Composition for semiconductor photoresist, and method for forming patterns using the same

Abstract

This invention provides a semiconductor photoresist composition with excellent resolution characteristics and pattern adhesion by reducing the influence of variables during pattern formation and improving CD (critical dimension) stability. It also provides a pattern formation method using the aforementioned semiconductor photoresist composition. [Solution] The present invention relates to a semiconductor photoresist composition comprising an organometallic compound represented by chemical formula 1 and a solvent, and a pattern formation method utilizing the same. Details regarding chemical formula 1 are described in the specification. JPEG2026089692000020.jpg2551 [Chemical formula 1]

Description

[Technical Field]

[0001] The present invention relates to a semiconductor photoresist composition and a pattern formation method utilizing the same. [Background technology]

[0002] EUV (extreme ultraviolet) lithography is attracting attention as one of the key technologies for manufacturing next-generation semiconductor devices. EUV lithography is a pattern formation technique that uses EUV light with a wavelength of 13.5 nm as the exposure light source. EUV lithography has been demonstrated to be able to form extremely fine patterns (for example, less than 20 nm) in the exposure process of semiconductor device manufacturing.

[0003] To realize extreme ultraviolet (EUV) lithography, compatible photoresist development that can be performed at spatial resolutions of 16 nm or less is required. Currently, traditional chemically amplified (CA) photoresists are striving to meet the specifications for resolution, photospeed, feature roughness, and line edge roughness (LER) for next-generation devices.

[0004] The intrinsic image blur caused by acid-catalyzed reactions in these polymer-type photoresists limits resolution at small feature sizes, a fact long known in electron beam lithography. Chemically amplified (CA) photoresists are designed for high sensitivity, but their typical elemental makeup reduces the photoresist absorbance at a wavelength of 13.5 nm. As a result, the reduced sensitivity of CA photoresists can sometimes lead to further difficulties under EUV exposure.

[0005] CA photoresists also sometimes experience difficulties due to roughness issues with small feature sizes, and in some cases, experiments have shown that line edge roughness (LER) increases due to a decrease in photospeed, which is inherent to the acid-catalyzed process. Due to the shortcomings and problems of CA photoresists, the semiconductor industry has a demand for new types of high-performance photoresists.

[0006] To overcome the shortcomings of the chemically amplified organic photosensitive compositions described above, inorganic photosensitive compositions have been studied. Inorganic photosensitive compositions are mainly used for negative tone patterning that is resistant to removal by developer compositions through chemical modification via a non-chemical amplification mechanism. Inorganic photosensitive compositions contain inorganic elements that have a higher EUV absorption rate compared to hydrocarbons, and can ensure sensitivity even with a non-chemical amplification mechanism. They are also known for their low sensitivity to the stochastic effect, resulting in less line edge roughness and fewer defects.

[0007] Inorganic photoresists based on tungsten and peroxopolyacids of tungsten mixed with niobium, titanium, and / or tantalum have been reported for use as radiation-sensitive materials for patterning (US5061599; H.Okamoto, T.Iwayanagi, K.Mochiji, H.Umezaki, T.Kudo, Applied Physics Letters, 49(5), 298-300, 1986).

[0008] These materials have been used in deep UV, X-ray, and electron beam sources and have been effective in patterning large features in bilayer configurations. More recently, cationic hafnium metal oxide sulfate (HfSOx) materials with peroxo complexing agents have shown impressive performance for imaging 15 nm half-pitch (HP) by projection EUV lithography (see Patent Document 1 and Non-Patent Document 1). This system exhibits the best performance of non-CA photoresists and has a light speed close to the requirements for a viable EUV photoresist. However, hafnium metal oxide sulfate materials with peroxo complexing agents have several substantial drawbacks. Firstly, this material is coated with a highly corrosive sulfuric acid / hydrogen peroxide mixture, resulting in poor shelf-life stability. Secondly, these materials are composite mixtures, making structural modifications for performance improvement difficult. Thirdly, these materials must be developed with extremely high concentrations of TMAH (tetramethylammonium hydroxide) solution, such as 25 wt%.

[0009] Recently, there has been active research into tin-containing molecules, as it has become known that they exhibit outstanding absorption of extreme ultraviolet light. In the case of organotin polymers, one such example, the alkyl ligand is dissociated by light absorption or the secondary electrons generated by it, and negative tone patterning is possible through crosslinking via oxo bonds with surrounding chains, which prevents removal by organic developers. Such organotin polymers have shown a dramatic improvement in sensitivity while maintaining resolution and line edge roughness, but further improvement of the aforementioned patterning properties is necessary for commercialization. [Prior art documents] [Patent Documents]

[0010] [Patent Document 1] U.S. Patent Application Publication No. 2011-0045406 [Non-patent literature]

[0011] [Non-Patent Document 1] JKStowers, A. Telecky, M. Kocsis, BLClark, DAKEszler, A. Grenville, CN Anderson, "Directly patterned inorganic hardmask fwor EUV lithography" PPNaulleau, Proc. SPIE, 7969, 796915, 2011 [Overview of the project] [Problems that the invention aims to solve]

[0012] One embodiment of the present invention provides a semiconductor photoresist composition with excellent resolution characteristics and pattern adhesion by reducing the influence of variables during pattern formation and improving CD (critical dimension) stability.

[0013] Another embodiment of the present invention provides a pattern formation method using the semiconductor photoresist composition described above. [Means for solving the problem]

[0014] A semiconductor photoresist composition according to one embodiment of the present invention comprises an organometallic compound represented by the following chemical formula 1 and a solvent.

[0015] [ka] [Chemical formula 1]

[0016] In the aforementioned chemical formula 1, L 1 This is one or more selected from the group consisting of single bonds, substituted or unsubstituted alkylene groups having 1 to 10 carbon atoms, substituted or unsubstituted alkenylene groups having 2 to 10 carbon atoms, substituted or unsubstituted alkynylene groups having 2 to 10 carbon atoms, substituted or unsubstituted cycloalkylene groups having 3 to 20 carbon atoms, substituted or unsubstituted cycloalkenylene groups having 3 to 20 carbon atoms, and substituted or unsubstituted aromatic rings having 6 to 20 carbon atoms. R 1 and R 2 Each of these is independently selected from hydrogen, substituted or unsubstituted C1-C10 alkyl groups, substituted or unsubstituted C3-C10 cycloalkyl groups, substituted or unsubstituted C6-C20 aryl groups, and substituted or unsubstituted C7-C20 arylalkyl groups. n is 1 or greater, L 1 An integer less than or equal to (bond valence - 1), Y 1 ~Y 3 These are independently an alkoxy group and an aryloxy group (-OR a Here, R ais a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), a carboxyl group (-O(CO)R b where R b is hydrogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), an alkylamide group and a dialkylamide group (-NR c R d where R c and R d are each independently hydrogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), an amidato group (-NR e (COR f ) where R e and R f are each independently hydrogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), an amidinato group (-NR g C(NR h )R i where R g R h and R iEach of these is independently hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), an alkylthio group, and an arylthio group (-SR). j Here, R j (These are substituted or unsubstituted C1-C20 alkyl groups, substituted or unsubstituted C3-C20 cycloalkyl groups, substituted or unsubstituted C2-C20 alkenyl groups, substituted or unsubstituted C2-C20 alkynyl groups, substituted or unsubstituted C6-C30 aryl groups, or combinations thereof), and thiocarboxyl groups (-S(CO)R k , R k (The group is selected from hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof.)

