Transparent cover plate processing method and cover plate

Abstract

The present invention relates to a method for processing a transparent cover plate (10) for a flat body (1), the method comprising: a) providing a transparent cover plate (10) having an outer side (27) facing an external environment and an opposite inner side (28), the cover plate (10) comprising a structured area (15) having a light-diffusing structure on at least one cover plate surface (11, 13) selected from the outer surface (11) and the inner surface (13) of the cover plate (10), or alternatively a structured area (15) formed thereon; b) forming at least one optical interference layer (16) on a portion of the cover plate side (27, 28) selected from the outer side (27) and the inner side (28), b1) applying a mask (24) to the cover plate (10), in a vertical view through the cover plate (10), the mask (24) not covering a first region (22) of the cover plate surface (11, 13) on the cover plate side (27, 28) and covering a second region (23) of the cover plate surface (11, 13) on the cover plate side (27, 28), the first region (22) and the second region (23) being arranged to overlap the structured region (15) that may be further formed; b2) applying at least one optical interference layer (16) configured to reflect light within a predetermined wavelength range to the cover plate (10) on the selected cover plate side (27, 28), the optical interference layer (16) being applied so as to overlap the mask (24) and to overlap a first region (22) of the cover plate surface (11, 13) in a vertical view through the cover plate (10); b3) removing the mask (24), thereby also removing the optical interference layer (16) that overlaps the mask (24) in a vertical view; and Includes.

Description

[Technical field]

[0001] The present invention belongs to the technical field of manufacturing light absorbing and passive flat bodies, such as solar modules and solar collectors, intended to be used as an integral component of a building enclosure or independent wall and fulfilling an architectural function only. [Background technology]

[0002] Solar modules, which generate photovoltaic energy from sunlight, and solar collectors, which convert sunlight into thermal energy, are familiar in everyday life. Hereinafter, solar modules and solar collectors are collectively referred to as "light absorbing flat bodies". Light absorbing flat bodies are used to generate energy from sunlight or convert sunlight into thermal energy. They are also called "active" flat bodies, and are significantly different from "passive" flat bodies, which are not suitable or intended for this purpose.

[0003] Solar modules contain photoactive semiconductor layers for converting sunlight directly into electrical current. The term "thin-film solar module" refers to a layer system with a thickness of only a few microns, which requires a carrier substrate with sufficient mechanical strength. The known carrier substrates are usually made of glass or plastic and can be constructed as rigid plates or flexible films, depending on the thickness and the specific material properties of the respective layers. As is well known, thin-film solar modules are made in the form of a composite pane, in which a photoactive semiconductor layer is arranged between two separate panes, usually made of glass, which are rigidly connected to each other via a thermoplastic intermediate layer. Sunlight can be irradiated to the photoactive semiconductor layer through a cover pane, such as a cover glass.

[0004] A solar collector generally comprises a housing with an absorber and a heat transfer medium (fluid) circulating in a piping system. The housing is closed by a cover plate at the light inlet side. The absorber is heated by sunlight passing through the cover plate (e.g. cover glass) and transfers its energy to the heat transfer medium, which is thermally coupled to a buffer storage tank located at a certain distance from the solar collector, thereby making the thermal energy available.

[0005] There has been a strong increase in light absorbing flat bodies in open space systems, especially solar modules. However, applications in architecturally integrated environments remain at a much smaller scale to date. In view of the increasing focus on distributed energy solutions, applications are required, especially as integral components of the building shell, such as cladding, windows and roof elements. Further areas of application include noise barriers (road, rail), external privacy fences and freestanding walls such as greenhouse walls.

[0006] These new applications pose completely new demands on the light-absorbing flats, especially on their aesthetics, durability and other functions such as sealing and insulation. Different shapes, sizes and colors are available and the color impression should be as uniform as possible. However, there are technical problems that collide with the actual functionality of the light-absorbing flats. An ideal light-absorbing flat would be a black body that completely absorbs the incident sunlight in order to optimally utilize the incident radiant energy. However, real objects reflect the incident radiation and attenuate the absorbed radiation. The color impression on the human eye is essentially the result of spectrally selective reflection and visible light attenuation. If the light-absorbing flat is colored, i.e. if a color impression is formed on the human eye that is different from that of an ideal black body, the intensity of the light absorbed by the optically active semiconductor is reduced and therefore the power and efficiency of the solar module is reduced. In solar collectors, the heat absorbed by the absorber is reduced and the efficiency of the solar collector is also reduced.

[0007] A common feature between solar modules and solar collectors is that color effects can be realized by means of the cover plate on the light inlet side. Various methods are known for this.

[0008] According to the international patent application WO2014 / 045141, the use of optical filters is known, which consist of a multi-layer of at least 3 to 9 interference layers inside the deck glass. The optical filter layers reflect a certain spectral range of the sunlight to cause a color effect. The use of a diffusely scattering cover glass is also shown, in which the optical interference layer and the rough side of the cover glass are on different sides of the cover glass (interference layer on the inside, rough side on the outside), and the description of the optical and structural properties of the cover glass is omitted. The color impression is homogenized by surface structuring. However, the angular stability is realized by the complex adjustment of the special reflection spectrum by the layer structure of the multiple layers. Since the perceived color is highly dependent on the layer thickness and the refractive index, the individual interference layers must be deposited as uniformly as possible (i.e. have a uniform layer thickness). A loss of coloring efficiency due to the optical interference layers is acceptable. However, the continuous production of up to 9 multilayer films with precisely adjusted refractive index and layer thickness on an area of ​​1 square meter or more is technically very demanding and involves high costs.

[0009] The use of bioengineering methods to form butterfly-like nanostructures is also well known (see Fraunhofer, Blasi et al., 33rd European Photovoltaic Conference and Exhibition, 24-29 September 2017, Amsterdam, The Netherlands). These methods are very complex and costly and are therefore not yet suitable for industrial mass production of large-area solar modules and collectors.

[0010] It is also known to colour the cover plate by ceramic screen printing or by using organic glass colours. Both are relatively low-cost techniques and allow a wide range of colours to be produced. Furthermore, the colour impression is only slightly angle dependent. However, the colour layer itself is essentially opaque and absorbs light to a large extent, which inevitably results in very high efficiency losses. This is especially true for lighter shades, which usually result in unacceptable efficiency losses.

[0011] In this respect, only the use of optical interference coatings currently offers the possibility of achieving color effects in light-absorbing flat bodies with acceptable efficiency losses. However, so far only monochrome embodiments of cover glasses with optical interference layers are known, which correspond to the spectral range reflected by said optical interference layers. The color effects are usually due to a combination of the reflected color and the background color. Since the optical interference layer is located throughout the entire visible range of the flat body, the flat body has essentially the same color depending on the background color. However, monochrome embodiments of the flat body would greatly limit the creative freedom. Summary of the Invention [Problem to be solved by the invention]

[0012] In view of the above, the object of the present invention is to provide a multi-colored, in particular two-colored, flat body. In industrial series production, the flat body can be produced in a conventional manner and the production time should be relatively short. The multi-colored coloring of the flat body should only slightly affect the efficiency of the light-absorbing flat body. Furthermore, when used in architectural integrated environments, the color should be as independent as possible of the observation angle and the irradiation angle, since the color is strongly dependent on the position of the observer and the position of the sun. Equally important in industrial series production is that the flat body can be produced in large areas, at acceptable costs and with satisfactory uniformity. [Means for solving the problem]

[0013] For certain embodiments of exteriors, especially functional elements such as windows, doors, balconies, etc., it may be necessary to use colored flat bodies of different sizes and shapes. The problem with light-absorbing flat bodies is that, although in principle it is technically possible to manufacture flat bodies of different sizes and shapes, the relatively small and non-rectangular shapes incur considerable additional costs and are economically unfavourable. To solve this problem, it is conceivable to use exterior elements made of sheet metal or other conventional building materials. However, there are technical problems here that lie in the nature of the colour generation. Indeed, the colour of the light-absorbing flat body can be changed in different lighting conditions, depending on the origin of the colour (absorption / emission, interference, refraction), in particular depending on the type of light (diffuse, direct, colour of light), by changing the angle of incidence and / or the angle of observation. If the exterior elements are manufactured from a material different from the coloured light-absorbing flat bodies, this typically causes an undesirable white contrast. It is therefore desirable to have a passive exterior element that avoids these disadvantages and allows a simple multi-coloured colour construction.

[0014] According to the proposal of the present invention, these and other objects are solved by a method for processing a transparent cover plate for a flat body, a method for manufacturing a flat body, as well as a transparent cover plate and a flat body comprising a transparent cover plate according to the combined claims. Advantageous embodiments of the invention are indicated by the features of the subclaims.

[0015] For the purposes of the present invention, a "flat body" is a flat, preferably planar body with a transparent cover plate facing the external environment, which can be a light-absorbing flat body, such as a solar module or solar collector, or a passive flat body that fulfills only a structural function and is not suitable for generating and converting energy based on sunlight. In principle, any type of solar module can be realized as a solar module, in particular a silicon-based wafer-based solar module, or a thin-film solar module with solar cells connected in series in a monolithically integrated form.

[0016] The flat body allows sunlight to pass through the flat body. Overall, the flat body has one or typically several components on the rear side, i.e. opposite to the light entrance side. The opaque rear element is preferably, but not necessarily, firmly bonded to the transparent cover plate. The rear element can have one or more colors, usually determined by its components. The background color of the flat body is given by the color of the rear element.

[0017] In a solar module, the rear element includes the solar cells, other electrical components such as strip busbars, and, depending on the embodiment, a cover or base plate. Typically, the base plate with the solar cells is rigidly connected to the cover plate via a thermoplastic interlayer. The color of the rear element of the solar module is essentially determined by the color of the solar cells. In thin-film solar modules, the optically active cell area is usually black, anthracite gray, or with residual shades of dark blue and green. In silicon wafer modules, the optically active area is usually blue. In solar collectors, the rear element generally includes the housing, the absorber, and the heat transfer medium (fluid) in the tube. In solar collectors, the rear element is usually black. In passive flats, the rear element is usually opaque and black.

