SUBSTRATE PROCESSING APPARATUS AND SUBSTRATE PROCESSING METHOD

Abstract

To provide a substrate processing device and a substrate processing method with which it is possible to prevent particles from sticking to substrates.SOLUTION: A substrate processing device 1 comprises a processing tank 2 that stores a process liquid, a chamber 3 that encloses the processing tank 2, a solvent vapor nozzle 27 that supplies solvent vapor to the inside of the chamber 3, cleaning liquid nozzles 5, 16 that supply a cleaning liquid, and a control unit 81. The control unit 81 carries out an immersion process of immersing a substrate W in the process liquid stored in the processing tank 2 for a preset period, and carries out a drying process of drying the substrate W using the solvent vapor supplied from the solvent vapor nozzle 27, the substrate W that has been processed with the process liquid and pulled out of the processing tank. The control unit 81 causes the cleaning liquid nozzles 5, 16 to supply a cleaning liquid to the inside of the chamber 3 and the processing tank 2 to be immersed in the cleaning liquid stored in the chamber 3, thereby carrying out a chamber cleaning process of cleaning the inside of the chamber 3 including the outer wall of the processing tank 2.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a substrate processing apparatus and a substrate processing method for processing a substrate, for example, a semiconductor substrate, a substrate for an FPD (Flat Panel Display), a glass substrate for a photomask, a substrate for an optical disk, a substrate for a magnetic disk, a ceramic substrate, a substrate for a solar cell, etc. For example, an FPD may be a liquid crystal display device, an organic EL (electroluminescence) display device, etc. [Background technology]

[0002] The substrate processing apparatus includes a processing tank for storing a processing liquid such as pure water, a chamber surrounding the processing tank, a lifter for holding the substrate, a nitrogen nozzle for supplying nitrogen gas into the chamber, a solvent nozzle for supplying isopropyl alcohol (IPA) vapor into the chamber, and an exhaust pump for evacuating the chamber to reduce the pressure (see, for example, Patent Document 1).

[0003] The substrate processing apparatus operates, for example, as follows (see, for example, Patent Document 1). The lifter immerses the substrate in the processing liquid in the processing tank. Then, IPA vapor is supplied from the solvent nozzle, creating an IPA vapor atmosphere in the chamber. The lifter then removes the substrate from the processing liquid in the processing tank and moves the substrate to a drying position in the chamber. Then, the exhaust pump reduces the pressure in the chamber. This actively volatilizes IPA and other substances adhering to the substrate, and the substrate is dried. Then, the exhaust pump is stopped, and nitrogen gas is supplied from the nitrogen nozzle to return the chamber to atmospheric pressure.

[0004] Patent Document 2 discloses a neutralizing cleaning device for a substrate processing apparatus that includes a chemical tank that stores an "acidic chemical" or an "alkaline chemical" and a chamber that houses the chemical tank. The neutralizing cleaning device includes a pure water nozzle, a circulation nozzle, and a circulation pipe. The circulation pipe is connected to the circulation nozzle. The pure water nozzle and the circulation nozzle are each installed facing between the inner wall of the chamber and the outer wall of the chemical tank. The neutralizing cleaning device stores pure water inside the chamber via the pure water nozzle, and then circulates the pure water stored inside the chamber via the circulation pipe. As a result, the chemical components attached to the outer wall of the chemical tank are released from the attachment surface by the flow of pure water.

[0005] Patent Document 3 discloses that pure water is supplied into the chamber using a hand shower to wash away and remove condensed parts of the dilute hydrochloric acid vapor.

[0006] Patent Document 4 discloses a process for hydrophobizing the surface of a substrate. Patent Document 5 discloses a substrate processing apparatus capable of discharging a processing liquid from a chamber even in a reduced pressure solvent atmosphere. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] JP 2015-070148 A [Patent Document 2] JP 2008-251779 A [Patent Document 3] JP 2010-093097 A [Patent Document 4] JP 2018-056155 A [Patent Document 5] JP 2008-004874 A Summary of the Invention [Problem to be solved by the invention]

[0008] However, conventional substrate processing apparatuses have the following problems. When the apparatus is used, particles accumulate in the lower part of the chamber (including the outer wall of the processing tank), causing contamination. If the lower part of the chamber is contaminated, for example, when nitrogen gas is supplied, the nitrogen gas stirs up particles in the lower part of the chamber, and the particles adhere to the substrate.

[0009] The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a substrate processing apparatus and a substrate processing method capable of preventing particles from adhering to a substrate. [Means for solving the problem]

[0010] In order to achieve the above object, the present invention has the following configuration: That is, the substrate processing apparatus according to the present invention includes a processing tank for storing a processing liquid, a chamber surrounding the processing tank, a solvent vapor nozzle for supplying a solvent vapor into the chamber, a cleaning liquid nozzle for supplying a cleaning liquid into the chamber, and a control unit, the control unit performs an immersion process for immersing a substrate in the processing liquid stored in the processing tank for a preset period of time, and performs a drying process for drying the substrate treated with the processing liquid and pulled out of the processing tank using the solvent vapor supplied from the solvent vapor nozzle, and the control unit performs a chamber cleaning process for cleaning the inside of the chamber including the outer wall of the processing tank by immersing the processing tank in the cleaning liquid stored in the chamber.

[0011] According to the substrate processing apparatus of the present invention, a cleaning liquid is supplied into the chamber from a cleaning liquid nozzle, and the processing tank is immersed in the cleaning liquid stored in the chamber, thereby performing a chamber cleaning process for cleaning the inside of the chamber including the outer wall of the processing tank. This makes it possible to clean particles adhering to not only the outer wall of the processing tank but also the side wall and bottom wall of the chamber. This makes it possible to prevent particles at the bottom of the chamber from being lifted up and adhering to the substrate.

[0012] In the above-mentioned substrate processing apparatus, it is preferable that the control unit performs the chamber cleaning process after performing the immersion process, and the control unit performs the drying process after performing the chamber cleaning process, thereby making it possible to perform the cleaning process inside the chamber in the middle of a series of substrate processing.

[0013] In addition, it is preferable that the above-mentioned substrate processing apparatus further includes a water repellent vapor nozzle for supplying water repellent vapor into the chamber, and that after performing the immersion process, the control unit performs a water repellent vapor supply process for supplying the water repellent vapor from the water repellent vapor nozzle into the chamber in order to make the substrate water repellent, and that the control unit performs the chamber cleaning process after performing the water repellent vapor supply process.

[0014] The water repellent vapor supply process for making a substrate water repellent generates a large amount of particles derived from the water repellent. These particles accumulate in the lower part of the chamber. Then, there is a problem that the particles in the lower part of the chamber are stirred up and adhere to the substrate. According to the present invention, a cleaning process can be performed in the chamber during a series of substrate processing. Therefore, it is possible to prevent particles (including particles derived from the water repellent) in the lower part of the chamber from being stirred up and adhering to the substrate.

[0015] In addition, it is preferable that the above-mentioned substrate processing apparatus further includes an exhaust pump that evacuates the inside of the chamber, the cleaning liquid nozzle is provided at a lower part of the chamber and supplies the cleaning liquid into the chamber, and the control unit performs the chamber cleaning process while reducing the pressure in the chamber by the exhaust pump.

[0016] This allows the cleaning process in the chamber to be performed with the pressure in the chamber reduced by the exhaust pump. In addition, there is a case where the cleaning liquid is overflowed from the processing tank while being supplied to the processing tank, and the cleaning liquid is stored in the chamber. In a state where the pressure in the chamber is reduced, there is a problem that mist is easily generated from the cleaning liquid stored in the processing tank, and the generated mist is easily attached to the substrate. In addition, the attached mist may adversely affect the substrate. According to the present invention, the cleaning liquid can be directly supplied into the chamber from a cleaning liquid nozzle provided at the bottom of the chamber, so that the cleaning liquid can be separated from the substrate. Therefore, the generated mist can be prevented from adhering to the substrate.

[0017] In the above-described substrate processing apparatus, it is preferable that the exhaust pump exhausts the inside of the chamber through an exhaust port provided in a side wall of the chamber on the side of the processing tank, and the control unit performs the chamber cleaning process while depressurizing the inside of the chamber with the exhaust pump. Even if mist is generated from the cleaning liquid, the mist can be discharged from the exhaust port by the exhaust pump.

[0018] The substrate processing apparatus preferably further includes a shield plate provided between the outer wall of the processing tank and the inner wall of the chamber, for isolating the atmosphere between the upper part of the chamber and the lower part of the chamber, the shield plate having an opening for allowing the processing liquid overflowing from the processing tank to flow to the lower part of the chamber. By providing the shield plate, even if mist is generated from the cleaning liquid stored in the chamber, the mist can be prevented from moving from the lower part to the upper part of the chamber. Also, the particles being stirred up can be prevented from moving from the lower part to the upper part of the chamber.

[0019] In the above-mentioned substrate processing apparatus, the cleaning liquid nozzle is preferably provided at the bottom of the chamber at a position overlapping with the processing tank in a plan view. This allows the cleaning liquid nozzle to be hidden behind the processing tank. In addition, since the cleaning liquid nozzle can be located farther away from the substrate in the upper part of the chamber, even if mist is generated, it is possible to prevent the mist from adhering to the substrate.

[0020] In the above-described substrate processing apparatus, it is preferable that the control unit performs the chamber cleaning process while the solvent vapor is being supplied into the chamber from the solvent vapor nozzle. Since the chamber cleaning process can be performed in parallel with the process of supplying the solvent vapor into the chamber, substrates can be processed efficiently.