[0017] A pattern formation method according to another embodiment includes the steps of forming an etching target film on a substrate, applying the above-described semiconductor photoresist composition on the etching target film to form a photoresist film, exposing and developing the photoresist film to form a photoresist film on which a photoresist pattern is formed, and etching the etching target film using the photoresist pattern as an etching mask. [Effects of the Invention]

[0018] A pattern formed using a semiconductor photoresist composition according to one embodiment of the present invention can achieve excellent resolution by improving CD stability. [Brief explanation of the drawing]

[0019] [Figure 1] This is a cross-sectional view illustrating a pattern formation method using a semiconductor photoresist composition according to one embodiment. [Modes for carrying out the invention]

[0020] Embodiments of the present invention will be described in detail below with reference to the attached drawings. However, in order to clarify the gist of this description, descriptions of functions or configurations that are already publicly known will be omitted.

[0021] To clearly explain this description, unnecessary explanatory parts have been omitted, and the same or similar components are denoted by the same reference numerals throughout the specification. Furthermore, the dimensions and thicknesses of each component shown in the drawings are arbitrarily shown for explanatory purposes, and this description is not necessarily limited to those shown.

[0022] In the drawings, the thicknesses were enlarged to clearly represent multiple layers and regions. Furthermore, for explanatory purposes, the thicknesses of some layers and regions were exaggerated in the drawings. When a layer, film, region, plate, or other part is said to be "on top of" another part, this includes not only cases where it is "directly on top" of another part, but also cases where there is another part in between.

[0023] In this document, "substituted" means that the hydrogen atom is replaced by deuterium, halogen group, hydroxyl group, carboxyl group, thiol group, cyano group, nitro group, -NRR' (where R and R' are independently hydrogen, a substituted or unsubstituted saturated or unsaturated aliphatic hydrocarbon group having 1 to 30 carbon atoms, a substituted or unsubstituted saturated or unsaturated alicyclic hydrocarbon group having 3 to 30 carbon atoms, or a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 carbon atoms), -SiRR'R'' (where R, R', and R'' are independently hydrogen, a substituted or unsubstituted This means that the group is substituted with an alkyl group having 1 to 30 carbon atoms, a haloalkyl group having 1 to 10 carbon atoms, an alkylsilyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 30 carbon atoms, an aryl group having 6 to 30 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a sulfide group having 1 to 20 carbon atoms, or a combination thereof. "Unsubstituted" means that the hydrogen atom is not substituted by another substituent and remains as a hydrogen atom.

[0024] In this specification, "alkyl (alkyl) group" means a linear or branched aliphatic hydrocarbon group unless otherwise defined. The alkyl group may be a "saturated alkyl group" that does not contain any double or triple bonds.

[0025] The alkyl group may be an alkyl group having 1 to 8 carbon atoms. For example, the alkyl group may be an alkyl group having 1 to 7 carbon atoms, an alkyl group having 1 to 6 carbon atoms, or an alkyl group having 1 to 5 carbon atoms. For example, the alkyl group having 1 to 5 carbon atoms may be a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a sec-butyl group, or a tert-butyl group or a 2,2-dimethylpropyl group.

[0026] In this document, "cycloalkyl group" refers to a monovalent cyclic aliphatic saturated hydrocarbon group unless otherwise defined.

[0027] The cycloalkyl group may be a cycloalkyl group having 3 to 8 carbon atoms, for example, a cycloalkyl group having 3 to 7 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, a cycloalkyl group having 3 to 5 carbon atoms, or a cycloalkyl group having 3 to 4 carbon atoms. For example, the cycloalkyl group may be a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, or a cyclohexyl group, and is not limited to these.

[0028] In this specification, “aliphatic unsaturated organic group” means a hydrocarbon group that contains a bond between carbon atoms in the molecule that is a double bond, a triple bond, or a combination thereof.

[0029] The aliphatic unsaturated organic group may be an aliphatic unsaturated organic group having 2 to 8 carbon atoms. For example, the aliphatic unsaturated organic group may be an aliphatic unsaturated organic group having 2 to 7 carbon atoms, an aliphatic unsaturated organic group having 2 to 6 carbon atoms, an aliphatic unsaturated organic group having 2 to 5 carbon atoms, or an aliphatic unsaturated organic group having 2 to 4 carbon atoms. For example, the aliphatic unsaturated organic group having 2 to 4 carbon atoms may be a vinyl group, an ethynyl group, an allyl group, a 1-propenyl group, a 1-methyl-1-propenyl group, a 2-propenyl group, a 2-methyl-2-propenyl group, a 1-propynyl group, a 1-methyl-1-propynyl group, a 2-propynyl group, a 2-methyl-2-propynyl group, a 1-butenyl group, a 2-butenyl group, a 3-butenyl group, a 1-butynyl group, a 2-butynyl group, or a 3-butynyl group.

[0030] In this specification, “aryl group” means a substituent in which all elements of the cyclic substituent have p-orbitals and these p-orbitals form a conjugation, and includes monocyclic or fused-ring polycyclic (i.e., rings sharing adjacent pairs of carbon atoms) functional groups.

[0031] In this specification, a "heteroaryl group" means an aryl group containing at least one heteroatom selected from the group consisting of N, O, S, P, and Si. Two or more heteroaryl groups can be directly linked through sigma bonds, or, if the heteroaryl group contains two or more rings, the two or more rings can be fused together. If the heteroaryl group is a fused ring, each ring may contain one to three of the heteroatoms.

[0032] In this specification, "alkenyl group" means an aliphatic unsaturated alkenyl group, which is a linear or branched aliphatic hydrocarbon group containing one or more double bonds, unless otherwise defined.

[0033] In this specification, "alkynyl group" means an aliphatic unsaturated alkynyl group, which is a linear or branched aliphatic hydrocarbon group containing one or more triple bonds, unless otherwise defined.

[0034] A semiconductor photoresist composition according to one embodiment will be described below.

[0035] A semiconductor photoresist composition according to one embodiment of the present invention may contain an organometallic compound represented by the following chemical formula 1 and a solvent.

[0036] [ka] [Chemical formula 1]

[0037] In the aforementioned chemical formula 1, L 1This is one or more selected from the group consisting of single bonds, substituted or unsubstituted alkylene groups having 1 to 10 carbon atoms, substituted or unsubstituted alkenylene groups having 2 to 10 carbon atoms, substituted or unsubstituted alkynylene groups having 2 to 10 carbon atoms, substituted or unsubstituted cycloalkylene groups having 3 to 20 carbon atoms, substituted or unsubstituted cycloalkenylene groups having 3 to 20 carbon atoms, and substituted or unsubstituted aromatic rings having 6 to 20 carbon atoms. R 1 and R 2 Each of these is independently selected from hydrogen, substituted or unsubstituted C1-C10 alkyl groups, substituted or unsubstituted C3-C10 cycloalkyl groups, substituted or unsubstituted C6-C20 aryl groups, and substituted or unsubstituted C7-C20 arylalkyl groups. n is 1 or greater, L 1 An integer less than or equal to (bond valence - 1), Y 1 ~Y 3 These are independently an alkoxy group and an aryloxy group (-OR a Here, R a (These are substituted or unsubstituted C1-C20 alkyl groups, substituted or unsubstituted C3-C20 cycloalkyl groups, substituted or unsubstituted C2-C20 alkenyl groups, substituted or unsubstituted C2-C20 alkynyl groups, substituted or unsubstituted C6-C30 aryl groups, or combinations thereof), carboxyl groups (-O(CO)R b , R b (These are hydrogen, substituted or unsubstituted C1-C20 alkyl groups, substituted or unsubstituted C3-C20 cycloalkyl groups, substituted or unsubstituted C2-C20 alkenyl groups, substituted or unsubstituted C2-C20 alkynyl groups, substituted or unsubstituted C6-C30 aryl groups, or combinations thereof), alkylamide groups and dialkylamide groups (-NR) c R d Here, R c and R dEach of these is independently a hydrogen atom, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), an amidato group (-NR) e (COR f ), here R e and R f Each of these is independently a hydrogen atom, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), an amidinato group (-NR) g C(NR h )R i Here, R g , R h and R i Each of these is independently hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), an alkylthio group, and an arylthio group (-SR). j Here, R j (These are substituted or unsubstituted C1-C20 alkyl groups, substituted or unsubstituted C3-C20 cycloalkyl groups, substituted or unsubstituted C2-C20 alkenyl groups, substituted or unsubstituted C2-C20 alkynyl groups, substituted or unsubstituted C6-C30 aryl groups, or combinations thereof), and thiocarboxyl groups (-S(CO)R k , R k(The group is selected from hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof.)

