypyrim + SX, Fluazaindolizine + SX, Fluazuron + SX, Flubendiamide + SX, Fluchlordiniliprole + SX, Flucycloxuron + SX, Flucythrinate + SX, Fluensulfone + SX, Flufenoprox + SX, Flufenoxuron + SX, Flufiprole + SX, Flumethrin + SX, Flupentiofenox + SX, Flupymezotiaz + SX, Flupyradifurone + SX, Flupyrimin + SX, Flupyroxystrobin + SX, Fluralaner + SX, Fluvalinate + SX, Fluxametamide + SX, Formetanate + SX, Fosthiazate + SX, Fumaric acid + SX, Furamethrin + SX, Furathiocarb + SX, Gamma-cyhalothrin + SX, Halfenprox + SX, Halofenozide + SX, heptafluthrin + SX, heptenophos + SX, hexaflumuron + SX, hexythiazox + SX,Potassium salt of hop beta acid + SX, hydramethylnon + SX, imicyafos + SX, imidacloprid + SX, imidaclothiz + SX, imiprothrin + SX, indazapyroxamet + SX, indoxacarb + SX, isocycloseram + SX, isofenphos + SX, isoflualanam + SX, isoprocarb + SX, isopropyl-O-(methoxyaminothiophosphoryl) salicylate + SX, Isoxathion + SX, Kadesrin + SX, Kappa-tefluthrin + SX, Kappa-bifenthrin + SX, Lactic acid + SX, Lambda-cyhalothrin + SX, Lavendyl acetate + SX, Ledprona + SX, Lenoremycin + SX, Lepimectin + SX, Lime sulfur + SX, Lotilaner + SX, Lufenuron + SX, Machine oil + SX, Malathion + SX, Malic acid +SX, mecarbam + SX, meperfluthrin + SX, metaflumizone + SX, metam + SX,Methamidophos + SX, Methidathion + SX, Methiocarb + SX, Methomyl + SX, Methoxychlor + SX, Methoxyfenozide + SX, Methyl bromide + SX, Metofluthrin + SX, Metolcarb + SX, Methoxadiazone + SX, Mevinphos + SX, Milbemectin + SX, Milbemycin oxime + SX, Mivorilaner + SX, Modoflaner + SX, Momfluorothrin + SX, monocrotophos + SX, moxidectin + SX, napoxametamide + SX, naled + SX, nicofluprole + SX, nicotine + SX, nicotine-sulfate + SX, nitenpyram + SX, novaluron + SX, nobiflumulon + SX, omethoate + SX, organic acid + SX, oxalic acid + SX, oxamyl + SX, oxazosulfyl + SX, oxydemeton-methyl + SX, Parathion + SX, Parathion-methyl + SX, Permethrin + SX, Phenothrin + SX, Phenthoate + SX, Phorate + SX, Phosalone + SX, Phosmet + SX, Phosphamidon + SX, Phosphine + SX, Phoxim + SX, Pioxaniliprole + SX, Piperflanilide + SX, Pirimicarb + SX, Pirimiphos-methyl + SX, Prallethrin + SX, Profenofos + SX, profluthrin + SX, propionic acid + SX, propargite + SX, propetamphos + SX, propoxur + SX, propylene glycol alginate + SX, prothiofos + SX, pyflubumide + SX, pymetrozine + SX, pyraclofos + SX, pyrethrins + SX, pyridaben + SX, pyridalyl + SX, pyridaphenthion + SX, pyrifluquinazone + SX, pyrimidifen + SX, Pyriminostrobin + SX, Pyriprole + SX, Pyriproxyfen + SX, Quinalphos + SX,Resmethrin + SX, sarolaner + SX, selamectin + SX, sigma-cypermethrin + SX, silafluofen + SX, sodium borate + SX, sodium metaborate + SX, spidoxamat + SX, spinetoram + SX, spirobudifen + SX, spirodiclofen + SX, spiromesifen + SX, spiropidion + SX, spirotetramat + SX, sulfiflumin + SX, Sulfindoflufen + SX, sulfuramide + SX, sulfotep + SX, sulfoxaflor + SX, sulfoxamyl + SX, sulfur + SX, sulfuryl fluoride + SX, tartar emetic + SX, tartaric acid + SX, tau-fluvalinate + SX, tebufenozide + SX, tebufenpyrad + SX, tebupirimfos + SX, teflubenzuron + SX, tefluthrin + SX, temephos + SX, terbufos + SX, tetrachlorantraniliprole + SX, tetrachlorvinphos + SX, tetradifon + SX,Tetramethrin + SX, Tetramethylfluthrin + SX, Tetraniliprole + SX, Theta-cypermethrin + SX, Thiacloprid + SX, Thiamethoxam + SX, Thiocyclam + SX, Thiodicarb + SX, Thiofanox + SX, Thiometon + SX, Thiosultap-disodium + SX, Thiosultap-monosodium + SX, Tigolaner + SX, Thiorantraniliprole + SX, Thioxazafen + SX, tolfenpyrad + SX, tralomethrin + SX, transfluthrin + SX, trizamate + SX, triazophos + SX, trichlorfon + SX, trifluenfuronate + SX, triflumezopyrim + SX, triflumuron + SX, trimethacarb + SX, trioxyflanilide + SX, tyclopyrazoflor + SX, umifoxolaner + SX, vadescana + SX, vamidothion + SX, vinylfluthrin + SX, XMC (3,5-dimethylphenyl N-methylcarbamate) + SX,xylylcarb + SX, zeta-cypermethrin + SX, zinc phosphide + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluoropropanesulfinyl)propanamide (1477923-37-7) + SX, 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3) + SX, 3-methoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}indan-1-yl)propanamide (1118626-57-5) + SX, 2-({2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolidin-4-one (1445683-71-5) + SX, N-{4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl}-1-methyl-4-(methanesulfonyl)-3-(1,1,2,2,2-pentafluoroethyl)-1H-pyrazole-3-carboxamide (1400768-21-9) + SX, N-[3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl]-2-(methanesulfonyl)propanamide (2396747-83-2) + SX, N-[4-chloro-2-(pyridin-3-yl)-1,3-thiazol-5-yl]-N-ethyl-3-(methanesulfonyl)propanamide + SX, 1,4-dimethyl-2-[2-(pyridin-3-yl)-2H-indazol-5-yl]-1,2,4-triazolidine-3,5-dione (2171099-09-3) + SX, 2-isopropyl-5-[(3,4,4-trifluoro-3-buten-1-yl)sulfonyl]-1,3,4-thiadiazole (2058052-95-0) + SX, N-({2-fluoro-4-[(2S,3S)-2-hydroxy-3-(3,4,5-trichlorophenyl)-3-(trifluoromethyl)pyrrolidin-1-yl]phenyl}methyl)cyclopropanecarboxamide + SX, 7-fluoro-N-[1-(methylsulfanyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfinyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 7-fluoro-N-[1-(methanesulfonyl)-2-methylpropan-2-yl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, N-[1-(difluoromethyl)cyclopropyl]-2-(pyridin-3-yl)-2H-indazole-4-carboxamide + SX, 2,9-dihydro-9-(methoxymethyl)-2-(pyridin-3-yl)-10H-pyrazolo[3,4-f]pyrido[2,3-b][1,4]oxazepin-10-one (2607927-97-7) + SX, 4-[5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5R)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-5-(trifluoromethyl)-4,5-dihydro-1,2-oxazol-3-yl]-N-[(4S)-2-ethyl-3-oxo-1,2-oxazolidin-4-yl]-2-methylbenzamide + SX, (S)-2-chloro-N-(3-ethylpentan-2-yl)furan-3-carboxamide + SX。,
[0041] Combination of this component of group (b) and this compound: Acibenzolar-S-methyl + SX, Aldimorph + SX, Ametoctradin + SX, Aminopyrifen + SX, Aminotipyr + SX, Amisulbrom + SX, Anilazine + SX, Azaconazole + SX, Azoxystrobin + SX, Basic copper sulfate + SX, Benalaxyl + SX, Benalaxyl-M + SX, Benodanil + SX, Benomyl + SX, Benthiavalicarb + SX, Benthiavalicarb-isopropyl + SX, Benzovindiflupyr + SX, Bifemetstrobin + SX, Binapacryl + SX, Biphenyl + SX, Bitertanol + SX, Bixafen + SX, Blastoicidin-S + SX, Bordeaux mixture + SX, Boscalid + SX, Bromothalonil + SX, Bromuconazole + SX, Bupirimate + SX, Captafol + SX, Captan + SX, Carbendazim + SX, Carboxin + SX, Carmeconazole + SX, Carpropamid + SX, Chinomethionate + SXChloroinconazide + SX, Chloroneb + SX, Chlothalonil + SX, Chlozolinate + SX, Copper(II) acetate + SX, Copper(II) hydroxide + SX, Basic copper chloride + SX, Copper(II) sulfate + SX, Coumoxystrobin + SX, Cyazofamide + SX, Cyclobunofen + SX, Cyflufenamid + SX, Cymoxanil + SX, Cyproconazole + SX, Cyprodinil + SX, cyprometoxazam + SX, diclobentiazox + SX, dichlofluanid + SX, diclocymet + SX, diclomezine + SX, dichloran + SX, diethofencarb + SX, difenoconazole + SX, diflumetorim + SX, dimethachlone + SX, dimethirimol + SX, dimethomorph + SX, dimoxystrobin + SX, diniconazole + SX, Diniconazole-M + SX, Dinocap + SX, Dipotassium hydrogen phosphite + SX, Dipymetitrone + SX,Dithianon + SX, Dodecylbenzenesulfonic acid bisethylenediamine copper(II) complex salt + SX, Dodemorph + SX, Dodine + SX, Edifenphos + SX, Enoxastrobin + SX, Enprocymid + SX, Epoxiconazole + SX, Erysichrona + SX, Etaconazole + SX, Etaboxam + SX, Ethirimol + SX, Etridiazole + SX, Famoxadone + SX, Fenamidone + SX, fenaminstrobin + SX, fenarimol + SX, fenbuconazole + SX, feneptamidoquin + SX, fenfuram + SX, fenhexamid + SX, fenopyramid + SX, fenoxanil + SX, fenpiclonil + SX, fenpicoxamid + SX, fenpropidin + SX, fenpropimorph + SX, fenpyrazamine + SX, fentin acetate + SX, fentin chloride + SX, fentin hydroxide + SX, ferbam + SX, ferimzone + SX,Florylpicoxamide + SX, fluazinam + SX, flubeneteram + SX, fludioxonil + SX, flufenoxadiazam + SX, flufenoxystrobin + SX, fluindapyr + SX, flumetylsulforim + SX, flumorph + SX, fluopicolide + SX, fluopyram + SX, fluopimomide + SX, fluoroimide + SX, fluoxapiprolin + SX, Fluoxastrobin + SX, Fluoxytioconazole + SX, Fluquinconazole + SX, Fluquinometoate + SX, Flusilazole + SX, Flusulfamide + SX, Flutianil + SX, Flutolanil + SX, Flutriafol + SX, Fluxapyroxad + SX, Folpet + SX, Fosetyl + SX, Fosetyl-aluminium + SX, Fuberidazole + SX, Furalaxyl + SX, Furametpyr + SX, galquin + SX, guazatine + SX, hexaconazole + SX, hymexazole + SX, imazalil + SX,Imibenconazole + SX, iminoctadine + SX, iminoctadine triacetate + SX, iminoctadine trialbesilate + SX, inpyrfluxam + SX, iodocarb + SX, ipconazole + SX, ipfentrifluconazole + SX, ipflufenoquin + SX, iprobenfos + SX, iprodione + SX, iprovalicarb + SX, isofetamide + SX, isoflucypram + SX, Isoprothiolane + SX, isopyrazam + SX, isotianil + SX, kresoxim-methyl + SX, mancozeb + SX, mandestrobin + SX, mandipropamid + SX, maneb + SX, mefentrifluconazole + SX, mepanipyrim + SX, mepronil + SX, meptyldinocap + SX, metalaxyl + SX, metalaxyl-M + SX, metarylpicoxamid + SX, metconazole + SX, metcyclofenstrobin + SX, methasulfocarb + SX, metiram + SX,Metominostrobin + SX, Metrafenone + SX, Methyltetraprole + SX, Mineral oils + SX, Myclobutanil + SX, Naftifine + SX, Nuarimol + SX, Octilinone + SX, Ofurace + SX, Orysastrobin + SX, Oxadixyl + SX, Oxathiapiprolin + SX, Oxine-copper + SX, Oxolinic acid + SX, Oxpoconazole + SX, Oxpoconazole fumarate fumarate) + SX, oxycarboxin + SX, oxytetracycline + SX, pefurazoate + SX, penconazole + SX, pencycuron + SX, penflufen + SX, penthiopyrad + SX, phenamacril + SX, phosphorus acid + SX, phthalide + SX, picarbutrazox + SX, picoxystrobin + SX, piperalin + SX, potassium hydrogencarbonate + SX, potassium dihydrogen phosphite + SX, Probenazole + SX, Prochloraz + SX, Procymidone + SX,Propamidine + SX, Propamocarb + SX, Propiconazole + SX, Propineb + SX, Proquinazid + SX, Prothiocarb + SX, Prothioconazole + SX, Pydiflumetofen + SX, Pyraclostrobin + SX, Pyrametostrobin + SX, Pyraoxystrobin + SX, Pyrapropoyne + SX, Pyraziflumid + SX, Pyrazophos + SX, Pyribencarb + SX, Pyribticarb + SX, Pyridachlometyl + SX, Pyrifenox + SX, Pyrimethanil + SX, Pyrimorph + SX, Pyriofenone + SX, Pyrisoxazole + SX, Pyrroquilon + SX, Quinconazole + SX, Quinofumelin + SX, Quinoxyfen + SX, Quintozene + SX, Saccharin + SX, Saccharin sodium + SX, Saccharin potassium + SX, Saccharin calcium + SX, Saccharin ammonium + SX, Saccharin salt + SX, Seboctylamine + SX, Sedaxane + SX, Silthiofam + SX, Simeconazole + SX, Sodium carbonate peroxhydrate + SX, Sodium hydrogencarbonate + SX, Spiroxamine + SX, Sulfur + SX, Tebuconazole + SX, Tebufloquin + SX, Teclofthalam + SX, Tecnazene + SX, Terbinafine + SX, Tetraconazole + SX, Thiabendazole + SX,Tifluzamide + SX, Thiophanate + SX, Thiophanate-methyl + SX, Thiram + SX, Thiadinil + SX, Tolclofos-methyl + SX, Tolfenpyrad + SX, Tolprocarb + SX, Tolylfluanid + SX, Triadimefon + SX, Triadimenol + SX, Triazoxide + SX, Triclopyricarb + SX, Tricyclazole + SX, Tridemorph + SX, Trifloxystrobin + SX, Triflumizole + SX, Triforine + SX, Triticonazole + SX, Validamycin + SX, Valifenalate + SX, Vinclozolin + SX, Zinc thiazole + SX, Zineb + SX, Ziram + SX, Zoxamide + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1R)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-48-7) + SX, 3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1S)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-49-8) + SX, 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide (141573-94-6) + SX, 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide (1513466-73-3) + SX, N'-[4-({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-ethyl-N-methylmethanimidamide (1202781-91-6) + SX, N'-{4-[(4,5-dichlorothiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) + SX, N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) + SX, N'-[5-chloro-4-(2-fluorophenoxy)-2-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055589-28-9) + SX,N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methylmethanimidamide (2055756-21-1) + SX, N'-(2-chloro-4-phenoxy-5-methylphenyl)-N-ethyl-N-methylmethanimidamide (2062599-39-5) + SX, N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-methyl-5-methoxyphenyl]-N-isopropyl-N-methylmethanimidamide (2101814-55-3) + SX, N'-[5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylmethanimidamide (1817828-69-5) + SX, [4-(difluoromethoxy)phenyl]methyl 4-[(N-ethyl-N-methylamino)methylidene]amino-2,5-dimethylbenzoate + SX, 4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) + SX, 2-[6-(3-fluoro-4-methoxyphenyl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) + SX, ethyl (2Z)-3-amino-2-cyano-3-phenylacrylate (39491-78-6) + SX, N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amine (1446247-98-8) + SX, α-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229605-96-2) + SX, (αS)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-46-5) + SX, (αR)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-02-3) + SX, 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) + SX, (1R, 2S, 5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-06-2) + SX, (1S, 2R, 5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol ( 1801930-07-3) + SX, (1R,2R,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-53-8) + SX, (1S,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-54-9) + SX, (1R,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-55-0) + SX, (1S,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-56-1) + SX, (1R,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-57-2) + SX, (1S,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-58-3) + SX, methyl 3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (1791398-02-1) + SX, methyl (1R,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-90-2) + SX, methyl (1S,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-91-3) + SX, methyl (1R,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-92-4) + SX,methyl (1S,2S,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-93-5) + SX, methyl (1R,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-94-6) + SX, methyl (1S,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-95-7) + SX, methyl (1R,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-22-3) + SX, methyl (1S,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2081061-23-4) + SX, 2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) + SX, (1R,2S,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-08-4) + SX, (1S,2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) + SX, (1R,2R,3R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-08-4) + SX, (1S,2S,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-10-8) + SX, (1R,2R,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-13-1) + SX, (1S,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-16-4) + SX, (1R,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-20-0) + SX, (1S,2R,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-24-4) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-86-0) + SX, 1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018316-13-5) + SX, 1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018317-25-2) + SX, 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082661-43-4) + SX, 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) + SX, methyl ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carbamate (1605879-98-8) + SX, 2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-21-4) + SX, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-33-8) + SX, 2-(difluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-02-9) + SX, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952305-97-3) + SX, 2-(difluoromethyl)-N-[3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460-05-2) + SX, 2-(difluoromethyl)-N-[(3R)-3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1952306-00-1) + SX, (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) + SX, (2E,3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-54-3) + SX, 5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl]ethyl}amino)-6-methylpyrimidine (1605340-92-8) + SX, N-(1-benzyl-1,3-dimethylbutyl)-8-fluoroquinoline-3-carboxamide (2132414-04-9) + SX, N-[(1S)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide + SX, N-[(1R)-1-benzyl-1,3-dimethylbutyl]-8-fluoroquinoline-3-carboxamide (2132414-06-1) + SX, N-acetyl-2-(ethanesulfonyl)-N-[2-(methoxycarbonyl)-4-(trifluoromethoxy)phenyl]-4-(trifluoromethyl)benzamide (2043675-28-9) + SX, 3-(4-bromo-7-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromoindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(7-bromo-4-fluoroindol-1-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, 3-(3,5-dichloropyridin-2-yl)butan-2-yl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-hydroxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-[(3-acetoxy-4-methoxypyridin-2-yl)carbonyl]-L-alaninate + SX, (1S)-1-[1-(naphthalen-1-yl)cyclopropyl]ethyl N-{[3-(acetoxymethoxy)-4-methoxypyridin-2-yl]carbonyl}-L-alaninate + SX, 1-(2,3-dimethylpyridin-5-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-[2-(difluoromethyl)-3-methylpyridin-5-yl]-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 2,2-difluoro-N-[6-({[1-(1-methyl-1H-tetrazol-5-yl)benzimidazol-2-yl]oxy}methyl)pyridin-2-yl]-2-phenoxyacetamide + SX,1-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile + SX, ethyl 1-[(4-{[2-(trifluoromethyl)-1,3-dioxolan-2-yl]methoxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, ethyl 1-[(4-{[(1Z)-2-ethoxy-3,3,3-trifluoro-1-propen-1-yl]oxy}phenyl)methyl]-1H-pyrazole-4-carboxylate + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(2,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-3-(3-cyclopropyl-2-fluorophenoxy)-N-[2-(3,4-dimethylphenyl)-2,2-difluoroethyl]-5-methylpyridazine-4-carboxamide + SX, 6-chloro-N-[2-(2-chloro-4-methylphenyl)-2,2-difluoroethyl]-3-(3-cyclopropyl-2-fluorophenoxy)-5-methylpyridazine-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-(spiro[3.4]octan-1-yl)-5-methylthiazole-4-carboxamide + SX, 2-[cyano(2,6-difluoropyridin-4-yl)amino]-N-hexyl-5-methylthiazole-4-carboxamide + SX, 2-[acetyl(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methoxyacetyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2-methylpropanoyl)(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-[(2,6-difluoropyridin-4-yl)amino]-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxetan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxolan-3-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 2-{[(oxan-4-yl)carbonyl](2,6-difluoropyridin-4-yl)amino}-N-(2,2-dimethylcyclobutyl)-5-methylthiazole-4-carboxamide + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)ethyl]pyrimidin-2-amine + SX,5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(3,5-difluorophenyl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(6-chloropyridin-3-yl)ethyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2,6-difluorophenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-N-[1-(2-fluoro-3-methoxyphenyl)cyclopropyl]pyrimidin-2-amine + SX, 5-[5-(difluoromethyl)-1,3,4-oxadiazol-2-yl]-2-{[1-(2,6-difluorophenyl)cyclopropyl]oxy}pyrimidine + SX, 3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-cyclopropyl-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2,4-dimethylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX,3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(4-bromo-2-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, 3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5S)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, (5R)-3-[3-(3-chloro-2-fluorophenoxy)-6-methylpyridazin-4-yl]-5-[(2-chloro-4-methylphenyl)methyl]-5,6-dihydro-4H-1,2,4-oxadiazine + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}-3-methylbutan-2-yl)-2,2-dimethylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(2-methoxyphenyl)-2-hydroxyethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-((2S)-1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[(E)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, N-(1-{3-[2-(5-fluoro-2-methoxyphenyl)-2-(2-cyanoethoxy)ethyl]-5-[(Z)-1-(isopropoxyimino)ethyl]-2,6-dioxo-3,6-dihydropyrimidin-1(2H)-yl}propan-2-yl)-2-methylpropanamide + SX, methyl ({5-[1-(2,6-difluoro-4-isopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-cyclopropylphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, methyl ({5-[1-(2,6-difluoro-4-methoxyphenyl)-1H-pyrazol-3-yl]-2-methylphenyl}methyl)carbamate + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(4,5-dimethyl-1H-benzimidazol-1-yl)-4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(pyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline + SX, 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-6-fluoro-3,3-dimethylisoquinolin-4(3H)-one + SX, rel-N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[(1R,2R)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide + SX, N-[2-(pyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2S)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[(2R)-2-(6-chloro-4-methoxypyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-(2-{6-[(1E)-(methoxyimino)ethyl]pyridin-2-yl}-2-(1-methylpyrazol-4-yl)propyl)-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(5-methylpyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-dichlorophenyl)isoxazole-3-carboxamide + SX, methyl 6-(2-{[5-(2,4-difluorophenyl)isoxazole-3-carbonyl]amino}-1-methyl-1-(1-methylpyrazol-4-yl)ethyl)pyridine-3-carboxylate + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)isoxazole-3-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-3-(2,4-difluorophenyl)-1,2,4-oxadiazole-5-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(5-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,4-difluorophenyl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-cyanopyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(3,5-difluoropyridin-2-yl)-1,3,4-thiadiazole-2-carboxamide + SX, N-[2-(6-chloropyridin-2-yl)-2-(1-methylpyrazol-4-yl)propyl]-5-(2,6-difluoropyridin-3-yl)-1,3,4-thiadiazole-2-carboxamide + SX, ethyl 1-[(4-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}-2-fluorophenyl)methyl]pyrazole-4-carboxylate + SX, ethyl 1-[(5-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}thiophen-2-yl)methyl]pyrazole-4-carboxylate + SX, 1-[(4-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}phenyl)methyl]-1,3-dimethoxyurea + SX, N-[(4-{5-[chloro(difluoro)methyl]-1,2,4-oxadiazol-3-yl}phenyl)methyl]-N,2-dimethoxypropanamide + SX, 2-(4-fluorophenoxy)-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}ethanone + SX, 2-[(6-fluoropyridin-3-yl)oxy]-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}ethanone + SX, 2-(4-fluoroanilino)-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}ethanone + SX, 1-(4-{4-[5-(2,6-dichlorophenyl)-4,5-dihydroisoxazol-3-yl]thiazol-2-yl}piperidin-1-yl)-2-[3-(trifluoromethyl)pyrazin-2-yl]oxyethanone + SX, 1-(4-{4-[5-(2-chloro-6-fluorophenyl)-4,5-dihydroisoxazol-3-yl]thiazol-2-yl}piperidin-1-yl)-2-[3-(trifluoromethyl)pyridin-2-yl]oxyethanone + SX, tert-butyl 4-{4-[5-(2-bromo-6-fluorophenyl)-4,5-dihydroisoxazol-3-yl]thiazol-2-yl}piperidine-1-carboxylate + SX。,
[0042] Combination of this component of group (c) and this compound:1-methylcyclopropene + SX, 1,3-diphenylurea + SX, 1,3,5-triazinane-2,4,6-trithione + SX, 2,3,5-triiodobenzoic acid + SX, IAA ((1H-indol-3-yl)acetic acid) + SX, IBA (4-(1H-indol-3-yl)butyric acid) + SX, MCPA (2-(4-chloro-2-methylphenoxy)acetic acid) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butyric acid) + SX, 4-CPA (4-chlorophenoxyacetic acid) + SX, 5-aminolevulinic acid hydrochloride + SX, 6-benzylaminopurine + SX, abscisic acid + SX, AVG (aminoethoxyvinylglycine) + SX, anisiflupurin + SX, ancymidol + SX, butralin + SX, calcium carbonate + SX, calcium chloride + SX, calcium formate + SX, calcium peroxide + SX, calcium polysulfide + SX, calcium sulfate + SX, chlormequat-chloride + SX, chlorpropham + SX, choline chloride + SX, cloprop + SX, cyanamide + SX, cyclanilide + SX, cyprosulfamide + SX, daminozide + SX, Decan-1-ol + SX,Dichlorprop + SX, Dikegulac + SX, Dimethipin + SX, Diquat + SX, Ethephon + SX, Ethychlozate + SX, Flumetralin + SX, Flurprimidol + SX, Forchlorfenuron + SX, Formononetin + SX, Gibberellin A + SX, Gibberellin A3 + SX, Inabenfide + SX, Kinetin + SX, Lipochitooligosaccharide MOR116 + SX, Lipochitooligosaccharide SP104 + SX, maleic hydrazide + SX, mefluidide + SX, mepiquat-chloride + SX, methyl-alpha-D-mannopyranoside + SX, oxidized glutathione + SX, paclobutrazol + SX, pendimethalin + SX, prohexadione-calcium + SX, prohydrojasmon + SX, pyraflufen-ethyl + SX, pyroglutamic acid + SX, sintofen + SX, sodium 1-naphthaleneacetate 1-naphthaleneacetate) + SX, sodium cyanate + SX, thidiazuron + SX, titanium apatite + SX,Tripenthenol + SX, Tribufos + SX, Trinexapac-ethyl + SX, Uniconazole-P + SX, 2-(naphthalen-1-yl)acetamide + SX, [4-oxo-4-(2-phenylethyl)amino]butyric acid + SX, 5-(trifluoromethyl)benzo[b]thiophene-2-carboxylate methyl + SX, 3-[(6-chloro-4-phenylquinazolin-2-yl)amino]propan-1-ol + SX, Strigolactone + SX, (1E)-1-[[1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-5-oxo-2H-pyrrol-2-yl]oxymethylene]-3,3a,4,8b-tetrahydroindeno[2,1-b]pyrrol-2-one + SX, as described in International Publication No. 2018 / 145979, (2R)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX, as described in International Publication No. 2018 / 145979 (2S)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one + SX, as described in International Publication No. 2018 / 145979.
[0043] Combinations of the component in group (d) above and the compound in question: Allidochlor + SX, Benoxacor + SX, Cloquintocet + SX, Cloquintocet-mexyl + SX, Cyometrinil + SX, Cyprosulfamide + SX, Dichlormid + SX, Dicyclonone + SX, Dimepiperate + SX, Disulfoton + SX, Dymron + SX, Fenchlorazole + SX, Fenchlorazole-ethyl + SX, Fenchlorrim + SX, Flurazole + SX, Furilazole + SX, Fluxofenim + SX, Hexim + SX, Isoxadifen + SX, Isoxadifen-ethyl + SX, Jiecaowan + SX, Jiecaoxi + SX, Mecoprop + SX, Mefenpyr + SX, Mefenpyr-ethyl + SX, Mefenpyr-diethyl + SX, Mephenate + SX, Metocamifen + SX, Oxabetrinil + SX, 1,8-Naphthalic anhydride + SX, Octane-1,8-diamine + SX, AD-67 (4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5] decane) + SX, CL-304415 (4-carboxy-3,4-dihydro-2H-1-benzopyran-4-acetic acid) + SX, CSB (1-bromo-4-[(chloromethyl)sulfonyl]benzene) + SX, DKA-24 (2,2-dichloro-N-[2-oxo-2-(2-propenylamino)ethyl]-N-(2-propenyl)acetamide) + SX, MG191 (2-(dichloromethyl)-2-methyl-1,3-dioxolane) + SX, MG-838 (2-propenyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate) + SX, PPG-1292 (2,2-dichloro-N-(1,3-dioxan-2-ylmethyl)-N-(2-propenyl)acetamide) + SX, R-28725 (3-(dichloroacetyl)-2,2-dimethyl-1,3-oxazolidine) + SX, R-29148 (3-(dichloroacetyl)-2,2,5-trimethyl-1,3-oxazolidine) + SX, TI-35 (1-(dichloroacetyl)azepane) + SX。
[0044] Combination of this component and this compound of group (e) above: 1-dodecyl-1H-imidazole + SX, N-(2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide + SX, bucarpolate + SX, N,N-dibutyl-4-chlorobenzenesulfonamide + SX, dietholate + SX, diethylmaleate + SX, Jiajizengxiaolin + SX, octachlorodipropyl ether + SX, perbutin + SX, piperonyl butoxide (butoxide) + SX, piperonyl cyclonene + SX, piprotal + SX, propyl isome + SX, safroxan + SX, sesamex + SX, sesamolin + SX, sulfoxide + SX, verbutin + SX, DMC (1,1-bis(4-chloro phenyl)ethanol) + SX, FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol) + SX, ETN (1,2-epoxy-1,2,3,4-tetrahydronaphthalene) + SX, ETP (1,1,1-trichloro-2,3-expoxypropane) + SX, PSCP (phenylsaligenin cyclic phosphate) + SX, TBPT (S,S,S-tributyl phosphorotrithioate) + SX, TPP (triphenyl phosphate) + SX.
[0045] Combinations of the above group (f) and the present compound: Anthraquinone + SX, Chloralose + SX, Acrep + SX, Butopyronoxyl + SX, Camphor + SX, D-Camphor + SX, Carboxide + SX, Dibutyl phthalate + SX, DEET + SX, Dimethyl carbate + SX, Dimethyl phthalate + SX, Dibutyl succinate + SX, Dibutyl adipate + SX, Ethohexadiol + SX, Hexamide + SX, Icaridin + SX, Methoquin-butyl + SX, methylneodecanamide + SX, 2-(octylthio)ethanol + SX, butoxypolypropylene glycol + SX, oxamate + SX, quwenzhi + SX, quyingding + SX, zengxiaon + SX, rebemide + SX, copper naphthenate + SX, zinc naphthenate + SX.
[0046] Combinations of the above group (g) and the present compound: Bis(tributyltin) oxide + SX, Allicin + SX, Bromoacetamide + SX, Calcium arsenate + SX, Cloethocarb + SX, Copper sulfate + SX, Fentin + SX, Ferric phosphate + SX, Metaldehyde + SX, Niclosamide + SX, Paris green + SX, Pentachlorophenol + SX, Sodium ferric EDTA + SX, Sodium pentachlorophenoxide + SX, Tazimcarb + SX, Tralopyril + SX, tributyltin oxide + SX, trifenmorph + SX.