[0021] In the above-mentioned substrate processing apparatus, it is preferable that the control unit performs a discharge process of discharging the cleaning liquid from an outlet provided in the chamber while the chamber is depressurized by the exhaust pump, and the control unit repeats the chamber cleaning process and the discharge process a preset number of times. The more the chamber cleaning process is repeated, the better the inside of the chamber can be cleaned.

[0022] In addition, it is preferable that the above-mentioned substrate processing apparatus further includes an inert gas nozzle for supplying an inert gas into the chamber, and the control unit returns the inside of the chamber from a reduced pressure state to atmospheric pressure by supplying an inert gas into the chamber from the inert gas nozzle after the drying process is performed. By performing a cleaning process inside the chamber, particles stirred up by the inert gas can be reduced.

[0023] In addition, in the above-mentioned substrate processing apparatus, it is preferable that the cleaning liquid nozzle is positioned in a position facing an outer wall of the processing tank, and the control unit supplies the cleaning liquid from the cleaning liquid nozzle into the chamber while directing the cleaning liquid against the outer wall of the processing tank while reducing the pressure in the chamber using the exhaust pump.

[0024] Since the liquid flows relatively easily on the bottom surface of the chamber, particles are relatively unlikely to accumulate on the bottom surface of the chamber. However, for example, the outer wall of the processing tank is a part where the liquid does not flow easily even if floating particles adhere to it, so particles accumulate there. Since the cleaning liquid is applied to that part while being stored in the chamber, it is easy to remove particles that have adhered to the outer wall of the processing tank.

[0025] In the substrate processing apparatus described above, it is preferable that the substrate processing apparatus further includes a nozzle cover provided at the bottom of the chamber so as to face the upward discharge port of the cleaning liquid nozzle, the nozzle cover including a ceiling wall and a plurality of side walls connected to the ceiling wall and having holes through which the cleaning liquid passes. The cleaning liquid can be stored in the chamber while suppressing the diffusion of mist.

[0026] In the above-mentioned substrate processing apparatus, it is preferable that the cleaning liquid nozzle is provided at the bottom of the processing tank and supplies the cleaning liquid into the processing tank, and the control unit, while supplying the cleaning liquid from the cleaning liquid nozzle into the processing tank in a state in which the inside of the chamber is at atmospheric pressure, stores the cleaning liquid overflowing from the processing tank in the chamber, and further performs a chamber cleaning process in which the processing tank is immersed in the cleaning liquid stored in the chamber to clean the chamber including the outer wall of the processing tank. This makes it possible to perform a cleaning process in the chamber in a state in which the inside of the chamber is at atmospheric pressure. In addition, since the cleaning liquid is also supplied to the processing tank, the cleaning process of the processing tank and the cleaning process in the chamber can be performed in parallel.

[0027] In the above-mentioned substrate processing apparatus, it is preferable that the control unit performs the chamber cleaning process between two successive substrate processing series, each time a series of substrate processing including the immersion process and the drying process is performed on a preset number of substrates or a preset number of lots. A cleaning process in the chamber can be performed between two successive substrate processing series, each time a series of substrate processing is performed on a preset number of substrates or a preset number of lots.

[0028] In the above-mentioned substrate processing apparatus, it is preferable that the cleaning liquid nozzle is provided at the bottom of the processing tank and supplies the cleaning liquid into the processing tank, and the control unit supplies the cleaning liquid from the cleaning liquid nozzle into the processing tank while the inside of the chamber is at atmospheric pressure, and stores the cleaning liquid overflowing from the processing tank in the chamber.

[0029] Furthermore, a substrate processing method according to the present invention is a substrate processing method for a substrate processing apparatus including a processing tank for storing a processing liquid and a chamber surrounding the processing tank, and includes an immersion process for immersing a substrate in the processing liquid stored in the processing tank for a predetermined period of time, a drying process for drying the substrate treated with the processing liquid and pulled out of the processing tank using the solvent vapor supplied from the solvent vapor nozzle, and a chamber cleaning process for cleaning the chamber including the outer wall of the processing tank by supplying the cleaning liquid from the cleaning liquid nozzle into the chamber and immersing the processing tank in the cleaning liquid stored in the chamber. Effect of the Invention

[0030] According to the substrate processing apparatus and substrate processing method of the present invention, it is possible to prevent particles from adhering to the substrate. [Brief description of the drawings]

[0031] [Figure 1] 1 is a schematic configuration diagram of a substrate processing apparatus according to a first embodiment. [Diagram 2] 5A to 5C are diagrams for explaining the operation of the substrate processing apparatus according to the first embodiment. [Diagram 3] 4 is a timing chart showing the operation of the substrate processing apparatus in accordance with the first embodiment. [Figure 4] 1A is a diagram for explaining the problem of mist, and FIG. 1B is a diagram for explaining the effect of the substrate processing apparatus 1. FIG. [Diagram 5] FIG. 11 is a schematic configuration diagram of a substrate processing apparatus according to a second embodiment. [Figure 6]10A and 10B are diagrams for explaining the operation of the substrate processing apparatus according to the second embodiment. [Figure 7] 10 is a timing chart showing the operation of the substrate processing apparatus in accordance with the second embodiment. [Figure 8] 13 is a diagram for explaining the operation of the substrate processing apparatus according to the third embodiment. FIG. [Figure 9] 10 is a timing chart showing the operation (series of substrate processing) of the substrate processing apparatus in accordance with the third embodiment. [Figure 10] 13 is a timing chart showing the operation (cleaning of the inside of a chamber) of the substrate processing apparatus according to the third embodiment. [Figure 11] FIG. 13 is a diagram showing a chamber equipped with a nozzle cover according to a modified example. [Figure 12] FIG. 13 is a diagram showing a chamber provided with two cleaning liquid nozzles according to a modified example. [Figure 13] FIG. 13 is a diagram showing a chamber provided with two cleaning liquid nozzles according to a modified example. Example 1

[0032] A first embodiment of the present invention will be described below with reference to the drawings. Fig. 1 is a schematic diagram of a substrate processing apparatus according to the first embodiment.

[0033] (1) Configuration of the Substrate Processing Apparatus 1 Referring to Fig. 1, the substrate processing apparatus 1 includes a processing tank 2 that stores a processing liquid, a chamber 3 that surrounds the processing tank 2, and a lifter 4. The processing tank 2 is configured to be capable of accommodating a plurality of substrates W in an upright position (vertical position). The processing tank 2 is disposed away from the bottom surface of the chamber 3.

[0034] The lifter 4 includes a holding member 4A that holds multiple substrates W arranged at equal intervals in the Y direction in an upright position, and a lifting mechanism 4B that raises and lowers the holding member 4A in the vertical direction (Z direction). The lifting mechanism 4B includes, for example, an electric motor or an air cylinder. The lifting mechanism 4B raises and lowers the substrates W between a "standby position H1" above the chamber 3, a "drying position H2" above the processing tank 2 and within the chamber 3, and a "processing position H3" inside the processing tank 2.

[0035] Two ejection pipes 5 are provided at the bottom of the processing tank 2 to supply processing liquid into the processing tank 2. Each ejection pipe 5 is formed linearly along the Y direction (the front-rear direction of the paper) in which multiple substrates W are aligned. Each ejection pipe 5 has multiple discharge ports aligned in the Y direction.

[0036] A tip of a processing liquid pipe 7 is connected to each of the spray pipes 5. A base end of the processing liquid pipe 7 is connected to a processing liquid supply source 9. The processing liquid supply source 9 sends pure water as the processing liquid to the processing liquid pipe 7. For example, deionized water (DIW) is used as the pure water. An on-off valve V1 is provided in the processing liquid pipe 7. The on-off valve V1 starts and stops the supply of pure water. Specifically, when the on-off valve V1 is in an open state, pure water is supplied to the processing tank 2 from the two spray pipes 5. On the other hand, when the on-off valve V1 is in a closed state, the supply of pure water from the two spray pipes 5 is stopped.

[0037] Further, the tip of the second processing liquid pipe 11 is connected to the processing liquid pipe 7 between the two ejection pipes 5 and the on-off valve V1. The base end of the second processing liquid pipe 11 is connected to the second processing liquid supply source 13. The second processing liquid supply source 13 sends an isopropyl alcohol liquid (i.e., a mixed liquid of isopropyl alcohol and pure water) diluted with pure water (e.g., DIW) to the second processing liquid pipe 11 as the second processing liquid. The isopropyl alcohol liquid diluted with pure water is hereinafter referred to as a "diluted IPA liquid". The second processing liquid pipe 11 is provided with an on-off valve V2. The on-off valve V2 starts and stops the supply of the diluted IPA liquid. The two ejection pipes 5 are configured to selectively supply pure water and the diluted IPA liquid by the two on-off valves V1 and V2.

[0038] A QDR valve (on-off valve) 14 is provided at the bottom of the treatment tank 2, which releases the treatment liquid in the treatment tank 2 to the bottom surface of the chamber 3. When the QDR valve 14 is opened, the treatment liquid in the treatment tank 2 is rapidly released to the bottom surface of the chamber 3. When the QDR valve 14 is closed, the treatment liquid can be stored in the treatment tank 2.

[0039] Two cleaning liquid nozzles 16 are provided at the bottom of the chamber 3. The two cleaning liquid nozzles 16 are provided at positions overlapping with the processing tank 2 in a plan view. The two cleaning liquid nozzles 16 may be provided so that their entirety overlaps with the processing tank 2 in a plan view. The two cleaning liquid nozzles 16 directly supply the cleaning liquid into the chamber 3. Each cleaning liquid nozzle 16 is configured in the same manner as the ejection pipe 5. Each cleaning liquid nozzle 16 is a pipe formed linearly along the Y direction. Each cleaning liquid nozzle 16 has a plurality of outlets aligned in the Y direction.

