Dicing and die bonding integrated film, die bonding film, and manufacturing method of semiconductor device

Abstract

To provide a dicing / die bonding integrated film having a clinging layer and an adhesive layer, in which the adhesive strength between the clinging layer and the adhesive layer can be sufficiently reduced after UV irradiation.SOLUTION: A dicing / die bonding integrated film 100 has a base material 40, a dicing tape 50 having a clinging layer 30 provided on the base material 40, and a die bonding film 10 disposed on the clinging layer 30 of the dicing tape 50. The die bonding film 10 contains silver-containing particles that are surface-treated with saturated fatty acids. The content of the silver-containing particles is 75 mass% or more, based on the total amount of the die bonding film 10.SELECTED DRAWING: Figure 2

Description

[Technical field]

[0001] The present disclosure relates to a dicing / die bonding integrated film, a die bonding film, and a method for manufacturing a semiconductor device. [Background technology]

[0002] Conventionally, semiconductor devices are manufactured through the following steps. First, a semiconductor wafer is attached to a dicing adhesive sheet, and in this state, the semiconductor wafer is diced into semiconductor chips (dicing step). Then, an ultraviolet irradiation step, a pick-up step, a pressure bonding step, a die bonding step, etc. are performed. Patent Document 1 discloses an adhesive sheet (dicing die bonding sheet) that has both the function of fixing the semiconductor wafer in the dicing step and the function of adhering the semiconductor chip to a substrate in the die bonding step. In the dicing step, the semiconductor wafer and the adhesive layer are diced into individual chips with adhesive pieces attached.

[0003] In recent years, devices called power semiconductor devices that control electric power and the like have become widespread. Power semiconductor devices tend to generate heat due to the current supplied to them, and therefore require excellent heat dissipation. Patent Document 2 discloses a conductive film-like adhesive and a dicing tape with a film-like adhesive that have higher heat dissipation properties after curing than before curing. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2008-218571 A [Patent Document 2] Patent No. 6396189 Summary of the Invention [Problem to be solved by the invention]

[0005] In the process of developing a semiconductor device with excellent heat dissipation, the present inventors have found that when a dicing-die bonding integrated film having an adhesive layer and an adhesive layer made of a die bonding film containing silver-containing particles in an amount (for example, 75% by mass or more based on the total amount of the die bonding film) that provides sufficient heat dissipation is used, the adhesive strength between the adhesive layer and the adhesive layer may not be sufficiently reduced after ultraviolet irradiation. If the adhesive strength between the adhesive layer and the adhesive layer is not sufficiently reduced, a problem may occur in which the chip with the adhesive piece cannot be picked up from the adhesive layer in the subsequent pick-up process.

[0006] Therefore, one aspect of the present disclosure aims to provide a dicing-die bonding integrated film having an adhesive layer and an adhesive layer, which is capable of sufficiently reducing the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet light irradiation. [Means for solving the problem]

[0007] One aspect of the present disclosure relates to a dicing-die bonding integrated film. The dicing-die bonding integrated film includes a dicing tape having a substrate and an adhesive layer provided on the substrate, and a die bonding film arranged on the adhesive layer of the dicing tape. The die bonding film contains silver-containing particles surface-treated with saturated fatty acid, and the content of the silver-containing particles is 75 mass% or more based on the total amount of the die bonding film. According to such a dicing-die bonding integrated film, it is possible to sufficiently reduce the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet irradiation. According to the study by the present inventors, it was found that when silver-containing particles surface-treated with unsaturated fatty acid are used, the adhesive strength between the adhesive layer and the adhesive layer is not sufficiently reduced and tends to be maintained as it is. The reason for this is not necessarily clear, but it is considered that, for example, ultraviolet irradiation advances the reaction between the unsaturated bond of the unsaturated fatty acid and the components of the adhesive layer, making it difficult to separate the adhesive layer and the adhesive layer. Therefore, it is presumed that by using silver-containing particles surface-treated with saturated fatty acid instead of unsaturated fatty acid, the reaction with the components of the adhesive layer can be suppressed, and the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet irradiation can be sufficiently reduced. In addition, by using silver-containing particles surface-treated with saturated fatty acid, the compatibility with other resin components in the adhesive layer is improved, and the surface roughness (Ra) of the adhesive layer tends to be improved. By improving the surface roughness (Ra) of the adhesive layer, the adhesion between the adhesive layer and the adhesive layer is improved, and for example, the defect (chip jump) that the chip with the adhesive piece is detached from the adhesive layer during the dicing process can be suppressed. Furthermore, the die shear strength after the die bonding process also tends to be excellent.

[0008] The carbon number of the saturated fatty acid may be from 8 to 20. By using such a fatty acid, it becomes possible to more sufficiently reduce the adhesive strength between the pressure-sensitive adhesive layer and the adhesive layer after ultraviolet irradiation.

[0009] The die bonding film may further contain a thermosetting resin, a curing agent, and an elastomer. The die bonding film containing these tends to have an easier adjustment of the surface roughness (Ra).

[0010] The thermosetting resin may contain an epoxy resin that is liquid at 25° C. When the thermosetting resin contains such an epoxy resin, a die bonding film with improved surface roughness (Ra) tends to be obtained.

[0011] Another aspect of the present disclosure relates to a method for manufacturing a semiconductor device. The method for manufacturing a semiconductor device includes a step of attaching the die bonding film of the dicing-die bonding integrated film described above to a semiconductor wafer, a step of dividing the semiconductor wafer and the die bonding film, a step of irradiating the adhesive layer with ultraviolet light, a step of picking up the semiconductor chip to which the die bonding film piece is attached from the dicing tape, and a step of bonding the semiconductor chip to a support substrate via the die bonding film piece. According to this method for manufacturing a semiconductor device, since the dicing-die bonding integrated film described above is used, it is possible to manufacture a semiconductor device with excellent heat dissipation properties.