[0038] A pattern formation method using a semiconductor photoresist composition containing an organometallic compound comprises the following steps: the photoresist composition is applied onto a film to be etched, thereby coating the film with the organometallic compound or its cluster molecules; and the organic matter in the photoresist composition is removed and the metal oxide is patterned through a first baking step, an exposure step, a second baking step, and a development step.

[0039] In this process, the patterning of the metal oxide is affected by various variables such as temperature, solvent, concentration, catalyst, and atmospheric conditions, and this effect is relatively greater as the pattern size decreases. Typically, in the case of patterns formed by photoresist compositions containing organometallic compounds, the size is very small, ranging from a few nanometers to tens of nanometers, and the influence of process conditions on pattern formation is greater compared to existing photoresists.

[0040] In particular, it is known that pattern formation using photoresist compositions containing organometallic compounds is affected by the concentration of nitrogen oxides (NOx) in the atmosphere. NOx is highly reactive among substances present in the atmosphere and can react with moisture in the atmosphere, sunlight, etc., to cause phenomena such as smog. When the NOx concentration exceeds a certain level, problems have been observed where the pattern width and other parameters observed after development differ from the target values.

[0041] Therefore, in this invention, we aimed to develop a photoresist composition that can suppress the deformation phenomenon of pattern width caused by NOx by introducing a compound containing a photoreactive group substituted with one or more nitro groups to remove nitrogen oxide radicals, or by ultimately oxidizing the metal in the organometallic compound to reduce its reactivity with nitrogen oxides.

[0042] For example, n may be an integer of 1 or 2, or n may be an integer of 1.

[0043] Said L 1 For example, this may be one or more selected from the group consisting of single-bonded, substituted or unsubstituted alkylene groups having 1 to 10 carbon atoms, substituted or unsubstituted alkenylene groups having 2 to 10 carbon atoms, substituted or unsubstituted alkynylene groups having 2 to 10 carbon atoms, substituted or unsubstituted cycloalkenes having 3 to 20 carbon atoms, and substituted or unsubstituted aromatic rings having 6 to 20 carbon atoms.

[0044] As a specific example, L 1 This may be one or more selected from the group consisting of substituted or unsubstituted C2-C10 alkenylene groups, substituted or unsubstituted C2-C10 alkynylene groups, substituted or unsubstituted C3-C20 cycloalkenes, and substituted or unsubstituted C6-C20 aromatic rings.

[0045] As a more specific example, the L 1 This may be one or more selected from the group consisting of substituted or unsubstituted alkenylene groups having 2 to 10 carbon atoms, and substituted or unsubstituted aromatic rings having 6 to 20 carbon atoms.

[0046] For example, L 1 This may be one or more selected from the group consisting of substituted or unsubstituted alkenylene groups having 2 to 5 carbon atoms, and substituted or unsubstituted aromatic rings having 6 to 12 carbon atoms.

[0047] In one embodiment, the L 1This can include at least one conjugation system in which two or more multiple bonds are linked via single bonds.

[0048] In one specific embodiment, the L 1 It can contain at least one conjugated diene.

[0049] A conjugation system refers to a type of bond where two or more multiple bonds are separated by a single bond, forming an alternating sequence of single and multiple bonds.

[0050] In a conjugation system, each carbon atom forms a bond, and the remaining p orbitals interact in parallel to each other to form a π molecular orbital. This π molecular orbital enables electron transfer throughout the entire molecule, resulting in a uniform distribution of electrons and a uniform electron density throughout the molecule.

[0051] For example, L 1 This may be one or more selected from the group consisting of substituted or unsubstituted ethylene groups, substituted or unsubstituted ethynylene groups, and substituted or unsubstituted benzene groups.

[0052] For example, L 1 This may be a conjugated form of two or more groups selected from the group consisting of substituted or unsubstituted ethylene groups, substituted or unsubstituted ethynylene groups, and substituted or unsubstituted benzene groups.

[0053] When a linking group connecting NO2 and Sn is conjugated, the ability to suppress the deformation phenomenon of pattern width caused by NOx is further improved.

[0054] As an example, Y 1 ~Y 3 These are independently an alkoxy group and an aryloxy group (-OR a Here, R a(which is a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof), a carboxyl group (-O(CO)R b , R b (These are hydrogen, substituted or unsubstituted C1-C10 alkyl groups, substituted or unsubstituted C3-C10 cycloalkyl groups, substituted or unsubstituted C2-C10 alkenyl groups, substituted or unsubstituted C2-C10 alkynyl groups, substituted or unsubstituted C6-C20 aryl groups, or combinations thereof), alkylamide groups and dialkylamide groups (-NR) c R d Here, R c and R d Each of these is independently a hydrogen atom, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), an amidato group (-NR) e (COR f ), here R e and R f Each of these is independently a hydrogen atom, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof), an amidinato group (-NR) g C(NR h )R i Here, R g , R h and R iis independently hydrogen, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof), an alkylthio group and an arylthio group (-SR j , where R j is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof), and a thiocarboxyl group (-S(CO)R k , R k is hydrogen, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof) and can be selected from.

[0055] As a specific example, the above Y 1 ~Y 3 are each independently an alkoxy group and an aryloxy group (-OR a , where R a % is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof), a carboxyl group (-O(CO)R b , R bis hydrogen, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof), and an amidato group (-NR e (COR f ), where R e and R f are each independently selected from hydrogen, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof).

[0056] More specifically, as an example, the Y 1 ~Y 3 are each independently an alkoxy group and an aryloxy group (-OR a , where R a is a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof), and a carboxyl group (-O(CO)R b , R b is hydrogen, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 10 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 20 carbon atoms, or a combination thereof), and can be selected from the above.

[0057] For example, the R aThese are substituted or unsubstituted methyl groups, substituted or unsubstituted ethyl groups, substituted or unsubstituted propyl groups, substituted or unsubstituted butyl groups, substituted or unsubstituted isopropyl groups, substituted or unsubstituted tert-butyl groups, substituted or unsubstituted tert-pentyl groups, substituted or unsubstituted 2,2-dimethylpropyl groups, substituted or unsubstituted cyclopropyl groups, substituted or unsubstituted cyclobutyl groups, substituted or unsubstituted cyclopentyl groups, substituted or unsubstituted cyclohexyl groups, substituted or unsubstituted ethenyl groups, substituted or unsubstituted propenyl groups, substituted or unsubstituted butenyl groups, substituted or unsubstituted ethynyl groups, substituted or unsubstituted propynyl groups, substituted or unsubstituted butynyl groups, substituted or unsubstituted phenyl groups, substituted or unsubstituted tolyl groups, substituted or unsubstituted xylene groups, substituted or unsubstituted benzyl groups, or combinations thereof. R b , R c , R d , R e , R f , R g , R h , R i , R j and R k Each of these may independently be hydrogen, a substituted or unsubstituted methyl group, a substituted or unsubstituted ethyl group, a substituted or unsubstituted propyl group, a substituted or unsubstituted butyl group, a substituted or unsubstituted isopropyl group, a substituted or unsubstituted tert-butyl group, a substituted or unsubstituted tert-pentyl group, a substituted or unsubstituted 2,2-dimethylpropyl group, a substituted or unsubstituted cyclopropyl group, a substituted or unsubstituted cyclobutyl group, a substituted or unsubstituted cyclopentyl group, a substituted or unsubstituted cyclohexyl group, a substituted or unsubstituted ethenyl group, a substituted or unsubstituted propenyl group, a substituted or unsubstituted butenyl group, a substituted or unsubstituted ethynyl group, a substituted or unsubstituted propynyl group, a substituted or unsubstituted butynyl group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted tolyl group, a substituted or unsubstituted xylene group, a substituted or unsubstituted benzyl group, or a combination thereof.

