Carbon Dioxide Capture System

Abstract

To provide a carbon dioxide recovery system that can improve purity of a carbon dioxide to be recovered.SOLUTION: A carbon dioxide recovery system comprises: an electrochemical cell 101 having an action electrode 102 and a counter electrode 103, in which electrons are supplied from the counter electrode 103 to the action electrode 102 by applying a voltage between the action electrode 102 and the counter electrode 103, and the action electrode 102 combines with a carbon dioxide accompanied by the supply of the electrons; an adsorption unit 100 into which a carbon dioxide-containing gas is introduced along with the accommodation of the electrochemical cell 101; supply units 142 and 143 that supply a liquid into the adsorption unit 100 in a state that the voltage is applied between the action electrode 102 and the counter electrode 103; and discharge units 1b, 144, and 145 that discharge the liquid supplied from the supply units 142 and 143 and a carbon dioxide-removed gas from the adsorption unit 100 in the state that the voltage is applied between the action electrode 102 and the counter electrode 103.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a carbon dioxide capture system that captures carbon dioxide from a carbon dioxide-containing gas that contains carbon dioxide. [Background technology]

[0002] Patent Document 1 proposes a gas separation system that separates carbon dioxide from a carbon dioxide-containing gas by an electrochemical reaction. In the gas separation system of Patent Document 1, a carbon dioxide adsorbent capable of adsorbing carbon dioxide is provided on the working electrode of an electrochemical cell. The carbon dioxide adsorbent is an electroactive species, and by changing the potential difference between the working electrode and the counter electrode, it is possible to switch between adsorption and release of carbon dioxide by the carbon dioxide adsorbent. [Prior art documents] [Patent documents]

[0003] [Patent Document 1] Special Publication No. 2018-533470 Summary of the Invention [Problem to be solved by the invention]

[0004] However, in the configuration of Patent Document 1, there is a possibility that gases other than carbon dioxide (e.g., nitrogen, oxygen, etc.) that are present around the working electrode may also be collected during carbon dioxide collection, which may result in a decrease in the purity of the collected carbon dioxide.

[0005] In view of the above, an object of the present invention is to provide a carbon dioxide capture system capable of improving the purity of captured carbon dioxide. [Means for solving the problem]

[0006] In order to achieve the above object, the carbon dioxide recovery system according to claim 1 is a carbon dioxide recovery system that separates carbon dioxide from a carbon dioxide-containing gas that contains carbon dioxide by an electrochemical reaction, an electrochemical cell (101) having a working electrode (102) and a counter electrode (103), in which, when a voltage is applied between the working electrode and the counter electrode, electrons are supplied from the counter electrode to the working electrode, and the working electrode combines with carbon dioxide as the electrons are supplied; an adsorption section (100) in which an electrochemical cell is housed and into which a carbon dioxide-containing gas is introduced; a supply unit (142, 143) that supplies a liquid into the adsorption unit while a voltage is applied between the working electrode and the counter electrode; and an exhaust section (1b, 144, 145) that exhausts, from the adsorption section, the liquid supplied from the supply section and the carbon dioxide-removed gas obtained after carbon dioxide is separated from the carbon dioxide-containing gas, while a voltage is applied between the working electrode and the counter electrode. 、 The working electrode has an electrode substrate (102a) and a carbon dioxide adsorbent (102b), When a voltage is applied between the working electrode and the counter electrode, electrons are supplied from the counter electrode to the working electrode, and the carbon dioxide adsorbent bonds with carbon dioxide as the electrons are supplied. The carbon dioxide adsorbent is covered with a covering material (102c). .

[0007] According to this, by providing the supply parts (142, 143) and the discharge parts (1b, 144, 145), the carbon dioxide-removed gas can be discharged together with the liquid from the adsorption part (100). As a result, the purity of carbon dioxide in the adsorption part (100) can be increased, and the purity of the recovered carbon dioxide can be improved.

[0008] In addition, the reference symbols in parentheses for each means described in this column and in the claims indicate the correspondence with the specific means described in the embodiments described later. [Brief description of the drawings]

[0009] [Figure 1] 1 is an overall configuration diagram showing a carbon dioxide capture system according to a first embodiment. [Diagram 2] FIG. 1 is an explanatory diagram showing a carbon dioxide capture device in a first embodiment. [Diagram 3] FIG. 1 is an explanatory diagram showing an electrochemical cell in a first embodiment. [Figure 4] FIG. 1 is a cross-sectional view showing an electrochemical cell in a first embodiment. [Diagram 5] FIG. 2 is an explanatory diagram showing a working electrode in the first embodiment. [Figure 6] FIG. 2 is an enlarged cross-sectional view of the periphery of the surface of a working electrode in the first embodiment. [Figure 7] FIG. 2 is an explanatory diagram showing an adsorption portion in the first embodiment. [Figure 8] 4 is a time chart showing an example of a result of a control process executed by the control device of the carbon dioxide capture system according to the first embodiment. [Figure 9] FIG. 2 is an explanatory diagram for explaining the operation of the carbon dioxide capture device in a carbon dioxide adsorption mode in the first embodiment. [Figure 10] FIG. 2 is an explanatory diagram for explaining the operation of the carbon dioxide capture device in a carbon dioxide capture mode in the first embodiment. [Figure 11] FIG. 11 is an explanatory diagram showing an adsorption portion in a second embodiment. [Figure 12] FIG. 13 is an explanatory diagram showing an adsorption portion in a third embodiment. [Figure 13] FIG. 13 is an explanatory diagram showing a carbon dioxide capture device in a fourth embodiment. [Figure 14] FIG. 2 is an explanatory diagram showing an electrochemical cell in another embodiment (1). DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0010] Hereinafter, embodiments of the present invention will be described with reference to the drawings. In the following embodiments, the same or equivalent parts are denoted by the same reference numerals in the drawings.