[0047] Combinations of the component in group (h) above and the compound in question: (4Z,7Z)-deca-4,7-dien-1-yl acetate + SX, (2E)-dec-2-en-1-ol + SX, (4Z)-dec-4-en-1-yl acetate + SX, (5Z)-dec-5-en-1-ol + SX, +-5Z a-ceta-1-dec (8Z)-dec-8-en-1-ol + SX, (7Z,13Z,16Z,19Z)-docosa-7,13,16,19-tetraen-1-ly isobutylate + SX, (7Z)-dodec-7-en-1-yl acetate + SX-,1-ol +8)-endo (8E)-dodec-8-en-1-yl acetate + SX, (8Z)-dodec-8-en-1-yl acetate + SX, (9E)-dodec-9-en-1-yl acetate + SX, (9Z)-dodec-9-en-1-yl acetate-Z3-Z-endo, (de (2E)-but-2-enoate + SX, (7E,9E)-dodeca-7,9-diene-1-yl acetate + SX, (7E,9Z)-dodeca-7,9-diene-1-yl acetate + SX, (7Z,9E)-dodeca-7,9-dien-te +1-yl (8E,10E)-dodeca-8,10-diene-1-ol + SX, (8E,10E)-dodeca-8,10-diene-1-yl acetate + SX, (6Z)-henicos-6-en-1-one + SX, (9Z)-hexadec-9-enal-9l- SX, + SX, (10Z)-hexadec-10-en-1-yl acetate + SX, (11Z)-hexadec-11-enal + SX, (11Z)-hexadec-11-en-1-ol + SX, (11Z)-hexadec-11-en-1-yl acetate (13Z)-hexadec-13-en-11-yn-1-yl acetate + SX, (7Z,11Z)-hexadeca-7,11-dienal + SX, (7E,11E)-hexadeca-7,11-dien-1-yl acetate + SX, (7E,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (7Z,11E)-hexadeca,ta-7,1-Xcel-dien (7Z,11Z)-hexadeca-7,11-dien-1-yl acetate + SX, (10E,12E)-hexadeca-10,12-dienal + SX, (11Z,13Z)-hexadeca-11,13-dienal + SX, (7Z,1caZ-37-Z + SX, (7Z,11Z,13E)-hexadeca-7,11,13-trienal + SX, (13Z)-icos-13-en-10-one + SX, (2E)-6-methylhept-2-en-4-ol + SX, (11Z)-ol-octadec,1-11 (11Z)-octadec-11-enal + SX, (13Z)-octadec-13-enal + SX, (2E,13Z)-octadeca-2,13-diene-1-ol + SX, (2E,13Z)-octadeca-2,13-dienete-1-1-yl acetate (2Z,13Z)-octadeca-2,13-diene-1-yl acetate + SX, (3E,13Z)-octadeca-3,13-dien-1-ol + SX, (3E,13Z)-octadeca-3,13-diene-1-yl acetate + SX, (3Z,13Z)-octadeca-3,13-dien-1-ol + SX, (3Z,13Z)-octadeca-3,13-diene-1-yl acetate + SX, (7Z)-tetradec-7-enal + SX, (7Z)-tetradec-1c-Z-7-en-X-en-9-ol + SX, (9Z)-tetradec-9-en-1-yl acetate + SX, (11Z)-tetradec-11-enal + SX,(11E)-tetradec-11-en-1-yl acetate + SX, (11Z)-tetradec-11-en-1-yl acetate + SX, (3E,8Z)-tetradeca-3,8-dien-1-yl acetate + SX, (4E,10Z)-tetradeca-4,10-dien-1-yl acetate + SX, (8E,10Z)-tetradeca-8,10-dienal + SX, (9E,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,11E)-tetradeca-9,11-dien-1-yl acetate + SX, (9Z,12E)-tetradeca-9,12-dien-1-yl acetate + SX, (3E,8Z,11Z)-tetradeca-3,8,11-trien-1-yl acetate + SX, (9E)-tricos-9-ene + SX, (4E)-tridec-4-en-1-yl acetate + SX, (4Z)-tridec-4-en-1-yl acetate + SX, allyl isothiocyanate + SX, 4-allylanisole + SX, 3-carene + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + SX, (5R)-5-[(1Z)-dec-1-en-1-yl]dihydro-2(3H)-furanone + eugenol + 2-phenylethyl propionate + SX, (Z)-2-(3,3-dimethylcyclohexylidene)ethanol + SX, (4R,8R)-4,8-dimethyldecanal + SX, (4R,8S)-4,8-dimethyldecanal + SX, 2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3,2,1]octane + SX, 1,7-dioxaspiro[5,5]undecane + SX, dodecan-1-ol + SX, dodecyl acetate + SX, ethyl (2E,4Z)-deca-2,4-dienoate + SX, ethyl 4-methyloctanoate + SX, (2R,5R)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (2R,5S)-ethyl-1,6-dioxaspiro[4,4]nonane + SX, (E)-β-farnesene + SX, farnesyl alcohol + SX, ferrugineol + SX, geranyl hexanoate + SX, (E)-2-hexenyl butyrate + SX, (E)-2-hexenyl butyrate + hexyl butyrate + (E)-4-oxo-2-hexenal + SX, hexyl butyrate + SX, jasmone + SX, 3-ketopetromyzonol-24-sulfate ammonium salt + SX, methyl 2,6,10-trimethyldodecanoate + SX, methyl (2E,4E)-hepta-2,4-dienoate + SX, 2-methylbut-3-en-1-ol + SX, 2-(1-methyl-2-prop-1-en-2-ylcyclobutyl)ethanol + SX, 3-methylcyclohex-2-en-1-one + SX, (-)-4-methylheptan-3-ol + SX, 4-methylnonan-5-ol + SX, 4-methylnonan-5-one + SX, 14-methyloctadec-1-ene + SX, nepetalactone + SX, ocimene + SX, 1,2-octanediol + SX, oct-1-en-3-ol + SX, (R)-oct-1-en-3-ol + SX, olean + SX, 4-(3-oxobutyl)phenyl acetate + SX, (E)-4-oxo-2-hexenal + SX, pentacosane + SX, penta-termanone + SX, phenylacetaldehyde + SX, putrescine + SX, tetradecan-1-ol + SX,tetradecyl acetate + SX, tricosane + SX, tridecan-2-one + SX, 1,2,4-trimethoxybenzene + SX, trimethylamine + SX, trimethylamine hydrochloride + SX, 2-(undecyloxy)ethanol + SX, querciverol + SX, alpha-terpinene + SX, alpha-terpineol + SX, alpha-terpinoline + SX, animal tissue hydrolysate + SX, beet molasses-urea hydrolysate + SX, camphene + SX, capilure + SX, ceralure + SX, chalcogran + SX, codlerure + SX, codlemone + SX, copaene + SX, cosmolure + SX, cucujolide VIII + SX, cuelure + SX, cyclotene + SX, disparlure + SX, dominanticalure + SX, endobrevicomin + SX, eugenol + SX, exitlure + SX, exobrevicomin + SX, farnesol + SX, ferrolure + SX, frontalin + SX, German cockroach pheromone + SX, Gossyplure + SX, Gossyplure HF + SX,Grandlure + SX, Grandlure I + SX, Grandlure II + SX, Grandlure III + SX, Grandlure IV + SX, Hexalure + SX, Ipsdienol + SX, Ipsenol + SX, Japonilure + SX, Lavandin oil + SX, Lineatin + SX, Litlue + SX, Looplure + SX, Medlure + SX, Megatomoic acid + SX, Methyl eugenol + SX, Multistriatin + SX, Muscalure + SX, Nerolidol + SX, Orfralure + SX, Oryctalure + SX, Ostramone + SX, Peachflure + SX, Prodenialure B + SX, Rescalure + SX, Rhyncolure + SX, Siglure + SX, Sordidin + SX, Sulcatol + SX, Trimedlure + SX, Trimedlure A + SX, Trimedlure B1 + SX, Trimedlure B2 + SX, Trimedlure C + SX, Trunc-call + SX, (E)-verbenol + SX, (Z)-verbenol + SX, Trans-verbenol + SX,S-verbenone + SX.
[0048] Combinations of the component in group (i) above and the compound in question: 2,3,6-TBA (2,3,6-trichlorobenzoic acid) + SX,2,3,6-TBA-dimethylammonium + SX,2,3,6-TBA-lithium salt + SX,2,3,6-TBA-potassium salt + SX,2,3,6-TBA-sodium salt + SX,2,4-D + SX,2,4-D choline salt + SX,2,4-D biproamine + SX,2,4-D doboxyl + SX,2,4-D 2-ethylhexyl (2,4-D-2-ethylhexyl) + SX, 2,4-D 3-butoxypropyl (2,4-D-3-butoxypropyl) + SX, 2,4-D ammonium (2,4-D-ammonium) + SX, 2,4-D butotyl (2,4-D-butotyl) + SX, 2,4-D butyl (2,4-D-butyl) + SX, 2,4-D diethylammonium (2,4-D-diethylammonium) + SX, 2,4-D dimethylammonium (2,4-D-dimethylammonium) + SX, 2,4-D diolamine salt (2,4-D-diolamine) + SX, 2,4-D dodecylammonium (2,4-D-dodecylammonium) + SX, 2,4-D ethyl (2,4-D-ethyl) + SX, 2,4-D-heptylammonium + SX,2,4-D-isobutyl + SX,2,4-D-isooctyl + SX,2,4-D-isopropyl + SX,2,4-D-isopropylammonium + SX,2,4-D-lithium + SX,2,4-D-meptyl + SX,2,4-D-methylSX, 2,4-D-methyl) + SX, 2,4-D-octyl + SX, 2,4-D-pentyl + SX, 2,4-D-propyl + SX, 2,4-D-sodium + SX, 2,4-D-tefuryl + SX, 2,4-D-tetradecylammonium + SX, 2,4-D-triethylammonium + SX, 2,4-D-tris(2-hydroxypropyl)ammonium + SX, 2,4-D-trolamine + SX, 2,4-DB + SX, 2,4-DB choline salt + SX, 2,4-DB biproamine + SX, 2,4-DB butyl + SX, 2,4-DB dimethylammonium + SX, 2,4-DB isooctyl + SX, 2,4-DB potassium salt + SX, 2,4-DB sodium salt + SX, acetochlor + SX, acifluorfen + SX, acifluorfen-sodium + SX, acroniphen + SX, ACN (2-amino-3-chloronaphthalene-1,4-dione) + SX, alachlor + SX, alloxydim + SX, ametryn + SX, amicarbazone + SX, amidosulfuron + SX, aminocyclopyrachlor + SX,Aminocyclopyrachlor-methyl + SX, Aminocyclopyrachlor-potassium salt + SX, Aminopyralid + SX, Aminopyralid choline salt + SX, Aminopyralid-potassium salt + SX, Aminopyralid-tripromine + SX, Amiprophos-methyl + SX, Amitrol + SX, Anilofos + SX, Asulam + SX, Atrazine + SX, Azafenidin + SX, Azimsulfuron + SX, Beflubutamid + SX, Benazolin-ethyl + SX, Bencarbazone + SX, Benfluralin + SX, Benfuresate + SX, Benquitrione + SX, Bensulfuron + SX, Bensulfuron-methyl + SX, Bensulide + SX, Bentazon + SX, Benthiocarb + SX, Benzfendizone + SX, Benzobicyclon + SX, Benzofenap + SX, Benzthiazuron + SX, Bialaphos + SX, Bicyclopyrone + SX, Bifenox + SX, Bipyrazone + SX, Bispyribac + SX,Bispyribac-sodium + SX, Bixlozone + SX, Bromacil + SX, Bromobutide + SX, Bromofenoxim + SX, Bromoxynil + SX, Bromoxynil-octanoate + SX, Butachlor + SX, Butafenacil + SX, Butamifos + SX, Butroxydim + SX, Butyrate + SX, Cafenstrole + SX, Carbetamide + SX, Carfentrazone + SX, Carfentrazone-ethyl + SX, Chlomethoxyfen + SX, Chloramben + SX, Chloridazon + SX, Chlorimuron + SX, Chlorimuron-ethyl + SX, Chlorbromuron + SX, Chlortoluron + SX, Chlorxuron + SX, Chlorpropham + SX, Chlorsulfuron + SX, Chlorthal-dimethyl + SX, Chlorthiamid + SX, Cinflubrolin + SX, Cinidone + SX, Cinidone-ethyl + SX, Cinmethylin + SX, Cinosulfuron + SX, Clethodim + SX, Clodinafop + SX,Clodinafop-propargyl + SX, Clomazone + SX, Clomeprop + SX, Clopyralid + SX, Clopyralid choline salt + SX, Clopyralid-methyl + SX, Clopyralid-olamine + SX, Clopyralid-potassium + SX, Clopyralid-tris(2-hydroxypropyl)ammonium + SX, Cloransulam + SX, Cloransulam-methyl + SX, Cumyluron + SX, Cyanazine + SX, Cycloate + SX, Cyclopyranil + SX, Cyclopyrimorate + SX, Cyclosulfamuron + SX, Cycloxydim + SX, Cyhalofop + SX, Cyhalofop-butyl + SX, Cypyrafluone + SX, Dalapon + SX, Dazomet + SX, Desmedipham + SX, Desmetryn + SX, Dialate + SX, Dicamba + SX, Dicamba choline salt + SX, Dicamba-biproamine + SX, Dicanba trolamine salt + SX, Dicanba diglycolamine salt + SX,Dicamba-dimethylammonium + SX, Dicamba-diolamine + SX, Dicamba-isopropylammonium + SX, Dicamba-methyl + SX, Dicamba-olamine + SX, Dicamba-potassium + SX, Dicamba-sodium + SX, Diclobenil + SX, Dichlorprop choline salt + SX, Dichlorprop-biproamine + SX, Dichlorprop-2-ethylhexyl + SX, Dichlorprop-butotyl + SX, Dichlorprop-dimethylammonium + SX, Dichlorprop-ethylammonium + SX, Dichlorprop-isoctyl + SX, Dichlorprop-methyl + SX, Dichlorprop-P + SX, Dichlorprop-P choline salt + SX, Dichlorprop-P-biproamine + SX, Dichlorprop-P-etexyl + SX, Dichlorprop-P-dimethylammonium + SX, Dichlorprop-potassium salt + SX, Dichlorprop-sodium salt + SX, Diclofop + SX,Diclofop-methyl + SX, Diclosulam + SX, Difenoxuron + SX, Difenzoquat + SX, Difenzoquat metilsulfate + SX, Diflufenican + SX, Diflufenzopyr + SX, Diflufenzopyr-sodium + SX, Dimefuron + SX, Dimepiperate + SX, Dimepyrolimet + SX, Dimesulfazet + SX, Dimethachlor + SX, Dimethametryn + SX, Dimethenamid + SX, Dimethenamid-P + SX, Dinitramine + SX, Dinoseb + SX, Dinoterb + SX, Dioxopyritrione + SX, Diphenamid + SX, Diquat-dibromide + SX, DSMA (disodium methylarsonate) + SX, Dithiopyr + SX, Diuron + SX, DNOC (2-methyl-4,6-dinitrophenol) + SX, Epirifenacil + SX, Esprocarb + SX, Ethalfluralin + SX, Ethamethsulfuron + SX, Ethamethsulfuron-methyl + SX, Ethidimuron + SX, Ethofumesate + SX, Ethoxyfen-ethyl + SX, Ethoxysulfuron + SX, Etobenzanid + SX, Fendioxypyracil + SX, Fenoxaprop + SX,Fenoxaprop-ethyl + SX, Fenoxaprop-P + SX, Fenoxaprop-P-ethyl + SX, Fenoxasulfone + SX, Fenpyrazone + SX, Fenquinotrione + SX, Fentrazamide + SX, Fenuron + SX, Feproxydim + SX, Flamprop-M + SX, Flazasulfuron + SX, Florasulam + SX, Florpyrauxifen + SX, Florpyrauxifen-benzyl + SX, Fluazifop + SX, Fluazifop-butyl + SX, Fluazifop-P + SX, Fluazifop-P-butyl + SX, Fluazolate + SX, Flucarbazone + SX, Flucarbazone-sodium + SX, Flucetosulfuron + SX, Fluchloraminopyr + SX, Fluchloraminopyr-tefuryl + SX, Flufenacet + SX, Flufenauxirim + SX, Flufenauxirim-metotyl + SX, Flufenazopyr + SX, Flufenoximacil + SX, Flufenpyr + SX, Flufenpyr-ethyl + SX,Flumetsulam + SX, Flumetslam + SX, Flumiclorac + SX, Flumiclorac-pentyl + SX, Flumioxazin + SX, Fluometuron + SX, Fluoroglycofen-ethyl + SX, Flupoxam + SX, Flupropanate + SX, Flupyrsulfuron + SX, Flupyrsulfuron-methyl-sodium + SX, Flurenol + SX, Fluridone + SX, Flurochloridone + SX, Fluroxypyr + SX, Fluroxypyr-butometyl + SX, Fluroxypyr-meptyl + SX, Flurtamone + SX, Flusulfinam + SX, Fluthiacet + SX, Fluthiacet-methyl + SX, Fomesafen + SX, Fomesafen-sodium + SX, Foramsulfuron + SX, Fosamine + SX, Glufosinate + SX, Glufosinate-ammonium + SX, Glufosinate-P + SX, Glufosinate-P-ammonium salt + SX, Glufosinate-P-sodium salt + SX, Glyphosate + SX,Glyphosate choline salt + SX, Glyphosate-isopropylammonium + SX, Glyphosate-biproamine + SX, Glyphosate-ammonium salt + SX, Glyphosate-diammonium salt + SX, Glyphosate-potassium salt + SX, Glyphosate-sodium salt + SX, Glyphosate-trimesium + SX, Halauxifen + SX, Halauxifen-benzyl + SX, Halauxifen-methyl + SX, Halosafen + SX, Halosulfuron + SX, Halosulfuron-methyl + SX, Haloxyfop + SX, Haloxyfop-etotyl + SX, Haloxyfop-methyl + SX, Haloxyfop-P + SX, Haloxyfop-P-etotyl + SX, Haloxyfop-P-methyl + SX, Hexazinone + SX, Icafolin + SX, Icafolin-methyl + SX, Imazametabenz + SX, Imazametabenz-methyl + SX, Imazamox + SX, imazamox-ammonium salt + SX, imazamox-sodium salt + SX,imazapic + SX, imazapic-ammonium + SX, imazapyr + SX, imazapyr-ammonium + SX, imazapyr-isopropylammonium + SX, imazaquin + SX, imazaquin-ammonium + SX, imazethapyr + SX, imazethapyr-ammonium + SX, imazosulfuron + SX, indanofan + SX, indaziflam + SX, indolauxipyr + SX, indolauxipyr-cyanomethyl + SX, Iodosulfuron + SX, Iodosulfuron-methyl-sodium + SX, Iofensulfuron + SX, Iofensulfuron-sodium + SX, Ioxynil + SX, Ioxynil-octanoate + SX, Ipfencarbazone + SX, Iptriazopyrid + SX, Isoproturon + SX, Isouron + SX, Isoxaben + SX, Isoxachlortole + SX, Isoxafenacil + SX, Isoxaflutole + SX, Lactofen + SX, Lenacil + SX, Linuron + SX,Maleic hydrazide + SX, MCPA choline salt + SX, MCPA-biproamine + SX, MCPA-etexyl + SX, MCPA-butotyl + SX, MCPA-butyl + SX, MCPA-dimethylammonium + SX, MCPA-diolamine + SX, MCPA-ethyl + SX, MCPA-isobutyl + SX, MCPA-isoctyl + SX, MCPA-isopropyl + SX, MCPA-methyl + SX, MCPA-olamine + SX, MCPA sodium salt (MCPA-sodium) + SX, MCPA trolamine salt (MCPA-trolamine) + SX, MCPB (4-(4-chloro-2-methylphenoxy)butanoic acid) + SX, MCPB choline salt (MCPB-choline salt) + SX, MCPB biproamine (MCPB-biproamine) + SX, MCPB ethyl (MCPB-ethyl) + SX, MCPB methyl (MCPB-methyl) + SX, MCPB sodium salt (MCPB-sodium) + SX, mecoprop choline salt (mecoprop choline salt) + SX, mecoprop biproamine (mecoprop-biproamine) + SX, mecoprop 2-ethylhexyl (mecoprop-2-ethylhexyl) + SX, mecoprop dimethylammonium (mecoprop-dimethylammonium) + SX, mecoprop diolamine salt (mecoprop-diolamine) + SX, mecoprop-ethadyl + SX,Mecoprop-isoctyl + SX, Mecoprop-methyl + SX, Mecoprop-potassium + SX, Mecoprop-sodium + SX, Mecoprop-trolamine + SX, Mecoprop-P + SX, Mecoprop-P choline salt + SX, Mecoprop-P 2-ethylhexyl + SX, Mecoprop-P-dimethylammonium + SX, Mecoprop-P-isobutyl + SX, Mecoprop-P-potassium + SX, Mefenacet + SX, Mesosulfuron + SX, Mesosulfuron-methyl + SX, Mesotrione + SX, Metam + SX, Metamifop + SX, Metamitron + SX, Metazachlor + SX, Metazosulfuron + SX, Metabenzthiazuron + SX, Methiozolin + SX, Methyldymron + SX, Metobromuron + SX, Metolachlor + SX, Metoxuron + SX, Metosulam + SX, Metoproxybicyclone + SX, Metribuzin + SX, Metosulfuron + SX, Metosulfuron-methyl + SX, Molinate + SX, Monolinuron + SX, Naproanilide + SX, Napropamide + SX, Napropamide-M + SX, Naptalam + SX, Neburon + SX, Nicosulfuron + SX, norflurazon + SX, oleic acid + SX, orbencarb + SX, orthosulfamuron + SX, oryzalin + SX, oxadiargyl + SX, oxadiazon + SX, oxasulfuron + SX, oxaziclomefone + SX, oxyfluorfen + SX, paraquat + SX, paraquat-dichloride + SX, pebulate + SX, pelargonic acid + SX, pendimethalin + SX, penoxsulam + SX, pentanochlor + SX, pentoxazone + SX, petoxamide + SX, phenisopham + SX,Phenmedipham + SX, picloram, picolinafen + SX, picolinafen + SX, pinoxaden + SX, piperophos + SX, pretilachlor + SX, primisulfuron + SX, primisulfuron-methyl + SX, prochlorosulfone + SX, prodiamine + SX, profluazol + SX, profoxydim + SX, prometon + SX, promethrin + SX, propachlor + SX, propanil + SX, Propaquizafop + SX, Propazine + SX, Profam + SX, Propisochlor + SX, Propoxycarbazone + SX, Propoxycarbazone-sodium + SX, Propyrisulfuron + SX, Propyzamide + SX, Prosulfocarb + SX, Prosulfuron + SX, Pyraclonil + SX, Pyraquinate + SX, Pyrasulfotole + SX, Pyrazolynate + SX, Pyrazosulfuron + SX, Pyrazosulfuron-ethyl + SX, Pyrazoxyfen + SX, Pyribenzoxim + SX,Pyributicarb + SX, Pyridafol + SX, Pyridate + SX, Pyriflubenzoxim + SX, Pyriftalid + SX, Pyriminobac + SX, Pyriminobac-methyl + SX, Pyrimisulfan + SX, Pyrithiobac + SX, Pyrithiobac-sodium + SX, Pyroxasulfone + SX, Pyroxsulam + SX, Quinclorac + SX, Quinmerac + SX, Quizalofop + SX, Quizalofop-ethyl + SX, Quizalofop-tefuryl + SX, Quizalofop-P + SX, Quizalofop-P-ethyl + SX, Quizalofop-P-tefuryl + SX, Rimisoxafen + SX, Rimsulfuron + SX, Saflufenacil + SX, Setoxydim + SX, EPTC (S-ethyl N,N-dipropylcarbamothioate) + SX, Siduron + SX, Simazine + SX, Simetryn + SX, S-metolachlor + SX, MSMA (sodium hydrogen methylarsonate) + SX, sulcotrione + SX, sulfentrazone + SX, sulfometuron + SX,Sulfometuron-methyl + SX, sulfosulfuron + SX, swep + SX, TCA (2,2,2-trichloroacetic acid) + SX, TCA-ammonium + SX, TCA-calcium + SX, TCA-ethadyl + SX, TCA-magnesium + SX, TCA-sodium + SX, tebutam + SX, tebuthiuron + SX, tefuryltrione + SX, tembotrione + SX, tepraloxydim + SX, terbacil + SX, terbumeton + SX, terbuthylazine + SX, terbutryn + SX, tetflupyrolimet + SX, thaxtomin A + SX, thenylchlor + SX, thiazopyr + SX, thidiazimin + SX, thiencarbazone + SX, thiencarbazone-methyl + SX, thifensulfuron + SX, thifensulfuron-methyl + SX, tiafenacil + SX, tiocarbazil + SX, tolpyralate + SX, Topramezone + SX, Toxapyzone + SX, Tralkoxydim + SX, Triafamone + SX, Tri-allate + SX,Triasulfuron + SX, Triaziflam + SX, Tribenuron + SX, Tribenuron-methyl + SX, Triclopyr + SX, Triclopyr-butotyl + SX, Triclopyr-ethyl + SX, Triclopyr-triethylammonium + SX, Tridiphane + SX, Trietazine + SX, Trifloxysulfuron + SX, Trifloxysulfuron-sodium + SX, Trifludimoxazin + SX, Trifluralin + SX, Triflusulfuron + SX, Triflusulfuron-methyl + SX, Tripyrasulfone + SX, Tritosulfuron + SX, Vernolate + SX, 4-(4-fluorophenyl)-6-[(2-hydroxy-6-oxo-1-cyclohexen-1-yl)carbonyl]-2-methyl-1,2,4-triazine-3,5(2H,4H)-dione + SX, 2-chloro-N-(1-methyl-1H-tetrazol-5-yl)-3-(methylthio)-4-(trifluoromethyl)benzamide + SX, 2-methyl-N-(5-methyl-1,3,4-oxadiazol-2-yl)-3-(methanesulfonyl)-4-(trifluoromethyl)benzamide + SX, 1-{2-chloro-6-[(5-chloropyrimidin-2-yl)oxy]phenyl}-4,4,4-trifluorobutan-1-one (2052297-97-7) + SX. ,
[0049] Combinations of the component in group (j) above and the compound in question:
[0050] Subgroup (j-1): Combinations of the bacterial component and this compound: Acidovax wautersii + SX, Agrobacterium radiobacter strain K1026 + SX, Agrobacterium radiobacter strain K84 + SX, Agrobacterium vitis strain VAR03-1 + SX, Arthrobacter globiformis + SX, Arthrobacter globiformis + Erwinia gerundensis + SX, Azorhizobium spp. + SX, Azorhizobium caulinodans strain ZB-SK-5 + SX, Azospirillum amazonense + SX, Azospirillum brasilense + SX, Azospirillum brasilense strain XOH + SX, Azospirillum brasilense strain Ab-V5 + SX, Azospirillum brasilense strain Ab-V6 + SX, Azospirillum caulinodans + SX, Azospirillum halopraeferens + SX, Azospirillum irakense + SX, Azospirillum lipoferum + SX, Azotobacter + SX,Azotobacter chroococcum + SX, Azotobacter chroococcum strain H23 + SX, Azotobacter salinestris strain CECT9690 + SX, Azotobacter vinelandii strain ATCC12837 + SX, Bacillus acidocaldarius + SX, Bacillus acidoterrestris + SX, Bacillus agri + SX, Bacillus albolactis + SX, Bacillus alcalophilus + SX, Bacillus alvei + SX, Bacillus aminoglucosidicus + SX, Bacillus aminovorans + SX, Bacillus amyloliquefaciens strain PTA-4838 (Aveo (trademark) EZ nematicide) + SX, Bacillus amyloliquefaciens strain AH2 + SX, Bacillus amyloliquefaciens strain AT79 + SX, Bacillus amyloliquefaciens strain AT332 + SX, Bacillus amyloliquefaciens strain B3 + SX,Bacillus amyloliquefaciens strain BV03 + SX, Bacillus amyloliquefaciens strain CECT7657 + SX, Bacillus amyloliquefaciens strain D203 + SX, Bacillus amyloliquefaciens strain D747 + SX, Bacillus amyloliquefaciens strain DB101 + SX, Bacillus amyloliquefaciens strain DB102 + SX, Bacillus amyloliquefaciens strain ENV503 + SX, Bacillus amyloliquefaciens strain F727 + SX, Bacillus amyloliquefaciens strain FZB24 + SX, Bacillus amyloliquefaciens strain FZB42 + SX, Bacillus amyloliquefaciens strain GB03 + SX, Bacillus amyloliquefaciens strain IN937a + SX, Bacillus amyloliquefaciens strain IT-45 + SX, Bacillus amyloliquefaciens strain MBI600 + SX,Bacillus amyloliquefaciens strain R6-CDX + SX, Bacillus amyloliquefaciens isolate strain B246 + SX, Bacillus amyloliquefaciens subsp. Plantarum strain D747 + SX, Bacillus amylolyticus + SX, Bacillus aneurinolyticus + SX, Bacillus atrophaeus + SX, Bacillus atrophaeus strain Abi05 + SX, Bacillus azotoformans + SX, Bacillus badius + SX, Bacillus cereus strain Ar56 + SX, Bacillus cereus strain B4 + SX, Bacillus cereus strain BP01 + SX, Bacillus cereus strain bromelia + SX, Bacillus cereus strain CIL + SX, Bacillus cereus CNCM strain I-1562 + SX, Bacillus cereus DGA34 Bacillus cereus strain DGA34) + SX, Bacillus cereus strain N6 + SX, Bacillus cereus strain N7 + SX,Bacillus cereus strain peumo + SX, Bacillus cereus strain UW85 + SX, Bacillus chitinosporus strain AQ746 + SX, Bacillus chitinosporus strain CM-1 + SX, Bacillus circulans + SX, Bacillus coagulans strain TQ33 + SX, Bacillus fastidiosus + SX, Bacillus firmus strain GB-126 + SX, Bacillus firmus strain I-1582 + SX, Bacillus firmus strain NCIM2637 + SX, Bacillus lacticola + SX, Bacillus lactimorbus + SX, Bacillus lactis + SX, Bacillus lautus + SX, Bacillus lentimorbus + SX, Bacillus lentus + SX, Bacillus licheniformis strain copihue + SX, Bacillus licheniformis strain B000106 (Bacillus Bacillus licheniformis strain B000106) + SX, Bacillus licheniformis strain DSM17236 + SX,Bacillus licheniformis strain FMCH001 + SX, Bacillus licheniformis strain HB-2 + SX, Bacillus licheniformis strain SB3086 + SX, Bacillus maroccanus + SX, Bacillus medusa + SX, Bacillus megaterium strain ATCC10778 + SX, Bacillus megaterium strain NCIM2087 + SX, Bacillus megaterium strain YFM3.25 (Bacillus megaterium strain YFM3.25) + SX, Bacillus methylotrophicus strain BAC-9912 + SX, Bacillus methylotrophicus strain C1 + SX, Bacillus methylotrophicus isolate UFPEDA20 + SX, Bacillus metiens + SX, Bacillus mojavensis strain R3B + SX, Bacillus mojavensis strain SR11 + SX, Bacillus mycoides strain AQ726 + SX, Bacillus mycoides isolate J + SX, Bacillus nematocida + SX, Bacillus nigrificans + SX,Bacillus nigrum + SX, Bacillus popilliae + SX, Bacillus psychrosaccharolyticus + SX, Bacillus pumilus strain AQ717 + SX, Bacillus pumilus strain BUF-33 + SX, Bacillus pumilus strain CCTB05 + SX, Bacillus pumilus strain GB34 + SX, Bacillus pumilus strain QST2808 + SX, Bacillus safensis strain HCX-01 + SX, Bacillus siamensis strain KCTC 13613 + SX, Bacillus simplex strain CGF2856 + SX, Bacillus smithii + SX, Bacillus sp. AQ175 strain + SX, Bacillus sp. AQ177 strain + SX, Bacillus sp. AQ178 strain + SX, Bacillus sphaericus strain 2362 antigen type H5a5b 2362 serotype H5a5b) + SX, Bacillus sphaericus strain ABTS1743 + SX, Bacillus subtilis strain AFS032321 + SX, Bacillus subtilis strain antumavida + SX, Bacillus subtilis strain AP-01 + SX, Bacillus subtilis strain AQ153 + SX, Bacillus subtilis strain AQ743 + SX, Bacillus subtilis strain B246 + SX, Bacillus subtilis strain BU1814 + SX, Bacillus subtilis strain BV02 + SX, Bacillus subtilis strain BV09 + SX, Bacillus subtilis strain C-3102 + SX, Bacillus subtilis strain CCTB04 + SX, Bacillus subtilis strain CX-9060 + SX, Bacillus subtilis strain D747 + SX, Bacillus subtilis strain DB101 + SX, Bacillus subtilis strain DB102 + SX, Bacillus subtilis strain FMCH002 + SXBacillus subtilis strain FZB24 + SX, Bacillus subtilis strain GB03 + SX, Bacillus subtilis strain HAI0404 + SX, Bacillus subtilis strain IAB / BS03 + SX, Bacillus subtilis strain MBI600 + SX, Bacillus subtilis strain DSM17231 + SX, Bacillus subtilis strain N5 + SX, Bacillus subtilis strain NCIM2063 + SX, Bacillus subtilis strain NCIM8872 + SX, Bacillus subtilis strain NSRS89-24 + SX, Bacillus subtilis strain PAH17 + SX, Bacillus subtilis strain QST30002 / AQ30002 + SX, Bacillus subtilis strain QST30004 / AQ30004 + SX, Bacillus subtilis strain QST713 + SX, Bacillus subtilis strain QST714 + SX, Bacillus subtilis strain RTI477 + SX,Bacillus subtilis strain S1 + SX, Bacillus subtilis strain S2 + SX, Bacillus subtilis strain SEIBS23 + SX, Bacillus subtilis strain UFPEDA764 + SX, Bacillus subtilis strain Y1336 + SX, Bacillus subtilis strain YL13 + SX, Bacillus subtilis subsp. natto + SX Bacillus subtilis var. Amyloliquefaciens strain FZB24 + SX, Bacillus tequilensis strain 10b + SX, Bacillus tequilensis strain NII-0943 + SX, Bacillus thuringiensis strain 4042 + SX, Bacillus thuringiensis strain anemophila + SX, Bacillus thuringiensis strain AQ52 + SX, Bacillus thuringiensis strain BD#32 Bacillus thuringiensis strain BD#32) + SX, Bacillus thuringiensis strain CR-371 + SX, Bacillus thuringiensis strain EX297512 + SX,Bacillus thuringiensis subsp. aizawai strain ABTS-1857 + SX, Bacillus thuringiensis subsp. aizawai strain GC-91 + SX, Bacillus thuringiensis subsp. aizawai strain NB200 + SX, Bacillus thuringiensis subsp. aizawai Serotype H-7 + SX, Bacillus thuringiensis subsp. galleriae strain SDS-502 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 + SX, Bacillus thuringiensis subsp. israelensis strain AM65-52 serotype H-14 + SX, Bacillus thuringiensis subsp. israelensis strain BMP144 + SX, Bacillus thuringiensis subsp. israelensis strain D142 + SX, Bacillus thuringiensis subsp. israelensis strain EG2215 + SX,Bacillus