[0012] Another aspect of the present disclosure relates to a die bonding film. The die bonding film contains silver-containing particles that have been surface-treated with a saturated fatty acid. The content of the silver-containing particles is 75 mass% or more based on the total amount of the die bonding film. Effect of the Invention

[0013] According to the present disclosure, a dicing-die bonding integrated film having an adhesive layer and an adhesive layer, capable of sufficiently reducing the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet irradiation, is disclosed. Also, according to the present disclosure, a method for manufacturing a semiconductor device using such a dicing-die bonding integrated film is provided. Furthermore, according to the present disclosure, a die bonding film suitable for use in such a dicing-die bonding integrated film is provided. [Brief description of the drawings]

[0014] [Figure 1] FIG. 1 is a schematic cross-sectional view showing one embodiment of a die bonding film. [Diagram 2] FIG. 2 is a schematic cross-sectional view showing one embodiment of a dicing / die bonding integrated film. [Diagram 3] 3A, 3B, 3C, 3D, 3E, and 3F are schematic cross-sectional views showing one embodiment of a method for manufacturing a semiconductor device, in which (a), (b), (c), (d), (e), and (f) are schematic cross-sectional views showing each step. [Figure 4] FIG. 4 is a schematic cross-sectional view showing one embodiment of a semiconductor device. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0015] Hereinafter, the embodiments of the present disclosure will be described with reference to the drawings as appropriate. However, the present disclosure is not limited to the following embodiments. In the following embodiments, the components (including steps, etc.) are not essential unless specifically stated. The size of the components in each figure is conceptual, and the relative relationship of the size between the components is not limited to that shown in each figure.

[0016] The same applies to the numerical values ​​and their ranges in this specification, and they do not limit the present disclosure. In this specification, a numerical range indicated using "~" indicates a range including the numerical values ​​before and after "~" as the minimum and maximum values, respectively. In the numerical ranges described in stages in this specification, the upper limit or lower limit value described in one numerical range may be replaced with the upper limit or lower limit value of another numerical range described in stages. In addition, in the numerical ranges described in this specification, the upper limit or lower limit value of the numerical range may be replaced with a value shown in the examples.

[0017] In this specification, (meth)acrylate means acrylate or the corresponding methacrylate, and the same applies to other similar expressions such as (meth)acryloyl group, (meth)acrylic copolymer, etc.

[0018] [Die bonding film] Fig. 1 is a schematic cross-sectional view showing one embodiment of a die bonding film. The die bonding film 10 shown in Fig. 1 has a first surface 10A and a second surface 10B opposite to the first surface 10A. The first surface 10A can be a surface to be placed on an adhesive layer of a dicing tape, as described below. The die bonding film 10 can be provided on a support film 20, as shown in Fig. 1. The die bonding film 10 is thermosetting, and can be in a semi-cured (B stage) state and then in a completely cured (C stage) state after a curing process.

[0019] The die bonding film 10 contains (a) silver-containing particles surface-treated with a saturated fatty acid, and may further contain, as necessary, (b) a thermosetting resin, (c) a curing agent, and (d) an elastomer.

[0020] (a) Component: Silver-containing particles surface-treated with saturated fatty acid The component (a) is a component used to enhance the heat dissipation property of the die bonding film. The silver-containing particles (component (a1)) before surface treatment in the component (a) may be particles containing silver on the surface of the particles, for example, silver particles made of silver or silver-coated metal particles in which the surface of metal particles (copper particles, etc.) is coated with silver. The silver-coated metal particles may be, for example, silver-coated copper particles. The component (a1) may be silver particles made of silver.

[0021] The (a) component is obtained by surface-treating the (a1) component with a saturated fatty acid. For example, by surface-treating the (a1) component with a fatty acid, it is possible to prevent the particles from agglomerating together. In addition, since the (a) component is obtained by surface-treating the (a1) component with a saturated fatty acid, not an unsaturated fatty acid, it is presumed that the reaction between the unsaturated bond of the unsaturated fatty acid and the components of the adhesive layer can be suppressed. This is thought to make it possible to sufficiently reduce the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet irradiation.

[0022] Examples of saturated fatty acids include caproic acid (hexanoic acid), heptanoic acid (enanthic acid), caprylic acid (octanoic acid), pelargonic acid (nonanoic acid), capric acid (decanoic acid), undecylic acid, lauric acid, tridecylic acid, myristic acid, pentadecanoic acid, palmitic acid, margaric acid, stearic acid, nonadecylic acid, arachidic acid, henicosylic acid, behenic acid, tricosylic acid, lignoceric acid, etc. Among these, the number of carbon atoms of the saturated fatty acid may be, for example, 6 or more, 8 or more, 10 or more, 12 or more, 14 or more, or 16 or more, and may be 30 or less, 24 or less, 22 or less, or 20 or less. When the number of carbon atoms of the saturated fatty acid is within such a range, it is possible to more sufficiently reduce the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet irradiation. In addition, the compatibility with other resin components in the adhesive layer is improved, the surface roughness (Ra) of the adhesive layer tends to be improved, and further, the die shear strength after the die bonding step tends to be excellent.

[0023] The method of surface-treating the component (a1) with a saturated fatty acid is not particularly limited, and a conventionally known method can be applied. For example, in the production of silver-containing particles by a liquid phase reduction method using a reducing agent, the component (a1) can be surface-treated with a saturated fatty acid by using a saturated fatty acid as a surface treatment agent (lubricant).

[0024] The shape of the (a) component and the (a1) component are not particularly limited, and may be, for example, flake-like, resin-like, spherical, etc., but the shape of the (a) component is preferably spherical. When the (a) component is spherical, a die bonding film with improved surface roughness (Ra) tends to be obtained. The shape of the (a) component tends to maintain the shape of the (a1) component.