[0011] (First embodiment) A first embodiment for carrying out the present invention will be described with reference to Figures 1 to 10. As shown in Figure 1, a carbon dioxide capture system 1 of this embodiment is provided with a compressor 11, a carbon dioxide capture device 10, a flow path switching valve 12, a carbon dioxide utilization device 13, a liquid circuit 14, and a control device 15.

[0012] The compressor 11 pumps the carbon dioxide-containing gas to the carbon dioxide capture device 10. The carbon dioxide-containing gas is a mixed gas containing carbon dioxide and a gas other than carbon dioxide, and may be, for example, the atmosphere or exhaust gas from an internal combustion engine. The compressor 11 has its rotation speed (i.e., pumping capacity) controlled by a control voltage output from the control device 15.

[0013] The carbon dioxide capture device 10 is a device that separates and captures carbon dioxide from a carbon dioxide-containing gas. The carbon dioxide capture device 10 discharges a carbon dioxide-removed gas after carbon dioxide is captured from the carbon dioxide-containing gas, or carbon dioxide captured from the carbon dioxide-containing gas. The configuration of the carbon dioxide capture device 10 will be described in detail later.

[0014] The flow path switching valve 12 is a three-way valve that switches the flow path of the exhaust gas from the carbon dioxide capture device 10. When carbon dioxide removed gas is discharged from the carbon dioxide capture device 10, the flow path switching valve 12 switches the flow path of the exhaust gas to the atmosphere side, and when carbon dioxide is discharged from the carbon dioxide capture device 10, it switches the flow path of the exhaust gas to the carbon dioxide utilization device 13 side. The operation of the flow path switching valve 12 is controlled by a control voltage output from the control device 15.

[0015] The carbon dioxide utilization device 13 is a device that utilizes carbon dioxide. For example, a storage tank that stores carbon dioxide or a conversion device that converts carbon dioxide into fuel can be used as the carbon dioxide utilization device 13. The conversion device can be a device that converts carbon dioxide into a hydrocarbon fuel such as methane. The hydrocarbon fuel may be a gas fuel at normal temperature and pressure, or a liquid fuel at normal temperature and pressure.

[0016] The liquid circuit 14 circulates the liquid through the carbon dioxide capture device 10. Hereinafter, the liquid circulating through the liquid circuit 14 will be referred to as the circulating liquid. As the circulating liquid, a liquid that is non-chemically reactive and insoluble with respect to carbon dioxide can be used. The configuration of the liquid circuit 14 will be described in detail later.

[0017] The control device 15 is composed of a well-known microcomputer including a CPU, ROM, RAM, etc., and its peripheral circuits. The control device 15 performs various calculations and processes based on a control program stored in the ROM, and controls the operation of various controlled devices. The control device 15 corresponds to an example of a control unit.

[0018] Various controlled devices are connected to the output side of the control device 15. The various controlled devices include the compressor 11, the carbon dioxide capture device 10, the flow path switching valve 12, and components of the liquid circuit 14 (i.e., the liquid supply pump 143 and the liquid discharge pump 145 described later).

[0019] Next, the carbon dioxide capture device 10 will be described with reference to Fig. 2 and Fig. 3. As shown in Fig. 2, the carbon dioxide capture device 10 has an adsorption unit 100 and an electrochemical cell 101. The adsorption unit 100 is a container that houses the electrochemical cell 101. A carbon dioxide-containing gas and a circulating liquid are introduced into the adsorption unit 100.

[0020] The adsorption unit 100 is provided with a gas inlet 100a, a gas outlet 100b, a liquid inlet 100c, and a liquid outlet 100d. The gas inlet 100a allows the carbon dioxide-containing gas to flow into the adsorption unit 100. The gas outlet 100b allows the carbon dioxide-removed gas and carbon dioxide to flow out from the adsorption unit 100. The liquid inlet 100c allows the circulating liquid to flow into the adsorption unit 100. The liquid outlet 100d allows the circulating liquid to flow out from the adsorption unit 100.

[0021] A gas supply flow path 1a is connected to the gas inlet 100a. The gas supply flow path 1a connects the discharge port side of the compressor 11 to the gas inlet 100a, and supplies the carbon dioxide-containing gas discharged from the compressor 11 to the adsorption section 100.

[0022] The gas outlet 100b is connected to a gas exhaust passage 1b. The gas exhaust passage 1b connects the gas outlet 100b to the inlet side of the passage switching valve 12, and guides the carbon dioxide-removed gas and carbon dioxide exhausted from the adsorption unit 100 to the inlet side of the passage switching valve 12.