[0018] Colored solar modules in which a cover plate has at least one structured region and at least one optical interference layer are described in the unpublished European patent applications EP 18186153.5 and EP 18186161.8, the disclosures of which are fully referenced with regard to the embodiment, function and use of these solar modules.

[0019] Preferably, the colored passive cladding elements are used in combination with colored solar modules for cladding. Colored passive cladding elements are described in the unpublished European patent application EP 18186175.8. For the embodiment, function and use of the cladding elements, reference is made in full to the disclosure of said European patent application.

[0020] According to the present invention, a method for fabricating a transparent cover plate for a flat body is presented.

[0021] The method includes providing a transparent cover plate having an outer side facing the external environment and an inner side opposite to it. The cover plate thus has two opposing cover plate surfaces, an outer surface associated with the outer side and an inner surface associated with the inner side. The cover plate comprises a structured area having a light diffusing structure on at least one cover plate surface selected from the outer surface and the inner surface. The structured area has a light scattering structure as described below. The structured area may be composed of a single section of the cover plate surface. Similarly, the structured area may include several sections of the cover plate surface that are spatially separated from each other. The cover plate surface preferably has a structured area over the entire surface, except for the edge area, which may not have a structured area.

[0022] Alternatively, an unstructured transparent cover plate may be provided, whereby at least one structured region having light-scattering structures is formed on at least one surface of the cover plate selected from the outer and inner surfaces, The formation of the structured region may occur before or after the formation of at least one optical interference layer, as described below.

[0023] The method further includes forming at least one optical interference layer on a portion of a selected one of the exterior and interior sides of the cover plate.

[0024] For the purposes of the present invention, a "part" or "partial area" is understood to mean an incomplete coverage of the cover plate surface as viewed vertically through the cover plate, as opposed to a "total area" which means a complete coverage. If a layer is applied directly to a part of the cover plate surface, the layer does not cover the cover plate surface completely, but only partially. If a full-surface layer is applied directly to the cover plate surface, the layer covers the cover plate surface completely. If a layer is not applied directly to the cover plate surface but is arranged between one or more other layers, this is applied in a manner that corresponds to the (orthogonal) projection of the layer on the cover plate surface when viewed vertically through the cover plate surface, whereby the term "covering" is used instead of "overlapping". The cover plate surface can be divided into areas where layers overlap and areas where they do not overlap. An "area" can be constituted by one or more adjacent sections of the cover plate surface. The cover plate surface may be constituted by overlapping and non-overlapping areas, but it is possible that the overlapping and non-overlapping areas only affect a part of the cover plate surface, e.g. not including the edge areas of the cover plate surface. Advantageously, the uncoated areas of the cover plate surface are arranged inside, i.e. completely surrounded by the coated areas of the cover plate surface.

[0025] Forming the partial region of at least one optical interference layer on the selected cover plate side comprises applying a mask to the cover plate on the selected cover plate side, which, when viewed vertically through the cover plate, does not cover a first region of the cover plate surface on the selected cover plate side, but covers a second region of the cover plate surface on the selected cover plate side. Furthermore, the first and second regions are arranged such that, when viewed vertically through the cover plate, they overlap an already formed or to be further formed structured region. Advantageously, in vertical viewing through the cover plate, the entire first and second regions overlap the structured region. The mask can be arranged directly on the cover plate surface (i.e. without the need for further intermediate layers). However, one or more intermediate layers may be located between the mask and the cover plate surface.

[0026] At least one (first) optical interference layer for reflecting light within a given or predeterminable wavelength range is then applied to the cover plate on the selected cover plate side, the optical interference layer being applied so as to overlap the mask (i.e., overlap the second area of ​​the cover plate surface) and overlap the first area of ​​the cover plate surface not covered by the mask in a vertical view through the cover plate. The optical interference layer can be disposed directly on the cover plate surface and on the mask (i.e., without the need for further intermediate layers). However, one or more intermediate layers may be located between them. Preferably, the optical interference layer is applied to the entire cover plate surface partially covered by the mask.

[0027] The mask is then removed, thereby removing any optical interference layers (eg, optical interference layers directly covering the mask).

[0028] As used herein and further, the term "vertical view through the cover plate" means the orthogonal projection (i.e. vertical extension) of the structure onto a surface parallel to the cover plate plane, where vertical means perpendicular to the cover plate plane. The cover plate plane is the plane in which the cover plate extends.

[0029] Preferably, the cover plate has no curvature and is therefore flat (planar). However, the cover may also be curved. The cover plate may be rigid or flexible. It may be provided in a planar form, that is to say in the form of a flexible cover plate. In the case of a planar (flat) cover plate, the extension of the cover plate itself defines a plane, which is understood as the "plane of the cover plate" in the sense of the present invention. In the case of a curved cover plate, a local plane can be defined by a (virtual) flat tangent surface at any point of the plane. This tangent surface also belongs to the term "plane of the cover plate".

[0030] The mask can be applied by known techniques such as lithography, digital printing or screen printing. The mask can be made of any material, provided that it can be removed from the cover plate without damaging it. For example, a coating with a thickness in the micrometer range can be used as the mask. Tape can also be used as the mask.

[0031] As already explained, according to an alternative, the formation of a structured area having light-scattering structures on the outer and / or inner surface of the cover plate can be carried out before or after the formation of a portion of the (first) interference layer, as long as no optical interference layer is applied to the structured area, which necessarily determines the temporal order, i.e. the formation of the structured area is temporally prior to the application of the mask.

[0032] According to the invention, a transparent cover plate with at least one partial optical interference layer can be produced simply and cost-effectively by using a mask that only partially covers the cover plate surface (external and / or internal surface). In particular, the cover plate surface has an optical interference layer in a first region that is not covered by the mask in a vertical view through the cover plate, and does not have an optical interference layer in a second region that is covered by the mask. As a result, the only partially applied interference layer produces partially different color effects of the cover plate or flat body depending on the reflection of light in a given wavelength range. More precisely, the overall color is obtained by combining the color of the rear element and the color of the light reflected by the at least one optical interference layer. For example, in a CIGS thin-film solar module, the photovoltaically active solar cells have a blue-black color and thus contribute to the overall color of the flat body in the optical interference layer region. In the second region of the surface that is not covered by the (first) optical interference layer, such a color effect does not exist unless a further optical interference layer is provided (see below). In this case, the color of this region is mainly determined by the background color visible through the cover (i.e. the color of the rear element). For this reason, the cover plate is color-neutral. Of course, it is also possible to change the background color of the rear element by coloring the transparent cover plate. For example, in a CIGS thin-film solar module, the blue-black color of the photovoltaically active solar cells is seen in the areas where there is no optical interference layer. In a CIGS thin-film solar module, and in general in solar modules, the background color is determined by the color of the solar cells. The solar cells cover a large part of the cover plate, for example at least 90%, in particular at least 95%. In the case of a passive flat body, for example the flat body at the rear is uncolored, dark, non-glossy. It is also possible for the rear element to be colored. As will be explained below, the cover plate can have one or more additional optical interference layers. In this case, locally different colors result depending on whether, after the mask is locally removed (in the second area), only the first optical interference layer or at least one more optical interference layer is present. The (first) optical interference layer may be formed on part of one or both sides of the cover plate.

[0033] According to an advantageous embodiment of the method according to the invention, after forming the partial regions of the (first) optical interference layer, at least one more (second) optical interference layer for reflecting light within a defined or predeterminable wavelength range is applied to the cover plate on the selected cover plate side, said (second) optical interference layer overlapping the first and second regions of the cover plate surface when viewed perpendicularly through the cover plate. Thus, the at least one (second) optical interference layer is in particular applied to the already applied (first) optical interference layer. Preferably, but not necessarily, the (second) optical interference layer is applied directly, i.e. without the need for any further intermediate layers.

[0034] According to another advantageous embodiment of the method according to the invention, a transparent cover plate is provided having at least one more (third) optical interference layer for reflecting light within a predefined wavelength range on the selected cover plate side and / or on the non-selected cover plate side, the (third) optical interference layer covering a first region and a second region of the cover plate surface on the selected cover plate side when viewed perpendicularly through the cover plate.

[0035] According to the above-mentioned embodiment of the method according to the present invention, the cover plate may have at least one second optical interference layer located above the at least one first optical interference layer (from the perspective of the cover plate) (i.e., the at least one first optical interference layer is located between the cover plate surface and the at least one second optical interference layer). Alternatively or additionally, the cover plate may have at least one third optical interference layer located below the at least one first optical interference layer (from the perspective of the cover plate) (i.e., the at least one third optical interference layer is located between the cover plate surface and the at least one first optical interference layer). What is important here is that at least one more optical interference layer (at least one second optical interference layer and / or at least one third optical interference layer) completely covers the at least one (first) partial optical interference layer when viewed vertically through the cover plate, and is also arranged in a second area of ​​the cover plate surface that is not covered by the (first) partial optical interference layer. Thereby, the at least one first partial-region optical interference layer and the at least one second optical interference layer are superimposed on one another, and the at least one second optical interference layer is formed without being superimposed on the first partial-region optical interference layer. Alternatively or additionally, the at least one first partial-region optical interference layer and the at least one third optical interference layer are superimposed on one another, and the at least one third optical interference layer is also formed without being superimposed on the first partial-region optical interference layer (but optionally, overlapping on the at least one second optical interference layer).

[0036] The cover plate can also be provided with at least a third optical interference layer on the non-selected side of the cover plate.

[0037] For example, the flat body may have at least two freely selectable colors, i.e., a first color caused by light reflection at two vertically adjacent optical interference layers (first and second optical interference layers) in a first area of ​​the surface, and a second color caused by light reflection only at the second optical interference layer in a second area of ​​the surface. In either case, the color impression is generated by a combination of the color caused by reflection at the optical interference layer and the background color of the surface. Thus, at least one optical interference layer is used to provide a specific two-color embodiment over the entire cover plate, i.e., even in areas of the cover plate that are previously covered by a mask and do not have an optical interference layer, so that the two colors can be freely selected.

[0038] This allows the flat body to be easily constructed in two colors, especially in multiple colors, where one color is generated by the combination of one or more superimposed optical interference layers and the background color of the rear element, and at least one other color is generated by the background color of the rear element. In a particularly advantageous manner, for example, colored patterns or colored characters encoding information can be displayed on backgrounds of different colors.