thuringiensis subsp. israelensis strain SA3A + SX, Bacillus thuringiensis subsp. israelensis strain SUM-6218 + SX, Bacillus thuringiensis subsp. israelensis strain VCRC B17 serotype 11-14 + SX, Bacillus thuringiensis subsp. japonensis + SX, Bacillus thuringiensis subsp. crylA delta endotoxins Kurstaki (CrylA delta endotoxins) + SX, Bacillus thuringiensis subsp. Kurstaki (CrylC delta endotoxins) + SX, Bacillus thuringiensis subsp. Kurstaki strain 3A3B + SX, Bacillus thuringiensis subsp. Kurstaki strain ABTS351 + SX, Bacillus thuringiensis subsp. Kurstaki strain BMP123 + SX, Bacillus thuringiensis subsp. Kurstaki strain CCT1306 (Bacillus thuringiensis subsp. Kurstaki strain CCT1306) + SX,Bacillus thuringiensis subsp. Kurstaki strain EG2348 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2371 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG2424 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7673 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7826 + SX, Bacillus thuringiensis subsp. Kurstaki strain EG7841 + SX, Bacillus thuringiensis subsp. Kurstaki strain EVB113-19 + SX, Bacillus thuringiensis subsp. Kurstaki strain F810 + SX, Bacillus thuringiensis subsp. Kurstaki strain HD-1 + SX, Bacillus thuringiensis subsp. Kurstaki strain M-200 + SX, Bacillus thuringiensis subsp. Kurstaki strain NCIM2514 + SX, Bacillus thuringiensis subsp. Kurstaki strain PB54 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-11 + SX, Bacillus thuringiensis subsp. Kurstaki strain SA-12 + SX, Bacillus thuringiensis subsp. Kurstaki strain VBTS-2546 + SX, Bacillus thuringiensis subsp. Kurstaki strain Z-52, serotype H-3a,3b + SX, Bacillus thuringiensis subsp. morrisoni + SX, Bacillus thuringiensis subsp. tenebriosis strain NB 176 + SX, Bacillus thuringiensis subsp. tenebriosis strain SA-10 + SX, Bacillus thuringiensis subsp. thuringiensis strain MPPL002 MPPL002) + SX, Bacillus thuringiensis subsp. var. colmeri + SX,Bacillus thuringiensis subsp. var. darmstadiensis strain 24-91 + SX, Bacillus thuringiensis subsp. var. dendrolimus + SX, Bacillus thuringiensis subsp. var. galleriae + SX, Bacillus thuringiensis subsp. var. japonensis strain buibui + SX, Bacillus thuringiensis subsp. var. aegypti + SX, Bacillus thuringiensis var. 7216 + SX, Bacillus thuringiensis var. sandiego strain M-7 + SX, Bacillus thuringiensis var. T36 + SX, Bacillus velezensis + SX, Bacillus velezensis isolate CNPSo3602 + SX, Bacillus velezensis strain ABi19 + SX, Bacillus velezensis strain FZB42 + SX, Bacillus velezensis strain FZB45 + SX, Bacillus velezensis strain NRRL B-41580 + SX,Bacillus velezensis strain RTI301 + SX, Bradyrhizobium spp. + SX, Bradyrhizobium elkanii + SX, Bradyrhizobium elkanii strain SEMIA 587 + SX, Bradyrhizobium elkanii strain SEMIA 5019 + SX, Bradyrhizobium japonicum + SX, Bradyrhizobium japonicum strain TA-11 + SX, Bradyrhizobium japonicum strain USDA 110 + SX, Bradyrhizobium japonicum strain WB74 + SX, Bradyrhizobium liaoningense + SX, Bradyrhizobium lupini + SX, Bradyrhizobium lupini strain LL13 + SX, Bradyrhizobium spp. (Arachis) + SX, Bradyrhizobium spp. (Vigna) + SX, Brevibacillus brevis strain maguellines I + SX, Brevibacillus brevis strain 2904 + SX, Brevibacillus brevis strain SS86-3 + SX,Brevibacillus brevis strain SS86-4 + SX, Brevibacillus brevis strain SS86-5 + SX, Brevibacillus laterosporus strain ATCC64 + SX, Brevibacillus laterosporus strain BPM3 + SX, Brevibacillus laterosporus strain G4 + SX, Brevibacillus laterosporus strain NCIMB 41419 + SX, Brevibacillus laterosporus strain NRS1111 + SX, Brevibacillus laterosporus strain NRS1645 + SX, Brevibacillus laterosporus strain NRS1647 + SX, Burkholderia ambifaria strain AMMD + SX, Burkholderia cenocepacia strain A396 + SX, Burkholderia cenocepacia strain Ral-3 + SX, Burkholderia cepacia type Wisconsin strain J82 + SX, Burkholderia cepacia type Wisconsin strain M54 + SX,Burkholderia cepacia + SX, Burkholderia gladii strain BA-7 + SX, Burkholderia rinojensis strain A396 + SX, Chromobacterium subtsugae strain PRAA4-1T + SX, Corynebacterium flavescens strain B2575 + SX, Corynebacterium glutamicum + SX, Delftia acidovorans + SX, Delftia acidovorans strain RAY209 (Delftia acidovorans strain RAY209) + SX, Erwinia carotovora subsp. carotovora strain CGE234M403 + SX, Erwinia gerundensis + SX, Gluconacetobacter diazotrophicus strain IMI504853 + SX, Klebsiella variicola 137 + SX, Kosakonia cowanii strain SYM00028 + SX, Lactobacillus acidophilus + SX, Lactobacillus brevis + SX, Lactobacillus casei strain LPT-111 + SX, Lactobacillus plantarum + SX,Lactobacillus spp. + SX, Lysobacter antibioticus strain 13-1 + SX, Lysobacter enzymogenes strain B25 + SX, Lysobacter enzymogenes strain C3 + SX, Metylobacterium spp. + SX, Methylobacterium isolate ISO01 + SX, Methylobacterium isolate ISO02 + SX, Methylobacterium isolate ISO03 + SX, Methylobacterium isolate ISO04 + SX, Methylobacterium isolate ISO07 + SX, Methylobacterium isolate ISO09 + SX, Methylobacterium isolate ISO10 + SX, Methylobacterium isolate ISO11 + SX, Methylobacterium symbioticum + SX, Mesorhizobium spp. + SX, Mesorhizobium ciceri + SX, Mesorhizobium fuwakui huakii) + SX, Mesorhizobium loti + SX, Paenibacillus alvei strain 2771 + SX,Paenibacillus alvei strain 46C3 + SX, Paenibacillus alvei strain III2E + SX, Paenibacillus alvei strain III3DT-1A + SX, Paenibacillus alvei strain T36 + SX, Paenibacillus macerans + SX, Paenibacillus polymyxa strain AC-1 + SX, Paenibacillus polymyxa strain BS-0105 + SX, Paenibacillus polymyxa strain H-5 + SX, Paenibacillus popilliae + SX, Pantoea agglomerans strain E325 + SX, Pantoea vagans strain C9-1 + SX, Pasteuria nishizawae strain Pn1 + SX, Pasteuria penetrans + SX, Pasteuria ramose + SX, Pasteuria usgae + SX, Pectobacterium carotovorum + SX, Pasteuria thornei + SX, Pseudomonas aeruginosa strain PN1 + SX, Pseudomonas aeruginosa strain WS-1 + SX, Pseudomonas aureofaciens strain TX-1 TX-1) + SX, Pseudomonas alcaligenes + SX, Pseudomonas cepacia type Wisconsin strain J82 + SX,Pseudomonas cepacia type Wisconsin strain M54 + SX, Pseudomonas chlororaphis strain 63-28 + SX, Pseudomonas chlororaphis strain AFS009 + SX, Pseudomonas chlororaphis strain MA342 + SX, Pseudomonas entomophilla strain 1257 + SX, Pseudomonas fluorescens isolate Pf-5 + SX, Pseudomonas fluorescens strain 1629RS + SX, Pseudomonas fluorescens strain A506 + SX, Pseudomonas fluorescens strain ACK55 + SX, Pseudomonas fluorescens strain CL145A + SX, Pseudomonas fluorescens strain D7 + SX, Pseudomonas fluorescens strain G7090 + SX, Pseudomonas fluorescens biover B XJ3 (Pseudomonas fluorescens biover B strain XJ3) + SX, Pseudomonas fluorescens biover B strain XS18 + SX,Pseudomonas fluorescens biover A strain LRS12 + SX, Pseudomonas proradix + SX, Pseudomonas putida strain CECT8538 + SX, Pseudomonas reactans + SX, Pseudomonas resinovorans + SX, Pseudomonas rhodesiae strain HAI-0804 + SX, Pseudomonas sp. strain CAB-02 + SX, Pseudomonas sp. DSMZ13134 strain sp. strain DSMZ13134) + SX, Pseudomonas syringae strain 742RS + SX, Pseudomonas syringae strain ESC-10 + SX, Pseudomonas syringae strain ESC-11 + SX, Pseudomonas syringae strain MA-4 + SX, Pseudomonas trivialis + SX, Rhizobium etli + SX, Rhizobium galegae + SX, Rhizobium regminosalm bv. Phaseoli (Rhizobium leguminosarum bv. Phaseoli) + SX, Rhizobium leguminosarum bv. Trifolii (Rhizobium leguminosarum bv. Trifolii) + SX,Rhizobium leguminosarum bv. Viciae + SX, Rhizobium trifolii + SX, Rhizobium tropici + SX, Rhodococcus globerulus strain AQ719 + SX, Saccharopolyspora spinosa + SX, Serratia entomophila strain 626 + SX, Serratia marcescens strain 35 + SX, Serratia marcescens strain SRM + SX, Serratia nematodiphila strain S-CSR-0024 + SX, Sphingobacterium nematocida strain ZY-71-1 + SX, Sinorhizobium fredii + SX, Sinorhizobium meliloti + SX, Streptomyces acidiscabies strain RL-110T + SX, Streptomyces candidus strain Y21007-2 + SX, Streptomyces colombiensis + SX, Streptomyces galbus strain QST6047 + SX, Streptomyces globosus strain LZH-48 + SX,Streptomyces goshikiensis + SX, Streptomyces griseofuscus strain 200101 + SX, Streptomyces griseoviridis strain K61 + SX, Streptomyces jalisciencis isolate CM-CNRG0001 + SX, Streptomyces jofer isolate CM-CNRG0002 + SX, Streptomyces lavendulae + SX, Streptomyces lydicus strain WYCD108US + SX, Streptomyces lydicus strain WYEC108 + SX, Streptomyces microflavus strain AQ6121 + SX, Streptomyces prasinus + SX, Streptomyces rimosus + SX, Streptomyces saraceticus + SX, Streptomyces sp. NRRL No. B-30145 + SX, Streptomyces sp. strain WYE20 + SX, Streptomyces sp. strain WYE 324 + SX, Streptomyces venezuelae + SX,Thiobacillus spp. + SX, Variovorax paradoxus strain GF4526 + SX, Virgibacillus pantothenticus strain ATCC14576 + SX, Virgibacillus pantothenticus strain DSM491 + SX, Wolbachia pipientis + SX, Xanthomonas campestris pv poae + SX, Xanthomonas campestris + SX, Xenorhabdus luminescens + SX, Xenorhabdus nematophila + SX.
[0051] Subgroup (j-2): Combinations of the main component of fungi and yeast with this compound. Acaulospora spp. + SX, Acaulospora longula + SX, Alternaria destruens + SX, Alternaria destruens strain 59 + SX, Ambispora spp. + SX, Ambispora leptoticha + SX, Ampelomyces quisqualis strain AQ10 + SX, Ampelomyces quisqualis strain RSAQ7690 + SX, Ampelomyces quisqualis strain M-10 + SX, Archaeospora spp. + SX, Arkansas Fungus 18 + SX, Arthrobotrys dactyloides + SX, Arthrobotrys superba + SX, Aschersonia aleyrodis + SX, Aspergillus flavus strain AF36 + SX, Aspergillus flavus strain MUCL54911 + SX, Aspergillus flavus strain NRRL21882 + SX, Aureobasidium pullulans strain DSM14940 + SX, Aureobasidium pullulans strain DSM14941 + SX,Aureobasidium pullulans strain YBCA5 + SX, Beauveria bassiana isolate B21 + SX, Beauveria bassiana isolate B33 + SX, Beauveria bassiana isolate CBMAI1306 + SX, Beauveria bassiana strain 147 + SX, Beauveria bassiana strain 203 + SX, Beauveria bassiana strain 447 + SX, Beauveria bassiana strain ANT-03 ANT-03) + SX, Beauveria bassiana strain ATCC74040 + SX, Beauveria bassiana strain ATP02 + SX, Beauveria bassiana strain CFL-A + SX, Beauveria bassiana strain CG716 + SX, Beauveria bassiana strain ESALQ PL63 + SX, Beauveria bassiana strain GHA + SX, Beauveria bassiana strain HF23 + SX, Beauveria bassiana strain IBCB66 + SX, Beauveria bassiana strain IMI389521 + SX,Beauveria bassiana strain J25 + SX, Beauveria bassiana strain NCIM1216 ATCC26851 + SX, Beauveria bassiana strain NPP111B005 + SX, Beauveria bassiana strain PL63 + SX, Beauveria bassiana strain PPRI 5339 + SX, Beauveria bassiana strain R444 + SX, Beauveria bassiana strain ZJU435 ZJU435) + SX, Beauveria brongniartii + SX, Beauveria brongniartii isolate IMBST95.031 + SX, Beauveria brongniartii isolate IMBST95.041 + SX, Candida oleophila strain O + SX, Candida oleophila isolate I-182 + SX, Candida saitoana + SX, Candida spp. + SX, Cell walls of Saccharomyces cerevisiae strain LAS117 + SX, Chaetomium cupreum + SX, Chlorella + SX, Chondrostereum purpureum + SX,Cladosporium cladosporioides strain H39 + SX, Claroideoglomus spp. (formerly Glomus spp.) + SX, Claroideoglomus claroideum (formerly Glomus claroideum) + SX, Claroideoglomus etunicatum (formerly Glomus etunicatum) + SX, Claroideoglomus luteum + SX, Clonostachys rosea strain ACM941 + SX, Clonostachys rosea strain CR-7 CR-7) + SX, Clonostachys rosea strain IDAC 040913-01 + SX, Clonostachys rosea strain J1446 + SX, Colletotrichum gloeosporioides + SX, Conidiobolus obscurus + SX, Conidiobolus thromboide + SX, Coniothyrium minitans strain CGMCC8325 + SX, Coniothyrium minitans strain CON / M / 91-08 CON / M / 91-08) + SX, Cryphonectria parasitica + SX, Cryptococcus albidus + SX,Cryptococcus flavescens + SX, Cylindrobasidium laeve + SX, Dactyllela ellipsospora + SX, Dectilaria thaumasia + SX, Dilophosphora alopecuri + SX, Diversispora spp. + SX, Enterococcus faecium + SX, Entomophthora virulenta + SX, Entrophospora spp. + SX, Entyloma agerachinae ageratinae) + SX, Epicoccum nigrum + SX, Funneliformis spp. (formerly Glomus spp.) + SX, Funneliformis mosseae (formerly Glomus mosseae) + SX, Fusarium oxysporum strain Fo47 + SX, Fusarium oxysporum strain RS-21 + SX, Fusarium oxysporum strain RS-25 + SX, Fusarium proliferatum strain NCIM1101 + SX, Geosiphon species + SX, Gigaspora species + SX, Gigaspora margarita + SX, Gigaspora rosea + SX,Gliocladium catenulatum strain J1446 + SX, Gliocladium roseum + SX, Gliocladium virens strain GL-21 + SX, Glomus spp. + SX, Glomus aggregatum + SX, Glomus deserticola + SX, Glomus etunicatum + SX, Glomus iranicum + SX, Glomus monosporum + SX, Hirsutella minesotensis minnesotensis) + SX, Hirsutella rhossiliensis + SX, Hirsutella thompsonii + SX, Isaria fumosorosea isolate B3 + SX, Isaria fumosorosea strain Isfm-CPF + SX, Isaria tenuipes + SX, Laccaria bicolor + SX, Laccaria laccata + SX, Lagenidium giganteum + SX, Lecanicillium lecanii KV01 + SX, Conidia of strain DAOM198499 + SX, conidia of strain DAOM216596 + SX,Lecanicillium muscarium (formerly Verticillium lecanii) strain 1 / 1 + SX, Lecanicillium muscarium Ve6 strain (formerly Verticillium lecanii) strain Ve6 + SX, Metarhizium anisopliae isolate D1 + SX, Metarhizium anisopliae isolate IBCB425 + SX, Metarhizium anisopliae strain CQMa421 + SX, Metarhizium anisopliae strain ESALQ E9 + SX, Metarhizium anisopliae strain ESF1 + SX, Metarhizium anisopliae strain F52 + SX, Metarhizium anisopliae strain FI-985 (Metarhizium Metarhizium anisopliae strain FI-985) + SX, Metarhizium anisopliae strain FI-1045 + SX, Metarhizium anisopliae strain ICIPE30 + SX, Metarhizium anisopliae strain ICIPE62 + SX, Metarhizium anisopliae strain ICIPE69 + SX, Metarhizium anisopliae strain ICIPE78 + SX, Metarhizium anisopliae strain NCIM1311 (Metarhizium anisopliae strain NCIM1311) + SX, Metarhizium anisopliae var. acridum strain EVCH077 + SX,Metarhizium anisopliae var. acridum isolate IMI 330189 + SX, Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52 + SX, Metarhizium brunneum strain Cb15-III + SX, Metarhizium flavoviride strain F001 + SX, Metarhizium rileyi strain PHP1705 + SX, Metschnikowia fructicola strain NRRLY-27328 + SX, Metschnikowia fructicola strain NRRLY-30752 + SX, Microdochium dimerum strain L13 + SX, Microsphaeropsis ochracea + SX, Monacrosporium phymatopagum + SX, Mucor hiemalis + SX, Muscodor albus strain 620 + SX, Muscodor albus QST 20799 strain (Muscodor albus strain QST 20799) + SX, Muscodor albus strain SA13 + SX, Muscodor roseus strain A3-5 + SX,Myrothecium verrucaria strain AARC-0255 + SX, Nomuraea rileyi strain CG128 + SX, Nomuraea rileyi strain GU87401 + SX, Nomuraea rileyi strain SA86101 + SX, Nomuraea rileyi strain SR86151 + SX, Nomuraea rileyi strain VA9101 + SX, Ophiostoma piliferum strain D97 + SX, Pacispora spp. + SX, Paecilomyces fumosoroseus Apopka strain 97 (now known as Isaria fumosorosea Apopka strain 97) + SX, Paecilomyces fumosoroseus strain FE9901 (now known as Isaria fumosorosea strain FE9901) + SX, Paecilomyces lilacinus strain 251 + SX, Paecilomyces tenuipes strain 1 T1) + SX, Paecilomyces variotii strain Q-09 + SX, Pandora delphacis + SX, Paraglomus spp. + SX,Paraglomus brasilianum (formerly Glomus brasilianum) + SX, Penicillium bilaiae strain ATCC22348 + SX, Penicillium citrinum strain VFI-51 + SX, Penicillium vermiculatum + SX, Phlebiopsis gigantea strain FOC PG410.3 + SX, Phlebiopsis gigantea strain VRA1835 + SX, Phlebiopsis gigantea strain VRA1984 + SX, Phlebiopsis gigantea strain VRA1985 + SX, Phlebiopsis gigantea strain VRA1986 + SX, Phlebiopsis gigantea strain VRA1992 + SX, Phlebiopsis spp. + SX, Phoma macrostroma strain 94-44B + SX, Phytophthora palmivora + SX, Pichia anomala strain WRL-076 + SX, Pichia guilliermondii strain Z1 + SX, Pichia guilliermondii strain Z8 + SX, Pisolithus tinctorius + SXPochonia chlamydosporia isolate strain PC10 + SX, Pochonia chlamydosporia + SX, Pseudozyma flocculosa strain ATTC64874 + SX, Pseudozyma flocculosa strain PF-A22UL + SX, Puccinia thlaspeos strain woad + SX, Purpureocillium lilacinum strain 251 + SX, Purpureocillium lilacinum strain PL11 PL11) + SX, Pythium oligandrum strain DV74 + SX, Pythium oligandrum strain M1 + SX, Racocetra spp. + SX, Rhizophagus spp. (formerly Glomus spp.) + SX, Rhizophagus clarus (formerly Glomus clarum) + SX, Rhizophagus intraradices (formerly Glomus intraradices) + SX, Rhizophagus intraradices strain RTI-801 + SX, Rhizophagus irregularis irregularis (formerly Glomus intraradices) + SX, Rhizophagus irregularis strain DAOM 197198 + SX,Scutellospora species + SX, Rhizopogon amylopogon + SX, Rhizopogon fulvigleba + SX, Rhizopogon luteolus + SX, Rhizopogon villosullus + SX, Saccharomyces cerevisiae strain LAS02 + SX, Saccharomyces cerevisiae strain DDSF623 + SX, Saccharomyces cerevisiae strain SP.1026 + SX, Scleoderma cepa + SX, Scleoderma citrinum + SX, Sclerotinia minor strain IMI34414 + SX, Sporothrix insectorum + SX, Suillus granulatus + SX, Suillus punctatapies + SX, Talaromyces flavus strain SAY-Y-94-01 + SX, Talaromyces flavus strain V117b + SX, Trichoderma afrohardianum afroharzianum) + SX, Trichoderma album + SX, Trichoderma asperelloides strain JM41R + SX,Trichoderma asperellum strain CBMAI840 + SX, Trichoderma asperellum strain CBMAI1622 + SX, Trichoderma asperellum strain BV09 + SX, Trichoderma asperellum strain BV10 + SX, Trichoderma asperellum strain ICC012 + SX, Trichoderma asperellum strain kd + SX, Trichoderma asperellum strain M103 + SX, Trichoderma asperellum strain RNCIM F-1323 + SX, Trichoderma asperellum T11 + SX, Trichoderma asperellum T25 + SX, Trichoderma asperellum strain T34 + SX, Trichoderma asperellum strain SKT-1 + SX, Trichoderma asperellum strain TV1 + SX, Trichoderma atroviride strain 77B + SX, Trichoderma atroviride strain CNCM 1-1237 + SX, Trichoderma atroviride strain I-1237 + SX, Trichoderma atroviride strain IMI 206040 + SX, Trichoderma atroviride strain K4 + SX, Trichoderma atroviride strain LC52 + SX, Trichoderma atroviride LU132 strain (Trichoderma atroviride strain LU132) + SX, Trichoderma atroviride SC1 strain + SX, Trichoderma atroviride SKT-1 strain + SX, Trichoderma atroviride T11 strain + SX, Trichoderma atroviride TV1 strain + SX, Trichoderma atroviride WW10TC4 strain + SX, Trichoderma gamsii strain ICC080 strain + SX, Trichoderma harmatum strain 382 + SX, Trichoderma harmatum strain TH382 + SX, Trichoderma harzianum strain 21 + SX,Trichoderma harzianum strain AP-001 + SX, Trichoderma harzianum strain BK-Th001 + SX, Trichoderma harzianum strain CBS101525 + SX, Trichoderma harzianum strain DB 104 + SX, Trichoderma harzianum strain DSM 14944 + SX, Trichoderma harzianum strain ESALQ-1303 + SX Trichoderma harzianum strain ESALQ-1306 + SX, Trichoderma harzianum strain F11Bab + SX, Trichoderma harzianum strain Gomorteka + SX, Trichoderma harzianum strain IB19 / 17 + SX, Trichoderma harzianum strain IBLF006 + SX, Trichoderma harzianum strain IIHR-Th-2 + SX Trichoderma harzianum strain ITEM908 + SX, Trichoderma harzianum strain K2 + SX, Trichoderma harzianum strain kd + SXTrichoderma harzianum strain KRL-AG2 + SX, Trichoderma harzianum strain MO1 + SX, Trichoderma harzianum strain queule + SX, Trichoderma harzianum strain RR17Bc + SX, Trichoderma harzianum strain SF + SX, Trichoderma harzianum strain T5 + SX, Trichoderma harzianum strain T22 + SX, Trichoderma harzianum strain T24 (Trichoderma Trichoderma harzianum strain T24) + SX, Trichoderma harzianum strain T39 + SX, Trichoderma harzianum strain T78 + SX, Trichoderma harzianum strain TH35 + SX, Trichoderma harzianum strain TH315 + SX, Trichoderma harzianum rifai + SX, Trichoderma koningii + SX, Trichoderma lignorum strain TL-0601 + SX, Trichoderma lignorum + SX, Trichoderma longibrachiatum strain T-397 + SX,Trichoderma polysporum strain IMI206039 + SX, Trichoderma parceramosum + SX, Trichoderma reesei + SX, Trichoderma strain SKT-1 + SX, Trichoderma spp. + SX, Trichoderma saturnisporium strain PBP-TH-001 + SX, Trichoderma stromaticum + SX, Trichoderma virens strain chagual + SX, Trichoderma virens strain G-41 + SX, Trichoderma virens strain GL-21 (formally Gliocladium virens GL-21) + SX, Trichoderma virens strain nire + SX, Trichoderma virens strain sherwood + SX, Trichoderma viride strain (NRRL B-50520) + SX, Trichoderma viride strain K5 + SX, Trichoderma viride strain T111 + SX, Tsukamurella paurometabola strain C-924 + SX, Tsukamurella paurometabola + SX,Typhula phacorrhiza strain 94671 + SX, Ulocladium oudemansii strain HRU3 + SX, Ulocladium oudemansii strain U3 + SX, Verticillium alboatrum strain WCS850 + SX, Verticillium chlamydosporium + SX, Verticillium dahliae + SX, Verticillium lecanii strain ID05-F0117 + SX, Verticillium lecanii strain NCIM1312 + SX, Verticillium lecanii strain SZWL7 + SX, Zoohtora radicans + SX.
[0052] Subgroup (j-3): Combinations of the main component of protozoa and this compound: Nosema locustae + SX, Thelohania solenopsis + SX, Variimorpha spp. strain Q-09 + SX.
[0053] Subgroup (j-4): Combinations of the virus's main component and this compound: Adoxophyes orana GV (granulovirus) strain BV-0001 + SX, Agrotis segetum NPV (nucleopolyhedrovirus) + SX, Anagraoha falcifera NPV + SX, Anticarsia gemmatalis MNPV (multiple nucleocapsid nucleopolyhedrovirus) + SX, Autographa californica MNPV strain FV11 + SX, Autographa californica MNPV strain R3 + SX, Bacteriophage of Clavibacter michiganesis + SX, Bacteriophage active against Clavibacter michiganensis subsp. michiganensis + SX, Bacteriophage active against Erwinia amylovora + SX, Bacteriophage active against Pseudomonas syringae pv. tomato + SX, Bacteriophage active against Xanthomonas campestris pv. vesicatoria + SX, Bacteriophage active against Xanthomonas citri subsp. citri + SX, Bacteriophage against Xylella fastidiosa + SX, Biston suppressaria NPV + SX, Bombyx mori NPV + SX,Chrysodeixis includens NPV isolate 460 + SX, Cryptophlebia leucotreta GV + SX, Cydia pomonella GV + SX, Cydia pomonella GV M + SX, Cydia pomonella GV strain CP4 + SX, Cydia pomonella GV strain R5 + SX, Cydia pomonella GV strain V15 + SX, Cydia pomonella GV strain V22 + SX, Douglas fir tussock moth NPV + SX, Dendrolimus punctatus cytoplasmic polyhedron virus + SX, Ectropis obliqua picorna-like virus + SX, Helicoverpa armigera NPV + SX, Helicoverpa armigera NPV strain BV-0003 + SX, Helicoverpa zea NPV + SX, Indian meal moth granule virus GV) + SX, Leucoma salicis NPV + SX, Lymantria dispar MNPV + SX, Mamestra brassicae NPV + SX,Mamestra configurata NPV + SX, Neodiprion abietis NPV + SX, Neodiprion lecontei NPV + SX, Neodiprion sertifer NPV + SX, Orgyia pseudotsugata NPV + SX, pepino mosaic virus strain CH2 isolate 1906 + SX, pepino mosaic virus strain CH2 isolate Abp1 + SX, Pepino mosaic virus strain CH2 isolate Abp2 + SX, Pepino mosaic virus isolate VC1 + SX, Pepino mosaic virus isolate VX1 + SX, Phthorimaea operculella GV isolate DSMZ GV-0019 + SX, Pieris rapae GV + SX, Plodia interpunctella GV + SX, Plutella xylostella GV + SX Spodoptera albula MNPV + SX, Spodoptera exempta MNPV + SX,Spodoptera exigua MNPV strain BV-0004 + SX, Spodoptera frugiperda MNPV + SX, Spodoptera littoralis MNPV isolate DSMZ BV-0005 + SX, Spodoptera litura NPV + SX, Tobacco mild tobamovirus strain U2 + SX, Zucchini Yellow Mosaic Virus weak strain + SX.
[0054] Subgroup (j-5): Combination of the nematode component and this compound: Abbreviata caucasica + SX, Acuaria spp. + SX, Agamermis decaudata + SX, Allantonema spp. + SX, Amphimermis spp. + SX, Deladenus siricidicola + SX, Bovienema spp. + SX, Cameronia spp. + SX, Chitwoodiella ovofilamenta + SX, Contortylenchus spp. + SX, Culicimermis spp. + SX, Diplotoriana spp. + SX, Empidomermis spp. + SX, Filipjevimermis leipsandra + SX, Gastromermis spp. + SX, Gongylonema spp.) + SX, Gynopoecilia pseudovipara + SX, Heterorhabditis bacteriophora + SX, Heterorhabditis baujardi + SX, Heterorhabditis downesi + SX, Heterorhabditis heliothidis + SX, Heterorhabditis indica + SX, Heterorhabditis marelatus + SX, Heterorhabditis megidis + SX, Heterorhabditis zealandica (Heterorhabditis zealandica) + SX, Hexamermis spp. + SX, Hydromermis spp. + SX, Isomermis spp. + SX, Limnomermis spp. + SX, Maupasina weissi + SX, Mermis nigrescens + SX, Mesomermis spp. + SX, Neomesomermis spp. + SX, Neoparasitylenchus rugulosi + SX, Octomyomermis spp. spp.) + SX, Parasaitaphelenchus spp. + SX, Parasitorhabditis spp. + SX, Parasaitylenchus spp.) + SX, Perutilimermis culicis + SX, Phasmarhabditis hermaphrodita isolate DDT M1 + SX, Physaloptera spp. + SX, Protrellatus spp. + SX, Pterygodermatites spp. + SX, Romanomermis spp. + SX, Seuratum cadarachense + SX, Sphaerulariopsis spp. + SX, Spirura guianensis + SX, Steinernema bibionis + SX, Steinernema carpocapsae + SX, Steinernema feltiae isolate DDT D2 + SX, Steinernema glaseri + SX, Steinernema indica + SX, Steinernema kraussei + SX, Steinernema riobrave + SX, Steinernema scapterisci + SX, Steinernema scarabaei + SX, Steinernema siamkayai + SX, Steinernema thailandse + SX, Steinernema spp.) + SX, Strelkovimermis peterseni + SX, Subulura spp. + SX, Sulphuretylenchus elongatus + SX, Tetrameres spp. + SX.