[0023] As shown in Fig. 3, an electrochemical cell 101 has a working electrode 102, a counter electrode 103, and an insulating layer 104. In the example shown in Fig. 3, the working electrode 102, the counter electrode 103, and the insulating layer 104 are each configured in a plate shape. Note that in Fig. 3, the working electrode 102, the counter electrode 103, and the insulating layer 104 are illustrated with a gap between them, but in reality, these components are arranged so as to be in contact with each other.

[0024] The carbon dioxide capture device 10 adsorbs and desorbs carbon dioxide through an electrochemical reaction, and separates and captures carbon dioxide from a carbon dioxide-containing gas. The carbon dioxide capture device 10 has a power source 105, which is a voltage application unit that applies a predetermined voltage to the working electrode 102 and the counter electrode 103, and can change the potential difference between the working electrode 102 and the counter electrode 103. The working electrode 102 is a negative electrode, and the counter electrode 103 is a positive electrode.

[0025] In the electrochemical cell 101, when a voltage is applied between the working electrode 102 and the counter electrode 103, electrons are supplied from the counter electrode 103 to the working electrode 102, and the working electrode 102 (more specifically, the carbon dioxide adsorbent 102b described later) bonds with carbon dioxide as the electrons are supplied.

[0026] The electrochemical cell 101 can be operated in a carbon dioxide adsorption mode in which carbon dioxide is adsorbed onto the working electrode 102, and a carbon dioxide capture mode in which carbon dioxide is captured from the working electrode 102, by changing the potential difference between the working electrode 102 and the counter electrode 103. The carbon dioxide adsorption mode is a charge mode in which the electrochemical cell 101 is charged, and the carbon dioxide capture mode is a discharge mode in which the electrochemical cell 101 is discharged.

[0027] In the carbon dioxide adsorption mode, a first voltage V1 is applied between the working electrode 102 and the counter electrode 103, and electrons are supplied from the counter electrode 103 to the working electrode 102. At the first voltage V1, the working electrode potential is smaller than the counter electrode potential. The first voltage V1 can be set within a range of 0.5 to 2.0 V, for example.

[0028] In the carbon dioxide capture mode, a low second voltage V2 is applied between the working electrode 102 and the counter electrode 103, and electrons are supplied from the working electrode 102 to the counter electrode 103. The second voltage V2 may be any voltage lower than the first voltage V1, and the magnitude relationship between the working electrode potential and the counter electrode potential is not limited. That is, in the carbon dioxide capture mode, the working electrode potential may be less than the counter electrode potential, the working electrode potential may be equal to the counter electrode potential, or the working electrode potential may be greater than the counter electrode potential.

[0029] As shown in Fig. 4, the working electrode 102 is provided with a working electrode side substrate 102a and a carbon dioxide adsorbent 102b. For convenience, in Fig. 4, the carbon dioxide adsorbent 102b is illustrated as being located on the outside of the working electrode side substrate 102a, but in reality, the carbon dioxide adsorbent 102b is provided inside the porous working electrode side substrate 102a. The working electrode side substrate 102a corresponds to an example of an electrode substrate.

[0030] The working electrode substrate 102a is a porous conductive material that allows carbon dioxide to pass through. For example, a carbonaceous material or a metal material can be used as the working electrode substrate 102a. For example, carbon paper, carbon cloth, nonwoven carbon mat, porous gas diffusion layer (GDL), etc. can be used as the carbonaceous material constituting the working electrode substrate 102a. For example, a mesh structure of a metal (e.g., Al, Ni, etc.) can be used as the metal material constituting the working electrode substrate 102a.

[0031] The carbon dioxide adsorbent 102b has redox activity and is an electroactive species capable of reversibly causing an oxidation-reduction reaction. The carbon dioxide adsorbent 102b can bind and adsorb carbon dioxide in a reduced state and can release carbon dioxide in an oxidized state.

[0032] The carbon dioxide adsorbent 102b has a functional group that bonds with carbon dioxide. The functional group that bonds with carbon dioxide gives and receives electrons to become a carbon dioxide adsorption site. Examples of the functional group that bonds with carbon dioxide include functional groups containing elements with high electronegativity (F, O, N, Cl, S, etc.), and for example, a ketone group (C=O) can be used.

[0033] Furthermore, in this embodiment, the carbon dioxide adsorbing material 102b has no affinity for the circulating liquid. Specifically, the carbon dioxide adsorbing material 102b contains an amine compound.

[0034] A working electrode side binder 102c is provided between the working electrode side substrate 102a and the carbon dioxide adsorbing material 102b. The working electrode side binder 102c has an adhesive force and holds the carbon dioxide adsorbing material 102b to the working electrode side substrate 102a.

[0035] The working electrode side binder 102c is a conductive material having electrical conductivity, which ensures the transfer of electrons between the working electrode side base material 102a and the carbon dioxide adsorbing material 102b.

[0036] The carbon dioxide adsorbent 102b is held inside the working electrode-side binder 102c. That is, the carbon dioxide adsorbent 102b is covered with the working electrode-side binder 102c. Therefore, the working electrode-side binder 102c corresponds to an example of a covering material. The carbon dioxide adsorbent 102b can be firmly held by the working electrode-side binder 102c.

[0037] The working electrode side binder 102c of this embodiment has carbon dioxide permeability that allows carbon dioxide to pass through. Furthermore, the working electrode side binder 102c of this embodiment has carbon dioxide selective permeability that allows carbon dioxide to selectively pass through among a plurality of types of gases contained in the carbon dioxide-containing gas. In addition, the working electrode side binder 102c of this embodiment has non-affinity for the circulating liquid.