[0039] According to an advantageous embodiment of the present invention, the formation of the partial regions of at least one first optical interference layer can be repeated once or several times. In particular, at least one (first) optical interference layer can be formed on both sides of the cover plate. The first optical interference layer can be formed several times on the same side of the cover plate. In the case of repetition, the different steps for forming the partial regions of the first optical interference layer are performed in the same manner as described above.

[0040] According to an embodiment of the invention, the transparent cover plate consists of a single material, for example glass or plastic, preferably soda-lime glass. Preferably, the cover plate is a rigid glass or plastic plate. In this case, the outer or inner surface of the cover plate is formed by the respective material of the cover plate. According to an alternative embodiment, the cover plate consists of at least two different materials, the outer and / or inner surface of the cover plate is formed by a material different from the core of the cover plate. Preferably, the core of the cover plate is made of a single material, such as glass or plastic, preferably soda-lime glass. The outer and / or inner side of the cover plate core is applied with a material different from the cover plate core, which material is transparent and has the same optical index of refraction as the material of the cover plate core. In this case, the outer and / or inner surface of the cover plate is formed by the respective material applied to the core of the cover plate. According to the invention, the term "cover plate" thus also includes a composite, with the proviso that the material forming the cover plate is transparent and has the same optical index of refraction.

[0041] For the purposes of the present invention, the term "transparent" or "transparent" means that the transmission of visible light is at least 80%, in particular at least 90%, preferably at least 95%, in particular 100%. Typically, visible light is present in the wavelength range from 380 nm to 780 nm. "Opaque" means that the transmission of visible light is less than 5%, in particular 0%. The percentage values ​​refer to the light intensity measured on one side of the cover plate and related to the intensity of light incident on the other side of the cover plate. For such measurements, a white light source (visible light source) may be arranged on one side of the cover plate and a detector for visible light may be arranged on the other side of the cover plate. The values ​​of the optical refractive index below always refer to the optical refractive index in the visible wavelength range from 380 nm to 780 nm.

[0042] The optical interference layers may each be single or multiple layers, i.e., have one or multiple refractive layers. The optical interference layers are used to generate color, whereby the optical interference layers are configured to allow constructive and destructive interference of light reflected at various interfaces of the optical interference layers. Color is generated by the interference of light reflected at the interfaces of the optical interference layers. When illuminated with (white) light, especially sunlight, the optical interference layers act as color filters and generate uniform color.

[0043] In principle, the optical interference layers can have the same refractive index and layer thickness. According to an advantageous embodiment of the method of the present invention, at least two optical interference layers have different refractive indexes and / or layer thicknesses, which makes it possible to produce cover plates with different colors.

[0044] When illuminated from the outside with white light, in particular with sunlight, the flat body gives the observer a color impression of at least two colors, i.e. that the flat body is multicolored. Preferably, the multicolor color impression extends over the entire outer surface of the flat body or its cover plate.

[0045] The colours of a plane can be described by the three colour coordinates L*, A*, B*, whereby the colour coordinates refer to the (CIE) L*a*b* colour space, known to experts, in which all perceptible colours are precisely defined. This colour space is defined in the European standard EN ISO 11664-4 "Colorimetry - Part 4: CIE 1976 L*a*b* Colour Space", which is cited in full in the context of the present invention description. In the CIE (L*a*b*) colour space, each colour is defined by a colour locus with three Cartesian coordinates L*, a*, b*. On the a* axis green and red are opposed, the b* axis extends between blue and yellow, and the L* axis describes the lightness (luminance) of the colour. For a more descriptive representation, these quantities can be transformed into the Lhc colour space, where L remains the same, chroma is the radius of the colour point in the a*b* plane and h is the angle.

[0046] The color of the flat body refers to the observation from the external environment, i.e. from the front cover plate. The color coordinates of the flat body can be easily measured or determined using a commercially available colorimeter (spectrophotometer). For this purpose, the color measuring device is directed to the outer surface, in particular the outer surface, of the front cover plate. Conventional color measuring instruments allow standard-compliant color measurements, so their implementation and tolerances typically comply with international standards defined in DIN 5033, ISO / CIE 10527, ISO 7724, ASTM E1347. For example, for color measurements, full reference is made to the DIN 5033 standard. The colorimeter has, for example, a xenon flash lamp, a tungsten halogen lamp, or one or more LEDs as light sources, thereby illuminating the outer surface of the body with the generated (e.g. white) light and measuring the light received by the flat body. The color of the body measured by the colorimeter is generated by the reflected and attenuated light of the flat body.

[0047] In the case of different embodiments of the method or the cover plate according to the invention, the outer surface and / or the inner surface of the cover plate may each have or be provided with a structured area. The first optical interference layer and, if necessary, at least one more (second and / or third) optical interference layer may be arranged on the outer surface and / or the inner surface. For example, the outer surface has a structured area, the inner surface does not have a structured area, and at least one optical interference layer is formed on a part of the inner side of the cover plate. At least one more (second) optical interference layer may be formed on the inner side of the cover plate (particularly also on the first optical interference layer). The cover plate may have at least one more (third) optical interference layer on the inner side of the cover plate (particularly also below the first optical interference layer).

[0048] To achieve a uniform color impression, at least one surface of the cover plate (i.e. the outer and / or inner surface) has a structured area. Preferably, the structured area extends over the entire surface of the cover plate, i.e. the entire outer and / or inner surface of the cover plate, so that the flat body has an overall uniform color impression.

[0049] The term "textured region" or "structured region" refers in a particularly advantageous manner to a region of the outer and / or inner surface of a cover plate, in which the features described below are present in combination.

[0050] Thus, the structured area perpendicular to the plane of the cover plate has a height profile with peaks (risers) and valleys (recesses), the average height difference between the peaks and valleys being at least 2 μm and preferably, but not necessarily, at most 20% of the thickness of the transparent cover plate. Furthermore, at least 50% of the structured area of ​​the surface (external and / or internal) consists of segments or facets (reflective areas of the surface) with different inclinations. The segments are parts of the cover plate surface and are realized as flat surfaces inclined with respect to the plane of the cover plate. At least 20% of the segments have an inclination angle lying in the range of more than 0° and up to 15°, and at least 30% of the segments have an inclination angle lying in the range of more than 15° and up to 45°. Advantageously, but not necessarily, less than 30% of the segments have an inclination angle greater than 45°. The structures are preferably non-periodic and anisotropic. However, for special optical effects, periodic and anisotropic structures can also be used. Furthermore, the segments are flat and have a height difference of at least 1 μm. 2 The structured areas can be produced, for example, by etching, sandblasting or rolling the cover plate.

[0051] The structured region has a number of planar segments. For the purposes of the present invention, the planar segments may be formed from non-curved surfaces. However, the planar segments may also be formed by slightly curved surfaces. Area 1 μm 2 If the (virtual) tangent plane of is constructed at the points of the segment, and the condition that the distance between the segment area and the cut surface relative to the normal direction of the tangent plane is less than 50 nm is applied to each point of the segment, then the segment will be slightly curved in the sense of the present invention, for example, if the configuration of the segments, in particular their inclination angle or average roughness, does not correspond to a normal distribution.

[0052] Furthermore, in at least one region (i.e., area) of the structured region, the segments each preferably have an average roughness less than 15% of the layer thickness of the at least one optical interference layer. If the optical interference layer is composed of multiple refractive layers, the segments of the at least one region each have an average roughness less than 15% of the layer thickness of the refractive layer having the smallest layer thickness. The region whose segments each have an average roughness less than 15% of the layer thickness of the optical interference layer can correspond to the structured region, i.e., the region and the structured region are the same.

[0053] If the surface is not structured, it is smooth (within manufacturing tolerances).

[0054] The structured area can be advantageously used to achieve that when the cover plate is illuminated with light, a relatively high intensity of light is reflected even when viewed outside the gloss angle (the angle of incidence of the incident light corresponds to the angle of reflection of the reflected light with respect to the plane of the cover plate). This is due to the different segments of inclination having a sufficient number, suitable size, suitable roughness and suitable inclination angle to achieve a high intensity of reflected light even when viewed outside the gloss angle. There is always a sufficient number of inclined segments to scatter sufficient intensity in directions outside the gloss angle of the cover plate, both when structuring externally by reflection or refraction at the segments and when building compartments internally by reflection at the segments.

[0055] As used herein and further, the term "gloss angle" refers to the normal to the cover plate plane, and "local gloss angle" refers to the normal to the plane of the segment. The gloss angle and the local gloss angle may be the same (the segment is parallel to the cover plate plane), but are usually different (the segment is tilted with respect to the cover plate plane).

[0056] As a result, the intensity of the light that is not reflected (i.e., scattered) at the gloss angle is relatively high and has little angular dependence on the direction of incidence and the direction of observation, compared to a reflective surface that does not have such structured regions. The optical interference layer allows the light reflected outside the gloss angle to be color selected according to the refractive index and layer thickness of the at least one optical interference layer, thereby allowing the surface of the cover plate to have a uniform color with relatively low angular dependence.

[0057] In this respect, the structured area has a height profile in which the average height difference between the peaks and the valleys is at least 2 μm, preferably at least 10 μm, particularly preferably at least 15 μm. Such a structured area can be produced by etching the cover plate (e.g. cover glass). In this respect, the structured area has an equally advantageous height profile in which the average height difference between the peaks and the valleys is at least 50 μm, preferably at least 100 μm, in particular more than 100 μm, more than 150 μm or more than 200 μm. Such a structured area can be produced by rolling the cover plate (e.g. cover glass). The invention thus advantageously extends to exterior elements in which at least one structured area of ​​the cover plate is produced by etching or rolling, whereby said height profile can be produced. However, these structures can also be produced by applying a transparent structured layer to the cover plate. The refractive index of the layer must be the same as (or at least very similar to) the cover. According to the invention, the structuring of the cover plate surface should also include the application of such a transparent structured layer.

[0058] The mentioned properties of the structured region of the cover plate can be determined, for example, by conventional measuring instruments such as a microscope, in particular a confocal microscope, or a needle profilometer.