[0025] The average particle size of the (a) component and the (a1) component may be 0.01 to 10 μm. When the average particle size of the (a) component is 0.01 μm or more, the viscosity increase when the adhesive varnish is prepared can be prevented, a desired amount of the (a) component can be contained in the die bonding film, and the wettability of the die bonding film to the adherend can be ensured, tending to exhibit better adhesion. When the average particle size of the (a) component is 10 μm or less, the film formability is excellent, and the heat dissipation due to the addition of the (a) component tends to be improved. In addition, by setting the average particle size in this range, the thickness of the die bonding film can be made thinner, and the semiconductor chips can be highly laminated, and the occurrence of chip cracks due to the (a) component protruding from the die bonding film tends to be prevented. The average particle size of the (a) component and the (a1) component may be 0.1 μm or more, 0.5 μm or more, 1.0 μm or more, or 1.5 μm or more, and may be 8.0 μm or less, 7.0 μm or less, 6.0 μm or less, 5.0 μm or less, 4.0 μm or less, or 3.0 μm or less. When the average particle size of the (a) component is 5.0 μm or less, a die bonding film with improved surface roughness (Ra) tends to be obtained. The average particle size of the (a) component is the particle size (D) when the ratio (volume fraction) of the volume of the (a) component to the total volume is 50%. 50(a) Average particle size of the component (D 50 ) can be determined by measuring a suspension of component (a) in water by a laser scattering method using a laser scattering type particle size measuring device (e.g., Microtrac). The average particle size of component (a1) is also synonymous with the average particle size of component (a), and can be determined by a similar method. In addition, the average particle size of component (a) tends to maintain the average particle size of component (a1).

[0026] The components (a) and (a1) are preferably spherical particles having an average particle size of 5.0 μm or less.

[0027] The content of the (a) component is 75% by mass or more based on the total amount of the die bonding film. When the content of the (a) component is 75% by mass or more based on the total amount of the die bonding film, the thermal conductivity of the die bonding film can be improved, and as a result, the heat dissipation property can be improved. The content of the (a) component may be 77% by mass or more, 80% by mass or more, 83% by mass or more, or 85% by mass or more based on the total amount of the die bonding film. The upper limit of the content of the (a) component is not particularly limited, but may be 98% by mass or less, 96% by mass or less, or 95% by mass or less based on the total amount of the die bonding film.

[0028] (b) Component: Thermosetting resin Component (b) is a component that has the property of forming three-dimensional bonds between molecules and curing by heating or the like, and is a component that exhibits adhesive properties after curing. Component (b) may be an epoxy resin. Component (b) may contain an epoxy resin that is liquid at 25°C. The epoxy resin may be any epoxy resin that has an epoxy group in the molecule. The epoxy resin may have two or more epoxy groups in the molecule.

[0029] Examples of epoxy resins include bisphenol A type epoxy resins, bisphenol F type epoxy resins, bisphenol S type epoxy resins, phenol novolac type epoxy resins, cresol novolac type epoxy resins, bisphenol A novolac type epoxy resins, bisphenol F novolac type epoxy resins, stilbene type epoxy resins, triazine skeleton-containing epoxy resins, fluorene skeleton-containing epoxy resins, triphenol methane type epoxy resins, biphenyl type epoxy resins, xylylene type epoxy resins, biphenyl aralkyl type epoxy resins, naphthalene type epoxy resins, dicyclopentadiene type epoxy resins, polyfunctional phenols, and diglycidyl ether compounds of polycyclic aromatics such as anthracene. These may be used alone or in combination of two or more. Among these, the epoxy resin may be a bisphenol type epoxy resin or a cresol novolac type epoxy resin from the viewpoint of heat resistance of the cured product.

[0030] The epoxy resin may contain an epoxy resin that is liquid at 25° C. By containing such an epoxy resin, a die bonding film with improved surface roughness (Ra) tends to be obtained. Examples of commercially available epoxy resins that are liquid at 25° C. include EXA-830CRP (trade name, manufactured by DIC Corporation) and YDF-8170C (trade name, manufactured by Nippon Steel Chemical & Material Co., Ltd.).

[0031] The epoxy equivalent of the epoxy resin is not particularly limited, but may be 90 to 300 g / eq, 110 to 290 g / eq, or 110 to 290 g / eq. When the epoxy equivalent of the (A) component is within such a range, the bulk strength of the die bonding film is maintained, and the flowability of the adhesive composition when forming the die bonding film tends to be easily ensured.

[0032] The content of the (b) component may be 0.1 mass% or more, 1 mass% or more, 2 mass% or more, or 3 mass% or more, and may be 15 mass% or less, 12 mass% or less, 10 mass% or less, 8 mass% or less, or 6 mass% or less, based on the total amount of the die bonding film.

[0033] When the (b) component contains an epoxy resin that is liquid at 25° C., the mass ratio of the epoxy resin to the (b) component (mass of the epoxy resin / total mass of the (b) component) may be, in percentage, 10 to 100%, 40 to 100%, 60% to 100%, or 80% to 100%. When the (b) component contains an epoxy resin that is liquid at 25° C., the content of the epoxy resin may be 0.1 mass% or more, 1 mass% or more, 2 mass% or more, or 3 mass% or more, and may be 15 mass% or less, 12 mass% or less, 10 mass% or less, 8 mass% or less, or 6 mass% or less, based on the total amount of the die bonding film.