[0038] As shown in Fig. 5, carbon dioxide contained in the carbon dioxide-containing gas can permeate the working electrode side binder 102c and reach the carbon dioxide adsorbent 102b present inside the working electrode side binder 102c. On the other hand, gases other than carbon dioxide contained in the carbon dioxide-containing gas (nitrogen, oxygen, etc.) cannot permeate the working electrode side binder 102c having carbon dioxide selective permeability. Furthermore, the circulating liquid does not penetrate into the working electrode side binder 102c having no affinity for the circulating liquid.

[0039] A non-fluid substance having no fluidity can be used as the working electrode side binder 102c. Examples of the non-fluid substance include a gel substance or a solid substance. Examples of the gel substance include an ionic liquid gel. Examples of the solid substance include a solid electrolyte or a conductive resin.

[0040] When a solid electrolyte is used as the working electrode side binder 102c, it is preferable to use an ionomer made of a polymer electrolyte or the like in order to increase the contact area with the carbon dioxide adsorbent 102b. When a conductive resin is used as the working electrode side binder 102c, an epoxy resin containing Ag or the like as a conductive filler, or a fluororesin such as polytetrafluoroethylene (PTFE) or polyvinylidene fluoride (PVDF) can be used.

[0041] The raw material of the working electrode side binder 102c may be a liquid substance having fluidity. In this case, the carbon dioxide adsorbent 102b may be dispersed or mixed in the raw material of the working electrode side binder 102c, and may be attached to the working electrode side base material 102a by impregnation, coating, or the like. Thereafter, the raw material of the working electrode side binder 102c may be gelled or solidified under a predetermined condition. The predetermined condition may be a specific pressure, a specific temperature, a specific time, or the like, that can gel or solidify the raw material of the working electrode side binder 102c.

[0042] 6, the working electrode side binder 102c enters holes and gaps between the recesses and projections formed in the working electrode side base material 102a and is fixed there. The working electrode side binder 102c can generate a mechanical bonding force between the working electrode side binder 102c and the working electrode side base material 102a by an anchoring effect.

[0043] In this embodiment, an ionic liquid gel obtained by gelling an ionic liquid is used as the working electrode side binder 102c. The ionic liquid gel is a gel-like structure in which an ionic liquid is held in a polymer network structure.

[0044] As the ionic liquid gel, the structure disclosed in JP 2015-25056 A can be suitably used. In this structure, an ionic liquid is held in a three-dimensional network structure made of two different types of polymer chains. The three-dimensional network structure includes a first network structure formed by condensation polymerization and a second network structure formed by radical polymerization.

[0045] Tetraethoxyorthosilicate (TEOS) can be used as a monomer for condensation polymerization. TEOS also functions as a cross-linking agent for condensation polymerization.

[0046] As a monomer for radical polymerization, N,N-dimethylacrylamide (DMAAm) can be used. In radical polymerization, N,N'-methylenebisacrylamide (MBAA) can be used as a crosslinking agent, and 2,2'-azobis(isobutyronitrile) (AIBN) can be used as an initiator.

[0047] The ionic liquid constituting the ionic liquid gel functions as a solvent for the monomer constituting the first network structure and the monomer constituting the second network structure. After the first network structure and the second network structure are formed, the first network structure and the second network structure become entangled with each other, and the ionic liquid is contained in these network structures.

[0048] Examples of ionic liquids that can be used to form the ionic liquid gel include 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([EMIM][Tf2N]), 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([BMIM][Tf2N]), and 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF4]).

[0049] Returning to FIG. 4, the counter electrode 103 has a similar structure to the working electrode 102, and is provided with a counter electrode-side substrate 103a, an electroactive auxiliary material 103b, and a counter electrode-side binder 103c.

[0050] The counter electrode side substrate 103a is a conductive material, and may be made of the same material as the working electrode side substrate 102a or a different material. The counter electrode side binder 103c may be made of any material that can hold the electroactive auxiliary material 103b on the counter electrode side substrate 103a and has conductivity. The counter electrode side binder 103c may be made of the same material as the working electrode side binder 102c or a different material.

[0051] The electroactive auxiliary material 103b is an auxiliary electroactive species that has an opposite redox state to that of the carbon dioxide adsorbent 102b and transfers electrons between the carbon dioxide adsorbent 102b. As the electroactive auxiliary material 103b, for example, a metal complex that allows transfer of electrons by changing the valence of the metal ion can be used. Examples of such metal complexes include cyclopentadienyl metal complexes such as ferrocene, nickelocene, and cobaltocene, and porphyrin metal complexes.

[0052] The insulating layer 104 is disposed between the working electrode 102 and the counter electrode 103, and separates the working electrode 102 from the counter electrode 103. The insulating layer 104 prevents physical contact between the working electrode 102 and the counter electrode 103, and suppresses electrical short circuits.

[0053] A separator or a gas layer such as air can be used as the insulating layer 104. In this embodiment, a porous separator is used as the insulating layer 104. The separator may be made of a cellulose film, a polymer, a composite material of polymer and ceramic, or the like.