[0055] Subgroup (j-6): Combinations of the main component of the natural product and this compound: (2S,3R,4R,5S)-2,5-bis(hydroxymethyl)pyrrolidine-3,4-diol + SX, 1,4-dimethylnaphthalene + SX, 2-methyl-1-butanol + SX, 2-phenylethyl propionate + SX, 9,21-didehydroryanodine + SX, alizarin 2-glucoside + SX, dihydroazadirachtin + SX, ethyl 3-[acetyl(butyl)amino]propanoate + SX, glycerol monocaprate + SX, glycerol monocaprylate + SX, glycerol monolaurate + SX, heptyl butyrate + SX, methyl anthranilate + SX, methyl nonyl ketone + SX, methyl Salicylate + SX, N-(3-methyl-2-buten-1-yl)-9H-purin-6-amine + SX, N,N'-diformylurea + SX, octanal + SX, oxypurinol + SX, p-cymene + SX, p-menthane-3,8-diol + SX, phenazine-1-carboxylic acid + SX, propylene glycol monocaprylate + SX, propylene glycol monolaurate + SX, sorbitol octanoate + SX, sucrose octanoate + SX, terpinen-4-ol + SX, balsam fir oil (Abies balsamea oil) + SX, α-ionone + SX, β-citronellol + SX, gamma-Terpinene + SX, ammonium bicarbonate + SX, anabasine + SX, anise oil + SX,Ascaridole + SX, Azadirachtin + SX, Bark of Celastrus angulatus + SX, Brassica juncea + SX, Brassinolide + SX, Cry1Ab protein from Bacillus thuringiensis + SX, Cry1Ac protein from Bacillus thuringiensis + SX, Cry1Fa protein from Bacillus thuringiensis + SX, Cry1A.105 protein from Bacillus thuringiensis + SX, Bacillus Cry2Ab protein from Bacillus thuringiensis + SX, Vip3A protein from Bacillus thuringiensis + SX, mCry3A protein from Bacillus thuringiensis + SX, Cry3Ab protein from Bacillus thuringiensis + SX, Cry3Bb protein from Bacillus thuringiensis + SX,Cry34Ab1 / Cry35Ab1 protein from Bacillus thuringiensis + SX, insecticidal protein Tma12 derived from Tactaria macrodonta + SX, insecticidal protein IPD083 derived from Adiantum spp. + SX, insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa + SX, calcium acetate + SX, calcium lactate + SX, calcium polysulfide + SX, canola oil + SX, capsaicin + SX, capsicum oleoresin + SX, castor oil + SX, cedarwood oil + SX, cevadine + SX, chitin + SX, chitosan + SX, chlorophyllin + SX, chlortetracycline + SX, cinerin I + SX, cinerin II + SX, cinnamaldehyde + SX, cis-jasmone + SX, citral + SX, citric acid + SX,Citronella oil + SX, Citrus bergamia fruit oil + SX, clarified hydrophobic extract of neem oil + SX, Clove oil + SX, Collagen protein hydrolysate + SX, Colletochlorin B + SX, Concanamycin A + SX, Cottonseed oil + SX, Cytokinin + SX, Cow's milk + SX, Deguelin + SX, Diallyl sulfide + SX, d-Limonene + SX, Dried leaves of Dryopteris filix-mas + SX, Ea peptide 91398 + SX, eucalyptol + SX, black wattle extract (extract of Acacia mearnsii) + SX, Achillea fragrantissima extract (extract of Achillea fragrantissima) + SX, onion extract (extract of Allium cepa) + SX, garlic extract (extract of Allium sativum) + SX, dill extract (extract of Anethum graveolens) + SX, custard extract (extract of Annona squamosa) + SX, burdock extract (extract of Arctium lappa) + SX, wormwood extract (extract of Artemisia absinthium) + SX, jackfruit extract (extract of Artocarpus heterophyllus) + SX,Indian lilac extract (extract of Azadirachta indica) + SX, Calendula officinalis extract (extract of Calendula officinalis) + SX, Camelia sinensis extract (extract of Camelia sinensis) + SX, Capsicum annuum extract (extract of Capsicum annuum) + SX, Cassia nigricans extract (extract of Cassia nigricans) + SX, Chenopodium ambrosioides extract (extract of Chenopodium quinoa) + SX, Cinnamomum verum extract (extract of Cinnamomum verum) + SX, Butterfly bean extract (extract of Clitoria ternatea) + SX, Cotyledons of lupine plantlets ("BLAD") + SX, Daphne gunidium extract (extract of Daphne gnidium) + SX, extract of Equisetum arvense + SX, extract of Equisetum giganteum + SX, extract of Galenia africana + SX, extract of green tea + SX, extract of Liliaceae plant Liliaceae) + SX, extract of Macleaya + SX, extract of Matricaria chamomilla + SX, extract of Melaleuca alternifolia + SX, extract of Millettia pinnata + SX,Opuntia lindheimeri extract + SX, Origanum vulgare extract + SX, Piper auritum extract + SX, Pyrethrum extract, Southern red oak extract (Quercus falcata) + SX, Quillaja saponaria extract + SX, Japanese knotweed extract (Reynoutria sachalinensis) + SX, Siebold's tree extract (Rhamnus utilis) + SX, Rhus aromatica extract + SX, Rheum officinale extract + SX, Rhizophora mangle extract + SX, Rosemary extract (extract of Rosmarinus officinalis) + SX, Ruta chalepensis extract + SX, Schoenocaulon spp. seed extract + SX, Sweet lupin seed extract + SX, Swinglea glutinosa extract + SX, Symphytum officinale extract + SX, Sweet lupinseed extract + SX, Tagetes erecta extract + SX, Tansy extract + SX, Thymus vulgaris extract + SX,Nasturtium extract (Tropaeolus majus) + SX, Urtica dioica extract (Urtica dioica) + SX, Mistletoe extract (Viscum album) + SX, Yucca schidigera extract (Yucca schidigera) + SX, Fenugreek seed powder + SX, Fish oil + SX, Formic acid + SX, Geraniol + SX, Ginkgolide A + SX, Ginkgolide B + SX, Ginkgolide C + SX, Ginkgolide J + SX, Ginkgolide M + SX, Gougerotin + SX, GS-omega / kappa HXTX-Hv1a peptide + SX, Harpin protein + SX, hydrogenated castor oil + SX, hydroprene + SX, Illicium verum oil + SX, ivermectin + SX, jasmolin I + SX, jasmolin II + SX, jojoba oil + SX, Karanjin + SX, kasugamycin + SX, kinoprene + SX, laminarine + SX, L-ascorbic acid + SX, Oak leaves and bark of Quercus + SX, Lemongrass oil + SX, L-glutamic acid + SX, Linalool + SX,Linseed oil + SX, Alyssum (Lobularia maritima) + SX, Lysophosphatidylethanolamine + SX, Maltodextrin + SX, Matrine + SX, Matrine N-oxide + SX, Menthol + SX, Methoprene + SX, Milbemycin A4 + SX, Mildiomycin + SX, Natamycin + SX, Nemadectin + SX, Nepeta cataria oil + SX, Nootkatone + SX, Oil of the seeds of Chenopodium anthelminticum + SX, Orange oil + SX, Pelargonium odoratissimum oil + SX, Pellitorine + SX, Piperine + SX, Piper nigrum seed oil + SX, Polyoxin B + SX, Polyoxorim + SX, Potassium phosphonate + SX, Potassium silicate + SX, Precocene II + SX, Putrescent whole egg solids + SX, Pyrethrin I + SX, Pyrethrin II + SX, Quillaya extract + SX, Quinaminoprole + SX, Rotenone + SX, Rapeseed oil + SX, Rhamnolipid + SX, Ryanodine + SX, Rosemary oil + SX, Sabadilla + SX, Salicylic acid + SX, Sanguinarine + SX, Saponins of Chenopodium quinoa + SX, Sesame oil + SX,Soy lecithin + SX, soybean oil + SX, spinosad + SX, squamocin + SX, streptomycin + SX, sunflower oil + SX, marigold oil + SX, terpene constituents of the extract of chenopodium ambrosioides near ambrosioides (Brand name: Terpenoid blend QRD 460) + SX, thyme oil + SX, thymol + SX, trypsin modulating oostatic factor + SX, veratrine + SX, veratridine + SX, wood extract of Suriname japonica Quassia amara extract + SX, Xanthine + SX, Yellow mustard powder + SX.
[0056] Subgroup (j-7): Combinations of the insect component and this compound: Adalia bipunctata + SX, Amitus hesperidum + SX, Amitus spiniferus + SX, Anagrus atomus + SX, Anagrus epos + SX, Anagyrus fusciventris + SX, Anagyrus fusciventris + SX, Anagyrus pseudococci + SX, Anaphes flavipes + SX, Anaphes iole + SX, Anaphes nitens + SX, Anastatus tenuipes + SX, Anthocoris nemoralis + SX, Aphelinus abdominalis + SX, Aphelinus asychis + SX, Aphelinus mali + SX, Aphelinus semiflavus + SX, Aphidius colemani + SX, Aphidius ervi + SX, Aphidius gifuensis + SX, Aphidius matricariae + SX, Aphidius smithi + SX, Aphidius aphidimyza + SX, Aphytis holoxanthus + SX, Aphytis lepidosaphes + SX, Aphytis lignanensis + SX, Aphytis melinus + SX, Aphytis mytilaspidis + SX, Apion fuscirostre + SX, Apion ulicis + SX, Aprostocetus hagenowii + SX, Avetianella longoi + SX, Bangasternus orientalis + SX, Bathyplectes anurus + SX, Bathyplectes curculionis + SX, Bracon cushmani + SX,Bracon gelechiae + SX, Bracon hebetor + SX, Cales noacki + SX, Calosoma sycophanta + SX, Carcinops pumillio + SX, Catolaccus grandis + SX, Cephalonomia tarsalis + SX, Chilocorus baileyi + SX, Chilocorus bipustulatus + SX, Chilocorus circumdatus + SX, Chilocorus kuwanae + SX, Chilocorus nigritus + SX, Chilocorus stigma + SX, Chrysoperla carnea + SX, Chrysoperla rufilabris + SX, Clitostethus arcuatus + SX, Coccidoxenoides perminutus + SX, Coccophagus cowperi + SX, Coccophagus lycimnia + SX, Coenosia attenuata + SX, Coleomegilla maculata + SX, Comperia merceti + SX, Comperiella bifascita + SX, Copidosoma floridanum + SX, Copidosoma truncatellum + SX, Cotesia flavipes + SX, Cotesia glomerata + SX, Cotesia marginiventris + SX, Cotesia medicaginis + SX, Cotesia melanoscela + SX, Cotesia plutellae + SX, Cotesia ruficrus + SX, Cryptolaemus montrouzieri + SX, Cybocephalus nipponicus + SX,Dacnusa sibirica + SX, Dalotia coriaria + SX, Delphastus catalinae + SX, Delphastus pusillus + SX, Dendrolimus punctatus + SX, Deraeocoris brevis + SX, Diaeretiella rapae + SX, Dicyphus hesperus + SX, Diglyphus isaea + SX, Encarsia aurantii + SX, Encarsia formosa + SX, Encarsia inaron + SX, Encarsia opulenta + SX, Encarsia perplexa + SX, Ephedrus cerasicola + SX, Episyrphus balteatus + SX, Eretmocerus eremicus + SX, Eretmocerus mundus + SX, Feltiella acarisuga + SX, Franklinothrips megalops + SX, Franklinothrips orizabensis + SX, Franklinothrips vespiformis + SX, Geocoris punctipes + SX, Glyptapanteles liparidis + SX, Goniozus legneri + SX, Harmonia axyridis + SX, Hippodamia convergens + SX, Hyposoter exiguae + SX, Hyposoter fugitivus + SX, Lariophagus distinguendus + SX, Leptomastidea abnormis + SX, Leptomastix algirica + SX, Leptomastix dactylopii + SX,Leptomastix epona + SX, Lydella thompsoni + SX, Lysiphlebus testaceipes + SX, Macrocentrus ancylivorus + SX, Macrocentrus iridescens + SX, Macrolophus pygmaeus + SX, Mallada signata + SX, Metaphycus bartletti + SX, Metaphycus californicus + SX, Metaphycus flavus + SX, Metaphycus funicularis + SX, Metaphycus helvolus + SX, Metaphycus luteolus + SX, Metaphycus stanleyi + SX, Meteorus autographae + SX, Meteorus laphygmae + SX, Meteorus pulchricornis + SX, Meteorus trachynotus + SX, Metoecus paradoxus + SX, Microctonus aethiopoides + SX, Red-bellied toad (Micromus angulatus) + SX, Micromus tasmaniae + SX, Micromus variegatus + SX, Microplitis brassicae + SX, Microplitis plutellae + SX, Microterys flavus + SX, Muscidifurax raptor + SX, Muscidifurax raptorellus + SX, Nabis kinbergii + SX, Necremnus artynes + SX, Neochrysocharis formosa + SX, Neodryinus typhlocybae + SX, Nesidiocoris tenuis + SX, Orius albidipennis + SX, Orius armatus + SX, Orius insidiosus + SX, Orius laevigatus + SX,Orius majusculus + SX, Orius niger + SX, Orius strigicollis + SX, Orygia pseudotsugata + SX, Pediobius foveolatus + SX, Pentalitomastix plethorica + SX, Pnigalio flavipes + SX, Podisus maculiventris + SX, Praon volucre + SX, Pseudaphycus maculipennis + SX, Psyllaephagus pilosus + SX, Rhapalosiphum padi + SX, Rhizophagus grandis + SX, Rhyzobius forestieri + SX, Rhyzobius lophantae + SX, Bedariia tentacles (Rodolia cardinalis) + SX, Scolothrips sexmaculatus + SX, Serangium parcesetosum + SX, Spalangia cameroni + SX, Spalangia endius + SX, Stethorus punctillum + SX, Sympiesis stigmata + SX, Telenomus podisi + SX, Tenodera sinensis + SX, Tetrastichus brevistigma + SX, Tetrastichus gallerucae + SX, Tetrastichus howardi + SX, Tetrastichus setifer + SX, Thripobius semiluteus + SX, Torymus sinensis + SX, Trichogramma achaeae + SX, Trichogramma brassicae + SX, Trichogramma evanescens + SX, Trichogramma minutum + SX, Trichogramma ostriniae + SX, Trichogramma platneri + SX,Trichogramma pretiosum + SX, Trichogramma semifumatum + SX, Trichogrammatoidea bactrae + SX, Trichopoda pennipes + SX, Trioxys complanatus + SX, Trioxys curvicaudus + SX, Trioxys pallidus + SX, Trioxys tenuicaudus + SX, Trissolcus bathos + SX, Vairimorpha necatrix + SX, Volucella inanis + SX, Voria ruralis + SX, Squid (Xylocoris flavipes) + SX, Zelus renardii + SX.
[0057] Material (j-8): Details and designs of the fish: Amblydromalus limonicus + SX, Amblyseius andersoni + SX, Amblyseius barkeri + SX, Amblyseius californicus + SX, Amblyseius cucumeris + SX, Amblyseius degenerans + SX, Amblyseius montdorensis + SX, Amblyseius swirskii + SX, Amblyseius womersleyi + SX, Anystis agilis + SX, Cheyletus eruditus + SX, Euseius gallicus + SX, Euseius stipulatus + SX, Euseius tularensis + SX, Gaeolaelaps gillespiei + SX, Galendromus annectens + SX, Galendromus helveolus + SX, Galendromus occidentalis + SX, Hypoaspis aculeifer + SX, Hypoaspis miles + SX, Macrocheles robustulus + SX, Mesoseiulus longipes + SX, Neoseiulus fallacis + SX, Phytoseiulus macropilis + SX, Phytoseiulus persimilis + SX, Thyreophagus entomophagus + SX, Typhlodromus pyri + SX。
[0058] Subgroup (j-9): Combination of the main component of mollusks and this compound: Rumina decollata + SX。
[0059] The components selected from group (j) are usually prepared by methods known in the art. For example, in the case of (j-1) bacteria or (j-2) fungi / yeast, they are prepared by culture media and fermentation methods known in the art. If the component is (j-1) bacteria or (j-2) fungi / yeast, the preparation is 10 times per gram. 4 ~1 × 10 13 CFU (colony-forming units), preferably 1 × 10 8 ~1 × 10 12 This product contains the main component of CFU. If this component is (j-4) virus, the preparation contains 1 × 10⁶ per gram. 4 ~1 × 10 13 Occlusion bodies (sometimes referred to as Obs), preferably 1 × 10 8 ~1 × 10 12 This product contains the main component from occlurion bodies (sometimes referred to as Obs). If the main component is (j-5) nematode, the preparation contains 1 × 10⁶ units per gram. 4 ~1 × 10 13 Individual, preferably 1 × 10 8 ~1 × 10 12 Contains solid components.
[0060] This compound can be mixed with or used in combination with chemical fertilizers (such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, and ammonium chloride).
[0061] The weight ratio of the amount of this compound applied to the amount of this component applied in composition A is not particularly limited, but can be adjusted to the optimal weight ratio as appropriate depending on the type of plant to be protected, the type and frequency of occurrence of harmful arthropods, harmful nematodes, harmful mollusks, plant pathogenic microorganisms, or weeds to be controlled, the formulation form, the timing of application, the method of application, the location of application, weather conditions, etc. For example, in the agricultural field, when applied to plants (especially stems, leaves, seeds, and vegetative reproductive organs) or to the cultivation carrier (especially soil) on which plants are grown, the following weight ratios can be given. Note that the weight of the component selected from group (j) refers to the weight of its preparation. For example, a weight ratio of 1:500 means that the amount of one or more components selected from group (j) applied is 500 parts by weight per 1 part by weight of the compound.
[0062] The weight ratio [(this compound):(this component)] = 1:10^15 to 10^15:1, specifically, for example, approximately 1:10^15, 1:10^14, 1:10^13, 1:10^12, 1:10^11, 1:10^10, 1:10^9, 1:10^8, 1:10^7, 1:10^6, 1:10^5, 1:10000, 1:9000, 1:8000, 1:7000, 1:6000, 1:5000, 1:4000, 1:3000, 1:2000, 1:1000, 1:900, 1:800, 1:700, 1:600, 1:500. ,1:400, 1:350, 1:300, 1:250, 1:200, 1:150, 1:100, 1:90, 1:80, 1:70, 1:60, 1:50, 1:40, 1:30, 1:20, 1:19, 1:18, 1:17, 1:16, 1:15, 1:14, 1:13, 1:12, 1:11, 1:10, 1:9, 1:8, 1:7, 1:6, 1:5, 2:9, 1:4, 2:7, 3:10, 1:3, 3:8, 2:5, 3:7, 4:9, 1:2, 5:9, 4:7, 3:5, 5:8, 2:3, 7:10, 5:7, 3:4, 7:9, 4:5, 5:6, 6:7, 7:8, 8:9, 9:10, 1:1, 10:9, 9:8, 8:7, 7:6, 6:5, 5:4, 9:7, 4:3, 7:5, 10:7, 3:2, 8:5, 5:3, 7:4, 9:5, 2:1, 9:4, 7:3, 5:2, 8:3, 3:1, 10:3, 7:2, 4:1, 9:2, 5:1, 6:1, 7:1, 8:1, 9:1, 10:1, 11:1, 12:1, 13:1, 14:1, 15:1, 16:1, 17:1, 18:1, 19:1, 20:1, 30:1, 40:1, 50:1, 60:1, 70:1 , 80:1, 90:1, 100:1, 150:1, 200:1, 250:1, 300:1, 400:1, 500:1, 600:1, 700:1, 800:1, 900:1, 1000:1, 2000:1, 3000:1, 4000:1, 5000:1, 6000:1, 7000:1, 8000:1, 9000:1, 10000:1, 10^5:1, 10^6:1, 10^7:1, 10^8:1, 10^9:1, 10^10:1, 10^11:1, 10^12:1, 10^13:1, 10^14:1, 10^15:1. Here, the caret symbol "^" is the operator that represents exponentiation; for example, "10^5" is "10 5This means (i.e., 10 to the power of 5). In the previous section, "approximately" includes the range of ratios that are 10% more or less in weight relative to the specified ratio. For example, approximately 1:2 includes the range of 1:1.8 to 1:2.2.
[0063] This compound or composition A is usually used as a composition further containing an inert carrier (hereinafter referred to as composition B). Composition B is usually prepared by mixing this compound or composition A with a solid carrier, liquid carrier, surfactant, etc., and adding formulation aids such as binders, dispersants, stabilizers, and gases as needed, to form aqueous suspensions, oily suspensions, emulsions, microemulsions, microcapsules, wettable powders, granular wettable powders, powders, granules, tablets, aerosols, resin formulations, etc. Not limited to these formulations, it can be prepared and used in dosage forms described in Manual on development and use of FAO and WHO Specifications for pesticides, FAO Plant Production and Protection Papers-271~276, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2016, ISSN:0259-2517. Furthermore, composition B may also be processed and used in the form of, for example, sprays (aerosols, pump sprays, ultrasonic vibration formulations, electrostatic spray formulations, etc.), poison baits, combustion agents (incense sticks, etc.), heat vaporizers (electric mosquito mats, liquid mosquito repellent formulations, etc.), fan vaporizers (fan-type mosquito repellent formulations, etc.), fumigants (self-combusting fumigants, chemical reaction fumigants, porous ceramic plate fumigants, etc.), fumigants, smoking agents, ULV agents, mist agents, foam agents, paste formulations, paints, wood protective coatings, sealing materials, carbon dioxide formulations, sheet formulations, tape formulations, paper formulations, nonwoven fabric formulations, animal collars, animal ear tags, shampoos, spot-on agents, pore-on agents, suppositories, injections, oral administration agents (capsules, tablets, chewables, feed, etc.), sublimation tablets, mosquito nets, attractant strings, garden stakes, and screen doors. These formulations typically contain the compound in an amount of 0.0001 to 99% by weight, preferably 0.1 to 99%, and more preferably 0.2 to 90%.
[0064] When this compound or composition A is formulated into an aqueous suspension, an oily suspension, a wettable powder, or a wettable granule, the particle size of this compound or composition A is usually in the range of 0.1 to 20 μm, preferably 0.2 μm to 15 μm. When this compound or composition A is formulated into granules, the particle size of this compound or composition A is usually in the range of 0.1 to 200 μm, preferably 0.5 μm to 100 μm. The particle size of this compound or composition A refers to the particle size that accounts for 50% of the cumulative frequency in the volume-based frequency distribution (volume median diameter), and can be determined by wet measurement using a laser diffraction particle size analyzer. An example of a laser diffraction particle size analyzer is the Mastersizer 3000 manufactured by Malvern. In a volume-based frequency distribution, the cumulative frequency can be expressed based on any percentage other than the median (50%), and a preferred range can be expressed as "40% volume diameter is 2.5 μm to 60% volume diameter is 2.5 μm," etc. Furthermore, it can be expressed using the median weight diameter in addition to the median volume diameter, and this can also be expressed as any percentage.
[0065] Examples of solid supports include the following: Inorganic materials: Minerals (natural silicates, marble, pumice, limestone, rare earth minerals, cryolite, activated clay, lime, activated carbon, talc, attapulgite, sodium montmorillonite, calcium montmorillonite, kaolinite, calcite, dolomite, diatomite, bentonite, zeolite, sepiolite, pyrophyllite, vermiculite, crystalline silica, amorphous silica, etc.), silicon dioxide, calcium sulfate, magnesium sulfate, barium sulfate, magnesium oxide, aluminum oxide, ammonium sulfate, ammonium phosphate, ammonium nitrate, calcium phosphate, sulfur, calcium carbonate, sodium bicarbonate, sodium carbonate, synthetic silicates, and their pulverized products; Organic materials: grain powders (rice bran, rice flour, corn flour, wheat flour, etc.), sugars (cellulose, starch, lactose, glucose, fructose, sucrose, etc.), plant-derived powders (nut shell powders (coconut, walnut, peanut, etc.), tree-derived powders (bark powder, sawdust, etc.), other plant powders (tobacco stems, soybeans, cottonseed husks, etc.)), lignin, wax, seashells, urea, polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resins, melamine resins, epoxy resins. Furthermore, the above-mentioned solid carrier can also be used as an adsorption carrier.
[0066] Examples of liquid carriers include water, aliphatic hydrocarbons (hexane, 1-hexene, cyclohexane, octane, isooctane, 1-heptene, d-limonene, pinene, hexadecane, etc.), aromatic hydrocarbons (alkylbenzenes (toluene, xylene, isopropylbenzene, p-diethylbenzene, etc.), alkylbenzene derivatives, alkylnaphthalenes, alkylnaphthalene derivatives, tetrahydronaphthalene, etc.), and chlorinated hydrocarbons (monochloroethylene, dichloroethylene, trichloroethylene, tetrachloroethylene). Dichloromethane, 1,1,1-trichloroethane, 1,1,2-trichloroethane, 1,2-dichloropropane, etc.), ketones (cyclohexanone, acetone, 2-heptanone, isophorone, mesityl oxide, methyl isoamyl ketone, methyl ethyl ketone, methyl isobutyl ketone, acetophenone, diacetone alcohol, methylcyclohexanone, etc.), esters (fatty acid esters (ethyl acetate, butyl acetate, amyl acetate, isoamyl acetate, isobornyl acetate, hexyl acetate, heptyl acetate, octyl acetate) (Isopropyl myristate, methyl octanoate, methyl oleate, methyl laurate, dibutyl adipate, tributyl citrate, dibutyl phthalate, etc.), lactate esters (ethyl lactate, propyl lactate, etc.), carbonate esters (ethylene carbonate, propylene carbonate, butylene carbonate, diethyl carbonate, dibutyl carbonate, etc.), esterified polyols (glycerol acetate, glycol acetate, glycerin monoacetate, glycerin diacetate, glycerin triacetate, diethylene glycol abietate, dibutyl) (Propylene glycol dibenzoate, dipropylene glycol monomethyl ester, etc.), lactones (γ-butyllactone, etc.), ethers (1,4-dioxane, tetrahydrofuran, dipropylene glycol methyl ether, ethylene glycol methyl ether, propylene glycol methyl ether, etc.), amides (N-octyl-caprolactam, N-dodecyl-caprolactam, N,N-dimethylformamide, fatty acid dimethylamides (N,N-dimethylacetamide, N,N-dimethyldecanamide, N,N-dimethyloctanamide, alkylpyrrolidones (N-methylpyrrolidone, N-octylpyrrolidone, N-dodecylpyrrolidone, etc.), lactams (α-lactam, β-lactam, γ-lactam, δ-lactam, etc.), amines (octylamine, octylamine acetate, oleylamine, diethanolamine, laurylamine, etc.), alcohols (methanol, ethanol, butanol, propanol, isopropanol, butanol, amyl alcohol, hexanol, heptanol, octanol, 2-ethylhexanol, etc.), hexylene glycol, cyclohexanol, phenol, benzyl alcohol, methoxypropanol (1-methoxy-2-propanol), tetrahydrofurfuryl alcohol, furfuryl alcohol, polyethylene glycol, ethylene glycol, diethylene glycol, hexylene glycol, ethylene glycol methyl ether, diethylene glycol Examples include methyl ether, diethylene glycol butyl ether, triethylene glycol, propylene glycol methyl ether, dipropylene glycol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol butyl ether, dipropylene glycol methyl ether, dipropylene glycol ether, dipropylene glycol monomethyl ether, glycerin, etc.), mineral oils (naphtha, petroleum ether, kerosene, diesel oil, paraffin, olefins, etc.), animal and vegetable-derived oils, plant-derived oils (palm oil, rapeseed oil, castor oil, coconut oil, soybean oil and their derivatives, etc.), animal-derived oils (sardine oil, saury oil, whale oil and their derivatives, etc.), dimethyl sulfoxide, silicone oil, acetonitrile, propanenitrile, acid anhydrides (acetic anhydride, etc.), triethyl phosphate, oleic acid, propionic acid, lactic acid, and xylene sulfonic acid.
[0067] Examples of gaseous carriers include fluorocarbons, butane gas, LPG (liquefied petroleum gas), dimethyl ether, nitrogen, and carbon dioxide.
[0068] Examples of anionic surfactants include carboxylic acids, sulfonic acids, sulfate esters, and phosphate esters, and specifically, the following are listed below. Carboxylic acids: Fatty acid salts (octanoate, decanoate, laurate, myristicate, palmitate, stearate, behenate, oleate, polyoxyethylene alkyl ether carboxylate, laureth-3-carboxylate, α-(carboxymethyl)-ω-(dodecyloxy)poly(oxyethylene) salt, etc.), N-acyl sarcosine salts (N-lauroyl sarcosine salt, etc.), N-acyl glutamate salts (N-lauroyl glutamate, etc.), polycarboxylates (polyacrylate, polyvinyl acetate, comb-type polymers of polysalts, and their derivatives, etc.); Sulfonic acids: Alkyl sulfonic acids and their salts (dodecyl sulfonate, etc.), alpha-olefin sulfonates (alkene (C14-18) hydroxysulfonate, alkapoliene (C12-20) hydroxysulfonate, alkene (C14-18) hydroxysulfonate, alkene (C12-20) hydroxysulfonate, tetradecene-1-sulfonate, α-olefin (C14-16) sulfonate, etc.), alkylbenzene sulfonates (decylbenzene sulfonate, dodecylbenzene sulfonate, tridecylbenzene sulfonate, diphenyl sulfonate, etc.), alkylnaphthalene sulfonates (naphthalene sulfonate, 6-methyl (e.g., 2,2'-dinaphthylmethane-6,6'-disulfonate, diisopropylnaphthalenesulfonate, triisopropylnaphthalenesulfonate, 1-isopropyl2-naphthalenesulfonate, etc.), sulfosuccinic acid, monoalkyl sulfosuccinate, dialkyl sulfosuccinate (e.g., di(2-ethylhexyl)sulfosuccinate), N-methyl-N-acyl taurate (e.g., oleoylmethyl taurate), lignin sulfonate, alkylphenol sulfonate, naphthalenesulfonate-formaldehyde condensate, benzimidazole sulfonate and its derivatives; Sulfate esters: Alkyl sulfates (hexyl sulfate, heptyl sulfate, octyl sulfate, lauryl sulfate, lauryl sulfate diethanolate, hexadecyl sulfate, octadecyl sulfate, etc.), polyoxyethylene alkyl ether sulfates and their salts (laureth-3 sulfate, polyoxyethylene monotridecyl ether sulfate, α-sulfo-ω-hydroxyalkyl(C6-10) ether poly(oxyethylene) salt, etc.), polyoxyethylene alkylphenyl ether sulfates (poly(oxyethylene)2-decylphenyl ether sulfate, poly(oxyethylene)3-decylphenyl ether sulfate, α-sulfo-ω-[2,4-bis(1,1,3,3-tetramethylbutyl)phenoxy]poly(oxyethylene) salt, etc.), polyoxypropylene alkyl ether sulfates, lignosulfite wastewater, and derivatives thereof; Phosphate esters: Alkyl phosphates (propyl phosphate, hexadecyl phosphate, lauryl phosphate, dioctyl phosphate, etc.), polyoxyethylene alkyl ether phosphates (polyoxyethylene decyl phosphate, α-phosphono-ω-butoxypoly(oxyethylene), etc.), polyoxyethylene alkylphenyl ether phosphates (α-(dinonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(dodecylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, α-(nonylphenyl)-ω-hydroxypoly(oxyethylene) phosphate, etc.), polyoxypropylene alkyl ether phosphates, and derivatives thereof.
[0069] Examples of cationic surfactants include amine salts and quaternary ammonium salts, specifically the following: Amine salts: Alkylamine salts (monomethylamine salts, dimethylamine salts, trimethylamine salts, etc.), fatty acid amide amine salts (stearamidopropyldimethylamine, behenamidopropyldimethylamine, etc.), polyamine salts (polyvinylamine, polyethyleneimine, etc.), and their derivatives; Quaternary ammonium salts: lauryltrimethylammonium salt, cetyltrimethylammonium salt, dodecyltrimethylammonium salt, stearyltrimethylammonium salt, penzalkonium chloride, benzethonium chloride, benzylbis(2-chloroethyl)ethylammonium bromide salt.
[0070] Examples of amphoteric surfactants include betaine, alkylbetaine, alkyldimethylbetaine, imidazoline, taurine, alkyltaurine, dodecyldimethylammonium acetate, 4-carboxy-N,N,N-trimethyl-1-butanaminonium, 1-carboxy-N,N,N-2-tetramethyl-1-propanaminonium, N-alkyl (or alkenyl)(C12-18)glycine and its salts, N-dodecylglycine and its salts, and derivatives thereof.