[0040] The two cleaning liquid nozzles 16 are connected to the tip of a cleaning liquid pipe 18. The base end of the cleaning liquid pipe 18 is connected to a cleaning liquid supply source 20. The cleaning liquid supply source 20 supplies pure water, diluted IPA liquid, or hydrogen peroxide solution diluted with pure water (e.g., DIW) (hereinafter referred to as "diluted H2O2 liquid") to the cleaning liquid pipe 18 as a cleaning liquid. An on-off valve V3 is provided in the cleaning liquid pipe 18. The on-off valve V3 starts and stops the supply of the cleaning liquid.

[0041] The chamber 3 contains the treatment tank 2. The chamber 3 is provided with an upper cover 23 on its upper surface which can be opened and closed freely. Two inert gas nozzles 25, two solvent vapor nozzles 27, and two water repellent vapor nozzles 29 are provided inside the chamber 3. Between the upper cover 23 and the treatment tank 2, the two inert gas nozzles 25, the two solvent vapor nozzles 27, and the two water repellent vapor nozzles 29 are arranged in this order from the top.

[0042] The six nozzles 25, 27, and 29 are formed linearly so as to extend along the Y direction. Each of the two inert gas nozzles 25 has a plurality of outlets (not shown) aligned along the Y direction to eject the inert gas. Similarly, the four nozzles 27 and 29 also have a plurality of outlets.

[0043] Each of the two inert gas nozzles 25 supplies an inert gas into the chamber 3. A tip of a supply pipe 31 is connected to each inert gas nozzle 25. A base end of the supply pipe 31 is connected to an inert gas supply source 33. The inert gas supply source 33 sends an inert gas, such as nitrogen gas, to the supply pipe 31. An on-off valve V4 is provided in the supply pipe 31. The on-off valve V4 starts and stops the supply of the inert gas.

[0044] Each of the two solvent vapor nozzles 27 supplies solvent vapor into the chamber 3. The tip of a supply pipe 35 is connected to each solvent vapor nozzle 27. The base end of the supply pipe 35 is connected to a solvent vapor supply source 37. The solvent vapor supply source 37 sends, for example, isopropyl alcohol vapor (hereinafter referred to as "IPA vapor") as the solvent vapor to the supply pipe 35. The solvent vapor is generated by evaporating a liquid solvent using a heater. The solvent vapor may contain an inert gas (nitrogen gas) as a carrier gas. An on-off valve V5 is provided in the supply pipe 35. The on-off valve V5 starts and stops the supply of the solvent vapor.

[0045] Each of the two water repellent vapor nozzles 29 supplies water repellent vapor into the chamber 3. A tip of a supply pipe 39 is connected to each water repellent vapor nozzle 29. A base end of the supply pipe 39 is connected to a water repellent vapor supply source 41. The water repellent vapor supply source 41 sends water repellent vapor to the supply pipe 39. The water repellent vapor is generated by evaporating liquid water repellent with a heater. The water repellent vapor may contain an inert gas (nitrogen gas) as a carrier gas. An on-off valve V6 is provided in the supply pipe 39. The on-off valve V6 starts and stops the supply of the water repellent vapor.

[0046] The water repellent (silylation agent) is a silicon-based water repellent that hydrophobicizes silicon itself and compounds containing silicon, or a metal-based water repellent that hydrophobicizes metal itself and compounds containing metal. The water repellent is preferably used in a state diluted with a solvent that is compatible with a hydrophilic organic solvent such as IPA.

[0047] The metal-based water repellent agent contains, for example, at least one of an amine having a hydrophobic group and an organosilicon compound.

[0048] The silicon-based water repellent is, for example, a silane coupling agent, which includes, for example, at least one of HMDS (hexamethyldisilazane), TMS (tetramethylsilane), fluorinated alkylchlorosilane, alkyldisilazane, and a non-chloro-based water repellent.

[0049] An exhaust port 43 is provided on the side wall of the chamber 3. The exhaust port 43 is disposed at a height such that it faces the outer surface 2A of the treatment tank 2. In other words, the exhaust port 43 is disposed at a height between a shield plate 63 (described later) and the lower surface 2B of the treatment tank 2. This allows the gas in the chamber 3 to be exhausted from the exhaust port 43 while, for example, a cleaning liquid is stored at a position lower than the exhaust port 43. An exhaust pipe 45 is connected to the exhaust port 43. An opening / closing valve V7 and an exhaust pump 47 are provided in the exhaust pipe 45 in this order from the exhaust port 43 side. The exhaust pump 47 exhausts the gas in the chamber 3 to reduce the pressure in the chamber 3.

[0050] Furthermore, a discharge port 49 is provided in the bottom wall of the chamber 3. The upper end of a discharge pipe 51 is connected to the discharge port 49. The lower end of the discharge pipe 51 is connected to the upper outer wall of the drainage tank 53. An opening / closing valve V8 is provided in the discharge pipe 51. The opening / closing valve V8 is used when sending the processing liquid or cleaning liquid in the chamber 3 to the drainage tank 53. The drainage tank 53 is a container for storing the processing liquid discharged from the chamber 3. An exhaust pipe 55 is connected to the drainage tank 53. An opening / closing valve V9 and an exhaust pump 57 are provided in this order from the drainage tank 53 side in the exhaust pipe 55.

[0051] In addition, a gas pipe 59 and a discharge pipe 61 are connected to the waste liquid tank 53. An on-off valve V11 is provided in the gas pipe 59. In addition, an on-off valve V12 is provided in the discharge pipe 61. The gas pipe 59 sends an inert gas (e.g., nitrogen gas) or outside air to the waste liquid tank 53. The on-off valve V11 starts and stops the supply of the inert gas, etc. The discharge pipe 61 discharges the processing liquid, etc. in the waste liquid tank 53.

[0052] The drain tank 53 discharges the processing liquid and the like at an appropriate timing. When discharging the processing liquid stored in the drain tank 53, for example, the on-off valve V11 is opened while the on-off valves V8, V9, and V12 are closed, and the inside of the drain tank 53 is returned to atmospheric pressure. Thereafter, while the on-off valves V8 and V9 are closed, the on-off valves V11 and V12 are opened to discharge the processing liquid and the like in the drain tank 53.

[0053] The chamber 3 also includes a shield plate 63. The shield plate 63 is provided slightly below the upper edge (or opening 2C) of the treatment tank 2, over the entire circumference of the outer surface 2A of the treatment tank 2. In other words, the shield plate 63 is provided between the outer wall of the treatment tank 2 and the inner wall of the chamber 3. The shield plate 63 blocks the atmosphere between the upper part (upper space) of the chamber 3 and the lower part (lower space) of the chamber 3. The shield plate 63 has gaps G1 and G2 (openings) that allow the treatment liquid overflowing from the treatment tank 2 to flow to the lower part of the chamber 3. That is, the shield plate 63 has a gap G1 between the outer wall of the treatment tank 2 and a gap G2 between the inner wall of the chamber 3. Note that one of the gaps G1 and G2 may not be provided as necessary. The shield plate 63 may be attached to the outer wall of the treatment tank 2 or the inner wall of the chamber 3.

[0054] The chamber 3 is provided with a pressure sensor PS1 that measures the pressure inside the chamber 3. Furthermore, the drainage tank 53 is provided with a pressure sensor PS2 that measures the pressure inside the drainage tank 53. Furthermore, the chamber 3 is provided with a liquid level sensor LS that detects the liquid level of, for example, the cleaning liquid stored in the chamber 3. The pressure values ​​measured by the pressure sensors PS1 and PS2 and the value of the liquid level detected by the liquid level sensor LS are transmitted to a control unit 81, which will be described later.

[0055] The substrate processing apparatus 1 includes a control unit 81 and a storage unit (not shown). The control unit 81 controls each component of the substrate processing apparatus 1. The control unit 81 includes one or more processors, such as a central processing unit (CPU). The storage unit includes at least one of a read-only memory (ROM), a random-access memory (RAM), and a hard disk, for example. The storage unit stores computer programs required to control each component of the substrate processing apparatus 1.

[0056] The substrate processing apparatus 1 is equipped with two cleaning liquid nozzles 16. In this regard, the substrate processing apparatus 1 may be equipped with one or three or more cleaning liquid nozzles 16. The same is true for the two ejection pipes 5, the two inert gas nozzles 25, the two solvent vapor nozzles 27, and the two water repellent vapor nozzles 29.

[0057] (2) Operation of the Substrate Processing Apparatus 1 Next, the operation of the substrate processing apparatus 1 will be described with reference to Fig. 2 and Fig. 3. Note that the lifter 4 is omitted in Fig. 2. Note that the exhaust operation by the exhaust pump 47 and the like is indicated by the symbol "VAC" in Fig. 2. In Fig. 3, the diluted IPA liquid is indicated as "dIPA liquid".

[0058] [Step S01] First immersion process (loading the substrate into the chamber) Pure water is stored in the processing tank 2 as a processing liquid. The pure water is supplied from a jet pipe 5. First, the upper cover 23 is moved to open the top opening of the chamber 3. The lifter 4 lowers the substrate W held by the holding member 4A from the standby position H1 to the processing position H3. That is, the lifter 4 immerses the entire substrate W in the pure water stored in the processing tank 2 for a preset time. By immersing the substrate W in the pure water, the substrate W is cleaned. After the substrate W is immersed in the pure water, the upper cover 23 is moved to close the top opening of the chamber 3.