[0054] 4, an ion conductive member 106 is provided between the working electrode 102 and the counter electrode 103. The ion conductive member 106 is provided between the working electrode side substrate 102a and the counter electrode side substrate 103a with an insulating layer 104 interposed therebetween.

[0055] The ion conductive member 106 is in contact with the carbon dioxide adsorbent 102b inside the working electrode side substrate 102a. The ion conductive member 106 has ion conductivity and promotes conduction to the carbon dioxide adsorbent 102b. The ions contained in the ion conductive member 106 do not directly react with the functional groups contained in the carbon dioxide adsorbent 102b that bind to carbon dioxide.

[0056] A non-fluid substance having no fluidity can be suitably used for the ion conductive member 106. Examples of the non-fluid substance include a gel substance or a solid substance, such as an ionic liquid gel or a solid electrolyte. The ion conductive member 106 may be made of the same material as the working electrode side binder 102c, or may be made of a material different from that of the working electrode side binder 102c.

[0057] Next, the liquid circuit 14 will be described with reference to Figures 1 and 7. As shown in Figure 1, the liquid circuit 14 has a liquid tank 141, a liquid supply flow path 142, a liquid supply pump 143, a liquid discharge flow path 144, and a liquid discharge pump 145.

[0058] The liquid tank 141 is a tank that stores the circulating liquid. The liquid supply flow path 142 is a flow path that connects the outlet side of the liquid tank 141 and the liquid inlet 100c of the adsorption unit 100, and supplies the circulating liquid from the liquid tank 141 to the adsorption unit 100.

[0059] The liquid supply pump 143 is provided in the liquid supply flow path 142 and is a pump that pressure-feeds the circulating liquid from the liquid tank 141 to the adsorption unit 100. The rotation speed (i.e., pumping capacity) of the liquid supply pump 143 is controlled by a control voltage output from the control device 15.

[0060] The liquid discharge flow path 144 connects the liquid outlet 100d of the adsorption unit 100 and the inlet side of the liquid tank 141, and is a flow path for discharging the circulating liquid from the adsorption unit 100 to the liquid tank 141. In other words, the liquid discharge flow path 144 is a flow path for discharging the circulating liquid in the adsorption unit 100 to the outside of the adsorption unit 100.

[0061] The liquid discharge pump 145 is provided in the liquid discharge flow path 144, and is a pump that pumps the circulating liquid from the adsorption unit 100 to the liquid tank 141. The rotation speed (i.e., pumping capacity) of the liquid discharge pump 145 is controlled by a control voltage output from the control device 15.

[0062] 7, the liquid supply flow path 142 and the liquid discharge flow path 144 are each connected to the vertically lower side of the adsorption unit 100. In this embodiment, the liquid supply flow path 142 and the liquid discharge flow path 144 are each connected to the lower end surface (i.e., the bottom surface) of the adsorption unit 100.

[0063] Each of the gas supply flow path 1a and the gas exhaust flow path 1b is connected to the vertical upper side of the adsorption unit 100. In this embodiment, each of the gas supply flow path 1a and the gas exhaust flow path 1b is connected to the upper end surface of the adsorption unit 100.

[0064] Next, the operation of the carbon dioxide capture system 1 of this embodiment will be described with reference to Figs. 8 to 10. As shown in Fig. 8, the carbon dioxide capture system 1 is configured to be able to execute a carbon dioxide adsorption mode, a removed gas discharge mode, and a carbon dioxide capture mode. The carbon dioxide capture system 1 operates by switching between the following modes in this order: carbon dioxide adsorption mode, removed gas discharge mode, carbon dioxide capture mode, carbon dioxide adsorption mode, removed gas discharge mode, carbon dioxide capture mode, .... The operation of the carbon dioxide capture system 1 is controlled by a control device 15.

[0065] First, the carbon dioxide adsorption mode will be described. As shown in Fig. 9, in the carbon dioxide adsorption mode, the compressor 11 is operated to supply a carbon dioxide-containing gas to the adsorption section 100. In the carbon dioxide adsorption mode, the voltage applied between the working electrode 102 and the counter electrode 103 is set to a first voltage V1. This allows electron donation by the electroactive auxiliary material 103b of the counter electrode 103 and electron attraction by the carbon dioxide adsorbent 102b of the working electrode 102 to be realized simultaneously.

[0066] The electroactive auxiliary material 103b of the counter electrode 103 emits electrons and becomes oxidized, and the electrons are supplied from the counter electrode 103 to the working electrode 102. The carbon dioxide adsorbent 102b of the working electrode 102 receives electrons and becomes reduced.

[0067] The carbon dioxide adsorbing material 102b in the reduced state has a high carbon dioxide binding strength and binds and adsorbs the carbon dioxide contained in the carbon dioxide-containing gas, thereby enabling the carbon dioxide capture device 10 to capture carbon dioxide from the carbon dioxide-containing gas.

[0068] Next, the removed gas discharge mode will be described. As shown in Fig. 8, the removed gas discharge mode has a liquid supply mode and a liquid discharge mode. The carbon dioxide capture system 1 executes the liquid supply mode and then the liquid discharge mode.

[0069] In the removed gas discharge mode (i.e., both the liquid supply mode and the liquid discharge mode), the first voltage V1 is continuously applied between the working electrode 102 and the counter electrode 103. In the removed gas discharge mode, the compressor 11 stops operating, and the supply of the carbon dioxide-containing gas to the adsorption unit 100 stops.