[0059] Preferably, the structured area of ​​the cover plate ensures that at observation angles of 45° and 15° (each observation angle relative to the normal to the plane of the cover plate) and at angles of incidence offset by 45° (in both directions) from the respective gloss angle, a reflected light brightness L of at least 10 is obtained. The resulting reflected light brightness L is preferably at least 15, more preferably at least 20. To carry out such measurements, a black cover is placed on the side of the (uncoated) cover plate facing away from the side to be characterized. A D65 lamp is used for the measurements, and the brightness L is measured with a commercially available multi-angle colorimeter (10° aperture angle). The measurement setup is described in detail below, in which full reference is made to the European standard EN ISO 11664-4.

[0060] In an advantageous embodiment, at least 80%, preferably at least 90%, of the structured area of ​​the outer or inner surface (depending on which surface is structured) consists of segments inclined with respect to the plane of the cover plate. By increasing the number of segments, the intensity of the light reflected from the structured area of ​​the cover plate surface and its angular stability can be further improved, even outside the gloss angle.

[0061] In another advantageous embodiment, at least 30% of the segments of the structured area have an inclination angle in the range of more than 0 ° to a maximum of 15 °, at least 40% of the segments have an inclination angle in the range of more than 15 ° to a maximum of 45 °, preferably, but not necessarily, less than 10% of the segments have an inclination angle greater than 45 °. Particularly preferably, at least 40% of the segments have an inclination angle in the range of more than 0 ° to a maximum of 15 °, at least 50% of the segments have an inclination angle in the range of more than 15 ° to a maximum of 45 °, preferably, but not necessarily, less than 10% of the segments have an inclination angle greater than 45 °. If there is a relatively large number of faces with small inclination angles of less than 15 °, the reflection intensity occurs substantially only at observation angles close to the gloss angle (similar to unstructured surfaces), which is undesirable according to the invention. For steeper facets, the angular dependence of the reflected light is reduced, but for many very steep facets (greater than 45°), multiple reflections can occur with increasing intensity, which is disadvantageous since it can result in a greater coupling of the light into the absorber layer, where reflection is desired. Furthermore, due to many coating processes, it is difficult to simultaneously guarantee conformal coatings of the same layer thickness on flat and steep surface segments. Thus, the layer thickness of the optical interference layer of the optical interference coating applied to the structured area depends on the tilt angle, which results in an undesirable angular dependence. In this respect, the embodiment in which the segments each have a tilt angle greater than 0° and up to 45° is most preferred. These conditions allow a very high reflected light intensity to be achieved even outside the gloss angle, with a particularly low reflected light angle dependence of the intensity.

[0062] The structures are preferably non-periodic and anisotropic. However, periodic and / or anisotropic structures can also be used for special optical effects. In glass drawing, periodic and anisotropic structures such as pyramids, square or hexagonal honeycomb structures, or hemispheres can be easily produced by rolling. These can be used for attractive gloss and color effects. If the surface structure satisfies the above conditions, the flat body will have a significantly reduced color loss at angles outside the gloss angle, but the angle dependence is anisotropic with respect to the in-plane direction of the flat body.

[0063] This allows a very satisfactory realization of uniform color effects with low angle dependence, while ensuring high efficiency of the flat body. On the one hand, the structured surface of the cover plate reflects light with high intensity and low angle dependence, even outside the gloss angle. On the other hand, the filtering action of the at least one optical interference layer allows absorption of high intensity light, so that a large part of the incident light can be utilized with high efficiency or with as little efficiency loss as possible. Furthermore, a good uniform color impression is achieved by the at least one color-forming optical interference layer, whereby two different colors can be realized in a simple manner by utilizing mask technology and the selective arrangement of the first applied (first) optical interference layer. The optical interference layer acts as a filter with narrow-band reflection and wide-band transmission.

[0064] Each optical interference layer may in particular comprise one or more refractive layers. The refractive layers are made of the same material (same composition) and in particular have a uniform (same) refractive index across the layer thickness. If the optical interference layer comprises a plurality of refractive layers, at least two of the refractive layers are made of different materials and have different refractive indices. Advantageously, at least one refractive layer has a refractive index n greater than 1.7, preferably greater than 2.0, particularly preferably greater than 2.3. In principle, the higher the refractive index, the lower the angle dependency of the reflected light and the lower the angle dependency of the color impression.

[0065] Advantageously, at least one optical interference layer is made of TiO x , ZrO x, SiC, and Si3N4. When the optical interference layer is two, three, or more layers, it preferably contains at least one compound selected from the group consisting of MgF2, AI2O3, SiO2, and silicon oxynitride. These are compounds with relatively low refractive indices.

[0066] A good color impression can be achieved by the combination of a structured surface and at least one optical interference layer having a small number of refractive layers (e.g. 1 to 3 refractive layers). The small number of refractive layers simplifies production and reduces production costs.

[0067] Advantageously, at least one optical interference layer (in particular all optical interference layers) comprises (or consists of) a refractive layer having a refractive index n greater than 1.9, preferably greater than 2.3.

[0068] It is also advantageous if at least one optical interference layer (in particular all optical interference layers) comprises (or consists of) exactly two refractive layers, with a first refractive layer having a first refractive index n1 on a cover plate having a refractive index nd and a second refractive layer having a second refractive index n2 on the first refractive layer. The following applies to the absolute values ​​of the refractive index differences: |n1-nd|>0.3 and |n2-n1|>0.3, and at least one of the refractive indices n1 and n2 is greater than 1.9, preferably greater than 2.3.

[0069] Equally advantageous is that at least one optical interference layer (in particular all optical interference layers) comprises exactly three refractive layers (or consists of these refractive layers), with a first refractive layer having a first refractive index n1 present on a cover plate having a refractive index nd, a second refractive layer having a second refractive index n2 present on the first refractive layer, and a third refractive layer having a third refractive index n3 present on the second refractive layer. The following applies to the absolute value of the refractive index difference: |n3 - n2| > 0.3, |n2 - n1| > 0.3 and |n1 - nd| > 0.3, and thus the refractive index values alternate such that n1 > n2 and n3 > n2, or n1 < n2 and n3 < n2. Furthermore, at least one of the refractive indices n1, n2, n3 is greater than 1.9, preferably greater than 2.3.

[0070] An optical interference layer having exactly one, exactly two, or exactly three refractive layers can be used to achieve a uniform color impression of the flat body, a simplification of the production of the flat body, and a reduction in the production costs of the flat body. By using two or three refractive layers, it is possible to increase the color strength (i.e., brightness) and chroma (i.e., reflectance) in a certain narrow wavelength range. A relatively high refractive index reduces the angular dependence. Structured cover plates and interference layers from layer stacks having more than three layers combined with the shown embodiments are also within the scope of the invention, but are more complex to manufacture. A four-layer stack of refractive layers having alternating high and low refractive indices can, for example, make the bandwidth of the reflected light smaller and improve the transmittance.

[0071] In the structured region of the cover plate, reflection of the incident light radiation occurs with a relatively high intensity even outside the gloss angle. For this purpose, the structured region is preferably configured such that there is a reflection haze of more than 50%, preferably more than 90%. The reflection haze can be determined with a commercially available haze measuring instrument. According to ASTM D1003, the haze is the ratio of the diffused part of the reflected light to the total reflection.

[0072] At least one area is provided in the structured surface, in which the segments have an average roughness of less than 15% of the layer thickness of at least one optical interference layer, thereby allowing constructive or destructive interference of the reflected light. Advantageously, this area extends over the entire cover plate. According to one embodiment, the structured area has at least one further area, i.e. a (partial) area, in which the segments each have an average roughness such that no interference occurs on the optical interference layer. For example, the segments there have an average roughness of 50% to 100% of the layer thickness of at least one optical interference layer. In these areas, no color is generated by the optical interference layer.

[0073] The invention also extends to a method for manufacturing a flat body, which method includes a method for fabricating a transparent cover plate for a flat body according to the invention.

[0074] The invention also extends to a transparent cover plate for flat bodies, which cover plate is advantageously, but not necessarily, manufactured by the method described above.

[0075] The transparent cover plate has an outer side intended to face the external environment and an opposite inner side, and at least one cover plate surface selected from the outer and inner sides is provided with a structured area having light scattering structures. At least one (first) optical interference layer reflecting light within a predetermined wavelength range is arranged on the cover plate surface selected from the outer and inner sides, where the (first) optical interference layer is arranged on a first area of ​​the cover plate surface facing the cover plate and not on a second area of ​​the cover plate surface facing the cover plate, and the first and second areas are arranged to overlap the structured area in a vertical view through the cover plate.

[0076] In an advantageous embodiment of the transparent cover plate, the transparent cover plate has at least one more (second and / or third) optical interference layer on the selected cover plate side, which (second and / or third) optical interference layer covers the first and second regions of the cover plate surface on the selected cover plate side when viewed perpendicularly through the cover plate, wherein the at least one more (second and / or third) optical interference layer is located on one or both sides of the partially coated optical interference layer.

[0077] In another advantageous embodiment of the transparent cover plate, the transparent cover plate has at least another (third) optical interference layer on the selected cover plate side, which (third) optical interference layer overlaps with the first and second regions of the cover plate surface on the selected cover plate side when viewed perpendicularly through the cover plate.

[0078] The above description of the method for fabricating the transparent cover plate applies equally to the transparent cover plate itself, and reference is made to the description therein to avoid unnecessary duplication.

[0079] The invention also extends to a flat body comprising a transparent cover plate according to the invention. The flat body is in particular a light-absorbing flat body, such as a solar module for generating photovoltaic energy from sunlight or a solar collector for energy conversion. The light-absorbing flat body can be used, for example, as an integral component of a building enclosure or an independent wall, such as a window, cladding or roof element. The flat body may also be a passive flat body that only functions as an integral component of a building enclosure or an independent wall.

[0080] The invention further extends to the use of the flat body according to the invention as an integral part of an architectural enclosure or a separate wall, in particular as a window, cladding or roof element. The flat body can be an active or passive flat body. It is preferred and intended that the flat body is installed as a visible flat component in the architectural enclosure or separate wall, in particular the cladding, so that the flat body is part of the exterior surface visible from the outside environment. The flat body may also be integrated as an independent component, so that the exterior surface of the flat body is part of the exterior surface of the architectural enclosure or separate wall.