[0058] As an example, R 1 and R 2 Each of these may independently be hydrogen or a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms.

[0059] As a specific example, R 1 and R 2 Each of these may independently be hydrogen or a substituted or unsubstituted alkyl group having 1 to 5 carbon atoms.

[0060] As a more specific example, the aforementioned R 1 and R 2 Each of these may independently be a hydrogen atom, a substituted or unsubstituted methyl group, a substituted or unsubstituted ethyl group, or a substituted or unsubstituted propyl group.

[0061] In one specific embodiment, the organometallic compound represented by chemical formula 1 can be selected from the compounds listed in Group 1 below.

[0062] [Group 1] [ka]

[0063] [ka]

[0064] [ka]

[0065] The organometallic compound represented by chemical formula 1 strongly absorbs extreme ultraviolet light at 13.5 nm and exhibits excellent sensitivity to high-energy light.

[0066] In one embodiment of a semiconductor photoresist composition, the organometallic compound represented by chemical formula 1 may be contained in an amount of 0.5% to 30% by weight, for example, 1% to 30% by weight, 1% to 25% by weight, for example, 1% to 20% by weight, for example, 1% to 15% by weight, for example, 1% to 10% by weight, for example, 1% to 5% by weight, based on 100% by weight of the semiconductor photoresist composition, and is not limited to these amounts. When the organometallic compound is contained in an amount within the above range, the storage stability and etching resistance of the semiconductor photoresist composition are improved, and the resolution characteristics are improved.

[0067] A semiconductor photoresist composition according to one embodiment of the present invention, by containing the above-mentioned organometallic compound, can provide a semiconductor photoresist composition having excellent sensitivity and pattern-forming properties.

[0068] The solvent contained in the semiconductor photoresist composition according to one embodiment may be an organic solvent, and may include, but is not limited to, aromatic compounds (e.g., xylene, toluene), alcohols (e.g., 4-methyl-2-pentanol, 4-methyl-2-propanol, 1-butanol, methanol, isopropyl alcohol, 1-propanol), ethers (e.g., anisole, tetrahydrofuran), esters (n-butyl acetate, propylene glycol monomethyl ether acetate, ethyl acetate, ethyl lactate), ketones (e.g., methyl ethyl ketone, 2-heptanone), and mixtures thereof.

[0069] In one embodiment, the semiconductor photoresist composition may further contain a resin in addition to the organometallic compound and the solvent.

[0070] The aforementioned resin may be a phenolic resin containing at least one of the aromatic moieties listed in Group 2 below.

[0071] [Group 2] [ka]

[0072] The resin may have a weight-average molecular weight of 500 to 20,000.

[0073] The resin may be included in an amount of 0.1% to 50% by weight relative to the total content of the semiconductor photoresist composition.

[0074] When the aforementioned resin is included within the above-mentioned content range, it can have excellent etching resistance and heat resistance.

[0075] On the other hand, a semiconductor photoresist composition according to one embodiment is preferably composed of the organometallic compound, solvent, and resin described above. However, the semiconductor photoresist composition according to the above embodiment may optionally further contain additives. Examples of such additives include surfactants, crosslinking agents, leveling agents, organic acids, quenchers, or combinations thereof.

[0076] The surfactant may be, but is not limited to, alkylbenzene sulfonates, alkylpyridinium salts, polyethylene glycol, quaternary ammonium salts, or combinations thereof.

[0077] Examples of crosslinking agents include, but are not limited to, melamine-based crosslinking agents, substituted urea-based crosslinking agents, acrylic-based crosslinking agents, epoxy-based crosslinking agents, or polymer-based crosslinking agents. Examples of crosslinking agents having at least two crosslinking substituents include compounds such as methoxymethylated glycolyl, butoxymethylated glycolyl, methoxymethylated melamine, butoxymethylated melamine, methoxymethylated benzoguanamine, butoxymethylated benzoguanamine, 4-hydroxybutyl acrylate, acrylic acid, urethane acrylate, acrylic methacrylate, 1,4-butanediol diglycidyl ether, glycidol, diglycidyl 1,2-cyclohexane dicarboxylate, trimethylpropane triglycidyl ether, 1,3-bis(glycidoxypropyl)tetramethyldisiloxane, methoxymethylated urea, butoxymethylated urea, or methoxymethylated thiourea.

[0078] Leveling agents are used to improve coating flatness during printing, and commercially available, known leveling agents can be used.

[0079] The organic acid may be, but is not limited to, p-toluenesulfonic acid, benzenesulfonic acid, p-dodecylbenzenesulfonic acid, 1,4-naphthalenedisulfonic acid, methanesulfonic acid, sulfonium fluoride salts, malonic acid, citric acid, propionic acid, methacrylic acid, oxalic acid, lactic acid, glycolic acid, succinic acid, or a combination thereof.

[0080] The quencher may be diphenyl(p-tolyl)amine, methyldiphenylamine, triphenylamine, phenylenediamine, naphthylamine, diaminonaphthalene, or a combination thereof.

[0081] The amount of these additives used can be easily adjusted according to the desired physical properties, and they can also be omitted.

[0082] Furthermore, the semiconductor photoresist composition may be further enhanced with a silane coupling agent as an adhesion enhancer to improve adhesion to the substrate (for example, to improve the adhesion strength of the semiconductor photoresist composition to the substrate). The silane coupling agent may be, but is not limited to, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltrichlorosilane, vinyltris(β-methoxyethoxy)silane; or 3-methacryloxypropyltrimethoxysilane, 3-acryloxypropyltrimethoxysilane, p-styryltrimethoxysilane, 3-methacryloxypropylmethyldimethoxysilane, 3-methacryloxypropylmethyldiethoxysilane; or carbon-carbon unsaturated bond-containing silane compounds such as trimethoxy[3-(phenylamino)propyl]silane.

[0083] The semiconductor photoresist composition may not experience pattern collapse even when forming patterns with a high aspect ratio. Therefore, it can be used in photoresist processes using light with wavelengths of 5 nm to 150 nm, such as a photoresist process using light with wavelengths of 5 nm to 100 nm, such as a photoresist process using light with wavelengths of 5 nm to 100 nm, such as a photoresist process using light with wavelengths of 5 nm to 80 nm, such as a photoresist process using light with wavelengths of 5 nm to 50 nm, such as a photoresist process using light with wavelengths of 5 nm to 30 nm, such as a photoresist process using light with wavelengths of 5 nm to 20 nm, for example, to form fine patterns with widths of 5 nm to 100 nm, such as a photoresist process using light with wavelengths of 5 nm to 830 nm, and such as a photoresist process using light with wavelengths of 5 nm to 20 nm. Therefore, by using a semiconductor photoresist composition according to one embodiment, extreme ultraviolet lithography using an EUV light source with a wavelength of approximately 13.5 nm can be realized.