[0070] In the liquid supply mode, the liquid supply pump 143 operates to supply the circulating liquid from the liquid tank 141 to the adsorption unit 100. At this time, the carbon dioxide in the adsorption unit 100 remains adsorbed by the carbon dioxide adsorbent 102b, and does not dissolve in the circulating liquid or undergo a chemical reaction with the circulating liquid.

[0071] In the liquid discharge mode, the liquid supply pump 143 stops operating, and the supply of the circulating liquid to the adsorption unit 100 stops. Furthermore, in the liquid discharge mode, the liquid discharge pump 145 operates, and the circulating liquid is discharged from the adsorption unit 100 and recovered in the liquid tank 141. At this time, the flow of the circulating liquid discharged from the adsorption unit 100 causes the carbon dioxide-removed gas that does not contain carbon dioxide to be discharged from the adsorption unit 100 to the gas discharge flow path 1b. In the liquid discharge mode, the flow path switching valve 12 switches the gas discharge flow path 1b to the atmosphere side, and the carbon dioxide-removed gas discharged from the adsorption unit 100 is discharged to the atmosphere.

[0072] Next, the carbon dioxide capture mode will be described. As shown in Fig. 10, in the carbon dioxide capture mode, the liquid discharge pump 145 stops operating, and the discharge of the circulating liquid from the adsorption section 100 stops. In the carbon dioxide capture mode, the voltage applied between the working electrode 102 and the counter electrode 103 is set to a second voltage V2. This allows electron donation by the carbon dioxide adsorbent 102b of the working electrode 102 and electron attraction by the electroactive auxiliary material 103b of the counter electrode 103 to be realized simultaneously.

[0073] The carbon dioxide adsorbent 102b of the working electrode 102 releases electrons and becomes oxidized. The carbon dioxide adsorbent 102b loses its bond with carbon dioxide, and releases the carbon dioxide. The electroactive auxiliary 103b of the counter electrode 103 receives electrons and becomes reduced.

[0074] The carbon dioxide released from the carbon dioxide adsorbent 102b is discharged from the adsorption section 100. The flow path switching valve 12 switches the gas exhaust flow path 1b to the carbon dioxide utilization device 13 side, and the carbon dioxide discharged from the adsorption section 100 is supplied to the carbon dioxide utilization device 13.

[0075] In this embodiment, the liquid supply flow path 142 and the liquid supply pump 143 correspond to an example of a supply part that supplies the circulating liquid into the adsorption part 100. In addition, the gas discharge flow path 1b, the liquid discharge flow path 144, and the liquid discharge pump 145 correspond to an example of a discharge part that discharges the circulating liquid and the carbon dioxide-removed gas supplied from the supply part from the adsorption part 100.

[0076] As described above, the carbon dioxide capture system 1 of this embodiment has the liquid supply flow path 142 and the liquid supply pump 143 which are the supply parts, and the gas discharge flow path 1b, the liquid discharge flow path 144, and the liquid discharge pump 145 which are the discharge parts. The carbon dioxide capture system 1 is configured to be capable of executing a removed gas discharge mode in which, with a voltage applied between the working electrode 102 and the counter electrode 103, the circulating liquid is supplied into the adsorption unit 100, and then the circulating liquid and the carbon dioxide-removed gas are discharged from the adsorption unit 100.

[0077] According to this, the carbon dioxide-removed gas can be discharged together with the circulating liquid from the adsorption section 100. As a result, the purity of the carbon dioxide in the adsorption section 100 can be increased, and therefore the purity of the recovered carbon dioxide can be improved.

[0078] In this embodiment, the carbon dioxide adsorbent 102b of the working electrode 102 in the electrochemical cell 101 is covered with the working electrode-side binder 102c. This makes it difficult for the carbon dioxide adsorbent 102b to peel off from the working electrode-side base material 102a, and it is possible to suppress a decrease in the carbon dioxide adsorption amount of the electrochemical cell 101 over time.

[0079] In addition, the working electrode side binder 102c of this embodiment has no affinity for the circulating liquid. Therefore, even in the presence of the circulating liquid, the circulating liquid can be prevented from reaching the working electrode side binder 102c. This makes it possible to prevent the circulating liquid from preferentially reacting with the carbon dioxide adsorbing material 102b, thereby increasing the amount of carbon dioxide adsorbed by the carbon dioxide adsorbing material 102b.

[0080] In this embodiment, the working electrode side binder 102c has carbon dioxide permeability. Therefore, carbon dioxide can permeate through the working electrode side binder 102c and reach the carbon dioxide adsorbent 102b. As a result, even if the carbon dioxide adsorbent 102b is covered with the working electrode side binder 102c, it is possible to capture carbon dioxide by the carbon dioxide adsorbent 102b.

[0081] In this embodiment, an ionic liquid gel is used as the working electrode side binder 102c. Therefore, it is possible to easily impart non-affinity to the circulating liquid and carbon dioxide permeability to the working electrode side binder 102c. Furthermore, it is also possible to impart non-volatility at room temperature and normal pressure to the working electrode side binder 102c.