[0081] The different embodiments of the invention can be realised alone or in any combination, in particular the features mentioned above and those to be described below can be used not only in the combinations shown, but also in other combinations or alone, without departing from the scope of the invention. [Brief description of the drawings]

[0082] The invention will now be explained in more detail with reference to the accompanying drawings, which are shown in simplified, non-scale representations, in which: FIG. [Figure 1-4] 1A-1D are schematic cross-sectional views of the basic structure of various embodiments of a flat body according to the present invention; [Figure 5-6] 1A-1D are schematic cross-sectional views of various embodiments of the flat body cover plate of the present invention. [Figure 7] 1 is a schematic cross-sectional view of the manufacture of a flat body cover plate according to the present invention; [Figure 8] 8 is a flow chart showing method steps performed in the manufacture of a cover plate according to FIG. 7; [Figure 9] FIG. [Figure 10] FIG. 1 is a schematic diagram of typical lighting conditions on a flat body. [Figure 11-14] 1 is a schematic diagram of an exemplary light path when reflected from a structured region. [Figure 15] FIG. 2 is a schematic diagram of light interference in an optical interference layer. [Figure 16]1 is a schematic cross-sectional view of an embodiment of a cover plate. [Figure 17] 7 is a schematic diagram of an exemplary light path when reflected by a cover having a structured outer surface combined with an inner interference layer according to the embodiment of FIG. 6. [Figure 18] FIG. 2 is a schematic diagram of a multi-angle color measurement method. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0083] In FIG. 1, a flat body generally designated 1 according to the invention is shown diagrammatically in a cross-section. In this case, the flat body 1 has the form of, for example, a solar module with a composite pane structure. The cross-section is perpendicular to the module surface. The flat body 1 comprises a cover plate 10 (e.g. a front glass) and a rear substrate 2, which are firmly connected to each other via an adhesive layer 9 (e.g. a laminate foil). Solar cells 12 (silicon wafers or thin-film solar cells) are arranged on the substrate 2. The color-producing element of the flat body 1 is the coated cover plate 10, whose outer surface 11 faces the incident light and whose inner surface 13 is connected to the solar cells 12 via an adhesive layer 9. The outer surface 11 of the cover plate 10 is located on its outer side 27, and the inner surface 13 is located on its inner side 28. The substrate 2 with the solar cells 12 forms an opaque rear element 21, whose inherent color is essentially determined by the solar cells 12. However, in the edge regions and between the solar cells 12, the color can also be determined by contact strips and edge sealing or, in the case of wafer solar cells, by a back foil.

[0084] Here, the cover plate 10 is a least absorbent glass pane, for example made of soda-lime glass. The outer surface 11 and / or the inner surface 13 of the cover plate 10 are structured (for example by etching, sand-blasting or rolling during the drawing process), and furthermore the outer surface 11 and / or the inner surface 13 have at least one optical interference layer, which is not shown in Figure 2 but will be explained in more detail below (see Figures 5 and 6). The flat body 1 can be used as an integral part of the building enclosure or of a free-standing wall, in particular as an exterior element.

[0085] FIG. 2 shows an exemplary structure of a passive flat body 1, which is used as an integral component of a building envelope or a freestanding wall, in particular as an exterior element, and which fulfills only a structural function. The flat body 1 comprises a transparent cover plate 10 and an opaque rear element 21. The cover plate 10 is constructed as shown in FIG. 1. The above-mentioned embodiment applies in the same way. The cover plate 10 itself can also be constructed as a composite, whereby it consists of a transparent core embedded (for example in a sandwich) in another transparent material having the same optical refractive index as the core, which then forms the outer surface 11 and the inner surface 13. This is not shown in FIG. 2. Here, the rear element 21 is for example in the form of an opaque coating 19 on the inner surface 13, which extends over the entire inner surface 13. The opaque coating 19 may consist of one or more layers. The coating can be, for example, a lacquer, a polymer layer, a polymer film or an inorganic layer of metal oxide powder, carbon, semiconductor material. The layer thickness of the rear element 21 can be freely selected, as long as the desired optical properties of the coating are ensured. The rear element 21 can, if necessary, be protected from environmental influences by a rear cover, for example in the form of another coating or film. In its embodiment as a coating, the rear element 21 is not load-bearing, so that the cover plate 10 must meet certain requirements to function as an exterior element. In particular, the mechanical load-bearing capacity and the possibility of a proper connection with the building structure must be ensured, for example by the use of frames, clamps or rear rails. For this purpose, the cover plate 10 preferably consists of refined glass, such as heat-strengthened glass, tempered safety glass (ESG) or partially tempered glass (TVG). The coating is opaque and may, for example, have a predetermined color, such that the background color of the coating creates the overall color impression of the flat body 1 in the desired manner. Likewise, for this purpose, the rear element 21 may be achromatic, dark and non-glossy.

[0086] FIG. 3 shows a variant of the passive flat body 1 of FIG. 2, according to which the rear element 21 is an independent body with a defined spatial shape, here rigidly connected to the inner surface 13 of the cover plate 10, for example by a transparent adhesive layer 9 (for example a laminate foil). In principle, the cover plate and the rear element 21 can be rigidly connected using any suitable joining technique, such as gluing or potting. Joining techniques in which the connecting transparent material (for example an adhesive layer, a laminate foil or a potting material) has a refractive index greater than 1.4 and less than 1.6 are advantageous. Otherwise the resulting color of the flat body 1 may be undesirably altered. For example, the rear element 21 is configured in the form of a flat plate forming a complex with the cover plate 10. The rear element 21 preferably bears a load and has suitable mechanical properties for this purpose in order to ensure the load-bearing capacity of the flat body 1 itself or of the combination with the cover plate 10. The flat body 1 thus formed can be easily connected to the building as an exterior element and must meet the overall requirements as an exterior element in the building enclosure. The rear element 21 can for example consist of a fiber composite, glass, stone, metal or ceramic and can be coated with paints or suitable inorganic thin films, such as in particular ceramic screen printing inks or organic glass paints, to obtain the desired background color. The material of the rear element 21 itself can already have the desired color. For example, the rear element 21 consists of colored glass in a glass matrix. It is also possible to use CIGS thin films, which are waste from the serial production of thin-film solar modules, in combination with the CIGS thin-film solar modules used as exterior elements, to achieve a particularly uniform color impression of the exterior. The layer structure 3 used for the solar cells 12 does not have a power generation function. The glass rear element 21 can be easily connected to the glass cover plate 10 using conventional lamination methods. For example, the rear element 21 is a metal sheet, a metal foil or consists of a metal composite. For example, the metal sheet or metal foil can be treated by anodizing or coating to obtain the desired optical properties.The rear element 21 may likewise consist of a building material suitable for outdoor use, such as for example a fibre cement board, a concrete board, a textile or fibre reinforced concrete shell, wood / wood fibre material, plastic or other non-metallic composite material. The surface of the material can be configured with suitable colouring techniques to achieve the desired optical properties. The cover plate 10 is configured as shown in Figure 1. The above embodiments apply in the same way.

[0087] An exemplary structure of a thin-film solar module is described in more detail in FIG. 1 with reference to FIG. 4. The flat body 1 in the form of a thin-film solar module comprises a number of solar cells 12 interconnected in series in an integrated manner, only two of which are shown in simplified form. Needless to say, in the flat body 1, there are usually a large number of solar cells 12 (for example, about 100 to 150) connected in series. The flat body 1 has a composite pane structure of a substrate structure. It comprises a back substrate 2 to which a layer structure 3 of thin films is applied, whereby the layer structure 3 is arranged on the light-entrance side surface of the back substrate 2. Here, the substrate 2 is configured, for example, as a rigid flat glass plate having a relatively high light transmittance, whereby other electrically insulating materials having the desired strength and inert behavior for the method steps to be performed can be used as well. The layer structure 3 comprises an opaque back electrode layer 5, which is provided on the surface of the substrate 2 and consists of an opaque metal, for example molybdenum (Mo), applied to the substrate 2 by evaporation or magnetic field-assisted cathodic sputtering. The back electrode layer 5 has a layer thickness, for example, in the range of 300 nm to 600 nm. On the back electrode layer 5, a photovoltaically active (opaque) absorber layer 6 is deposited, which consists of a semiconductor with a band gap that allows absorbing as much solar radiation as possible. The absorber layer 6 consists of a conductive chalcopyrite semiconductor, for example a compound of the Cu(Ln / Ga)(S / Se)2 group, in particular sodium (Na)-doped Cu(Ln / Ga)(S / Se)2. In the above formula, indium (In) and gallium (Ga) as well as sulfur (S) and selenium (Se) may be present optionally or in combination. The layer thickness of the absorber layer 6 is, for example, in the range of 1 to 5 μm, in particular around 2 μm. To produce the absorber layer 6, layers of different materials are usually applied, for example by sputtering, which are then thermally converted into compound semiconductors by heating in a furnace, optionally in an atmosphere containing S and / or Se (RTP=rapid thermal processing). Experts are familiar with this method of producing compound semiconductors, so it is not necessary to discuss it in detail here. A buffer layer 7 is deposited on the absorber layer 6, in this case the buffer layer 7 being a single layer of cadmium sulfide (CdS), indium sulfide (InS). x S y) or zinc oxide sulfide (ZnOS) and optionally a single layer of intrinsic zinc oxide (i-ZnO) or zinc magnesium oxide (ZnMgO), not shown in FIG. 1. A front electrode layer 8 is applied to the buffer layer 7, for example by sputtering. The front electrode layer 8 is transparent to radiation in the visible spectral range ("window electrode"), so that the incident sunlight 4 (shown by the arrow in FIG. 1) is only slightly attenuated. The front electrode layer 8 is based on a doped metal oxide, for example n-type conductive aluminum (Al) doped zinc oxide (ZnO). Such a front electrode layer 8 is generally called a TCO layer (TCO = transparent conductive oxide). The layer thickness of the front electrode layer 8 is for example in the order of 1000 nm. The front electrode layer 8 forms a heterojunction (i.e. a series of layers of opposite conductivity type) together with the buffer layer 7 and the absorber layer 6. The buffer layer 7 allows for electronic matching between the absorber layer 6 and the front electrode layer 8. To protect against environmental influences, a (plastic) adhesive layer 9 is applied to the layer structure 3 and is used to seal it. Bonded to the adhesive layer 9 is a solar-transparent front or light-entry cover plate 10, which in this case takes the form of a rigid (flat) glass plate, for example made of extra-white glass with a low iron content. The cover plate 10 is used for sealing and mechanical protection of the layer structure 3. The cover plate 10 has an inner surface 13 facing the solar cells 12 and an outer surface 11, facing away from the solar cells 12 and which is also the module surface or top surface. Via the outer surface 11, the thin-film solar module can absorb sunlight 4 and generate a voltage at the resulting voltage connections (+, -). In FIG. 4, the current paths are indicated by arrows arranged in series. The cover plate 10 and the substrate 2 are firmly bonded ("laminated") via an adhesive layer 9, whereby the adhesive layer 9 is formed, for example, as a thermoplastic adhesive layer which is plastically deformable when heated and which firmly bonds the cover plate 10 and the substrate 2 to one another when cooled. The adhesive layer 9 can be provided in the production method as a laminating film, here consisting, for example, of PVB. The cover plate 10, the substrate 2 and the solar cells 12 embedded in the adhesive layer 9 together form a laminated composite.The module rear side 14 is formed by the surface of the substrate 2 facing away from the solar cells 12 .

