cosmetic ingredients

Abstract

This invention provides a cosmetic composition and method that can promote the penetration of B vitamins or their derivatives into the skin, as well as a polymer suitable for use as a transdermal penetration enhancer for B vitamins or their derivatives. [Solution] A cosmetic composition comprising vitamin B group or its derivatives and a polymer having repeating units of formula (I): TIFF2026048919000015.tif76152 (In the formula, R1 to R5 are independently H or an alkyl group having 1 to 3 carbon atoms, and M is H, an alkali metal atom, an alkaline earth metal atom, an earth metal atom, or an ammonium atom.)

Description

Technical Field

[0001] The present invention relates to a cosmetic composition, and particularly to a cosmetic composition containing vitamin B group or its derivatives.

Background Art

[0002] In recent years, research on beauty regarding skin, such as whitening, prevention and improvement of wrinkles, improvement of rough skin, etc. has been actively conducted. For example, many cosmetic compositions containing vitamin B group or its derivatives have been developed.

[0003] Among vitamin B group or its derivatives, for example, niacinamide has attracted attention as a cosmetic active ingredient having both whitening effect and anti-wrinkle effect (such as effects of preventing and improving wrinkles). And when applying a cosmetic composition containing such vitamin B group or its derivatives to the skin, it is desired to enhance the penetration of vitamin B group or its derivatives into the skin to enhance its cosmetic effect.

[0004] For example, in Patent Document 1, as a cosmetic composition that enhances the permeability of an active ingredient to the skin and extends the residence time of the active ingredient in the skin, a cosmetic composition suitable for topical application, which contains i) glycerin, ii) a lipid bilayer structuring agent having a glycerol head group, iii) a penetration enhancer, and iv) a skin care active ingredient, is disclosed.

[0005] On the other hand, as also mentioned in Patent Document 1, various skin penetration enhancers are known, but their mechanism of action, particularly the mechanism of action in the stratum corneum, is still under research, and it is difficult to rationally select a penetration enhancer for a given permeating substance.

Prior Art Documents

Patent Documents

[0006]

Patent Document 1

Summary of the Invention

[0007] Thus, while the effects of specific individual ingredients on skin penetration have been studied to some extent, the penetration of many cosmetic active ingredients into the skin remains unclear. For this reason, research is still needed to enhance the cosmetic effects of, for example, vitamin B group or its derivatives, by increasing their penetration into the skin.

[0008] The present invention aims to improve upon the above circumstances, and its objective is to provide a cosmetic composition and method that can promote the penetration of B vitamins or their derivatives into the skin, as well as a polymer suitable for use as a transdermal penetration enhancer for B vitamins or their derivatives. [Means for solving the problem]

[0009] The present invention, which achieves the above objectives, is as follows:

[0010] <Aspect 1> Vitamin B group or its derivatives, A polymer having repeating units represented by the following formula (I) as a transdermal penetration enhancer for the vitamin B group or its derivatives, Beauty composition containing: [ka] (In the formula, R1, R2, R3, R4, and R5 are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and M is a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an earth metal atom, or an ammonium atom.) <Aspect 2> In the above formula (I), R1, R4, and R5 are hydrogen atoms, R2 and R3 are methyl groups, and M is a hydrogen atom, a sodium atom, or an ammonium atom. The cosmetic composition according to Embodiment 1. <Aspect 3> The cosmetic composition according to embodiment 1 or 2, wherein the vitamin B group or its derivative is niacinamide. <Aspect 4> The polymers mentioned above include (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, (dimethylacrylamide / sodium acryloyldimethyltaurate) crosspolymer, (ammonium acryloyldimethyltaurate / beheneth-25 methacrylate) crosspolymer, (sodium acrylate / sodium acryloyldimethyltaurate) copolymer, sodium polyacryloyldimethyltaurate, (ammonium acryloyldimethyltaurate / steareth-25 methacrylate) crosspolymer, ammonium polyacryloyldimethyltaurate, (2-hydroxyethyl acrylate / sodium acryloyldimethyltaurate / steareth-20 methacrylate) copolymer, (acrylamide / sodium acryloyldimethyltaurate) copolymer, and (sodium acrylate / acryloyldimethyltaurate / dimethylacrylamide) crosspolymer. A cosmetic composition according to any one of embodiments 1 to 3, comprising at least one selected from the group consisting of a polymer, (sodium acrylate / sodium acryloyldimethyltaurate / acrylamide) copolymer, (hydroxyethyl acrylate / acryloyldimethyltaurate) sodium copolymer, (sodium acryloyldimethyltaurate / PEG-8 diacrylate) crosspolymer, (sodium acryloyldimethyltaurate / methacrylamide lauric acid) copolymer, (ammonium acryloyldimethyltaurate / carboxyethylammonium acrylate) crosspolymer, (ammonium acryloyldimethyltaurate / steareth-8 methacrylate) copolymer, (ammonium acryloyldimethyltaurate / laureth-7 methacrylate) copolymer, and (sodium acryloyldimethyltaurate / vinylpyrrolidone) crosspolymer. <Aspect 5> A cosmetic composition according to any one of embodiments 1 to 4, wherein the weight ratio of the vitamin B group or its derivative to the polymer (the vitamin B group or its derivative:the polymer) is 100:1 to 1:1. <Pattern 6> A cosmetic composition according to any one of embodiments 1 to 5, further comprising a base acceptable as a cosmetic. <Aspect 7> A cosmetic composition according to any one of embodiments 1 to 6, for topical application. <Aspect 8> A beauty method comprising applying a beauty composition described in any one of embodiments 1 to 7 to the skin. <Pattern 9> Use of polymers having repeating units represented by the following formula (I) as transdermal penetration enhancers for vitamin B group or its derivatives: [ka] (In the formula, R1, R2, R3, R4, and R5 are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and M is a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an earth metal atom, or an ammonium atom.) <Aspect 10> In the above formula (I), R1, R4, and R5 are hydrogen atoms, R2 and R3 are methyl groups, and M is a hydrogen atom, a sodium atom, or an ammonium atom. Use as described in aspect 9. <Aspect 11> The aforementioned B vitamins or their derivatives are niacinamide, and The polymer comprises at least one selected from the group consisting of (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, (dimethylacrylamide / sodium acryloyldimethyltaurate) crosspolymer, (ammonium acryloyldimethyltaurate / beheneth-25 methacrylate) crosspolymer, and (sodium acrylate / sodium acryloyldimethyltaurate) copolymer. The use according to aspect 9 or 10.

Advantages of the Invention

[0011] According to the present invention, it is possible to provide a cosmetic composition and a cosmetic method capable of promoting the penetration of vitamin B group or its derivatives into the skin, and a polymer suitable for use as a percutaneous penetration enhancer of vitamin B group or its derivatives.

Brief Description of the Drawings

[0012] [Figure 1] Figure 1 is a diagram showing the percutaneous penetration rate of niacinamide in Examples 1 to 4 and Comparative Example 1. [Figure 2] Figure 2 is a diagram showing the percutaneous penetration rate of niacinamide in Examples 5 to 8 and Comparative Example 1.

Modes for Carrying Out the Invention

[0013] Hereinafter, embodiments of the present invention will be described in detail. The present invention is not limited to the following embodiments, and can be variously modified and implemented within the scope of the gist of the invention.

[0014] 《Cosmetic Composition》 The cosmetic composition of the present invention comprises vitamin B group or its derivatives and a polymer having a repeating unit represented by the following formula (I) as a percutaneous penetration enhancer of vitamin B group or its derivatives and is a cosmetic composition containing:

Chemical Formula

[0015] Through diligent research by the present inventors, it has been found that polymers having repeating units represented by the above formula (I) act as transdermal penetration enhancers for vitamin B group or its derivatives.

[0016] <Vitamin B group or its derivatives> In the present invention, the B vitamin group or its derivatives are effective cosmetic ingredients. More specifically, the B vitamin group or its derivatives include, for example, one or more compounds selected from the group consisting of vitamin B1, vitamin B2, vitamin B3 (also called "niacin"), vitamin B5, vitamin B6, or vitamin B12, or derivatives thereof, and particularly preferably include vitamin B3, also called "niacin," or its derivatives. Note that "niacin" includes nicotinic acid and niacinamide (also called "nicotinamide").

[0017] Here, from the viewpoint that niacinamide possesses both a whitening effect and an anti-wrinkle effect, the vitamin B group or its derivative according to the present invention is preferably niacinamide. The structure of niacinamide is shown in the following formula (II).