[0059] [Step S02] Supply of nitrogen gas Thereafter, the on-off valve V4 is opened to supply nitrogen into the chamber 3 from the inert gas nozzle 25. Furthermore, by opening the on-off valve V7 while operating the exhaust pump 47, the gas in the chamber 3 is exhausted through the exhaust port 43 and the exhaust pipe 45. As a result, the inside of the chamber 3 becomes a reduced pressure state in which the pressure is lower than atmospheric pressure.

[0060] [Step S03] First supply of IPA vapor (creation of IPA vapor atmosphere) The exhaust of the chamber 3 continues with the exhaust pump 47 etc. The on-off valve V4 is closed to stop the supply of nitrogen gas from the inert gas nozzle 25. Furthermore, in order to create an IPA vapor atmosphere in the chamber 3, the on-off valve V5 is opened to supply IPA vapor from the solvent vapor nozzle 27 into the chamber 3.

[0061] [Step S04] Supply of first IPA vapor (IPA replacement) The exhaust pump 47 is stopped and the on-off valve V7 is closed. The pressure inside the chamber 3 is reduced. The supply of IPA vapor from the solvent vapor nozzle 27 continues. In this state, the lifter 4 raises the substrate W from the processing position H3 to the drying position H2 while lifting the substrate W from the pure water in the processing bath 2. When the substrate W is exposed to the IPA vapor, the pure water adhering to the substrate W is replaced with IPA. Note that the effectiveness of the water repellent agent decreases when the water comes into contact with water. However, by performing the IPA replacement, this decrease in effectiveness can be prevented.

[0062] [Step S05] Supply of first IPA vapor (release of processing liquid from processing tank) The pressure inside the chamber 3 is reduced. In addition, the supply of IPA vapor from the solvent vapor nozzle 27 continues. In this state, the QDR valve 14 is opened to rapidly release pure water from the processing tank 2 onto the bottom surface of the chamber 3. After that, after the processing tank 2 is emptied, the QDR valve 14 is closed.

[0063] [Step S06] Supply of water repellent vapor By opening the on-off valve V7 while operating the exhaust pump 47, the gas in the chamber 3 is exhausted. This reduces the pressure in the chamber 3. Also, the on-off valve V5 is closed to stop the supply of solvent vapor from the solvent vapor nozzle 27. Furthermore, the on-off valve V6 is opened to supply water repellent vapor from the water repellent vapor nozzle 29 into the chamber 3. At this time, the substrate W is moved up and down between the two water repellent vapor nozzles 29 by the lifter 4. This allows the water repellent vapor to be supplied uniformly over the entire substrate W. This replaces the IPA adhering to the substrate W with the water repellent. The surface of the substrate W is modified by the water repellent.

[0064] [Step S07] Supply of second IPA vapor The exhaust of the chamber 3 by the exhaust pump 47 and the like continues. The on-off valve V6 is closed to stop the supply of the water repellent vapor from the water repellent vapor nozzle 29. In addition, the on-off valve V5 is opened to supply the IPA vapor from the solvent vapor nozzle 27. The supply of the IPA vapor (rinsing with the IPA vapor) is performed from step S07 (this step) to step S11. As a result, the atmosphere in the chamber 3 is replaced from the water repellent vapor to the IPA vapor. Furthermore, when the substrate W is exposed to the IPA vapor, the liquefied IPA adheres to the substrate W. As a result, the water repellent adhering to the surface of the substrate W is replaced with IPA, while the particles derived from the water repellent and organic matter are washed away from the substrate W by the IPA. The particles (foreign matter) derived from the water repellent are generated, for example, by direct contact between moisture and the water repellent.

[0065] [Step S08] Supplying second IPA vapor and discharging the processing liquid outside the chamber The exhaust of the chamber 3 by the exhaust pump 47 etc. continues. In addition, the supply of IPA vapor from the solvent vapor nozzle 27 continues. In this state, the pure water stored at the bottom of the chamber 3 is discharged to the outside of the chamber 3 for chamber cleaning.

[0066] 1, for example, when the pressure value P2 in the drain tank 53 is higher than the pressure value P1 in the chamber 3, if the on-off valve V8 is opened, a reverse flow from the drain tank 53 toward the chamber 3 occurs. Therefore, the pure water in the chamber 3 cannot be discharged to the drain tank 53. Therefore, first, with the three on-off valves V8, V11, and V12 closed, the on-off valve V9 is opened and the exhaust pump 57 is operated to exhaust the inside of the drain tank 53.

[0067] A pressure value P1 in the chamber 3 is measured by the pressure sensor PS1. A pressure value P2 in the drainage tank 53 is measured by the pressure sensor PS2. The exhaust pump 57 exhausts the inside of the drainage tank 53 so that the pressure value P2 in the drainage tank 53 becomes lower than the pressure value P1 in the chamber 3. After the pressure value P2 in the drainage tank 53 becomes lower than the pressure value P1 in the chamber 3, the on-off valve V8 is opened, whereby the pure water in the chamber 3 can be discharged to the drainage tank 53.

[0068] The pressure value P1 in the chamber 3 may be determined by the exhaust pump 47 controlling the exhaust flow rate. The pressure value P1 in the chamber 3 may be determined by the on-off valve V7 controlling the flow rate of gas passing through the exhaust pipe 45. The pressure value P2 in the drainage tank 53 may be determined by the exhaust pump 57 controlling the exhaust flow rate. The pressure value P2 in the drainage tank 53 may be determined by the on-off valve V9 controlling the flow rate of gas passing through the exhaust pipe 55.

[0069] [Step S09] Stop supplying the second IPA vapor and stopping exhaust of the processing liquid outside the chamber The exhaust of the chamber 3 by the exhaust pump 47 etc. continues. In addition, the supply of IPA vapor from the solvent vapor nozzle 27 continues. When the chamber 3 is emptied, the on-off valve V8 is closed.

[0070] [Step S10] Second supply of IPA vapor and cleaning process inside the chamber The control unit 81, while reducing the pressure in the chamber 3 using the exhaust pump 47, supplies pure water (cleaning liquid) into the chamber 3 from the cleaning liquid nozzle 16, and cleans the inside of the chamber 3, including the outer wall of the processing tank 2, by immersing the processing tank 2 in the pure water stored in the chamber 3.

[0071] A more specific description will be given. The exhaust of the chamber 3 by the exhaust pump 47 etc. continues. In addition, the supply of IPA vapor from the solvent vapor nozzle 27 continues. In this state, the on-off valve V3 is opened to supply pure water (cleaning liquid) from the cleaning liquid nozzle 16 into the chamber 3. When the liquid level sensor LS detects that the liquid level of the pure water has reached a height slightly below the exhaust port 43, the on-off valve V3 is closed to stop the supply of pure water from the cleaning liquid nozzle 16.

[0072] The outer wall of the treatment tank 2 is immersed for a preset period of time. The pure water stored in the lower part of the chamber 3 can clean the lower part of the chamber 3 (the outer surface 2A and the lower surface 2B of the treatment tank 2, and the inner surface 3A of the chamber 3).

[0073] Here, the effect of directly supplying pure water (cleaning liquid) to the chamber 3 by the cleaning liquid nozzle 16 will be described. In order to supply pure water (cleaning liquid) to the lower part of the chamber 3, there is a method of sending the pure water overflowing from the processing tank 2 to the lower part of the chamber 3 while supplying the pure water from the ejection pipe 5 to the processing tank 2. In this case, as shown in FIG. 4(a), mist generated from the pure water stored in the processing tank 2 under reduced pressure lower than atmospheric pressure is likely to adhere to the substrate W. If the mist adheres to the substrate W, the moisture in the mist directly contacts the water repellent agent, thereby reducing the effectiveness of the water repellent agent and possibly generating particles (foreign matter). For this reason, it is not preferable for the mist to adhere to the substrate W.

[0074] Therefore, a cleaning liquid nozzle 16 is provided at the bottom of the chamber 3. As a result, even if pure water is stored in the chamber 3, the surface of the pure water is relatively far from the substrate W, so that even if mist is generated, the mist can be prevented from adhering to the substrate W (see FIG. 4(b)). In addition, the shield plate 63 prevents the mist from moving to the upper part of the chamber 3. The inside of the chamber 3 is exhausted by the exhaust pump 47. Therefore, the mist is exhausted from the exhaust port 43. In addition, IPA vapor is supplied from the solvent vapor nozzle 27 to the upper part of the chamber 3 and is exhausted by the exhaust pump 47. Therefore, a downward air current is generated in the gaps G1 and G2 of the shield plate 63, and the mist can be prevented from moving to the upper part of the chamber 3.

[0075] [Step S11] Supplying a second IPA vapor and discharging the cleaning liquid outside the chamber The control unit 81 performs a discharge process to discharge the pure water (cleaning liquid) from the discharge port 49 provided on the bottom wall of the chamber 3 while the chamber 3 is decompressed by the exhaust pump 47. That is, the exhaust of the chamber 3 by the exhaust pump 47 and the like continues. In addition, the supply of IPA vapor from the solvent vapor nozzle 27 continues. In this state, the on-off valve V8 is opened to discharge the pure water in the chamber 3 into the drain tank 53. At this time, the exhaust pump 57 makes the pressure value P2 in the drain tank 53 lower than the pressure value P1 in the chamber 3. When the chamber 3 is emptied, the on-off valve V8 is closed.

[0076] Furthermore, the two steps S10 and S11 may be repeated a preset number of times (once or more than twice). That is, steps S10 and S11 are performed alternately. Note that each of steps S10 and S11 may be performed only once, and steps S10 and S11 may not be performed repeatedly.