[0088] To form the solar cells 12 and connect them in series, the layer structure 3 is structured using a suitable structuring technique, for example laser writing and / or mechanical ablation. For this, a direct arrangement of typically three structured lines P1-P2-P3 is respectively placed in the layer structure (stack) 3. Here, at least the back electrode layer 5 is subdivided by a first structured line P1, thereby forming the back electrode of the solar cell 12. A second structured line P2 is used to divide at least the absorber layer 6, such that the photovoltaically active areas (absorbers) of the solar cells 12 are generated. A third patterned line P3 divides at least the front electrode layer 8, thereby forming the front electrode of the solar cell 12. By means of the second structured line P2, the front electrode of the solar cell 12 is electrically connected to the back electrode of the adjacent solar cell 12, whereby, for example, the front electrode is in direct contact with the back electrode. In the example of FIG. 4, the grooves of the first structured line P1 are filled with the material of the absorber layer 6. The grooves of the second structured line P2 are filled with the material of the front electrode layer 8 and the grooves of the third structured line P3 are filled with an adhesive layer 9. Each direct arrangement of the first, second and third structured lines P1-P2-P3 forms a structured area for connecting two adjacent solar cells 12 in series. The invention also covers solar modules based on silicon wafer cells and any other technology for producing solar cells.

[0089] FIG. 5 shows an enlarged cross section of the cover plate 10 of the flat body 1 shown in FIGS. 1 to 4. The outer surface 11 of the cover plate 10 is structured in an area 15 which in this example covers the entire outer surface 11, i.e. the outer surface 11 and the structured area 15 are identical. The inner surface 13 is not structured. A first optical interference layer 16 is partially provided directly on the outer surface 11. In the structured area 15 the outer surface 11 has a height profile with peaks and valleys. More than 50% of the outer surface 11 consists of flat segments 17, each plane of which is inclined with respect to the plane of the cover plate 10, i.e. has an angle different from zero. The average height sublayer between the highest point (peak) and the lowest point (valley) of the outer surface 11 is at least 5 μm and at most, for example, 20% of the thickness of the transparent cover plate 10. At least 20% of the segments 17 have an inclination angle in the range of greater than 0° to a maximum of 15°, at least 30% of the segments have an inclination angle in the range of greater than 15° to 45°, and less than 30% of the segments 17 have an inclination angle greater than 45° relative to the plane of the cover plate 10. In the example of Figure 3, the maximum inclination angle of all segments is 45°.

[0090] The first optical interference layer 16 is thin, with a layer thickness in the range of 0.1 to a few (e.g. 5) micrometers. The first optical interference layer 16 also has a refractive index greater than 1.7, preferably greater than 2.0, particularly preferably greater than 2.3, and as low an absorption as possible for the incident light. The first optical interference layer 16 may be a single layer or a multilayer, i.e., it may consist of one or more refractive layers. Each refractive layer has a specific refractive index and is made of the same material. For example, the optical interference layer 16 may be made of MgO, SiON, etc. x , Si3N4, ZrO2, TiO xand / or SiC. It is desirable that the electrical conductivity of the individual refractive layers, particularly that of first optical interference layer 16, be as low as possible. First optical interference layer 16 does not completely cover outer surface 11, but only partially covers outer surface 11. Specifically, outer surface 11 is composed of a first region 22 that is covered by first optical interference layer 16 and a second region 23 that is not covered by first optical interference layer 16. In particular, first optical interference layer 16 can extend over and completely cover the entire outer surface 11, except for second region 23.

[0091] When viewed vertically through the cover plate 10, i.e. in the vertical projection (vertical extension) of the structured area 15 onto a (virtual) plane parallel to the plane GE of the cover plate 10, and when viewed in the vertical projection (vertical extension) of the second area 23 and the first area 22, respectively, onto the same plane of the cover plate 10, the second area 23 and the first area 22 overlap with the structured area 15, and the second area 23 and the first area 22 overlap and are advantageously located within the structured area 15. For example, the surface parallel to the plane GE is the inner surface 13.

[0092] 5 shows an example of a plane GE of the cover plate 10. The plane GE is obtained due to the substantially planar shape of the cover plate 10. The depicted plane GE is only exemplary and may have a different position. In this example, the inner surface 13 is not structured and the plane GE is parallel to the inner surface 13. For a structured outer surface 11, the plane GE is parallel to a virtual surface of the outer surface 11, which is generated by averaging the segments 17.

[0093] In a first region 22 of exterior surface 11 that is coated with first optical interference layer 16, a filtered reflection of light rays within a predetermined or predeterminable wavelength range occurs, as described in more detail below. Such filtered reflection is essentially absent in a second region 23 of exterior surface 11 that is not coated with first optical interference layer 16. Thus, the color effect due to optical interference layer 16 exists only in first region 22 of exterior surface 11. In any event, contrast exists.

[0094] Figure 6 shows a variation of the cover plate 10 of Figure 5. To avoid unnecessary repetition, only the differences from Figure 5 will be described, and otherwise reference will be made to the description of Figure 5. Thus, the first optical interference layer 16 is not located on the outer surface 11 of the cover plate 10, but only on the unstructured inner surface 13 of the cover plate 10. Similar to Figure 5, the inner surface 13 has a first region 22 that is coated with the first optical interference layer 16 and a second region 23 that is not coated with the first optical interference layer 16.

[0095] With reference to Figures 7A-7E, an exemplary production of the cover plate 10 of Figure 6 is shown by means of schematic cross-sections. Accordingly, the outer surface 11 is structured and the inner surface 13 is not structured. An optical interference layer 16 is applied only to the inner surface 13. Intermediate stages during the production of the cover plate 10 are shown. For the sake of brevity, the structuring of the outer surface 11 has been omitted. In Figure 8, a flow chart of the successive steps carried out in this method is also shown.

[0096] Step i): According to a first alternative, a transparent cover plate 10 (front glass) is provided which already has a structured area 15 on its outer face 11 (FIG. 7A).

[0097] Step i'): According to a second alternative, an unstructured transparent cover plate 10 is provided, which after provision is provided with a structured region 15. The method thus comprises providing an unstructured transparent cover plate 10 having an outer surface 11 designed to face the external environment and an opposite inner surface 13, and forming a structured region 15 with light scattering structures in at least one surface chosen from the outer surface and the inner surface (Figure 7a).

[0098] In this case, the first optical interference layer 16 and the structured area 15 are located on different surfaces of the cover plate 10, so that the formation of the structured area 15 can be performed at any time. In the variant of Figure 5, the structured area 15 needs to be formed before the mask 24 is applied.

[0099] It goes without saying that a cover plate 10 already having a structured area 15 may be provided again with a structured area 15 after provision. In the first alternative according to step i), the formation of a structured area 15 with light-scattering structures on at least one surface selected from the outer and inner surfaces can be provided as an option.

[0100] Step ii): A mask 24 is then applied to a portion of the inner surface 13 of the cover plate 10. The mask 24 does not cover a first region 22 of the inner surface 13, but covers a second region 23 of the inner surface 13. When viewed vertically through the cover plate 10, the second region 23, preferably the entire second region 23, overlaps with the structured region 15 (FIG. 7B).

[0101] Step iii): Next, a (first) optical interference layer 16, which reflects light within a predetermined wavelength range, is applied to inner surface 13 that is partially covered by mask 24. Optical interference layer 16 is applied to mask 24 and at least partially to first regions 22 of inner surface 13 that are not covered by mask 24 (FIG. 7C).

[0102] Step iv): Mask 24 is then removed, thereby also removing optical interference layer 16 applied to mask 24 (FIG. 7D).

[0103] By the above steps i) to iv), the cover plate 10 having the structure shown in FIG. 6 can be manufactured.

[0104] According to a particularly preferred embodiment of the method, a further step v) is optionally performed:

[0105] Step v) Now, at least another optical interference layer 16' that reflects light within a particular wavelength range is applied to a second region 23 of inner surface 13 and is at least partially, and particularly completely, applied to the previously applied optical interference layer 16. Cover plate 10 thus formed is shown in Figure 7E.

[0106] The first optical interference layer 16, which is only partially applied in the first region 22, provides a local color effect of the cover plate 10 corresponding to the reflection of light within a predetermined wavelength range of the optical interference layer 16. In the mounted state of the cover plate 10, the color of the flat body 1 in the first region 22 is generated by a combination of the color adjusted by the first optical reflective layer 16 and the background color of the rear element 21.

[0107] 5 and 6, first optical interference layer 16 is absent in second region 23. With cover plate 10 attached, the local color effect in second region 23 is primarily due to the background color of rear element 21, which can be seen through transparent cover plate 10.