[0018] [ka]

[0019] In the cosmetic composition of the present invention, the content of vitamin B group or its derivatives is not particularly limited as long as it is an amount that produces a cosmetic effect on the skin. For example, it may be 0.001% by mass or more, 0.005% by mass or more, 0.01% by mass or more, 0.05% by mass or more, 0.1% by mass or more, 0.5% by mass or more, 1.0% by mass or more, 2.0% by mass or more, 3.0% by mass or more, 4.0% by mass or more, or 5.0% by mass or more, based on the total amount of the composition (100% by mass), or it may be 20% by mass or less, 15% by mass or less, 10% by mass or less, 8.0% by mass or less, or 5.0% by mass or less.

[0020] <Transdermal penetration enhancer> In the present invention, "transdermal penetration enhancer" refers to a substance that improves the skin penetration of medicinal ingredients, with the aim of enhancing the effect of medicinal ingredients applied to the skin. Here, "specific substance" may be, for example, a cosmetic active ingredient, and more specifically, a vitamin B group or its derivatives according to the present invention, such as niacinamide.

[0021] (The polymer of the present invention) In the cosmetic composition of the present invention, a polymer having repeating units represented by the following formula (I) (hereinafter also simply referred to as "the polymer of the present invention") can act as a transdermal penetration enhancer for vitamin B group or its derivatives.

[0022] [ka] (In the formula, R1, R2, R3, R4, and R5 are each independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and M is a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an earth metal atom, or an ammonium atom.)

[0023] In formula (I), R1, R2, R3, R4, and R5 may each be independently a hydrogen atom (H) or an alkyl group having 1 to 3 carbon atoms. More specifically, R1, R4, and R5 may be hydrogen atoms, and R2 and R3 may be methyl groups (-CH3).

[0024] Furthermore, in formula (I), -SO3M may be a sulfonic acid or a sulfonate. Specifically, M may be a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an earth metal atom, or ammonium (NH4). Examples of alkali metal atoms include sodium (Na) or potassium (K). Examples of alkaline earth metal atoms include magnesium (Mg) or calcium (Ca). Examples of earth metal atoms include aluminum (Al). Of these, M may be, for example, a hydrogen atom, a sodium atom, or ammonium.

[0025] The polymer of the present invention may be a water-soluble polymer, and in particular may be an anionic water-soluble polymer.

[0026] The polymer of the present invention may be a homopolymer having repeating units represented by the above formula (I), or it may be a copolymer or crosspolymer having repeating units represented by the above formula (I).

[0027] Here, if the polymer of the present invention is a copolymer or crosspolymer, other copolymer components that can constitute the copolymer or crosspolymer together with the repeating unit represented by formula (I) above include, but are not limited to, N-vinylpyrrolidone, sodium or ammonium salts of acrylic acid or methacrylic acid, acrylamide, dimethylacrylamide, hydroxyethyl acrylate, methacrylamide lauric acid, carboxyethylammonium acrylate, 2-hydroxyethyl acrylate, beheneth-25 methacrylate, steareth-25 methacrylate, steareth-20 methacrylate, PEG-8 diacrylate, steareth-8 methacrylate, laureth-7 methacrylate, etc.

[0028] More specifically, the polymers of the present invention include (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, (dimethylacrylamide / sodium acryloyldimethyltaurate) crosspolymer, (ammonium acryloyldimethyltaurate / beheneth-25 methacrylate) crosspolymer, (sodium acrylate / sodium acryloyldimethyltaurate) copolymer, sodium polyacryloyldimethyltaurate, (ammonium acryloyldimethyltaurate / steareth-25 methacrylate) crosspolymer, ammonium polyacryloyldimethyltaurate, (2-hydroxyethyl acrylate / sodium acryloyldimethyltaurate / steareth-20 methacrylate) copolymer, (acrylamide / sodium acryloyldimethyltaurate) copolymer, and (sodium acrylate / acryloyldimethyltaurate The present invention may contain at least one selected from the group consisting of (dimethylacrylamide) crosspolymer, (sodium acrylate / sodium acryloyldimethyltaurate / acrylamide) copolymer, (hydroxyethyl acrylate / acryloyldimethyltaurate) sodium copolymer, (sodium acryloyldimethyltaurate / PEG-8 diacrylate) crosspolymer, (sodium acryloyldimethyltaurate / methacrylamide lauric acid) copolymer, (ammonium acryloyldimethyltaurate / carboxyethylammonium acrylate) crosspolymer, (ammonium acryloyldimethyltaurate / steareth-8 methacrylate) copolymer, (ammonium acryloyldimethyltaurate / laureth-7 methacrylate) copolymer, and (sodium acryloyldimethyltaurate / vinylpyrrolidone) crosspolymer. These polymers may be obtained by synthesis or may be commercially available. In the case of commercially available polymers, other solvents and additives may be present in the commercially available polymer as long as they do not impair the effects of the present invention.