[0034] (c) Component: Hardener The component (c) may be a phenolic resin that can be a curing agent for epoxy resins. Any phenolic resin can be used without particular limitation as long as it has a phenolic hydroxyl group in the molecule. Examples of phenolic resins include novolac-type phenolic resins obtained by condensing or co-condensing phenols such as phenol, cresol, resorcin, catechol, bisphenol A, bisphenol F, phenylphenol, and aminophenol and / or naphthols such as α-naphthol, β-naphthol, and dihydroxynaphthalene with a compound having an aldehyde group such as formaldehyde under an acidic catalyst, allylated bisphenol A, allylated bisphenol F, allylated naphthalenediol, phenol novolac, and phenol aralkyl resins, naphthol aralkyl resins, biphenyl aralkyl-type phenolic resins, and phenyl aralkyl-type phenolic resins synthesized from phenols such as phenol and / or naphthols with dimethoxy-paraxylene or bis(methoxymethyl)biphenyl, and the like. These may be used alone or in combination of two or more.

[0035] The hydroxyl equivalent of the phenol resin may be 40 to 300 g / eq, 70 to 290 g / eq, or 100 to 280 g / eq. When the hydroxyl equivalent of the phenol resin is 40 g / eq or more, the storage modulus of the film tends to be improved, and when it is 300 g / eq or less, defects due to the generation of foaming, outgassing, etc. can be prevented.

[0036] The ratio of the epoxy equivalent of the epoxy resin (b) to the hydroxyl equivalent of the phenol resin (c) (epoxy equivalent of the epoxy resin (b) / hydroxyl equivalent of the phenol resin (c)) may be 0.30 / 0.70 to 0.70 / 0.30, 0.35 / 0.65 to 0.65 / 0.35, 0.40 / 0.60 to 0.60 / 0.40, or 0.45 / 0.55 to 0.55 / 0.45 from the viewpoint of curability. When the equivalent ratio is 0.30 / 0.70 or more, more sufficient curability tends to be obtained. When the equivalent ratio is 0.70 / 0.30 or less, it is possible to prevent the viscosity from becoming too high, and more sufficient fluidity can be obtained.

[0037] The content of the (c) component may be 0.1 mass% or more, 0.5 mass% or more, 1 mass% or more, or 2 mass% or more, and may be 15 mass% or less, 12 mass% or less, 10 mass% or less, 8 mass% or less, or 6 mass% or less, based on the total amount of the die bonding film.

[0038] (d) Component: Elastomer Examples of the (d) component include polyimide resin, acrylic resin, urethane resin, polyphenylene ether resin, polyetherimide resin, phenoxy resin, modified polyphenylene ether resin, etc. The (d) component may be any of these resins having a crosslinkable functional group, or may be an acrylic resin having a crosslinkable functional group. Here, the acrylic resin means a polymer containing a structural unit derived from a (meth)acrylic acid ester. The acrylic resin may be a polymer containing a structural unit derived from a (meth)acrylic acid ester having a crosslinkable functional group such as an epoxy group, an alcoholic or phenolic hydroxyl group, or a carboxy group as a structural unit. The acrylic resin may also be an acrylic rubber such as a copolymer of a (meth)acrylic acid ester and an acrylonitrile. These may be used alone or in combination of two or more.

[0039] Commercially available acrylic resins include, for example, SG-70L, SG-708-6, WS-023 EK30, SG-280 EK23, HTR-860P-3, HTR-860P-3CSP, and HTR-860P-3CSP-3DB (all manufactured by Nagase ChemteX Corporation).

[0040] The glass transition temperature (Tg) of the (d) component may be -50 to 50°C or -30 to 20°C. When the Tg of the acrylic resin is -50°C or higher, the tackiness of the die bonding film tends to be lowered, and thus the handleability tends to be improved. When the Tg of the acrylic resin is 50°C or lower, the fluidity of the adhesive composition when forming the die bonding film tends to be more sufficiently ensured. Here, the glass transition temperature (Tg) of the (d) component means a value measured using a DSC (differential scanning calorimeter) (for example, Thermo Plus 2, product name, manufactured by Rigaku Corporation).

[0041] The weight average molecular weight (Mw) of the (d) component may be 50,000 to 1.6 million, 100,000 to 1.4 million, or 300,000 to 1.2 million. When the weight average molecular weight of the (d) component is 50,000 or more, the film-forming property tends to be more excellent. When the weight average molecular weight of the (d) component is 1.6 million or less, the flowability of the adhesive composition when forming a die bonding film tends to be more excellent. The weight average molecular weight (Mw) is a value measured by gel permeation chromatography (GPC) and converted using a calibration curve of standard polystyrene.

[0042] The measurement device, measurement conditions, etc. for the weight average molecular weight (Mw) of the component (d) are, for example, as follows: Pump: L-6000 (manufactured by Hitachi, Ltd.) Column: A column consisting of Gelpack GL-R440 (Hitachi Chemical Co., Ltd.), Gelpack GL-R450 (Hitachi Chemical Co., Ltd.), and Gelpack GL-R400M (Hitachi Chemical Co., Ltd.) (each 10.7 mm (diameter) × 300 mm) connected in this order. Eluent: tetrahydrofuran (hereinafter referred to as "THF") Sample: 120 mg of sample dissolved in 5 mL of THF Flow rate: 1.75mL / min

[0043] The content of the (d) component may be 0.1 mass% or more, 0.5 mass% or more, 1 mass% or more, or 2 mass% or more, and may be 10 mass% or less, 8 mass% or less, 6 mass% or less, or 5 mass% or less, based on the total amount of the die bonding film.

[0044] The die bonding film 10 may further contain (e) a curing accelerator.

[0045] (e) Component: Curing accelerator By containing the component (e), the die bonding film tends to be able to achieve both adhesiveness and connection reliability. Examples of the component (e) include imidazoles and their derivatives, organic phosphorus compounds, secondary amines, tertiary amines, and quaternary ammonium salts. These may be used alone or in combination of two or more. Among these, the component (e) may be imidazoles and their derivatives from the viewpoint of reactivity.