[0084] On the other hand, according to another embodiment, a method for forming a pattern using the semiconductor photoresist composition can be provided. For example, the manufactured pattern may be a photoresist pattern.

[0085] A pattern formation method according to one embodiment includes the steps of forming an etching target film on a substrate, applying the semiconductor photoresist composition on the etching target film to form a photoresist film, exposing and developing the photoresist film to form a photoresist film on which a photoresist pattern is formed, and etching the etching target film using the photoresist pattern as an etching mask.

[0086] The following describes a method for forming a pattern using the semiconductor photoresist composition described above, with reference to Figure 1. Figure 1 is a cross-sectional view illustrating a pattern formation method using the semiconductor photoresist composition according to the present invention.

[0087] Referring to Figure 1(a), first, the object to be etched is prepared. An example of the object to be etched may be a thin film 102 formed on a semiconductor substrate 100. The following explanation will only cover the case where the object to be etched is a thin film 102. The surface of the thin film 102 is cleaned to remove any contaminants remaining on the thin film 102. The thin film 102 may be, for example, a silicon nitride film, a polysilicon film, or a silicon oxide film.

[0088] Next, a resist underlayer forming composition for forming a resist underlayer 104 is coated onto the surface of the cleaned thin film 102 using a spin coating method. However, one embodiment is not necessarily limited thereto, and various known coating methods, such as spray coating, dip coating, knife-edge coating, and printing methods, such as inkjet printing and screen printing, can also be used.

[0089] The above-mentioned resist underlayer coating step can be omitted, and the following description will focus on the case where the resist underlayer is coated.

[0090] Subsequently, a drying and baking process is performed to form a resist underlayer film 104 on the thin film 102. The baking process is carried out at approximately 100 to 500°C, for example, at approximately 100°C to 300°C.

[0091] The resist underlayer 104 is formed between the substrate 100 and the photoresist film 106. This prevents the scattering of irradiation lines reflected from the interface between the substrate 100 and the photoresist film 106 or from the interlayer hard mask into unintended photoresist regions, thereby preventing non-uniformity of the photoresist linewidth and interference with pattern formation.

[0092] Referring to Figure 1(b), the semiconductor photoresist composition is coated onto the resist underlayer film 104 to form a photoresist film 106. The photoresist film 106 may also be formed by coating the semiconductor photoresist composition onto a thin film 102 formed on the substrate 100 and then curing it by a heat treatment process.

[0093] More specifically, the step of forming a pattern using a semiconductor photoresist composition may include the steps of applying the semiconductor photoresist composition onto a substrate 100 on which a thin film 102 is formed by spin coating, slit coating, inkjet printing, etc., and drying the applied semiconductor photoresist composition to form a photoresist film 106.

[0094] Since the compositions for semiconductor photoresists have already been explained in detail, we will omit any redundant explanations.

[0095] Next, a first baking step is performed in which the substrate 100 on which the photoresist film 106 is formed is heated. The first baking step can be performed at a temperature of approximately 80°C to approximately 120°C.

[0096] Referring to Figure 1(c), the photoresist film 106 is selectively exposed using a patterned mask 110.

[0097] As an example, examples of light that can be used in the exposure process include not only short-wavelength light such as the activation irradiation diagram i-line (wavelength 365 nm), KrF excimer laser (wavelength 248 nm), and ArF excimer laser (wavelength 193 nm), but also high-energy wavelength light such as EUV (Extreme UltraViolet; wavelength 13.5 nm) and E-Beam (electron beam).

[0098] More specifically, the exposure light in one embodiment may be short-wavelength light having a wavelength range of 5 nm to 150 nm, or it may be light having a high-energy wavelength such as EUV (Extreme UltraViolet; wavelength 13.5 nm) or E-Beam (electron beam).

[0099] The exposed region 106b in the photoresist film 106 forms a polymer through crosslinking reactions such as condensation between organometallic compounds, resulting in a solubility different from that of the unexposed region 106a of the photoresist film 106.

[0100] Next, a second baking step is performed on the substrate 100. The second baking step can be performed at a temperature of approximately 90°C to approximately 200°C. By performing the second baking step, the exposed region 106b of the photoresist film 106 becomes less soluble in the developer.

[0101] Figure 1(d) shows a photoresist pattern 108 formed by dissolving and removing the photoresist film 106a corresponding to the unexposed region using a developer. Specifically, the photoresist pattern 108 corresponding to the negative tone image is completed by dissolving and then removing the photoresist film 106a corresponding to the unexposed region using an organic solvent such as 2-heptanone.

[0102] As described above, the developer used in the pattern formation method according to one embodiment may be an organic solvent. Examples of organic solvents used in the pattern formation method according to one embodiment include ketones such as methyl ethyl ketone, acetone, cyclohexanone, and 2-heptanone; alcohols such as 4-methyl-2-propanol, 1-butanol, isopropanol, 1-propanol, and methanol; esters such as propylene glycol monomethyl ether acetate, ethyl acetate, ethyl lactate, n-butyl acetate, and butyrolactone; aromatic compounds such as benzene, xylene, and toluene; or combinations thereof.

[0103] However, the photoresist pattern according to one embodiment is not necessarily limited to being formed as a negative tone image, but can also be formed to have a positive tone image. In this case, examples of developers that can be used to form a positive tone image include quaternary ammonium hydroxide compositions such as tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide, or combinations thereof.

[0104] As described above, the photoresist pattern 108 formed by exposure with light having wavelengths such as i-line (wavelength 365nm), KrF excimer laser (wavelength 248nm), and ArF excimer laser (wavelength 193nm), as well as high-energy light such as EUV (Extreme UltraViolet; wavelength 13.5nm) and E-Beam (electron beam), can have a width of 5nm to 100nm in thickness. For example, the photoresist pattern 108 can be formed with widths of 5nm to 90nm, 5nm to 80nm, 5nm to 70nm, 5nm to 60nm, 5nm to 50nm, 5nm to 40nm, 5nm to 30nm, 5nm to 20nm, and 5nm to 10nm.

[0105] On the other hand, the photoresist pattern 108 can have a half-pitch of approximately 50 nm or less, for example 40 nm or less, for example 30 nm or less, for example 20 nm or less, for example 10 nm or less, and a pitch having a line width roughness of approximately 5 nm or less, approximately 3 nm or less, approximately 2 nm or less, or approximately 1 nm or less.

[0106] Furthermore, according to another embodiment, a photoresist film manufactured by the pattern forming method described above can be provided.

[0107] Next, the photoresist pattern 108 formed on the photoresist film is used as an etching mask to etch the resist underlayer film 104. This etching process forms an organic film pattern 112. The formed organic film pattern 112 can also have a width corresponding to the photoresist pattern 108.

[0108] Referring to Figure 1(e), the photoresist pattern 108 is applied as an etching mask to etch the exposed thin film 102. As a result, the thin film is formed as a thin film pattern 114.

[0109] The thin film 102 can be etched, for example, by dry etching using an etching gas, and the etching gas can be, for example, CHF3, CF4, Cl2, BCl3, or a mixture thereof.

[0110] The thin film pattern 114 formed using the photoresist pattern 108 formed by the exposure process using an EUV light source in the preceding exposure process can have a width corresponding to the photoresist pattern 108. For example, it can have a width of 5 nm to 100 nm, similar to the photoresist pattern 108. For instance, the thin film pattern 114 formed by the exposure process using an EUV light source can have widths of 5 nm to 90 nm, 5 nm to 80 nm, 5 nm to 70 nm, 5 nm to 60 nm, 5 nm to 50 nm, 5 nm to 40 nm, 5 nm to 30 nm, and 5 nm to 20 nm, similar to the photoresist pattern 108, and more specifically, it can be formed with a width of 20 nm or less.