[0029] In the cosmetic composition of the present invention, the content of the polymer of the present invention is not particularly limited as long as it is in an amount that can act as a transdermal penetration enhancer for vitamin B group or its derivatives. For example, it may be 0.001% by mass or more, 0.005% by mass or more, 0.01% by mass or more, 0.05% by mass or more, 0.1% by mass or more, 0.2% by mass or more, 0.3% by mass or more, 0.4% by mass or more, 0.5% by mass or more, 0.6% by mass or more, 0.7% by mass or more, 0.8% by mass or more, or 0.9% by mass or more, based on the total amount of the composition (100% by mass), or it may be 5.0% by mass or less, 4.0% by mass or less, 3.0% by mass or less, 2.0% by mass or less, or 1.0% by mass or less.

[0030] In the cosmetic composition of the present invention, the weight ratio of vitamin B group or its derivative to the polymer of the present invention (vitamin B group or its derivative: polymer of the present invention) may be 100:1 to 1:1, or in the range of 100:5 to 100:50, 100:5 to 100:20, or 100:5 to 100:15.

[0031] (Applications of the polymer of the present invention) The polymer of the present invention described above can also be used as a general thickening agent in cosmetics. In contrast, the inventors have found that using the polymer of the present invention together with B vitamins or their derivatives can promote the penetration of B vitamins or their derivatives into the skin.

[0032] <Bases acceptable for use in cosmetics> The cosmetic composition of the present invention may further contain a base that is acceptable as a cosmetic. The base that is acceptable as a cosmetic may act as a diluent, dispersant, or carrier for other materials present in the composition and may play a role in promoting their distribution when the composition is applied to the skin.

[0033] Cosmetic-approved bases may consist of components including fatty acids having 10 to 30 carbon atoms and their salts, water, liquid or solid emollients, solvents, humectants, thickeners, and powders. These components may be used individually or in mixtures thereof to form cosmetic-approved bases.

[0034] Examples of fatty acids that can be used as a base for cosmetics include fatty acids having 10 to 30 carbon atoms, and may include pelargonic acid, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, arachidic acid, behenic acid or erucic acid, and their derivatives, as well as mixtures thereof. Examples of fatty acid salts may include potassium stearate.

[0035] Examples of emollients that can be used as a base for cosmetics include stearyl alcohol, glyceryl monoricinoleate, mink oil, cetyl alcohol, isopropyl isostearate, stearic acid, isobutyl palmitate, isocetyl stearate, oleyl alcohol, isopropyl laurate, hexyl laurate, decyl oleate, octadecane-2-ol, isocetyl alcohol, eicosanyl alcohol, behenyl alcohol, cetyl palmitate, silicone oils such as dimethylpolysiloxane, di-n-butyl sebacate, isopropyl myristate, and palmitate. This product may contain isopropyl mitate, isopropyl stearate, butyl stearate, polyethylene glycol, triethylene glycol, lanolin, cocoa butter, corn oil, cottonseed oil, olive oil, palm kernel oil, rapeseed oil, safflower seed oil, evening primrose oil, soybean oil, sunflower oil, avocado oil, sesame oil, coconut oil, peanut oil, castor oil, acetylated lanolin alcohol, petrolatum, mineral oil, butyl myristate, isostearic acid, palmitic acid, isopropyl linoleate, lauryl lactate, myristyl lactate, decyl oleate, myristyl myristate, and mixtures thereof.

[0036] Examples of powders that can be used as a base for cosmetics include chalk, talc, fuller's earth, kaolin, starch, gums, colloidal silica sodium polyacrylate, tetraalkyl and / or trialkylarylammonium smectite, chemically modified magnesium aluminum silicate, organically modified montmorillonite clay, hydrated aluminum silicate, fumed silica, carboxyvinyl polymer, sodium carboxymethylcellulose, and ethylene glycol monostearate.