[0108] In the embodiment of Fig. 7E, the second region 23 includes an additional (second) optical interference layer 16'. In the first region 22, two optical interference layers 16, 16' are superimposed. In the mounted state of the cover plate 10, the color of the flat body 1 in the second region 23 is generated by a combination of the color due to the optically reflective layer 16' and the background color of the rear element 21. In the first region 22, the color is generated by a combination of the color due to the two light-reflective layers 16, 16' superimposed on each other and the background color of the rear element 21.

[0109] As shown in FIG. 7A', cover plate 10 may have at least one more (third) optical interference layer 16'', which may be applied over the entire surface, particularly to outer surface 11 and / or inner surface 13. Third optical interference layer 16'' is applied to first region 22 and second region 23 of inner surface 13. Third optical interference layer 16'' may be provided as an alternative or complement to second optical interference layer 16'.

[0110] In all embodiments, the surface of the flat body 1 may have two colors, as shown in Fig. 9 in the view of the flat body 1 with the cover plate 10. This allows patterns (here bars) or letters (here "A-3") encoding information, in particular text, to stand out against a background of a different color. In Fig. 9, the observer is looking at the cover plate 10 from above.

[0111] In the embodiment of the cover plate 10 of Figs. 5 and 6, the first color in the first region 22 is generated from the combination of the color effect of the optical interference layer 16 and the background color of the rear element 21, and the second color in the second region 23 is generated from the background color of the rear element 21. The color in the first region 22 can be freely selected. When constructing the cover plate 10 of Fig. 7E, the first color in the first region 22 is generated from the combination of the color effect of the two optical interference layers 16, 16' and the background color of the rear element 21, and the second color in the second region 23 is generated from the combination of the color effect of the later applied optical interference layer 16' and the background color of the rear element 21. Both the first color in the first region 22 and the second color in the second region 23 can be selected in a large color space within the limits of physical freedom (layer thickness, refractive index). In FIG. 9, the pattern and text correspond to the second region 23 and the background of a different color corresponds to the first region 22, but the same is true when the pattern and text correspond to the first region 22 and the background of a different color corresponds to the second region 23.

[0112] In the following, the structuring function of the outer surface 11 of the cover plate 10 will be explained in more detail. First, consider FIG. 10, in which a typical lighting condition of a flat body 1 configured as an exterior element is shown. According to this, light from the sun S is directly irradiated on the cover plate 10 and is reflected at the gloss angle (angle of incidence = angle of reflection, relative to the surface normal of the cover plate plane). An incident light beam E and a beam R reflected at the gloss angle are shown. In addition to the reflected light beam R, due to the structure according to the invention on at least one structured side, inside or outside, and the interference layer on the inside, the incident light is also diffusely scattered outside the gloss angle. Two diffusely scattered light beams R' are shown as an example. The color effect is the result of reflection, scattering and interference. If an observer B stands in front of the flat body 1 and looks perpendicularly at the cover plate 10 in front of it, his eyes rarely encounter the directly reflected light R (i.e., the observer is usually not standing at the gloss angle). This is shown in FIG. 10, in which observer B is outside the gloss angle and can only see the diffusely scattered light beam R'. On a smooth cover plate without inner or outer structured regions, the intensity of the diffusely scattered light beam R' is relatively low and shows a very strong angular dependence. Only if the diffusely scattered portion is sufficiently large can bright colors with a satisfactory intensity (brightness, L value) be obtained.

[0113] The basic principle of the operating mode of the inclined segments 17 of the structured area 15 is shown in FIG. 11, which shows, as an example, different light paths of an observer B looking perpendicularly at the glass or outer surface 11 of the flat body 1. Three segments 17 with different inclinations relative to the diagrammatically shown plane GE of the cover plate 10 and a light ray E irradiated to the segments 17 are shown, which is reflected in all cases by the segments 17 at a local gloss angle to the observer B (reflected ray R). The central segment 17 is arranged parallel to the plane GE, whereby the incident light beam E is irradiated perpendicularly to the segment 17 and is reflected perpendicularly to the observer B (reflected ray R). For the central segment 17, the gloss angle and the local gloss angle are identical. For two adjacent segments 17, the incident ray E each has an angle different from zero relative to the surface normal on the plane GE and is also irradiated to the observer B at a local gloss angle. Due to the different inclination angles of the segments 17, light from different directions is reflected to an observer B looking perpendicularly at the module surface, in each case at the local gloss angle of the segments 17. In the example of Figure 11, the angles of incidence and reflection are at most 45°.

[0114] In FIG. 12, observer B is shown observing the plane GE of the cover plate 10 at an angle of 45° to its surface normal. As shown in FIG. 11, three segments 17 with different inclinations to the plane GE of the cover plate 10 are shown as an example with a ray E incident on the segment 17, which is reflected by the segment 17 at a local glancing angle to observer B (reflected ray R). Due to the different inclination angles of the segments 17, light from different directions is reflected at a local gloss angle to observer B. In the example of FIG. 12, the incidence angle and reflection angle are up to 67.5°. Basically, if the value of the gloss angle is relatively large, the reflected light n is shifted towards shorter wavelengths. Such a spectral shift can be reduced, for example, by a higher refractive index of the optical interference layer. However, the effect on the color seen by the human eye depends on a complex weighting of the spectrum to the sensitivity curve of the human eye. In the case of a relatively steep surface inclination, multiple reflections may occur at adjacent facets.

[0115] FIG. 13 shows the state in which the light source and accordingly the incident light are always inclined at an angle of 45° to the plane GE of the cover plate 10. Observer B observes the surface of the flat body 1 at a different angle. The angles shown in FIG. 13 should be understood as follows: the angle of incidence (with respect to the plane GE of the cover plate 10) / angle of observation or the angle of reflection (deviation from the gloss angle with respect to the surface normal on the plane GE). The degree letter "°" is not specified. FIG. 13 shows an example of four segments 17 with different inclinations with respect to the plane GE. Only in one segment 17 with a plane parallel to the plane of the cover plate 10, observer B is located at the gloss angle with respect to the plane GE: 45 / 0. This means that the angle of the incident light beam with respect to the GE plane is 45° and the angular deviation of the reflected light beam with respect to the gloss angle is zero. For the other segments 17, observer B is outside the gloss angle. In the two left segments 17 (45 / 90, 45 / 45), the observer views the surface of the flat body 1 at angles of 90° and 45° to the gloss angle, respectively, and the light is incident at an angle of 45° to the plane GE. In the right segment 17 (45 / -15), the observer is at an angle of -15° to the glancing angle. Due to the differently inclined segments 17 and the resulting reflections within the local gloss angle, the light is reflected with sufficient intensity towards observer B, even if the observer is not located within the gloss angle with respect to the plane GE of the cover plate 10.

[0116] FIG. 14 shows that observer B always observes the surface of the flat body 1 at an angle of 45° to the module surface or plane GE of the cover plate 10. FIG. 14 shows an example of four segments 17 with different inclinations to the plane GE. Only in one segment 17 with a plane parallel to the plane GE, observer B is located at the gloss angle: 45 / 0. In the other segments 17, observer B is located outside the gloss angle. In the two left segments 17 (45 / 90, 45 / 45), observer B observes the surface of the flat body 1 at an angle of 45°, so that light is incident with a deviation of 90° or 45° to the gloss angle. In the right segment 17 (45 / -15), light is incident at an angle of -15° to the gloss angle. Due to the different inclinations of the segments 17 and the resulting reflections within the local gloss angle, light is reflected with sufficient intensity towards observer B even if it is incident outside the gloss angle.

[0117] In the flat body 1 according to the present invention, the outer surface 11 of the cover plate 10 is structured in combination with at least one color-forming optical interference layer 16, 16', thereby making it possible to achieve a uniform color impression in a specifiable wavelength range, whereby the angular dependence of the color impression is significantly smaller than in unstructured surfaces.

[0118] FIG. 15 shows the reflection at the optical interference layer 16, 16' with layer thickness d. An incident light beam E is reflected at both the interface air interference layer (R1) and the interface interference layer-cover plate (R2). If the optical path difference of the two light beams R1, R2 is a multiple of the wavelength of the incident light beam, constructive interference occurs, whereas if the optical path difference is a multiple of 1 / 2 wavelength, destructive interference occurs. When illuminated with white light, the optical interference layer 9 acts as a color filter, since constructive interference occurs only for light of the appropriate wavelength, depending on the refractive index n and the layer thickness d. Here, α is the angle of the reflected rays R1, R2 to the surface normal. The ray R' illustrates the reflection of light outside the gloss angle, which may occur in the structured area 15 if the interface between the interference layer and the cover plate is too rough. To satisfy the interference condition, the scattering center must be smaller than the wavelength and the layer thickness. This can be achieved by a minimum surface area of ​​the segments 17 and their maximum roughness, as claimed in the present invention.

[0119] If the outer surface 11 of the cover plate 10 is coated with an optical interference layer 16 made of an inorganic, chemically inert and hard layer such as Si3N4, the flat body 1 can be made highly scratch-resistant, chemically resistant and anti-pollution. Also, a self-cleaning effect can be obtained by using a photocatalytic layer such as TiO2. Climate tests have also shown that interference layers of materials such as Si3N4 and TiO2 also prevent corrosion of the glass cover plate due to high temperature and humidity.

[0120] With reference to FIG. 16, an embodiment of the cover plate 1 is shown. To avoid unnecessary repetition, only the differences from the embodiment of FIG. 5 are described, otherwise reference is made to the above description. In this embodiment, the structured area 15 of the outer surface 11 has a first area 25 and a second area 26. Here, the first area 25 is configured such that the segments 17 have an average roughness less than 15% of the layer thickness d of the optical interference layer 16 on the outer surface 11. In the embodiment of FIG. 5, this applies to the entire structured area 15. Conversely, the average roughness in the second area 26 is high enough to prevent interference in the optical interference layer 16. For example, the average roughness of the segments 17 in the second area 26 is greater than 50% of the layer thickness of the optical interference layer 16. Thereby, due to the color filter effect of the optical interference layer 16, the flat body 1 has a uniform color in the first area 25. In the second region 26, the optical interference layer 16 does not have a color filter effect due to the lack of constructive interference, so that there is essentially a surface corresponding to the flat body 1 where the optical interference layer 16 is not present. This allows the flat body 1 to obtain a uniform color in the first region 25. In FIG. 16, the second region 16 is shown diagrammatically by a greater roughness. For simplicity, the first region 22, which does not include the optical interference layer 16, is not shown. This description is equally applicable to at least one other optical interference layer 16'.