[0111] The present invention will be described in more detail below through the examples of the manufacturing of the semiconductor photoresist composition described above. However, the technical features of the present invention are not limited by the following examples.

[0112] (Synthesis of organometallic compounds) Synthesis Example 1 [ka] [Chemical formula 2]

[0113] 1 g of magnesium (Mg) (turnings) was placed in a 250 ml round-bottom flask, and then 100 ml of tetrahydrofuran (THF) was added. The flask was thoroughly purged with nitrogen, cooled to -20°C, and then 4.6 g (340 mmol) of 1-bromo-4-nitrobenzene was gradually added dropwise. After the addition was complete, the mixture was raised to room temperature and stirred for at least 6 hours to prepare the Grindard reagent. In another 250 ml flask, 10 g (340 mmol) of tetrakis(dimethylamino)tin(IV) was weighed, and then 100 ml of THF was added and cooled to -20°C. The Grindard reagent prepared above was gradually added dropwise using a cannular. After adding the solvent, the mixture was heated to room temperature and stirred for more than 6 hours. Then, it was cooled again to -20°C, and methyl isobutyl carbinol (3.0 eq to 3.5 eq) was added and the mixture was stirred at room temperature for one day. The solvent and impurities were removed under reduced pressure to obtain the compound represented by chemical formula 2 in 50-70% yield.

[0114] Synthesis Example 2 [ka] [Chemical formula 3]

[0115] 1 g of Mg (turnings) was placed in a 250 ml round-bottom flask, and then 100 ml of THF was added. The flask was thoroughly purged with nitrogen, cooled to -20°C, and then 4.6 g of 2-Bromo-1-nitropropane (340 mmol) was gradually added dropwise. After the addition was complete, the mixture was raised to room temperature and stirred for at least 6 hours to prepare the Grindard reagent. In another 250 ml flask, 10 g of tetrakis(dimethylamino)tin(IV) (TDMASn Tetrakis(dimethylamino)tin(IV)) (340 mmol) was weighed, and then 100 ml of THF was added, followed by cooling to -20°C. The Grindard reagent prepared above was gradually added dropwise using a cannular filter. After adding the compounds, the mixture was heated to room temperature and stirred for at least 6 hours. Then, it was cooled again to -20°C, and methyl isobutyl carbinol (3.0 eq to 3.5 eq) was added and the mixture was stirred at room temperature for one day. The solvent and impurities were removed under reduced pressure to obtain the compound represented by chemical formula 3 in 50-70% yield.

[0116] Synthesis Example 3 [ka] [Chemical formula 4]

[0117] 1 g of Mg(turnings) was placed in a 250 ml round-bottom flask, and then 100 ml of THF was added. The flask was thoroughly purged with nitrogen, cooled to -20°C, and then 1-bromo-4-nitrobenzene (4.6 g, 340 mmol) was gradually added dropwise. After the addition was complete, the mixture was raised to room temperature and stirred for at least 6 hours to prepare the Grindard reagent. Tetrakis(dimethylamino)tin(IV) (10 g, 340 mmol) was weighed into another 250 ml flask, and then 100 ml of THF was added, followed by cooling to -20°C. The Grindard reagent prepared above was gradually added dropwise using a cannular siphon. After the addition was complete, the mixture was raised to room temperature and stirred for at least 6 hours, then cooled again to -20°C, and then propionic acid (3.0 eq~3.5 eq) was added and the mixture was stirred at room temperature for one day. The solvent and impurities were removed by reducing the pressure to obtain the compound represented by chemical formula 4 in a yield of 50-70%.

[0118] Synthesis Example 4 [ka] [Chemical formula 5]

[0119] 1 g of Mg(turnings) was placed in a 250 ml round-bottom flask, and then 100 ml of THF was added. The flask was thoroughly purged with nitrogen, cooled to -20°C, and then 4.6 g of 2-Bromo-1-nitropropane (340 mmol) was gradually added dropwise. After the addition was complete, the mixture was raised to room temperature and stirred for at least 6 hours to prepare the Grindard reagent. Tetrakis(dimethylamino)tin(IV) (10 g of 340 mmol) was weighed into another 250 ml flask, and then 100 ml of THF was added, followed by cooling to -20°C. The Grindard reagent prepared above was gradually decanted using a cannular cannula. After the addition was complete, the mixture was raised to room temperature and stirred for at least 6 hours, then cooled again to -20°C, and then propionic acid (3.0 eq to 3.5 eq) was added and the mixture was stirred at room temperature for one day. The solvent and impurities were removed by reducing the pressure to obtain the compound represented by chemical formula 5 in a yield of 50-70%.

[0120] Comparative Synthesis Example 1 [ka] [Chemical formula 6]

[0121] 8.2 g (69.2 mmol) of tin powder (Sn powder) and 120 ml of dry toluene were placed in a 250 ml three-necked flask, and the temperature was raised to 90°C. Approximately 1.0 ml of deionized water (DI water) was added, and then 10.0 g (69.2 mmol) of 4-fluorobenzyl chloride was added dropwise for 10 minutes. After heating under reflux and stirring at 130°C for 4 hours, the unreacted Sn powder was filtered using a Buchner funnel. Simultaneously, as the filtered solution cooled, 6.5 g (36% yield) of the product, white crystals (SM1 precursor), was obtained. 1.5 g (3.7 mmol) of SM1 precursor and 21.0 ml of dry acetone were placed in a 50 ml one-necked flask, and the temperature was lowered to 0°C. After adding 0.6 g (7.4 mmol) of sodium acetate, the mixture was stirred for approximately 12 hours. The sodium chloride (NaCl salt) generated in the solution was filtered using a 0.45 μm filter, and the resulting solution was concentrated by rotary evaporation and vacuum drying to obtain the compound represented by chemical formula 6 in 74% yield (1.6 g).

[0122] Comparative Synthesis Example 2 [ka] [Chemical formula 7]

[0123] 8.2 g (69.2 mmol) of Sn powder and 120 ml of dry toluene were placed in a 250 ml three-necked flask, and the temperature was raised to 90°C. Approximately 1.0 ml of DI water was added, and then 5.0 g (19.9 mmol) of 4-iodobenzyl chloride was added dropwise for 10 minutes. After heating under reflux and stirring at 130°C for 4 hours, the unreacted Sn powder was filtered using a Buchner funnel. Simultaneously, 1.7 g (36% yield) of the product, white crystals (SM2 precursor), was obtained while the filtered solution was cooling. 1.7 g (2.7 mmol) of SM2 precursor and 42.9 ml of dry acetone were placed in a 100 ml one-necked flask, and the temperature was lowered to 0°C. 0.6 g (7.4 mmol) of sodium acetate was added, and the mixture was stirred for approximately 12 hours. The NaCl salt generated in the solution was filtered using a 0.45 μm filter, and the resulting solution was concentrated by rotary evaporation and vacuum drying to obtain the compound represented by chemical formula 7 in 84% yield (1.8 g).

[0124] Comparative Synthesis Example 3 [ka] [Chemical formula 8]

[0125] 8.2 g (69.2 mmol) of Sn powder and 120 ml of dry toluene were placed in a 250 ml three-necked flask, and the temperature was raised to 90°C. Approximately 1.0 ml of DI water was added, and then 10.7 g (50.7 mmol) of 4-(trifluoromethoxybenzyl) chloride was added dropwise for 10 minutes. After heating under reflux and stirring at 130°C for 4 hours, the unreacted Sn powder was filtered using a Buchner funnel. The filtered solution was crystallized at -20°C for 3 to 6 days, then concentrated by rotary evaporation and vacuum drying to obtain 3.7 g (35% yield) of the product, white crystals (SM3 precursor). 2.0 g (3.7 mmol) of SM3 precursor and 26.1 ml of dry acetone were placed in a 50 ml one-necked flask, and the temperature was lowered to 0°C. After adding 0.6 g (7.4 mmol) of sodium acetate, the mixture was stirred for approximately 12 hours. The NaCl salt generated in the solution was filtered using a 0.45 μm filter, and the resulting solution was concentrated by rotary evaporation and vacuum drying to obtain the compound represented by chemical formula 8 in 74% yield (1.9 g).