[0046] Examples of imidazoles include 2-methylimidazole, 1-benzyl-2-methylimidazole, 1-cyanoethyl-2-phenylimidazole, 1-cyanoethyl-2-methylimidazole, etc. These may be used alone or in combination of two or more.

[0047] The content of the component (e) may be 0.001 to 1 mass % based on the total amount of the die bonding film. When the content of the component (e) is in this range, there is a tendency that both adhesiveness and connection reliability can be more effectively achieved.

[0048] The die bonding film 10 may further contain, as other components in addition to the components (a) to (e), a coupling agent, an antioxidant, a rheology control agent, a leveling agent, etc. Examples of coupling agents include γ-ureidopropyltriethoxysilane, γ-mercaptopropyltrimethoxysilane, 3-phenylaminopropyltrimethoxysilane, 3-(2-aminoethyl)aminopropyltrimethoxysilane, etc. The content of the other components may be 0.01 to 3 mass% based on the total amount of the die bonding film.

[0049] The die bonding film 10 shown in FIG. 1 can be produced by forming an adhesive composition containing the above-mentioned component (a), and, if necessary, components (b) to (e) and other components, into a film. Such a die bonding film 10 can be formed by applying the adhesive composition to a support film 20. The adhesive composition can be used as an adhesive varnish diluted with a solvent. When an adhesive varnish is used, the adhesive varnish is applied to the support film 20, and the solvent is removed by heating and drying, thereby forming the die bonding film 10.

[0050] The solvent is not particularly limited as long as it can dissolve components other than the component (a). Examples of the solvent include aromatic hydrocarbons such as toluene, xylene, mesitylene, cumene, and p-cymene; aliphatic hydrocarbons such as hexane and heptane; cyclic alkanes such as methylcyclohexane; cyclic ethers such as tetrahydrofuran and 1,4-dioxane; ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, and 4-hydroxy-4-methyl-2-pentanone; esters such as methyl acetate, ethyl acetate, butyl acetate, methyl lactate, ethyl lactate, and γ-butyrolactone; carbonates such as ethylene carbonate and propylene carbonate; and amides such as N,N-dimethylformamide, N,N-dimethylacetamide, and N-methyl-2-pyrrolidone. These may be used alone or in combination of two or more. Among these, the solvent may be toluene, xylene, methyl ethyl ketone, methyl isobutyl ketone, or cyclohexanone from the viewpoints of solubility and boiling point. The solid component concentration in the adhesive varnish may be 10 to 80% by mass based on the total mass of the adhesive varnish.

[0051] The adhesive varnish can be prepared by mixing and kneading the components (a) to (e), other components, and a solvent. The order of mixing and kneading the components is not particularly limited and can be set appropriately. Mixing and kneading can be performed by appropriately combining a dispersing machine such as a normal stirrer, a grinding machine, a triple roll, a ball mill, or a bead mill. After preparing the adhesive varnish, air bubbles in the varnish can be removed by vacuum deaeration or the like.

[0052] The support film 20 is not particularly limited, and examples thereof include films of polytetrafluoroethylene, polyethylene, polypropylene, polymethylpentene, polyethylene terephthalate, polyimide, etc. The support film may be subjected to a release treatment. The thickness of the support film 20 may be, for example, 10 to 200 μm or 20 to 170 μm.

[0053] The adhesive varnish can be applied to the support film 20 by a known method, such as knife coating, roll coating, spray coating, gravure coating, bar coating, curtain coating, etc. The conditions for heat drying are not particularly limited as long as the solvent used is sufficiently volatilized, and may be, for example, at 50 to 200° C. for 0.1 to 90 minutes.

[0054] The thickness of the die bonding film 10 can be appropriately adjusted depending on the application, and may be, for example, 3 to 200 μm. When the thickness of the die bonding film 10 is 3 μm or more, the adhesive strength with the semiconductor wafer tends to be sufficient, and when it is 200 μm or less, the heat dissipation tends to be sufficient. The thickness of the die bonding film 10 may be 5 to 100 μm or 10 to 50 μm from the viewpoints of adhesive strength and thinning of the semiconductor device.

[0055] In the die bonding film 10, the surface roughness of the first surface 10A may be, for example, 1.0 μm or less. Here, the first surface 10A is the surface placed on the adhesive layer of the dicing tape (i.e., the surface opposite to the surface of the die bonding film 10 in contact with the support film 20). In this specification, the surface roughness means the arithmetic mean roughness Ra (JIS B 0601-2001), and the arithmetic mean roughness Ra means a value calculated by the method described in the examples. The measurement magnification may be 50 to 100 times.

[0056] The surface roughness of the first surface 10A may be, for example, 0.9 μm or less, 0.8 μm or less, 0.7 μm or less, or 0.6 μm or less, from the viewpoint of preventing a decrease in adhesiveness due to the surface roughness. The surface roughness of the first surface 10A may be, for example, 0.1 μm or more, 0.2 μm or more, or 0.3 μm or more, from the viewpoint of preventing a decrease in anchor effect due to an excessively high surface smoothness.

[0057] In the die bonding film of the present disclosure, the component (a) is surface-treated with a saturated fatty acid, not an unsaturated fatty acid, and therefore does not have a site that reacts with the components of the adhesive layer, so that the reaction with the components of the adhesive layer can be suppressed, and the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet irradiation can be sufficiently reduced. Therefore, the die bonding film of the present disclosure can be combined with a dicing tape having an adhesive layer made of an ultraviolet-curing adhesive, and can be suitably used in a dicing-die bonding integrated film.

[0058] [Dicing and die bonding integrated film] 2 is a schematic cross-sectional view showing one embodiment of a dicing-die bonding integrated film. The dicing-die bonding integrated film 100 shown in FIG. 2 includes a dicing tape 50 having a substrate 40 and an adhesive layer 30 provided on the substrate 40, and a die bonding film 10 arranged on the adhesive layer 30 of the dicing tape 50. The die bonding film 10 has a first surface 10A and a second surface 10B opposite to the first surface 10A. The dicing-die bonding integrated film 100 may include a support film 20 on the second surface 10B of the die bonding film 10.