[0077] [Step S12] Cleaning the processing tank (nitrogen gas supply) The exhaust pump 47 is stopped and the on-off valve V7 is closed. Furthermore, the on-off valve V5 is closed to stop the supply of IPA vapor from the solvent vapor nozzle 27. Furthermore, the on-off valve V4 is opened to supply nitrogen gas from the inert gas nozzle 25. This returns the pressure inside the chamber 3 from the reduced pressure state to atmospheric pressure.

[0078] [Step S13] Cleaning the processing tank (supply of cleaning liquid) The supply of nitrogen gas from the inert gas nozzle 25 continues. In this state, the on-off valve V1 is opened to supply pure water as a cleaning liquid from the ejection pipe 5 into the processing tank 2. The inside of the processing tank 2 is cleaned with the pure water stored in the processing tank 2. When the pure water is stored in the processing tank 2, the pure water supplied from the ejection pipe 5 into the processing tank 2 may be allowed to overflow from the processing tank 2.

[0079] [Step S14] Cleaning the processing tank (draining the cleaning solution) The supply of nitrogen gas from the inert gas nozzle 25 continues. In this state, the QDR valve 14 is opened to rapidly release the pure water from the processing tank 2 onto the bottom surface of the chamber 3. In addition, the on-off valve V8 is opened to drain the pure water (cleaning liquid) stored at the bottom of the chamber 3 into the drain tank 53. After the processing tank 2 is emptied, the QDR valve 14 is closed. After the chamber 3 is emptied, the on-off valve V8 is closed.

[0080] [Step S15] Second immersion treatment The supply of nitrogen gas from the inert gas nozzle 25 continues. In this state, the on-off valve V2 is opened and the diluted IPA liquid is supplied from the ejection pipe 5 into the processing tank 2. When a preset amount of diluted IPA liquid is stored in the processing tank 2, the lifter 4 lowers the substrate W from the drying position H2 to the processing position H3, thereby immersing the substrate W in the diluted IPA liquid in the processing tank for a preset period of time. This further cleans the substrate W. After the diluted IPA liquid has been supplied, the on-off valve V2 is closed.

[0081] [Step S16] Supply of third IPA vapor (drying process) By opening the on-off valve V7 while operating the exhaust pump 47, the gas in the chamber 3 is exhausted. This reduces the pressure in the chamber 3. In addition, the on-off valve V5 is opened to supply IPA vapor from the solvent vapor nozzle 27. After the atmosphere in the chamber 3 is filled with IPA vapor, the lifter 4 removes the substrate W from the diluted IPA liquid in the processing tank 2 and raises the substrate W from the processing position H3 to the drying position H2. This replaces the diluted IPA liquid adhering to the substrate W with IPA.

[0082] While continuing to evacuate the chamber 3 using the exhaust pump 47 or the like, the on-off valve V5 is closed to stop the supply of IPA vapor from the solvent vapor nozzle 27. With the supply of IPA vapor stopped and the pressure inside the chamber 3 reduced, the IPA adhering to the substrate W is actively volatilized, and the substrate W is dried. Note that, as indicated by the symbol NS in FIG. 3, nitrogen gas may be supplied from the inert gas nozzle 25 after the supply of IPA vapor is stopped.

[0083] [Step S17] Supply of nitrogen The exhaust pump 47 is stopped and the on-off valve V7 is closed. Furthermore, the on-off valve V4 is opened to supply nitrogen gas from the inert gas nozzle 25. This returns the pressure inside the chamber 3 from the reduced pressure state to atmospheric pressure.

[0084] If the inside of chamber 3 is contaminated and nitrogen gas is supplied when the inside of chamber 3 is at atmospheric pressure, particles at the lower part of chamber 3 are stirred up, and even though shield plate 63 is provided, the particles passing through gaps G1, G2 may adhere to substrate W. By performing a cleaning process for chamber 3, it is possible to reduce the particles stirred up by nitrogen gas, and as a result, it is possible to prevent particles from adhering to the substrate.

[0085] [Step S18] Unloading the substrate from the chamber The upper cover 23 is moved to release the top opening of the chamber 3. The lifter 4 lifts the substrate W held by the holding member 4A from the drying position H2 to the waiting position H1. The substrate W lifted to the waiting position H1 is moved to its next destination by a transport robot (not shown).

[0086] In steps S10 and S11, the process of cleaning chamber 3 and the process of draining the cleaning liquid are performed in parallel with the process of supplying the second IPA vapor. In this regard, the process of cleaning chamber 3 and the process of draining the cleaning liquid in steps S10 and S11 may be performed after the process of supplying the second IPA vapor in steps S07 to S11. By performing these processes in parallel, a series of substrate processes can be performed efficiently.

[0087] That is, the control unit 81 performs the chamber cleaning process while the solvent vapor is being supplied from the solvent vapor nozzle 27 into the chamber 3 (steps S10 and S11). Since the chamber cleaning process can be performed in parallel with the process of supplying the solvent vapor into the chamber 3, the substrate W can be processed efficiently.

[0088] According to this embodiment, a cleaning liquid is supplied from the cleaning liquid nozzle 16 into the chamber 3, and the processing tank 2 is immersed in the cleaning liquid stored in the chamber 3, thereby performing a chamber cleaning process for cleaning the inside of the chamber 3 including the outer wall of the processing tank 2. This makes it possible to clean not only the outer wall (including the outer surface 2A and the lower surface 2B) of the processing tank 2, but also particles adhering to the side walls and bottom wall in the chamber 3. Therefore, it is possible to prevent particles at the lower part of the chamber 3 from being blown up and adhering to the substrate W.

[0089] The substrate processing apparatus 1 further includes water repellent vapor nozzles 29 for supplying water repellent vapor into the chamber 3. After performing the immersion process (step S01), the control unit 81 performs a water repellent vapor supply process (step S06) for supplying water repellent vapor into the chamber 3 from the two water repellent vapor nozzles 29 in order to make the substrate W water repellent. After performing the water repellent vapor supply process, the control unit 81 performs a chamber cleaning process (step S10).

[0090] This allows the chamber 3 to be cleaned during a series of substrate processing (steps S01 to S18). Furthermore, the water repellent agent vapor supply process (step S06) for making the substrate W water repellent generates a large number of particles derived from the water repellent agent. These particles accumulate in the lower part of the chamber 3. Then, there is a problem that the particles at the lower part of the chamber 3 are stirred up and adhere to the substrate W. According to this embodiment, the chamber 3 can be cleaned during a series of substrate processing. Therefore, it is possible to prevent the particles at the lower part of the chamber 3 (including particles derived from the water repellent agent) from being stirred up and adhering to the substrate W.

[0091] The substrate processing apparatus 1 further includes an exhaust pump 47 that exhausts the inside of the chamber 3. The cleaning liquid nozzle 16 is provided at a lower part of the chamber 3 and supplies the cleaning liquid into the chamber 3. The control unit 81 performs a chamber cleaning process while the inside of the chamber 3 is depressurized by the exhaust pump 47.

[0092] As a result, the chamber 3 can be cleaned while the chamber 3 is depressurized by exhausting the inside of the chamber 3 with the exhaust pump 47. In addition, it is assumed that the cleaning liquid is overflowed from the processing tank 2 while the cleaning liquid is being supplied to the processing tank 2, and the cleaning liquid is stored in the chamber 3. In this case, when the chamber 3 is depressurized, there is a problem that mist is easily generated from the cleaning liquid stored in the processing tank 2, and the generated mist is easily attached to the substrate W. For example, if the moisture of the mist directly contacts the water repellent attached to the substrate W, the effect of the water repellent may be reduced. In addition, if the moisture directly contacts the water repellent, particles may be generated. In addition, it may cause other particle attachment. According to this embodiment, the cleaning liquid can be directly supplied into the chamber 3 from the cleaning liquid nozzle 16 provided at the bottom of the chamber 3, so that the cleaning liquid can be separated from the substrate W. Therefore, it is possible to suppress the generated mist from adhering to the substrate.

[0093] Furthermore, the exhaust pump 47 exhausts the air from the chamber 3 through an exhaust port 43 provided in a side wall of the chamber 3 on the side of the processing tank 2. The control unit 81 performs the chamber cleaning process while reducing the pressure in the chamber 3 while exhausting the air from the chamber 3 with the exhaust pump 47. Even if mist is generated from the cleaning liquid, the mist can be discharged from the exhaust port 43 by the exhaust pump 47.

[0094] The substrate processing apparatus 1 also includes a shield plate 63 that is provided between the outer wall of the processing tank 2 and the inner wall of the chamber 3 and that shields the atmosphere between the upper part of the chamber 3 and the lower part of the chamber 3. The shield plate 63 has gaps (openings) G1, G2 that allow the processing liquid overflowing from the processing tank 2 to flow to the lower part of the chamber 3. By providing the shield plate 63, even if mist is generated from the cleaning liquid stored in the chamber 3, the mist can be prevented from moving from the lower part to the upper part of the chamber 3. Furthermore, the particles that are stirred up can be prevented from moving from the lower part to the upper part of the chamber 3.

[0095] The cleaning liquid nozzle 16 is provided at the bottom of the chamber 3 at a position overlapping with the processing tank 2 in a plan view. This allows the cleaning liquid nozzle 16 to be hidden behind the processing tank 2. In addition, since the cleaning liquid nozzle 16 can be located farther away from the substrate W in the upper part of the chamber 3, even if mist is generated, it is possible to prevent the mist from adhering to the substrate W.

[0096] Furthermore, the control unit 81 performs a discharge process to discharge the cleaning liquid from the discharge port 49 provided in the chamber 3 while the exhaust pump 47 is depressurizing the chamber 3. The control unit 81 repeats the chamber cleaning process (step S10) and the discharge process (step S11) a preset number of times. The more the chamber cleaning process is repeated, the better the inside of the chamber 3 can be cleaned.