[0126] Comparative Synthesis Example 4 [ka] [Chemical formula 9]

[0127] 8.2 g (69.2 mmol) of Sn powder and 120 ml of dry toluene were placed in a 250 ml three-necked flask, and the temperature was raised to 90°C. Approximately 1.0 ml of DI water was added, and then 10.7 g (50.7 mmol) of 4-(trifluoromethyl)benzyl chloride was added dropwise for 10 minutes. After heating under reflux and stirring at 130°C for 4 hours, the unreacted Sn powder was filtered using a Buchner funnel. The filtered solution was crystallized at -20°C for 3 to 6 days, then concentrated by rotary evaporation and vacuum drying to obtain 3.7 g (35% yield) of the white crystal product (SM4 precursor). 2.0 g (3.7 mmol) of SM4 precursor and 26.1 ml of dry acetone were placed in a 50 ml one-necked flask, and the temperature was lowered to 0°C. 0.6 g (7.4 mmol) of sodium acetate was added, and the mixture was stirred for approximately 12 hours. The NaCl salt generated in the solution was filtered using a 0.45 μm filter, and the resulting solution was concentrated by rotary evaporation and vacuum drying to obtain the compound represented by chemical formula 9 in 82% yield (1.7 g).

[0128] (Manufacturing of semiconductor photoresist compositions) Examples 1-4 and Comparative Examples 1-4 The organometallic compounds obtained in Synthesis Examples 1-4 and Comparative Synthesis Examples 1-4 were each dissolved in 3 wt% PGMEA (propylene glycol monomethyl ether acetate) and filtered through a 0.1 μm polytetrafluoroethylene syringe filter (PTFE syringe filter) to produce photoresist compositions.

[0129] Evaluation 1: Sensitivity and Line Edge Roughness (LER) Evaluation The photoresist compositions according to the above examples and comparative examples were spin-coated onto a 200 mm circular silicon wafer whose surface was deposited with HMDS at 1500 rpm for 30 seconds, baked at 110°C for 60 seconds (post-apply bake, PAB), and then left at room temperature (23±2°C) for 30 seconds.

[0130] Subsequently, a linear array of 50 circular pads with a diameter of 500 μm was projected onto a wafer coated with the photoresist composition using EUV light (Lawrence Berkeley National Laboratory Micro Exposure Tool, MET). The pad exposure time was adjusted to ensure that the increasing EUV dose was applied to each pad.

[0131] Subsequently, the resist and substrate were exposed on a hot plate at 160°C for 120 seconds and then fired. The fired film was developed with PGMEA solvent to form a negative tone image. Finally, the process was completed by hot plate firing at 150°C for 2 minutes.

[0132] The residual resist thickness of the exposed pads was measured using a polarization analysis method (Ellipsometer). The remaining thickness was measured for each exposure level, and the results were graphed as a function of the exposure level to determine the sensitivity. The LER was then measured from the FE-SEM images, and the results are shown in Table 1.

[0133] Evaluation 2: Delay characteristic evaluation The photoresist compositions according to the above examples and comparative examples were spin-coated onto a 200 mm circular silicon wafer whose surface was deposited with HMDS at 1500 rpm for 30 seconds, then baked at 100°C to 120°C for 60 seconds (post-apply bake, PAB), and then left at room temperature for 10 minutes (process delay time).

[0134] Subsequently, a linear array of 50 circular pads with a diameter of 500 μm was projected onto a wafer coated with the photoresist composition using EUV light (Lawrence Berkeley National Laboratory Micro Exposure Tool, MET). The pad exposure time was adjusted to ensure that the increasing EUV dose was applied to each pad.

[0135] Subsequently, the resist and substrate were exposed to a hot plate at 180°C for 120 seconds and then fired. The fired film was developed with PGMEA solvent to form a negative tone image, and finally, the process was completed by hot plate firing at 150°C for 2 minutes.

[0136] The resist linewidths formed by exposure with the same dose (energy) were measured using a CD-SEM (Critical Dimension Scanning Electron Microscope). The linewidth (CD) values ​​of the formed resist patterns were confirmed according to the process delay time (10 minutes, 20 minutes, 30 minutes, 40 minutes, 50 minutes, 60 minutes), and the delay characteristics were calculated using Equation 1 below. The results are shown in Table 1.

[0137] [Formula 1] Delay characteristic = {Maximum CD value among the CD values ​​of patterns formed at 10-minute intervals for 60 minutes after PAB / CD value of the pattern formed without waiting} * 100 [Evaluation Criteria] -◎:△CD more than 2% and less than 7% -○:△CD more than 7% and less than 15% -X:△CD over 15%

[0138] Evaluation 3: Storage stability evaluation The storage stability of the organometallic compounds used in Examples 1-4 and Comparative Examples 1-4 was evaluated according to the following criteria, and the results are shown in Table 1 below.

[0139] [Storage stability] The semiconductor photoresist compositions prepared in Examples 1-4 and Comparative Examples 1-4 were left standing for a specified period under room temperature conditions. The degree of precipitation was observed visually and evaluated according to the following storage standards. *Evaluation criteria -○: Can be stored for 3 months or more. -△: Can be stored for more than 1 week but less than 3 months. -X: Can be stored for less than one week.

[0140] [Table 1]

[0141] The results in Table 1 confirm that the patterns formed using the semiconductor photoresist compositions of Examples 1 to 4 exhibit superior sensitivity and storage stability, as well as significantly improved coating performance, while maintaining a comparable level of LER compared to Comparative Examples 1 to 4.

[0142] Although specific embodiments of the present invention have been described and illustrated above, it is obvious to those ordinary skill in the art that the present invention is not limited to the described embodiments and can be modified and transformed in various ways without departing from the spirit and scope of the invention. Therefore, such modifications or variations should not be understood individually from the technical spirit or viewpoint of the invention, and the modified embodiments can be said to fall within the scope of the claims of the present invention. [Explanation of Symbols]

[0143] 100 circuit boards 102 Thin film 104 Resist underlayer 106 Photoresist film 106a Unexposed area 106b Exposed region 108 Photoresist Patterns 112 Organic film patterns 110 patterned masks 114 Thin Film Patterns

Claims

1. Organometallic compounds represented by the following chemical formula 1; and Compositions for semiconductor photoresists containing a solvent: 【Chemistry 1】 [Chemical formula 1] In the aforementioned chemical formula 1, L １ This is one or more selected from the group consisting of a single bond, a substituted or unsubstituted alkylene group having 1 to 10 carbon atoms, a substituted or unsubstituted alkenylene group having 2 to 10 carbon atoms, a substituted or unsubstituted alkynylene group having 2 to 10 carbon atoms, a substituted or unsubstituted cycloalkylene group having 3 to 20 carbon atoms, a substituted or unsubstituted cycloalkenylene group having 3 to 20 carbon atoms, and a substituted or unsubstituted aromatic ring having 6 to 20 carbon atoms. R １ and R ２ Each of these is independently selected from hydrogen, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C6-C20 aryl group, and a substituted or unsubstituted C7-C20 arylalkyl group. n is 1 or greater, L １ An integer less than or equal to (bond valence - 1), Y １ to Y ３ are each independently an alkoxy group and an aryloxy group (—OR ａ , where R ａ is a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), a carboxyl group (—O(CO)R ｂ , R ｂ is hydrogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), an alkylamide group and a dialkylamide group (—NR ｃ R ｄ , where R ｃ and R ｄ are each independently hydrogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), an amidato group (—NR ｅ (COR ｆ ), where R ｅ and R ｆ are each independently hydrogen, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted cycloalkyl group having 3 to 20 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 20 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 20 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms, or a combination thereof), an amidinato group (—NR ｇ C(NR ｈ )R ｉ , where R ｇ , R ｈ and R ｉ Each of these is independently hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), alkylthio group and arylthio group (-SR ｊ Here, R ｊ (which is a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), and a thiocarboxyl group (-S(CO)R ｋ , R ｋ (The carbon atom is selected from hydrogen, a substituted or unsubstituted C1-C20 alkyl group, a substituted or unsubstituted C3-C20 cycloalkyl group, a substituted or unsubstituted C2-C20 alkenyl group, a substituted or unsubstituted C2-C20 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof.)