[0059] Examples of the substrate 40 in the dicing tape 50 include plastic films such as polytetrafluoroethylene film, polyethylene terephthalate film, polyethylene film, polypropylene film, polymethylpentene film, and polyimide film. Furthermore, the substrate 40 may be subjected to a surface treatment such as primer coating, UV treatment, corona discharge treatment, polishing treatment, and etching treatment, as necessary.

[0060] The adhesive layer 30 may be an adhesive layer made of an adhesive used in the field of dicing tape, and may be an adhesive layer made of a pressure-sensitive adhesive or an adhesive layer made of an ultraviolet-curing adhesive. Since the die bonding film does not have a site that reacts with the component of the adhesive layer, the adhesive layer 30 may be an adhesive layer made of an ultraviolet-curing adhesive. When the adhesive layer 30 is an adhesive layer made of an ultraviolet-curing adhesive, the adhesive layer 30 may have a property that the adhesiveness decreases when irradiated with ultraviolet light. The following describes the case where the adhesive layer 30 is an adhesive layer made of an ultraviolet-curing adhesive.

[0061] The dicing / die bonding integrated film 100 can be produced by preparing a dicing tape 50 and a die bonding film 10 , and attaching the first surface 10 A of the die bonding film 10 to the adhesive layer 30 of the dicing tape 50 .

[0062] In the dicing / die bonding integrated film 100, the die bonding film 10 contains 75 mass % or more of the component (a) based on the total amount of the die bonding film. The dicing / die bonding integrated film having such an adhesive layer and a bonding agent layer has excellent heat dissipation properties, and can sufficiently reduce the adhesive strength between the adhesive layer and the bonding agent layer after ultraviolet irradiation.

[0063] [Manufacturing method for semiconductor device (semiconductor package)] 3A, 3B, 3C, 3D, 3E, and 3F are schematic cross-sectional views showing one embodiment of a method for manufacturing a semiconductor device, in which (a), (b), (c), (d), (e), and (f) are schematic cross-sectional views showing each step. The method for manufacturing a semiconductor device includes a step of attaching the die bonding film 10 (adhesive layer) (the second surface 10B) of the above-mentioned dicing-die bonding integrated film 100 to a semiconductor wafer W (wafer lamination step, see Figures 3(a) and (b)), a step of dividing the semiconductor wafer W and the die bonding film 10 (adhesive layer) (dicing step, see Figure 3(c)), a step of irradiating the adhesive layer 30 (through the substrate 40) with ultraviolet rays (ultraviolet irradiation step, see Figure 3(d)), a step of picking up the semiconductor chip Wa (semiconductor chip 60 with adhesive piece) to which the die bonding film piece 10a is attached from the adhesive layer 30a (pickup step, see Figure 3(e)), and a step of adhering the semiconductor chip 60 with adhesive piece to a support substrate 80 through the die bonding film piece 10a (semiconductor chip adhering step, see Figure 3(f)).

[0064] <Wafer lamination process> First, the dicing / die bonding integrated film 100 is placed in a predetermined device. Then, the second surface 10B of the die bonding film 10 (adhesive layer) of the dicing / die bonding integrated film 100 is attached to the surface Ws of the semiconductor wafer W (see FIGS. 3(a) and 3(b)). The circuit surface of the semiconductor wafer W is preferably provided on the surface opposite to the surface Ws.

[0065] <Dicing process> Next, the semiconductor wafer W and the die bonding film 10 (adhesive layer) are diced (see FIG. 3(c)). At this time, a part of the adhesive layer 30, or the entire adhesive layer 30 and a part of the base material 40 may be diced. In this manner, the dicing / die bonding integrated film 100 also functions as a dicing sheet.

[0066] <Ultraviolet irradiation process> Next, the adhesive layer 30 is irradiated with ultraviolet light (through the substrate 40) (see FIG. 3(d)). This causes the adhesive layer 30 to harden, and since the die bonding film 10 (adhesive layer) does not have any sites that react with the components of the adhesive layer, the adhesive strength between the adhesive layer 30 and the die bonding film 10 (adhesive layer) can be sufficiently reduced. For the ultraviolet light irradiation, it is preferable to use ultraviolet light with a wavelength of 200 to 400 nm. The ultraviolet light irradiation conditions are an illuminance and an irradiation amount of 30 to 240 mW / cm, respectively. 2 range and 50~500mJ / cm 2 It is preferable to adjust the range to be within the range of 100 to 200 mm.

[0067] <Pickup process> Next, the substrate 40 is expanded to separate the diced semiconductor chips 60 with adhesive pieces from each other, while the semiconductor chips 60 with adhesive pieces pushed up by the needles 72 from the substrate 40 side are sucked by the suction collet 74 to be picked up from the adhesive layer 30a (see FIG. 3(e)). The semiconductor chips 60 with adhesive pieces have a semiconductor chip Wa and a die bonding film piece 10a. The semiconductor chip Wa is obtained by dicing the semiconductor wafer W into individual pieces, and the die bonding film piece 10a is obtained by dicing the die bonding film 10 into individual pieces. The adhesive layer 30a is obtained by dicing the adhesive layer 30 into individual pieces. The adhesive layer 30a may remain on the substrate 40 when the semiconductor chips 60 with adhesive pieces are picked up. In the pick-up process, it is not necessarily necessary to expand the substrate 40, but by expanding the substrate 40, the pick-up property can be further improved.