[0097] The substrate processing apparatus 1 further includes an inert gas nozzle 25 that supplies an inert gas into the chamber 3. After performing the drying process (step S16), the control unit 81 supplies an inert gas from the inert gas nozzle 25 into the chamber 3, thereby returning the reduced pressure inside the chamber 3 to atmospheric pressure (step S17). Since the cleaning process of the chamber 3 is performed, it is possible to reduce particles stirred up by the inert gas. Example 2

[0098] Next, a second embodiment of the present invention will be described with reference to the drawings. Note that descriptions that overlap with those of the first embodiment will be omitted. In the first embodiment, in the course of a series of substrate processing steps shown in steps S01 to S18 in Fig. 2, the chamber 3 is cleaned in a state where the pressure inside the chamber 3 is reduced in parallel with the supply of the second IPA vapor (steps S07 to S11). In this regard, in the second embodiment, the chamber 3 is cleaned in a state where the pressure inside the chamber 3 is atmospheric in parallel with the cleaning of the processing tank 2 (steps S28 to S31).

[0099] Fig. 5 is a schematic diagram of a substrate processing apparatus 1 according to Example 2. The substrate processing apparatus 1 shown in Fig. 5 is different from the substrate processing apparatus 1 of Example 1 shown in Fig. 1 in that it does not have a cleaning liquid nozzle 16 provided at the bottom of the chamber 3. The rest of the configuration is the same as that of the substrate processing apparatus 1 of Example 1. The ejection pipe 5 corresponds to the cleaning liquid nozzle of the present invention.

[0100] (3) Operation of the Substrate Processing Apparatus 1 Next, the operation of the substrate processing apparatus 1 will be described with reference to Fig. 6 and Fig. 7. Note that steps S21 to S27 and S32 to S35 shown in Fig. 6 are the same as steps S01 to S07 and S15 to S18 in the first embodiment shown in Fig. 2, and therefore detailed description thereof will be omitted. Note that in step S27, IPA vapor is supplied sufficiently.

[0101] The lifter 4 immerses the substrate W in the pure water stored in the processing tank 2 (step S21). Then, with the upper cover 23 closed, nitrogen gas is supplied from the inert gas nozzle 25 (step S22). Then, IPA vapor is supplied from the solvent vapor nozzle 27 (step S23). Then, the lifter 4 removes the substrate W from the processing tank 2 and exposes the substrate W to an atmosphere of IPA vapor (step S24). Then, the QDR valve 14 is opened to release the pure water in the processing tank 2 onto the bottom surface of the chamber 3 (step S25).

[0102] Thereafter, water repellent vapor is supplied from the water repellent vapor nozzle 29 to make the substrate W water repellent (step S26). Thereafter, IPA vapor is supplied from the solvent vapor nozzle 27 to wash away the water repellent and particles derived from the water repellent adhering to the surface of the substrate W with the IPA vapor (step S27). Note that in steps S22, S23, S26, and S27, the inside of the chamber 3 is evacuated and reduced in pressure by the exhaust pump 47. In steps S22 to S27, the inside of the chamber 3 is in a reduced pressure state.

[0103] [Step S28] Clean the processing tank (by supplying nitrogen gas) and drain the processing solution The exhaust pump 47 is stopped and the on-off valve V7 is closed. Furthermore, the on-off valve V5 is closed to stop the supply of IPA vapor from the solvent vapor nozzle 27. Furthermore, the on-off valve V4 is opened to supply nitrogen gas from the inert gas nozzle 25. This returns the pressure inside the chamber 3 from the reduced pressure state to atmospheric pressure.

[0104] After the pressure inside chamber 3 is returned to atmospheric pressure, the on-off valve V8 is opened to discharge the pure water (treatment liquid) stored in chamber 3 into the waste liquid tank 53. When all the pure water stored in chamber 3 has been discharged, that is, when the liquid level sensor LS detects that chamber 3 is empty, the on-off valve V8 is closed.

[0105] [Step S29] Cleaning the processing tank (supplying cleaning liquid to the processing tank) Thereafter, the supply of nitrogen gas from the inert gas nozzle 25 continues. The inside of the chamber 3 is at atmospheric pressure. In this state, the on-off valve V1 is opened to supply pure water as a cleaning liquid from the ejection pipe 5 into the processing tank 2. The pure water is stored in the processing tank 2.

[0106] [Step S30] Cleaning of the processing tank (supply of cleaning liquid to the chamber, cleaning inside the chamber) Thereafter, while supplying the pure water from the ejection pipe 5, the pure water overflowing from the opening 2C of the processing tank 2 is stored in the chamber 3. A shield plate 63 is provided on the side of the processing tank 2. Gaps G1 and G2 of the shield plate 63 allow the pure water overflowing from the processing tank 2 to flow to the lower part of the chamber 3. The pure water is stored up to a position slightly below the opening 2C of the processing tank 2, specifically, slightly below the shield plate 63. When the liquid level sensor LS detects that the liquid level has reached a preset height, the on-off valve V1 is closed to stop the supply of the pure water from the ejection pipe 5. The state in which the pure water is stored in the processing tank 2 and the chamber 3 is then maintained for a preset time.

[0107] [Step S31] Cleaning the processing tank (draining the cleaning solution) Thereafter, the supply of nitrogen gas from the inert gas nozzle 25 continues. The on-off valve V8 is opened to discharge the pure water stored in the chamber 3 into the drain tank 53. Furthermore, the QDR valve 14 is opened to release the pure water from the processing tank 2 onto the bottom surface of the chamber 3. The pure water in the processing tank 2 is also discharged into the drain tank 53 via the drain pipe 51. After the processing tank 2 is emptied, the QDR valve 14 is closed. After the chamber 3 is emptied, the on-off valve V8 is closed. Note that in order to maintain the cleanliness of the processing tank 2, the pure water in the chamber 3 may be discharged into the drain tank 53 first, and then the pure water in the processing tank 2 may be discharged into the drain tank.

[0108] Furthermore, the three steps S29 to S31 may be repeated a preset number of times (once or more than twice). The cleaning process of the processing tank 2 and the chamber 3 in steps S29 and S30 and the discharge process in step S31 are repeated a preset number of times. Note that each of steps S29 to S31 is performed only once, and steps S29 to S31 do not have to be performed repeatedly.

[0109] Thereafter, the diluted IPA liquid is supplied from the ejection pipe 5 into the processing tank 2, and the substrate W is immersed in the diluted IPA liquid stored in the processing tank 2 (step S32). Thereafter, the substrate W processed with the pure water is dried using IPA vapor supplied from the solvent vapor nozzle 27 (step S33). Thereafter, nitrogen gas is supplied to return the pressure inside the chamber 3 to atmospheric pressure (step S34). Thereafter, the substrate W is removed from the chamber 3 and moved to the next destination (step S35).

[0110] According to this embodiment, the ejection pipe 5 is provided at the bottom of the processing tank 2. The ejection pipe 5 supplies the cleaning liquid into the processing tank 2, and supplies the cleaning liquid into the chamber 3 through the processing tank 2. The control unit 81 supplies the cleaning liquid from the ejection pipe 5 into the processing tank 2 while the pressure inside the chamber 3 is atmospheric, and stores the cleaning liquid overflowing from the processing tank 2 in the chamber 3. Furthermore, the control unit 81 performs a chamber cleaning process to clean the chamber 3 including the outer wall of the processing tank 2 by immersing the processing tank 2 in the cleaning liquid stored in the chamber 3. This allows the cleaning process of the chamber 3 to be performed while the pressure inside the chamber 3 is atmospheric. Therefore, it is possible to prevent particles at the bottom of the chamber 3 from being lifted up and adhering to the substrate W. In addition, since the cleaning liquid is also supplied to the processing tank 2, the cleaning process of the processing tank 2 and the cleaning process of the chamber 3 can be performed in parallel.

[0111] In steps S29 to S31, the supply of cleaning liquid to processing tank 2, the supply of cleaning liquid to chamber 3 (cleaning of chamber 3), and the discharge of cleaning liquid are performed in parallel with the cleaning of processing tank 2. In this regard, the supply of cleaning liquid to chamber 3 (cleaning of chamber 3), etc. may be performed before or after cleaning of processing tank 2. By performing these steps in parallel, a series of substrate processing steps can be performed efficiently. Example 3

[0112] Next, a third embodiment of the present invention will be described with reference to the drawings. Note that descriptions overlapping with those of the first and second embodiments will be omitted. In the first embodiment, the chamber 3 is cleaned in the middle of a series of substrate processing steps shown in steps S01 to S18 of Fig. 2. In this regard, in the third embodiment, the chamber 3 is cleaned between two successive series of substrate processing steps.

[0113] The configuration of the substrate processing apparatus 1 of the third embodiment is the same as the configuration of the substrate processing apparatus 1 of the second embodiment shown in FIG.

[0114] (4) Operation of the Substrate Processing Apparatus 1 Next, the operation of the substrate processing apparatus 1 will be described with reference to Fig. 8 to Fig. 10. Fig. 8 is a diagram for explaining the operation of the substrate processing apparatus according to the third embodiment. Fig. 9 is a timing chart showing the operation (series of substrate processing) of the substrate processing apparatus according to the third embodiment. Fig. 10 is a timing chart showing the operation (cleaning of the chamber 3) of the substrate processing apparatus according to the third embodiment.