[0121] The function of the structured outer surface 11 in combination with the inner interference layer 16 according to the embodiment of FIG. 6 is shown in detail in FIG. 17. For simplicity, the first area 22, which does not include the optical interference layer 16, is not shown. An example of different light paths for segments 17 of the cover plate 10 with different inclinations is shown. As an example, three segments 17 are shown, the right segment 17 is parallel to the plane of the cover plate 10, and the other two segments 17 have angles different from zero to the plane of the cover plate 10. The reflection of the light rays at the interference layer 16 is shown in a simplified form. The reflection at the interference layer 16 is explained in relation to FIG. 12. FIG. 17 shows the light paths of three light beams that are incident on segments 17 of the outer surface 11 of the cover plate 10 with different inclinations at the same angle to the normal to the plane of the cover plate 10. The respective normals to the segments 17 are shown with dashed lines. The segments 17 with different inclinations cause the light rays to be reflected in different ways. The first light beam 1-1 is irradiated to the segment 17, passes through the cover plate 2 as a refracted light beam 1-2, is reflected by the interference layer 16 as a light beam 1-3 (within the gloss angle), and leaves the cover plate 10 as a refracted light beam 1-4 towards the external environment. The light beam 1-4 finally reflected by the cover plate 10 has a different angle with respect to the normal to the plane of the cover plate 10 than the incident light beam 1-1, so it is scattered without reflection at the gloss angle. Similarly, the second light beam 2-1 is irradiated to another segment 17, passes through the cover plate 2 as a refracted light beam 2-2, is reflected by the interference layer 16 as a light beam 2-3, and leaves the cover plate 10 as a refracted light beam 2-4 towards the external environment. The reflected light beam 2-4 leaves the cover plate 10 in a direction approximately opposite to the incident direction of the light beam 2-1, also in a scattering manner, not a reflection within the gloss angle. The third light beam 3-1 is incident on another segment 17, passes through the cover plate 10 as refracted light beam 3-2, is reflected by the interference layer 16 as light beam 3-3, and emerges from the cover plate 10 towards the external environment as refracted light beam 3-4. This segment 17 is parallel to the plane of the cover plate 10 so that the light beams 2-4 are reflected within the gloss angle.As a result of refraction at the respective segments 17 and subsequent reflection at the interface with the interference layer 16 and further refraction at the structured surface, those segments 17 inclined relative to the plane of the cover plate 10 cause a strong overall reflection outside the gloss angle (relative to the plane of the cover plate 2) so that in combination with the interference layer 16, a color effect of the reflected light is obtained even outside the gloss angle of the glass plane. Figure 17 shows an example of a position of the observer B outside the gloss angle. Due to the relatively strongly (diffuse) scattering cover plate 10 with the external structuring and the inner interference layer, there is usually a suitable light path for different viewing angles outside the gloss angle, already passing through the interference layer. This results in a less directional color impression compared to conventional modules without structured areas 15.

[0122] FIG. 18 shows a measuring device for determining the diffuse scattering of a flat body 1 by a commercial multi-angle colorimeter 20 (multi-angle colorimetry) according to the invention. A structured area 15, not shown in detail, extends over the entire cover plate 10 (e.g. glass). Here, a light beam is directed to the outer surface 11 of the flat body 1 and characterized at different angles of incidence, and the scattered or reflected light is measured spectrally from different observation angles, for example 15° (related to the gloss angle). For example, at an observation angle of 45° (measured relative to the surface normal) and an incidence angle of 45° (measured from the gloss angle), the incident light is completely perpendicular to the surface (45 / 45). At an observation angle of 15° and an incidence angle of 45°, the incidence direction at 30° from the surface normal is on the same side as the observation direction (15 / 45). The multi-angle colorimeter 20 is positioned at an observation angle of 45° or 15° relative to the surface normal.

[0123] As can be seen from the above description of the invention, the invention provides an improved cover plate with at least two very uniform and strong colors with little or no directional dependency, a flat body with an improved cover plate, and a method for manufacturing the same. The surface of the flat body may be provided with at least two colors to display colored patterns or characters that code information on backgrounds of different colors. The active and passive flat bodies can be produced cost-effectively in various shapes and sizes and can be used as integrated components of architectural or freestanding walls, in particular as exterior elements. The active and passive flat bodies can be beautifully combined as exterior elements. Multicolored solar modules (colored by interference layers, in particular CIGS thin-film solar modules) can be advantageously provided, whereby uniform color effects of the exterior can be achieved. In the case of active flat bodies, a loss of efficiency is acceptable. For passive flat bodies, the semiconductor layer stack can be replaced by other cheaper materials and other elements such as junction boxes, edge sealing, contact strips, cables, etc. can be eliminated. The invention is particularly advantageous for producing multicolored accessories, which are particularly required for transitions to openings or edges of buildings. The passive surface elements can give approximately the same color impression as the solar modules under different lighting conditions. If non-rectangular exterior elements are required to complement the solar modules, the passive flat bodies can be produced much more cost-effectively than the solar modules. The present invention therefore provides an advantageous improvement that allows the production of multi-color flat bodies with relatively low efficiency losses as active flat bodies. In particular, it is possible to use active and passive flat bodies as exterior elements in an aesthetic way. [Explanation of symbols]

[0124] 1 flat body 2. Board 3 layer structure 4. Sunlight 5 Back electrode layer 6 Absorber layer 7 Buffer Layer 8 Front electrode layer 9 Adhesive layer 10 Cover plate 11 Exterior 12. Solar Cells 13. Inside 14 Module rear side 15 Structured area 16, 16' Optical interference layer 17 Segments 19 Opaque Coating 20 Multi-angle colorimeter 21 Rear element 22 First area 23 Second area 24 Mask 25 Area 1 26 Second area 27 Outside 28 Inside

Claims

1. A method for processing a transparent cover plate (10) for a flat body (1), comprising the steps of: a) providing a transparent cover plate (10) having an outer side (27) facing an external environment and an opposite inner side (28), said cover plate (10) comprising a structured area (15) having a light diffusing structure on at least one outer surface (11) of said cover plate (10) selected from an outer surface (11) of said cover plate (10) and an inner surface (13) connected to a solar cell (12) via an adhesive layer (9), said inner surface (13) being free of a structured area (15); b) forming at least one first optical interference layer (16) on a portion of an interior side (28) of the cover plate (10); b1) applying a mask (24) to a portion of the inner surface (13) of the cover plate (10), such that, in a vertical view through the cover plate (10), the mask (24) does not cover a first region (22) of the inner surface (13) on the cover plate side (28) and covers a second region (23) adjacent to the first region (22) on the inner surface (13) on the cover plate side (28), the first region (22) and the second region (23) being arranged to overlap the structured region (15) which may be further formed; b2) applying at least one first optical interference layer (16) configured to reflect light within a predetermined wavelength range to an inner surface (13) of the cover plate (10) on the selected cover plate side (28), the first optical interference layer (16) being applied to overlap the mask (24) in a vertical view through the cover plate (10) and to the first region (22) of the inner surface (13) of the cover plate; b3) removing the mask (24), thereby removing the first optical interference layer (16) overlapping the mask (24) when viewed vertically, so that only the first optical interference layer (16) applied to the first region (22) remains; applying at least one more second optical interference layer (16') configured to reflect light within a predetermined wavelength range to the selected cover plate (10) on the inner surface (13) of the cover plate (10), the second optical interference layer (16') overlapping the first optical interference layer (16) in a first region (22) of the cover plate surface (13) and covering a second region (23) when viewed vertically through the cover plate (10); As a result, the color in the first region (22) is generated by a combination of the color from the first optical interference layer (16) and the second optical interference layer (16') and the background color of the solar cell (12), and the color in the second region (23) is generated by a combination of the color from the second optical interference layer (16') and the background color of the solar cell (12).

2. 2. The method of claim 1, further comprising providing a cover plate (10) having, on a selected cover plate side (27, 28), at least one more third optical interference layer (16'') configured to reflect light within a predetermined wavelength range, the third optical interference layer (16'') covering a first region (22) and a second region (23) of a cover plate surface (13) on the selected cover plate side (27, 28) when viewed perpendicularly through the cover plate (10).

3. The formation of the at least one first optical interference layer (16) is repeated one or several times. The method according to claim 1 or 2.

4. 2. The method of claim 1, wherein the cover plate (10) has at least two of the first (16), second (16') optical interference layers having different refractive indices and / or layer thicknesses.

5. The structured area (15) comprises: - perpendicular to the plane of said cover plate (10), it has a height profile with peaks and valleys, the average height difference between said peaks and said valleys being at least 2 μm; at least 50% of the structured area (15) are made up of segments (17) inclined relative to the plane of the cover plate (10), at least 20% of the segments (17) having an inclination angle lying in the range of more than 0° and up to a maximum of 15° and at least 30% of the segments (17) having an inclination angle lying in the range of more than 15° and up to a maximum of 45° relative to the plane of the cover plate (10); 5. The method according to claim 1, wherein the first and second electrodes are connected to a first electrode.

6. a) at least 80% of the structured area (15) consists of segments (17) inclined with respect to the plane of the cover plate (10); and / or b1) at least 30% of the segments (17) have an inclination angle in the range of greater than 0° and up to 15°, at least 40% of the segments (17) have an inclination angle in the range of greater than 15° and up to 45°, and less than 10% of the segments (17) have an inclination angle greater than 45°, or b2) The method according to claim 5, wherein at least 40% of the segments (17) have an inclination angle in the range of greater than 0° and up to 15°, at least 50% of the segments (17) have an inclination angle in the range of greater than 15° and up to 45°, and less than 10% of the segments (17) have an inclination angle greater than 45°.

7. 7. The method according to claim 5, wherein the average elevation difference between the peaks and the valleys is at least 50 μm or at least 100 μm.

8. A method for manufacturing a flat body (1), said method comprising a method for processing a transparent cover plate (10) according to one of the claims 1 to 7.

Images