[0082] Moreover, the carbon dioxide adsorbing material 102b of this embodiment has no affinity for the circulating liquid, which makes it possible to suppress the circulating liquid from preferentially reacting with the carbon dioxide adsorbing material 102b, thereby increasing the amount of carbon dioxide adsorbed by the carbon dioxide adsorbing material 102b.

[0083] Furthermore, in the carbon dioxide capture system 1 of the present embodiment, the liquid supply flow path 142 and the liquid discharge flow path 144 are each connected to the vertically lower side of the adsorption unit 100. Furthermore, the gas discharge flow path 1b is connected to the vertically upper side of the adsorption unit 100. This facilitates phase separation between the liquid and the gas within the adsorption unit 100, making it possible to easily discharge the carbon dioxide-removed gas, which is a gas, from the adsorption unit 100.

[0084] Second embodiment Next, a second embodiment of the present invention will be described with reference to Fig. 11. In this embodiment, the connection positions of the liquid supply flow path 142 and the liquid discharge flow path 144 to the adsorption part 100 are changed from those in the first embodiment.

[0085] 11, in the carbon dioxide capture system 1 of the present embodiment, the liquid supply flow path 142 and the liquid discharge flow path 144 are each connected to the vertically upper side of the adsorption unit 100. In the present embodiment, the liquid supply flow path 142 and the liquid discharge flow path 144 are each connected to the upper end surface of the adsorption unit 100.

[0086] As described above, in the carbon dioxide capture system 1 of the present embodiment, the liquid supply flow path 142, the liquid discharge flow path 144, and the gas discharge flow path 1b are connected to the vertically upper side of the adsorption unit 100. This makes it possible to easily supply the circulating liquid to the adsorption unit 100 and to easily discharge the carbon dioxide-removed gas, which is a gas, from the adsorption unit 100.

[0087] Third embodiment Next, a third embodiment of the present invention will be described with reference to Fig. 12. In this embodiment, the connection positions of the gas supply flow path 1a, the gas exhaust flow path 1b, the liquid supply flow path 142, and the liquid exhaust flow path 144 to the adsorption unit 100 are changed from those in the first embodiment.

[0088] As shown in FIG. 12, in the carbon dioxide capture system 1 of this embodiment, the gas supply flow path 1a, the gas discharge flow path 1b, the liquid supply flow path 142, and the liquid discharge flow path 144 are each connected to the vertical center of the adsorption unit 100.

[0089] In this embodiment, the adsorption unit 100 is formed in a shape extending in the horizontal direction. That is, the carbon dioxide capture device 10 is arranged so that the longitudinal direction of the adsorption unit 100 is parallel to the horizontal direction. The gas supply flow path 1a and the liquid supply flow path 142 are connected to one end side of the adsorption unit 100 in the longitudinal direction. The gas discharge flow path 1b and the liquid discharge flow path 144 are connected to the other end side of the adsorption unit 100 in the longitudinal direction.

[0090] As described above, in the carbon dioxide capture system 1 of this embodiment, the gas supply flow path 1a, the gas discharge flow path 1b, the liquid supply flow path 142, and the liquid discharge flow path 144 are each connected to the vertical center of the adsorption unit 100. This makes it possible to reduce the space required for the carbon dioxide capture system 1.

[0091] (Fourth embodiment) Next, a fourth embodiment of the present invention will be described with reference to Fig. 13. In this embodiment, the configuration of the carbon dioxide capture device 10 is changed from that of the first embodiment.

[0092] As shown in Fig. 13, in the carbon dioxide capture system 1 of this embodiment, the carbon dioxide capture device 10 has a temperature adjustment unit 107. The temperature adjustment unit 107 increases the temperature of the working electrode side binder 102c, which is a coating material, during carbon dioxide adsorption when carbon dioxide is adsorbed into the carbon dioxide adsorbing material 102b. In addition, the temperature adjustment unit 107 decreases the temperature of the working electrode side binder 102c during carbon dioxide desorption when carbon dioxide is desorbed from the carbon dioxide adsorbing material 102b. The operation of the temperature adjustment unit 107 is controlled by a control voltage output from the control device 15.

[0093] In this embodiment, an ionic liquid gel obtained by gelling an ionic liquid is used as the working electrode side binder 102c. The ionic liquid has a property that the solubility of carbon dioxide increases at high temperatures and decreases at low temperatures.

[0094] Therefore, according to the carbon dioxide capture system 1 of the present embodiment, when carbon dioxide is adsorbed, the temperature of the working electrode side binder 102c is increased by the temperature adjustment unit 107, so that carbon dioxide becomes more easily dissolved in the working electrode side binder 102c. This can promote the adsorption of carbon dioxide into the carbon dioxide adsorbing material 102b.

[0095] Furthermore, when carbon dioxide is desorbed, the temperature of the working electrode side binder 102c is lowered by the temperature adjusting unit 107, so that carbon dioxide is less likely to dissolve in the working electrode side binder 102c. This can promote desorption of carbon dioxide from the carbon dioxide adsorbing material 102b.

[0096] (Other embodiments) The present invention is not limited to the above-described embodiment, and various modifications can be made without departing from the spirit of the present invention. Furthermore, the means disclosed in each of the above-described embodiments may be appropriately combined within the scope of feasibility.