[0071] Examples of nonionic surfactants include alcohols, amides, amines, esters, ethers, ether esters, and carboxylic acids, and specifically, the following are listed below. Alcohols: Aromatic alcohols (alkylphenols (allylphenol, octylphenol, nonylphenol, octyl cresol, etc.), acylphenols, etc.), aliphatic alcohols (isotridecyl alcohol, oleyl alcohol, cetyl alcohol, etc.), polyhydric alcohols (polysaccharides, starch, starch derivatives, sucrose, alkyl polyglucosides, sorbitan, ethoxylated sorbitan, cellulose derivatives, gum arabic, etc.), synthetic polymers (polyvinyl alcohol, polyethylene glycol, etc.); Amides: Alkanolamides (fatty acid alkanolamides (e.g., lauric acid diethanolamide)), fatty acid glucamides (e.g., alkoxylated propylene oxide fatty acid glucamide), alkoxylated amides (e.g., polyoxyethylene oleamide, polyoxyethylene stearate amide), synthetic polymers (e.g., polyvinylpyrrolidone); Amines: Alkoxylated amines (polyoxyethylene oleylamine, α,α'-[(9-octadecenylimino)diethylene]bis(ω-hydroxy)polyoxyethylene, etc.); Esters: Fatty acid esters (fatty acid esters of polyols, monoglycerides, phospholipids, etc.), sugar-derived esters (sucrose fatty acid esters (sucrose stearate diester, etc.), sorbitan fatty acid esters (sorbitan oleic acid monoester, etc.), glucose esters, cellulose esters, etc.), synthetic polymers (vinyl acetate copolymers, polymethacrylic acid, copolymers of methacrylic acid and methacrylic acid esters, etc.); Ethers: Alcohol ethoxylates (aliphatic alcohol ethoxylates (tridecyl alcohol ethoxylate, isooctyl alcohol ethoxylate, lauryl alcohol ethoxylate, hexadecyl alcohol ethoxylate, stearyl alcohol ethoxylate, etc.)), alkylphenol ethoxylates (nonylphenol ethoxylate, tristyrylphenol ethoxylate, tributylphenol ethoxylate, octylphenol ethoxylate, etc.), arylalkylphenol ethoxylates, arylphenol ethoxylates (monobenzyl biphenol alcohol ethoxylate, etc.), alcohol propoxylates (aliphatic alcohol propoxylates, alkylphenol propoxylates, arylalkylphenol propoxylates, etc.), block polymers (polyethylene oxide and polypropylene oxide block polymers, polyethylene oxide block polymers, polypropylene oxide block polymers, alkanol and polyethylene oxide and polypropylene oxide block polymers, etc.); Ether esters: Polyoxyethylene fatty acid esters (polyoxyethylene castor oil ester, polyoxyethylene stearate ester, polyoxyethylene beef tallow fatty acid ester, etc.), polyoxyethylene sorbitan fatty acid esters (polyoxyethylene sorbitan monooleate ester, polyoxyethylene sorbitan trioleate ester, polyoxyethylene sorbitan monolaurate ester, polyoxyethylene sorbitan stearate ester, etc.), polyoxyethylene fatty acid amine esters, polyoxyethylene rosin esters, polyoxypropylene fatty acid esters (polyoxypropylene castor oil ester, etc.), polyoxypropylene fatty acid amine esters; Carboxylic acids: Undecafluorohexanoic acid.
[0072] Other pharmaceutical additives include, for example, thickeners, antifreezes / humectants, defoamers, antioxidants, pH adjusters, colorants, preservatives / bactericides, binders, adhesives / spreaders, lubricants, anticaking agents, light stabilizers, fragrances, propellants, fertilizers, film-forming agents, deodorizers, plasticizers, desiccants / moisture-proofing agents, fumigant aids, attractants, inclusion agents, and efficacy enhancers. Specifically, these include the following: Thickeners: Polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose and their salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tyrose, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay, etc.), minerals (bentonite, attapulgite, silica, silicates, etc.), synthetic polymers (polycarboxylates, polyacrylic acid derivatives, polyvinylpyrrolidone, polyvinyl alcohol, etc.); Antifreezing and humectants: Alcohols (ethylene glycol, propylene glycol, dipropylene glycol, triethylene glycol, ethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol butyl ether, glycerin, polyethylene glycol, etc.), esters (dipropylene glycol dibenzoate, glycerol acetate, glycerol diacetate, glycerol triacetate, gamma butyrolactone, etc.), ethers (1,4-dioxane, etc.), urea; Antifoaming agents: Silicones (polysiloxane, diblock ethoxysiloxane, triblock ethoxysiloxane, etc.), alkyl sulfosuccinates, higher alcohols, higher alcohol derivatives, fatty acid salts, fatty acid derivatives; Antioxidants: Phenols (2,6-di-t-butyl-p-cresol, 2,2'-methylenebis(4-methyl-6-t-butylphenol), etc.), amines (p,p'-dioctyldiphenylamine, N,N'-diphenyl-p-phenylenediamine, etc.), dibutylhydroxytoluene, butylhydroxyanisole, sodium erythorbate, sodium sulfite, potassium sulfite, potassium pyrosulfite, catechin, propyl gallate, sulfurs (didodecyl thiodipropionate, etc.), phosphoric acids (trisnonylphenyl phosphite, etc.), vitamins (alpha-tocopherol, L-ascorbic acid, sodium ascorbate, ascorbyl palmitate, etc.); pH adjusters: sulfuric acid, nitric acid, hydrochloric acid, acetic acid, carbonic acid, oxalic acid, lactic acid, succinic acid, gluconic acid, citric acid, phosphoric acid, sorbic acid, and their salts, sodium bicarbonate, sodium hydroxide, potassium hydroxide, calcium hydroxide, aluminum hydroxide, copper hydroxide, magnesium hydroxide; Colorants: Monoazo compounds (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, Cl Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazo compounds (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinone compounds (Pigment Red 83, etc.), dioxazine compounds (Pigment Blue 80, etc.), xanthenes (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethane compounds (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium, titanium dioxide, zinc oxide, zinc sulfide, iron hexacyanoate, chromium vermilion, yellow lead, calcium carbonate, barite powder, aluminum powder; Preservatives and disinfectants: Phenols (orthophenylphenol, thymol, 3,5-dimethyl-4-chlorophenol, etc.), isothiazolinone derivatives (methylisothiazolinone (2-methyl-4-isothiazolinone-3-one), chloromethylisothiazolinone (5-chloro-2-methyl-4-isothiazolinone-3-one), octylisothiazolinone (2-n-octyl-4-isothiazolinone-3-one), dichlorooctylisothiazolinone (4,5-dichloro-2-octyl-4-isothiazolinone-3-one), benzisothiazolinone (1,2-benzisothiazolinone-3-one), etc.), bronopo Derivatives (such as bronopol (2-bromo-2-nitropropane-1,3-diol)), benzyl alcohol hemifomal, isopropylmethylphenol, parabens (methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, heptylparaben, benzylparaben), imidazoles (thiabendazole), benzalkonium chloride, glyceryl caprylate, glyceryl caprate, glycerin fatty acid esters, sodium dehydroacetate, hinokitiol, acids (citric acid, phosphoric acid, sorbic acid, salicylic acid, benzoic acid, and their salts, etc.); Binders: Polysaccharides (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay), minerals (bentonite), synthetic polymers (polycarboxylic acid or its salts, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salts), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefins, etc.); Adhesives and spreading agents: The above-mentioned surfactants and liquid carriers (esters (alkyl fatty acid esters, sorbitan fatty acid esters, ethoxylated fatty acid esters, ethoxysorbitan fatty acids, etc.), alcohols (ethoxylated aliphatic alcohols, ethoxysorbitan aliphatic alcohols, etc.), waxes (vegetable oils, animal oils, and their derivatives, paraffin, olefins, etc.), vegetable oils (alkylated vegetable oils, etc.), mineral oils (mineral oil, etc.), silicone emulsions, synthetic polymers (styrene-butadiene copolymer, methyl methacrylate-butadiene copolymer, polyacrylic acid or its salts, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), natural polymers (xanthan gum, cellulose esters, cellulose ethers, carboxymethylcellulose or its salts), dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tyrose, etc.); Lubricants and Lubricants: Alcohols, fatty acid esters, sucrose fatty acid esters, glycerin fatty acid esters, hydrocarbons, paraffin, ethylene wax, aliphatic amides, erucic acid amide, stearic acid amide, oleic acid amide, methylenebisstearate amide, ethylenebisstearate amide, metal soaps, lead stearate, zinc stearate, calcium stearate, magnesium stearate, mineral oil, vegetable oil, kerosene, diesel oil; Anticaking agents: The above-mentioned solid or liquid carriers, calcium phosphate, sodium phosphate, sodium carbonate, sodium silicate, calcium silicate, magnesium silicate, potassium aluminum silicate, silicon dioxide, talc, sodium aluminosilicate, calcium aluminosilicate, bentonite, stearic acid, dimethylpolysiloxane, powdered cellulose; Light stabilizers: Titanium dioxide, zinc oxide, activated carbon, carbon black, ethylhexyl methoxycinnamate, tert-butyl methoxydibenzoylmethane, hindered amines, ferulic acid, phenyl hydroxybenzoate, ethyl para-aminobenzoate, octyl salicylate, t-butylphenyl salicylate, 4-tert-octylphenyl salicylate, 2-cyano-3,3-diphenylpropane-2-enoic acid-2-ethylhexyl ester (octocrylene), drometrizole trisiloxane, 2,4,6-tris[4-(2-ethylhexyloxycarbonyl)anilino]-1,3,5-triazine (octyltriazone, TEAT), 2,2'-methylenebis[6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)phenol](MBP), 2-Ethylhexyl paradimethylaminobenzoate (EDB), homomenthyl salicylate (HS), phenylbenzimidazole sulfonic acid (PBS), hydroxymethoxybenzophenone sulfonic acid (oxybenzone 4, OXB4), sodium hydroxymethoxybenzophenone sulfonate (oxybenzone 5, OXB5), sodium dihydroxydimethoxybenzophenone disulfonate (oxybenzone 9, OXB9), tetrahydroxybenzophenone, dihydroxybenzophenone, dihydroxydimethoxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-ethylhexyl dimethoxybenzylidene dioxoimidazolidinepropionate, 2,4-dihydroxybenzophenone, bis(2-methoxy-4-hydroxy-5-benzoylphenyl)methane; Fragrance: Hydrocarbons, α-Limonene, β-Caryophyllene, Alcohols, cis-3-Hexenol, Linalool, Farnesol, β-Phenylethyl Alcohol, Aldehydes, 2,6-Nonagenal, Citral, α-Hexyl Cinnamic Aldehyde, Ketones, β-Ionone, L-Carvone, Cyclopentadecanone, Esters, Linalyl Acetate, Benzyl Benzoate, Lactones, γ-Undecalactone, Phenols, Eugenol, Oxides, Rose Oxide, Acetals, Phenylacetaldehyde Dimethyl Acetal, α-Pinene, β-Pinene; Propellant: Liquefied petroleum gas, aliphatic hydrocarbons with 3 to 5 carbon atoms such as propane, n-butane, isobutane, n-pentane, and isopentane, hydrofluoroolefins such as trans-1,3,3,3-tetrafluoropropane-1-ene and trans-2,3,3,3-tetrafluoropropane-1-ene, dimethyl ether, nitrogen gas, carbon dioxide, nitrous oxide gas, compressed air, and mixtures thereof; Fertilizers: Nitrogen fertilizer components (urea, ammonium nitrate, magnesium ammonium nitrate, ammonium chloride, ammonium sulfate, ammonium phosphate, sodium nitrate, calcium nitrate, potassium nitrate, calcium cyanamide, formaldehyde-modified urea (UF), acetaldehyde-modified urea (CDU), isobutyraldehyde-modified urea (IBDU), guanylate urea (GU)), Phosphate fertilizer components (superphosphate, supersuperphosphate, fused phosphorus, humic acid phosphorus, calcined phosphorus, double calcined phosphorus, magnesium superphosphate, ammonium polyphosphate, potassium metaphosphate, calcium metaphosphate, magnesium phosphate, sulfur (such as ammonium phosphate, potassium ammonium nitrate, ammonium phosphate chloride, etc.), potassium-based fertilizer components (potassium chloride, potassium sulfate, sodium potassium sulfate, magnesium sulfate, potassium bicarbonate, potassium phosphate, etc.), silicate-based fertilizer components (calcium silicate, etc.), magnesium-based fertilizer components (magnesium sulfate, magnesium chloride, etc.), calcium-based fertilizer components (quicklime, slaked lime, calcium carbonate, etc.), manganese-based fertilizer components (manganese sulfate, magnesium manganese sulfate, slag manganese, etc.), boron-based fertilizer components (boric acid, borate, etc.), iron-containing fertilizer components (steel slag, etc.), and other fertilizer components (copper, cobalt, zinc, etc.); Film-forming agents: Natural rubber, synthetic rubber, resins (styrene-butadiene copolymer, polyacrylonitrile, polyester, polyamide, polyurethane, polyurea, polyether, rosin, melamine, etc.), waxes (vegetable oils, animal oils, and their derivatives, paraffin, olefins, etc.), polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethylcellulose or its salts, dextrin, starch, guar gum, gum arabic, hydroxypropyl guar gum, tyrose, starch xanthate, carrageenan, etc.), proteins (gelatin, etc.); Deodorizers: Organic clay, organically modified clay, unmodified clay, zinc silicate, silica gel; Plasticizers: Triethyl phosphate, citrate ester, phthalate ester, adipic acid ester, sebacate ester, phosphate ester; Desiccants / Moisture-proofing agents: Silica gel, calcium chloride, quicklime, aluminum oxide, zeolite, allophane; Fumigation agent additives: nitrocellulose, potassium chlorate, calcium oxide, melamine, potassium nitrate, azodicarbonamide; Attractants: starch, cellulose, dextrin, vinegars, alcoholic beverages, yeast extract; Inclusion agents: Cyclodextrins, α-cyclodextrin, β-cyclodextrin, γ-cyclodextrin; Potency enhancer: The liquid carrier or surfactant described above.
[0073] When this compound or composition A is formulated into an aqueous suspension or an oily suspension, an antifreeze and / or preservative are usually added. Preferred antifreezes include ethylene glycol, propylene glycol, and glycerin. Preferred preservatives include isothiazolinone derivatives (e.g., 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n-octyl-4-isothiazolin-3-one) and proxel (1,2-benzisothiazolin-3-one). Ethylene glycol (hereinafter referred to as EG), propylene glycol (hereinafter referred to as PG), glycerin (hereinafter referred to as GL), 2-methyl-4-isothiazolin-3-one (hereinafter referred to as MIT), 5-chloro-2-methyl-4-isothiazolin-3-one (hereinafter referred to as CMIT), 2-n-octyl-4-isothiazolin-3-one (hereinafter referred to as OIT), 4,5-dichloro-2-octyl-4-isothiazolin-3-one (hereinafter referred to as DCOIT), 1,2-benzisothiazolin-3-one (hereinafter referred to as BIT), and 2-bromo-2-nitropropane-1,3-diol (hereinafter referred to as BNPD), which are used as antifreeze and preservatives, are available commercially.
[0074] Examples of combinations of this compound or composition A with the above-mentioned antifreeze or preservative are shown below. SX + EG, SX + PG, SX + GL, SX + MIT, SX + CMIT, SX + OIT, SX + DCOIT, SX + BIT, SX + BNPD, Composition A + EG, Composition A + PG, Composition A + GL, Composition A + MIT, Composition A + CMIT, Composition A + OIT, Composition A + DCOIT, Composition A + BIT, composition A+ BNPD.
[0075] The weight ratio of this compound or composition A to the above-mentioned antifreeze or preservative is in the range of 1:0.0001 to 1:100, for example, in the ranges of 1:0.0001 to 1:1, 1:0.005 to 1:0.01, 1:0.15 to 1:0.35, and 1:0.125 to 1:0.25. 1:0.0001, 1:0.0002, 1:0.0003, 1:0.0004, 1:0.0005, 1:0.0006, 1:0.0007, 1:0.0008, 1:0.0009, 1:0.001, 1:0.002, 1:0.003, 1:0.004, 1:0.005, 1:0.006, 1:0.007, 1:0.008, 1:0.009, 1:0.01, 1:0.02, 1:0.03, 1:0.04, 1:0.05, 1 The following weight ratios can be listed: 0.06, 1:0.07, 1:0.08, 1:0.09, 1:0.1, 1:0.125, 1:0.15, 1:0.2, 1:0.25, 1:0.3, 1:0.4, 1:0.5, 1:0.6, 1:0.7, 1:0.8, 1:0.9, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:20, 1:30, 1:40, 1:50, 1:60, 1:70, 1:80, 1:90, and 1:100. The above weight ratios can also be expressed as approximate. "Approximate" means plus or minus 10%, for example, "approximately 1:2" means 1:1.8 to 1:2.2.
[0076] Examples of combinations of this compound or composition A with the above-mentioned antifreeze and preservatives are described below. SX + EG + MIT, SX + EG + CMIT, SX + EG + OIT, SX + EG + DCOIT, SX + EG + BIT, SX + EG + BNPD, SX + PG + MIT, SX + PG + CMIT, SX + PG + OIT, SX + PG + DCOIT, SX + PG + BIT, SX + PG + BNPD, SX + GL + MIT, SX + GL + CMIT, SX + GL + OIT, SX + GL + DCOIT, SX + GL + BIT, SX + GL + BNPD, Composition A + EG + MIT, Composition A + EG + CMIT, Composition A + EG + OIT, Composition A + EG + DCOIT, Composition A + EG + BIT, Composition A + EG + BNPD, composition A + PG + MIT, composition A + PG + CMIT, Composition A + PG + OIT, Composition A + PG + DCOIT, Composition A + PG + BIT, Composition A + PG + BNPD, Composition A + GL + MIT, Composition A + GL + CMIT, Composition A + GL + OIT, Composition A + GL + DCOIT, Composition A + GL + BIT, Composition A + GL + BNPD. When this compound or composition A is combined with the above-mentioned antifreeze and preservative, the mixing ratio of this compound or composition A to the antifreeze, and the mixing ratio of this compound or composition A to the preservative can be used within the same range as the above-mentioned ratio.
[0077] In the case of granular or fine granular formulations, a coloring agent may be added to make it easier to identify the granular or fine granular formulations during or after application. Similarly, when applying composition B to plant seeds or vegetative reproductive organs, a coloring agent may be added to make it easier to identify that the formulation has been applied.
[0078] Examples of base materials for the resin formulation include polyethylene, polypropylene, polyvinyl alcohol, polycarbonate, polyester, polyamide, polyurethane, polyvinyl chloride, polyvinyl acetate, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, polyvinylpyrrolidone-methacrylic acid copolymer, polyvinylpyrrolidone-vinyl acetate copolymer, cellulose derivatives, phenolic resins, melamine resins, and epoxy resins. These base materials may contain plasticizers such as phthalate esters (dimethyl phthalate, dioctyl phthalate, etc.), adipic acid esters, and stearic acid as needed. The resin formulation can be processed into various forms by molding as needed, such as plates, films, tapes, threads, nets, cloths, strings, and blocks. Specifically, it can be used in the form of animal collars, animal ear tags, clothing, protective hats, arm / leg covers, leashes, garden stakes, screens, mosquito nets, etc. It can also be obtained by post-treating the resin with composition B after molding. Examples of base materials for poison bait include grain flour, vegetable oil, sugar, and crystalline cellulose. Furthermore, if necessary, antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid, preservatives such as dehydroacetic acid, agents to prevent accidental ingestion by children and pets such as chili pepper powder, and insect-attracting flavors such as cheese flavor, onion flavor, and peanut oil may be added.
[0079] This compound, composition A, or composition B can be used to control harmful arthropods by applying an effective amount directly to them or to their habitats. The term "habitat" here includes not only places where harmful arthropods currently live, but also places where they are expected to live. Specifically, this includes plants, plant cultivation areas, plant growing media, indoor and outdoor areas of buildings, building materials, food, daily necessities, wood, vehicles, animal carcasses, etc.
[0080] In the present invention, "plant" includes the whole plant and specific parts of the plant. Examples of specific parts of a plant include stems and leaves, flowers, spikes, fruits, trunks, branches, canopies, seeds, vegetative reproductive organs, and seedlings.
[0081] Vegetative reproductive organs refer to parts of a plant, such as roots, stems, and leaves, that have the ability to grow when detached from the main plant and placed in the soil. Examples of vegetative reproductive organs include tuberous roots, creeping roots, bulbs, corms (or solid bulbs), tubers, rhizomes, stolons, rhizophores, cane cuttings, propagules, and vine cuttings. Stolons are sometimes called runners, and bulbils, also called broad buds, are divided into broad buds and bulbils. Vines refer to shoots (a general term for leaves and stems) of plants such as sweet potatoes and yams. Bulbs, corms, tubers, rhizomes, stem fragments, rhizomes, or tubers are collectively called bulbs. Potato cultivation begins with planting tubers in the soil, and the tubers used are generally called seed potatoes.
[0082] Seedlings include seedlings and saplings.
[0083] Examples of plant cultivation areas include agricultural land such as fields, rice paddies, and orchards, as well as non-agricultural land such as lawns and forests.
[0084] A plant cultivation support is a support for plants, and can be any material on which plants can grow, such as soil, seedling mats, and water. Specific materials for soil and seedling mats include sand, pumice, vermiculite, diatomaceous earth, gel-like substances, polymer substances, rock wool, glass wool, wood chips, and bark.
[0085] Examples of buildings include houses, commercial facilities, train stations, airports, hospitals, factories, offices, schools, accommodation facilities, waste disposal facilities, livestock barns, and warehouses. Examples of interior spaces within buildings include closets, cupboards, wardrobes, cupboards, toilets, bathrooms, storage rooms, living rooms, bedrooms, and dining rooms.
[0086] Examples of outdoor locations include the ground, exterior walls, fences, ditches, open spaces, water jars, water tanks, wells, puddles, rainwater drains, gutters, septic tanks, old tires, reservoirs, rivers, waterways, forests, and lakes.
[0087] Examples of building materials include wood, concrete, brick, plastic, glass, wallpaper, insulation, gaskets, pipes, electrical cables, paint, and sealants.
[0088] Examples of food products include agricultural products (grains, fruits, spices, and processed products thereof) and livestock and marine products (meat, fish, eggs, milk, and processed products thereof). Examples of daily necessities include plant-derived products (cotton, paper, tobacco, and processed products thereof), animal-derived products (leather, hair, wool, feathers, silk, and processed products thereof), electrical appliances, and other products (furniture, stationery, toys, tableware).
[0089] Examples of wood include wood processed for construction (high-density wood, laminated wood, plywood and fiberboard, hardboard, MDF, insulation board, particleboard, insulation hardboard, OSB, LSL, glued laminated timber, cross-laminated timber, flooring, engineered flooring, etc.).
[0090] Examples of modes of transportation include bicycles, cars (private cars, buses, taxis, freight vans, etc.), trains, airplanes, and ships.
[0091] Examples of animal bodies include livestock (cows, horses, pigs, sheep, goats, chickens, etc.) and small animals (dogs, cats, rats, mice, etc.).
[0092] When Composition B is used for controlling harmful arthropods in agriculture, the application rate can be varied widely depending on the type of plant being treated, the type and frequency of occurrence of the harmful arthropods being controlled, the formulation form, the timing of application, the method of application, the location of application, weather conditions, etc. Typically, the application rate of this compound or one of its components is 1 to 10,000 g per hectare, preferably 5 to 5,000 g, more preferably 50 to 2,000 g (specifically, for example, 100 g, 200 g, 300 g, or 500 g). When Composition B is formulated as an emulsion, wettable powder, flowable formulation, etc., it is usually diluted with water and applied so that the concentration of this compound or one of its components is 0.01 to 10,000 ppm, preferably 0.1 to 5,000 ppm, more preferably 1 to 1,000 ppm (specifically, for example, 10 ppm, 100 ppm, or 500 ppm). If composition B is formulated as granules, powder, etc., it is usually applied as is.
[0093] These formulations or aqueous dilutions of these formulations may be sprayed directly onto harmful arthropods or plants that should be protected from harmful arthropods, or they may be applied to the cultivation carrier to control harmful arthropods that infest the carrier.
[0094] Furthermore, Composition B, which is a resin preparation processed into a sheet or string shape, can also be used to treat plants by methods such as wrapping it around the plants, stretching it near the plants, or laying it on a cultivation carrier.
[0095] When applying composition B to plants or the area where plants are grown, it should be applied once or multiple times. The plants or the area where plants are grown may already be infested with harmful arthropods, or they may not be infested at all.
[0096] Examples of treatment methods for composition B include foliar treatment, soil treatment, root treatment, shower treatment, mist spraying treatment, fumigation treatment, water surface treatment, hydroponic solution treatment, and seed treatment.
[0097] Examples of foliar treatment include applying composition B to the surface of the stems, leaves, trunk, fruits, flowers, or spikes. Examples of root treatment methods include immersing the roots in a chemical solution containing composition B, and applying a solid formulation containing composition B to the roots of a plant. Soil treatment methods include, for example, soil application, soil mixing, and chemical drenching of the soil. Locations for soil treatment include, for example, planting holes, furrows, areas around planting holes, areas around furrows, and cultivated fields. Examples of application areas include the entire surface, the base of plants, between plants, under tree trunks, main ridges, growing media, seedling boxes, seedling trays, and seedbeds. Examples of application timing include before sowing, at sowing, after sowing, during the seedling stage, before transplanting, at transplanting, and during the growth stage after transplanting. In addition, in the above soil treatment, composition B may be applied to the plants simultaneously, or paste fertilizers, liquid fertilizers, solid fertilizers, etc. containing composition B may be applied to the soil. It may also be mixed with irrigation solution, for example, by injection into irrigation equipment (irrigation tubes, irrigation pipes, sprinklers, etc.), mixing into inter-row flooding solution, or mixing into hydroponic solution. Alternatively, the active ingredient can be mixed with the irrigation solution in advance and treated using the above irrigation method or other appropriate irrigation methods such as sprinkling or flooding. One example of a shower treatment is showering harvested fruit with a diluted solution of composition B. As a mist spraying treatment, for example, a method is to atomize a diluted solution of composition B and disperse it into the air, allowing it to adhere to the stems, leaves, and fruits of plants. As a fumigation treatment, for example, a method is to heat a solid formulation containing composition B to produce smoke, which is then suspended in the air and allowed to adhere to the stems, leaves, and fruits of plants. As an example of surface treatment, one method is to spray a chemical solution containing composition B or a solid formulation containing composition B onto a flooded rice paddy. Examples of hydroponic solution treatments include mixing or adding a chemical solution containing composition B or a solid formulation containing composition B to the hydroponic solution (hydroponic solution mixing treatment, hydroponic solution mixing treatment, etc.).
[0098] Seed treatment Seed treatment refers to the treatment of seeds or vegetative reproductive organs with composition B. Examples of seed treatment methods with composition B include spraying, in which a suspension of composition B is atomized and sprayed onto the surface of the seeds or vegetative reproductive organs; coating, in which composition B is applied to the seeds or vegetative reproductive organs; immersion, in which the seeds are immersed in a solution of composition B for a certain period of time; and coating the seeds or vegetative reproductive organs with a carrier containing composition B (e.g., film coating, pellet coating). Seed potatoes are a particularly good example of the vegetative reproductive organs mentioned above. When treating seeds or vegetative reproductive organs with composition A, the seeds or vegetative reproductive organs may be treated with composition A as a single formulation, or the seeds or vegetative reproductive organs may be treated with composition A in multiple separate formulations in several separate applications. Examples of methods for treating seeds or vegetative reproductive organs with composition A in multiple separate formulations include treating the seeds or vegetative reproductive organs with a formulation containing only the compound as the active ingredient, air-drying the seeds or vegetative reproductive organs, and then treating the seeds or vegetative reproductive organs with formulations containing the compound and the active ingredient, air-drying the seeds or vegetative reproductive organs, and then treating the seeds or vegetative reproductive organs with formulations containing the compound other than the one that has already been treated with composition A. After seed treatment, the active ingredient may completely or partially coat the seed or vegetative reproductive organ, be scattered on its surface, and / or be present inside it. When performing treatment, it is preferable to use a composition containing the active ingredient having one or more bactericidal activities selected particularly from groups (b) and (j) within composition B. In this case, the compound may be applied to commercially available seeds or vegetative reproductive organs that have been treated with the active ingredient having one or more bactericidal activities selected from groups (b) and (j). When treating seeds or vegetative reproductive organs with composition B, manganese, copper, zinc, etc., may also be treated at the same time. When treating seeds with composition B, the application rate of composition B is usually 0.001 to 100 g, preferably 0.02 to 50 g, per 1 kg of seeds or vegetative reproductive organs. The application rate per active ingredient contained in composition B is usually 0.001 to 100 g, preferably 0.01 to 50 g, more preferably 0.1 to 10 g, per 1 kg of seeds or vegetative reproductive organs. Specifically, for example, the following treatment amounts are given. 0.05 g of active ingredient per 1 kg of seeds or vegetative reproductive organs; 0.5 g of active ingredient per 1 kg of seeds or vegetative reproductive organs; 5g of active ingredient per 1kg of seeds or vegetative reproductive organs. In the present invention, a seed or vegetative reproductive organ holding the compound or composition A means a seed or vegetative reproductive organ in which the compound or composition A is attached to its surface. The above-mentioned seed or vegetative reproductive organ holding the compound or composition A may have other materials attached to it before or after the compound or composition A is attached to it. Furthermore, if composition A is attached to the surface of a seed or vegetative reproductive organ in a layer, the layer consists of one or more layers. If it consists of multiple layers, each layer either contains one or more active ingredients, or consists of a layer containing one or more active ingredients and a layer not containing any active ingredients. Seeds or vegetative reproductive organs containing the compound or composition A can be obtained, for example, by applying composition B containing the compound or composition A to the seeds or vegetative reproductive organs using the seed treatment method described above.
[0099] Commonly known seed treatment formulations include DS, ES, FS, LS, WS, CF, GF, SS, etc., but CS, EG, EW, GW, ME, OD, OF, SC, SE, SG, SL, SP, ST, WG, WP, WT, ZC, ZE, ZW, etc. can also be used. Each of these formulations contains one of the active compounds or components in a weight ratio of 0.01 to 70%, preferably 0.1 to 50%. When treating seeds or vegetative reproductive organs with these formulations, they may be used as is or diluted with water. When treating seeds or vegetative reproductive organs with a water-diluted formulation, the dilution can be adjusted as needed depending on the active ingredient content in the formulation and the amount of active ingredient to be retained in the seeds or vegetative reproductive organs, but it is generally common to dilute it 2 to 1000 times. When treating seeds, the treatment can be applied to seeds before sowing or to seeds after germination. When treating seeds with this compound or composition A, adjuvants such as colorants and binders may be mixed in during formulation, or further mixed in when treating seeds with the formulated composition B. The coloring agent facilitates confirmation that composition B has been applied to each individual seed or vegetative reproductive organ. A binder may also be added to improve the adhesion of the active ingredient to the seeds or vegetative reproductive organ. Specific examples of coloring agents and binders are shown below. Colorants: For example, monoazo compounds (Pigment Red 48:1, Pigment Red 48:2, Pigment Red 53:1, Pigment Red 57:1, Pigment Red 112, Pigment Brown 25, Cl Solvent Red 1, Pigment Yellow 1, Pigment Orange 5, Acid Red 14, Acid Yellow 23, etc.), disazo compounds (Pigment Yellow 13, Pigment Orange 34, etc.), phthalocyanines (Pigment Blue 15:1, Pigment Blue 15:2, Pigment Blue 15:3, Pigment Blue 15:4, Pigment Green 7, Pigment Green 36, etc.), anthraquinone compounds (Pigment Red 83, etc.), dioxazine compounds (Pigment Blue 80, etc.), xanthenes (Basic Violet 10 (Rhodamine B), Acid Red 51, Acid Red 52, etc.), triarylmethane compounds (Acid Blue 9, etc.), Pigment Orange 43, iron oxide, titanium, titanium dioxide, zinc oxide, zinc sulfide, iron hexacyanoate, chromium vermilion, yellow lead, calcium carbonate, barite powder, aluminum powder; Binders: Polysaccharides (xanthan gum, cellulose ester, cellulose ether, carboxymethylcellulose, hydroxypropyl guar gum, guar gum, natural gum arabic, synthetic gum arabic, dextrin, starch, carrageenan, etc.), clays (organic clay, organically modified clay, inorganic clay, inorganically modified clay, etc.), minerals (bentonite, etc.), synthetic polymers (polycarboxylic acid or its salts, polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylic acid or its salts, styrene-butadiene copolymer, methyl methacrylate-butadiene copolymer, polyacrylic acid or its salts, polyvinyl acetate, polyvinyl alcohol, polyvinylpyrrolidone, polyethylene glycol, polypropylene glycol, etc.), waxes (vegetable oils and fats, animal oils and fats, and their derivatives, paraffin, olefins, etc.). When treating seeds or vegetative reproductive organs with composition B, an adjuvant may be mixed with composition B as needed. Seeds or vegetative reproductive organs treated with composition B are sown or planted in a field using conventional methods.
[0100] This compound and this component may be applied simultaneously and separately to plants, soil in which plants are cultivated, or locations where harmful arthropods occur, or they may be applied separately at different times to plants, cultivation carriers, or locations where harmful arthropods occur. Specifically, for example, seeds or vegetative reproductive organs treated with either this compound or this component may be applied to the cultivation carrier (e.g., soil) before or after planting the said cultivation carrier.
[0101] Composition B can be applied to plants that have been pre-treated with seeds containing one or more components selected from this composition, and to the cultivation carriers for said plants. Examples of application methods include foliar treatment, soil treatment, root treatment, shower treatment, mist spraying treatment, fumigation treatment, water surface treatment, and hydroponic solution treatment.