[0068] The amount of push-up by the needle 72 can be set appropriately. Furthermore, from the viewpoint of ensuring sufficient pick-up performance even for an extremely thin wafer, for example, two-stage or three-stage push-up may be performed. Furthermore, the semiconductor chip 60 with the adhesive piece attached may be picked up by a method other than the method using the suction collet 74.

[0069] <Semiconductor chip bonding process> After picking up the semiconductor chip 60 with the adhesive piece, the semiconductor chip 60 with the adhesive piece is bonded to the support substrate 80 via the die bonding film piece 10a by thermocompression bonding (see FIG. 3(f)). A plurality of semiconductor chips 60 with adhesive pieces may be bonded to the support substrate 80.

[0070] The method for manufacturing a semiconductor device may further include, as necessary, a step of electrically connecting the semiconductor chip Wa and the support substrate 80 by wire bonding, and a step of resin-sealing the semiconductor chip Wa on the surface 80A of the support substrate 80 using a resin sealing material.

[0071] Fig. 4 is a schematic cross-sectional view showing one embodiment of a semiconductor device. The semiconductor device 200 shown in Fig. 4 can be manufactured through the above-mentioned steps. In the semiconductor device 200, the semiconductor chip Wa and the support substrate 80 may be electrically connected by wire bonds 70. In the semiconductor device 200, the semiconductor chip Wa may be resin-encapsulated on the front surface 80A of the support substrate 80 using a resin encapsulant 92. Solder balls 94 may be formed on the surface of the support substrate 80 opposite to the front surface 80A for electrical connection with an external substrate (motherboard). EXAMPLES

[0072] The present disclosure will be described below with reference to examples, but the present disclosure is not limited to these examples.

[0073] <Preparation of adhesive varnish> Cyclohexanone was added to (b) epoxy resin as a thermosetting resin, (c) phenolic resin as a curing agent, and (d) acrylic rubber as an elastomer, with the symbols and composition ratios (unit: parts by mass) shown in Table 1, and the mixture was obtained by stirring. After each component was dissolved, (a) silver-containing particles surface-treated with saturated fatty acid were added to the mixture, and the mixture was stirred using a dispersing blade to disperse each component until it was uniform. Thereafter, (e) a curing accelerator was added, and each component was dispersed until it was uniform, to obtain adhesive varnishes A to C with a solid content of 78% by mass.

[0074] The symbols for each component in Table 1 represent the following products.

[0075] (a) Silver-containing particles surface-treated with saturated fatty acid SF134 Ag Flake (stearic acid) (SF134 Ag Flake (manufactured by Ames Advanced Materials Co., Ltd.) is silver particles with a surface treatment using stearic acid, shape: spherical, average particle size (laser 50% particle size (D 50 )):2.2μm) SF134 Ag Flake (decanoic acid) (SF134 Ag Flake (manufactured by Ames Advanced Materials Co., Ltd.) is a silver particle surface-treated with decanoic acid, shape: spherical, average particle size (laser 50% particle size (D 50 )):2.2μm)

[0076] (a') Silver-containing particles surface-treated with unsaturated fatty acid AO-UCI-9 (product name, silver-coated copper particles surface-treated with oleic acid, manufactured by DOWA Electronics Co., Ltd., shape: spherical, average particle size (laser 50% particle size (D 50 )):2.3μm)

[0077] (b) Thermosetting resin EXA-830CRP (product name, manufactured by DIC Corporation, bisphenol type epoxy resin, epoxy equivalent: 159g / eq, liquid at 25℃)

[0078] (c) Hardener MEH-7800M (product name, manufactured by Meiwa Kasei Co., Ltd., phenolic resin, viscosity (150°C): 0.31-0.43 Pa·s (3.1-4.3 poise), hydroxyl equivalent: 175 g / eq)

[0079] (d) Elastomer HTR-860P-3CSP (product name, Nagase ChemteX Corporation, glycidyl group-containing acrylic rubber, weight average molecular weight: 1 million, Tg: -7°C)

[0080] (e) Curing accelerator 2PZ-CN (product name, Shikoku Chemical Industry Co., Ltd., 1-cyanoethyl-2-phenylimidazole)

[0081] [Table 1]

[0082] Example 1 <Preparation of die bonding film> Adhesive varnish A was used to prepare the die bonding film. The adhesive varnish A, which had been vacuum degassed, was applied onto a polyethylene terephthalate (PET) film (thickness 38 μm) that had been subjected to a release treatment, which was a support film. The applied varnish was heated and dried in two stages, at 90° C. for 5 minutes and then at 130° C. for 5 minutes, to prepare a die bonding film of Example 1 having a thickness of 20 μm in a B-stage state on the support film.

[0083] <Surface roughness measurement> The surface roughness of the first surface (the surface opposite to the support film) of the die bonding film was measured. The surface roughness (arithmetic mean roughness Ra, JIS B 0601-2001) was measured at a magnification of 50 times using a shape measuring laser microscope VK-X100 (manufactured by Keyence Corporation). The results are shown in Table 2.

[0084] <Production of integrated dicing and die bonding tape> A dicing tape having a substrate and an adhesive layer (product name: 6363-30, manufactured by Hitachi Chemical Co., Ltd.) was prepared, and the adhesive layer of the dicing tape was bonded to the die bonding film of Example 1 with a rubber roll to produce the integrated dicing and die bonding tape of Example 1 having the substrate, adhesive layer, and adhesive layer (die bonding film) in that order.