[0037] In the cosmetic composition of the present invention, if a base acceptable as a cosmetic is further included, the content thereof is not particularly limited and may be, for example, 5.0 to 99.5% by mass, 20 to 80% by mass, or 30 to 75% by mass, based on the total amount (100% by mass) of the composition.

[0038] <Other ingredients> The cosmetic composition of the present invention may further contain other components in addition to those described above. Examples of other components include, but are not limited to, skin whitening agents, sunscreens, surfactants, antioxidants, binders, biological additives, buffers, colorants, polymers, astringents, fragrances, emulsions, conditioners, exfoliants, pH adjusters, preservatives, natural extracts, skin sensory agents, skin smoothing agents, and skin healing agents. Furthermore, the amount of each of these other components present is not particularly limited and should be within an acceptable range for cosmetic use.

[0039] <Form of composition> The cosmetic composition of the present invention may be for topical application to the skin. Therefore, examples of the cosmetic composition of the present invention include, but are not limited to, lotions, creams, gels, masks, or mousses.

[0040] 《Beauty method》 The present invention's cosmetic method includes applying the above-described cosmetic composition to the skin.

[0041] According to the present invention's cosmetic method, the penetration of B vitamins or their derivatives, which are effective cosmetic ingredients, into the skin can be promoted. [Examples]

[0042] The present invention will be explained in more detail below with reference to examples, but the present invention is not limited to these examples. Unless otherwise specified, the numerical values ​​in the tables below represent the amount of each component, and the unit is mass%.

[0043] Examples 1-8 and Comparative Example 1 Based on the formulations in Tables 1 and 2, compositions for Examples 1-8 and Comparative Example 1 were prepared, and the transdermal penetration of the vitamin B group or its derivatives contained in each composition was evaluated.

[0044] In Table 1, the structural formula of (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, used as a transdermal penetration enhancer, is as follows (product name: Aristoflex AVC, manufactured by Clariant):

[0045] [ka]

[0046] Furthermore, in Table 1, the structural formula of (ammonium acryloyldimethyltaurate / beheneth-25 methacrylate) crosspolymer as a transdermal penetration enhancer is as follows (note: l:m = 95:5~98:2 (molar ratio), trade name: Aristoflex HMB, manufactured by Clariant):

[0047] [ka]

[0048] Furthermore, in Table 2, the structural formula of (dimethylacrylamide / sodium acryloyldimethyltaurate) crosspolymer as a transdermal penetration enhancer is as follows (note that a:b:c = 80:20:0.1 (molar ratio)):

[0049] [ka]

[0050] Furthermore, in Table 2, the structural formula of the (sodium acrylate / sodium acryloyldimethyl taurate) copolymer is as follows (trade name: SIMULGEL EG, manufactured by Sepic):

[0051] [ka]

[0052] [Table 1]

[0053] [Table 2]

[0054] "evaluation" (Evaluation method) Franz-type diffusion cell (effective transmission area: 0.79 cm²) 2 A receiver cell was filled with 7.5 mL of phosphate-buffered saline (also abbreviated as "PBS"), a skin substitute membrane (Strat-M® (Merck)) was sandwiched between the cells, and the surface temperature was adjusted to 32°C. Strat-M® is one of the commonly used skin substitute membranes for evaluating skin permeability by passive diffusion.

[0055] After hydrating the skin substitute membrane, 10 μL / cm³ 2 The cosmetic compositions of each example and comparative example were applied to the donor cell in the specified volume and spread with a spatula for 30 seconds.

[0056] Then, 1, 2, 3, 4, 6, and 8 hours after the application of each cosmetic composition, 0.3 mL of the receiver solution was sampled and replenished with the same amount of PBS.

[0057] The sampled receivers were quantified by HPLC to determine the amount of niacinamide that penetrated over time in the cosmetic compositions of each example and comparative example. The transdermal penetration rate (%) of niacinamide was then calculated from the obtained penetration amounts using the following formula 1: Transdermal penetration rate of NA (%) = (Amount of NA penetrated / Amount of NA applied) × 100% (Note that "NA" stands for niacinamide.)