[0102] Examples of seed treatment agents that are applied to soybeans in advance include the following: STANDAK-TOP 500FS (Fipronil / Pyraclostrobin / Thiophanate-m), DERMACOR 625FS (Chlorantraniliprole), CRUISER 350FS (Thiamethoxam), CROPSTAR 600FS (Imidacloprid / Thiodicarb), FORTENZA 600FS (Cyantraniliprole), S-UNSPEC-INS-WHEAT, NEMAT 300WP (Verticillium), FIPRONIL-ALTA 250FS (Fipronil), MAXIM-ADVANCED 195FS (Fludioxonil / Metalaxyl-M / Thiabendazole), SHELTER 250SC (Fipronil), MAXIM-XL 035FS (Fludioxonil / Metalaxyl-M), DEROSAL Plus(Carbendazim / Thirum), Vitavax - THIRAM (Carboxin / Thiram).
[0103] Examples of seed treatment agents that are applied to corn in advance include the following: PONCHO-VOTIVO 601EC (Bacillus-firmus / Clothianidin), ACCELERON-IC-609 600EC (Clothianidin), CRUISER 600FS (Thiamethoxam), ACCELERON-D-342 480FS (Prothioconazole), PONCHO 600FS (Clothianidin), MAXIM-QUATTRO 382.5FS (Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole), AVICTA-COMPLETE-CORN-250 280FS, Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), AVICTA-COMPLETE-CORN-500 423FS, (Abamectin / Azoxystrobin / Fludioxonil / Metalaxyl-M / Thiabendazole / Thiamethoxam), LUMIVIA 625FS (Chlorantraniliprole), ACCELERON-D-281 480FS (Fluoxastrobin), ACCELERON-DC-309 312FS (Metalaxyl).
[0104] Examples of seed potato treatment agents that are applied to potatoes beforehand include the following: Maxim 4FS (fludioxonil), Maxim MZ (fludioxonil + Mancozeb), Cruiser MAXX Vibrance Potato (fludioxonil + difenoconazole + Sedaxane + Thiamethoxam), Emesto Silver (penflufen + prothioconazole), MonCoat MZ (flutolanil + Mancozeb), Moncut (flutolanil), Elatus (azoxystrobin + benzovindiflupyr), Quadris (azoxystrobin), Serenade ASO (Bacillus subtilis), DoubleNickel LC (Bacillus amyloliquefaciens), Attackin (streptomycin, thiophanate M), Flonside (fluazinam), Basidac (mepronil), Moncut (flutolanil), Rovral (iprodione), Moncut (flutolanil), Benlate (benomyl).
[0105] When applying composition B, spraying equipment can be used. Examples of equipment that can be used for application include hand-cranked sprayers, power sprayers, Pankle sprayers, manned aircraft (such as manned helicopters), unmanned aircraft (such as radio-controlled helicopters and drones), tractors, planters, etc. Alternatively, application may be done by hand without using spraying equipment.
[0106] When applying composition B using a sprayer, the spray pressure is not particularly limited, but is usually 30 to 120 PSI, preferably 40 to 80 PSI. Here, spray pressure refers to the setting before introduction to the nozzle.
[0107] When applying composition B using a sprayer, the spray nozzle is not particularly limited, but examples include flat spray nozzles, conical nozzles, rotating nozzles, hollow cone nozzles, deflector nozzles, and straight nozzles.
[0108] When composition B is applied in solution form, the pH and hardness of the solution are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500 on the American hardness scale. The time of day for applying composition B is not particularly limited, but it is generally between 5 a.m. and 9 p.m. Furthermore, the photon flux density at the grass canopy level at the location where composition B is applied is usually 10 to 2500 micromoles / m². 2 The rate is / second. The weather conditions when applying composition B are not particularly limited, but the temperature is usually 0-30°C, preferably 10-20°C, the soil temperature is usually 0-30°C, preferably 10-20°C, the relative humidity is 50-90%, preferably 40-80%, and the wind speed is 0-2 MPH.
[0109] When spraying composition B, it is usually done by spraying a spray solution obtained by mixing composition B with water. When preparing the spray solution, it can be obtained by directly diluting it with the amount of water required for the spray solution, or by mixing composition B with a small amount of water to make it uniform, and then adding water to adjust it to the specified volume. The amount of spray solution is not particularly limited, but is usually in the range of 5 to 5000 L / ha, preferably 20 to 1000 L / ha, and more preferably 140 to 300 L / ha. Specific spraying liquid volume is 10L / ha, 30L / ha, 50L / ha, 70L / ha, 90L / ha, 100L / ha, 120L / ha, 150L / ha, 180L / ha, 20 Examples include 0L / ha, 250L / ha, 300L / ha, 400L / ha, 500L / ha, 700L / ha, 900L / ha, 2000L / ha, and 4000L / ha.
[0110] When composition B is sprayed using a manned or unmanned aircraft, the spraying height is not particularly limited, but is usually 0.5 to 30 m, preferably 1 to 10 m.
[0111] When performing foliar treatment, soil treatment, root treatment, shower treatment, fumigation treatment, water surface treatment, seed treatment, and hydroponic solution treatment with composition B, composition B and an adjuvant may be mixed. They may be mixed in advance during formulation (premix) or mixed immediately before use (tank mix). The type of adjuvant is not particularly limited, but examples include COC (Crop oil concentrate) derived from mineral oil, MSO (methylated seed oil) derived from vegetable oil, alcohol-based solvents, nonionic surfactants, anionic surfactants, cationic surfactants, silicones, nitrogen fertilizers, and mixtures thereof. Specifically, AgriDex(registered trademark), Induce(registered trademark), Gramin S(registered trademark), Genamin T 200BM(registered trademark), Silwet L77(registered trademark), Nimbus(registered trademark), Assist(registered trademark), Aureo(registered trademark), Iharol Gold(registered trademark), BreakThru(registered trademark), SundanceII(registered trademark), Lutensol A8(registered trademark), NP-7(registered trademark), Triton(registered trademark), Nufilm(registered trademark), Emulgator NP7(registered trademark), Emulad(registered trademark), TRITON X 45(registered trademark), AGRAL 90(registered trademark), AGROTIN(registered trademark), ARPON(registered trademark), EnSpray N(registered trademark), BANOLE(registered trademark), Ochima(registered trademark), Agris(registered trademark), AMS (Ammonium Sulfate), UAN (Urea Ammonium Examples include Nitrate (ammonium urea nitrate), AdGreen (registered trademark), Mees (trademark), Rumba (registered trademark), Strides (registered trademark), Partner, Orix (registered trademark), and Penetrator. Furthermore, drift reducing agents such as Intact (registered trademark) may be mixed in. The weight ratio of composition B to the above adjuvant or drift reducing agent is not particularly limited, but for example, it is in the range of 1:100 to 100:1.
[0112] Composition B and fertilizer can be mixed or used in combination. When mixed, they may be pre-mixed during formulation (premix) or mixed immediately before application (tank mix). Examples of fertilizers include substances containing various elements such as nitrogen (N), phosphorus (P), potassium (K), silicon, magnesium, calcium, manganese, boron, iron, copper, zinc, sulfur, molybdenum, and cobalt. Examples of substances containing nitrogen, phosphorus, and potassium include urea, ammonium nitrate, ammonium chloride, ammonium sulfate, sodium nitrate, magnesium nitrate, nitric acid, anhydrous ammonia, urea ammonium nitrate, calcium nitrate, lime nitrogen, phosphoric acid, superphosphate, super superphosphate, potassium sulfate, potassium chloride, potassium silicate, caustic potassium, potassium nitrate, potassium phosphate, MAP (ammonium phosphate), and DAP (diammonium phosphate). The fertilizer may be in granular, powder, lump, or liquid form, and various forms of fertilizer can be used. Applications can be made on the soil surface, within the soil, or on plants. Equipment used for application includes, for example, hand-cranked sprayers, power sprayers, pankol sprayers, manned aircraft (such as manned helicopters), unmanned aircraft (such as radio-controlled helicopters and drones), tractors, planters, broadcasters, sowers, and seeders. Alternatively, application can be done by hand without using any spraying equipment. Specific application methods include, for example, applying composition B and fertilizer together to the seeds, vegetative reproductive organs, or near seedlings at the time of sowing or planting, or around the time immediately before or after sowing or planting (e.g., ±0, 1, 2, 3, 4, 5 days after sowing) (sometimes called in-furrow application). The fertilizer applied at the time of sowing or planting, or around the time immediately before or after sowing or planting, may be solid fertilizer and / or liquid fertilizer, and may include, for example, fertilizers having an N:P:K ratio (sometimes called starter fertilizer, pop-up fertilizer, etc.). Composition B and fertilizer may be mixed immediately before application, or they may be applied separately at the same time. The application location is not particularly limited as long as it is near the seeds, vegetative reproductive organs, or seedlings, but may be in the planting furrow of the seeds, vegetative reproductive organs, or seedlings, or it may be several inches away from the planting furrow of the seeds, vegetative reproductive organs, or seedlings, for example, 2 inches laterally and 2 inches below the planting furrow of the seeds, vegetative reproductive organs, or seedlings (sometimes called a 2-by-2 band). Examples of crops include corn, soybeans, sugarcane, potatoes, wheat, barley, rye, oats, and rice. The ratio of the weight of one active ingredient in composition B to the total weight of NPK in the fertilizer is not particularly limited, but for example, it may be in the range of 1:1 to 1:10000.
[0113] Composition B can be applied by spot treatment. Spot treatment is a concept opposite to uniformly applying Composition B, and means selectively spraying Composition B on areas where harmful arthropods are present or likely to be present. "Applying to a location" means applying to plants or soil where harmful arthropods are present or likely to be present, but preferably to plants. When applying to plants, this includes applying only to individuals within a plant population where harmful arthropods are present or likely to be present, as well as applying to parts of a plant where harmful arthropods are present or likely to be present. Even if Composition B is sprayed in small amounts in areas where harmful arthropods are not present or are unlikely to be present due to drift or transpiration, it is still considered a spot treatment unless it is a uniform, area-wide treatment. Furthermore, a spot treatment is not considered to occur only when all areas in a continuous cultivation area where harmful arthropods are present or likely to be present are selectively treated. In other words, even if only a portion of the cultivation area is treated in an area-wide manner, or if some areas where harmful arthropods are present or likely to be present are not treated with Composition B, if there are areas in the continuous cultivation area that have been spot-treated, it is still considered a spot treatment.
[0114] The following are specific examples of spot treatment methods. Spot treatment may be performed in a plant cultivation area by a sprayer visually spraying composition B using a handheld nozzle or robotic arm nozzle while walking, or while riding on a ground-based vehicle or flying vehicle. Furthermore, spot treatment may be performed by mapping locations where harmful arthropods have occurred or are likely to occur in advance, and spraying composition B based on the map information. In spraying based on map information, in addition to the above method, spot treatment may be performed by automatically or manually opening and closing the nozzle on the boom or robotic arm nozzle while the sprayer is moving or flying, based on the sprayer's position information (obtained by GPS, etc.) and the map information. The map information may be created based on image information taken by a manned or unmanned flying object, etc., or it may be created visually by an observer walking on the ground, an observer riding on a ground-based vehicle, or an observer riding on a flying vehicle. Furthermore, a mobile or flying sprayer may be equipped with a function to detect locations where harmful arthropods are present or likely to be present, and may perform spot treatment using the boom or robotic arm while performing real-time mapping.
[0115] Locations where harmful arthropods are present can be identified not only by visual inspection by sprayers or observers, but also through visible light image analysis, or by image analysis using specific wavelengths with hyperspectrum images. Image analysis may involve visually inspecting the screen to recognize the presence of harmful arthropods, or it may utilize artificial intelligence-based image recognition (for example, OPTiM Corporation press release, December 26, 2017). These images may be taken by manned or unmanned flying objects, or by photographers walking on the ground, photographers riding on ground-based devices, or photographers in flying devices. Locations where harmful arthropods are likely to appear may be estimated based on the fact that the harmful arthropods have occurred in patchy outbreaks during past crop cultivation seasons, or from the distribution of harmful arthropods in the soil. The distribution of harmful arthropods in the soil may be investigated by soil sampling or estimated by remote sensing. Furthermore, the presence of harmful arthropods lurking in plants may be detected and estimated through image analysis. Such technology is known as a form of emerging agriculture, also called precision agriculture, smart agriculture, or digital agriculture, and the non-uniform spraying pattern resulting from the spot treatment is sometimes referred to as VRA (Variable Rate Application) in the terminology of this emerging agriculture.
[0116] Methods for spot treatment with composition B include spraying it on the soil in areas where harmful arthropods are present or in areas where harmful arthropods are likely to be present (soil treatment), and spraying composition B on plants where harmful arthropods are present or in areas where harmful arthropods are likely to be present (foliar treatment). Spraying is usually carried out using a spray solution prepared by mixing composition B with water. The amount of spray solution is not particularly limited, but is usually 50 to 1000 L / ha, preferably 100 to 500 L / ha, and more preferably 140 to 300 L / ha within the area to be spot treated. The proportion of the area to be spot treated in the plant cultivation area (the proportion of the area to which composition B is sprayed relative to the total area of a continuous cultivation area) is usually 1 to 99%, preferably 10 to 80%. Specifically, this includes 20%, 30%, 40%, 50%, 60%, and 70%. The amount of composition B used for spot treatment is 5 to 2000 g per hectare, preferably 50 to 1500 g per hectare, more preferably 200 to 1000 g per hectare, and even more preferably 400 to 700 g per hectare, as the amount of active ingredient used for one section within the area to be spot treated. Furthermore, when performing spot treatment, adjuvants or drift reducers may be mixed in. The types of adjuvants and drift reducers are not particularly limited, but the ones mentioned above are examples. The pH and hardness of the aforementioned spray solution are not particularly limited, but the pH is usually in the range of 5 to 9, and the hardness is usually in the range of 0 to 500 on the American hardness scale. There are no specific time restrictions for performing spot treatment, but it is usually between 5:00 AM and 9:00 PM. The photon flux at the grass canopy level in the area where spot treatment is performed is typically 10 to 2500 micromoles / m². 2 The rate is per second. On the other hand, spot processing can also be performed at night using the aforementioned map information and location information. The spray pressure when performing spot treatment is not particularly limited, but is usually 30 to 120 PSI, preferably 40 to 80 PSI. Here, spray pressure is the setting before introduction to the nozzle. The weather conditions when performing spot treatment are not particularly limited, but the temperature is usually 0-30°C, preferably 10-20°C, the ground temperature is usually 0-30°C, preferably 10-20°C, the relative humidity is 50-90%, preferably 40-80%, and the wind speed is 0-2 MPH.
[0117] The treatment methods for composition B include, more specifically, treatment of planting holes (spraying in planting holes, mixing into soil during planting hole treatment), treatment around the base of the plant (spraying around the base of the plant, mixing into soil around the base of the plant, drenching around the base of the plant, treatment around the base of the plant in the latter half of the seedling stage), treatment of planting furrows (spraying in planting furrows, mixing into soil during planting furrows), treatment of furrows (spraying in furrows, mixing into soil during furrows, spraying during the growing season), treatment of furrows at the time of sowing (spraying in furrows at the time of sowing, mixing into soil during furrows), treatment of the entire area (spraying into the entire area with soil, mixing into the entire area with soil), treatment of side rows, treatment of the water surface (application to the water surface, application to the water surface after flooding), other soil spraying treatments (foliar application of granular material during the growing season, application under the tree canopy or around the main trunk, application to the soil surface, mixing into the soil surface, spraying in planting holes, application to the soil surface on ridges, application between plants), and other drenching treatments. These are sometimes called (soil drenching, seedling stage drenching, chemical injection treatment, drenching at the base of the plant, chemical drip irrigation, chemigation), seedling tray treatment (seedling tray spraying, seedling tray drenching, seedling tray watering), seedling tray treatment (seedling tray spraying, seedling tray drenching, seedling tray watering), seedbed treatment (seedbed spraying, seedbed drenching, watered seedbed spraying, seedling soaking), bed soil mixing treatment (bed soil mixing, bed soil mixing before sowing, spraying before covering with soil at sowing, spraying after covering with soil at sowing, covering with soil mixing), and other treatments (growing soil mixing, tilling in, topsoil mixing, rainwater soil mixing, planting location treatment, granular flower cluster spraying, paste fertilizer mixing, hydroponic solution mixing, hydroponic solution incorporation), etc.
[0118] Application of this compound or composition A may reduce the mycotoxin content in harvested materials and the foods and feeds prepared therefrom. The mechanism of mycotoxin reduction is not limited, but can be exerted through direct or indirect effects on mycotoxin-producing fungi, for example. Examples of direct effects include bactericidal effects on mycotoxin-producing fungi and inhibitory effects on mycotoxin biosynthesis. Examples of indirect effects include effects on the microbiome, such as the ratio of mycotoxin-producing to non-producing fungi, and reduction of fungal infections by suppressing damage from harmful arthropods. In addition, examples of mycotoxins are not limited, but include the following: Deoxynivalenol (DON), nivalenol, fusarenone X, 15-Ac-DON, 3-Ac-DON, T2- and HT2-toxins, neosolaniol, fumonisin, zearalenone, moniliformin, fusarin, diacetoxysylpenol (DAS), beaubericin, enniatin, fusaroproliferin, fusarenol, ochratoxin, patulin, sterigmatocystine, maltolidine, citrinin, rugrosin, rubratoxin, citreobyridine, cyclochlorotin, luteoskairin, loritrem B, suraflamin, sporidesmin, ergot alkaloids (e.g., lysergic acid, ergotamine, ergometrine), aflatoxin, and cyclopiazonic acid. These mycotoxins can be produced by, for example, the following fungi: Fusarium species, such as F. acuminatum, F. asiaticum, F. avenaceum, F. crookwellense, F. culmorum, F. graminearum (Gibberella zeae) F. zeae), F. equiseti, F. fujikoroi, F. moniliforme, F. musarum, F. oxysporum, F. proliferatum, F. poae, F. pseudograminearum, F. sam-bucinum, F. sam-bucinum, F. scirpi, F. semitectum, F. solani, F. sporotrichoides, F. langsethiae, F. subglutinans, F. tricinctum, F. verticillioides, etc.; Aspergillus species, e.g., A. flavus, A. parasiticus, A. nomius. , A. ochraceus, A. carbonarius, A. clavatus, A. terreus, A. versicolor; species of the genus Penicillium, e.g., P. verrucosum, P. viridicatum, P. citrinum, P. expansum, P. claviforme, P. roqueforti; species of the genus Claviceps, e.g., C. purpurea (C.*C. purpurea*, *C. fusiformis*, *C. paspali*, *C. africana*, etc.; species of the genus *Stachybotrys*; species of the genus *Slafractonia*, e.g., *S. leguminicola*; species of the genus *Neotyphodium*, e.g., *N. lolii*; species of the genus *Pithomyces*, e.g., *P. chatarum*.
[0119] Application of this compound or composition A can improve the seedling establishment rate, plant growth, and tolerance to abiotic stresses, depending on the plant species or variety, their growing location, and growing conditions (soil, climate, growing season, nutrients). These include: improved seedling establishment rates, improved plant growth, improved tolerance to abiotic stresses (e.g., improved tolerance to high or low temperatures, improved tolerance to drought, excessive moisture, or salinity in water or soil, improved tolerance to osmotic stress, improved tolerance to drought stress, improved tolerance to ozone exposure, improved tolerance to ultraviolet stress, improved tolerance to wind stress, and improved tolerance to sunlight stress). Possible improvements include enhanced fertility, improved flowering ability, easier harvesting, accelerated maturation, increased yield, increased number, size, or weight of seeds or fruits, improved leaf greenness, prolonged maintenance of leaf greenness, increased number of healthy leaves, suppression of aging, reduced plant lodging, earlier flowering, increased number of flowers or fruits, increased fruit set rate, improved quality and / or nutritional value of harvested produce (e.g., increased sugar content in fruits, improved gluten strength, optimized protein content, optimized oil content, improved nutritional value), improved storage stability and / or processability of harvested produce. More specifically, improvements in plant growth include promoting stem elongation, promoting stem thickening, promoting an increase in the number or total area of leaves, increasing the number of healthy leaves, promoting stem branching (e.g., promoting an increase in the number of stem branches), promoting lateral root formation (e.g., increasing the number of lateral roots), increasing the auxin-producing sites in the root system (tap root or lateral roots), promoting root elongation, improving root spread, and promoting root thickening. In some cases, it may also be possible to improve tolerance to nutritional stress caused by a deficiency in any of the 17 essential nutrients (essential elements) necessary for plant growth.
[0120] When composition B is used for harmful arthropods in non-agricultural fields, the application rate can be varied widely depending on the type and frequency of occurrence of the harmful arthropods being controlled, the formulation form, the timing of application, the method of application, the application location, weather conditions, etc. Specific application methods include, for example, when applied to a building, treatment of the building's walls, floors, underfloors, ceilings, roofs, attics, doors, windows, screens, etc., treatment of the building's indoor spaces, and installation of poison bait or resin formulations. When applied outdoors, examples include treatment of the ground, exterior walls, fences, and ditches; soil injection into underfloors and the ground; treatment of open spaces; and treatment of granular or resin-based formulations in water. When applied to building materials, methods such as mixing or coating the materials can be used. When applied to food and daily necessities, examples include treating the walls, floors, and ceilings of the places where the food and daily necessities are stored with emulsions, wettable powders, flowable powders, oils, etc.; treating the air with fumigants, steaming agents, or aerosols; installing poison baits, resin formulations, etc.; mixing, coating, or applying powders or emulsions to the daily necessities. When applied to wood, examples include coating, spraying, immersion, impregnation, injection, mixing during wood processing, and mixing with adhesives. When applied to vehicles, this may include treatment of the interior spaces and walls of the vehicle, or the installation of poison bait or resin formulations. When administered to animals, methods include oral administration by mixing capsules, chewable tablets, syrups, tablets, powders, and feed / drinking water; administration by suppositories and injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.); spraying, applying, or dropping liquid preparations such as spot-on, pour-on, shampoo, lotion, and paste preparations; or processing resin preparations into collars, ear tags, bracelets, and clothing and attaching them.
[0121] When composition B is used for controlling harmful arthropods in non-agricultural fields, the application rate when applied to a surface is 1 m² of treatment area. 2 The amount of one active ingredient per unit is typically 0.01 to 1000 mg, preferably 10 to 500 mg, and more preferably 20 to 400 mg (specifically, for example, 25 mg, 50 mg, or 400 mg), and the application rate when treating a space is 1 m² of the treatment space. 3The amount of one active ingredient per unit is usually 0.01 to 500 mg. When applied in water, the application rate is usually 0.001 to 1000 mg, more preferably 0.01 to 100 mg, of one active ingredient per liter of water. When applied to animals, the application rate is usually in the range of 0.01 to 1000 mg, of one active ingredient per kilogram of animal body weight. If composition B is formulated as an emulsion, wettable powder, flowable formulation, etc., it is usually diluted with water to a concentration of 0.1 to 10000 ppm of one active ingredient before application. If it is formulated as an oil formulation, etc., it is usually applied as is, or diluted with kerosene, light oil, etc. to a concentration of 0.1 to 10000 ppm of one active ingredient before application. Granules, powders, aerosols, fumigants, baits, resin formulations, etc., are applied as is. Incense sticks should be lit before use. Electric mosquito repellent mats, liquid mosquito repellent formulations, fan-type mosquito repellent formulations, ultrasonic vibration formulations, electrostatic spray formulations, etc., are usually applied using a power source or batteries.
[0122] Composition B can be used by applying it to the body surface of humans or animals to suppress the biting and unpleasant behavior of harmful arthropods such as mosquitoes and flies. It can also be used by incorporating it into feed and administering it orally to animals to suppress the occurrence and growth of flies and other insects that breed in their excrement.
[0123] Furthermore, Composition B can also be used to prevent the spread of infectious diseases transmitted by harmful arthropods (such as malaria, dengue fever, West Nile fever, yellow fever, Zika fever, filariasis, onchocerciasis, leishmaniasis, Chagas disease, and African sleeping sickness). Specific application methods include treating the interior walls of houses with Composition B (Indoor Residual Spray; IRS), treating outdoor spaces (Space spray), using mosquito nets (Long-lasting insecticidal nets), wallpaper, poison bait, egg-laying traps, traps, spatial repellent devices, and automatic propagation devices, as well as treating water jars, reservoirs, streams, etc. (pest source control, Larvicide).
[0124] Application of this compound or composition A can improve the seedling establishment rate, plant growth, and tolerance to abiotic stresses, depending on the plant species or variety, their growing location, and growing conditions (soil, climate, growing season, nutrients). These include: improved seedling establishment rates, improved plant growth, improved tolerance to abiotic stresses (e.g., improved tolerance to high or low temperatures, improved tolerance to drought, excessive moisture, or salinity in water or soil, improved tolerance to osmotic stress, improved tolerance to drought stress, improved tolerance to ozone exposure, improved tolerance to ultraviolet stress, improved tolerance to wind stress, and improved tolerance to sunlight stress). Possible improvements include enhanced fertility, improved flowering ability, easier harvesting, accelerated maturation, increased yield, increased number, size, or weight of seeds or fruits, improved leaf greenness, prolonged maintenance of leaf greenness, increased number of healthy leaves, suppression of aging, reduced plant lodging, earlier flowering, increased number of flowers or fruits, increased fruit set rate, improved quality and / or nutritional value of harvested produce (e.g., increased sugar content in fruits, improved gluten strength, optimized protein content, optimized oil content, improved nutritional value), improved storage stability and / or processability of harvested produce. More specifically, improvements in plant growth include promoting stem elongation, promoting stem thickening, promoting an increase in the number or total area of leaves, increasing the number of healthy leaves, promoting stem branching (e.g., promoting an increase in the number of stem branches), promoting lateral root formation (e.g., increasing the number of lateral roots), increasing the auxin-producing sites in the root system (tap root or lateral roots), promoting root elongation, improving root spread, and promoting root thickening. In some cases, it may also be possible to improve tolerance to nutritional stress caused by a deficiency in any of the 17 essential nutrients (essential elements) necessary for plant growth.
[0125] When composition B is used for controlling harmful arthropods in non-agricultural fields, the application rate can be varied widely depending on the type and frequency of occurrence of the harmful arthropods being controlled, the formulation form, the timing of application, the method of application, the application location, weather conditions, etc. Specific application methods include, for example, when applied to a building, treatment of the building's walls, floors, underfloors, ceilings, roofs, attics, doors, windows, screens, etc., treatment of the building's indoor spaces, and installation of poison bait or resin formulations. When applied outdoors, examples include treatment of the ground, exterior walls, fences, and ditches; soil injection into underfloors and the ground; treatment of open spaces; and treatment of granular or resin-based formulations in water. When applied to building materials, methods such as mixing or coating the materials can be used. When applied to food and daily necessities, examples include treating the walls, floors, and ceilings of the places where the food and daily necessities are stored with emulsions, wettable powders, flowable powders, oils, etc.; treating the air with fumigants, steaming agents, or aerosols; installing poison baits, resin formulations, etc.; mixing, coating, or applying powders or emulsions to the daily necessities. When applied to wood, examples include coating, spraying, immersion, impregnation, injection, mixing during wood processing, and mixing with adhesives. When applied to vehicles, this may include treatment of the interior spaces and walls of the vehicle, or the installation of poison bait or resin formulations. When administered to animals, methods include oral administration by mixing capsules, chewable tablets, syrups, tablets, powders, and feed / drinking water; administration by suppositories and injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.); spraying, applying, or dropping liquid preparations such as spot-on, pour-on, shampoo, lotion, and paste preparations; or processing resin preparations into collars, ear tags, bracelets, and clothing and attaching them.
[0126] When composition B is used for controlling harmful arthropods in non-agricultural fields, the application rate when applied to a surface is 1 m² of treatment area. 2 The amount of one active ingredient per unit is typically 0.01 to 1000 mg, preferably 10 to 500 mg, and more preferably 20 to 400 mg (specifically, for example, 25 mg, 50 mg, or 400 mg), and the application rate when treating a space is 1 m² of the treatment space. 3The amount of one active ingredient per unit is usually 0.01 to 500 mg. When applied in water, the application rate is usually 0.001 to 1000 mg, more preferably 0.01 to 100 mg, of one active ingredient per liter of water. When applied to animals, the application rate is usually in the range of 0.01 to 1000 mg, of one active ingredient per kilogram of animal body weight. If composition B is formulated as an emulsion, wettable powder, flowable formulation, etc., it is usually diluted with water to a concentration of 0.1 to 10000 ppm of one active ingredient before application. If it is formulated as an oil formulation, etc., it is usually applied as is, or diluted with kerosene, light oil, etc. to a concentration of 0.1 to 10000 ppm of one active ingredient before application. Granules, powders, aerosols, fumigants, baits, resin formulations, etc., are applied as is. Incense sticks should be lit before use. Electric mosquito repellent mats, liquid mosquito repellent formulations, fan-type mosquito repellent formulations, ultrasonic vibration formulations, electrostatic spray formulations, etc., are usually applied using a power source or batteries.
[0127] Composition B can be used by applying it to the body surface of humans or animals to suppress the biting and unpleasant behavior of harmful arthropods such as mosquitoes and flies. It can also be used by incorporating it into feed and administering it orally to animals to suppress the occurrence and growth of flies and other insects that breed in their excrement.
[0128] Furthermore, Composition B can also be used to prevent the spread of infectious diseases transmitted by harmful arthropods (such as malaria, dengue fever, West Nile fever, yellow fever, Zika fever, filariasis, onchocerciasis, leishmaniasis, Chagas disease, and African sleeping sickness). Specific application methods include treating the interior walls of houses with Composition B (Indoor Residual Spray; IRS), treating outdoor spaces (Space spray), using mosquito nets (Long-lasting insecticidal nets), wallpaper, poison bait, egg-laying traps, traps, spatial repellent devices, and automatic propagation devices, as well as treating water jars, reservoirs, streams, etc. (pest source control, Larvicide).
[0129] Examples of plants that can use composition B include the following: Crops; Corn (Horsetail, hard-grain, soft-grain, popping, glutinous, sweet, field corn), Rice (Long-grain, short-grain, medium-grain, Japonica, tropical Japonica, Indica, Javanica, paddy rice, upland rice, floating rice, direct seeding, transplanting, glutinous rice), Wheat (Bread wheat (hard, soft, medium, red wheat, white wheat), durum wheat, spelt wheat) Crab wheat (winter wheat type, spring wheat type), barley (two-row barley (=malting barley), six-row barley, hulless barley, glutinous barley, winter wheat type, spring barley type), rye (winter rye type, spring rye type), triticare (winter triticare type, spring triticare type), oats (winter oat type, spring oat type), sorghum, cotton (Upland variety, Pima variety), soybeans (fully ripened seed harvest varieties, edamame varieties, green-harvested varieties, infinite growth type, finite growth type, semi-finite growth type), peanuts, kidney beans, lima beans, adzuki beans, cowpeas, mung beans, black beans, red beans, bamboo beans, moth beans, teparly beans, broad beans, edamame Gentiana, chickpea, lentil, lupin, pigeon pea, alfalfa, potato (tetraploid, diploid, true seed varieties), buckwheat, sugar beet (for sugar production, animal feed, root vegetables, leafy vegetables, fuel), rapeseed (winter rapeseed type, spring rapeseed type), canola (winter canola type, spring canola type), sunflower (for oil extraction, food, ornamental), sugarcane, tobacco, tea plant, mulberry, etc. Vegetables; Solanaceae vegetables (eggplant, tomato, bell pepper, chili pepper, bell pepper, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, squash, etc.), Brassicaceae vegetables (radish, turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, mustard greens, broccoli, cauliflower, etc.), Asteraceae vegetables (burdock, garland chrysanthemum, artichoke, lettuce, etc.), Liliaceae vegetables (leek, onion, garlic, asparagus, etc.), Apiaceae vegetables (carrot, parsley, celery, angelica tree, etc.), Amaranthaceae vegetables (spinach, Swiss chard, etc.), Lamiaceae vegetables (perilla, mint, basil, lavender, etc.), strawberries, sweet potatoes, yams, taro, etc. Fruit trees; pome fruits (apples, European pears, Japanese pears, Chinese pears, quince, cinnamon, etc.), drupes (peaches, plums, nectarines, apricots, cherries, prunes, etc.), citrus fruits (Satsuma mandarins, oranges, lemons, limes, grapefruit, etc.), nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, macadamia nuts, etc.), berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons, figs, olives, loquats, bananas, coffee, dates, coconuts, etc. Ornamental plants; flowering trees, street trees (ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, redbud, sweetgum, plane tree, zelkova, cypress, fir, hemlock, juniper, pine, spruce, yew), flowering plants, foliage plants, grasses.
[0130] The aforementioned plants are not limited to any varieties that are commonly cultivated.