[0115] In this embodiment, the cleaning process of the chamber 3 is performed between a predetermined series of substrate processes (steps S41 to S54 in FIG. 9) and the next series of substrate processes (steps S41 to S54 in FIG. 9). The cleaning process of the chamber 3 is performed every time a series of substrate processes (steps S41 to S54) including immersion (step S41) and drying (step S52) is performed on a preset number of substrates W or a preset lot number of substrates W.

[0116] The substrates W are processed in units of lots. For example, 25 substrates W accommodated in a carrier for transporting the substrates W are treated as one lot.

[0117] In the substrate processing sequence shown in Fig. 9, steps S41 to S54 shown in Fig. 9 are the same as steps S01 to S07 and S13 to S18 in the first embodiment shown in Fig. 3 and step S28 in the second embodiment shown in Fig. 7, and therefore description thereof will be omitted. Note that in step S47, IPA vapor is supplied sufficiently.

[0118] Next, the cleaning process of the chamber 3 in this embodiment will be described. See FIG. 8 and FIG. 10. The control unit 81 counts, for example, the number of substrates W that have undergone a series of substrate processes. Then, when a predetermined (for example, the fifth) series of substrate processes has been performed, it is assumed that the number of substrates W that have undergone a series of substrate processes has become equal to or greater than a preset number. At this time, the control unit 81 performs a cleaning process of the chamber 3 between the predetermined (for example, the fifth) series of substrate processes and the next (for example, the sixth) series of substrate processes. Note that the count number of substrates W is reset (to 0). The same applies to the number of lots. That is, the control unit 81 counts the number of lots that have undergone a series of substrate processes. Then, it is assumed that when a predetermined (for example, the fifth) series of substrate processes has been performed, the number of lots that have undergone a series of substrate processes has become equal to or greater than a preset number. At this time, the control unit 81 performs a cleaning process of the chamber 3 between the predetermined (for example, the fifth) series of substrate processes and the next (for example, the sixth) series of substrate processes.

[0119] [Step S61] Preparation for cleaning The inside of the chamber 3 is at atmospheric pressure. Note that from step S61 to step S65, the inside of the chamber 3 is at atmospheric pressure. In step S61, the chamber 3 is empty, with no processing liquid or the like stored therein.

[0120] [Step S62] Supply of cleaning liquid Thereafter, while the QDR valve 14 and the on-off valves V7 and V8 are closed, the on-off valve V2 is opened to supply, for example, diluted IPA liquid as a cleaning liquid from the ejection pipe 5 to the processing tank 2. Furthermore, the diluted IPA liquid is made to overflow from the opening 2C of the processing tank 2, and the diluted IPA overflowing from the processing tank 2 is stored in the chamber. Then, when the liquid level sensor LS detects that the diluted IPA in the chamber 3 has reached a preset liquid level, the on-off valve V2 is closed to stop the supply of the diluted IPA liquid. Then, the state in which the diluted IPA liquid is stored in the processing tank 2 and the chamber 3 is maintained for a preset time. In this embodiment, the diluted IPA liquid is supplied as a cleaning liquid, but in this respect, diluted H2O2 liquid or pure water may be used.

[0121] [Step S63] Discharge of cleaning solution Thereafter, the on-off valve V8 is opened to discharge the diluted IPA liquid stored in the chamber 3 into the drain tank 53. Furthermore, the QDR valve 14 is opened to release the diluted IPA liquid from the processing tank 2 onto the bottom surface of the chamber 3. The diluted IPA liquid in the processing tank 2 is also discharged into the drain tank 53 via the drain pipe 51. After the processing tank 2 is emptied, the QDR valve 14 is closed. Furthermore, after the chamber 3 is emptied, the on-off valve V8 is closed.

[0122] These steps S62 and S63 may be repeated a preset number of times (once or more than once). Note that, if necessary, steps S62 and S63 may be performed once each, and steps S62 and S63 may not be repeated.

[0123] [Step S64] Supply of rinsing liquid After step S63, while the QDR valve 14 and the on-off valves V7 and V8 are closed, the on-off valve V1 is opened to supply, for example, pure water as a rinsing liquid from the spray pipe 5 to the processing tank 2. Furthermore, the pure water is made to overflow from the opening 2C of the processing tank 2, and the pure water overflowing from the processing tank 2 is stored in the chamber 3. Then, when the liquid level sensor LS detects that the pure water in the chamber 3 has reached a preset liquid level, the on-off valve V1 is closed to stop the supply of pure water. Thereafter, the state in which the pure water is stored in the processing tank 2 and the chamber 3 is maintained for a preset time.

[0124] [Step S65] Draining the rinse solution Thereafter, the on-off valve V8 is opened to discharge the pure water stored in the chamber 3 into the drain tank 53. Furthermore, the QDR valve 14 is opened to release the pure water from the processing tank 2 onto the bottom surface of the chamber 3. The pure water in the processing tank 2 is also discharged into the drain tank 53 via the drain pipe 51. After the processing tank 2 is emptied, the QDR valve 14 is closed. Furthermore, after the chamber 3 is emptied, the on-off valve V8 is closed.

[0125] These steps S64 and S65 may be repeated a preset number of times (once or more than once). Note that, if necessary, steps S64 and S65 may be performed once each, and steps S64 and S65 may not be repeated.

[0126] After the cleaning process of the chamber 3 in steps S61 to S65, the next series of substrate processes (S41 to S54) are performed.

[0127] According to this embodiment, the control unit 81 performs a chamber cleaning process between two successive series of substrate treatments, each time a series of substrate treatments including immersion and drying processes is performed on a preset number or a preset number of lots of substrates W. A cleaning process of the chamber 3 can be performed between two successive series of substrate treatments, each time a series of substrate treatments is performed on a preset number or a preset number of lots of substrates W. This makes it possible to prevent particles at the bottom of the chamber 3 from being blown up and adhering to the substrates W.

[0128] Further, the ejection pipe 5 is provided at the bottom of the treatment tank 2, and supplies the cleaning liquid into the treatment tank 2. The control unit 81 supplies the cleaning liquid from the ejection pipe 5 into the treatment tank 2 while the inside of the chamber 3 is at atmospheric pressure, and also stores the cleaning liquid that overflows from the treatment tank 2 in the chamber 3, and further immerses the treatment tank 2 in the cleaning liquid stored in the chamber 3, thereby cleaning the inside of the chamber 3 including the outer wall of the treatment tank 2. This makes it possible to simultaneously clean the treatment tank 2 and the chamber 3.

[0129] The present invention is not limited to the above-described embodiment, but can be modified as follows.

[0130] (1) In the above-described third embodiment, in step S62, diluted IPA liquid is supplied as the cleaning liquid from the ejection pipe 5. When pure water is used as the cleaning liquid, steps S64 and S65 may be omitted.

[0131] (2) In the above-described Examples 1 and 2, between two successive substrate processing series, no cleaning process is performed on the chamber 3. In this regard, in each of Examples 1 and 2, in addition to performing a cleaning process on the chamber 3 midway through a substrate processing series, as in Example 3, a cleaning process on the chamber 3 may be performed between two successive substrate processing series.

[0132] 8 and 10, the series of substrate processing (steps S41 to S54) may be replaced with a series of substrate processing (steps S01 to S18 shown in FIGS. 2 and 3). Also, the series of substrate processing (steps S41 to S54) may be replaced with a series of substrate processing (steps S21 to S35 shown in FIGS. 6 and 7).

[0133] (3) In the above-mentioned Examples 2 and 3, the cleaning liquid was supplied only from the ejection pipe 5 (see FIG. 5). In this regard, a cleaning liquid nozzle 16 shown in FIG. 1 may be provided at the bottom of the chamber 3. When supplying a cleaning liquid (e.g., pure water), the cleaning liquid may be supplied from the ejection pipe 5 and the cleaning liquid nozzle 16 to the processing tank 2 and the chamber 3, respectively. This can shorten the time required to supply the cleaning liquid.

[0134] In the third embodiment, a rinse liquid may be supplied from the ejection pipe 5 and the cleaning liquid nozzle 16 to the processing tank 2 and the chamber 3, respectively.

[0135] (4) In the above-described embodiment 1 and modified examples (2) and (3), the cleaning liquid nozzle 16 supplies the cleaning liquid (e.g., pure water) into the chamber 3 without any obstruction. In this regard, as shown in Fig. 11, a nozzle cover 71 that covers the cleaning liquid nozzle 16 may be provided at the bottom of the chamber 3 so as to face the upward outlet 16A of the cleaning liquid nozzle 16. The nozzle cover 71 may be attached to the bottom of the chamber 3.

[0136] The nozzle cover 71 is a box-shaped member whose bottom surface is open. The nozzle cover 71 includes a ceiling wall 71A and a plurality of (for example, two or four) side walls 71B connected to the ceiling wall 71A. The ceiling wall 71A does not have a hole 71C, but the side walls 71B have a hole 71C through which the cleaning liquid passes. The side walls 71B are formed longitudinally so as to extend in the Y direction. The area of ​​the hole 71C is larger than that of the discharge port 16A.

[0137] The discharge port of the cleaning liquid nozzle 16 faces upward, for example, and the cleaning liquid discharged upward is blocked by the ceiling wall 71A, but the cleaning liquid is supplied to the outside of the nozzle cover 71 through the hole 71C in the side wall 71B. When the pressure inside the chamber 3 is reduced, the cleaning liquid nozzle 16 is likely to become a source of mist generation. For this reason, the nozzle cover 71 is made to face the discharge port 16A of the cleaning liquid nozzle 16. Therefore, even if mist is generated near the cleaning liquid nozzle 16, it can be held by the nozzle cover 71, and the cleaning liquid can be stored in the chamber 3 while suppressing the diffusion of the mist. In addition, since the cleaning liquid passes through the hole 71C in the side wall 71B, the force of the flow of the cleaning liquid can be suppressed.