[0097] (1) In the above-described embodiment, the working electrode 102, the counter electrode 103, and the insulating layer 104 of the electrochemical cell 101 are each formed as a plate-shaped member, but as shown in Fig. 14, the working electrode 102, the counter electrode 103, and the insulating layer 104 may each be formed as a cylindrical member. In this case, the working electrode 102 may be disposed on the innermost side, the counter electrode 103 may be disposed on the outermost side, and the insulating layer 104 may be disposed between the working electrode 102 and the counter electrode 103. This allows the space formed inside the working electrode 102 to be a gas flow path through which the carbon dioxide-containing gas passes.

[0098] (2) In the above embodiment, an example was described in which an ionic liquid gel was used as the working electrode side binder 102c, but the working electrode side binder 102c is not limited to an ionic liquid gel. For example, an ionic liquid may be used as the working electrode side binder 102c.

[0099] (3) In the above-described embodiment, a liquid that is non-chemically reactive and insoluble in carbon dioxide is used as the circulating liquid. However, the circulating liquid does not necessarily have to be non-chemically reactive and insoluble in carbon dioxide.

[0100] For example, water may be used as the circulating liquid. In this case, the carbon dioxide adsorbing material 102b and the working electrode side binder 102c may have hydrophobic properties. [Explanation of symbols]

[0101] 1b Gas exhaust flow path (exhaust section) 100 Adsorption part 142 Liquid supply flow path (supply section) 143 Liquid supply pump (supply section) 144 Liquid discharge flow path (discharge section) 145 Liquid discharge pump (discharge section)

Claims

1. A carbon dioxide capture system that separates carbon dioxide from a carbon dioxide-containing gas that contains carbon dioxide by an electrochemical reaction, an electrochemical cell (101) having a working electrode (102) and a counter electrode (103), in which, when a voltage is applied between the working electrode and the counter electrode, electrons are supplied from the counter electrode to the working electrode, and the working electrode is bonded to carbon dioxide as the electrons are supplied; an adsorption section (100) in which the electrochemical cell is housed and into which the carbon dioxide-containing gas is introduced; A supply unit (142, 143) that supplies a liquid into the adsorption unit while a voltage is applied between the working electrode and the counter electrode; and a discharge section (1b, 144, 145) that discharges, from the adsorption section, the liquid supplied from the supply section and the carbon dioxide-removed gas obtained after carbon dioxide is separated from the carbon dioxide-containing gas, while a voltage is applied between the working electrode and the counter electrode; The working electrode has an electrode substrate (102a) and a carbon dioxide adsorbent (102b), When a voltage is applied between the working electrode and the counter electrode, electrons are supplied from the counter electrode to the working electrode, and the carbon dioxide adsorbent is bonded to carbon dioxide as the electrons are supplied, A carbon dioxide capture system, wherein the carbon dioxide adsorbent is covered with a covering material (102c).

2. Furthermore, a voltage application unit (105) that applies a voltage between the working electrode and the counter electrode; A control unit (15) that controls the operation of the voltage application unit, the supply unit, and the discharge unit, The carbon dioxide capture system according to claim 1, wherein the control unit supplies the liquid into the adsorption unit using the supply unit while a voltage is applied between the working electrode and the counter electrode, and then discharges the liquid and the carbon dioxide-removed gas from the adsorption unit using the discharge unit.

3. 3. The carbon dioxide capture system according to claim 1, wherein the covering material has carbon dioxide permeability that allows carbon dioxide to pass therethrough.

4. 4. The carbon dioxide capture system according to claim 1, wherein the coating material is an ionic liquid gel obtained by gelling an ionic liquid.

5. The carbon dioxide capture system according to claim 4, further comprising a temperature adjustment unit (107) that increases the temperature of the covering material during carbon dioxide adsorption (adsorption of carbon dioxide into the carbon dioxide adsorbent) and decreases the temperature of the covering material during carbon dioxide desorption (desorption of carbon dioxide from the carbon dioxide adsorbent).

6. the supply unit is connected to a lower side of the adsorption unit and has a liquid supply flow path (142) that supplies the liquid to the adsorption unit; The discharge section is a gas exhaust passage (1b) connected to an upper side of the adsorption section and configured to exhaust the carbon dioxide-removed gas in the adsorption section to the outside; 6. The carbon dioxide capture system according to claim 1, further comprising: a liquid discharge passage (144) connected to a lower side of the adsorption section and discharging the liquid in the adsorption section to the outside.

7. the supply unit is connected to an upper side of the adsorption unit and has a liquid supply flow path (142) that supplies the liquid to the adsorption unit; The discharge section is a gas exhaust passage (1b) connected to an upper side of the adsorption section and configured to exhaust the carbon dioxide-removed gas in the adsorption section to the outside; 6. The carbon dioxide capture system according to claim 1, further comprising: a liquid discharge passage (144) connected to an upper side of the adsorption section and discharging the liquid in the adsorption section to the outside.

8. The supply unit has a liquid supply flow path (142) connected to a vertical center of the suction unit and supplying the liquid to the suction unit; The discharge section is a gas exhaust passage (1b) connected to a vertical center of the adsorption section and configured to exhaust the carbon dioxide-removed gas in the adsorption section to the outside; 6. The carbon dioxide capture system according to claim 1, further comprising: a liquid discharge flow path (144) connected to a vertical center portion of the adsorption section and discharging the liquid in the adsorption section to the outside.

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