[0131] Examples of corn varieties include the following: P30F53, P30F53RR, P30F53YHV, DKB390, DKB390IPRO3, DKC62-08, DKC35-88RIB RR2 BT, P7958AM RR2 LL BT, NK1120-3122 RR+GLU+ECB+CRW, P9608AM LL RR2 CRW ECB, Golden Bantam
[0132] Examples of wheat varieties include the following: PAKITO; KWS Zyatt; Skyfall; Crusoe; RGT Illustrious; KWS Extrase; KWS Extase; KWS Siskin; LG Detroit; KWS Lili; KWS Firefly; KWS Barrel; Elicit; KWS Basset; Zulu; Viscount; Revelation; SY Insight; KWS Kinetic; Gleam; RGT Gravity; KWS Kerrin; Shabras; Graham; KWS Crispin; Theodore; Dunston; Costello
[0133] Examples of barley varieties include the following: Electrum; Craft; SY Venture; KWS Hawking; LG Mountain; KWS Gimlet; Jordan; LG Flynn; KWS Orwell; Valerie; Surge; KWS Creswell; KWS Tower; KWS Glacier; California; KWS Cassia; Belmont; SY Kingsbarn; SY Baracooda; Cosmopolitan; SY Tungsten; LG Diablo; Laureate; RGT Planet; RGT Asteroid; Iconic; KWS Sassy; Sienna; Propino; Fairing; Concerto; Fairway; Prospect
[0134] Examples of soybean varieties include the following: 5G8015 RR IPRO; ANTA 82 PR; AS 3797 IPRO; BMX POTENCIA RR; BRS 8170IPRO; BRS 8280 RR; DM 6583 IPRO; M 5947 IPRO; M 6410 IPRO; M 8644 IPRO; M8372 IPRO; M9114PR; MONSOY 5947 IPRO; MONSOY 7730 IPRO; MSOY 8372 IPRO; NA 5909 RG; NS 5445 IPRO; NS 5909 PR; NS 5969 IPRO; NS 6700 IPRO; ST 797; TMG 1180 RR; TMG 1188 RR NS 4823 RR; NS 5445 IPRO; NA 5909 RR; NS 6209 RR; NS 6601 IPRO; NS 6823 RR; NS 6906 IPRO; NS 7000 IPRO; NS 7200 RR; NS 7227 RR; NS 7300 IPRO; NS 7474 IPRO; NS 7505 IPRO; NS 7709 IPRO; NS 8270 IPRO; NS 8393 IPRO RR; NS 5106 IPRO; NS 5727 IPRO; NS 5959 IPRO; NS 6390; NS 6700 IPRO; NS 6828; NS 6909 IPRO - Centro; NS 7000 IPRO -SUL; NS 7202 IPRO; NS 7237 IPRO; NA 7337 RR; NS 7490 RR; NS 7667 IPRO; NS 7901; NS 8338 IPRO; NS 8490 IPRO; NS 5160 IPRO; NA 5909- RG IPRO; NS 6006 IPRO; NS 6535 IPRO; NS 6767 RR; NS 6906 IPRO - Centro; NS 6909 IPRO - Sul; NS 7070 IPRO; NS 7209 IPRO; NS 7300 IPRO - Centro; NS 7338 IPRO; NS 7497 RR; NS 7670 RR ; NS 8094 RR; NS 8383 RR; Syn 15600 IPRO;Syn 16861 IPRO; Syn 1059 RR; Syn 1163 RR; Syn 1258 RR; Syn 1281 RR; Syn 1683 IPRO; Syn 1785 IPRO; Syn 1687 IPRO; Syn 13610 IPRO; Syn 15640 IPRO; Syn 15630 IPRO; Syn 1562 IPRO; Syn 1561 IPRO; Syn 1366 IPRO; CZ 15B64 IPRO; CZ15B70 IPRO; CZ 15B92 IPRO; CZ 26B05 IPRO; CZ 26B10 IPRO; CZ 26B77 IPRO; CZ 7022 IPRO; CZ 26B42 IPRO; CZ 26B36 IPRO; CZ 26B42 IPRO; CZ 26B77 IPRO; TEC 7022 IPRO; CZ 37B22 IPRO; CZ 37B43 IPRO; CZ 47B90 IPRO; CZ 58B28 IPRO; CZ 48B32 IPRO; CZ 58B61 IPRO; W 791 RR; W 842 RR; CZ 58B61 IPRO; BS 1511 IPRO; BS 1543 IPRO; ST 575 IPRO; BS 1580 IPRO; ST 592 IPRO; BS 2590 IPRO; BS 2606 IPRO- SUL; ST 644 IPRO; BSIRGA 1642 IPRO; TEC 6702 IPRO; BS 1691 IPRO; TEC 7849 IPRO; TECIRGA 6070 RR; BS 1519 LL; BS 2606 IPRO -CERRADO; TEC 6702 IPRO -CERRADO; TEC 7849 IPRO-CERRADO; ST 721 IPRO; TEC 7578 IPRO; ST 777 IPRO; ST 797 IPRO; ST 804 IPRO; ST 830 IPRO; ST 845 IPRO; W 787 IPRO; W 799 RR; ST 815 RR; ST 820 RR; ST 860 RR; ST 920 RR; W 870; BRASMAX COMPACTA IPRO; BRASMAX FIBRA IPRO BRASMAX ZEUS IPRO; BRASMAX DELTA IPRO; BRASMAX RAIO IPRO; BRASMAX ICONE IPRO; BRASMAX LANCA IPRO; BRASMAX GARRA IPRO; BRASMAX PONTA IPRO BRASMAX VALENTE RR; BRASMAX POTENCIA RR; BRASMAX TORNADO RR; BRASMAX ALVO RR; BRASMAX ATIVA RR; BRASMAX VELOZ RR; BRASMAX VELOZ RR; BRASMAX VORAZ IPRO; BRASMAX EXTREMA IPRO; BRASMAX UNICA IPRO; BRASMAX DOMINIO IPRO; BRASMAX FOCO IPRO; BRASMAX EXTREMA IPRO; BRASMAX EXTRA IPRO; BRASMAX CERTA IPRO; BRASMAX POWER IPRO; BRASMAX ULTRA IPRO; BRASMAX FLX IPRO; BRASMAX BONUS; BRASMAX PONTA IPRO; BRASMAX OPUS IPRO; BRASMAX DESAFIO RR; M5705IPRO; MS5838IPRO; M5892IPRO; M8644IPRO; M5917IPRO; M5947IPRO; M6210IPRO; M7739IPRO; M8349IPRO; M8372IPRO; M6410IPRO; M7110IPRO; M7198IPRO; M8210IPRO; M8808IPRO; 95R51; 95Y52; 97R22IPRO; 99R03; P98Y70; 95R90IPRO; 95Y72; 98Y21IPRO; 99R09; 95R95IPRO; 96Y90; 98Y30; P98C81; BG4290; BG4786; CD2720 IPRO; CD2728 IPRO; CD2820 IPRO; CD2851 IPRO; CD2857 RR; DS5916 IPRO; 5D6215 IPRO; 5D634 RR; 5G8015 IPRO; DS6017 IPRO; DS7417 IRPO; B5860 IPRO; BG4781 IPRO; DS6217 IPRO; TMG2375 IPRO; TMG2379 IPRO; TMG7058 IPRO; TMG2165 IPRO; TMG2165 IPRO; TMG4377 IPRO; TMG1180 RR;TMG7063IPRO; TMG7062 IPRO; TMG7067 IPRO; TMG4182; TMG4182; TMG7262 RR; TMG2185 IPRO; TMG7061 IPRO; TMG2381 IPRO; TMG2383 IPRO; TMG1288 RR; TMG2181 IPRO; TMG1188 RR; TMG2378 IPRO; TMG2173 IPRO; TMG4185; TMG 7363 RR: TMG7260 IPRO; TMG133 RR; TMG132 RR; ANTA82; TMG1182 RR; TMG2182 IPRO; TMG7161 RR; TMG2183 IPRO; TMG2286 IPRO; K8620 IPRO; RK5519 RR; M6210 IPRO; RK6719 IPRO; RK6316 IPRO; RK7518 IPRO; RK8115 IPRO; RK8317 IPRO; RK5813 RR; RK6813 RR; BRS 1001IPRO; BRS 1074IPRO; BRS 6970IPRO; BRS 7570IPRO; BRS 9383IPRO; BRS 1003IPRO; BRS 706IPRO; BRS 7170IPRO; BRS 7780IPRO; BRS 1007IPRO; BRS 713IPRO; BRS 7270IPRO; BRS 7180IPRO; BRS1010IPRO; BRS 729IPRO; 413RR; BRS 8890RR; BRSGO 8151RR; BRSMG 850GRR; BRS 378RR; BRSMG 760SRR; BRS 9090RR; BRS 740SRR; 750SRR; BRS Sambaiba RR; BRS 359RR; BRS 399RR; BRS 8160RR; BRS 7460RR; BRSMG 811CRR; BRS VALIOSA RR; BRS 232; BRS 283; BRS 257;BRS 284; BRSGO LUZIANIA; BRS Petala; BRSMG 790A; BRSMG 7525; MG / BR 46 (Conquista); BRS 8381; BRS 217 (Flora); BRS 252 (Serena); BRSMG 810C; BRSMG 68 (Vencedora); BRSGO Chapadoes; BRS Raimunda; BRS313 (TIETA); BRS Corisco; BRS Barreiras; BRS 314 (Gabriela); BRS Tracaja; BRS Perola
[0135] The aforementioned plant varieties are not particularly limited as long as they are commonly cultivated varieties.
[0136] The aforementioned plants may include plants that can be produced through natural crossbreeding, plants that can arise through spontaneous mutation, F1 hybrid plants, and transgenic plants (also known as genetically modified plants). These plants generally possess characteristics such as resistance to herbicides, accumulation of toxic substances in harmful organisms (also known as pest resistance), suppression of susceptibility to diseases (also known as disease resistance), increased yield potential, improved resistance to biological and abiotic stressors, modification of product quality (e.g., increase or decrease in the content of specific components, changes in composition, improvement of storability or processability), and modification of harvest time (e.g., very early, early, mid-season, late, very late).
[0137] F1 hybrid plants are first-generation hybrids obtained by crossing two different strains of a variety, and generally possess hybrid vigor, meaning they have superior traits compared to either parent. Transgenic plants are plants that have been given traits that cannot be easily obtained through natural crossbreeding, mutation induction, or natural recombination by introducing foreign genes from other organisms such as microorganisms.
[0138] The technologies used to create the plants mentioned above include, for example, conventional plant breeding techniques; genetic engineering techniques; genome breeding techniques; new breeding techniques; and genome editing techniques. Conventional plant breeding techniques are those that obtain plants with desirable traits through mutation or crossbreeding. Genetic engineering techniques are those that confer new traits to an organism by extracting a target gene (DNA) from an organism (for example, a microorganism) and introducing it into the genome of another target organism, or by silently interfering with other genes present in a plant to confer new or improved characteristics, such as antisense techniques or RNA interference techniques. Genome breeding techniques are those that use genomic information to streamline breeding, and include DNA marker (also called genome marker or gene marker) breeding techniques and genomic selection. For example, DNA marker breeding is a method of selecting offspring with the desired useful trait gene from a large number of crossbreeding offspring using DNA markers, which are DNA sequences that serve as markers for the location of a specific useful trait gene on the genome. By analyzing the progeny of the cross using DNA markers while they are still seedlings, this method effectively shortens the time required for breeding. Furthermore, genomic selection is a technique that creates a prediction formula from previously obtained phenotypic and genomic information, and predicts characteristics from the prediction formula and genomic information without evaluating phenotypes, and is a technology that can contribute to the efficiency of breeding. New breeding techniques are a general term for plant breeding techniques that combine molecular biological methods. Examples include cisgenesis / intragenesis, oligonucleotide-directed mutagenesis, RNA-dependent DNA methylation, genome editing, grafting onto GM rootstock or scion, reverse breeding, agroinfiltration, and seed production technology (SPT). Genome editing technology is a technique that transforms genetic information in a sequence-specific manner, and can perform deletions of base sequences, substitutions of amino acid sequences, and introduction of foreign genes. Examples of such tools include zinc finger nucleases (ZFNs), TALEN, CRISPR / Cas9, CRISPR / Cpf1, and meganucleases, which are capable of sequence-specific DNA cleavage. In addition, there are sequence-specific genome modification technologies such as CAS9 nickase and Target-AID, which have been created by modifying the aforementioned tools.
[0139] Examples of the aforementioned plants include those listed in the GM Approval Database on the International Service for the Acquisition of Agri-Biotech Applications (ISAA) electronic information site (http: / / www.isaaa.org / ). More specifically, these include herbicide-resistant plants, insect-resistant plants, disease-resistant plants, plants with modified product quality (e.g., increased or decreased component content, changes in composition, improved shelf life or processability), plants with modified fertility traits, plants with abiotic stress tolerance, or plants with modified growth or yield traits.
[0140] Examples of plants that have been given herbicide resistance are listed below. Mechanisms of herbicide resistance include, for example, reducing the affinity between the herbicide and its target; rapid metabolism of the herbicide (decomposition, modification, etc.) through the expression of enzymes that inactivate the herbicide; inhibition of herbicide uptake into the plant; and inhibition of herbicide transfer within the plant.
[0141] Plants that have been conferred herbicide resistance through genetic engineering include, for example, plants that have been conferred resistance to protoporphyrinogen oxidase (hereinafter abbreviated as PPO) herbicides such as flumioxazine; 4-hydroxyphenylpyruvate dioxygenase (hereinafter abbreviated as HPPD) inhibitors such as isoxaflutol and mesotrione; acetolactic acid synthase (hereinafter abbreviated as ALS) inhibitors such as imidazolinone herbicides such as imazetapir and sulfonylurea herbicides such as thifensulfuron-methyl; 5-enolpyruvirshikimate-3-phosphate synthase (hereinafter abbreviated as EPSPS) inhibitors such as glyphosate; glutamine synthase inhibitors such as glufosinate; auxin-type herbicides such as 2,4-D and dicamba; and oxynyl herbicides such as bromoxynil. Preferred herbicide-resistant transgenic plants include cereals such as wheat, barley, rye, and oats, as well as vegetables such as canola, sorghum, soybeans, corn, cotton, rice, rapeseed, sugar beets, sugarcane, grapes, lentils, sunflowers, alfalfa, pome fruits, drupes, coffee, tea, strawberries, grass, tomatoes, potatoes, cucumbers, and lettuce; more preferably, cereals such as wheat, barley, rye, and oats, as well as soybeans, corn, rice, grapes, tomatoes, potatoes, and pome fruits. The following lists specific herbicide-resistant plants. Glyphosate-resistant plants are obtained by introducing one or more of the following: a glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4; a modified glyphosate N-acetyltransferase gene (gat4601 or gat4621) derived from Bacillus licheniformis; a glyphosate oxidase gene (goxv247) derived from Ochrobacterium anthropi strain LBAA; or an EPSPS gene (mepsps or 2mepsps) from maize (Zea mays) that has a glyphosate-resistant mutation. The main plants include, for example, alfalfa (Medicago sativa), Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), creeping bentgrass (Agrostis stolonifera), corn (Zea mays L.), Polish canola (Brassica rapa), potato (Solanum tuberosum L.), soybean (Glycine max L.), sugar beet (Beta vulgaris), and wheat (Triticum aestivum). Several glyphosate-tolerant plants are commercially available. For example, genetically modified plants that have been introduced with CP4 epsps are sold under trademark names including "Roundup Ready(registered trademark)", genetically modified plants that have been introduced with gat4601 or gat4621 are sold under trademark names such as "Optimum GAT(registered trademark)" and "Optimum(registered trademark) Gly canola", and genetically modified plants that have been introduced with mepsps or 2mepsps are sold under the trademark name "GlyTol(registered trademark)".More specific examples of glyphosate-tolerant plants include, for example, corn varieties such as "Roundup Ready™ Maize," "Roundup Ready™ 2 Maize," "Agrisure™ GT," "Agrisure™ GT / CB / LL," "Agrisure™ GT / RW," "Agrisure™ 3000GT," "YieldGard™ VT™ Rootworm™ RR2," and "YieldGard™ VT Triple"; soybeans such as "Roundup Ready™ Soybean" and "Optimum GAT™"; cotton varieties such as "Roundup Ready™ Cotton," "Roundup Ready™ Flex Cotton," and "GlyTol™"; canola varieties such as "Roundup Ready™ Canola" and "Optimum™ Gly canola"; alfalfa varieties such as "Roundup Ready™ Alfalfa"; and rice varieties such as "Roundup Ready® Rice; sugarcane is sold under the trademark names "Roundup Ready® sugarbeet" and "InVigor® sugarbeet"; and wheat (Triticum aestivum) is sold under the trademark name "Roundup Ready® wheat". Glyfosinate herbicide-resistant plants are obtained by introducing one or more of the following: the phosphinothricin N-acetyltransferase (PAT) gene (bar) from Streptomyces hygroscopicus, the PAT gene (pat) from Streptomyces viridochromogenes, or the synthesized PAT gene (pat syn) from Streptomyces viridochromogenes strain Tu494. Commonly resistant plants include, for example, Argentine canola (Brassica napus), chicory (Cichorium intybus), cotton (Gossypium hirsutum L.), corn (Zea mays L.), Polish canola (Brassica rapa), rice (Oryza sativa L.), soybean (Glycine max L.), and sugar beet (Beta vulgaris). Several glufosinate-resistant plants are commercially available. For example, genetically modified plants with bar or pat introduced are sold under the trademark names "LibertyLink®", "InVigor®", or "WideStrike®". More specific glyfosinate-tolerant plants are sold under the brand names "Roundup Ready™ 2", "Liberty Link™", "Herculex™ I", "Herculex RW", "Herculex XTRA™", "Agrisure™ GT / CB / LL", "Agrisure™ CB / LL / RW", and "Bt10" for corn; "FiberMax™ Liberty Link™" for cotton; "Liberty Link™ Rice" for rice; "inVigor™ Canola" for canola; "Liberty Link™ Soybean" for soybeans; and "Liberty Link™ sugarbeet" for sugarcane. Plants resistant to oxynyl herbicides (e.g., bromoxynil) are obtained by introducing the nitrilase gene (bxn) derived from Klebsiella pneumoniae subsp. Ozaenae. Examples of such plants include Argentine canola (Brassica napus), cotton (Gossypium hirsutum L.), and tobacco (Nicotiana tabacum L.). Several oxynyl herbicide-resistant plants are commercially available, for example, sold under brand names including "Navigator®" or "BXN®". More specific examples of oxynyl herbicide-resistant plants include cotton sold under the brand name "BXN® Cotton" and Argentine canola sold under the brand name "Navigator® Cotton". ALS herbicide-resistant plants: Carnations (Dianthus caryophyllus) into which the ALS gene (surB) derived from tobacco (Nicotiana tabacum) has been introduced as a selection marker are sold under the trademark names "Moondust(trademark)", "Moonshadow(trademark)", "Moonshade(trademark)", "Moonlite(trademark)", "Moonaqua(trademark)", "Moonvista(trademark)", "Moonique(trademark)", "Moonpearl(trademark)", "Moonberry(trademark)", or "Moonvelvet(trademark)". Flax (Linum usitatissumum L.) into which the ALS gene (als) derived from Arabidopsis thaliana has been introduced is sold under the trademark name "CDC Triffid Flax", for example. For example, corn (Zea mays L.) that has been introduced with the corn-derived ALS herbicide-resistant ALS gene (zm-hra) and is resistant to sulfonylurea and imidazolinone herbicides is sold under the brand name "Optimum GAT(trademark)". For example, soybeans that have been introduced with the Arabidopsis thaliana-derived ALS herbicide-resistant ALS gene (csr1-2) and are resistant to imidazolinone herbicides are sold under the brand name "Cultivance". For example, soybeans that have been introduced with the soybean (Glycine max)-derived ALS herbicide-resistant ALS gene (gm-hra) are sold under the brand names "Treus(trademark)", "Plenish(trademark)", and "Optimum GAT(trademark)". In addition, there is cotton that has been introduced with the tobacco (Nicotiana tabacum cv. Xanthi)-derived ALS herbicide-resistant ALS gene (S4-HrA). HPPD herbicide-resistant plants are obtained by introducing the HPPD gene (avhppd-03) derived from oats (Avena sativa). For example, soybeans into which the above gene and the PAT gene (pat) derived from Streptomyces viridochromogenes have been introduced simultaneously are sold under the trademark name "Herbicide-tolerant Soybean line" as soybeans resistant to mesotrione and glufosinate. 2,4-D-resistant plants or ACCase herbicide-resistant plants: Corn resistant to 2,4-D or ACCase herbicides, introduced with the aryloxyalkanoate dioxygenase gene (aad-1) from Sphingobium herbicidovorans, is sold under the brand name "Enlist(trademark) Maize," for example. Soybeans and cotton resistant to 2,4-D or ACCase herbicides, introduced with the aryloxyalkanoate dioxygenase gene (aad-12) from Delftia acidovorans, are known and sold under the brand name "Enlist(trademark) Soybean," for example. Dicamba herbicide-resistant plants are obtained by introducing the dicamba monooxygenase gene (dmo) derived from Stenotrophomonas maltophilia strain DI-6. Soybeans and cotton plants into which this gene has been introduced are known. Soybeans (Glycine max L.) into which the glyphosate-resistant EPSPS gene (CP4 epsps) derived from Agrobacterium tumefaciens strain CP4 has been introduced simultaneously with this gene are sold under the trademark name "Genuity® Roundup Ready® 2 Xtend®". Further plants with modified resistance to herbicides are widely known, for example, alfalfa, apple, barley, eucalyptus, flax, grape, lentil, rapeseed, pea, potato, rice, sugar beet, sunflower, tobacco, tomato, sedge, and wheat resistant to glyphosate (see, e.g., US5188642, US4940835, US5633435, US5804425, US5627061); and beans, cotton, soybeans, peas, potatoes, sunflowers, and tomatoes resistant to dicamba. , tobacco, corn, sorghum and sugarcane (see, e.g., WO2008 / 051633, US7105724 and US5670454); soybeans, sugar beets, potatoes, tomatoes and tobacco resistant to glufosinate (see, e.g., US6376754, US5646024, US5561236); cotton, peppers, apples, tomatoes, sunflowers, tobacco, potatoes, corn, cucumbers, wheat, soybeans, sorghum and other grains resistant to 2,4-D (see, e.g., US6153401, See US6100446, WO2005 / 107437, US5608147 and US5670454; Canola, corn, millet, barnyard grass, cotton, mustard, lettuce, lentils, melon, foxtail millet, oats, kudzu, potatoes, rice, rye, sorghum, soybeans, sugar beets, sunflowers, tobacco, tomatoes and wheat (see US5013659, WO2006 / 060634, US4761373, US5304732, US6211438, US6211439 and US5670454) which are resistant to ALS inhibitor herbicides (e.g., sulfonylurea herbicides or imidazolinone herbicides); See US6222100), and in particular, rice plants resistant to imidazolinone herbicides are known to have specific mutations in the acetohydroxyacid synthase gene (e.g., S653N, S654K, A122T, S653(At)N, S654(At)K, A122(At)T (see, e.g., US2003 / 0217381, WO2005 / 020673); HPPD inhibitor herbicides (e.g., isoxazole herbicides such as isoxaflutol);Examples include barley, sugarcane, rice, maize, tobacco, soybean, cotton, rapeseed, sugar beet, wheat, and potato resistant to diketonitrile, a degradation product of isoxaflutol (see, e.g., WO2004 / 055191, WO1996 / 38567, WO1997 / 049816, and US6791014); and wheat, soybean, cotton, sugar beet, rapeseed, rice, maize, sorghum, sugarcane, and sugar beet resistant to PPO inhibitor herbicides (see, e.g., US2002 / 0073443, US2008 / 0052798, Pest Management Science, 61, 2005, 277-285).
[0142] Plants that have been given herbicide resistance through conventional breeding techniques or genome breeding techniques include, for example, rice "Clearfield® Rice", wheat "Clearfield® Wheat", sunflower "Clearfield® Sunflower", lentils "Clearfield® lentils", and canola "Clearfield® canola" (BASF products) that are resistant to imidazolinone-based ALS inhibitor herbicides such as imazetapyr and imazamox; soybeans "STS soybean" that are resistant to sulfonylurea-based ALS inhibitor herbicides such as thifensulfuron-methyl; and corn "SR corn" ("Poast Protected®") that is resistant to acetyl-CoA carboxylase inhibitors such as trione oxime herbicides and aryloxyphenoxypropionic acid herbicides. Examples include "ExpressSun®," a sunflower resistant to sulfonylurea herbicides such as tribeurone (also known as "corn"); "Provisia® Rice," a rice variety resistant to acetyl-CoA carboxylase inhibitors such as quizalohop; and "Triazine Tolerant Canola," a canola resistant to photosystem II inhibitors; and "Igrowth®," a sorghum resistant to imidazolinone herbicides.
[0143] One example of a plant conferred with herbicide resistance through genome editing technology is "SU Canola®," a canola variety with sulfonylurea herbicide resistance developed using Rapid Trait Development System (RTDS®). RTDS® is a genome editing technology that involves oligonucleotide-directed mutagenesis, and it is a technology that can introduce mutations in plants without cleaving the DNA, via Gene Repair Oligonucleotide (GRON), which is a chimeric oligonucleotide of DNA and RNA. Other examples include maize in which herbicide resistance and phytic acid content were reduced by deleting the endogenous gene IPK1 using zinc finger nuclease (see, e.g., Nature 459, 437-441 2009); and rice in which herbicide resistance was conferred using CRISPR-Cas9 (see, e.g., Rice 7, 5 2014).
[0144] An example of a plant conferred with herbicide resistance through new breeding techniques is soybeans, in which the properties of a GM rootstock have been conferred to the scion using grafting-based variety improvement techniques. Specifically, this includes soybeans in which glyphosate resistance has been conferred to non-transgenic soybean scions by using Roundup Ready® soybeans, which have glyphosate resistance, as the rootstock (see Weed Technology 2013, 27, 412).
[0145] Examples of plants that have been given pest resistance are listed below.
[0146] Examples of plants that have been genetically modified to possess resistance to lepidopteran pests include corn (Zea mays L.), soybeans (Glycine max L.), cotton (Gossypium hirsutum L.), rice (Oryza sativa L.), poplar (Populus sp.), tomatoes (Lycopersicon esculentum), eggplants (Solanum melongena), and sugarcane (Saccharum sp.), into which genes encoding delta-endotoxin, an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereinafter abbreviated as Bt bacteria), have been introduced. Examples of delta-endotoxins that confer resistance to lepidopteran pests include Cry1A, Cry1Ab, modified Cry1Ab (partially deficient Cry1Ab), Cry1Ac, Cry1Ab-Ac (a hybrid protein fused with Cry1Ab and Cry1Ac), Cry1C, Cry1F, Cry1Fa2 (modified cry1F), moCry1F (modified Cry1F), Cry1A.105 (a hybrid protein fused with Cry1Ab, Cry1Ac, and Cry1F), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, and Vip3Aa20. Examples of plants conferred with resistance to Coleopteran pests through genetic modification include corn and potatoes into which genes encoding delta-endotoxin, an insecticidal protein derived from the soil bacterium Bt, have been introduced. Examples of delta-endotoxins that confer resistance to Coleopteran pests include Cry3A, mCry3A (modified Cry3A), Cry3Bb1, Cry34Ab1, Cry35Ab1, Cry6A, Cry6Aa, and mCry6Aa (modified Cry6Aa). Examples of plants conferred with resistance to Diptera pests through genetic modification include corn (Zea mays L.) into which a synthetic gene encoding the hybrid protein eCry3.1Ab, a fusion of Cry3A and Cry1Ab derived from the soil bacterium Bt, has been introduced, and cotton (Gossypium hirsutum L.) into which a gene encoding the trypsin inhibitor CpTI derived from cowpea (Vigna unguiculata) has been introduced. Furthermore, there are poplars into which a gene encoding API, a protease inhibitor protein A derived from arrowhead (Sagittaria sagittifolia), has been introduced, exhibiting resistance to a wide range of pests. An example of a plant conferred with resistance to nematodes through genetic modification is soybeans (Glycine max L.) into which the gene encoding Cry14Ab-1.b, derived from the soil bacterium Bt, has been introduced. Insecticidal proteins that confer pest resistance to plants include hybrid proteins, partially deficient proteins, and modified proteins of the above-mentioned insecticidal proteins. Hybrid proteins are created using genetic engineering techniques by combining different domains of multiple insecticidal proteins, and Cry1Ab-Ac and Cry1A.105 are known examples. Partially deficient proteins include Cry1Ab, which has a partial deletion in its amino acid sequence. Modified proteins are those in which one or more amino acids of the natural delta-endotoxin are substituted, and Cry1Fa2, moCry1F, and mCry3A are known examples. Modified proteins also include cases in which a protease recognition sequence not found in nature is inserted into the toxin, for example, Cry3A055 (see WO2003 / 018810), in which a cathepsin G-recognition sequence is inserted into the Cry3A toxin. Monsanto has developed a cotton plant (event MON88702) into which a modified BT protein, Cry51Aa2 (Cry51Aa2.834_16), has been introduced using genetic engineering technology. This plant exhibits resistance to species of the genus Lygus, such as Lygus lineolaris, as well as hemipterans such as aphids and thrips such as Frankliniella. Other insecticidal proteins used to confer pest resistance to plants through genetic engineering include, for example, insecticidal proteins derived from Bacillus cereus or Bacillus popilliae; plant insecticidal proteins Vip1, Vip2, Vip3 (with subclasses Vip3Aa~Vip3Aj, Vip3Ba, Vip3B, and Vip3Ca, specifically Vip3Aa20 and Vip3Aa61) and Vip4; insecticidal proteins derived from nematode-symbiotic bacteria (which colonize nematodes), such as Photorhabdus spp. (e.g., Photorhabdus luminescens) or Xenorhabdus spp. (e.g., Xenorhabdus nematophilus); and the fern plant Tectaria. Insecticidal protein Tma12 derived from Tactaria macrodonata; insecticidal protein IPD083 derived from Adiantum spp.; insecticidal protein IPD113 derived from Pteris cretica cv. albolineata or Pteris umbrosa.albolineata or Pteris Examples of toxins include: umbrosa; toxins produced by animals, including insect-specific neurotoxins such as scorpion venom, spider venom, and wasp venom; toxins produced by filamentous fungi, such as Streptomycetes venom; plant lectins such as pea lectin, barley lectin, and snowdrop lectin; aglutinin; protease inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin, and papain inhibitors; ribosome inactivating proteins (RIPs) such as lysine, maize-RIP, abrin, rufin, saporin, and bryodin; steroid metabolic enzymes such as 3-hydroxysteroid oxidase, ecdysteroid-UDP-glucosyltransferase, and cholesterol oxidase; ecdysone inhibitors; HMG-CoA-reductase; ion channel inhibitors such as sodium channel inhibitors and calcium channel inhibitors; juvenile hormone esterase; diuretic hormone receptor; stilbenzyl synthase; bibenzyl synthase; chitinase; and glucanase.