[0138] A gap G3 may be formed between the nozzle cover 71 and the bottom surface of the chamber 3 so as not to obstruct the flow at the bottom surface of the chamber 3.

[0139] (5) In the above-described embodiment 1 and each of the modified examples (2) to (4), the two cleaning liquid nozzles 16 are provided at the bottom of the chamber 3, at positions overlapping with the processing tank 2 in a plan view. In this regard, the two cleaning liquid nozzles 16 may be provided at corners of the lower part of the chamber 3, as shown in FIG. 12. The cleaning liquid nozzle 16 provided at the corner may have an outlet facing horizontally. Therefore, the cleaning liquid is discharged horizontally from the cleaning liquid nozzle 16.

[0140] (6) In the above-described embodiment 1 and each of the modified examples (2) to (4), the two cleaning liquid nozzles 16 are each provided at the bottom of the chamber 3 or on the bottom surface inside the chamber 3. In this regard, as shown in FIG. 13 , the two cleaning liquid nozzles 16 may each be provided away from the bottom surface inside the chamber 3. Furthermore, the two cleaning liquid nozzles 16 may each be provided on the inner wall of the chamber 3 at a position lower than the shield plate 63 and higher than the bottom surface inside the chamber 3. That is, the two cleaning liquid nozzles 16 may each be provided in the lower part inside the chamber 3.

[0141] Furthermore, the control unit 81 may supply the cleaning liquid from the cleaning liquid nozzle 16 into the chamber 3 while applying the cleaning liquid to the outer wall of the processing tank 3, with the chamber 3 decompressed by the exhaust pump. Since the liquid flows on the bottom surface of the chamber 3, particles are relatively unlikely to accumulate on the bottom surface of the chamber 3. However, for example, the outer wall of the processing tank 2 is a portion where the liquid does not easily flow even if floating particles adhere thereto, and so particles accumulate there. Since the cleaning liquid is stored in the chamber 3 while applying the cleaning liquid to that portion, it is easy to remove particles that have adhered to the outer wall of the processing tank 2.

[0142] (7) In the above-described embodiments and modifications, the substrate processing apparatus 1 includes two exhaust pumps 47, 57. In this regard, the substrate processing apparatus 1 does not have to include, for example, the exhaust pump 57. That is, the exhaust pump 47 may exhaust the inside of the chamber 3 via the exhaust pipe 45 and also exhaust the inside of the waste liquid tank 53 via the exhaust pipe 55.

[0143] For example, the on-off valve V7 is configured to be able to control the flow rate of gas passing through the exhaust pipe 45. Furthermore, the on-off valve V9 is configured to be able to control the flow rate of gas passing through the exhaust pipe 55. The control unit 81 controls the flow rates of gas passing through the two exhaust pipes 45, 55 by operating the two on-off valves V7, V9. This makes the pressure value P2 in the drain tank 53 smaller than the pressure value P1 in the chamber 3.

[0144] (8) In the above-described embodiments and modifications, the particles at the lower part of the chamber 3 are stirred up when nitrogen gas is supplied to return the pressure inside the chamber 3 to atmospheric pressure (steps S17, S34, and S53). In this regard, there is a possibility that the particles may be stirred up in steps S12, S28, S48, and the like.

[0145] (9) In each of the above-described embodiments and modifications, for example, in step S06 shown in Fig. 2, the substrate W is made water-repellent by supplying vapor of a water-repellent agent. In this regard, if it is not necessary to make the substrate W water-repellent, step S06 of supplying vapor of a water-repellent agent and steps related thereto may be omitted. The same applies to step S26 in Fig. 6 and step S46 in Fig. 9. [Explanation of symbols]

[0146] 1 ... Substrate processing equipment 2 … Treatment tank 3 … Chamber 5 … Ejection pipe 14 … QDR valve 16 … Cleaning fluid nozzle 25 ... Inert gas nozzle 27 ... Solvent vapor nozzle 29 ... Water repellent steam nozzle 43 ... Exhaust port 47 ... Exhaust pump 63 ... Shield plate G1, G2 … Gap

Claims

1. a processing tank for storing a processing liquid; a chamber surrounding the treatment tank; a solvent vapor nozzle for supplying a solvent vapor into the chamber; a cleaning liquid nozzle for supplying a cleaning liquid into the chamber; A control unit, the control unit performs an immersion process of immersing the substrate in the processing liquid stored in the processing tank for a preset period of time, and performs a drying process of drying the substrate, which has been processed with the processing liquid and then pulled up from the processing tank, by using the solvent vapor supplied from the solvent vapor nozzle; The control unit supplies the cleaning liquid from the cleaning liquid nozzle into the chamber and immerses the processing tank in the cleaning liquid stored in the chamber, thereby performing a chamber cleaning process to clean the inside of the chamber including the outer wall of the processing tank.

2. 2. The substrate processing apparatus according to claim 1, The control unit performs the chamber cleaning process after performing the immersion process, The substrate processing apparatus according to claim 1, wherein the control unit performs the drying process after performing the chamber cleaning process.

3. 3. The substrate processing apparatus according to claim 2, a water repellent vapor nozzle for supplying water repellent vapor into the chamber; the control unit performs a water repellent vapor supply process of supplying the water repellent vapor from the water repellent vapor nozzle into the chamber in order to make the substrate water repellent after the immersion process; the control unit performs the chamber cleaning process after performing the water repellent vapor supply process.

4. 4. The substrate processing apparatus according to claim 1, Further comprising an exhaust pump for exhausting the inside of the chamber, the cleaning liquid nozzle is provided at a lower portion in the chamber and supplies the cleaning liquid into the chamber; The control unit performs the chamber cleaning process while reducing the pressure inside the chamber by the exhaust pump.

5. 5. The substrate processing apparatus according to claim 4, The exhaust pump exhausts the inside of the chamber through an exhaust port provided in a side wall of the chamber on a side of the processing tank; the control unit performs the chamber cleaning process while reducing the pressure inside the chamber by evacuating the inside of the chamber with the exhaust pump.

6. 5. The substrate processing apparatus according to claim 4, A substrate processing apparatus further comprising a shield plate provided between an outer wall of the processing tank and an inner wall of the chamber, for isolating the atmosphere between an upper part of the chamber and a lower part of the chamber, the shield plate having an opening for allowing processing liquid overflowing from the processing tank to flow to the lower part of the chamber.

7. 5. The substrate processing apparatus according to claim 4, The cleaning liquid nozzle is provided at a bottom of the chamber at a position overlapping with the processing tank in a plan view.

8. 5. The substrate processing apparatus according to claim 4, the control unit performs the chamber cleaning process while the solvent vapor is being supplied into the chamber from the solvent vapor nozzle.

9. 5. The substrate processing apparatus according to claim 4, the control unit performs a discharge process of discharging the cleaning liquid from a discharge port provided in the chamber while the chamber is depressurized by the exhaust pump; The control unit repeats the chamber cleaning process and the discharge process a preset number of times.

10. 5. The substrate processing apparatus according to claim 4, further comprising an inert gas nozzle for supplying an inert gas into the chamber; The substrate processing apparatus according to claim 1, wherein the control unit returns the reduced pressure inside the chamber to atmospheric pressure by supplying an inert gas from the inert gas nozzle into the chamber after the drying process.

11. 5. The substrate processing apparatus according to claim 4, the cleaning liquid nozzle is disposed in a position facing an outer wall of the treatment tank, The control unit supplies the cleaning liquid from the cleaning liquid nozzle into the chamber while applying the cleaning liquid to an outer wall of the processing tank while reducing the pressure of the chamber using the exhaust pump.

12. 5. The substrate processing apparatus according to claim 4, a nozzle cover provided at a bottom portion of the chamber so as to face an upward outlet of the cleaning liquid nozzle; The nozzle cover includes a ceiling wall and a plurality of side walls connected to the ceiling wall and having holes through which the cleaning liquid passes.

13. 4. The substrate processing apparatus according to claim 1, the cleaning liquid nozzle is provided at a bottom portion of the treatment tank and supplies the cleaning liquid into the treatment tank; The control unit supplies the cleaning liquid from the cleaning liquid nozzle into the processing tank while the chamber is at atmospheric pressure, and stores the cleaning liquid that overflows from the processing tank in the chamber, and further performs a chamber cleaning process to clean the chamber including the outer wall of the processing tank by immersing the processing tank in the cleaning liquid stored in the chamber.

14. 2. The substrate processing apparatus according to claim 1, The control unit performs the chamber cleaning process between two successive series of substrate treatments including the immersion process and the drying process for a predetermined number of substrates or a predetermined lot number of substrates.

15. 15. The substrate processing apparatus according to claim 14, the cleaning liquid nozzle is provided at a bottom portion of the treatment tank and supplies the cleaning liquid into the treatment tank; The control unit supplies the cleaning liquid from the cleaning liquid nozzle into the processing tank while the chamber is at atmospheric pressure, and stores the cleaning liquid that overflows from the processing tank in the chamber.

16. a processing tank for storing a processing liquid; a chamber surrounding the treatment tank; A substrate processing method for a substrate processing apparatus comprising: an immersion step of immersing a substrate in the treatment liquid stored in the treatment tank for a predetermined period of time; a drying step of drying the substrate, which has been treated with the treatment liquid and then removed from the treatment bath, using a solvent vapor supplied from a solvent vapor nozzle; a chamber cleaning step of supplying a cleaning liquid into the chamber from a cleaning liquid nozzle and immersing the treatment tank in the cleaning liquid stored in the chamber to clean the chamber including the outer wall of the treatment tank; A substrate processing method comprising:

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