[0085] <Measurement of T-peel strength between adhesive layer and adhesive layer before and after UV irradiation> The integrated dicing and die bonding tape of Example 1 was prepared and used to measure the T-peel strength between the adhesive layer and the adhesive layer. An Autograph EZ-S 50N (manufactured by Shimadzu Corporation) was used for the measurement. An easy-cut tape (manufactured by Oji Tack Co., Ltd.) was attached to the adhesive layer (die bonding film) side of the integrated dicing and die bonding tape, and the integrated dicing and die bonding tape was cut into a size of 25 mm wide and 100 mm long to obtain a sample. Using this sample, the T-peel strength between the adhesive layer and the adhesive layer was measured before and after ultraviolet irradiation at a chuck distance of 50 mm and a speed of 300 mm / min. The ultraviolet irradiation was performed with a halogen lamp at 80 mW / cm. 2 , 200mJ / cm 2 The measurements were carried out three times before and three times after UV irradiation, and the average value of the three measurements was taken as the peel strength. The results are shown in Table 2.

[0086] <Measurement of die shear strength> The dicing-die bonding integrated film of Example 1 was prepared. The support film of the dicing-die bonding integrated film was peeled off, and the die bonding film (adhesive layer) of the dicing-die bonding integrated film was attached to a semiconductor wafer having a thickness of 400 μm at 70 ° C. using a film laminator (manufactured by Teikoku Taping System Co., Ltd.) to obtain a laminate. Next, the laminate was diced into individual pieces having a size of 5 mm × 5 mm to obtain semiconductor chips to which the die bonding film pieces were attached. Dicing was performed by a step cut method using two blades, and dicing blades SD2000-FF and SD2000-EE were used. In the step cut method, dicing was performed to a position of 200 μm deep in the semiconductor wafer in the first cut, and then dicing was performed to a position of 20 μm deep in the base material of the dicing tape in the second cut. The dicing conditions were a blade rotation speed of 4000 rpm and a cutting speed of 30 mm / sec. The semiconductor chip with the obtained die-bonding film piece attached was subjected to thermocompression bonding of the die-bonding film with the semiconductor wafer attached to the lead frame at a temperature of 120°C, a pressure of 0.1 MPa, and a time of 5 seconds to obtain a test specimen. The obtained test specimen was then heated at 110°C for 1 hour, and then at 170°C for 3 hours to harden the die-bonding film piece, and the die shear strength was measured at 250°C using a universal bond tester (product name: Dage Series 4000, manufactured by Arctec Co., Ltd.). The results are shown in Table 2.

[0087] Example 2 Except for using adhesive varnish B to prepare the die bonding film, the die bonding film and the integrated dicing / die bonding tape of Example 2 were obtained in the same manner as in Example 1. The surface roughness, the T-peel strength between the adhesive layer and the adhesive layer before and after ultraviolet irradiation, and the die shear strength of the die bonding film and the integrated dicing / die bonding tape of Example 2 were measured in the same manner as in Example 1. The results are shown in Table 2.

[0088] Comparative Example 1 A die bonding film and a dicing / die bonding integrated tape of Comparative Example 1 were obtained in the same manner as in Example 1, except that adhesive varnish C was used to prepare the die bonding film. For the die bonding film and the dicing / die bonding integrated tape of Comparative Example 1, the surface roughness, the T-peel strength between the adhesive layer and the adhesive layer before and after ultraviolet irradiation, and the die shear strength were measured in the same manner as in Example 1. The results are shown in Table 2.

[0089] [Table 2]

[0090] As shown in Table 2, the dicing-die bonding integrated tapes of Examples 1 and 2, which contain silver-containing particles surface-treated with saturated fatty acid, were found to have sufficiently low T-peel strength and sufficiently high die shear strength after ultraviolet irradiation, compared to the dicing-die bonding integrated tape of Comparative Example 1, which contains silver-containing particles surface-treated with unsaturated fatty acid. These results confirmed that the dicing-die bonding integrated film comprising the adhesive layer and the adhesive layer of the present disclosure is capable of sufficiently reducing the adhesive strength between the adhesive layer and the adhesive layer after ultraviolet irradiation. [Explanation of symbols]

[0091] 10...die bonding film, 10A...first surface, 10B...second surface, 10a...die bonding film piece, 20...support film, 30...adhesive layer, 40...substrate, 50...dicing tape, 60...semiconductor chip with adhesive piece, 70...wire bond, 72...needle, 74...suction collet, 80...support substrate, 92...resin encapsulant, 94...solder ball, 100...dicing and die bonding integrated film, 200...semiconductor device.

Claims

1. a dicing tape having a substrate and an adhesive layer provided on the substrate; a die bonding film disposed on the adhesive layer of the dicing tape; Equipped with The die bonding film contains silver-containing particles surface-treated with a saturated fatty acid, a thermosetting resin, and an elastomer, The content of the silver-containing particles is 75 mass% or more based on the total amount of the die bonding film. Integrated dicing and die bonding film.

2. The saturated fatty acid has 8 to 20 carbon atoms.

2. The dicing and die bonding integrated film according to claim 1.

3. The die bonding film further contains a curing agent.

3. The dicing and die bonding integrated film according to claim 1 or 2.

4. The thermosetting resin contains an epoxy resin that is liquid at 25°C. The dicing and die bonding integrated film according to claim 3 .

5. A step of attaching the die bonding film of the dicing and die bonding integrated film according to any one of claims 1 to 4 to a semiconductor wafer; singulating the semiconductor wafer and the die bonding film; A step of irradiating the adhesive layer with ultraviolet light; picking up the semiconductor chip having the die bonding film piece attached thereto from the dicing tape; bonding the semiconductor chip to a support substrate via the die bonding film piece; Equipped with A method for manufacturing a semiconductor device.

6. The present invention comprises silver-containing particles that have been surface-treated with a saturated fatty acid, a thermosetting resin, and an elastomer, The content of the silver-containing particles is 75 mass% or more based on the total amount of the die bonding film. Die bonding film.

7. The saturated fatty acid has 8 to 20 carbon atoms. The die bonding film according to claim 6 .

8. Further containing a curing agent. The die bonding film according to claim 6 or 7.

9. The thermosetting resin contains an epoxy resin that is liquid at 25°C. The die bonding film according to claim 8 .

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