[0147] Furthermore, plants that have been conferred with insecticidal protein genes by introducing one or more such genes are already known, and some of these plants are commercially available. Examples of cotton with pest resistance include: "Bollgard® cotton," "BXN® Plus Bollgard® Cotton," "BXN® Plus Bollgard® Cotton," "JK 1," "Roundup Ready® Bollgard® Cotton," and "Ingard®," which express the insecticidal protein Cry1Ac derived from Bt bacteria; "Herculex® I" and "Herculex® CB," which express the modified insecticidal protein Cry1F (Cry1Fa2) derived from Bt bacteria; "VIPCOT® Cotton," which expresses the insecticidal protein Vip3A derived from Bt bacteria; and "Bollgard II® cotton," "Roundup Ready® Bollgard II® Cotton," and "Roundup Ready® Flex® Bollgard II®," which express the insecticidal proteins Cry1Ac and Cry2Ab derived from Bt bacteria. "Cotton" and "Fivermax (trademark), Liberty Link (trademark), Bollgard II (trademark)"; "Bollgard III (registered trademark)" and "Bollgard III x Roundup Ready (trademark) Flex (trademark)" expressing the insecticidal proteins Cry1Ac, Cry2Ab, and Vip3A derived from Bt bacteria; "VIPCOT (trademark), Roundup Ready Flex (trademark) Cotton" expressing the insecticidal proteins Vip3A and Cry1Ab derived from Bt bacteria; "VIPCOT (registered trademark) Cotton" expressing the insecticidal proteins Vip3A and Cry1Ac derived from Bt bacteria; "WideStrike (trademark) Cotton", "WideStrike (trademark), Roundup Ready (trademark) Cotton" and "Widestrike (trademark), Roundup Ready Flex (trademark)" expressing the insecticidal proteins Cry1Ac and Cry1F derived from Bt bacteria. "Cotton"; "TwinLink® Cotton" and "Glytol® x Twinlink®" express the insecticidal proteins Cry1Ab and Cry2Ae derived from Bt bacteria;Examples include "Widestrike® 3" and "Widestrike® x Roundup Ready Flex® x VIPCOT® Cotton," which express the insecticidal proteins Cry1Ac, Cry1F, and Vip3A derived from Bt bacteria; "Glytol® x Twinlink® x VIPCOT® Cotton," which expresses the insecticidal proteins Cry1Ab, Cry2Ae, and Vip3A derived from Bt bacteria; and "Bollgard® III ThryvOn® Cotton," which expresses the insecticidal proteins Cry1Ac, Cry2Ab, Vip3A, and Cry51Aa2 derived from Bt bacteria. These products are commercially available. Examples of corn conferred with pest resistance include: "YieldGard® Rootworm RW," "YieldGard® RW + RR," "YieldGard® VT® Rootworm® RR2," and "MaxGard®," which express the insecticidal protein Cry3Bb1 derived from Bt bacteria; "YieldGard® VT Triple" and "YieldGard® Plus with RR," which express the insecticidal proteins Cry3Bb1 and Cry1Ab derived from Bt bacteria; "Bt Xtra® Maize," which expresses the insecticidal protein Cry1Ac derived from Bt bacteria; "YieldGard Plus®," which expresses the insecticidal proteins Cry1Ab and Cry3Bb1 derived from Bt bacteria; and "Bt10" and "Liberty Link® Yieldgard®," which express the insecticidal protein Cry1Ab derived from Bt bacteria. "Maize," "Agrisure (trademark) GT / CB / LL," and "YieldGard (trademark) CB + RR"; Cry1A, an insecticidal protein derived from Bt bacteria."YieldGard® VT Pro®" and "Genuity® VT Double Pro®" expressing 105 and Cry2Ab2; "Agrisure® RW" and "Agrisure® GT / RW" expressing the insecticidal protein mCry3A derived from Bt bacteria; "Starlink® Maize" expressing the insecticidal protein Cry9C derived from Bt bacteria; "YieldGard®", "MaizeGard®", "NaturGard KnockOut®", "Maximizer®", "Roundup Ready® YieldGard® maize", "Agrisure® CB / LL", and "Mavera® YieldGard®" expressing the insecticidal protein Cry1Ab derived from Bt bacteria. "Maize"; "Agrisure® 3122" expressing the insecticidal proteins Cry1Ab, Cry1F, modified Cry3A, Cyr34Ab1 and Cyr35Ab1 derived from Bt bacteria; "Agrisure® Viptera" expressing the insecticidal protein Vip3Aa20 derived from Bt bacteria; "Agrisure® Viptera® 2100" and "Agrisure® Viptera® 3110" expressing the insecticidal proteins Vip3Aa20 and Cry1Ab derived from Bt bacteria; "Agrisure® Viptera® 3100", "Agrisure® Viptera® 3111", and "Agrisure® Viptera® 4); "Agrisure® Viptera® 3220" expressing the insecticidal proteins Vip3Aa20, Cry1Ab, and modified Cry1F derived from Bt bacteria; "Agrisure® Duracade®" expressing the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab) derived from Bt bacteria; the insecticidal protein eCry3."Agrisure® Duracade® 5122" expressing 1Ab (a chimeric protein of Cry3A-Cry1Ab), modified Cry3A, Cry1Ab, and modified Cry1F; "Agrisure® Duracade® 5222" expressing the insecticidal protein eCry3.1Ab (a chimeric protein of Cry3A-Cry1Ab), modified Cry3A, modified Cry1Ab, and Vip3A mutant derived from Bt bacteria; "Herculex® RW" expressing the insecticidal proteins Cyr34Ab1 and Cyr35Ab1 derived from Bt bacteria; "Herculex®" expressing the insecticidal proteins Cyr34Ab1, Cyr35Ab1, and Cry1F derived from Bt bacteria. "XTRA (trademark)"; "Genuity (registered trademark) VT Triple Pro (trademark)" expressing insecticidal proteins Cry1A.105, Cry2Ab2, and Cry3Bb1 derived from Bt bacteria; "Genuity (registered trademark) SmartStax (trademark)" expressing insecticidal proteins Cry1F, Cry2Ab, Cyr34Ab1, Cyr35Ab1, Cry3Bb1, and Cry1A.105 derived from Bt bacteria; "Power Core (trademark)" expressing modified insecticidal proteins Cry1F, Cry2Ab, and Cry1A.105 derived from Bt bacteria; "Herculex XTRA (trademark)" expressing modified insecticidal proteins Cry1F, Cyr34Ab1, and Cyr35Ab1 derived from Bt bacteria. Examples include "RR"; "Optimum® Intrasect Xtreme," which expresses modified insecticidal proteins Cry1F, Cyr34Ab1, Cyr35Ab1, Cry1Ab, and modified Cry3A derived from Bt bacteria; "Optimum® Intrasect XTRA," which expresses modified insecticidal proteins Cry1F, Cyr34Ab1, Cyr35Ab1, and Cry1Ab derived from Bt bacteria; and "Optimum® TRIsect," which expresses modified insecticidal proteins Cry1F and modified Cyr3A derived from Bt bacteria. These are commercially available. Other examples of plants conferred with pest resistance include potatoes expressing the insecticidal protein Cry3A derived from Bt bacteria, such as "Atlantic NewLeaf® potato," "NewLeaf® Russet Burbank potato," "Lugovskoi plus," "Elizaveta plus," "Hi-Lite NewLeaf® Y potato, Superior NewLeaf® potato," and "Shepody NewLeaf® Y potato"; rice varieties expressing the insecticidal proteins Cry1Ab and Cry1Ac derived from Bt bacteria, such as "hanyou 63" and "Huahui-1"; soybean variety expressing the insecticidal protein Cry1Ac derived from Bt bacteria, such as "Intacta® Roundup Ready® 2 Pro"; and eggplant varieties expressing the insecticidal protein Cry1Ac derived from Bt bacteria, such as "BARI Bt Begun-1, -2, -3 and -4." These are all commercially available. Furthermore, corn varieties resistant to corn rootworms include "YieldGard corn rootworm," "YieldGard VT," "Herculex RW," "Herculex Rootworm," and "Agrisure CRW"; corn varieties resistant to corn borers include "YieldGard corn borer," "YieldGard plus," "YieldGard VT Pro," "Agrisure CB / LL," "Agrisure 3000GT," "Hercules I," "Hercules II," "KnockOut," "NatureGard," and "StarLink"; corn varieties resistant to Western bean cutworms, corn borers, black cutworms, and fall armyworms include "Herculex I," "Herculex Xtra," "NewLeaf," "NewLeaf Y," and "NewLeaf Plus"; corn varieties resistant to corn borers and corn rootworms include "YieldGard Plus"; and cotton varieties resistant to false tobacco moths include "Bollgard I" and "Bollgard Known varieties of cotton include “Bollgard II”, “WideStrike®”, and “VipCot”, which are resistant to the tobacco moth, cotton ball worm, fall army worm, beet army worm, cabbage looper, soybean looper, and pink ball worm; “NewLeaf”, “NewLeaf Y”, and “NewLeaf Plus”, which are resistant to the tobacco hawk moth; and “Bt brinjal”, “Dumaguete Long Purple”, and “Mara”, which are resistant to the eggplant leafminer, fruit borer, and cotton ball worm (see, for example, US5128130). Further plants with pest resistance are generally known, including, for example, rice resistant to the rice leaf borer (see, e.g., Molecular Breeding, Vol. 18 (2006), No. 1), lepidopteran-resistant lettuce (see, e.g., US5349124), and rice resistant to lepidopterans (e.g., rice leaf borer, skipper, rice armyworm, rice borer, rice case worm, and rice army worm) (see, e.g., WO2001 / 021821). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above.
[0148] As a plant to which pest resistance has been conferred using RNA interference technology, corn that is resistant to coleopteran pests (corn rootworms) is commercially available under the trademark names "SmartStax® Pro" or "Vorceed Enlist®".
[0149] Examples of plants conferred with pest resistance through conventional breeding techniques or genome breeding techniques include: soybeans resistant to soybean aphids (Aphis glycines) possessing the aphid resistance genes "Rag1 (Resistance to Aphis glycines 1)" or "Rag2 (Resistance to Aphis glycines 2)" (see J. Econ. Entomol., 2015, 108, 326); soybeans resistant to soybean cyst nematodes (Heterodera glycines) (see Phytopathology, 2016, 106, 1444); and cotton resistant to root-knot nematodes (Meloidogyne incognita) (see J. Nematol., 2009, 41). 140); Examples include the rice variety "Kanto BPH1" which shows resistance to the brown planthopper, and the soybean variety "Fukuminori" which shows resistance to the beet armyworm.
[0150] These pest-resistant plants are conferred resistance to any harmful insects (especially lepidopteran, coleopteran, dipteran, and coleopteran insects), harmful spiders, and harmful nematodes. The pest-resistant plants are preferably selected from cereals (e.g., wheat, barley, rye, oats), corn, canola, sorghum, soybeans, rice, rapeseed, sugar beets, sugarcane, grapes, lentils, sunflowers, alfalfa, pome fruits, drupes, peanuts, coffee, tea, strawberries, turf, and vegetables (e.g., tomatoes, potatoes, cucurbits, and lettuce), more preferably selected from soybeans, corn, tomatoes, rice, and cereals (e.g., wheat, barley, rye, and oats), and most preferably selected from soybeans, rice, corn, and cereals (e.g., wheat, barley, rye, and oats).
[0151] Examples of plants that have been given disease resistance are listed below.
[0152] Plants conferred disease resistance through genetic engineering are, for example, plants that express so-called "pathogenicity-associated proteins" (PRP, see, e.g., EP0392225) or so-called "antifungal proteins" (AFP, see, e.g., US6864068). Various antifungal proteins with activity against plant pathogenic fungi have been isolated from specific plant species and are common knowledge. Examples of such antipathogenic substances and plants capable of synthesizing such substances are known, for example, from EP0392225, WO1993 / 05153, WO1995 / 33818, and EP0353191. Plants resistant to fungicidal pathogens, viral pathogens, and bacterial pathogens are created by introducing disease resistance genes. Numerous resistance genes have been identified, isolated, and used to improve disease resistance. Examples of such resistance genes include the N gene, introduced into TMV-susceptible tobacco lines to create TMV-resistant tobacco plants (see, e.g., US 5571706); the Prf gene, introduced into plants to obtain enhanced pathogen resistance (see, e.g., WO1998 / 02545); and the Rps2 gene derived from Arabidopsis thaliana, used to create resistance to bacterial pathogens such as Pseudomonas syringae (see, e.g., WO1995 / 028423). Plants exhibiting a systemic acquired resistance response were obtained by introducing a nucleic acid molecule encoding the TIR domain of the N gene (see, e.g., US 6630618).Further examples of known resistance genes include the Xa21 gene introduced into numerous rice varieties (see, e.g., US5952485, US5977434, WO1999 / 009151, WO1996 / 022375), the Rcg1 gene for resistance to the genus Colletotrichum (see, e.g., US2006 / 225152), the prp1 gene (see, e.g., US5859332, WO2008 / 017706), the ppv-cp gene for introducing resistance to plum poxvirus (see, e.g., US PP15,154Ps), the P1 gene (see, e.g., US5968828), and the potato blight pathogen (Phytophthora) in potatoes. Examples include genes such as Blb1, Blb2, Blb3, RB2, and Rpi-vnt1 (see, e.g., US7148397) for introducing resistance to infestans, the LRPKml gene (see, e.g., WO1999 / 064600), the P1 gene (see, e.g., US5968828) and the HA5-1 gene (see, e.g., US5877403 and US6046384) for resistance to potato virus Y, the PIP gene (see, e.g., EP0707069) for introducing broad resistance to viruses such as potato virus X (PVX), potato virus Y (PVY), and potato leaf curl virus (PLRV), and genes such as the NI16, ScaM4, and ScaM5 genes of Arabidopsis (see, e.g., US6706952 and EP1018553) for obtaining fungal resistance. Furthermore, kidney beans resistant to Bean Golden Mosaic Virus (BGMV) are plants in which resistance has been conferred through RNA interference technology. This involves introducing a double-stranded RNA gene for the replication protein (sense and antisense ac1 gene), which inhibits the synthesis of BGMV replication protein, thereby granting resistance to BGMV. Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. Examples of antipathogenic substances that can be expressed by such plants include ion channel blockers (sodium channel blockers, calcium channel blockers, etc.); viral KP1, KP4, and KP6 toxins; stilbene synthase; vibenzyl synthase; chitinase; glucanase; so-called "pathogenicity-associated proteins" (PRP; see, e.g., EP0392225); and antipathogenic substances produced by microorganisms (e.g., peptide antibiotics, heterocyclic antibiotics (see, e.g., WO1995 / 033818) and protein factors or polypeptide factors involved in plant pathogen defense (so-called "plant disease resistance genes" as described in WO2003 / 000906)). Antipathogenic substances produced by plants can protect plants from various pathogenic microorganisms such as fungi, viruses, and bacteria. Useful plants of increasing interest in connection with the present invention include cereals (e.g., wheat, barley, rye, and oats), soybeans, maize, rice, rapeseed, pomelo, drupes, peanuts, coffee, tea, strawberries, turf; climbing plants and vegetables (e.g., tomatoes, potatoes), cucurbits, papaya, melon, lenses, and lettuce, more preferably selected from soybeans, tomatoes, rice, and cereals (e.g., wheat, barley, rye, and oats), and most preferably selected from soybeans, rice, and cereals (e.g., wheat, barley, rye, and oats). Examples of plants resistant to fungal pathogens include: soybeans resistant to soybean rust (Phakopsora pachyrhizi and Phakopsora meibomiae) (see, e.g., WO2008 / 017706); Solanaceae plants such as cotton, tomatoes, and potatoes resistant to potato blight (Phytophthora infestans) (see, e.g., US5859332, US7148397, EP1334979); maize resistant to Colletotrichum species such as Colletotrichum graminicola (see, e.g., US2006 / 225152); apples resistant to apple scab (Venturia inaequalis) (see, e.g., WO1999 / 064600); and Fusarium species (e.g., Fusarium). graminearum, fusarium sporotrichioides, fusarium lateritium, fusarium pseudograminearum, fusarium sambucinum, fusarium culmorum, fusarium poae, fusarium acuminatum, fusarium Examples include plants resistant to equiseti (e.g., rice, wheat, barley, rye, maize, oats, potatoes, melons, soybeans, and sorghum) (see, for example, US6646184, EP1477557); and plants with broad fungicidal resistance, such as maize, soybeans, cereals (especially wheat, barley, rye, and oats), rice, tobacco, sorghum, sugarcane, and potatoes (see, for example, US5859332, US5689046, US6706952, EP1018553, and US6020129). Examples of plants resistant to bacterial pathogens include rice resistant to Xylella fastidiosa (see, e.g., US6232528); rice, cotton, soybeans, potatoes, sorghum, maize, wheat, barley, sugarcane, tomatoes, and peppers resistant to bacterial canker (see, e.g., WO2006 / 42145, US5952485, US5977434, WO1999 / 09151, WO1996 / 22375); and tomatoes resistant to Pseudomonas syringae (see, e.g., Can. J. Plant Path., 1983, 5:251-255). Examples of plants resistant to viral pathogens include: drupes resistant to plum pox virus (e.g., plums, almonds, apricots, cherries, peaches, nectarines) (see, e.g., US PP15154Ps, EP0626449); potatoes resistant to potato virus Y (see, e.g., US5968828); potatoes, tomatoes, cucumbers, and legumes resistant to tomato spotted wilt virus (see, e.g., EP0626449, US5973135); maize resistant to maize streak virus (see, e.g., US6040496); and papaya ring spot virus. Papaya resistant to (e.g., S5877403, US6046384); Cucurbitaceae plants (e.g., cucumbers, melons, watermelons, and pumpkins) and Solanaceae plants (e.g., potatoes, tobacco, tomatoes, eggplants, bell peppers, chili peppers, and peppers) resistant to cucumber mosaic virus (e.g., US6849780); Cucurbitaceae plants (e.g., cucumbers, melons, watermelons, and pumpkins) resistant to watermelon mosaic virus 2 and zucchini yellow mosaic virus (e.g., US6015942); Potatoes resistant to potato leafroll virus (e.g., US5576202); Potato virus X, Potato virus Y Y) Potatoes with broad resistance to viruses such as potato leafroll virus (see, for example, EP0707069);Examples include kidney beans resistant to the Bean Golden Mosaic Virus (see, for example, Mol Plant Microbe Interact. 2007 Jun;20(6):717-26). Some plants are resistant to antibiotics (e.g., kanamycin, neomycin, and ampicillin). The naturally occurring bacterial nptII gene expresses enzymes that block the action of the antibiotics kanamycin and neomycin. The ampicillin resistance gene ampR (also known as blaTEM1) originates from the bacterium Salmonella paratyphi and is used as a marker gene in microbial and plant transformation. ampR is involved in the synthesis of beta-lactamase, an enzyme that neutralizes penicillin antibiotics, including ampicillin. Examples of plants resistant to antibiotics include potatoes, tomatoes, flax, canola, rapeseed, rapeseed seeds, and maize (see, for example, Plant Cell Reports, 20, 2001, 610-615; Trends in Plant Science, 11, 2006, 317-319; Plant Molecular Biology, 37, 1998, 287-296; Mol Gen Genet., 257, 1998, 606-13; Plant Cell Reports, 6, 1987, 333-336; Federal Register (USA), Vol. 60, No. 113, 1995, p. 31139; Federal Register (USA), Vol. 67, No. 226, 2002, p. 70392). See Federal Register (USA), Vol. 63, No. 88, 1998, p. 25194; Federal Register (USA), Vol. 60, No. 141, 1995, p. 37870; Canadian Food Inspection Agency, FD / OFB-095-264-A, October 1999; FD / OFB-099-127-A, October 1999). Preferably, the plants are selected from soybeans, tomatoes and cereals (e.g., wheat, barley, rye and oats), most preferably from soybeans and cereals (e.g., wheat, barley, rye and oats). Examples of plants conferred with resistance to plant viral diseases that are available include, for example, the papaya varieties 'Rainbow', 'SunUp', and 'Huanong No. 1', which are resistant to papaya ringspot virus; the potato varieties 'Innate® Hibernate', 'Innate® Glaciate', and 'Innate® Acclimate', which are resistant to phytophthora infestans; and the potato variety 'Newleaf®', which is resistant to potato virus Y and / or potato leaf curl virus (PLRV).
[0153] Plants conferred with disease resistance through conventional breeding techniques or genome breeding techniques include: rice resistant to blast; rice resistant to sheath blight; wheat resistant to leaf rust; wheat resistant to stripe rust; wheat resistant to stem rust; wheat resistant to powdery mildew; wheat resistant to leaf blotch; wheat resistant to gluten blotch; wheat resistant to tan spot; barley resistant to powdery mildew; barley resistant to dwarf leaf rust; and net spot (a type of leaf blotch). Barley resistant to blotch; barley resistant to scald; barley res...
Claims
1. Equation (I) [During the ceremony, R 1 This represents a C1-C3 chain hydrocarbon group, a cyclopropyl group, or a hydrogen atom, which may be substituted with one or more halogen atoms. R 2 This includes a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group A, a phenyl group which may be substituted with one or more substituents selected from group A, a 9-membered aromatic heterocyclic group {the 9-membered aromatic heterocyclic group may be substituted with one or more substituents selected from the group consisting of a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, and halogen atoms}, a group represented by formula A1, a group represented by formula A2, a group represented by formula A3, or a group represented by formula A4 (# 1 (represents the connection site with Q), R a11 、R a12 、R a33 、and R a34 are the same or different and each represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a cyclopropyl group, C(O)OR aa1 、C(O)NR aa2 R aa3 、a cyano group, a halogen atom, or a hydrogen atom, provided that R a21 , R a23 , R a42 , and R a44 These represent the same or different halogen atoms or hydrogen atoms. R aa1 This represents a C1-C6 chain hydrocarbon group or a hydrogen atom, which may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group and halogen atoms. R aa2 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R aa3 This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R a31 , R a32 , R a53 , or R a54 This represents a C1-C6 chain hydrocarbon group, which may be substituted with one or more substituents selected from the group consisting of a phenyl group, a cyclopropyl group, and a halogen atom, which may be the same or different in nature, or a hydrogen atom. R 3 This includes a C1-C6 chain hydrocarbon group which may be substituted with one or more substituents selected from group B, a cyclopropyl group, a C1-C6 alkylsulfonyl group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkylsulfonyl group, OR 3a , C(O)R 3b , C(O)OR 3c , or represents a hydrogen atom, R 3a This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group, a phenyl group which may be substituted with one or more substituents selected from group C, and a halogen atom}, or a hydrogen atom. R 3b This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with a cyclopropyl group, a phenyl group which may be substituted with one or more substituents selected from group C, and a halogen atom which may be substituted with one or more substituents selected from group C}, a phenyl group which may be substituted with one or more substituents selected from group C, a cyclopropyl group, or a hydrogen atom. R 3c This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with a cyclopropyl group, a phenyl group which may be substituted with one or more substituents selected from group C, and one or more substituents selected from the group consisting of halogen atoms}, a phenyl group which may be substituted with one or more substituents selected from group C, or a cyclopropyl group. Q is a group represented by formula B1, a group represented by formula B2, or a group represented by formula B3 (# 2 is R 1 This represents the bonding site with the carbon atom that is bonded to it, # 3 is R 2 (represents the connection site with) R b11 This includes a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, a halogen atom, and NR ba1 C(O)R ba2 , NR ba3 C(O)OR ba4 , NR ba5 R ba6 C(O)NR ba7 R ba8 , C(O)OR ba9 , S(O) q R ba10 , represents a cyano group or a hydrogen atom, R ba1 C(O)R is a C1-C4 chain hydrocarbon group which may be substituted with one or more halogen atoms. ba11 , or represents a hydrogen atom, R ba2 , R ba4 , R ba9 , R ba10 , and R ba11 This represents a C1-C4 chain hydrocarbon group that is identical or different in phase and may be substituted with one or more halogen atoms. R ba3 , R ba5 , R ba6 , R ba7 and R ba8 This represents a C1-C4 chain hydrocarbon group, or a hydrogen atom, which may be the same or different in phase and may be substituted with one or more halogen atoms. q represents 0, 1, or 2. R b21 , and R b22 This represents a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, a halogen atom, or a hydrogen atom, which may be the same or different in phase. R b31 This includes a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, and NR bb1 C(O)R bb2 , NR bb3 C(O)OR bb4 , NR bb5 C(O)NR bb6 R bb7 , NR bb8 S(O) 2 R bb9 , NR bb10 R bb11 , represents a nitro group, a cyano group, a halogen atom, or a hydrogen atom, R bb1 , R bb3 , R bb5 , R bb6 , R bb8 , and R bb10 This represents a C1-C3 chain hydrocarbon group, which may be the same or different in phase and may be substituted with one or more halogen atoms, or a hydrogen atom. R bb2 This represents a C1-C3 chain hydrocarbon group, a cyclopropyl group, or a hydrogen atom, which may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group and halogen atoms. R bb4 This represents a C1-C3 chain hydrocarbon group or a cyclopropyl group, which may be substituted with one or more substituents selected from the group consisting of a cyclopropyl group and halogen atoms. R bb7 and R bb11 This represents a C1-C3 chain hydrocarbon group, a cyclopropyl group, or a hydrogen atom, which may be the same or different in phase and may be substituted with one or more halogen atoms. R bb9 This represents a C1-C3 chain hydrocarbon group or a cyclopropyl group which may be substituted with one or more halogen atoms. R b32 This includes a C1-C3 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C1-C3 alkoxy group which may be substituted with one or more halogen atoms, a cyclopropyl group, and C(O)NR bb12 R bb13 , C(O)OR bb14 , S(O) 2 R bb15 , represents a cyano group, a nitro group, a halogen atom, or a hydrogen atom, R bb12 This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R bb13 represents a C1-C6 chain hydrocarbon group optionally substituted with one or more halogen atoms, a cyclopropyl group, or a hydrogen atom, R bb14 This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R bb15 This represents a C1-C6 chain hydrocarbon group or a cyclopropyl group which may be substituted with one or more halogen atoms. Z 1 represents an oxygen atom, a sulfur atom, NR ZZ1 , N-OR ZZ2 , N-CN, N-NO 2 , C(CN) 2 , NS(O) 2 R ZZ3 , or NC(O)OR ZZ4 and R ZZ1 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. R ZZ2 This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a phenyl group which may be substituted with one or more substituents selected from group C, and halogen atoms}, or a hydrogen atom. R ZZ3 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from group C. R ZZ4 This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from group C, and one or more substituents selected from the group consisting of halogen atoms}, a phenyl group which may be substituted with one or more substituents selected from group C, or a cyclopropyl group. X is a group represented by formula C1-1, a group represented by formula C2-1, or a group represented by formula C3-1 (# 4 is Z 1 This represents the bonding site with the carbon atom that is bonded to it. Z 2 This represents an oxygen atom or a sulfur atom. Z 3 is a nitrogen atom, or CR C14 This represents, Z 4 Z 5 Z 6 and Z 7 The combination is, Z 4 CR C21 Z 5 CR C22 Z 6 CR C23 Z 7 CR C24 The combinations that are; Z 4 This is a nitrogen atom, Z 5 CR C22 Z 6 CR C23 Z 7 CR C24 The combinations that are; Z 4 CR C21 Z 5 This is a nitrogen atom, Z 6 CR C23 Z 7 CR C24 The combinations that are; Or, Z 4 CR C21 Z 5 CR C22 Z 6 CR C23 Z 7 This represents a combination where the atom is a nitrogen atom. R c21 , R c31 , R c14 , R c24 , and R c34 This represents a C1-C6 chain hydrocarbon group, a halogen atom, or a hydrogen atom, which may be the same or different in phase and may be substituted with one or more halogen atoms. R c22 , R c32 , R c13 , R c23 , and R c35 These are the same or different C1-C6 chain hydrocarbon group, cyclopropyl group {the C1-C6 chain hydrocarbon group and the cyclopropyl group may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms}, NR cc1 C(O)R cc2 C(O)NR cc3 R cc4 , C(O)OR cc5 , OR cc6 , S(O) 2 R cc7 , represents a nitro group, a cyano group, a halogen atom, or a hydrogen atom, R c15 , R c25 , and R c33 These are the same or different C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a phenyl group, a cyclopropyl group, a cyano group, and a halogen atom, which may be substituted with one or more substituents selected from group C}, a cyclopropyl group {the cyclopropyl group may be substituted with one or more substituents selected from the group consisting of a cyano group and a halogen atom}, C(O)NR cc8 R cc9 , C(O)R cc10 , or S(O) 2 R cc11 This represents, R cc1 This is a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, OR 1C , or represents a hydrogen atom, R 1C This represents a cyclopropyl group, a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a phenyl group which may be substituted with one or more substituents selected from group C, and halogen atoms}, and a hydrogen atom. R cc2 and R cc4 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom, R cc3 This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R cc5 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a phenyl group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. R cc6 C3-C6 cycloalkyl groups, C1-C6 chain hydrocarbon groups (the C1-C6 chain hydrocarbon groups may be substituted with one or more substituents selected from the group consisting of halogen atoms and cyano groups), C(O)R 61C , C(O)OR 62C C(O)NR 63C R 64C , S(O) 2 R 65C , or represents a hydrogen atom, R 61C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R 62C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms. R 63C This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R 64C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R 65C This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R cc7 This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms. R cc8 This represents a C1-C6 chain hydrocarbon group that may be substituted with one or more halogen atoms, or a hydrogen atom. R cc9 This represents a C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of a phenyl group which may be substituted with one or more substituents selected from group C, and halogen atoms}, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom. R cc10 and R cc11 This represents the same or different C1-C6 chain hydrocarbon group {the C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from group C, a phenyl group which may be substituted with one or more substituents selected from group C, a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group C, a cyclopropyl group, and one or more substituents selected from the group consisting of halogen atoms}, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group C, a 5 or 6-membered aromatic heterocyclic group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. Group A: C1-C6 chain hydrocarbon group {The C1-C6 chain hydrocarbon group may be substituted with one or more substituents selected from the group consisting of C3-C6 cycloalkyl groups, cyano groups, and halogen atoms, which may be substituted with one or more halogen atoms}, cyclopropyl group {The cyclopropyl group may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms}, OR 1A SF 5 , NR 2A C(O)R 3A , NR 4A C(O)OR 5A , NR 6A C(O)NR 7A R 8A N=S(O) p R 9A R 10A , C(O)R 11A , C(O)OR 12A C(O)NR 13A R 14A , S(O) 2 NR 15A R 16A , NR 17A S(O) 2 R 18A , S(O) m R 19A A group consisting of a cyano group and a halogen atom. R 1A This includes a C3-C6 cycloalkyl group which may be substituted with one or more substituents selected from the group consisting of halogen atoms and cyano groups, a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, and C(O)R 20A , C(O)OR 21A C(O)NR 22A R 23A , S(O) 2 R 24A , or represents a hydrogen atom, R 2A , R 4A , R 6A , R 7A , R 13A , R 15A , R 17A , and R 22A This represents a C1-C6 chain hydrocarbon group, which may be the same or different in phase and may be substituted with one or more halogen atoms, or a hydrogen atom. R 3A , R 8A , R 11A , R 14A , and R 16A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a hydrogen atom, R 5A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, or a (C3-C6 cycloalkyl)C1-C3 alkyl group which may be substituted with one or more halogen atoms. NR 2A C(O)R 3A If R 2A and R 3A R 2A The nitrogen atom to which it is bonded, and R 3A Together with the carbon atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. NR 4A C(O)OR 5A If R 4A and R 5A R 4A The nitrogen atom to which it is bonded, and R 5A Together with the oxygen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. NR 6A C(O)NR 7A R 8A If R 6A and R 7A R 6A The nitrogen atom to which it is bonded, and R 7A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. NR 6A C(O)NR 7A R 8A If R 7A and R 8A R 7A and R 8A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. C(O)NR 13A R 14A If R 13A and R 14A R 13A and R 14A Together with the nitrogen atom to which it is bonded, it may form a 5- or 6-membered non-aromatic heterocycle which may be substituted with a C1-C3 chain hydrocarbon group {the C1-C3 chain hydrocarbon group may be substituted with one or more halogen atoms}. p represents 0 or 1, R 9A and R 10A This represents a C1-C6 alkyl group that is the same or different in phase and may be substituted with one or more halogen atoms, or a C3-C6 cycloalkyl group that may be substituted with one or more halogen atoms. R 12A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. R 18A and R 19A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a phenyl group which may be substituted with one or more substituents selected from group C, or a C3-C6 cycloalkyl group which may be substituted with one or more halogen atoms, m represents 0, 1, or 2. R 20A This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms, a cyclopropyl group which may be substituted with one or more substituents selected from group C, or a hydrogen atom. R 21A , R 23A , and R 24A This represents a C1-C6 chain hydrocarbon group, a cyclopropyl group, or a phenyl group, which may be substituted with one or more substituents selected from group C, and which may be the same or different in phase. Group B: Cyclopropyl group, phenyl group which may be substituted with one or more substituents selected from Group C, OR 3B A group consisting of a cyano group and a halogen atom. R 3B This represents a C1-C6 chain hydrocarbon group which may be substituted with one or more halogen atoms. Group C: A group consisting of C1-C6 chain hydrocarbon groups (the C1-C6 chain hydrocarbon groups may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms), C3-C6 cycloalkyl groups (the C3-C6 cycloalkyl groups may be substituted with one or more substituents selected from the group consisting of cyano groups and halogen atoms), and C1-C6 alkoxy groups, cyano groups, and halogen atoms, which may be substituted with one or more halogen atoms. A method for controlling harmful arthropods, comprising the step of applying a compound shown in or its N oxide or a salt thereof to harmful arthropods, habitats of harmful arthropods, plants, or plant cultivation carriers.
2. The method for controlling harmful arthropods according to claim 1, wherein the plant cultivation carrier is soil.
3. A composition containing a compound represented by formula (I) as described in claim 1, its N oxide, or a salt thereof, and one or more components selected from the group consisting of group (a), group (b), group (c), group (d), group (e), group (f), group (g), group (h), group (i), and group (j): Group (a): A group consisting of arthropod-killing and nematode-killing active ingredients; Group (b): bactericidal active ingredient; Group (c): plant growth regulating ingredients; Group (d): Ingredients that reduce drug-induced harm; Group (e): Synergistic agents; Group (f): Repellent component; Group (g): Molluscicide components; Group (h): Insect pheromones; Group (i): herbicidal active ingredients; Group (j): Biological control materials.
4. A method for controlling harmful arthropods, comprising the step of applying an effective amount of the composition described in claim 3 to harmful arthropods, habitats of harmful arthropods, plants, or plant cultivation carriers.
5. The method for controlling harmful arthropods according to claim 4, wherein the plant cultivation carrier is soil.
6. Seeds or vegetative reproductive organs that retain an effective amount of the compound represented by formula (I) described in claim 1, its N oxide, or a salt thereof, or the composition described in claim 3.
Citation Information
Patent Citations
Pesticidally active heteroaromatic compounds
WO2022157188A2