2. Said L １ The semiconductor photoresist composition according to claim 1, wherein is one or more selected from the group consisting of a substituted or unsubstituted C2-C10 alkenylene group, a substituted or unsubstituted C2-C10 alkynylene group, a substituted or unsubstituted C3-C20 cycloalkene, and a substituted or unsubstituted C6-C20 aromatic ring.

3. Said L １ The semiconductor photoresist composition according to claim 2, comprising at least one conjugation system in which two or more multiple bonds are linked via single bonds.

4. Said L １ The semiconductor photoresist composition according to claim 2, comprising at least one conjugated diene.

5. The aforementioned Y １ ~Y ３ These are independently an alkoxy group and an aryloxy group (-OR ａ Here, R ａ (These are substituted or unsubstituted C1-C10 alkyl groups, substituted or unsubstituted C3-C10 cycloalkyl groups, substituted or unsubstituted C2-C10 alkenyl groups, substituted or unsubstituted C2-C10 alkynyl groups, substituted or unsubstituted C6-C20 aryl groups, or combinations thereof), carboxyl groups (-O(CO)R ｂ , R ｂ (These are hydrogen, substituted or unsubstituted C1-C10 alkyl groups, substituted or unsubstituted C3-C10 cycloalkyl groups, substituted or unsubstituted C2-C10 alkenyl groups, substituted or unsubstituted C2-C10 alkynyl groups, substituted or unsubstituted C6-C20 aryl groups, or combinations thereof), alkylamide groups and dialkylamide groups (-NR ｃ R ｄ Here, R ｃ and R ｄ Each of these is independently a hydrogen atom, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C30 aryl group, or a combination thereof), an amidato group (-NR ｅ (COR ｆ ), here R ｅ and R ｆ Each of these is independently a hydrogen atom, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof), an amidinate group (amidinato) (-NR ｇ C (NR ｈ ) R ｉ Here, R ｇ , R ｈ and R ｉ Each of these is independently hydrogen, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof), alkylthio group and arylthio group (-SR ｊ Here, R ｊ (wherein this is a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof), and a thiocarboxyl group (-S(CO)R ｋ , R ｋ The semiconductor photoresist composition according to claim 1, wherein is selected from hydrogen, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof.

6. The aforementioned Y １ ~Y ３ These are independently an alkoxy group and an aryloxy group (-OR ａ Here, R ａ (These are substituted or unsubstituted C1-C10 alkyl groups, substituted or unsubstituted C3-C10 cycloalkyl groups, substituted or unsubstituted C2-C10 alkenyl groups, substituted or unsubstituted C2-C10 alkynyl groups, substituted or unsubstituted C6-C20 aryl groups, or combinations thereof), carboxyl groups (-O(CO)R ｂ , R ｂ (wherein is hydrogen, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof), and an amidato group (-NR ｅ (COR ｆ ), here R ｅ and R ｆ The semiconductor photoresist composition according to claim 5, wherein each of the following is independently selected from hydrogen, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C6-C20 aryl group, or a combination thereof.

7. The aforementioned R ａ These are substituted or unsubstituted methyl groups, substituted or unsubstituted ethyl groups, substituted or unsubstituted propyl groups, substituted or unsubstituted butyl groups, substituted or unsubstituted isopropyl groups, substituted or unsubstituted tert-butyl groups, substituted or unsubstituted tert-pentyl groups, substituted or unsubstituted 2,2-dimethylpropyl groups, substituted or unsubstituted cyclopropyl groups, substituted or unsubstituted cyclobutyl groups, substituted or unsubstituted cyclopentyl groups, substituted or unsubstituted cyclohexyl groups, substituted or unsubstituted ethenyl groups, substituted or unsubstituted propenyl groups, substituted or unsubstituted butenyl groups, substituted or unsubstituted ethynyl groups, substituted or unsubstituted propynyl groups, substituted or unsubstituted butynyl groups, substituted or unsubstituted phenyl groups, substituted or unsubstituted tolyl groups, substituted or unsubstituted xylene groups, substituted or unsubstituted benzyl groups, or combinations thereof. R ｂ , R ｃ , R ｄ , R ｅ , R ｆ , R ｇ , R ｈ , R ｉ , R ｊ and R ｋ The semiconductor photoresist composition according to claim 1, wherein each of them independently is hydrogen, a substituted or unsubstituted methyl group, a substituted or unsubstituted ethyl group, a substituted or unsubstituted propyl group, a substituted or unsubstituted butyl group, a substituted or unsubstituted isopropyl group, a substituted or unsubstituted tert-butyl group, a substituted or unsubstituted tert-pentyl group, a substituted or unsubstituted 2,2-dimethylpropyl group, a substituted or unsubstituted cyclopropyl group, a substituted or unsubstituted cyclobutyl group, a substituted or unsubstituted cyclopentyl group, a substituted or unsubstituted cyclohexyl group, a substituted or unsubstituted ethenyl group, a substituted or unsubstituted propenyl group, a substituted or unsubstituted butenyl group, a substituted or unsubstituted ethynyl group, a substituted or unsubstituted propynyl group, a substituted or unsubstituted butynyl group, a substituted or unsubstituted phenyl group, a substituted or unsubstituted tolyl group, a substituted or unsubstituted xylene group, a substituted or unsubstituted benzyl group, or a combination thereof.

8. The organometallic compound represented by chemical formula 1 is one selected from the compounds listed in Group 1 below, according to claim 1, for use in semiconductor photoresists: [Group 1] 【Chemistry 2】 【Transformation 3】 【Chemistry 4】 。

9. The semiconductor photoresist composition according to claim 1, wherein the organometallic compound represented by chemical formula 1 is contained in an amount of 0.5% to 30% by weight based on 100% by weight of the semiconductor photoresist composition.

10. The semiconductor photoresist composition according to claim 1, further comprising a surfactant, a crosslinking agent, a leveling agent, an organic acid, an inhibitor (quencher), or other additives in combination thereof.

11. The steps include forming an etching target film on a substrate, The steps of forming a photoresist film by applying the semiconductor photoresist composition according to any one of claims 1 to 10 onto the film to be etched, The steps include: exposing and developing the photoresist film to form a photoresist film on which a photoresist pattern is formed; A pattern formation method comprising the step of etching a film to be etched using the aforementioned photoresist pattern as an etching mask.

12. The pattern forming method according to claim 11, wherein the step of forming the photoresist pattern uses light with a wavelength of 5 nm to 150 nm.

13. The pattern formation method according to claim 1, wherein the photoresist pattern has a width of 5 nm to 100 nm.

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