[0058] The transdermal penetration rates of niacinamide in Examples 1-4 and Comparative Example 1 are shown in Figure 1, and the transdermal penetration rates of niacinamide in Examples 5-8 and Comparative Example 1 are shown in Figure 2.

[0059] (Evaluation results) As is clear from Figures 1 and 2, it was found that the beauty compositions of Examples 1 to 8 all promoted the penetration of niacinamide (vitamin B group or its derivatives) into the skin compared to the beauty composition of Comparative Example 1 (a composition that does not contain a transdermal penetration enhancer for vitamin B group or its derivatives).

[0060] This is thought to be due to the use of the polymer of the present invention as a transdermal penetration enhancer for vitamin B group or its derivatives in the cosmetic compositions of Examples 1 to 8. In other words, it is suggested that the polymer of the present invention can be used as a transdermal penetration enhancer for vitamin B group or its derivatives.

[0061] Comparative Examples 2-5 In Comparative Examples 2 to 5, when a low-molecular-weight compound having a methyl taurine group was incorporated into the cosmetic composition instead of the polymer of the present invention, the transdermal penetration of B vitamins or their derivatives after 1, 2, 3, 4, 6, and 8 hours was evaluated in the same manner as described above.

[0062] The formulations of the cosmetic compositions for Comparative Examples 2 to 5 are shown in Table 3 below.

[0063] [Table 3]

[0064] As a result, none of the cosmetic compositions in Comparative Examples 2 to 5 showed any effect in promoting the transdermal penetration of niacinamide (vitamin B group or its derivatives).

Claims

1. Vitamin B group or its derivatives, An active ingredient for promoting the transdermal penetration of the aforementioned B vitamins or their derivatives, comprising a polymer having repeating units represented by the following formula (I), A cosmetic composition for promoting the transdermal penetration of the vitamin B group or its derivatives, comprising: 【Chemistry 1】 (In the formula, R １ , R ２ , R ３ , R ４ , and R ５ Each of these is independently a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and M is a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an earth metal atom, or an ammonium atom.

2. In the above formula (I), R １ , R ４ , and R ５ It is a hydrogen atom, R ２ and R ３ is a methyl group, and M is a hydrogen atom, a sodium atom, or an ammonium atom. The cosmetic composition according to claim 1.

3. The cosmetic composition according to claim 1, wherein the vitamin B group or its derivative is niacinamide.

4. The polymers mentioned above include (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymer, (dimethylacrylamide / sodium acryloyldimethyltaurate) crosspolymer, (ammonium acryloyldimethyltaurate / beheneth-25 methacrylate) crosspolymer, (sodium acrylate / sodium acryloyldimethyltaurate) copolymer, sodium polyacryloyldimethyltaurate, (ammonium acryloyldimethyltaurate / steareth-25 methacrylate) crosspolymer, ammonium polyacryloyldimethyltaurate, (2-hydroxyethyl acrylate / sodium acryloyldimethyltaurate / steareth-20 methacrylate) copolymer, (acrylamide / sodium acryloyldimethyltaurate) copolymer, (sodium acrylate / acryloyldimethyltaurate / dimethylacrylamide The cosmetic composition according to claim 1, comprising at least one selected from the group consisting of (d) crosspolymer, (sodium acrylate / sodium acryloyldimethyltaurate / acrylamide) copolymer, (hydroxyethyl acrylate / acryloyldimethyltaurate) copolymer sodium, (sodium acryloyldimethyltaurate / PEG-8 diacrylate) crosspolymer, (sodium acryloyldimethyltaurate / methacrylamide lauric acid) copolymer, (ammonium acryloyldimethyltaurate / carboxyethylammonium acrylate) crosspolymer, (ammonium acryloyldimethyltaurate / steareth-8 methacrylate) copolymer, (ammonium acryloyldimethyltaurate / laureth-7 methacrylate) copolymer, and (sodium acryloyldimethyltaurate / vinylpyrrolidone) crosspolymer.

5. The cosmetic composition according to claim 1, wherein the weight ratio of the vitamin B group or its derivative to the polymer (the vitamin B group or its derivative:the polymer) is 100:1 to 1:

1.

6. The cosmetic composition according to claim 1, further comprising a base acceptable as a cosmetic.

7. The cosmetic composition according to claim 1, for topical application.

8. A beauty method comprising applying a beauty composition according to any one of claims 1 to 7 to the skin.

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